Transcript
![Page 1: [Co(NH3 6 - units.it...5027 till (triply degenerate) eg (doubly degenerate) Ligand group orbitals for the F6 fragment in SF6 (Oh). These orbitals only include contributions from the](https://reader030.vdocuments.us/reader030/viewer/2022011901/5f095f307e708231d4268569/html5/thumbnails/1.jpg)
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[Co(NH3)6]3+
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Molecole ipervalenti: SF6 (gruppo Oh)
sei 2pz radiali E 8C3 6C2 6C4 3C2 i 6S4 8S6 3sh 6sd
6 0 0 2 2 0 0 0 4 2
A1g + T1u + Eg
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LGO del frammento F6 in SF6
nonlegame
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LGO di [Co(NH3)6]3+
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MO solo interazioni s
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p-donatore p-accettore
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LGO p in un piano di un ottaedro
pz
px
combinazione legante combinazione antilegante
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p-donatore
e.g. [CoF6]3-
LGO t2g
eg*
t2g*
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p-accettore
eg*
t2g
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![Page 11: [Co(NH3 6 - units.it...5027 till (triply degenerate) eg (doubly degenerate) Ligand group orbitals for the F6 fragment in SF6 (Oh). These orbitals only include contributions from the](https://reader030.vdocuments.us/reader030/viewer/2022011901/5f095f307e708231d4268569/html5/thumbnails/11.jpg)
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![Page 12: [Co(NH3 6 - units.it...5027 till (triply degenerate) eg (doubly degenerate) Ligand group orbitals for the F6 fragment in SF6 (Oh). These orbitals only include contributions from the](https://reader030.vdocuments.us/reader030/viewer/2022011901/5f095f307e708231d4268569/html5/thumbnails/12.jpg)
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Serie spettrochimica dei leganti
I– < Br– < S2– < NCS– < Cl– < F– < OH– < ox2– ≈ H2O <
NCS– < NH3 < en < bpy < phen < CH3– < CN– < CO
Campo debole Campo forte
p donatori < p donatori deboli < nessun contributo p < p accettori