Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 1
(Unit: Bhiwadi)
PRE-FEASIBILITY REPORT
1.0 EXECUTIVE SUMMARY
(I) INTRODUCTION
SRF is a multi-business entity engaged in the manufacture of chemical based industrial
intermediates. It has Fluorochemical Business and Speciality Chemical Business (Organic) Plant at
Village & P.O. Jhiwana, Tehsil Tijara, Distt. Alwar (Raj.); which was established in Year 1989. SRF
limited is proposing expansion of Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA to
6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000
TPA) and Change in Product Mix of Chloromethanes and HFC 134a.
As per the EIA Notification dated 14th Sept, 2006, and as amended from time to time, the project falls
under category ‘A’, Project or Activity 5(f).
Table - 1
Salient Features of the Project
S. No. PARTICULARS DETAILS
A. Nature & Size of the Project
Unit Existing Capacity
(TPA)
Proposed
Expansion
Capacity (TPA)
Total Capacity after
Expansion
(TPA)
Multi-Purpose
Plant/ Fluoro
speciality Plant
3000 3000 6000
New Generation
Refrigerants &
Refrigerant
Blends*
Nil 90,000 90,000
Chloromethane
Plant
50,000
(Product range
Methylene Chloride,
Chloroform, Carbon
tetra chloride)
Nil
(Extraction of
intermediate
Methyl chloride as
a product)
50,000
(Product range Methyl
chloride, Methylene
chloride, Chloroform,
Carbon tetra chloride)
HFC134a Plant
12000
(Product range
HFC134a)
Nil
(Swing over plant
for HFC32)
12000
(Product range
HFC134a & HFC32)
(*List of products is attached as Annexure - 1)
B. Category of the Project As per EIA Notification dated 14th Sept., 2006 & as amended from time to time;
this project falls under Category A, Project or Activity ‘5 (f)’
C. Location Details
Village Jhiwana
Tehsil Tijara
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 2
(Unit: Bhiwadi)
District Alwar
State Rajasthan
Latitude & Longitude
28° 9’ 18.41” N - 76° 50’ 27.58” E
28° 9’ 25.07” N - 76° 50’ 12.92” E
28° 9’ 45.73” N - 76° 50’ 20.41” E
28° 9’ 37.63” N - 76° 50’ 35.01” E
Toposheet No. 53 D/16
Location Map has been shown in Figure-1
D. Area Details
Total Plant Area 34 ha
Greenbelt / Plantation Area
(ha)
Out of the total plant area, 12.24 ha (~36 %) has already been developed under
green belt/ plantation and same will be maintained.
E. Environmental Setting Details (with approximate aerial distance & direction from plant site)
1. Nearest Town Bhiwadi (~ 4.0 km in NNE direction from the plant site)
2. Nearest City Rewari (~22 km in WNW direction from the plant site)
3. Nearest National Highway /
State Highway
NH-71B ( ~5.5 km in N direction from the plant site)
SH-25 ( ~1.3 km in W direction from the plant site)
4. Nearest Railway station Rewari Railway Station (~22 km in WNW direction from the plant site)
5. Nearest Airport Indira Gandhi International Airport, New Delhi (~50 km in NNE direction from
the plant site )
6. Archaeological important
site
None within the 10 km radius
7. National Parks, Wild Life
Sanctuaries, Biosphere
Reserves, Tiger/ Elephant
Reserves, Wildlife Corridors
etc. within 10 km radius
No National Park, Wildlife Sanctuary, Biosphere Reserve, Tiger / Elephant
Reserve, Wildlife Corridors etc. falls within 10 km radius of the plant site.
8. Reserved Forests (RF) /
Protected Forests (PF) etc.
within 10 Km. radius
Protected Forests
� Chaupanki (~5.5 km in ESE direction)
� Banvan (~2.5 km in E direction)
� Khori Kalan (~4.5.0 km in SE direction)
� Sarekalan (~7.0 km in SE direction)
� Protect Forest (adjacent in East direction)
� Gondhan (~1.2 km in NNE direction)
Reserve Forests
� Rangala (~7.5 km in NE direction)
� Indaur (~8.5 km in SE direction)
9. River / Water Body (within
10 km radius)
� Sahibi River (Seasonal) (~9.0 km in WNW direction)
� Indori lake (~9 km in SE direction)
� Indori Nala (~8.5 km in ENE direction)
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 3
(Unit: Bhiwadi)
10. Critically Polluted Area as
per CEPI - CPCB
Bhiwadi, a critically polluted area declared under CEPI as per MoEF Circular
dated 15.03.2010 exist within 15 km radius study area.
F. Cost Details
Total Cost of the Expansion
Project
Rs. 20 Crores (as per the information provided by M/s. SRF Ltd.)
Cost for Environment
Management Plan
� Capital Cost – Rs. 2.0 Crores
� Recurring Cost – Rs. 0.5 Crores/Annum
G. Basic Requirements for the project
Water requirement (KLD)
The allowable quota for water requirement is 2921 KLD; existing water
requirement is 2300 KLD and for proposed expansion, it will be 300 KLD. Thus,
after proposed expansion, the total water requirement will remain within the
allowable quota (i.e. 2921 KLD).
Source: Ground water & Recycled water
Power Requirement (MW) After expansion power requirement will be 11.1MW
Source: Captive power plant (12MW) and RSEB (4MW)
Man Power Requirement Existing man power requirement is 940
After proposed expansion total man power requirement will be 955
1.1 ENVIRONMENTAL MANAGEMENT PLAN
Particulars Details
Air Quality Management
Emissions
� Proper pollution control equipment e.g. Venturi Scrubbers / Graphite Scrubbers,
Central Absorption System (CAS), HCl Absorption System to remove the pollutants
such as Cl2, HF and HCl are in place and same will be maintained.
� Stacks of suitable height as per norms are being/will be provided.
� MPP (FSP) and New Refrigerant Plants - Central absorption (CAS) & Hypo system
having adequate size scrubber, running and stand by pump for water circulation,
running and stand by blower for vapour suction is being/ will be provided to ensure
Zero emission.
� Storage, filling and transfer of material will be in closed pipelines so that there is
Zero/ negligible fugitive emission.
� Green belt around the periphery and within premises is already in place and same
will be maintained.
Monitoring � Ambient air quality and stack emissions are being/will be regularly monitored and
effective controls exercised, so as to keep the emission within the statutory limits.
Water Management
Management � A full fledged ETP is already in place. Most of the treated water from ETP is
being/will be recycled back to the processes and remaining is/will be used for
greenbelt development.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 4
(Unit: Bhiwadi)
� Domestic waste water generated from the plant is being/ will be treated in Sewage
Treatment Plant. And treated water will be used in greenbelt development.
� Ultra filtration system rejects will be used as make up water for cooling system.
� Water conservation practices like construction of rain water harvesting and check-
dams is being/ will be practiced under CSR programme in nearby areas
Noise Management
Management � Green belt around the periphery and within premises has already been developed
and same will be maintained that helps in reducing noise.
� All rotating equipments are well lubricated and provided with acoustic enclosures to
reduce noise transmission.
� Noise generating units like, Air & Refrigeration compressors D.G set, and turbine and
boiler are installed in closed buildings and D.G. Sets are being/will be provided with
acoustic enclosure so that effect of noise is reduced.
� Acoustic Enclosures are being/will be provided to operators working in High Noise
area.
Solid & Hazardous Waste Management
� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed with the raw material of
HF plant & hence 100% recycling is being/will be done.
� The sludge from STP is being dried on sludge drying beds and is being/will be used for greenbelt development.
� Spent oil generated from existing/proposed facilities is being/will be sent to authorized recyclers.
� Plastic cut drums generated from existing/proposed facilities is being/will be sent to secured landfill.
Green Belt Development / Plantation
� Out of the total plant area, 12.24 ha (~36%) has already been developed under green belt/ plantation. The same
will be maintained properly.
� Green belt developed and there maintenance along with the road & plant boundary will attenuate noise level
arrest dust and improve the environment in surrounding.
� Native plant species has been planted in consultation with DFO.
2.0 INTRODUCTION OF THE PROJECT/ BACKGROUND INFORMATION
i. Identification of Project and Project Proponent
SRF is a multi-business entity engaged in the manufacture of chemical based industrial
intermediates. It was established in year 1973; its business portfolio covers Technical Textiles,
Fluorochemicals, Specialty Chemicals, Packaging Films and Engineering Plastics. Fluorochemical
Business and Speciality Chemical Business (Organic) Plant at Village & P.O. Jhiwana, Tehsil
Tijara, Distt. Alwar (Raj.) was established in Year 1989. Today, it has grown into a global
enterprise with operations in 4 countries and having a turnover of $450 million. SRF started its
journey in the space of fluorochemicals by manufacturing CFCs and HCFCs at Bhiwadi in
Rajasthan, faced with the challenge of phasing out of CFCs as per Montreal Protocol, SRF, to its
credit, made investments in R&D and successfully developed in-house technology to
manufacture ozone friendly and new generation of refrigerants of that time, HFC 134a in 2006.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 5
(Unit: Bhiwadi)
M/s. SRF Ltd. is the only Company in India which has developed indigenous capability for
manufacturing HFC-134A which is a new generation Refrigerant & and has zero ODP. Till date,
SRF remains the only manufacturer of HFC 134a in India. SRF's Specialty Chemicals Business
enjoys an enviable reputation for its capabilities in developing and manufacturing advanced
intermediates those are used in various agrochemical and pharmaceutical industries.
ii. Brief description of nature of the project
M/s. SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA
to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000
TPA) and Change in Product Mix of Chloromethanes and HFC 134a at Village & P.O. Jhiwana,
Tehsil Tijara, District Alwar (Rajasthan).
As per the EIA Notification dated 14.09.2006, and as amended time to time, the project falls
under category ‘A’, Project or Activity 5(f).
iii. Need for the project and its importance to the country and or region
M/s. SRF Ltd. are engaged presently in production of Fluorochemicals (Refrigerant gases),
Chloromethane and speciality chemicals products, which are used for a variety of Industrial,
commercial and household applications and intermediates for pharmaceutical & agrochemical
industry.
Hydro-Chlorofluoro carbons like R-22 are phasing out and new refrigerants/refrigerant blends
are coming in market. Also fluoro specialty product range has been growing in India, the project
proponent intends to put up new set ups for producing new refrigerant/refrigerant blends,
Expansion of MPP/Fluoro specialty products facility and change in product mix of
chloromethane to produce C1 (Methyl chloride) and change in product mix of HFC134a plant to
produce HFC32 at their existing facility in Rajasthan.
iv. Demand- Supply Gap
Demand - Supply projection for Fluorochemicals on National and State basis reveals that there
exists an imbalance between availability and demand of Fluorochemicals India. The long term
prospects for Fluorochemicals are great in India due to under penetration of most of the end use
products like AC’s, Automobiles, Cold Storages, Refrigerated transport, Pharma etc. Secondly the
weather is India is hot for most part of the year thereby demanding air conditioning &
refrigeration products over a longer stretch of time. Nearly 55% of the market demand in India is
for HCFC, while 45% is for HFC’s.
Most of the HFC’s like R134a, R410a, R407c, R404a etc. are imported into India. Except for one
domestic player making R134a (SRF), all HFC’s are imported.
The Specialty Chemicals Industry is a mature sector. For decades, many industries have utilized
specialty chemicals in manufacturing and finishing. Some specific areas where these products
are used include: agriculture, requiring fertilizers, construction materials, sealants, coatings,
paints and plastics; and consumer goods, such as perfumes, detergents, paper items and
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 6
(Unit: Bhiwadi)
pharmaceuticals out of which agriculture and pharmacy sector are need driven. Hence big
industries are dependent upon the indigenous availability of such chemicals for accelerated
growth and development of the nation. As such the Indian market is driven by global suppliers
to a great extent and is subject to global demand supply challenges.
Under these circumstances to bridge the gap, SRF has proposed for installation of new
generation refrigerants/blends & expansion of MPP/Fluorospeciality plant. Product mix change
in CMS & HFC134a plant.
Imports vs. Indigenous Production
The proposed expansion will utilize both locally and imported raw materials. Most of the raw
material for the the Refrigerant & Refrigerant blends plant is imported via sea route, most of
them from china. Raw materials for the speciality plant is being /will be sourced from both
national and international markets, via, sea, rail and road routes.
Basic raw material for the fuel including coal is being/will be sourced from Indian markets, in
trucks and tankers, via road.
v. Export Possibility-
Due to lacking competitive scale of production in the various countries of the world for the
production of both fluoro chemicals and specialty chemicals, and increase in demand scale of the
products, there is huge scope for export possibility of the products from both existing and new
plant units. Various Products from the existing units are exported to the various global markets
that hold customers from various developed and developing nations.
vi. Domestic / Export Markets
Most of the products from the existing plant units are sent to the national costumers, which
include various big and small manufacturing industries. Products are being exported to various
parts of the globe, mostly covering west Asian, European and North American markets. New
products after expansion in addition to the product from existing plant will be exported to
different parts of the world, most equally to both developing and developed nations, via sea and
air routes. Major section of the revenue is generated from the export sections, however due to
increased development and raised level of living standards, the demand of such chemicals have
been increased as part of various finished products in the domestic markets.
vii. Employment Generation (Direct and Indirect) due to the project
Table -2
Manpower requirement
Particulars Existing Proposed Total after expansion
Skilled 535 10 545
Semi – Skilled 87 5 92
Unskilled 318 - 318
Total 940 15 955
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 7
(Unit: Bhiwadi)
3.0 PROJECT DESCRIPTION
(i) Type of Project including interlinked and independent projects if any
M/s. SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA
to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000
TPA) and Change in Product Mix of Chloromethanes and HFC 134a.
There is no interlinked project.
(ii) Location (map showing general location, specific location, and project boundary & project
site layout) with coordinates
Figure -1: Location Map
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA)
Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
M/s. SRF Limited
(Unit: Bhiwadi)
speciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA)
8
Figure - 2: Plant Layout
speciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in
Pre-Feasibility Report
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in
Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 9
(Unit: Bhiwadi)
Figure - 3: Key Plan
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 10
(Unit: Bhiwadi)
(iii) Details of alternative sites consideration and basis of selecting the proposed site, particularly
the environmental considerations gone into should be highlighted.
Since, the proposed expansion and new installation will be done within the existing plant and no
additional land will be required; therefore, no alternative site has been considered.
(iv) Size or magnitude of operation
SRF Ltd. is proposing expansion in Multi-Purpose Plant / Fluorospeciality Plant (3000 TPA to 6000
TPA); Installation of New Generation Refrigerants & Refrigerant Blends Plant (90,000 TPA) and
Change in Product Mix of Chloromethanes and HFC134a at Village & P.O. Jhiwana, Tehsil Tijara,
District Alwar (Rajasthan).
Table - 3
Size or Magnitude of operation
S.
No.
Name Abbreviation Existing
capacity
(MTA)
Proposed
capacity
(MTA)
Total capacity
after
expansion
(MTA)
A. Multipurpose plant/Fluorospecialty plant
1 Trifluoroacetic acid TFA 1600.0 - 1600.0
2 Trifluoroacetic anhydride TFAA
3 Methyl chlorodifluoroacetate MCDFA
4 Chlorodifluoroacetic acid CDFA
5 Chlorodifluoroacetic anhydride CDFAA
6 Ethyl trifluoroacetate ETFA
7 Ethyl trifluoroacetoacetate ETFAA
8 2,3,4,5,6 Pentafluorobenzoic acid PFBA 100.0 125 225
9 Pentafluorobenzene PFB
10 Bromopentafluoro benzene BPFB
11 Pentafluorophenol PFP
12 Difluoroacetic acid DFA 600.0 600.0
13 Ethyl difluoroacetate EDFA
14 Ethyl difluoroacetoacetate EDFAA
15 Ethyl 3 – amino - 4, 4, 4 - trifluoro crotonate
P9 400.0 100 500
16 Tetrafluoro benzyl alcohol TFBAL 100.0 - 100.0
17 4-bromofluoro benzene PBFB 200.0 - 200.0
18 Difluoromethyl pyrazole acid - 225 225
19 Pyrazole acid amides
20 Alkyl & Phenyl Pyrazole derivatives
21 Other Pyrazolic acid/amides & derivatives
22 2,4,5 trifluorophenyl acetic acid TPA
23 Other fluorinated aliphatics
24 Other fluorinated acids
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 11
(Unit: Bhiwadi)
25 Methyl trifluoroacetate MTFA - 325 325
26 Methyl bromodifluoroacetate MBDFA
27 Ethyl bromodifluoroacetoacetate EBDFAA
28 Ethyl bromodifluoroacetate EBDFA
29 Ethyl chlorodifluoroacetate ECDFA
30 Isopropyl trifluoroacetate IPTFA
31 Methyl difluoroacetate MDFA
32 Sodium trifluoroacetate
33 Potassium trifluoroacetate
34 Sodium chlorodifluoroacetate
35 Other fluorinated esters
36 Other chlorofluoro esters
37 2,3,5,6 Tetrafluoro-4-methylbenzyl alcohol
- 125 125
38 Trifluorethanol
39 Hexafluoropropanol
40 Fluorinated alcohols
41 1,4-difluorobenzene - 325 325
42 1,3-difluorobenzene
43 1,2,4-trifluorobenzene
44 Hexafluorobenzene HFB
45 Trifluoroethoxy benzene
46 Cynopentafluoro benzene
47 Fluorobenzene FB
48 Difluoronitro benzene
49 Difluoro dinitro benzene
50 Fluorobenzenes
51 Fluoronitro benzenes
52 Fluoroiodo benzenes
53 Trifluoroacetamide - 275 275
54 Trifluoroacetone TFAc
55 Trifluoroacetonitrile
56 Trifluoroethyl amine
57 Trifluoroethyl amine hydrochloride
58 Fluoro anhydrides
59 Fluoro amides
60 Fluoro aldehydes
61 Fluoro ethers
62 Fluoro ketones
63 Other fluorinated acid derivatives
64 Sulphur tetrafluoride SF4 - 125 125
65 Nitrogen trifluoride NF3
66 Diethyl amino sulphur trifluoride
67 Other fluorine/fluorinated reagents
68 Difluoromethane sulphonyl chloride DFMSC - 175 175
69 Difluorobenzene sulphonyl chloride
70 Perfluorobutane sulphonyl fluoride
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 12
(Unit: Bhiwadi)
71 Perfluorobutane sulphonic acid
72 Fluoro aryl sulphonic acids & derivatives
73 Fluoro alkyl sulphonic acids & derivatives
74 Boron trifluoride - 750 750
75 Potassium fluoride
76 HF-Pyridine
77 BF3 Etherate
78 Other inorganic fluorides
79 3-trifluoromethyl aniline ABTF - 225 225
80 4-trifluoromethyl aniline
81 2,6-Dichloro-4-trifluoromethyl aniline Synthon1
82 Heptafluoroisopropyl-2-methyl aniline HFPOT
83 Difluoromethoxy aniline
84 Trifluoromethoxy aniline
85 Difluoro anilines & other fluorinated anilines
86 Other fluorinated anilines
87 Difluorobenzo dioxole - 225 225
88 5-Bromo-2,2-difluoro-1,3-benzodioxole DFBD
89 Difluorobenzodioxole methyl ester DFBD Me
90 Fluoroesters
Total 3000 3000 6000
B. Cloromethanes (TPA ) (Product range methylene chloride, chloroform, carbontetrachloride)
50000
Nil (Extraction of intermediate
Methyl chloride as a
product)
50000
C. New Generation Refrigerants & Refrigerant Blends (TPA) (details of the products is provided in Annexure-1) 0 90,000 90,000
D. HFC134a (Product range HFC134a) 12000
TPA
Nil (Addition of
HFC32) 12000 TPA
(v) Project description with process details (a schematic diagram/ flow chart showing the
project layout, components of the project etc. should be given)
The procedure for production of Multi-Purpose Plant / Fluorospeciality Plant, HFC 134a Plant,
Chloromethane plant and New Generation Refrigerants & Refrigerant Blends process details are
enclosed as Annexure -2.
Process flow chart for New Generation Refrigerants & Refrigerant Blends Plant, MPP /
Fluorospeciality Plant, CMS Plant & HFC134a Plant has been enclosed as Annexure - 3.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 13
(Unit: Bhiwadi)
(vi) Raw material required along with estimated quantity, likely source, marketing area
of final products, mode of transport of raw material and finished product.
a) Raw Material Requirements:
Details of Raw material requirement for Multi-Purpose Plant /Fluorospeciality Plant),
Chloromethane plant, New Generation Refrigerants & Refrigerant Blends & Chloromethane
plant has been enclosed as Annexure - 4.
Details reg. Fuel is given in Table 4.
Table - 4
Fuel Requirement
S.
No.
Name of
Raw
Material
Quantity Required (TPA) Calorific
value
(Kcal./kg)
% Ash
%
Sulphur
Source Distance & Mode of
Transportation Existing Proposed
Expansion
Total after
proposed
expansion
1. Coal 125070 Nil 125070 3500-4000 35-40 0.5 CCL Through trucks via road
2. Husk 67980 NIL 67980 3000-3300 5-7 <0.5 Open Market Through Trucks via road,
from different Locations
3. Lignite 128370 NIL 128370 3500-4000 15-20 2-3 Open Market Through trucks via road
3. HSD 1800 NIL 1800 11840 - <0.05 IOCL Rewari 30 kms through Tankers.
4. FO 3200 NIL 3200 9800 to
10200
.034 to
0.15
1.18 to
4.0
Reliance
industries by Tankers
b) Marketing Area and Mode of transportation of Final Product
SRF has explored National and international markets for their products from both existing and
proposed expansion units, Most of the product will be exported to the West Asian and North
American countries in sealed tankers, barrels and other sophisticated carrying containers via sea
and air route. Increasing markets has also been explored for both refrigerants products and
fluorospeciality products. Refrigerants products have markets available all over the nation with
increasing demand from small vehicle AC manufacturing unit to the large and big industries
requiring refrigeration.
Whereas Speciality products holds markets in a rapid booming and revolutionary sector like
pharmacy and agricultural products, with this demand from the other industries as a raw
material for production of various other products has also came in.
Products are being and will be provided to various sectoral markets of nation with the increasing
demand. Transportation within the country will be done in the various sealed containers,
isotanks, cylinders and barrels, via road, rail, waterways and airways.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 14
(Unit: Bhiwadi)
(vii) Resources optimization/ recycling and reuse envisaged in the project, if any, should be
briefly outlined.
Water as a resource is recycled at each possible step of the process and more latest technology
and methodology will be adopted to conserve and reuse the resource.
Waste water being/ will be generated from the process goes to ETP and treated water after pH
corrections is used again back into the various processes and remaining is used for the
horticulture purposes.
(viii) Availability of water its source, energy /power requirement and source should be given.
a) Water Requirement and Source
With their strong focus on conservation recycling & reuse of water, industry has significantly
reduced their water consumption & their existing consumption to 2300 KLD. Proposed
expansion further needs about 300 KLPD water. Therefore, total water requirement after
expansion will be 2600 KLPD.
Source: Ground water & Recycled water (Allowable quota 2921 KLPD).
b) Power Requirement and Source
Total power requirement after proposed expansion will be 11.1 MW.
Source: Captive Power Plant (12MW) and RSEB (4MW).
(vii) Quantity of waste to be generated (liquid and solid) and scheme for their
management/disposal
� A full fledged ETP is already in place. Most of the treated water from ETP is being/will be
recycled back to the processes and remaining is/will be used for greenbelt development.
� Domestic waste water generated from the plant is being/ will be treated in Sewage
Treatment Plant. And treated water will be used in greenbelt development.
� Ultra filtration system rejects is being / will be used as make up water for cooling system.
� Spent oil will be generated from the proposed expansion and new installation project. The
same will be sent to authorized recycler as per current practices followed.
� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed
with the raw material of HF plant & hence 100% recycling is being/will be done.
� The sludge from STP is being dried on sludge drying beds and is being/will be used for
greenbelt development.
� Plastic cut drums generated from existing/proposed facilities is/will be sent to secured
landfill.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 15
(Unit: Bhiwadi)
4.0 SITE ANALYSIS
(i) Connectivity
The plant site is well connected to National Highway i.e NH-71B (~5.5 km in N direction).
The nearest railway station is Rewari Railway Station (~20 km in WNW direction from the plant
site) and nearest Airport is Indira Gandhi International Airport, New Delhi (~50 km in NNE
direction from the plant site).
The site is suitably located with respect to availability of raw material, water, road network,
skilled / semi-skilled / unskilled and professional manpower etc. All communication facilities
such as telephone, telefax & internet are available in the vicinity of the plant site.
(ii) Land form Land use and land ownership
Total plant area is 34.0 ha. Since, the proposed expansion and new installation will be done
within the existing plant premises, thus, no additional land is required. Hence, land ownership
will be considered as industrial type.
The plant area break- up is given in Table - 5.
Table – 5
Plant Area Break- Up
Unit
Area (ha)
Existing Additional for
proposed expansion
Total after proposed
expansion
Total Constructed Plant area 7.99 1.0 8.99
Total road area 3.03 - 3.03
Greenbelt area 12.24 - 12.24
Open area 10.74 (-) 1.0 9.74
Total Plant Area 34.0 Nil 34.0
(iii) Topography
Rajasthan has varying topographic features though a major part of the state is dominated by
parched and dry region. The extensive topography includes rocky terrain, rolling sand dunes,
wetlands, barren tracts or land filled with thorny scrubs, river-drained plains, plateaus, ravines
and wooded regions. In a more broad way the topography of Rajasthan can be divided in the
following regions- The Aravalli or The Hilly regions, The Thar and other arid regions, the
Plateaus including Vindhaya and The Malwa, the Fertile plains including The Mewar, the Forest
Regions and the Water bodies including Rivers and Salt Lakes.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 16
(Unit: Bhiwadi)
(iv) Existing land use pattern (agriculture, non-agriculture, forest, water bodies (including
area under CRZ), shortest distances from the periphery of the project to periphery of the
forests, national park, wild life sanctuary, eco sensitive areas, water bodies (distance
from the HFL of the river), CRZ. In case of notified industrial area, a copy of the gazette
notification should be given
Table – 6
Environmental Settings of the Area
S. No. Particulars Details
(with approx. distance & direction from the plant site)
1. Nearest Town /City � Nearest Town: Bhiwadi (~4.0 km in NNW direction)
� Nearest City : Rewari(~22 km in NNE direction)
2. Nearest National Highway / State Highway NH-71B ( ~5.5 km in N direction)
SH-25 ( ~1.3 km in W direction)
3. Nearest Railway station Rewari Railway Station (~20 km in W direction)
4. Nearest Airport Indira Gandhi International Airport, New Delhi (at a distance of ~50
km in NNE direction)
5. Archaeological important site None within 10 km radius
6. National Parks, Wild Life Sanctuaries,
Biosphere Reserves, Tiger/ Elephant
Reserves, Wildlife Corridors etc. within 10
km radius
None within 10 km radius
7. Reserved Forests (RF) / Protected Forests
(PF) etc. within 10 Km. radius
Protected Forests
� Chaupanki (~5.5 km in ESE direction)
� Banvan (~2.5 km in E direction)
� Khori Kalan (~4.5.0 km in SE direction)
� Sarekalan (~7.0 km in SE direction)
� Chaupanki (~5.5 km in ESE direction)
� Khidarpur (~4.0 km in NE direction)
� Gondhan (~1.2 km in NNE direction)
Reserve Forests
� Rangala (~7.5 km in NE direction)
� Indaur (~8.5 km in SE direction)
8. River / Water Body (within 10 km radius) � Sahibi River (Seasonal) (~9.0 km in WNW direction)
� Indori lake (~9 km in SE direction)
� Indori Nala (~8.5 km in ENE direction)
9. Soil Type Sandy loam
10. Seismic Zone Zone – II [as per IS 1893 (Part-I): 2002]
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 17
(Unit: Bhiwadi)
(v) Existing Infrastructure
Total plant area is 34 ha and the proposed expansion and new installation will be done within
the existing plant premises.
(vi) Soil Classification
The soil is of silty loam type with yellowish brown colour.
(vii) Climatic Data from Secondary Sources
The Alwar district has a hot dry summer and a moderate cold season. The temperature
continuously rises in the hot season from March to June and goes down after mid-November till it
declines up to the month of January. The average minimum temperature in the district goes down
to 5oC while maximum temperature rises upto 440C throughout the year. The region is medium
rainfall area. On an average, 500 - 600 mm of rainfall annually occurs in the area, mainly from
southwest monsoon. Nearly 80 % of annual rainfall is received during the September. Only about
5 % of the normal rainfall is received during the other season. On an average there are 30 - 35
rainy days, that is, days with rainfall of 2.5 mm or more in a day.
(vii) Social Infrastructure available
Telephone and medical facilities are available in the nearby towns. Adequate infrastructure has
been developed by SRF around their existing chemical plant premises. Various infrastructure
development activities like construction of classrooms, toilets, drinking water facility, and
development of playground have been brought into existence. Other facilities like small shops
and markets are existing in the area that supports the basic lifestyle of the people.
5.0 PLANNING BRIEF
(i) Planning Concept (type of industries, facilities, transportation etc.) / Town and country
Planning/ Development authority classification.
The existing industry is chemical industry and proposed expansion and new installation will be
done within the existing plant premises. Facilities required for the proposed expansion and new
installation project will be provided as per requirement.
Transportation of raw material and final product will be done via existing road.
(ii) Population Projection
Temporary influx of people will be there as the managerial and supervisory staff will generally
be outsider. A projection may be made by a governmental organization, or by those unaffiliated
with a government.
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 18
(Unit: Bhiwadi)
(iii) Land use planning
Total existing area is 34.0 ha. Proposed expansion and new installation will be done within the
existing plant premises; thus, no additional land will be required. Out of the total plant area,
12.24 ha (~36 %) has already been developed under green belt/ plantation and same will be
properly maintained.
(iv) Assessment of infrastructure demand (Physical & Social)
M/s. SRF Limited has assess the demand of infrastructure (Physical & Social) in the nearby area
of the plant site and development activities are being undertaken under corporate social
responsibilities program for rural development initiatives for the upliftment of the nearby
communities.
(v) Amenities/Facilities
M/s. SRF Limited has taken various infrastructure development activities around the plant
premises, facilities like construction of classrooms, toilets, drinking water facility, development
of playground have been brought into existence. In nearby schools other facilities like small
establishment of IBM kid smart centres, capacity building training, community health
programmes are being /will be organised. Development of area by providing vocational training
and promoting women self help groups is also being done which will be promoted further. SRF is
being developing/will develop the amenities/facilities in nearby area of the plant site as per
requirement of local people of the nearby area under corporate social responsibilities
programme.
6.0 PROPOSED INFRASTRUCTURE
(i) Industrial Area (Processing Area)
No additional area will be required for the proposed expansion and new installation as
expansion will be within the existing plant premises.
(ii) Green Belt
Out of the total plant area i.e. 34 ha about, 12.24 ha (~36 %) has already been developed under
green belt/ plantation and same will be properly maintained.
(iii) Social Infrastructure
Proposed expansion and new installation project will result in growth of the surrounding areas
by increased direct and indirect employment opportunities in the region including development
and supporting infrastructure.
(iv) Connectivity
The plant site is well connected to National Highway i.e NH-71B (~5.5 km in N direction).
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 19
(Unit: Bhiwadi)
The nearest railway station is Rewari Railway Station ( ~22 km in WNW direction) and nearest
Airport is Indira Gandhi International Airport, New Delhi (~50 km in NNE direction).
The site is suitably located with respect to availability of raw material, water, road network,
skilled / semi-skilled / unskilled and professional manpower etc. All communication facilities
such as telephone, telefax & internet are available in the vicinity of the plant site.
(v) Drinking Water
As the proposal is of expansion of the facility at the existing site therefore increase in drinking
water requirement will be of insignificant amount. Approximate increase will be in the range of
100 to 200 Liter per day.
(vi) Sewerage system
� Domestic waste water generated from the plant is being/ will be treated in Sewage
Treatment Plant. And treated water will be used in greenbelt development.
� The sludge from STP is being dried on sludge drying beds and is being/will be used for
greenbelt development.
(vii) Industrial waste management
� A full fledged ETP is already in place. Most of the treated water from ETP is being/will be
recycled back to the processes and remaining is/will be used for greenbelt development.
� Ultra filtration system rejects will be used as make up water for cooling system.
� Domestic waste water generated from the plant is being/ will be treated in Sewage
Treatment Plant. And treated water will be used in greenbelt development.
(viii) Solid waste management
� The sludge from ETP arising out of water treatment contains CaF2. This would be mixed
with the raw material of HF plant & hence 100% recycling is being/will be done.
� The sludge from STP is being dried on sludge drying beds and used for horticulture purpose,
which is a common practice in the existing plant. .
� Plastic cut drums generated from existing/proposed facilities is/will be sent to secured
landfill.
(ix) Power requirement and source
After expansion power requirement will be 11.1MW which will be sourced from Captive power
plant (12MW) and RSEB (4MW).
Proposed Expansion of Multi-Purpose Plant/ Fluorospeciality Plant (3000 TPA to 6000 TPA); Installation of New Generation
Refrigerants & Refrigerant Blends Plant (90,000 TPA) and Change in Product Mix of Chloromethanes and HFC134a
At Village & P.O. Jhiwana, Tehsil Tijara, District Alwar (Rajasthan)
Pre-Feasibility Report
M/s. SRF Limited 20
(Unit: Bhiwadi)
7.0 REHABILITATION AND RESETTLEMENT (R & R) PLAN
(i) Policy to be adopted (Central/State) in respect of the project affected persons including
home oustees, land oustees and landless labourers
R & R Plan is not applicable to the proposed expansion and new installation project as the
proposed expansion will be done within the existing premises & no additional land is required
for the same.
8.0 PROJECT SCHEDULE AND COST ESTIMATES
(i) Likely date of start of construction and likely date of completion
The project will start only after obtaining Environmental Clearance and all other required
clearance. An implementation period of 60 months from the date of signing/ effectiveness of the
main equipment supply contract is foreseen for this project.
The likely date of start of construction is after obtaining EC from MoEFCC / CTE from SPCB &
likely date of start of operation within 3 years of obtaining EC/ CTO.
(ii) Estimated project cost:
� Capital Cost of the project is Rs. 20.0 Crores.
� Environment Management Protection Cost:
o Capital Cost: Rs. 2.0 Crores
o Recurring Cost: Rs. 0.5 Crores/annum.
9.0 ANALYSIS OF PROPOSAL
(i) Financial and social benefits with special emphasis on the benefit to the local people
including tribal, population, if any in the area
Proposed expansion and new installation project will result in growth of the surrounding areas
by increased direct and indirect employment opportunities in the region including development
and supporting infrastructure.
Special emphasis on financial and social benefits will be given to the local people including tribal
population, if any, in the area. Development of social amenities will be in the form of medical
facilities, education to underprivileged and creation of self-help groups.
Also, the state will get revenues in terms of taxes and local people will get opportunities in terms
of indirect employment. Business opportunities for the local people will be enhanced like
transport of product in the market, maintenance & housekeeping contract work etc.
No adverse effect on environment is envisaged as proper mitigation measure will be taken up for
the same.
ANNEXURE-1
List of Refrigerant & Refrigerant blends:
S. No Product Total Plant Capacity (TPA)
1 R-32 (Difluoro Methane) 120002 R-600A (Isobutane) 33003 R-600 (n-Butane) 10004 R-290 (Propane) 10005 R133A (Chlorotrifluoro Ethane) 7006 R21 (Dichlorofluoro Methane) 12507 TCE (Trichloro Ethylene) 18508 R-23 (Trifluoro Methane) 12509 R-227 (HeptaFluoro Ethane) Pharma Grade 2000
10 C1 (Methyl Chloride) 200011 R-125 (Pentafluoro Ethane) 1850012 R143A (Trifluoro Ethane) 300013 R-152A (Difluoro Ethane) 300014 R-142B (Chlorodifluoro Ethane) 140015 R404A (R-125+143A+R-134a) 200016 R407C (R-32+R-134A+R-125) 250017 R410A(R-32+R-125) 800018 Blend of R-152A+R-134A 200019 Blend of R-142B+R-22 75020 Blend of R-134A+ DME (Di Methyl Ether) 250021 R-407 A(R-32+R-134a+R-125) 125022 R-407 F(R-32+R-134a+R-125) 125023 R-417 A (R-125+R-134a+R-600) 125024 R-417 B(R-125+R-134a+R-600) 125025 R-421 A(R-125+R-134A) 125026 R-421 B (R-125+R-134A) 125027 R-422 A(R-125+R-134a+R-600A) 125028 R-422 B(R-125+R-134a+R-600A) 125029 R-422 C(R-125+R-134a+R-600A) 125030 R-422 D(R-125+R-134a+R-600A) 125031 R-424 A(R-125+R-134a+R-600+R-600a+R-601a) 125032 R-427 A(R-134+R-125+R-32+R-143a) 125033 R-428 A(R-125+143a+R-600a+propane) 125034 R-434 A(R-125+R-134a+R-143a+R-600a) 125035 R-438 A(R-134a+R-32+R-125+butane) 125036 R-507 A(R-134a+R-125) 1250
TOTAL 90,000
ANNEXURE - 2
1
MANUFACTURING PROCESS
MULTIPURPOSE PLANT (FLUOROSPECIALITY PLANT)
1. Trifluoroacetic acid (TFA)Trichloroacetyl chloride (TCAC) & hydrogen fluoride (HF) are passed through a reactor togenerate TFA & Hydrogen Chloride (HCl gas). Reaction outlet is absorbed in water togenerate Trifluoroacetic Acid (TFA). HCl is absorbed in water to make saleable 33% HCl.2. Trifluoroacetic Anhydride (TFAA)TFA is reacted with SO3 present in oleum to form TFAA & water. Unreacted TFA with spentsulfuric acid is recycled to TFA plant for TFA recovery. Crude TFA from reactor is taken fordistillation.3. Methyl chloro difluoro acetate (MCDFA)Methanol reacts with chlorodifluoroacetyl fluoride to form ester of methyl chlorodifluoroacetate. Product is distilled from top is sent to storage.4. Chlorodifluoro Acetic Acid (CDFA)Chlorodifluoro Acetic Acid is produced in the following two steps: Reaction of Trichloroacetylchloride with Hydrogen fluoride to form Chlorodifluoro acetyl fluoride. Hydrolysis ofChlorodifluoro acetyl fluoride with water to form Chlorodifluoro acetic acid & hydrogenfluoride.5. Chloro difluoro Acetic anhydride (CDFAA)Chloro difluoro Acetic Acid is reacted with SO3 present in oleum to form Chloro difluoroAcetic Anhydride & water. Crude Chloro difluoro acetic acid from reactor is taken fordistillation.6. Ethyl Trifluoroacetate (ETFA)Reaction:Ethanol reacts with Trifluoroacetyl fluoride to form ester of Ethyl Trifluoroacetate.Distillation:After reaction is complete product is removed from the reactor by reactive distillation.Product distilled from top is sent to storage.7. Ethyl trifluoroacetoacetate (ETFAA)Ethyltrifluoroacetate (ETFA) is reacted to form ETFAA. ETFAA is recovered by distillation.
ANNEXURE - 2
2
8. Pentafluorobenzoic Acid (PBFA)Benzonitrile and chlorine are passed through a reactor. HCL is absorbed in water to makesaleable 33% Hydrochloric Acid. PCBN is then hydrolyzed in H2SO4 acid to generatePentafluorobenzoic Acid (PFBA, solid)9. Pentafluorobenzene (PFB)Reaction:Pentafluorbenzoic acid is mixed with water and then heated to high temperature andpressure.Extraction & Distillation:After reaction is complete organic layer is extracted and then sent to distillation. Productobtained from column top is then sent to storage.10.Bromopentafluorobenzene (BPFB)Pentafluorobenzoic acid is heated to high temperature and pressure to form intermediatecompound. Product is extracted and aqueous layer is treated. Organic layer is then decantedand distilled to give product which is then sent to storage.
11. Pentafluorophenol (PFP)Pentafluorobromobenzene reacts with BF3 Etherate to form an intermediate product.This intermediate product is then extracted with ether and is heated at elevated pressure toform product pentafluorophenol.Product formed is then sent to distillation to remove ether from column top and pureproduct is obtained from column bottom. Product obtained is then sent to storage.12. Parabromofluorobenzene (PBFB)Fluorobenzene and bromine are reacted in a reactor to generate p-Bromofluorbenzene(PBFB, liquid) and Hydrobromic Acid (HBr, gas).Hbr is absorbed in water to generatesaleable 48 % Hydrobromic Acid.p-Bromofluorobenzene is distilled out and packed fordispatched.13. Tetrafluorobenzyl Alcohol (TFBAL)The process for the manufacture of Tetrafluorobenzyl Alcohol uses C6F5CN (as Rawmaterial), an intermediate, Produced in the manufacturing process of the existing productPentafluoro benzoic acid. All the reactions involved are in the solid/Liquid phase; hence noair emission is envisaged.
ANNEXURE - 2
3
14. Difluoroacetic Acid (DFA)Methyl Chloro Difluoroacetate is reacted with Methanol at high pressure & temperatureconditions to give an intermediate compound. This compound is then reacted withhydrochloric acid to give Difluoroacetic acid.The product is then neutralized with sodium hydroxide to kill acidity & then extracted toremove methanol & other organics.Final product is then bone dried by extraction with sulfuric acid. After removal of moistureproduct is sent to storage.15. Ethyldifluoroacetate (EDFA)R22 is passed through Ethanol solution to give product Ethyl Difluoroacetate.After reaction mixture is sent for layer separation where heavy organic layer is decantedfrom bottom and is then treated to remove any ethanol present in the product as impurity.Final product is then again layer separated to remove aqueous layer and organic layer is thensent to storage.16. Ethyldifluoroacetoacetate (EDFAA)EDFA is reacted to form salt of EDFAA in presence of suitable solvent. Salt is acidified withDry HCl to form EDFAA and Sodium salt at RT. Solvent is recovered from Rm and taken forfiltration. Crude product is further distilled and purified to get desired quantity product.17. Ethyl 3-amono-4,4,4-trifluorocrotonateETFAA is reacted with ammonia to form ammonium salt of ETFAA. Amino crotanate isformed by thermal decomposition of salt.18. 2,4,5 Trifluorophenyl Acetic Acid.2,4-Dichloroacetophenone is reacted with Chlorosulfonic acid to form 5-Acetyl-2,4-dichlorobenzene-1-sulfonylchloride, is fluorinated using KF .5-Acetyl-2,4-dichlorobenzene-1-sulfonyl fluoride is fluorinated using KF to form 1-(2,4,5-trifluorophenyl) ethanone.Reaction mass is reacted with morpholine and sulfur to form 2,4,5 Tri fluorophenylaceticacid.19. TrifluoroacetoneETFAA, reacts with water to form Trifluoroacetone, Ethanol and carbon dioxide. Which aresubsequently separated.
ANNEXURE - 2
4
20. Sulfur Tetra fluoride (SF4)Chlorine gas is purged into the molten for the formation of Sulfur Monochloride Vapor whichare condensed and collected. Fluorine gas is purged into the Sulfur Monochloride for theformation of Sulfur Tetra fluoride and Sulfur Dichloride. The Sulfur Tetra fluoride gas comingout of the reactor is condensed, collected and filled into the cylinders.21. Difluoromethane Sulphonyl Chloride (DFMSC)1. Benzyl chloride, thio-urea & caustic lye is reacted to form benzyl mercaptan thiouron HCl..2. Benzyl mercaptan on reaction with R22 (Chlorodifluoromethane) & caustic to form BDFMS(Benzyl Difluoromethyl Sulphide).3. Layer separation is done to remove aqueous layer. Organic layer is taken to distillation torecover pure DFMSC.22. 3-trifluoromethyl aniline (ABTF)Benzotrifluoride reacts with AHF to form benzotrifluoride which again reacts with sulphuricacid and nitric acid to form 3 nitro benzotrifluoride. 3-nitrobenzotrifluoride reacts to form 3amino benzotrifluoride.23. 2,6-dichloro-4-trifluoromethyl aniline (Synthon1)1. p-Chlorotoluene is photochlorinated to form 4-ClBTC (1-chloro-4-(trichloromethyl)benzene).2. 4-ClBTC is reacted with AHF to form 4-ClBTF (1-chloro-4-(trifluoromethyl) benzene).3. 4-ClBTF is treated with ammonia to form 4-ABTF (4-Amino benzotrifluoride).4. 4 -ABTF is treated with chlorine to form Synthon1.24. Heptafluoroisopropyl-2-methyl aniline (HFPOT)1. Hexafluoropropylene (HFP) is reacted with bromine to form DBHFP at atmospherictemperature.2. DBHFP is reacted with KF for the formation of HFiPBr.3. HFiPBr is reacted with o-toluidine & triethylamine to form HFPOT & HFPOT Isomer.4. HFPOT salt is dissolved in MTBE & then neutralized with ammonia to form ammonium saltwhich is filtered .MTBE & HFPOT is then taken to distillation to recover pure HFPOT.25. 5-Bromo-2,2-difluoro-1,3-benzodioxole (DFBD)1. 1,3-benzodioxide is reacted with Phosphorus pentachloride to give 2,2-Dichloro-1,3-benzodioxide.2. 2,2-Dichloro-1,3benzodioxide is fluorinated with HF to give 2,2-Difluoro-1,3-benzodioxide.3. 2,2-Difluoro-1,3-benzodioxide formed in then further brominated with HBr to give 5-Bromo-2,2-Difluoro-1,3-benzodioxole.
ANNEXURE - 2
5
26. Difluorobenzodioxole methyl ester (DFBDMe)1. 1,3-benzodioxole reacts with phosphorus pentachloride to form DCBD Me and phosphorustrichloride.2. 2,2 Difluoro benzodioxole reacts with bromine to form 5-Bromo-2,2-Difluoro-1,3-Benzodioxole and HBr.CHLOROMETHANES (CMS) PLANT
(a) Hydrochlorination & C1 Wash Section :In Hydro section, main raw materials are: Methanol and 100% HCL (FromPhotochlorination section). The reaction takes place. At the outlet of hydro-reactor, C1(Methyl Chloride) is formed which after purification (removal of acidity, free chlorine &moisture, etc.) and compression is sent to storage.CH3OH + HCL CH3CL + H2O
CH3Cl + Cl2 CH2Cl2 + HCl
CH3Cl + 2 Cl2 CHCl3 + 2 HCl
CH3Cl + 3 Cl2 CCl4 + 3 HCl
New Generation Refrigerants and Refrigerant Blends Plant
1. R-32 PLANTR-32 can be purchased directly from market and store in MTF (Main Tank Farm) or ProductR-32 is manufactured by the following stepwise process:FEEDSECTION
REACTORSECTION
CRUDEDISTILLATION
WASHSECTION
MTF(MAINTANKFARM)
ITF(INTERMEDIATETANK FARM)
PRODUCTDISTILLATION
ANNEXURE - 2
6
Feed Section:Dichloromethylene & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Dichloromethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-31A.Then R-31A reacts with AHF & produce Hydrochloric acid & R-32A.Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R-32A isremoved in a crude form. From this section AHF & R-31A is recycled back to reactors bydifferent columns.Wash Section:Crude R-32A gas is scrubbed in water as a result dilute hydrofluoric acid get seperated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-32A is recovered in this operation and distilled R-31A is recycled back to crudedistillation.ITF &MTF:Product R-32A is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
2. R-600A PLANTR-600A can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductR-600A is manufactured by the following stepwise process:FEED SECTION DE-ETHANIZER DE-PROPANIZER
MTF (MAINTANK FARM)
ITF(INTERMEDIATETANK FARM)
DE-ISOBUTANIZER
Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane, Propane, n-Butane and Iso-butane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.
ANNEXURE - 2
7
De-Isobutanizer :Isobutane will separate out from mixture of n-Butane and Isobutane.ITF & MTF:Product Isobutane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
3. N-Butane PLANTn-Butane can be purchased directly from market and fill in MTF (Main Tank Farm) orProduct n-butane is manufactured by the following stepwise process :FEED SECTION DE-ETHANIZER DE-PROPANIZER
MTF (MAINTANK FARM)
ITF(INTERMEDIATETANK FARM)
DE-ISOBUTANIZER
Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane,Propane,n-Butane and Isobutane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.De-Isobutanizer:Isobutane will separate out from mixture of n-Butane and Isobutane.ITF &MTF:Product n-butane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
4. Propane PLANTPropane can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductPropane is manufactured by the following stepwise process:FEED SECTION DE-ETHANIZER DE-PROPANIZER
MTF(MAIN TANKFARM)
ITF (INTERMEDIATETANK FARM)
ANNEXURE - 2
8
Feed Section:LPG pumped from the respective storage vessels to De-ethanizer column.De-ethanizer column:Ethane will separate out from mixture of Ethane,Propane,n-Butane and Isobutane.De-propanizer Column:Propane will separate out from mixture of Propane,n-Butane and Isobutane.ITF &MTF:Product Propane is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
5. R-133A PLANTR-133A can be purchased directly from market and fill in MTF (Main Tank Farm) or ProductR-133A is manufactured by the following stepwise process:FEEDSECTION
REACTORSECTION
CRUDEDISTILLATION
WASHSECTION
MTF(MAINTANKFARM)
ITF(INTERMEDIATETANK FARM)
PRODUCTDISTILLATION
Feed Section:Trichloroethylene & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloroethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-133Aand Hydrochloric acid.Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R-133A isremoved in a crude form. From this section AHF & TCE is recycled back to reactors.Wash Section:Crude R-133A gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-133A is recovered in this operation.
ANNEXURE - 2
9
ITF &MTF:Product R-133A is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.6. R-21 PLANTR-21 can be purchased directly from market and fill in MTF (Main Tank Farm) or Product R-21 is manufactured by the following stepwise process:
FEED SECTION REACTOR SECTION WASH SECTION
MTF (MAINTANK FARM)
ITF (INTERMEDIATETANK FARM)
PRODUCTDISTILLATION
Feed Section:Trichloromethane & Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloromethane & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-21.Wash Section:Crude R-21 gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-21 is recovered in this operation.ITF &MTF:Product R-21 is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
7. TCE (Trichloroethylene) PLANTTCE can be purchased directly from market and fill in MTF (Main Tank Farm) or Product TCEis manufactured by the following stepwise process:FEEDSECTION
REACTORSECTION
WASH SECTION DECANTATION
MTF (MAINTANKFARM)
ITF(INTERMEDIATETANK FARM)
PRODUCTDISTILLATION
ANNEXURE - 2
10
Feed Section:Di Chloroethylene& chlorine gas pumped from the respective storage vessels to plantreactors.Reactor Section:Di Chloroethylene& chlorine gas reacts in a gas phase to produce TCE and Tetrachloroethylene.Wash Section:Crude TCE is scrubbed in water as a result dilute hydrochloric acid get separated asbyproduct, then by caustic wash and decantation it leads to dry acidity free crude.Product Distillation:Pure TCE is recovered in this operation and distilled Tetra chloroethylene is used asbyproduct.ITF &MTF:Product TCE is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
8. R-23 PLANTR-23 can be purchased directly from market and fill in MTF (Main Tank Farm) or Product R-23 is manufactured by the following stepwise process:FEED SECTION REACTOR SECTION WASH SECTION
MTF (MAINTANK FARM)
ITF (INTERMEDIATETANK FARM)
PRODUCTDISTILLATION
Feed Section:Trichloromethane& Anhydrous Hydrofluoric acid pumped from the respective storagevessels to plant reactors.Reactor Section:Trichloromethane& Anhydrous Hydrofluoric acid reacts in a gas phase to produce R-22 & R-23.Wash Section:Crude R-22 & R-23 gas is scrubbed in water as a result dilute hydrofluoric acid get separatedas byproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompresses to liquid form.Product Distillation:Pure R-23 is recovered in this operation.
ANNEXURE - 2
11
ITF & MTF:Product R-23 is then stored in ITF (Intermediate Tank Farm) for quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.9. R-125 PLANTR-125 will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.10. R-143 PLANTR-143 will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.11. R-152A PLANTR-152A will be purchased directly from market and fill in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.12. R-142B PLANTR-142B will be purchased directly from market and store in MTF (Main Tank Farm). Afterapproval from quality it will be sent for filling.13. R-404A PLANT (R-125: R-134A: R-143A = 44 : 4 :52)R-125 and R-143A will be purchased directly from market and fill in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-143A in specific ratio. After approval from quality it will be sent forfilling.14. R-407C PLANT (R-125: R-134A: R-32 = 25 : 52 :23)R-125 and R-32 will be purchased directly from market and fill in MTF (Main Tank Farm). R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.15. R-410A PLANT (R-125: R-32 = 50:50)R-125 and R-32 will be purchased directly from market and fill in MTF (Main Tank Farm).Then we will make a blend of R-125 and R-32 in specific ratio. After approval from quality itwill be sent for filling.16. Blend of R-152A and R-134AR-152A will be purchased directly from market and fill in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-152Aand R-134A in specific ratio. After approval from quality it will be sent for filling.
ANNEXURE - 2
12
Blend of R-142B and R-22R-142B will be purchased directly from market and fill in MTF (Main TankFarm).R- 22 will be manufactured within SRF and will be stored in MTF.Then we will make a blend of R-142B and R-22 in specific ratio.After approval from quality it will be sent for filling.17. Blend of R-134A and DME (Dimethyl Ether)Dimethyl ether will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-134A and DME in specific ratio. After approval from quality it will be sent for filling.18. R-407A PLANT (R-125: R-134A: R-32 = 40:40:20)R-125 and R-32 will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.19. R-407F PLANT (R-125: R-134A: R-32 = 30:40:30)R-125 and R-32 will be purchased directly from market and store in MTF (Main Tank Farm).R-134A will be manufactured within SRF and will store in MTF. Then we will make a blend ofR-125, R-134A and R-32 in specific ratio. After approval from quality it will be sent for filling.20. R-417A PLANT (R-125: R-134A: R-600 = 46.6 : 50 : 3.4)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.21. R-417B PLANT (R-125: R-134A: R-600 = 79 : 18.25 : 2.75)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.22. R-421A PLANT (R-125: R-134A =58: 42)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125and R-134A in specific ratio. After approval from quality it will be sent for filling.
ANNEXURE - 2
13
23. R-421B PLANT (R-125: R-134A =85: 15)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125and R-134A in specific ratio. After approval from quality it will be sent for filling.24. R-422A PLANT (R-125: R-134A: R-600A = 85.1:11.5: 3.4R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.25. R-422B PLANT (R-125: R-134A: R-600A = 55:42: 3)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.26. R-422C PLANT (R-125: R-134A: R-600A = 82:15: 3)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio. After approval from quality it will besent for filling.27. R-422D PLANT (R-125: R-134A: R-600A = 65.1:31.5: 3.4)R-125 and R-600A will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600A and R-134A in specific ratio.After approval from quality it will besent for filling.28. R-424A PLANT (R-125: R-134A: R-600A: R-600: R-601A = 50 : 47 : 0.9: 1 : 0.6)R-125, R-600, R-601A and R-600A will be purchased directly from market and store in MTF(Main Tank Farm). R-134A will be manufactured within SRF and will store in MTF. Then wewill make a blend of R-125, R-600A, R-601A, R-600 and R-134A in specific ratio. Afterapproval from quality it will be sent for filling.29. R-427A PLANT (R-125: R-134A: R-32: R-143A = 25 : 50 :15 :10)R-125, R-32 and R-143A will be purchased directly from market and store in MTF (MainTank Farm). Then we will make a blend of R-125, R-32 and R-143A in specific ratio. Afterapproval from quality it will be sent for filling.
ANNEXURE - 2
14
30. R-428A PLANT (R-125: R-143A: R-600A: R-290 = 77.5:20:1.9:0.6)R-125, R-290, R-143A and R-600A will be purchased directly from market and store in MTF(Main Tank farm). Then we will make a blend of R-125, R-600A, R-290 and R-143A in specificratio. After approval from quality it will be sent for filling.31. R-434A PLANT (R-125: R-143A: R-134A: R-600A = 63.2:18:16:2.8)R-125, R-143A and R-600A will be purchased directly from market and store in MTF (MainTank Farm). R-134A will be manufactured within SRF and will store in MTF. Then we willmake a blend of R-125, R-600A, R-134A and R-143A in specific ratio. After approval fromquality it will be sent for filling.32. R-438A PLANT (R-125: R-32: R-134A: R-600 = 45:8.5:44.2:2.3)R-125, R-32 and R-600 will be purchased directly from market and store in MTF (Main TankFarm). R-134A will be manufactured within SRF and will store in MTF. Then we will make ablend of R-125, R-600, R-32 and R-134A in specific ratio. After approval from quality it willbe sent for filling.33. R-507A PLANT (R-125: R-134A = 50:50)R-125 will be purchased directly from market and store in MTF (Main Tank Farm). R-134Awill be manufactured within SRF and will store in MTF. Then we will make a blend of R-125,R-134A in specific ratio. After approval from quality it will be sent for filling.
HFC 134A PLANTHFC-134APLANTProduct R134a is manufactured by the following stepwise process:Feed Section Reactor section Crude Distillation WashSection Product Distillation ITF (Intermediate tank farm)MTF (Main tank Farm)1. Feed Section:Trichloroethylene & Anhydrous Hydrofluoric acid Pumped from the respective storagevessels to plant reactors.2. Reactor Section:Trichloroethylene & Anhydrous Hydrofluoric acid reacts in a gas phase to produce R133a.Then R133a reacts with AHF & produce Hydrochloric acid & R134a.3. Crude Distillation:In this section Hydrochloric acid is removed from reactor outlet crude mixture & R134a isremoved in a crude form. From this Section AHF & R133a is recycled back to reactors by
ANNEXURE - 2
15
different columns.4. Wash Section:Crude R134a gas is scrubbed in water as a result dilute hydrofluoric acid get separated asbyproduct, then by sulfuric wash it leads to dry acidity free crude gas which is thencompressed to liquid form.5. Product Distillation:Pure R134a is recovered in this operation and distilled R133a is recycled back to crudedistillation.6. ITF & MTF:Product R134a is then stored in ITF (Intermediate tank farm) for Quality approval. Afterapproval from quality it is sent to MTF (Main Tank Farm) for storage and filling intocylinders.
Water
1. TFA
HCl
Water 33% HCl
2. TFAA
3. MCDFA
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
ReactorNeutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium MetaBisulfite
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction Distillation TFBAl Storage
RM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction Distillation Step IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
4. CDFA
Water
5. CDFAA
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
ReactorNeutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium MetaBisulfite
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction Distillation TFBAl Storage
RM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction Distillation Step IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
6. ETFA
7. ETFAAHCl
Crude ETFAA
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
ReactorNeutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium MetaBisulfite
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction Distillation TFBAl Storage
RM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction Distillation Step IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
8. PFBA
9. PFB
H2O
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
Reactor Neutralization
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
Distillation
PFB Storage
RM2Storage
RM1storage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction Distillation TFBAl Storage
RM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction Distillation Step IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
10.BPFB
11.PFP
12.PBFB
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
ReactorNeutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
Distillation
PFB Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorageTFA
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium Meta
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction Distillation TFBAl Storage
RM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassium
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation DistillationStep IV
Reaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction Distillation Step IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
15.EDFA
13.TFBAl
14.DFA
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
Reactor Neutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium Meta
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction
DistillationTFBAl StorageRM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction
Distillation Step IVReaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
17. Amino Crotonate
16.EDFAA
18. Trifluorophenyl Acetic Acid
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
Reactor Neutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium Meta
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction
DistillationTFBAl StorageRM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction
Distillation Step IVReaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
20. SF4
19.Trifluoroacetone
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
Reactor Neutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium Meta
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction
DistillationTFBAl StorageRM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3
DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction Filteration
Conc.H2SO4 Conc. HNO3 MeOHH2
Distillation Storage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction
Distillation Step IVReaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Multipurpose plant
21. DFMSC
22. ABTF
Reactor
Crude TFAADistillation
ReactorDistillation
TFAAStorage
MCDFAStorage
ReactorDistillation
CDFAStorage
RM2storage
RM1storage
Reactor CrudeCDFAA
Distillation
Reactor
DistillationETFA
Storage
Reactor Neutralization
Distillation
Filtration
ChlorinationReactor
FluorinationReactor Hydrolysis
Reactor Extraction
CDFAAStorage
RM1storage
RM2storage
RM1storage
RM1storage
RM2storage
RM2storage
RM3storage
RM1storage
PFBAStorage
RM2Storage
RM1Storage
ChlorineStorage H2SO4
Storage
RM1Storage
DistillationPFB
Storage
RM2Storage
RM1storage
RM2storage
ETFAAStorage
Reactor
CrudeDistillation
Hydrolysis
RM2storage
RM1storage
Absorbtion
TFAStorage
TFADistillation
ReactionRM1
RM 2
Extraction Distillation
Sulfolane
Sodium
Sodium Meta
BPFB Storage
ReactionRM1
RM2
Extraction Distillation
Ether
PFP Storage
ReactionRM1
RM2
Distillation PBFB Storage
ReductionRM1
Water
Hydrolysis Esterification Reduction
DistillationTFBAl StorageRM2
Sulfuric Acid Alcohol
ReactionRM1
RM2
Neutralization Drying DFA Storage
Sodium hydroxide
ReactionRM 1
RM 2
Separation EDFA Storage
Potassiumhydroxide
ReactionRM 1
RM 2
Filtration Distillation EDFAA Storage
ReactionRM 1
RM 2
DistillationAmino Crotonate
Storage
1. Reaction-I2. Filteration-I3. Distillation-I
RM1
RM2
1. Reaction-II2. Filteration-II3. Distillation-II
1. Reaction-III2. Filteration-III3. Distillation-III
ReactionRM1
RM 2
SeparationTrifluoroacetone
Storage
1. Reaction-IV2. Filteration-IV3. Distillation-IV
Trifluorophenyl Aceticacid Storage
RM 4
RM 3RM 5
RM 6
1.Morpholine2. Sulphur3. p-Toluene sulphnicacid4. NaOH5. HCl
ReactionRM 1
RM 3
RM 2
Reaction SF4 StorageDistillation
ReactionRM 1
RM 4
RM 2
Filteration DistillationReaction
RM 3DFMSc Storage
Water Chlorine
Step IReactionRM 1
RM 2
Distillation Step IIIReaction
Step IIReaction
Conc.H2SO4 Conc. HNO3 MeOHH2
DistillationStorage
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMeStorage
Step IReaction
RM 1
RM 2
Step IIIReaction
Distillation Step IVReaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOTStorage
MTBE Ammonia
Filteration
Multipurpose plant
23.
SYNTHON1
24. HFPOT
Step IReaction
RM 1
RM 2
Step IIIReaction
DistillationStep IV
Reaction
HF
Step IIReaction Filteration Filteration Washing
Hexane Water
Distillation Distillation Synthon1Storage
Copper
Cao
NH3Chlorine HF
MTBE Ammonia
25. DFBD
26. DFBD-Me
Step IReaction
RM 1
RM 2
Step IIReaction
Step IIIReaction
DFBD Storage
HBr H2O2HF DCM
Distillation Distillation
Step IReaction
RM 1
RM
Step IIReaction
Step IIIReaction
Distillation
Br2 FeHF
Distillation Distillation
Step IVReaction
N-
Butylithuim Dry Ice
Step VReaction
Methanol H2SO4
Distillation Distillation DFBDMe Storage
ReactionRM 1
RM 2
Filteration Washing FilterationDistillation Distillation Purification Filteration Distillation HFPOT Storage
Multipurpose plant
1 R-600A (IsoButane)
2 R-600 (N-Butane)
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
De-
Isobutanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
De-
Isobutanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
De-
Isobutanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
De-
Isobutanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
3 R-290 (N-Propane)
4 R-133A (Chloro Tri Fluoro Ethane)
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Ethylene
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Crude
Distillation
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
LPG Storage
Tank
De-
Ethanizer
Column
De-
Propanizer
Column
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Ethylene
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Crude
Distillation
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
Refrigerant blends plant1
5 R-21 (Di Chloro Fluoro Methane)
6 TCE (Tri Chloro Ethylene)
Tri Chloro
Methane
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Ethylene
Filling Station
Tri Chloro
Methane
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Ethylene
Filling Station
7 R-23 (Tri Fluoro Methane)
Ethylene
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Decantat
ion
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Methane
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
Ethylene
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Decantat
ion
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Tri Chloro
Methane
Storage Tank
Anhydrous
Hydrofluoric
Acid Storage
Tank
Reaction
Section
Wash
Section
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank
Filling Station
Filling Station
Refrigerant blends plant2
8 R-227 (HeptaFluoro Ethane)
9 R-125 (Tri Fluoro Methane)
Main Storage
Tank
Filling Station
Crude Hepta
Fluoro Ethane
Storage Tank
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank Filling Station
Main Storage
Tank
Filling Station
Crude Hepta
Fluoro Ethane
Storage Tank
Product
Distillation
Intermediate
Storage Tank
Main Storage
Tank Filling Station
10 R-143 (Tri Fluoro Ethane)
11 R-152 (Di Fluoro Ethane)
Main Storage
Tank
Filling Station
Main Storage
Tank
Filling Station
Main Storage
Tank
Filling Station
Main Storage
Tank
Filling Station
Refrigerant blends plant3
12 R-142B (Chloro Di Fluoro Ethane)
13 R-404A
Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
14 R-407C
R-143A
Storage Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-32 Storage
Tank
R-143A
Storage Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-32 Storage
Tank
Refrigerant blends plant4
15 R-410A
16 Blend of R-152A and R-134A
R-125 Storage
Tank
R-32 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-152A
Storage Tank
R-125 Storage
Tank
R-32 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-152A
Storage Tank
17 Blend of R-142B and R-22
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-142B
Storage Tank
R-22 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-142B
Storage Tank
R-22 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
Refrigerant blends plant5
18 Blend of R-134A and DME (DiMethyl Ether)
19 R-407A
R-142B
Storage Tank
R-22 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-142B
Storage Tank
R-22 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
20 R-407F
R-32 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-32 Storage
Tank
R-32 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-32 Storage
Tank
Refrigerant blends plant6
21 R-417A
22 R-417B
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-125 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-125 Storage
Tank
23 R-421A
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
Refrigerant blends plant7
24 R-421B
25 R-422A
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
26 R-422B
Storage Tank
R-600A
Storage Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600A
Storage Tank
Storage Tank
R-600A
Storage Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600A
Storage Tank
Refrigerant blends plant8
27 R-422C
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-600A
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-600A
Storage Tank
28 R-422D
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-600A
Storage Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank Filling Station
R-600A
Storage Tank
Refrigerant blends plant9
29 R-424A
R-125
Storage Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-600A
Storage Tank
R-125
Storage Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-600 Storage
Tank
R-600A
Storage Tank
30 R-427A
R-601A
Storage Tank
R-125
Storage Tank
R-134 A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-32 Storage
Tank
R-143A
Storage Tank
R-601A
Storage Tank
R-125
Storage Tank
R-134 A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-32 Storage
Tank
R-143A
Storage Tank
Refrigerant blends plant10
31 R-428A
R-125 Storage
Tank
R-600A
Storage Tank
Blender Intermediate
Stotage tankDryer Main Storage
Tank Filling Station
Propane
Storage Tank
R-143A
Storage Tank
R-125 Storage
Tank
R-600A
Storage Tank
Blender Intermediate
Stotage tankDryer Main Storage
Tank Filling Station
Propane
Storage Tank
R-143A
Storage Tank
32 R-434A
R-125 Storage
Tank
R-600A
Storage Tank
Blender Intermediate
Stotage tankDryer Main Storage
Tank Filling Station
R-134A
Storage Tank
R-143A
Storage Tank
R-125 Storage
Tank
R-600A
Storage Tank
Blender Intermediate
Stotage tankDryer Main Storage
Tank Filling Station
R-134A
Storage Tank
R-143A
Storage Tank
Refrigerant blends plant11
33 R-438A
R-125 Storage
Tank
R-600 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-134A
Storage Tank
R-125 Storage
Tank
R-600 Storage
Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-134A
Storage Tank
34 R-507A
R-32 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
R-32 Storage
Tank
R-125 Storage
Tank
R-134A
Storage Tank
Blender Intermediate
Stotage tank
Dryer Main Storage
Tank
Filling Station
Refrigerant blends plant12
R-134A (1,1,1,2-Tetrafluoro Ethane)
RM 1
RM2 StorageTank
ReactionSection
CrudeDistillation
WashSection
ProductDistillation
IntermediateStorage Tank
Main StorageTank
Filling Station
R-32 (Di Fluoro Methane)
RM2 StorageTank
ReactionSection
CrudeDistillation
WashSection
ProductDistillation
IntermediateStorage Tank
Main StorageTank
Filling Station
RM 1
RM 2 Storage
ReactionSection
CrudeDistillation
WashSection
ProductDistillation
IntermediateStorage Tank
Main StorageTank
Filling Station
HFC 134a1
Methyl Chloride (C1)
CMS Plant C1IntermediateStorage Tank
C1 MainStorage Tank
Filling StationCMS Plant C1IntermediateStorage Tank
C1 MainStorage Tank
Filling Station
Chloromethane plant1
Annexure - 4
1
Raw Material Requirement, Source & Transportation
1. Multipurpose plant (Fluorospeciality plant)
S. No Name Existing
Storage (MT)
Proposed
(MT)
Total after
expansion
(MT)
Source of Raw Material Mode of
Transportation Mode of Storage
1. Trichloro acetyl
Chloride 60 30 90
Tml Industries Ltd & Hari Orgochem Pvt. Ltd.
Baroda, Gujarat By Road Tank/Drums
2. Anhydrous Hydrofluoric
Acid 3 1.5 4.5 In House
By Pipeline within
plant premises Tank
3. Methanol 12 6 18 B.K. Sales Corporation By Road Common Storage With
CMS Plant
4. Ethanol 16 8 24 DCM Shriram Industries Ltd. Unit - Daurala
Sugar Works, Daurala, UP By Road Tank/Barrels
5. Sulfuric Acid 8 4 12
Oriental Carbo & Chemicals Ltd. Dharuhera,
Gurgaon; Sunny Trading Co. Chittorgarh,
Udaipur, Rajasthan; The Jayshree Chemicals &
Fertilizers, Pataudi, Gurgaon
By Road Tank
6 Benzonitrile 3 1.5 4.5
Hebei Fulong Import & Export Co. Ltd, China;
Zhejiang Tongxiang Foreign Trade (Group)C
Ltd. China
By Ship & By Road Drums
7 Chlorine 1 0.5 2
Aditya Birla Chemicals India Ltd. Palamu,
Jharkhand; Grasim Industries Ltd. Nagda;
Kanoria Chemicals & Industries Ltd.
Renukoot; Lords Chloro Alkali Ltd. Alwar;
Shriram Vinyl & Chemicals Industries, Kota;
Shriram Alkali & Chemicals Ltd. Jhagadia;
Punjab Alkalies & CHemcials Ltd., Nangal Siel
Chemicals Complex, Rajpura
Nirma Limited, Vill. Kalatalav, Distt. Bhav
Nagar, Gujarat
By Road Tonners
8 Potassium Fluoride 100 50 150 Tanfac Ltd, Cuddulore,Tamil Nadu By Road Stored in Plastic
Annexure - 4
2
Packaging
9 Sodium Hydroxide(48
%) 27 13.5 40.5 Rajendra Trading Co./ SVCI Kota
By Pipeline within
plant premises
Common Storage With
CMS Plant
10 Potassium Hydroxide 35 17.5 52.5 Hukum Chand,Delhi By Road Stored in plastic
Packaging
11 Ferric Chloride 0.1 0.05 0.15 Tital Biotec Bhiwadi By Road Stored in Plastic
Packaging
12 Toulene 1.5 0.75 2.25 Hemco Organics,new Delhi & R.P.G
Enterprises, Delhi By Road Stored In Barrels
13 Bromine 5 2.5 7.5
Solaris Chemtech Industries Ltd, Tata
Chemicals Ltd & Agrocel Industries Ltd.
Kutch, Gujarat
By Road Stored In Bottles
14 Sodium Sulphate 0.1 0.05 0.15 Hukum Chand,Delhi By Road Stored In Bags
15 Zinc Dust/Powder 10 5 15 Transpek-Silox Limited, Gujarat By Road Drums
16 Sodium Borohydride 3 1.5 4.5 Hasmukhray & Co., Mumbai By Road Stored in Plastic
Packaging
17 Monoglyme 5 2.5 7.5 Hasmukhray & Co., Mumbai By Road Stored In Barrels
18 Methylene Chloride 1 0.5 1.5 In House By Road Stored In Barrels
19 Sodium Carbonate 3 1.5 4.5 J Brothers & Hukum Chand, Delhi By Road Stored in Plastic
Packaging
20 Sodium Bi Sulphite 0.5 0.25 0.75 Sheel Scientific, Rajasthan By Road Stored in Plastic
Packaging
21 Acetic Acid 0.5 0.25 0.75 Hukum Chand, Delhi By Road Stored In Carboys
22 Potassium Dihydrogen
Phosphate 3 1.5 4.5
Hukum Chand, Delhi
Oscar Chemicals, Ahmedabad By Road
Stored in Plastic
Packaging
23 Diethyl Ether
0 0 Sheel Scientific, Rajasthan By Road Stored in Plastic
Packaging
24 Sodium meta bi Sulphite 3 1.5 4.5 Hukum Chand,Delhi By Road Stored in Plastic
Packaging
25 Tetra Fluoro Ethyl
Methyl Ether 13 6.5 19.5 HFL Hyderabad By Road Tank
Annexure - 4
3
26 Ethyl Acetate 20 10 30 Sheel Scientific, Rajasthan By Road Tank
27 Anhydrous Hydrochloric
Acid - - - In House
By Pipeline within
plant premises
Tapping From the CMS
Plant Distillation
Column
28 Cyclo hexane 10 5 15
Sachin Chemical Mumbai
Hasmukhray & Co Mumbai
International Solvents & Chemicals Company,
Mumbai
By Road Stored In Barrels
29 Anhydrous Ammonia 1 0.5 1.5 Aggarwal Gas Agency, Bhiwadi, Rajasthan By Road Stored In Cylinders
30 Liquid Nitrogen 35 17.5 52.5 INOX AP, Dharuheda, Haryana By Pipeline within
plant premises
Common Storage With
CMS Plant/HFC-134a
plant
31 Fluorine 5 2.5 7.5 Solvay, South Korea By Road Drum/Cylinder/Tanks
32 Sulphur 0 15 15 - By Road Drum/Cylinder/Tanks
33 Benzyl Chloride 0 15 15 - By Road Drum/Cylinder/Tanks
34 Thiourea 0 20 20 - By Road Drum/Cylinder/Tanks
35 Benzotrichloride 0 30 30 - By Road Drum/Cylinder/Tanks
36 Nitric Acid 0 12 12 GNFC / Oswal Chemicals By Road Drum/Cylinder/Tanks
37 Raney Nickel 0 0.5 0.5 - By Road Drum/Cylinder/Tanks
38 Copper 0 2 2 - By Road Drum/Cylinder/Tanks
39 Copper Acetate 0 10 10 Vipul Life Sciences By Road Drum/Cylinder/Tanks
40 Hexane 0 15 15 - By Road Drum/Cylinder/Tanks
41 p-Chlorotoluene 0 30 30 - By Road Drum/Cylinder/Tanks
42 Dimethylformamide 0 20 20 - By Road Drum/Cylinder/Tanks
43 Hexafluoropropylene
(HFP) 0 25 25 Hangzhou Ruilipu Trade CO. Ltd. China By Road Drum/Cylinder/Tanks
44 Potassium Carbonate 0 1 1 Universal Chemicals /Manish Chemicals /
Oswal Chemicals/ R R Innovative By Road Drum/Cylinder/Tanks
45 Methyl tert-butyl ether
(MTBE) 0 12 12 SAVLA CHEMICALS / VINATI ORGANICS By Road Drum/Cylinder/Tanks
Annexure - 4
4
46 O-Toluidine 0 15 15 Oscar Chemicals (Deepak Nitrite) By Road Drum/Cylinder/Tanks
47 Sodium dithionite
(Na2S2O4) 0 6 6 Tranpsek - Silox By Road Drum/Cylinder/Tanks
48 Tetrabutyl ammonium
hydrogen sulfate 0 5 5 - By Road Drum/Cylinder/Tanks
49 1,3 Benzodioxide 0 25 25 MDB Chemicals By Road Drum/Cylinder/Tanks
50 Phosphorus
pentachloride 0 10 10 Sandhya Industries By Road Drum/Cylinder/Tanks
51 Hydrogen Bromide 0 20 20 - By Road Drum/Cylinder/Tanks
52 Hydrogen Peroxide
(50%) 0 5 5
Guljag Industries / Manish Chemicals and
others By Road Drum/Cylinder/Tanks
53 Acetonitrile 0 10 10 Krishna Solvchem (Alkyl Amines) and others By Road Drum/Cylinder/Tanks
54 Chloro sulfuric acid 0 50 50 - By Road Drum/Cylinder/Tanks
55 Dichloro acetophenone 0 20 20 - By Road Drum/Cylinder/Tanks
56 Morpholine 0 12 12 - By Road Drum/Cylinder/Tanks
57 p-Toluenesulfonic acid 0 1 1 - By Road Drum/Cylinder/Tanks
58 Sulfolane 0 10 10 Cadila Pharma (Casil Industries) By Road Drum/Cylinder/Tanks
59 Dimethyl Amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
60
Boron
tribromide/chloride/flu
oride
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
61 Boron trifluoride
etherate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
62 sec/n-butyl nitrite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
63
Ortho/meta/para-
fluoro/chloro/bromo/io
do-aniline
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
64 Boric acid (H3BO3) 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
65 Sodium nitrite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
66 ortho/meta/para-
difluoro/dichloro/dibro0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
Annexure - 4
5
mo/diiodo-benzene
67
Tetraalkyl ammonium
bromide/chloride/fluori
de/iodide
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
68 Sodium sulphite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
69
Aluminium
chloride/fluoride/bromi
de/iodide
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
70 butanol/popanol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
71 Ethylene dichloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
72 benzenediol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
73 N-Methyl pyrrolidone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
74 Lithium aluminium
hydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
75 n-/sec-butyl lithium 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
76 Tetrahydrofuran 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
77 N-Bromo/chloro-
succinimide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
78 Formaldehyde 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
79 Sodium/potassium -
iodide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
80 Iodine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
81 Alkyl iodide/chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
82 Methyl-2-chloroacetate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
83 Sodium/Potassiummetho
xide/ ethoxide/butoxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
84 Dioxane 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
85 Dimethyl oxalate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
86 Mono/Diethylene glycol 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
87 Acetone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
Annexure - 4
6
88 Acrylonitrile 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
89 Acetaldehyde 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
90 Acetophenone 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
91 Sodium hydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
92 Propionotrile 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
93
Ethyl
Chloride/bromide/iodid
e
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
94 Methyl pyridine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
95 Xylene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
96 Tri alkyl chloro silane 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
97 Ammonium chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
98 Ammonium hydroxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
99 Acetaldoxime 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
100 Monomethyl hydrazine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
101 Hydrazine hydrate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
102 Hydroxyl amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
103 Copper sulphate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
104 Magnesium
chloride/bromide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
105 Ethyl vinyl ether 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
106 Dimethyl sulphoxide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
107 Thionyl chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
108 Methane sulphonyl
chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
109 Pyridine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
110 Anisole 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
111 Sodium Thiosulphate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
112 Isopyopyl bromide/
chloride/iodide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
Annexure - 4
7
113 Hydroxyl toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
114 Benzene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
115 Triethyl/methyl amine 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
116 Carbon disulphide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
117 Chloro/bromo/fluoro/
iodo toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
118 Trimethyl acetyl
chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
119 Acetic anhydride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
120 Dimethyl acetamide 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
121 Potassium
Permanganate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
122 Phosphorus
oxy/tri/penta-chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
123 Ethyl acetoacetate 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
124 Aniline 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
125 Methyl trioctyl
ammonium chloride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
126 Butylated hydroxyl
toluene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
127 Sodium bisulphite 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
128 Benzotrifluoride 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
129
Amino benzo-
trifluoride/chloride/bro
mide/iodide
0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
130 Chloro/bromo/iodo/flu
oro-benzene 0 10 10 Domestic & International market By Road Drum/Cylinder/Tanks
Annexure - 4
8
2. Chloromethane plant
S. No. Raw Material Requirement (TPD) Source of Raw Material Transportation
1. Chlorine 170 Aditya Birla Chemicals India Ltd., Palamu, Jharkhand; Grasim
Industries Ltd., Nagda; Kanoria Chemicals & Industries Ltd., Renukoot;
Lords Chloro Alkali Ltd., Alwar; Shriram Vinyl & Chemicals Industries,
Kota
Shriram Alkali & Chemicals Ltd., Jhagadia; Punjab Alkalies & Chemicals
Ltd., Nangal; Siel Chemical Complex, Rajpura; Nirma Limited, Vill.
Kalatalav, Distt. Bhav Nagar
By Road
2. Sodium Hydroxide 7.5 Rajendra Trading Co. / Svci Kota By Road
3. Sulphuric Acid 10.0 Oriental Carbon & Chemicals Ltd., Dharuhera, Gurgaon; Sunny Trading
Co., Chittorgarh, Udaipur, Rajasthan; The Jayshree Chemicals &
Fertilizers, Pataudi, Gurgaon
By Road
4. Methanol 51.0 B.K. Sales Corporation By Road
5. Liq. Nitrogen 0.5 Air Liquide North India Ltd., Panipat & Roorkee By Road
3. New Generation Refrigerants & Refrigerant Blends Plant
S. No. Raw Material Requirement (TPA) Source Mode of transportation
1 MDC 21275.1 In House
2 HF 503.1 In House
3 LPG 13586.1 IOCL/BPCL/HPCL refineries By road
4 Chloroform (C3) 3870.9 In House
5 EDC 900.9 China By Sea
6 Cl2 600.6 Aditya Birla/Shriram Alkali/As Existing By Road
7 R-22 376.2 In House
8 DME 1250.7 China By Sea
9 R-134A 9520.5 In House
10 R-601A 9.9 China By Sea
Annexure - 4
9
11 R-32 (Difluoromethane) 5260.2 China/In house By Sea
12 R-600A (Isobutane) 234.3 China By Sea
13 R-600 (n-Butane) 85.8 China By Sea
14 R-290 (Propane) 9.9 China By Sea
15 TCE (Trichloroethylene) 600.6 In House
16 R-125 (Pentafluoroethane) 17087.4 China By Sea
17 R143A (Trifluoroethane) 1643.4 China By Sea
18 R-152A (Difluoroethane) 999.9 China By Sea
19 R-142B (Chlorodifluoro Ethane) 376.2 China By Sea
20 R-227 Technical grade 1999.8 China By Sea
4. HFC134a Plant
S. No. Raw Material Requirement
Source TPD TPA
1 TCE 52 17160 In House
2 AHF 36 12000 In House
3 C2 62 20460 In House