danube sediments of serbia v15v1 as is v16 only for suppinfo42 cashmeran (dpmi) 33704‐61‐9 musk...

Supplementary information

Investigating levels of organic contaminants in Danube River sediments in Serbia by multi–ratio equilibrium passive sampling

Tatsiana P. Rusinaa,1, Foppe Smedesa,1,*, Maja Brborićb and Branislav Vranaa

a Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Science,

Masaryk University, Kamenice 753/5, 625 00 Brno, Czech Republic

b Department of Environmental Engineering and Occupational Safety and Health, Faculty of

Technical Sciences, University of Novi Sad, Serbia

1 These authors contributed equally

* Corresponding Author: Foppe Smedes Email: [email protected]; Tel: +420 549 493 097; Fax: +420 549 492 840 Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Sciences, Masaryk University, Kamenice 753/5, 625 00 Brno, Czech Republic

1

Table of content

S1. Sampling locations in Danube River (Serbia) ............................................................................................. 2

S2. Water temperature and sediment macro parameters ................................................................................... 3

S3. List of target contaminants (A and B) and PRC (C) with relevant properties ............................................ 4

S4. Criteria used to identify data possibly affected by evaporation or degradation .......................................... 6

S5. Relationship of the error for calculated KAOC with fPRC ............................................................................... 7

S6. LogKAOC for PS1–3 versus the sampler–sediment uptake capacity ratio .................................................... 8

S7. Similar to S6 but comparing PCB145 and PCB204 for all locations but D11 ............................................ 9

S8. Location averaged KAOC for PRC equilibrated .......................................................................................... 10

S9. PRC (weighted) average KAOC versus KOW. ............................................................................................... 10

S10. CW corresponding to LOQ of sampler analysis ......................................................................................... 11

S11. Results of non-linear least squares regressions (NLS) .............................................................................. 12

S12. Profiles of dissolved and AOC based concentrations in the Danube stretch ............................................ 27

S13. Concentrations in surfacea and sediment poreb water ............................................................................... 34

S14. Concentrations in surface water versus pore-water .................................................................................. 36

S15. Ratio of CW in surface and pore water versus KOW ................................................................................... 37

S16. Relationships of dissolved and AOC based concentration ....................................................................... 38

S17. LogKAOC, average, median and weighted average .................................................................................... 39

S18. LogKAOC plotted versus logKOW for all data .............................................................................................. 40

S19. Testing compliance with the WFD EQS for priority substances .............................................................. 41

S20. PCB concentrations measured in fish and derived from sediment passive sampling ............................... 42

S21. Graphs of CW versus CAS with NLS results and CTot ................................................................................. 43

2

S1. Sampling locations in Danube River (Serbia)

Sample ID

Location name

River

kilometer

Coordinates of sampling location

Sampling date

Left or

right

Location or sampling information

D1 Apatin 1401 45˚40’12.59” N, 18˚58’10.78” E

19.11.2012 L Sample taken from the riverbank near the city of Apatin

D2 Labudnjača 1345 45˚25’12.63” N, 19˚01’54.25” E

19.11.2012 L Rural area, no special activities

D3 Neštin 1294 45˚13’50.25” N, 19˚26’16.35” E

19.11.2012 R Sediment sampled in a smaller right‐hand parallel river path near Neštin.

D4 Begeč 1276 45˚13’54.20” N, 19˚39’55.64” E

15.11.2012 L Sediment sampled in left‐hand side arm with no direct flow

D5 Ratno Ostrvo

1253 45˚15’48.02” N, 19˚53’00.87” E

15.11.2012 L Sediment sample taken immediately downstream of the thermal power and heating plant near Novi Sad

D6 Šangaj 1251 45˚14’08.33” N, 19˚55’35.65” E

15.11.2012 L Rural area, downstream from Novi Sad

D7 Knićanin 1214 45˚07’40.34” N, 20˚17’08.81” E

15.11.2012 L Sampling locations directly downstream where the Tisa river enters the Danube.

D8 Belegiš 1195 45˚00’34.70” N, 20˚20’28.59” E

16.11.2012 R Location at the right‐hand bank in a parallel stream of the Danube 40 km upstream of Belgrade

D9 Ritopek 1141 44˚44’39.99” N, 20˚38’32.66” E

16.11.2012 R Rural area with sampling on the right‐hand bank in the Danube 40 km downstream of Belgrade

D10 Dubravica 1102 44˚42’49.35” N, 21˚02’35.85” E

16.11.2012 R Sampling immediately downstream and in the outflow of Velika Morava river

D11 Ram 1077 44˚48’49.83” N, 21˚19’49.11” E

16.11.2012 R Sediment was sampled from near the ferry to Stara Palanka. In hindsight, likely not the best location as the extreme sandy sample and new constructed riverbank, suggests that perhaps construction sand was sampled.

3

S2. Water temperature and sediment macro parameters

Sample ID

Location name Water temperature,

ºC

Sediment

pHa fAOC b

fBC

fOC

D1 Apatin 8.2 7.47 0.0006 0.0034 0.0040

D2 Labudnjača 8.2 7.40 0.0017 0.0067 0.0084

D3 Neštin 8.2 7.63 0.0026 0.0107 0.0133

D4 Begeč 8.1 7.54 0.0014 0.0055 0.0069

D5 Ratno Ostrvo 8.0 7.47 0.0009 0.0045 0.0054

D6 Šangaj 8.0 7.42 0.0017 0.0064 0.0081

D7 Knićanin 7.6 7.24 0.0027 0.0102 0.0129

D8 Belegiš 8.4 7.50 0.0006 0.0024 0.0030

D9 Ritopek 8.2 7.48 0.0024 0.0096 0.0120

D10 Dubravica 8.4 7.39 0.0020 0.0078 0.0098

D11 Ram 9.0 7.84 0.0002 0.0003 0.0005

a Sediment pH measured after dilution of 50 mL sediment with and equal volume of Milli‐Q water

b Organic carbon fractions in the sampled sediments, i.e. amorphous‐ (AOC),

black residual carbon ‐ (BC) and total‐ organic carbon (OC), all on dry‐weight basis.

4

S3. List of target contaminants (A and B) and PRC (C) with relevant properties

S3A Hydrophobic target compounds

No Compound Cas No Typea MW logKOWb Mvolb logKPW KPW source

1 PCB 28 7012‐37‐5 PCB 257.55 5.70 196.06 5.53 Smedes et al 2009







8 Pentachlorobenzene 608‐93‐5 OCPc 250.34 5.11 151.72 4.61 Smedes et al 2009

9 Hexachlorobenzene 118‐74‐1 OCP 284.78 5.72 165.26 5.05 Smedes et al 2009

10 2,4‐DDE 3224‐82‐6 OCP 320.05 6.00 243.25 6.15 Smedes 2018a

11 2,4‐DDD 53‐19‐0 OCP 320.05 6.00 243.25 5.51 Smedes 2018a

12 4,4’‐DDE 72‐55‐9 OCP 318.03 6.05 237.01 6.27 Smedes 2018a

13 4,4’‐DDD 72‐54‐8 OCP 320.05 6.04 243.25 5.38 Smedes 2018a

14 Naphthalene 91‐20‐3 PAH 128.17 3.15 128.03 3.03 Smedes et al 2009

15 Biphenyl 92‐52‐4 PAH 154.21 3.73 155.45 3.63 Smedes et al 2009

16 Acenaphthylene 208‐96‐8 PAH 152.20 3.72 144.61 3.26 Smedes et al 2009

17 Acenaphthene 83‐32‐9 PAH 154.21 3.27 150.80 3.62 Smedes et al 2009

18 Fluorene 86‐73‐7 PAH 166.22 3.83 161.41 3.79 Smedes et al 2009

19 Phenanthrene 85‐01‐8 PAH 178.23 4.30 172.03 4.11 Smedes et al 2009

20 Anthracene 120‐12‐7 PAH 178.23 4.30 172.03 4.21 Smedes et al 2009

21 Fluoranthene 206‐44‐0 PAH 202.26 4.83 188.60 4.62 Smedes et al 2009

22 Pyrene 129‐00‐0 PAH 202.26 4.88 188.60 4.68 Smedes et al 2009

23 Benzo[b]fluorene 243‐17‐4 PAH 216.28 4.99 205.40 4.90 Fittedd

24 Benzo[ghi]fluoranthene 203‐12‐3 PAH 226.28 5.40 205.18 5.11 Fitted

25 Benz[a]anthracene 56‐55‐3 PAH 228.29 5.46 216.02 5.32 Smedes et al 2009

26 Chrysene 218‐01‐9 PAH 228.29 5.46 216.02 5.25 Smedes et al 2009

27 Triphenylene 217‐59‐4 PAH 228.29 5.42 216.02 5.15 Fitted

28 Retene 483‐65‐8 PAH 234.34 6.19 238.54 5.27 Fitted

29 Benzo[b]fluoranthene 205‐99‐2 PAH 252.32 5.96 232.59 5.74 Smedes et al 2009

30 Benzo[k]fluoranthene 207‐08‐9 PAH 252.32 5.99 232.59 5.74 Smedes et al 2009

31 Benzo[a]pyrene 50‐32‐8 PAH 252.32 6.01 232.59 5.69 Smedes et al 2009

32 Benzo[e]pyrene 192‐97‐2 PAH 252.32 5.99 232.59 5.63 Fitted

33 Benzo[j]fluoranthene 205‐82‐3 PAH 252.32 5.99 232.59 5.64 Fitted

34 Perylene 198‐55‐0 PAH 252.32 5.99 232.59 5.64 Fitted

35 Benzo[ghi]perylene 190‐86‐3 PAH 276.34 6.56 249.17 6.02 Smedes et al 2009

36 Dibenz[a,h]anthracene 53‐70‐3 PAH 278.35 6.62 260.01 6.24 Smedes et al 2009

37 Indeno[1,2,3‐cd]pyrene 193‐39‐5 PAH 276.34 6.54 249.17 6.06 Smedes et al 2009

38 Coronene 191‐07‐1 PAH 300.36 7.13 265.74 6.63 Fitted

39 Benzo‐Naphtho‐Thiophene 239‐35‐0 PAH 234.32 5.37 206.73 5.27 Fitted

40 Galaxolide (HHCB) 1222‐05‐5 Musk 258.40 5.02 270.98 5.32 Smedes 2018a

41 Tonalide (AHTN) 1506‐02‐1 Musk 258.40 5.32 274.75 5.29 Smedes 2018a

42 Cashmeran (DPMI) 33704‐61‐9 Musk 206.33 3.71 220.40 4.50 Smedes 2018a

43 Tris(1‐chloro‐2‐propyl) phosphate 13674‐84‐5 OPFR 327.57 2.47 259.12 3.59 Smedes 2018a

44 Tris(1,3‐dichloro‐2‐propyl) phosphate 13674‐87‐8 OPFR 430.91 3.16 300.44 3.85 Smedes 2018a

45 Triisobutylphosphate 126‐71‐6 OPFR 266.32 2.93 268.19 4.99e e

46 Tri‐n‐butylphosphate 126‐73‐8 OPFR 266.32 3.88 268.83 4.99 Smedes 2018a

47 Triphenyl phosphate 115‐86‐6 OPFR 326.29 4.66 282.16 5.00 Smedes 2018a

48 Tris(2‐ethylhexyl) phosphate 78‐42‐2 OPFR 434.64 8.76 469.81 6.36 Smedes 2018a

5

S3B Polar pesticides

No Compound Cas No Typea MW logKOWb Mvolb logKPW

f >99% Neutral in pH rangeg

49 Atrazine 1912‐24‐9 Pest 215.69 2.55 193.23 2.30 6.2‐12.5

50 Chlortoluron 15545‐48‐9 Pest 212.68 2.35 191.43 2.02 up to 11.5

51 Isoproturon 34123‐59‐6 Pest 206.29 2.81 211.28 2.25 up to 11.8

52 Terbuthylazine 5915‐41‐3 Pest 229.72 3.06 209.46 3.01 6.2‐12.1

53 Diazinon 333‐41‐5 Pest 304.35 3.58 273.15 4.24 6.2‐14.0

54 Carbendazim 10605‐21‐7 Pest 191.19 1.46 165.80 1.76 6.3‐7.7

55 Metolachlor 51218‐45‐2 Pest 283.80 3.55 271.81 3.24 up to 12

56 Chlorpyrifos 2921‐88‐2 Pest 350.59 5.16 251.40 4.90 no dissociation

57 Propiconazole 60207‐90‐1 Pest 342.23 3.64 283.81 4.10 4.0‐14.0

58 Tebuconazole 80443‐41‐0 Pest 307.82 3.59 287.16 3.23 4.0‐11.8

S3C Performance reference compounds

No Compound Cas No Typea MW logKOWb Mvolb logKPW KPW source

100 Biphenyl‐d10 PRC 1486‐01‐7 PRC 164.27 3.73

3.63 Smedes 2018a

101 PCB 1 PRC 2051‐60‐7 PRC 188.66 4.36 168.99 4.22 Smedes 2018b













a compound category related to its nature or use

b Molinspiration, 2017. Cheminformatics on the Web, http://www.molinspiration.com. Accessed December 2017.

c compound categorised under OCP but is not really an OCP

d the KPW of compounds marked with “Fitted” were calculated as logKPW=0.205 MW + 0.47, as proposed by Smedes et al 2009

e the KPW was set equal to that of Tri‐n‐butylphosphate

f Smedes et al in preparation

g estimated by online calculator https://chemicalize.com/#/calculation

Smedes, F., Geertsma, R.W., van der Zande, T., Booij, K., 2009. Polymer-water partition coefficients of hydrophobic compounds for passive sampling: Application of cosolvent models for validation. Environ. Sci. Technol. 43, 7047-7054.

Smedes, F., 2018a. Silicone–water partition coefficients determined by cosolvent method for chlorinated pesticides, musks, organo phosphates, phthalates and more. Chemosphere. 210, 662-671.

Smedes, F., 2018b. Corrigendum to “Silicone–water partition coefficients determined by cosolvent method for chlorinated pesticides, musks, organo phosphates, phthalates and more” [Chemosphere 210 (2018) 662–671]. Chemosphere. 212, 1180.

6

S4. Criteria used to identify data possibly affected by evaporation or degradation

Volatile compounds for with the results were suspected to be affected by evaporation if the recovery of the “corresponding” RIS did not meet the criterion listed in the last column. Benzo[a]pyrene and Perylene are sensitive for degradation, possibly by light, and monitored by perylene‐d12

No Compound RIS Criterion

8 Pentachlorobenzene PCB 4 >60%

9 Hexachlorobenzene PCB 4 >60%

14 Naphthalene Naphthalene‐d8 >60%

15 Biphenyl Naphthalene‐d8 >60%

16 Acenaphthylene Naphthalene‐d8 >50%

17 Acenaphthene Naphthalene‐d8 >50%

18 Fluorene Naphthalene‐d8 >40%

19 Phenanthrene Phenanthrene‐d10 >75%

20 Anthracene Phenanthrene‐d10 >75%

21 Fluoranthene Phenanthrene‐d10 >50%

22 Pyrene Phenanthrene‐d10 >50%

31 Benzo[a]pyrene Perylene‐d12 >60%

34 Perylene Perylene‐d12 >60%

7

S5. Relationship of the error for calculated KAOC with fPRC

8

S6. LogKAOC for PS1–3 versus the sampler–sediment uptake capacity ratio

Error bars represent one standard deviation. PS1 logKAOC (y‐axis) deviating downwards would indicate non‐

equilibrium. High uptake capacity ratios are associated with low fAOC. Sediment–sampler uptake capacity ratio

(x‐axis) is calculated as fPRC/(1‐fPRC)

For PCB104 at D11

fPRC 1 or above

no calculation possible

PS1

PS2

PS3

4.0

4.5

5.0

5.5

6.0

0 1 2 3 4

Log KAOC (L kg‐

1)

Uptake capacity ratio

PCB001 at D1

PS1

PS2

PS3

4.5

5.0

5.5

6.0

6.5

0 0.5 1 1.5 2

Log KAOC (L kg‐

1)


PCB002 at D2

PS1 PS2

PS3

4.5

5.0

5.5

6.0

6.5

0 0.15 0.3 0.45 0.6

Log KAOC (L kg‐

1)


PCB003 at D3

PS1 PS2

PS3

4.0

4.5

5.0

5.5

6.0

0 1 2 3 4

Log KAOC (L kg‐

1)


PCB010 at D4

PS1 PS2

PS3

4.5

5.0

5.5

6.0

6.5

0 1 2 3 4

Log KAOC (L kg‐

1 )


PCB014 at D5

PS1

PS2

PS3

4.5

5.0

5.5

6.0

6.5

0 1 2 3 4

Log KAOC (L kg‐

1)


PCB021 at D6

PS1 PS2

PS3

4.5

5.0

5.5

6.0

6.5

0 1 2 3

Log KAOC (L kg‐

1)


PCB030 at D7

PS1

PS2PS3

5.0

5.5

6.0

6.5

7.0

0 50 100 150

Log KAOC (L kg‐

1)


PCB050 at D8

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 1 2 3

Log KAOC (L kg‐

1)


PCB055 at D9

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 1 2 3 4

Log KAOC (L kg‐

1)


PCB078 at D10

PS1

PS2

PS3

6.0

6.5

7.0

7.5

8.0

0 4 8 12 16

Log KAOC (L kg‐

1)


PCB145 at D1

9

S7. Similar to S6 but comparing PCB145 and PCB204 for all locations but D11

Lower KAOC for PCB204 in PS1 confirms that PRC release did not accomplish equilibrium

PS1

PS2

PS3

6.0

6.5

7.0

7.5

8.0

0 4 8 12 16

Log KAOC (L kg‐

1 )


PCB145 at D1

PS1

PS2

PS3

7.0

7.5

8.0

8.5

9.0

0 2 4 6

Log KAOC (L kg‐

1)


PCB204 at D1

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 5 10

Log KAOC (L kg‐

1)


PCB145 at D6

PS1 PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 5 10 15

Log KAOC (L kg‐

1)


PCB204 at D6

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 5 10

Log KAOC (L kg‐

1)


PCB145 at D2

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 2 4 6

Log KAOC (L kg‐

1)


PCB204 at D2

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 4 8

Log KAOC (L kg‐

1)


PCB145 at D7

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 4 8

Log KAOC (L kg‐

1)


PCB204 at D7

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 5 10

Log KAOC (L kg‐

1)


PCB145 at D3

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 2 4 6

Log KAOC (L kg‐

1)


PCB204 at D3PS1

PS2

5.5

6.0

6.5

7.0

7.5

0 4 8

Log KAOC (L kg‐

1)


PCB145 at D8

PS1

PS2

PS3

7.0

7.5

8.0

8.5

9.0

0 4 8

Log KAOC (L kg‐

1)


PCB204 at D8

PS1

PS2

5.5

6.0

6.5

7.0

7.5

0 5 10

Log KAOC (L kg‐

1)


PCB145 at D4

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 2 4 6

Log KAOC (L kg‐

1)


PCB204 at D4

PS1

PS2

PS3

5.5

6.0

6.5

7.0

7.5

0 2 4 6 8

Log KAOC (L kg‐

1)


PCB145 at D9

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 5 10

Log KAOC (L kg‐

1)


PCB204 at D9

‐PS

‐PS

‐PS

5.5

6.0

6.5

7.0

7.5

0 3 6 9 12

Log KAOC (L kg‐

1)


PCB145 at D10

‐PS

‐PS

‐PS

6.0

6.5

7.0

7.5

8.0

0 5 10

Log KAOC (L kg‐

1)


PCB204 at D10

PS1

PS2

PS3

6.5

7.0

7.5

8.0

8.5

0 5 10 15

Log KAOC (L kg‐

1)


PCB204 at D5

10

S8. Location averaged KAOC for PRC equilibrated

PRC compounds Cl substitution

n‐ortho chlorines log Kow

log KAOC

Average log KAOC

Median log KAOC

st.dev log KAOC

weighted avg log KAOC

st.dev

PCB 1 2‐ 1 4.36 5.20 5.12 0.26 5.04 0.18

PCB 2 3‐ 0 4.39 5.61 5.64 0.14 5.68 0.13

PCB 3 4‐ 0 4.41 5.71 5.70 0.13 5.70 0.12

PCB 10 2,6‐ 2 4.62 5.30 5.22 0.18 5.14 0.13

PCB 14 3,5‐ 0 5.02 5.88 5.90 0.10 5.92 0.09

PCB 21 2,3,4‐ 1 5.62 5.99 5.98 0.08 5.99 0.06

PCB 30 2,4,6‐ 2 5.25 5.71 5.70 0.12 5.74 0.10

PCB 50 2,2’,4,6‐ 3 5.88 6.05 6.06 0.09 6.09 0.09

PCB 55 2,3,3’,4‐ 1 6.28 6.54 6.50 0.12 6.53 0.11

PCB 78 3,3’,4,5‐ 0 6.28 6.77 6.73 0.14 6.72 0.12

PCB 104 2,2’,4,6,6’‐ 4 6.15 6.42 6.43 0.08 6.43 0.08

PCB 145 2,2’,3,4,6,6’‐ 4 6.75 6.84 6.80 0.11 6.92 0.11

PCB 204 2,2’,3,4,4’,5,6,6’‐ 4 7.99 7.84 7.80 0.27 7.87 0.21

S9. PRC (weighted) average KAOC versus KOW.

PCB without ortho‐substituted chlorine (triangles) were not included in the regression.

4

5

6

7

8

4 5 6 7 8

log KAOC

log KOW

logKOC = 0.80(±0.02) logKOW + 1.52 (±0.10)

R2 = 0 .997, rmse = 0.05

11

S10. CW corresponding to LOQ of sampler analysis

The table lists the LOQ of the contaminant amount in the sampler and the corresponding CW calculated as NP/mPKPW for a medium‐weight sampler (PS2‐PS3) of 3 g for all target compounds. The measured range of NP over all sites and all sampler sizes is reflected by the 10 and 90% percentiles and mostly was well above LOQ. The last column shows the percentage of equilibrations for which a results was obtained.

LOQ Percentiles in ng %

No Compound logKPW NP in ng CW ng L‐1 10% 90% result

1 PCB 28 5.53 0.04 0.00004 …. 0.91 20 100 2 PCB 52 5.80 0.02 0.00001 1.1 26 100 3 PCB 101 6.28 0.06 0.00001 0.47 20 100 4 PCB 118 6.42 0.04 0.000005 0.13 4.9 98 5 PCB 138 6.77 0.06 0.000003 2.1 72 100 6 PCB 153 6.72 0.04 0.000003 2.5 86 100 7 PCB 180 6.99 0.06 0.000002 1.8 59 100 8 Pentachlorobenzene 4.61 0.02 0.0002 0.38 8.4 96 9 Hexachlorobenzene 5.05 0.04 0.0001 0.79 30 100 10 2,4‐DDE 6.15 0.02 0.000005 0.7 5.3 85 11 2,4‐DDD 5.51 0.06 0.00006 1.3 41 100 12 4,4’‐DDE 6.27 0.04 0.000007 4.3 218 100 13 4,4’‐DDD 5.38 0.06 0.00008 1.7 96 100 14 Naphthalene 3.03 2.7 0.9 13 97 85 15 Biphenyl 3.63 0.4 0.03 5.2 34 92 16 Acenaphthylene 3.26 1.4 0.3 2.6 23 100 17 Acenaphthene 3.62 1.4 0.1 2.1 74 94 18 Fluorene 3.79 0.9 0.05 7.6 210 100 19 Phenanthrene 4.11 3.2 0.08 53 581 100 20 Anthracene 4.21 1.5 0.03 7.1 136 100 21 Fluoranthene 4.62 2.9 0.02 66 1070 100 22 Pyrene 4.68 2.3 0.02 50 795 100 23 Benzo[b]fluorene 4.90 0.2 0.0008 5.7 129 100 24 Benzo[ghi]fluoranthene 5.11 0.2 0.0005 6.7 72 100 25 Benz[a]anthracene 5.32 1.2 0.002 25 448 100 26 Chrysene 5.25 1.8 0.003 17 220 100 27 Triphenylene 5.15 0.9 0.002 15 107 100 28 Retene 5.27 3.1 0.006 11 160 100 29 Benzo[b]fluoranthene 5.74 0.2 0.0001 18 215 100 30 Benzo[k]fluoranthene 5.74 0.5 0.0003 6.2 82 100 31 Benzo[a]pyrene 5.69 1.0 0.0007 3.9 105 100 32 Benzo[e]pyrene 5.63 0.6 0.0005 17 181 100 33 Benzo[j]fluoranthene 5.64 0.4 0.0003 11 115 100 34 Perylene 5.64 2.0 0.002 8.5 96 100 35 Benzo[ghi]perylene 6.02 0.4 0.0001 8.8 98 100 36 Dibenz[a,h]anthracene 6.24 0.3 0.00006 2.5 31 98 37 Indeno[1,2,3‐cd]pyrene 6.06 0.5 0.0001 8.8 95 98 38 Coronene 6.63 1.0 0.00008 4.9 44 92 39 Benzo‐Naphtho‐Thiophene 5.27 0.2 0.0004 4.3 65 100 40 Galaxolide (HHCB) 5.32 2.2 0.003 11 87 100 41 Tonalide (AHTN) 5.29 1.9 0.003 1.9 37 100 42 Cashmeran (DPMI) 4.50 2 0.02 15 39 94 43 Tris(1‐chloro‐2‐propyl) phosphate 3.59 3 0.3 54 135 75 44 Tris(1,3‐dichloro‐2‐propyl) phosphate 3.85 7 0.3 12 78 71 45 Triisobutylphosphate 4.99 7 0.02 8.8 45 75 46 Tri‐n‐butylphosphate 4.99 8 0.03 5.6 22 75 47 Triphenyl phosphate 5.00 2 0.007 2.6 6.3 54 48 Tris(2‐ethylhexyl) phosphate 6.36 23 0.003 7.7 56 77 49 Atrazine 2.3 0.1 0.2 0.18 1.7 52 50 Chlortoluron 2.02 0.5 2 0.58 3.6 27 51 Isoproturon 2.25 0.1 0.2 0.22 3.1 54 52 Terbuthylazine 3.01 0.1 0.03 0.36 5.3 58 53 Diazinon 4.24 0.3 0.006 0.49 3.1 38 54 Carbendazim 1.76 0.05 0.3 0.13 1.1 58 55 Metolachlor 3.24 0.3 0.06 0.38 2.3 48 56 Chlorpyrifos 4.9 0.5 0.002 2.3 17 52 57 Propiconazole 4.10 0.1 0.003 1.3 21 58 58 Tebuconazole 3.23 0.5 0.1 0.96 12 56

12

S11. Results of non‐linear least squares regressions (NLS)

a CW:0 freely dissolved concentration determined by MR–EPS (NLS);

b sCW:0 standard deviation of CW:0 ;

c CW:MAX highest measured freely dissolved concentration for PS1‐2 calculated as Cp/KPW, mostly that of PS1;

d EF – the factor CW:0 is higher than CW:MAX, i.e. the extrapolation factor;

e CAS:0 – accessible concentration determined by MR–EPS (NLS) ;

f sCW:0 standard deviation of CAS:0 ;

g CTot total concentration in sediment determined after soxhlet extraction;

h FAS – Accessible fraction, i.e. CAS:0/CTot;

I Meth “NLS” and “max” means that CW:0 or CW:MAX was applied for KAOC calculation, respectively;

J logKAOC Amorphous organic carbon–water partition coefficient calculated as CAS:0/CW:0 or CAS:0/CW:MAX and

divided by amorphous organic carbon fraction;

k slogKAOC standard deviation of logKAOC ;

l QF qualifier for KAOC data; QF was set “Ok” if n=4, EF<2 and fAOC≥0.001

Contaminant Loc. n CW:0a sCW:0

b CW:MAXc EFd CAS:0

e sCAS:0f CTotg FASh Methi logKAOC

j slogKAOCk QFl

ng L–1 ng L–1 ng L–1 µg kg–1 µg kg–1 µg kg–1 L kg–1 L kg–1

1 PCB 28 D1 3 0.04 ± 0.003 0.031 1.3 0.076 ± 0.0052 0.043 1.8 NLS 6.50 0.10 ‐

–~ – D2 4 0.029 ± 0.0014 0.024 1.2 0.094 ± 0.0052 0.12 0.76 NLS 6.28 0.06 Ok

–~ – D3 4 0.028 ± 0.0012 0.023 1.2 0.11 ± 0.0055 0.2 0.57 NLS 6.18 0.05 Ok

–~ – D4 4 0.015 ± 0.0013 0.013 1.2 0.041 ± 0.0034 0.055 0.74 NLS 6.28 0.07 Ok

–~ – D5 4 0.024 ± 0.00067 0.014 1.6 0.022 ± 0.00041 0.022 1.0 NLS 6.01 0.07 ‐

–~ – D6 4 0.027 ± 0.0053 0.022 1.2 0.067 ± 0.012 0.12 0.56 NLS 6.16 0.12 Ok

–~ – D7 4 0.074 ± 0.0019 0.065 1.1 0.42 ± 0.015 0.63 0.67 NLS 6.32 0.04 Ok

–~ – D8 4 0.028 ± 0.0018 0.019 1.5 0.032 ± 0.0015 0.028 1.1 NLS 6.28 0.10 ‐

–~ – D9 4 0.011 ± 0.0011 0.011 0.99 0.08 ± 0.012 0.18 0.45 max 6.48 0.09 Ok

–~ – D10 4 0.032 ± 0.0015 0.025 1.3 0.091 ± 0.0043 0.13 0.69 NLS 6.16 0.05 Ok

–~ – D11 4 0.017 ± 0.0078 0.0057 3 0.0026 ± 0.00045 0.0027 0.95 NLS 5.88 0.32 ‐

2 PCB 52 D1 4 0.041 ± 0.00095 0.024 1.7 0.068 ± 0.001 0.026 2.7 NLS 6.44 0.09 ‐

–~ – D2 4 0.038 ± 0.00029 0.029 1.3 0.13 ± 0.00079 0.08 1.6 NLS 6.30 0.05 Ok

–~ – D3 4 0.035 ± 0.0015 0.027 1.3 0.16 ± 0.0058 0.12 1.3 NLS 6.25 0.05 Ok

–~ – D4 4 0.024 ± 0.00065 0.017 1.4 0.07 ± 0.0015 0.046 1.5 NLS 6.33 0.05 Ok

–~ – D5 3 0.017 ± 0.0029 0.0048 3.6 0.037 ± 0.002 0.017 2.3 NLS 6.38 0.10 ‐

–~ – D6 4 0.039 ± 0.0055 0.027 1.4 0.11 ± 0.011 0.083 1.3 NLS 6.22 0.09 Ok

–~ – D7 4 0.083 ± 0.0025 0.066 1.3 0.43 ± 0.013 0.31 1.4 NLS 6.28 0.04 Ok

–~ – D8 4 0.032 ± 0.00051 0.017 1.8 0.042 ± 0.00037 0.02 2.1 NLS 6.34 0.09 ‐

–~ – D9 4 0.036 ± 0.0022 0.029 1.3 0.16 ± 0.0085 0.15 1 NLS 6.26 0.05 Ok

–~ – D10 4 0.047 ± 0.00097 0.032 1.4 0.15 ± 0.0023 0.095 1.5 NLS 6.20 0.04 Ok

–~ – D11 4 0.0082 ± 0.0013 0.0026 3.1 0.0022 ± 0.00013 0.0019 1.2 NLS 6.13 0.25 ‐

13


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


3 PCB 101 D1 4 0.0076 ± 0.00037 0.0045 1.7 0.038 ± 0.0012 0.045 0.85 NLS 6.92 0.10 ‐

–~ – D2 4 0.0092 ± 0.00027 0.0067 1.4 0.083 ± 0.0019 0.14 0.59 NLS 6.72 0.05 Ok

–~ – D3 4 0.012 ± 0.00042 0.0094 1.3 0.14 ± 0.004 0.29 0.5 NLS 6.64 0.04 Ok

–~ – D4 4 0.008 ± 0.00031 0.0058 1.4 0.069 ± 0.0021 0.1 0.69 NLS 6.79 0.06 Ok

–~ – D5 4 0.011 ± 0.004 0.0037 3 0.019 ± 0.0024 0.024 0.79 NLS 6.28 0.18 ‐

–~ – D6 4 0.0083 ± 0.00008 0.0059 1.4 0.081 ± 0.00061 0.15 0.54 NLS 6.76 0.05 Ok

–~ – D7 4 0.0073 ± 0.000059 0.0058 1.2 0.11 ± 0.00092 0.22 0.51 NLS 6.75 0.04 Ok

–~ – D8 4 0.0076 ± 0.0005 0.0042 1.8 0.031 ± 0.0012 0.038 0.83 NLS 6.83 0.10 ‐

–~ – D9 4 0.015 ± 0.0019 0.011 1.3 0.15 ± 0.015 0.32 0.46 NLS 6.62 0.08 Ok

–~ – D10 4 0.013 ± 0.00036 0.0088 1.5 0.11 ± 0.0023 0.17 0.66 NLS 6.62 0.05 Ok

–~ – D11 4 0.00044 ± 0.00011 0.00026 1.7 0.001 ± 0.00017 0.0015 0.66 NLS 7.05 0.27 ‐

4 PCB 118 D1 3 0.001 ± 0.00011 0.00072 1.4 0.011 ± 0.00095 0.032 0.36 NLS 7.25 0.11 ‐

–~ – D2 4 0.0014 ± 0.000016 0.0011 1.3 0.024 ± 0.00025 0.11 0.23 NLS 7.01 0.05 Ok

–~ – D3 4 0.0018 ± 0.000068 0.0015 1.2 0.041 ± 0.0015 0.19 0.21 NLS 6.94 0.04 Ok

–~ – D4 4 0.0012 ± 0.000042 0.00092 1.3 0.021 ± 0.00071 0.072 0.29 NLS 7.11 0.06 Ok

–~ – D5 4 0.002 ± 0.00065 0.0007 2.9 0.005 ± 0.00059 0.016 0.3 NLS 6.44 0.17 ‐

–~ – D6 4 0.0012 ± 0.00003 0.00093 1.3 0.022 ± 0.00047 0.1 0.22 NLS 7.03 0.05 Ok

–~ – D7 4 0.001 ± 0.000021 0.00091 1.1 0.039 ± 0.001 0.18 0.21 NLS 7.14 0.04 Ok

–~ – D8 4 0.0009 ± 0.000049 0.00059 1.5 0.008 ± 0.0003 0.024 0.33 NLS 7.17 0.10 ‐

–~ – D9 4 0.0017 ± 0.00011 0.0014 1.2 0.042 ± 0.0028 0.23 0.19 NLS 7.02 0.06 Ok

–~ – D10 4 0.0024 ± 0.000076 0.0018 1.3 0.041 ± 0.0011 0.15 0.27 NLS 6.93 0.05 Ok

–~ – D11 4 0.000099 ± 0.0000097 0.000056 1.8 0.00031 ± 0.000021 0.0014 0.21 NLS 7.19 0.24 ‐

5 PCB 138 D1 4 0.0076 ± 0.00027 0.0048 1.6 0.14 ± 0.0034 0.11 1.3 NLS 7.49 0.10 ‐

–~ – D2 4 0.0098 ± 0.00048 0.0073 1.3 0.31 ± 0.013 0.36 0.85 NLS 7.27 0.05 Ok

–~ – D3 4 0.014 ± 0.00036 0.011 1.3 0.61 ± 0.015 0.81 0.76 NLS 7.23 0.04 Ok

–~ – D4 4 0.014 ± 0.00037 0.01 1.3 0.41 ± 0.009 0.37 1.1 NLS 7.33 0.05 Ok

–~ – D5 4 0.0066 ± 0.0013 0.0037 1.8 0.085 ± 0.0096 0.06 1.4 NLS 7.15 0.12 ‐

–~ – D6 4 0.011 ± 0.00032 0.0084 1.4 0.37 ± 0.0086 0.42 0.89 NLS 7.28 0.05 Ok

–~ – D7 4 0.0045 ± 0.0001 0.0038 1.2 0.25 ± 0.0061 0.34 0.75 NLS 7.31 0.04 Ok

–~ – D8 4 0.0098 ± 0.00028 0.0061 1.6 0.16 ± 0.003 0.13 1.3 NLS 7.43 0.10 ‐

–~ – D9 4 0.013 ± 0.00085 0.01 1.2 0.56 ± 0.036 0.71 0.79 NLS 7.27 0.06 Ok

–~ – D10 4 0.01 ± 0.00027 0.0072 1.4 0.32 ± 0.007 0.32 1 NLS 7.20 0.05 Ok

–~ – D11 4 0.0002 ± 0.000027 0.00013 1.5 0.0022 ± 0.00024 0.0037 0.6 NLS 7.74 0.25 ‐

6 PCB 153 D1 4 0.012 ± 0.00053 0.0069 1.7 0.16 ± 0.0048 0.16 1 NLS 7.36 0.10 ‐

–~ – D2 4 0.015 ± 0.0004 0.011 1.4 0.39 ± 0.0086 0.5 0.78 NLS 7.19 0.05 Ok

–~ – D3 4 0.021 ± 0.00048 0.017 1.3 0.8 ± 0.016 1 0.77 NLS 7.16 0.04 Ok

–~ – D4 4 0.018 ± 0.00064 0.013 1.4 0.46 ± 0.013 0.46 1 NLS 7.25 0.06 Ok

–~ – D5 4 0.0098 ± 0.002 0.0052 1.9 0.1 ± 0.012 0.091 1.1 NLS 7.06 0.12 ‐

–~ – D6 4 0.015 ± 0.0034 0.011 1.4 0.54 ± 0.11 0.56 0.96 NLS 7.32 0.14 Ok

–~ – D7 4 0.0078 ± 0.00018 0.0064 1.2 0.36 ± 0.0087 0.48 0.76 NLS 7.23 0.04 Ok

–~ – D8 4 0.014 ± 0.00034 0.0083 1.7 0.19 ± 0.0029 0.15 1.2 NLS 7.36 0.09 ‐

–~ – D9 4 0.018 ± 0.0014 0.015 1.2 0.66 ± 0.045 0.84 0.79 NLS 7.19 0.06 Ok

–~ – D10 4 0.014 ± 0.00035 0.0098 1.4 0.37 ± 0.0073 0.37 1 NLS 7.12 0.05 Ok

–~ – D11 4 0.00028 ± 0.00002 0.00018 1.6 0.0024 ± 0.00013 0.0087 0.28 NLS 7.63 0.24 ‐

14


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


7 PCB 180 D1 4 0.0033 ± 0.00012 0.0022 1.5 0.12 ± 0.0032 0.11 1.1 NLS 7.78 0.10 ‐

–~ – D2 4 0.0036 ± 0.00017 0.0029 1.2 0.28 ± 0.013 0.33 0.84 NLS 7.66 0.06 Ok

–~ – D3 4 0.0047 ± 0.00018 0.0041 1.2 0.61 ± 0.027 0.88 0.69 NLS 7.70 0.05 Ok

–~ – D4 4 0.0059 ± 0.00024 0.0048 1.2 0.43 ± 0.017 0.41 1 NLS 7.72 0.06 Ok

–~ – D5 4 0.002 ± 0.00013 0.0014 1.4 0.08 ± 0.0042 0.059 1.4 NLS 7.65 0.08 ‐

–~ – D6 4 0.0048 ± 0.00079 0.0036 1.3 0.43 ± 0.073 0.46 0.94 NLS 7.72 0.11 Ok

–~ – D7 4 0.0022 ± 0.000093 0.002 1.1 0.3 ± 0.016 0.4 0.77 NLS 7.70 0.05 Ok

–~ – D8 4 0.0041 ± 0.000092 0.0029 1.4 0.18 ± 0.003 0.14 1.2 NLS 7.87 0.09 ‐

–~ – D9 4 0.0044 ± 0.00036 0.0041 1.1 0.71 ± 0.077 0.83 0.85 NLS 7.82 0.07 Ok

–~ – D10 4 0.003 ± 0.00014 0.0024 1.2 0.28 ± 0.014 0.29 0.96 NLS 7.67 0.05 Ok

–~ – D11 4 0.000021 ± 0.0000066 0.00002 1 0.001 ± 0.00032 0.0027 0.37 NLS 8.38 0.31 ‐

8 Pentachlorobenzene D1 3 0.53 ± 0.49 0.18 2.9 0.02 ± 0.0066 0.034 0.58 NLS 4.80 0.44 ‐

–~ – D2 4 0.048 ± 0.023 0.025 1.9 nr nr 0.11 na ns na na ‐

–~ – D3 4 0.21 ± 0.058 0.14 1.5 0.11 ± 0.036 0.18 0.58 NLS 5.31 0.20 Ok

–~ – D4 3 0.11 ± 0.012 0.095 1.2 0.049 ± 0.0079 0.078 0.63 NLS 5.48 0.10 ‐

–~ – D5 3 0.23 ± 0.029 0.097 2.4 0.012 ± 0.00089 0.028 0.43 NLS 4.76 0.09 ‐

–~ – D6 3 na na 0.074 na na na 0.13 na na na na ‐

–~ – D7 4 0.04 ± 0.0063 0.032 1.2 0.012 ± 0.0019 0.062 0.2 NLS 5.04 0.10 Ok


–~ – D9 4 0.063 ± 0.0047 0.062 1 0.053 ± 0.0061 0.097 0.55 NLS 5.54 0.07 Ok

–~ – D10 4 0.046 ± 0.015 0.033 1.4 0.016 ± 0.0055 0.024 0.68 NLS 5.24 0.21 Ok

–~ – D11 4 0.0049 ± 0.0034 0.0061 0.8 nr nr 0.0015 na ns na na ‐

9 Hexachlorobenzene D1 3 0.097 ± 0.029 0.091 1.1 0.12 ± 0.045 0.053 2.3 NLS 6.32 0.23 ‐

–~ – D2 4 0.073 ± 0.022 0.051 1.4 0.23 ± 0.15 0.24 0.94 NLS 6.27 0.31 Ok

–~ – D3 3 0.23 ± 0.022 0.2 1.1 0.42 ± 0.044 0.62 0.67 NLS 5.86 0.07 ‐

–~ – D4 4 0.19 ± 0.012 0.17 1.2 0.3 ± 0.025 0.27 1.1 NLS 6.05 0.07 Ok

–~ – D5 3 0.13 ± 0.0055 0.11 1.2 0.13 ± 0.0058 0.076 1.7 NLS 6.05 0.08 ‐

–~ – D6 4 0.096 ± 0.037 0.098 0.98 0.13 ± 0.063 0.32 0.41 max 5.89 0.27 Ok

–~ – D7 4 0.05 ± 0.0027 0.042 1.2 0.071 ± 0.0048 0.16 0.45 NLS 5.73 0.05 Ok

–~ – D8 4 0.12 ± 0.021 0.087 1.4 0.074 ± 0.011 0.057 1.3 NLS 6.01 0.13 ‐

–~ – D9 4 0.078 ± 0.006 0.071 1.1 0.17 ± 0.019 0.33 0.51 NLS 5.96 0.07 Ok

–~ – D10 4 0.059 ± 0.012 0.044 1.3 0.06 ± 0.013 0.089 0.68 NLS 5.70 0.13 Ok

–~ – D11 3 0.0052 ± 0.000039 0.0047 1.1 0.0047 ± 0.000039 0.0029 1.6 NLS 6.65 0.24 ‐

10 2,4‐DDE D1 3 0.003 ± 0.00061 0.0016 1.9 0.0084 ± 0.00096 0.0091 0.93 NLS 6.67 0.14 ‐

–~ – D2 4 0.0059 ± 0.0002 0.0039 1.5 0.028 ± 0.00065 0.081 NLS 6.45 0.05 Ok

–~ – D3 4 0.0039 ± 0.00012 0.0029 1.4 0.03 ± 0.00074 0.042 0.71 NLS 6.47 0.04 Ok

–~ – D4 4 0.0016 ± 0.000047 0.0011 1.4 0.0093 ± 0.0002 0.013 0.7 NLS 6.62 0.06 Ok

–~ – D5 4 0.0095 ± 0.00029 0.0044 2.1 0.021 ± 0.00033 0.018 1.1 NLS 6.39 0.07 ‐

–~ – D6 3 0.0052 ± 0.00037 0.0033 1.6 0.026 ± 0.0012 0.042 0.62 NLS 6.47 0.06 ‐

–~ – D7 4 0.0062 ± 0.000049 0.0047 1.3 0.056 ± 0.00041 0.094 0.6 NLS 6.52 0.04 Ok

–~ – D8 3 0.0033 ± 0.000012 0.0017 2 0.0083 ± 0.000016 0.0073 1.1 NLS 6.62 0.09 ‐

–~ – D9 4 0.0036 ± 0.00026 0.0028 1.3 0.03 ± 0.0018 0.0092 NLS 6.54 0.06 Ok

–~ – D10 4 0.0051 ± 0.00041 0.0026 1.9 0.016 ± 0.0007 0.051 0.32 NLS 6.20 0.06 Ok

–~ – D11 0 na na na na na na na na na na na ‐

15


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


11 2,4‐DDD D1 4 0.063 ± 0.0081 0.05 1.3 0.19 ± 0.027 0.11 1.7 NLS 6.70 0.13 ‐

–~ – D2 4 0.15 ± 0.0015 0.12 1.2 0.39 ± 0.0041 0.69 0.56 NLS 6.19 0.05 Ok

–~ – D3 4 0.037 ± 0.0047 0.029 1.3 0.2 ± 0.036 0.29 0.71 NLS 6.32 0.10 Ok

–~ – D4 4 0.035 ± 0.017 0.023 1.5 0.12 ± 0.068 0.086 1.4 NLS 6.38 0.33 Ok

–~ – D5 4 0.055 ± 0.0042 0.042 1.3 0.11 ± 0.0076 0.096 1.2 NLS 6.35 0.08 ‐

–~ – D6 4 0.13 ± 0.019 0.12 1.2 1 ± 0.26 0.63 1.6 NLS 6.65 0.14 Ok

–~ – D7 4 0.079 ± 0.016 0.059 1.4 0.61 ± 0.2 0.72 0.84 NLS 6.45 0.18 Ok

–~ – D8 4 0.032 ± 0.0036 0.026 1.3 0.089 ± 0.01 0.077 1.2 NLS 6.67 0.12 ‐

–~ – D9 4 0.073 ± 0.01 0.055 1.3 0.5 ± 0.11 0.75 0.66 NLS 6.46 0.12 Ok

–~ – D10 4 0.06 ± 0.0067 0.05 1.2 0.25 ± 0.035 0.25 0.99 NLS 6.32 0.09 Ok

–~ – D11 4 nr nr 0.0041 na 0.0013 ns 0.002 0.64 na na na ‐

12 4,4‐DDE D1 4 0.069 ± 0.0035 0.038 1.8 0.29 ± 0.0091 0.3 0.99 NLS 6.85 0.10 ‐

–~ – D2 4 0.11 ± 0.003 0.075 1.4 0.85 ± 0.019 1.4 0.59 NLS 6.68 0.05 Ok

–~ – D3 4 0.11 ± 0.0055 0.08 1.3 1.2 ± 0.051 1.6 0.72 NLS 6.64 0.05 Ok

–~ – D4 4 0.068 ± 0.0022 0.047 1.4 0.51 ± 0.012 0.65 0.78 NLS 6.73 0.06 Ok

–~ – D5 4 0.62 ± 0.017 0.3 2.1 2 ± 0.028 1.7 1.1 NLS 6.56 0.07 ‐

–~ – D6 4 0.084 ± 0.0046 0.059 1.4 0.75 ± 0.032 1.1 0.67 NLS 6.72 0.06 Ok

–~ – D7 4 0.12 ± 0.0018 0.094 1.2 1.7 ± 0.025 3 0.58 NLS 6.73 0.04 Ok

–~ – D8 4 0.065 ± 0.0016 0.036 1.8 0.25 ± 0.0036 0.25 1 NLS 6.81 0.09 ‐

–~ – D9 4 0.044 ± 0.004 0.036 1.2 0.59 ± 0.049 1.5 0.4 NLS 6.75 0.07 Ok

–~ – D10 4 0.059 ± 0.0025 0.041 1.4 0.52 ± 0.017 0.65 0.8 NLS 6.64 0.05 Ok

–~ – D11 3 0.0038 ± 0.0031 0.0012 3 0.0032 ± 0.001 0.01 0.32 NLS 6.63 0.46 ‐

13 4,4‐DDD D1 4 0.22 ± 0.14 0.14 1.5 0.86 ± 0.86 0.41 2.1 NLS 6.82 0.52 ‐

–~ – D2 4 0.49 ± 0.095 0.36 1.3 2.2 ± 0.7 1.8 1.2 NLS 6.42 0.17 Ok

–~ – D3 4 0.21 ± 0.04 0.16 1.3 0.8 ± 0.2 1 0.77 NLS 6.16 0.14 Ok

–~ – D4 4 0.19 ± 0.054 0.14 1.4 0.47 ± 0.15 0.33 1.4 NLS 6.24 0.19 Ok

–~ – D5 4 0.2 ± 0.024 0.16 1.2 0.53 ± 0.076 0.29 1.8 NLS 6.47 0.11 ‐

–~ – D6 4 0.44 ± 0.12 0.3 1.5 3.9 ± 2.5 1.7 2.4 NLS 6.72 0.30 Ok

–~ – D7 4 0.19 ± 0.047 0.14 1.4 1.6 ± 0.8 2.1 0.78 NLS 6.50 0.24 Ok

–~ – D8 4 0.099 ± 0.035 0.068 1.5 0.32 ± 0.15 0.24 1.4 NLS 6.73 0.27 ‐

–~ – D9 4 0.11 ± 0.026 0.079 1.4 0.72 ± 0.29 1.3 0.55 NLS 6.43 0.21 Ok

–~ – D10 4 0.062 ± 0.022 0.044 1.4 0.45 ± 0.35 0.45 1 NLS 6.56 0.38 Ok

–~ – D11 4 0.011 ± 0.0031 0.0066 1.6 0.004 ± 0.00088 0.0052 0.76 NLS 6.28 0.29 ‐

14 Naphthalene D1 3 nr nr 134 na nr ns 3.1 na na na na ‐

–~ – D2 2 na na 28 na na na 6.3 na na na na ‐

–~ – D3 4 19 ± 2.1 16 1.2 1.1 ± 0.25 10 0.11 NLS 4.35 0.12 Ok

–~ – D4 4 59 ± 7 52 1.1 1.3 ± 0.27 3.9 0.34 NLS 4.20 0.12 Ok

–~ – D5 4 35 ± 15 24 1.4 0.53 ± 0.3 2.6 0.2 NLS 4.22 0.31 ‐

–~ – D6 0 na na na na na na 7.4 na na na na ‐

–~ – D7 4 8.9 ± 0.87 8.8 1 2.2 ± 0.52 4.4 0.5 NLS 4.96 0.12 Ok

–~ – D8 4 48 ± 7.3 44 1.1 0.82 ± 0.18 3 0.27 NLS 4.45 0.15 ‐

–~ – D9 4 16 ± 2.1 15 1.1 1.9 ± 0.56 12 0.16 NLS 4.69 0.15 Ok

–~ – D10 4 9.7 ± 1.7 8.2 1.2 0.96 ± 0.45 5 0.19 NLS 4.70 0.22 Ok

–~ – D11 4 16 ± 5.4 13 1.2 0.55 ± 0.38 0.17 3.1 NLS 5.25 0.42 ‐

16


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


15 Biphenyl D1 3 11 ± 4.8 9.4 1.2 0.29 ± 0.12 1.3 0.23 NLS 4.63 0.27 ‐


–~ – D3 4 1.8 ± 0.15 1.7 1.1 0.69 ± 0.12 3.5 0.2 NLS 5.16 0.09 Ok

–~ – D4 4 4.3 ± 0.14 4.3 0.99 0.63 ± 0.046 1.6 0.4 max 5.02 0.06 Ok

–~ – D5 4 5 ± 1.5 3.8 1.3 0.26 ± 0.097 7.4 0.035 NLS 4.77 0.22 ‐


–~ – D7 4 1.1 ± 0.1 1.2 0.96 0.91 ± 0.2 2.1 0.43 max 5.45 0.11 Ok

–~ – D8 4 5.3 ± 1.5 4.8 1.1 0.29 ± 0.11 1 0.29 NLS 4.96 0.22 ‐

–~ – D9 4 1.2 ± 0.053 1.1 1.1 0.78 ± 0.081 3.7 0.21 NLS 5.43 0.06 Ok

–~ – D10 4 1 ± 0.11 1 1 0.8 ± 0.22 1.5 0.54 NLS 5.59 0.14 Ok

–~ – D11 4 9.2 ± 2 7.4 1.2 0.13 ± 0.025 0.24 0.53 NLS 4.85 0.27 ‐

16 Acenaphthylene D1 4 13 ± 2.5 11 1.1 0.2 ± 0.041 1.2 0.17 NLS 4.41 0.15 ‐

–~ – D2 4 3.4 ± 0.22 2.9 1.2 0.28 ± 0.046 2.2 0.13 NLS 4.68 0.09 Ok

–~ – D3 4 5 ± 0.92 3.8 1.3 0.38 ± 0.14 11 0.035 NLS 4.47 0.19 Ok

–~ – D4 4 5 ± 0.51 4.9 1 0.32 ± 0.075 2 0.16 NLS 4.66 0.12 Ok

–~ – D5 4 3.5 ± 0.17 2.9 1.2 0.081 ± 0.0052 1.9 0.043 NLS 4.42 0.08 ‐

–~ – D6 4 3.4 ± 1.1 4.9 0.7 0.3 ± 0.24 2.3 0.13 max 4.56 0.38 Ok

–~ – D7 4 2.6 ± 0.17 2.6 0.99 0.27 ± 0.041 2.8 0.098 max 4.58 0.08 Ok

–~ – D8 4 13 ± 1.9 12 1.1 0.31 ± 0.06 2.4 0.13 NLS 4.60 0.14 ‐

–~ – D9 4 4.6 ± 0.49 4.3 1.1 1.6 ± 0.43 16 0.1 NLS 5.16 0.13 Ok

–~ – D10 4 1.7 ± 0.086 1.7 0.99 0.16 ± 0.021 1.4 0.11 max 4.68 0.08 Ok

–~ – D11 4 0.85 ± 0.24 1.2 0.71 0.047 ± 0.027 0.27 0.17 max 5.30 0.37 ‐

17 Acenaphthene D1 3 33 ± 26 19 1.7 0.31 ± 0.15 1.7 0.19 NLS 4.20 0.41 ‐

–~ – D2 3 2.5 ± 1.2 1.6 1.5 nr nr 1.6 na ns na na ‐

–~ – D3 4 8.3 ± 4.4 5.2 1.6 0.48 ± 0.32 10 0.047 NLS 4.35 0.37 Ok

–~ – D4 4 3.4 ± 0.94 3.4 1 0.22 ± 0.087 1 0.22 NLS 4.66 0.22 Ok

–~ – D5 4 8.5 ± 0.8 6.9 1.2 0.26 ± 0.023 8.6 0.03 NLS 4.53 0.09 ‐

–~ – D6 3 nr nr 3.7 na 0.026 ns 1.7 0.016 na ‐2.58 785366.92 ‐

–~ – D7 4 1.3 ± 0.17 1.2 1.1 0.2 ± 0.053 1.3 0.15 NLS 4.77 0.14 Ok

–~ – D8 4 9.7 ± 0.71 7.2 1.3 0.2 ± 0.012 0.96 0.21 NLS 4.54 0.10 ‐

–~ – D9 4 1.3 ± 0.034 1.4 0.9 1.5 ± 0.12 4.7 0.32 max 5.64 0.05 Ok

–~ – D10 4 0.85 ± 0.32 0.57 1.5 0.091 ± 0.068 0.94 0.097 NLS 4.73 0.37 Ok

–~ – D11 4 na na 0.77 na na na na na na na na ‐

18 Fluorene D1 4 32 ± 16 32 1 1.9 ± 1.1 3.9 0.49 NLS 5.00 0.34 ‐

–~ – D2 4 4.7 ± 2.2 2.6 1.8 0.84 ± 0.83 2.6 0.32 NLS 5.03 0.48 Ok

–~ – D3 4 16 ± 4.6 11 1.5 2 ± 0.9 15 0.13 NLS 4.68 0.23 Ok

–~ – D4 4 11 ± 2.2 7.8 1.4 0.27 ± 0.042 1.3 0.22 NLS 4.25 0.12 Ok

–~ – D5 4 21 ± 16 13 1.6 1.3 ± 1.2 123 0.011 NLS 4.84 0.52 ‐

–~ – D6 4 40 ± 28 8.8 4.5 0.14 ± 0.021 2 0.071 NLS 3.31 0.31 ‐

–~ – D7 4 17 ± 5.1 11 1.5 0.5 ± 0.12 2.4 0.21 NLS 4.03 0.17 Ok

–~ – D8 4 35 ± 29 21 1.6 1.5 ± 1.1 2.2 0.67 NLS 4.86 0.49 ‐

–~ – D9 4 4.1 ± 0.7 4.3 0.97 2.6 ± 1 15 0.17 max 5.41 0.19 Ok

–~ – D10 4 2 ± 0.84 1.6 1.3 0.25 ± 0.17 1.7 0.15 NLS 4.79 0.35 Ok

–~ – D11 4 4.4 ± 3 6.2 0.71 0.31 ± 0.3 0.054 5.7 max 5.40 0.57 ‐

17


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


19 Phenanthrene D1 4 24 ± 10 25 0.95 7.8 ± 6.7 20 0.38 max 5.72 0.43 ‐

–~ – D2 4 6.8 ± 1 5 1.4 4.9 ± 2 20 0.24 NLS 5.62 0.19 Ok

–~ – D3 4 16 ± 3.9 11 1.4 7 ± 3.2 140 0.05 NLS 5.22 0.22 Ok

–~ – D4 4 9.7 ± 2.5 9.2 1 4.4 ± 2.6 13 0.35 NLS 5.51 0.28 Ok

–~ – D5 3 9.7 ± 0.096 7.9 1.2 0.99 ± 0.011 25 0.039 NLS 5.06 0.07 ‐

–~ – D6 4 6.9 ± 0.63 8.1 0.86 4.4 ± 0.99 20 0.22 max 5.51 0.12 Ok

–~ – D7 4 12 ± 4.1 9.7 1.3 1.2 ± 0.4 19 0.066 NLS 4.56 0.21 Ok

–~ – D8 4 51 ± 27 34 1.5 6.5 ± 3.7 19 0.34 NLS 5.32 0.35 ‐

–~ – D9 4 6.1 ± 0.16 5.7 1.1 36 ± 3.5 131 0.28 NLS 6.39 0.06 Ok

–~ – D10 4 9.3 ± 9 5.9 1.6 0.97 ± 0.93 8.5 0.11 NLS 4.72 0.59 Ok

–~ – D11 4 5.6 ± 3.6 8.7 0.64 nr nr 1 na ns na na ‐

20 Anthracene D1 4 3.3 ± 0.72 2.8 1.2 1.2 ± 0.47 3.9 0.31 NLS 5.78 0.22 ‐

–~ – D2 4 1.7 ± 0.41 1.2 1.5 1 ± 0.55 5.6 0.18 NLS 5.53 0.27 Ok

–~ – D3 4 2 ± 0.37 1.5 1.3 1.4 ± 0.51 19 0.071 NLS 5.43 0.18 Ok

–~ – D4 4 1.5 ± 0.15 1.4 1.1 0.85 ± 0.2 3.4 0.25 NLS 5.61 0.12 Ok

–~ – D5 4 1.3 ± 0.39 0.9 1.4 0.29 ± 0.12 4.9 0.06 NLS 5.40 0.23 ‐

–~ – D6 3 1 ± 0.13 1.1 0.92 0.73 ± 0.18 4.2 0.18 max 5.60 0.13 ‐

–~ – D7 4 0.72 ± 0.068 0.72 1 0.54 ± 0.11 4.3 0.12 NLS 5.44 0.11 Ok

–~ – D8 4 4.7 ± 0.85 3.7 1.3 0.91 ± 0.2 3.5 0.26 NLS 5.51 0.15 ‐

–~ – D9 4 1.1 ± 0.12 1 1.1 4.8 ± 1.4 29 0.16 NLS 6.25 0.14 Ok

–~ – D10 4 0.46 ± 0.041 0.44 1 0.35 ± 0.081 2.2 0.16 NLS 5.58 0.12 Ok

–~ – D11 4 1.3 ± 0.78 0.72 1.8 0.022 ± 0.0084 0.34 0.065 NLS 4.92 0.39 ‐

21 Fluoranthene D1 4 15 ± 2.4 13 1.2 15 ± 4.6 34 0.43 NLS 6.23 0.18 ‐

–~ – D2 4 4.8 ± 0.17 4.3 1.1 26 ± 2.5 57 0.46 NLS 6.51 0.06 Ok

–~ – D3 4 5.8 ± 1.5 3.7 1.6 20 ± 12 322 0.063 NLS 6.12 0.28 Ok

–~ – D4 4 4.3 ± 0.97 3.9 1.1 12 ± 7 44 0.28 NLS 6.29 0.27 Ok

–~ – D5 4 5 ± 3 3.3 1.5 3.6 ± 3.3 16 0.22 NLS 5.90 0.49 ‐

–~ – D6 4 4.5 ± 0.56 4 1.1 15 ± 4.9 55 0.26 NLS 6.29 0.16 Ok

–~ – D7 4 2.2 ± 0.056 2.3 0.94 10 ± 0.62 43 0.23 max 6.20 0.05 Ok

–~ – D8 4 16 ± 3.4 12 1.3 11 ± 3.2 49 0.22 NLS 6.06 0.19 ‐

–~ – D9 4 2.8 ± 0.55 1.9 1.5 nr nr 277 na ns na na Ok

–~ – D10 4 0.91 ± 0.079 0.88 1 3.9 ± 0.87 16 0.24 NLS 6.33 0.11 Ok

–~ – D11 4 4.6 ± 0.97 2.9 1.6 0.29 ± 0.046 2.2 0.13 NLS 5.50 0.26 ‐

22 Pyrene D1 4 10 ± 1.9 9 1.2 10 ± 3.3 24 0.44 NLS 6.20 0.18 ‐

–~ – D2 4 3.1 ± 0.1 2.8 1.1 18 ± 1.6 43 0.41 NLS 6.53 0.06 Ok

–~ – D3 4 3.9 ± 1.1 2.4 1.6 15 ± 9.4 252 0.059 NLS 6.17 0.30 Ok

–~ – D4 4 3 ± 0.68 2.7 1.1 9.1 ± 5.3 35 0.26 NLS 6.34 0.28 Ok

–~ – D5 4 3 ± 1.4 2 1.5 2.8 ± 2.1 13 0.21 NLS 6.01 0.40 ‐

–~ – D6 4 2.9 ± 0.36 2.8 1.1 10 ± 3.2 44 0.23 NLS 6.30 0.16 Ok

–~ – D7 4 1.5 ± 0.045 1.5 0.97 7.5 ± 0.55 35 0.21 max 6.26 0.05 Ok

–~ – D8 4 11 ± 2 8.3 1.3 8.1 ± 2.2 36 0.22 NLS 6.10 0.17 ‐


–~ – D10 4 0.66 ± 0.03 0.62 1.1 2.8 ± 0.34 12 0.23 NLS 6.33 0.07 Ok

–~ – D11 4 3.5 ± 0.63 2.1 1.7 0.21 ± 0.027 1.6 0.13 NLS 5.47 0.26 ‐

18


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


23 Benzo[b]fluorene D1 4 0.98 ± 0.23 0.81 1.2 1.6 ± 0.62 3.3 0.48 NLS 6.43 0.22 ‐

–~ – D2 4 0.43 ± 0.08 0.39 1.1 2.2 ± 1.1 6.3 0.36 NLS 6.48 0.24 Ok

–~ – D3 4 0.4 ± 0.13 0.26 1.6 1.9 ± 1.4 25 0.076 NLS 6.26 0.35 Ok

–~ – D4 4 0.26 ± 0.054 0.21 1.2 1.4 ± 0.74 4.7 0.3 NLS 6.59 0.25 Ok

–~ – D5 4 0.16 ± 0.056 0.11 1.5 0.39 ± 0.27 1.4 0.27 NLS 6.42 0.35 ‐

–~ – D6 4 0.37 ± 0.092 0.38 0.96 3.3 ± 2.2 6.1 0.54 max 6.71 0.31 Ok

–~ – D7 4 0.16 ± 0.01 0.16 1 0.9 ± 0.14 5.3 0.17 NLS 6.32 0.08 Ok

–~ – D8 4 1 ± 0.25 0.73 1.4 1.2 ± 0.41 4.4 0.27 NLS 6.30 0.21 ‐


–~ – D10 4 0.05 ± 0.013 0.037 1.4 0.43 ± 0.29 2.4 0.18 NLS 6.63 0.32 Ok

–~ – D11 4 0.47 ± 0.078 0.21 2.2 0.028 ± 0.0025 0.24 0.12 NLS 5.47 0.25 ‐

24 Benzo[ghi]fluoranthene D1 4 0.31 ± 0.047 0.26 1.2 1.3 ± 0.43 2.4 0.54 NLS 6.84 0.19 ‐

–~ – D2 4 0.16 ± 0.0045 0.16 1 2.3 ± 0.17 5.1 0.45 NLS 6.92 0.06 Ok

–~ – D3 4 0.21 ± 0.024 0.16 1.3 3.1 ± 0.81 19 0.16 NLS 6.76 0.13 Ok

–~ – D4 4 0.18 ± 0.024 0.14 1.2 1.4 ± 0.48 4.3 0.34 NLS 6.74 0.16 Ok

–~ – D5 4 0.14 ± 0.036 0.1 1.4 0.51 ± 0.26 1.4 0.36 NLS 6.60 0.25 ‐

–~ – D6 4 0.16 ± 0.014 0.18 0.88 1.6 ± 0.38 5.4 0.3 max 6.71 0.12 Ok

–~ – D7 4 0.093 ± 0.0071 0.082 1.1 1.2 ± 0.23 4.3 0.29 NLS 6.68 0.09 Ok

–~ – D8 4 0.38 ± 0.053 0.31 1.2 1 ± 0.23 3.6 0.28 NLS 6.64 0.15 ‐

–~ – D9 4 0.083 ± 0.015 0.061 1.4 6.3 ± 5.1 18 0.35 NLS 7.50 0.36 Ok

–~ – D10 4 0.048 ± 0.0014 0.044 1.1 0.7 ± 0.054 2.5 0.28 NLS 6.86 0.06 Ok

–~ – D11 4 0.066 ± 0.0083 0.053 1.2 0.028 ± 0.0032 0.21 0.13 NLS 6.33 0.25 ‐

25 Benz[a]anthracene D1 4 1 ± 0.27 0.81 1.3 6.1 ± 3.3 18 0.33 NLS 6.99 0.28 ‐

–~ – D2 4 0.46 ± 0.025 0.41 1.1 16 ± 2.4 43 0.37 NLS 7.32 0.08 Ok

–~ – D3 4 0.49 ± 0.16 0.28 1.8 13 ± 9.8 176 0.071 NLS 7.01 0.37 Ok

–~ – D4 4 0.46 ± 0.091 0.35 1.3 9.2 ± 4.6 37 0.25 NLS 7.16 0.24 Ok

–~ – D5 4 0.26 ± 0.096 0.16 1.6 1.9 ± 1.6 12 0.16 NLS 6.92 0.40 ‐

–~ – D6 4 0.44 ± 0.017 0.39 1.1 12 ± 1.2 47 0.25 NLS 7.20 0.07 Ok

–~ – D7 4 0.17 ± 0.019 0.14 1.2 6.2 ± 1.7 34 0.18 NLS 7.13 0.13 Ok

–~ – D8 4 1.3 ± 0.32 0.94 1.4 6.4 ± 2.9 30 0.22 NLS 6.92 0.24 ‐

–~ – D9 4 0.31 ± 0.086 0.15 2 nr nr 208 na ns na na ‐

–~ – D10 4 0.093 ± 0.017 0.068 1.4 2.3 ± 1.1 17 0.14 NLS 7.09 0.22 Ok

–~ – D11 4 0.11 ± 0.023 0.094 1.2 0.12 ± 0.026 1.4 0.087 NLS 6.72 0.27 ‐

26 Chrysene D1 4 0.6 ± 0.095 0.47 1.3 3.3 ± 1.2 11 0.31 NLS 6.96 0.19 ‐

–~ – D2 4 0.29 ± 0.011 0.29 1 12 ± 1.3 24 0.5 NLS 7.39 0.07 Ok

–~ – D3 4 0.33 ± 0.079 0.21 1.5 7.8 ± 4.5 98 0.08 NLS 6.96 0.28 Ok

–~ – D4 4 0.31 ± 0.054 0.24 1.3 6 ± 2.6 21 0.29 NLS 7.14 0.21 Ok

–~ – D5 4 0.18 ± 0.051 0.12 1.5 1.2 ± 0.73 7.1 0.16 NLS 6.86 0.30 ‐

–~ – D6 4 0.34 ± 0.011 0.33 1 18 ± 1.6 27 0.69 NLS 7.50 0.06 Ok

–~ – D7 4 0.16 ± 0.017 0.13 1.2 4.8 ± 1.2 21 0.24 NLS 7.05 0.13 Ok

–~ – D8 4 0.78 ± 0.16 0.57 1.4 3.4 ± 1.3 17 0.2 NLS 6.86 0.22 ‐


–~ – D10 4 0.088 ± 0.014 0.065 1.3 2.2 ± 0.86 10 0.21 NLS 7.10 0.19 Ok

–~ – D11 4 0.096 ± 0.018 0.076 1.3 0.098 ± 0.02 0.94 0.1 NLS 6.71 0.27 ‐

19


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


27 Triphenylene D1 4 0.42 ± 0.056 0.35 1.2 1.8 ± 0.51 3.5 0.5 NLS 6.86 0.17 ‐

–~ – D2 4 0.26 ± 0.0076 0.26 0.99 3.4 ± 0.27 7.9 0.44 max 6.88 0.06 Ok

–~ – D3 4 0.33 ± 0.038 0.27 1.3 4.1 ± 1.1 26 0.16 NLS 6.67 0.13 Ok

–~ – D4 4 0.3 ± 0.032 0.25 1.2 2.5 ± 0.67 7 0.35 NLS 6.78 0.14 Ok

–~ – D5 4 0.19 ± 0.037 0.14 1.3 0.85 ± 0.36 2.3 0.38 NLS 6.70 0.21 ‐

–~ – D6 4 0.3 ± 0.031 0.35 0.84 3.2 ± 0.88 9.9 0.32 max 6.73 0.14 Ok

–~ – D7 4 0.21 ± 0.02 0.18 1.2 3.1 ± 0.72 8.2 0.38 NLS 6.74 0.12 Ok

–~ – D8 4 0.5 ± 0.046 0.44 1.1 1.3 ± 0.18 5 0.25 NLS 6.64 0.12 ‐

–~ – D9 4 0.22 ± 0.03 0.17 1.3 6.8 ± 2.4 29 0.23 NLS 7.10 0.17 Ok

–~ – D10 4 0.15 ± 0.014 0.12 1.3 1.7 ± 0.45 4.5 0.39 NLS 6.76 0.13 Ok

–~ – D11 4 0.16 ± 0.023 0.11 1.4 0.044 ± 0.0052 0.32 0.14 NLS 6.14 0.25 ‐

28 Retene D1 4 1 ± 0.035 0.74 1.4 0.89 ± 0.024 1.7 0.52 NLS 6.15 0.10 ‐

–~ – D2 4 0.4 ± 0.038 0.4 1 1.5 ± 0.23 7.4 0.2 max 6.34 0.09 Ok

–~ – D3 4 0.35 ± 0.014 0.32 1.1 1.5 ± 0.094 8.6 0.17 NLS 6.21 0.05 Ok

–~ – D4 4 0.27 ± 0.015 0.23 1.2 0.7 ± 0.051 6.7 0.1 NLS 6.26 0.07 Ok

–~ – D5 4 1.5 ± 1 0.57 2.7 0.3 ± 0.075 2.9 0.1 NLS 5.34 0.31 ‐

–~ – D6 4 0.22 ± 0.031 0.22 0.98 0.86 ± 0.2 7.6 0.11 max 6.36 0.13 Ok

–~ – D7 4 0.71 ± 0.014 0.65 1.1 2.6 ± 0.077 22 0.12 NLS 6.13 0.04 Ok

–~ – D8 4 0.76 ± 0.074 0.52 1.5 0.54 ± 0.038 3.2 0.17 NLS 6.07 0.11 ‐

–~ – D9 4 0.25 ± 0.048 0.26 0.96 2.7 ± 1.1 19 0.14 max 6.64 0.21 Ok

–~ – D10 4 0.21 ± 0.025 0.2 1.1 0.57 ± 0.091 8.4 0.068 NLS 6.13 0.10 Ok

–~ – D11 4 0.071 ± 0.038 0.06 1.2 0.039 ± 0.018 0.71 0.055 NLS 6.44 0.39 ‐

29 Benzo[b]fluoranthene D1 4 0.17 ± 0.021 0.14 1.3 4 ± 1.2 12 0.34 NLS 7.58 0.17 ‐

–~ – D2 4 0.087 ± 0.0043 0.09 0.97 17 ± 2.8 29 0.59 max 8.05 0.09 Ok

–~ – D3 4 0.13 ± 0.022 0.094 1.4 13 ± 5.6 113 0.12 NLS 7.58 0.20 Ok

–~ – D4 4 0.12 ± 0.011 0.1 1.2 7.9 ± 1.8 29 0.28 NLS 7.66 0.12 Ok

–~ – D5 4 0.069 ± 0.015 0.05 1.4 1.5 ± 0.75 7.8 0.2 NLS 7.38 0.24 ‐

–~ – D6 4 0.11 ± 0.0035 0.12 0.9 11 ± 0.9 37 0.29 max 7.74 0.06 Ok

–~ – D7 4 0.052 ± 0.005 0.046 1.1 7.4 ± 1.8 26 0.29 NLS 7.72 0.12 Ok

–~ – D8 4 0.22 ± 0.049 0.18 1.2 4 ± 1.9 19 0.21 NLS 7.48 0.25 ‐


–~ – D10 4 0.034 ± 0.0048 0.027 1.3 2.8 ± 0.98 13 0.21 NLS 7.61 0.17 Ok

–~ – D11 4 0.017 ± 0.0059 0.011 1.5 0.12 ± 0.062 0.74 0.16 NLS 7.55 0.36 ‐

30 Benzo[k]fluoranthene D1 4 0.074 ± 0.0076 0.059 1.2 1.6 ± 0.39 5.5 0.29 NLS 7.56 0.15 ‐

–~ – D2 4 0.032 ± 0.00068 0.035 0.91 8.4 ± 0.65 13 0.66 max 8.15 0.06 Ok

–~ – D3 4 0.035 ± 0.0073 0.024 1.5 4.3 ± 2.5 46 0.094 NLS 7.68 0.27 Ok

–~ – D4 4 0.038 ± 0.0049 0.033 1.1 2.9 ± 0.92 12 0.25 NLS 7.73 0.16 Ok

–~ – D5 4 0.022 ± 0.0057 0.015 1.4 0.49 ± 0.3 3.3 0.15 NLS 7.39 0.29 ‐

–~ – D6 4 0.046 ± 0.0046 0.059 0.78 6.5 ± 1.7 15 0.43 max 7.81 0.13 Ok

–~ – D7 4 0.018 ± 0.0021 0.015 1.1 2.2 ± 0.63 10 0.22 NLS 7.66 0.14 Ok

–~ – D8 4 0.087 ± 0.015 0.068 1.3 1.5 ± 0.57 8.7 0.17 NLS 7.46 0.21 ‐


–~ – D10 4 0.01 ± 0.0014 0.0086 1.2 0.86 ± 0.3 4.9 0.17 NLS 7.63 0.17 Ok

–~ – D11 4 0.0067 ± 0.0015 0.0049 1.4 0.05 ± 0.017 0.55 0.09 NLS 7.57 0.30 ‐

20


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


31 Benzo[a]pyrene D1 4 0.12 ± 0.033 0.086 1.4 1.5 ± 0.87 7.1 0.22 NLS 7.33 0.29 ‐

–~ – D2 4 0.039 ± 0.003 0.032 1.2 7.7 ± 2 20 0.39 NLS 8.07 0.13 Ok

–~ – D3 4 0.038 ± 0.012 0.019 2 4 ± 3.6 85 0.047 NLS 7.61 0.42 ‐

–~ – D4 4 0.036 ± 0.0055 0.027 1.3 3.4 ± 1.3 18 0.19 NLS 7.84 0.19 Ok

–~ – D5 4 0.027 ± 0.01 0.017 1.6 0.49 ± 0.42 4.8 0.1 NLS 7.30 0.42 ‐

–~ – D6 4 0.034 ± 0.0018 0.033 1 2.6 ± 0.35 24 0.11 NLS 7.65 0.08 Ok

–~ – D7 4 0.018 ± 0.0019 0.014 1.2 2.7 ± 0.75 19 0.15 NLS 7.75 0.13 Ok

–~ – D8 4 0.11 ± 0.028 0.085 1.3 1.7 ± 0.9 13 0.13 NLS 7.39 0.27 ‐

–~ – D9 4 0.025 ± 0.0076 0.0098 2.6 nr nr 99 ns na na ‐

–~ – D10 4 0.0061 ± 0.0019 0.0029 2.1 0.59 ± 0.45 8.1 0.073 NLS 7.69 0.36 ‐

–~ – D11 4 0.0057 ± 0.0028 0.004 1.4 0.049 ± 0.041 0.36 0.14 NLS 7.63 0.48 ‐

32 Benzo[e]pyrene D1 4 0.2 ± 0.019 0.16 1.2 3.6 ± 0.87 10 0.36 NLS 7.49 0.15 ‐

–~ – D2 4 0.097 ± 0.0035 0.11 0.91 14 ± 1.6 24 0.59 max 7.89 0.07 Ok

–~ – D3 4 0.12 ± 0.018 0.091 1.3 10 ± 4 93 0.11 NLS 7.50 0.19 Ok

–~ – D4 4 0.13 ± 0.013 0.1 1.2 6.8 ± 1.7 24 0.29 NLS 7.59 0.13 Ok

–~ – D5 4 0.075 ± 0.016 0.054 1.4 1.3 ± 0.66 6.6 0.2 NLS 7.29 0.25 ‐

–~ – D6 4 0.14 ± 0.012 0.16 0.86 10 ± 2.4 30 0.35 max 7.57 0.12 Ok

–~ – D7 4 0.074 ± 0.0085 0.06 1.2 7.1 ± 2 22 0.32 NLS 7.55 0.14 Ok

–~ – D8 4 0.24 ± 0.03 0.2 1.2 3.4 ± 0.99 16 0.21 NLS 7.38 0.17 ‐


–~ – D10 4 0.05 ± 0.0053 0.04 1.2 3.3 ± 0.9 12 0.28 NLS 7.52 0.13 Ok

–~ – D11 4 0.026 ± 0.0067 0.019 1.4 0.098 ± 0.033 0.77 0.13 NLS 7.28 0.30 ‐

33 Benzo[j]fluoranthene D1 4 0.11 ± 0.011 0.092 1.2 2.7 ± 0.7 7.1 0.38 NLS 7.60 0.15 ‐

–~ – D2 4 0.06 ± 0.0044 0.065 0.92 13 ± 3.4 17 0.75 max 8.07 0.13 Ok

–~ – D3 4 0.071 ± 0.0071 0.063 1.1 8.5 ± 2.5 60 0.14 NLS 7.66 0.14 Ok

–~ – D4 4 0.069 ± 0.0036 0.076 0.91 5.1 ± 0.67 15 0.34 max 7.68 0.08 Ok

–~ – D5 4 0.045 ± 0.0089 0.033 1.4 0.92 ± 0.45 4.4 0.21 NLS 7.35 0.24 ‐

–~ – D6 4 0.1 ± 0.012 0.099 1 6.7 ± 2 18 0.37 NLS 7.59 0.15 Ok

–~ – D7 4 0.045 ± 0.0076 0.032 1.4 3.8 ± 1.6 12 0.31 NLS 7.50 0.20 Ok

–~ – D8 4 0.16 ± 0.027 0.14 1.1 1.2 ± 0.34 10 0.12 NLS 7.11 0.17 ‐


–~ – D10 4 0.024 ± 0.0029 0.019 1.3 1.7 ± 0.53 7.2 0.24 NLS 7.55 0.15 Ok

–~ – D11 4 0.012 ± 0.0032 0.0089 1.4 0.071 ± 0.027 0.53 0.13 NLS 7.45 0.31 ‐

34 Perylene D1 4 0.057 ± 0.012 0.041 1.4 1.2 ± 0.71 3.2 0.39 NLS 7.55 0.28 ‐

–~ – D2 4 0.05 ± 0.0016 0.048 1.1 24 ± 5.1 14 1.8 NLS 8.45 0.10 Ok

–~ – D3 4 0.041 ± 0.0056 0.03 1.4 14 ± 12 36 0.39 NLS 8.12 0.37 Ok

–~ – D4 4 0.033 ± 0.0034 0.025 1.3 5 ± 1.5 8.7 0.58 NLS 8.04 0.15 Ok

–~ – D5 4 0.035 ± 0.007 0.025 1.4 0.82 ± 0.41 2.5 0.33 NLS 7.42 0.24 ‐

–~ – D6 4 0.054 ± 0.0034 0.055 0.98 14 ± 3.1 16 0.88 max 8.18 0.11 Ok

–~ – D7 4 0.12 ± 0.012 0.097 1.2 24 ± 7.5 53 0.46 NLS 7.87 0.14 Ok

–~ – D8 4 0.087 ± 0.0098 0.069 1.3 2.5 ± 0.75 6.7 0.37 NLS 7.68 0.17 ‐


–~ – D10 4 0.045 ± 0.0065 0.031 1.5 7.5 ± 3 20 0.38 NLS 7.92 0.19 Ok

–~ – D11 4 0.01 ± 0.0034 0.0072 1.4 0.065 ± 0.033 na na NLS 7.50 0.36 ‐

21


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


35 Benzo[ghi]perylene D1 4 0.038 ± 0.0028 0.033 1.2 3.4 ± 0.67 9.6 0.36 NLS 8.17 0.13 ‐

–~ – D2 4 0.021 ± 0.00081 0.023 0.89 31 ± 9.7 23 1.3 max 8.90 0.15 Ok

–~ – D3 4 0.022 ± 0.0035 0.015 1.4 8 ± 4.4 106 0.076 NLS 8.15 0.25 Ok

–~ – D4 4 0.021 ± 0.0026 0.016 1.3 4.9 ± 1.6 23 0.21 NLS 8.22 0.16 Ok

–~ – D5 4 0.018 ± 0.0035 0.013 1.4 0.88 ± 0.42 6.4 0.14 NLS 7.74 0.23 ‐

–~ – D6 4 0.026 ± 0.0026 0.03 0.88 11 ± 3 30 0.36 max 8.33 0.14 Ok

–~ – D7 4 0.015 ± 0.0021 0.011 1.4 6.1 ± 2.4 25 0.25 NLS 8.18 0.18 Ok

–~ – D8 4 0.04 ± 0.0049 0.031 1.3 2.2 ± 0.7 16 0.13 NLS 7.96 0.18 ‐


–~ – D10 4 0.0096 ± 0.0018 0.0066 1.5 1.9 ± 0.85 12 0.15 NLS 7.99 0.22 Ok

–~ – D11 4 0.0034 ± 0.0014 0.0021 1.6 0.069 ± 0.05 0.52 0.13 NLS 8.00 0.43 ‐

36 Dibenz[a,h]anthracene D1 4 0.0088 ± 0.0013 0.0067 1.3 0.76 ± 0.29 2.3 0.33 NLS 8.16 0.20 ‐

–~ – D2 4 0.004 ± 0.00021 0.005 0.8 3.1 ± 0.56 5.5 0.57 max 8.56 0.09 Ok

–~ – D3 4 0.0051 ± 0.0011 0.0033 1.5 1.4 ± 0.74 20 0.07 NLS 8.03 0.25 Ok

–~ – D4 4 0.0052 ± 0.001 0.0037 1.4 1.2 ± 0.56 5.5 0.21 NLS 8.22 0.23 Ok

–~ – D5 4 0.0037 ± 0.0012 0.0025 1.5 0.22 ± 0.15 1.6 0.14 NLS 7.82 0.34 ‐

–~ – D6 4 0.0052 ± 0.00053 0.0052 1 1.8 ± 0.47 6.8 0.26 max 8.31 0.13 Ok

–~ – D7 4 0.0029 ± 0.00059 0.0019 1.5 0.81 ± 0.4 6.2 0.13 NLS 8.02 0.24 Ok

–~ – D8 4 0.0087 ± 0.0024 0.006 1.4 0.55 ± 0.36 3.4 0.16 NLS 8.02 0.33 ‐


–~ – D10 4 0.0016 ± 0.00039 0.0011 1.5 0.28 ± 0.18 2.7 0.1 NLS 7.93 0.30 Ok

–~ – D11 3 0.00045 ± 0.00026 0.00029 1.6 0.016 ± 0.015 na na NLS 8.25 0.54 ‐

37 Indeno[1,2,3‐cd]pyrene D1 4 0.033 ± 0.0023 0.028 1.2 3.6 ± 0.67 10 0.35 NLS 8.26 0.13 ‐

–~ – D2 4 0.018 ± 0.00098 0.023 0.8 37 ± 19 25 1.5 max 8.98 0.23 Ok

–~ – D3 4 0.025 ± 0.0039 0.017 1.4 9.7 ± 5.2 110 0.088 NLS 8.18 0.24 Ok

–~ – D4 4 0.022 ± 0.0019 0.018 1.2 6.2 ± 1.4 27 0.23 NLS 8.30 0.12 Ok

–~ – D5 4 0.014 ± 0.0035 0.0096 1.5 0.74 ± 0.45 6.6 0.11 NLS 7.76 0.29 ‐

–~ – D6 4 0.023 ± 0.0025 0.02 1.1 14 ± 5.2 32 0.44 NLS 8.55 0.17 Ok

–~ – D7 4 0.012 ± 0.0012 0.0097 1.2 5.4 ± 1.6 24 0.22 NLS 8.22 0.14 Ok

–~ – D8 4 0.036 ± 0.0058 0.027 1.4 2.1 ± 0.91 18 0.12 NLS 7.99 0.22 ‐


–~ – D10 4 0.0063 ± 0.0013 0.0042 1.5 1.4 ± 0.7 12 0.11 NLS 8.04 0.24 Ok

–~ – D11 3 0.0037 ± 0.0015 0.0022 1.7 0.038 ± 0.016 0.63 0.061 NLS 7.71 0.34 ‐

38 Coronene D1 4 0.004 ± 0.00034 0.0032 1.3 4.9 ± 1.1 7.1 0.69 NLS 9.31 0.14 ‐

–~ – D2 4 0.0031 ± 0.000095 0.0034 0.92 4.4 ± 0.41 19 0.24 max 8.88 0.06 Ok

–~ – D3 4 0.0035 ± 0.00042 0.0025 1.4 3 ± 0.95 80 0.038 NLS 8.52 0.15 Ok

–~ – D4 4 0.0028 ± 0.00048 0.002 1.4 1.8 ± 0.75 18 0.099 NLS 8.66 0.20 Ok

–~ – D5 4 0.0018 ± 0.00041 0.0013 1.4 0.35 ± 0.2 3.7 0.093 NLS 8.34 0.28 ‐

–~ – D6 4 0.0026 ± 0.00026 0.0032 0.81 5.2 ± 1.7 18 0.29 max 8.98 0.15 Ok

–~ – D7 4 0.0019 ± 0.00035 0.0011 1.7 2.3 ± 1.1 21 0.11 NLS 8.65 0.22 Ok

–~ – D8 4 0.0027 ± 0.0004 0.0019 1.4 0.78 ± 0.31 9.7 0.08 NLS 8.68 0.21 ‐

–~ – D9 4 0.0015 ± 0.00016 0.0011 1.4 4.5 ± 2.6 64 0.07 NLS 9.10 0.26 Ok

–~ – D10 4 0.00078 ± 0.00017 0.00051 1.5 0.56 ± 0.3 10 0.054 NLS 8.56 0.25 Ok


22


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


39 Benzo‐naphtho‐ D1 4 0.18 ± 0.034 0.14 1.3 0.89 ± 0.35 2.5 0.35 NLS 6.92 0.21 ‐

thiophene D2 4 0.086 ± 0.0034 0.081 1.1 2.2 ± 0.23 4.9 0.44 NLS 7.18 0.07 Ok

–~ – D3 4 0.086 ± 0.026 0.053 1.6 1.3 ± 0.84 21 0.06 NLS 6.76 0.32 Ok

–~ – D4 4 0.083 ± 0.015 0.062 1.3 1.2 ± 0.54 4 0.3 NLS 7.02 0.22 Ok

–~ – D5 4 0.048 ± 0.013 0.034 1.4 0.27 ± 0.14 1.5 0.18 NLS 6.79 0.27 ‐

–~ – D6 4 0.082 ± 0.0036 0.082 1 2.9 ± 0.32 5.6 0.51 NLS 7.32 0.07 Ok

–~ – D7 4 0.052 ± 0.0041 0.044 1.2 1.1 ± 0.2 5.4 0.19 NLS 6.89 0.10 Ok

–~ – D8 4 0.23 ± 0.048 0.17 1.3 0.84 ± 0.29 4.3 0.2 NLS 6.78 0.20 ‐


–~ – D10 4 0.029 ± 0.0051 0.021 1.4 0.42 ± 0.2 2.8 0.15 NLS 6.87 0.23 Ok

–~ – D11 4 0.027 ± 0.0073 0.024 1.2 0.021 ± 0.0052 0.19 0.11 NLS 6.58 0.29 ‐

40 Galaxolide (HHCB) D1 4 1.6 ± 0.3 0.63 2.5 0.39 ± 0.032 0.33 1.2 NLS 5.61 0.13 ‐

–~ – D2 4 0.21 ± 0.032 0.15 1.4 0.2 ± 0.025 0.35 0.59 NLS 5.74 0.10 Ok

–~ – D3 4 0.34 ± 0.12 0.2 1.7 0.17 ± 0.034 0.4 0.43 NLS 5.28 0.18 Ok

–~ – D4 4 0.58 ± 0.28 0.25 2.3 0.16 ± 0.034 0.34 0.48 NLS 5.30 0.23 ‐

–~ – D5 4 0.34 ± 0.17 0.17 2 0.13 ± 0.035 0.36 0.35 NLS 5.63 0.26 ‐

–~ – D6 4 0.6 ± 0.32 0.22 2.7 0.16 ± 0.032 0.49 0.32 NLS 5.20 0.25 ‐

–~ – D7 4 0.88 ± 0.18 0.43 2.1 0.35 ± 0.037 0.76 0.46 NLS 5.17 0.11 ‐

–~ – D8 4 1.6 ± 0.71 0.46 3.6 0.23 ± 0.027 0.3 0.77 NLS 5.37 0.22 ‐

–~ – D9 4 0.2 ± 0.1 0.12 1.7 0.11 ± 0.034 0.34 0.32 NLS 5.36 0.26 Ok

–~ – D10 4 0.73 ± 0.16 0.3 2.4 0.23 ± 0.021 0.61 0.37 NLS 5.20 0.11 ‐

–~ – D11 4 1.1 ± 0.58 0.29 3.7 0.073 ± 0.012 0.14 0.52 NLS 5.54 0.34 ‐

41 Tonalide (AHTN) D1 4 0.22 ± 0.047 0.13 1.7 0.11 ± 0.015 0.12 0.88 NLS 5.92 0.14 ‐

–~ – D2 4 0.13 ± 0.028 0.086 1.6 0.076 ± 0.01 0.17 0.46 NLS 5.52 0.12 Ok

–~ – D3 4 0.2 ± 0.0065 0.13 1.6 0.13 ± 0.0027 0.3 0.42 NLS 5.40 0.04 Ok

–~ – D4 4 0.28 ± 0.017 0.12 2.3 0.073 ± 0.002 0.21 0.35 NLS 5.27 0.06 ‐

–~ – D5 4 0.17 ± 0.032 0.058 2.9 0.031 ± 0.0021 0.23 0.13 NLS 5.31 0.11 ‐

–~ – D6 4 0.42 ± 0.0057 0.2 2.1 0.15 ± 0.00097 0.34 0.44 NLS 5.32 0.05 ‐

–~ – D7 4 0.15 ± 0.012 0.091 1.7 0.09 ± 0.0049 0.35 0.26 NLS 5.35 0.06 Ok

–~ – D8 4 3.4 ± 0.43 0.87 3.9 0.4 ± 0.012 0.4 0.99 NLS 5.29 0.11 ‐

–~ – D9 4 0.26 ± 0.022 0.16 1.7 0.14 ± 0.0073 0.45 0.31 NLS 5.35 0.06 Ok

–~ – D10 4 0.62 ± 0.012 0.23 2.7 0.16 ± 0.0011 0.42 0.37 NLS 5.11 0.04 ‐

–~ – D11 3 0.0049 ± 0.00043 0.0028 1.7 0.0076 ± 0.00061 0.087 0.088 NLS 6.89 0.24 ‐

42 Cashmeran (DPMI) D1 3 2.3 ± 0.36 1.8 1.2 0.49 ± 0.073 na na NLS 5.55 0.13 ‐

–~ – D2 4 0.6 ± 0.087 0.43 1.4 1.4 ± 0.56 na na NLS 6.14 0.19 Ok

–~ – D3 4 0.49 ± 0.051 0.63 0.78 0.94 ± 0.21 na na max 5.76 0.11 Ok

–~ – D4 4 0.29 ± 0.14 0.87 0.34 nr nr na na ns na na Ok

–~ – D5 4 0.98 ± 0.53 0.89 1.1 0.22 ± 0.12 1 0.22 NLS 5.40 0.34 ‐

–~ – D6 4 0.55 ± 0.13 0.91 0.6 1.2 ± 0.8 0.74 1.7 max 5.89 0.30 Ok

–~ – D7 4 0.41 ± 0.26 1.2 0.33 nr nr 1.7 na ns na na Ok

–~ – D8 4 0.55 ± 0.15 1.1 0.5 1.4 ± 1 1.2 1.2 max 6.33 0.37 ‐

–~ – D9 4 0.33 ± 0.12 0.8 0.42 1.5 ± 1.3 0.95 1.6 max 5.89 0.40 Ok

–~ – D10 4 0.19 ± 0.029 0.13 1.5 7.5 ± 6.7 na na NLS 7.30 0.40 Ok

–~ – D11 4 0.28 ± 0.072 0.52 0.54 0.53 ± 0.29 na na max 6.71 0.36 ‐

23


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


43 Tris(1‐chloro‐2‐propyl)‐ D1 3 27 ± 2.1 21 1.3 0.79 ± 0.064 na na NLS 4.69 0.11 ‐

phosphate D2 3 51 ± 16 32 1.6 0.57 ± 0.11 na na NLS 3.81 0.17 ‐

–~ – D3 4 8.7 ± 1.7 14 0.62 4.4 ± 2 na na max 5.08 0.22 Ok

–~ – D4 4 11 ± 2.3 15 0.75 5.6 ± 2.9 na na max 5.43 0.25 Ok

–~ – D5 3 15 ± 3.3 13 1.1 0.56 ± 0.14 na na NLS 4.62 0.16 ‐

–~ – D6 3 85 ± 19 39 2.2 0.57 ± 0.063 na na NLS 3.60 0.12 ‐

–~ – D7 4 9.7 ± 2.2 14 0.68 3.4 ± 1.9 na na max 4.95 0.26 Ok

–~ – D8 4 12 ± 3.8 18 0.66 1.6 ± 1.2 na na max 5.16 0.35 ‐

–~ – D9 4 8.7 ± 2.8 15 0.58 2.3 ± 1.7 na na max 4.81 0.35 Ok



44 Tris(1,3‐dichloro‐ D1 1 na na na na na na na na na na na ‐

2‐propyl) phosphate D2 3 2.2 ± 0.062 2.1 1.1 5.9 ± 0.52 na na NLS 6.20 0.06 ‐

–~ – D3 3 2 ± 0.051 2 1 40 ± 19 na na NLS 6.88 0.21 ‐

–~ – D4 4 2.5 ± 0.23 2.4 1 18 ± 9.9 na na NLS 6.71 0.25 Ok

–~ – D5 4 2.1 ± 0.17 2 1.1 nr nr na na ns na na ‐


–~ – D7 4 1.8 ± 0.19 1.3 1.3 14 ± 7.5 na na NLS 6.46 0.24 Ok

–~ – D8 4 1.7 ± 0.12 1.8 0.97 35 ± 30 na na max 7.51 0.38 ‐

–~ – D9 3 1.7 ± 0.2 1.4 1.2 7.6 ± 4.3 na na NLS 6.28 0.25 ‐


–~ – D11 3 5 ± 4 1.3 3.7 nr nr na na ns na na ‐

45 Triisobutylphosphate D1 1 na na na na na na na na na na na ‐


–~ – D3 4 0.3 ± 0.066 0.32 0.92 0.54 ± 0.18 na na max 5.81 0.18 Ok

–~ – D4 4 0.27 ± 0.063 0.32 0.84 0.74 ± 0.36 na na max 6.22 0.24 Ok

–~ – D5 4 0.35 ± 0.07 0.27 1.3 0.23 ± 0.042 na na NLS 5.87 0.14 ‐


–~ – D7 4 1.1 ± 0.66 0.49 2.2 0.19 ± 0.056 na na NLS 4.81 0.29 ‐

–~ – D8 4 0.79 ± 0.26 0.48 1.6 0.2 ± 0.041 na na NLS 5.63 0.19 ‐

–~ – D9 4 0.052 ± 0.016 0.093 0.56 1.7 ± 1.6 na na max 6.88 0.43 Ok

–~ – D10 3 nr nr 0.13 na 0.14 ns na na na 4.82 1.22 ‐

–~ – D11 3 0.068 ± 0.044 0.035 1.9 nr nr na na ns na na ‐

46 Tri‐n‐butylphosphate D1 2 na na 0.16 na na na na na na na na ‐

–~ – D2 3 0.044 ± 0.0032 0.037 1.2 0.37 ± 0.071 na na NLS 6.70 0.10 ‐

–~ – D3 4 0.035 ± 0.0049 0.045 0.79 1.1 ± 0.52 na na max 6.97 0.21 Ok

–~ – D4 4 0.098 ± 0.027 0.068 1.4 0.75 ± 0.53 na na NLS 6.74 0.33 Ok

–~ – D5 4 0.046 ± 0.0086 0.032 1.4 0.57 ± 0.27 na na NLS 7.14 0.24 ‐




–~ – D9 4 0.035 ± 0.0015 0.032 1.1 2.5 ± 0.57 na na NLS 7.47 0.11 Ok

–~ – D10 3 0.046 ± 0.0015 0.045 1 0.7 ± 0.055 na na NLS 6.88 0.06 ‐

–~ – D11 3 0.041 ± 0.0018 0.038 1.1 1 ± 0.15 na na NLS 8.09 0.25 ‐

24


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


47 Triphenyl phosphate D1 1 na na na na na na na na na na na ‐


–~ – D3 4 0.069 ± 0.049 0.061 1.1 0.04 ± 0.024 1.6 0.026 NLS 5.35 0.41 Ok

–~ – D4 4 0.024 ± 0.0042 0.026 0.89 0.14 ± 0.064 0.54 0.26 max 6.58 0.22 Ok

–~ – D5 4 0.021 ± 0.0038 0.028 0.73 0.09 ± 0.04 na na max 6.55 0.22 ‐



–~ – D8 3 0.098 ± 0.033 0.06 1.6 0.029 ± 0.0064 0.94 0.03 NLS 5.69 0.20 ‐


–~ – D10 3 0.084 ± 0.011 0.057 1.5 0.036 ± 0.0037 na na NLS 5.33 0.09 ‐


48 Tri(2‐ethylhexyl)‐ D1 3 0.011 ± 0.0073 0.013 0.9 nr nr na na ns na na ‐

phosphate D2 3 0.0079 ± 0.00055 0.0075 1 nr nr na na ns na na ‐

–~ – D3 4 0.014 ± 0.0014 0.012 1.2 1.6 ± 0.35 2.2 0.71 NLS 7.66 0.11 Ok

–~ – D4 4 0.0045 ± 0.00018 0.0041 1.1 0.31 ± 0.025 na na NLS 7.69 0.07 Ok



–~ – D7 4 0.0068 ± 0.0012 0.0069 0.99 0.63 ± 0.24 1.5 0.41 max 7.53 0.19 Ok

–~ – D8 3 0.01 ± 0.00064 0.0092 1.1 0.89 ± 0.17 na na NLS 8.17 0.13 ‐

–~ – D9 4 0.0041 ± 0.00056 0.0037 1.1 0.48 ± 0.14 na na NLS 7.69 0.15 Ok

–~ – D10 4 0.0086 ± 0.0016 0.0074 1.2 0.63 ± 0.25 na na NLS 7.56 0.19 Ok


49 Atrazine D1 3 3.1 ± 1.6 1.8 1.7 nr nr na na ns na na ‐








–~ – D9 4 2.5 ± 0.39 1.8 1.4 0.058 ± 0.021 na na NLS 3.98 0.17 Ok

–~ – D10 4 5.5 ± 1.2 3.5 1.6 0.074 ± 0.045 na na NLS 3.83 0.28 Ok

–~ – D11 4 6.7 ± 3.8 4.7 1.4 0.0047 ± 0.0024 na na NLS 3.55 0.41 ‐

50 Chlortoluron D1 3 4.4 ± 1.5 5.7 0.78 nr nr na na ns na na ‐

–~ – D2 2 na na 4 na na na na na na na na ‐




–~ – D6 3 5.8 ± 0.69 4.7 1.2 0.038 ± 0.011 na na NLS 3.58 0.14 ‐






25


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


51 Isoproturon D1 4 9.6 ± 3 8.7 1.1 0.014 ± 0.0043 na na NLS 3.39 0.22 ‐

–~ – D2 4 5.4 ± 0.46 4.8 1.1 0.016 ± 0.0022 na na NLS 3.24 0.08 Ok




–~ – D6 4 5.2 ± 0.11 4.8 1.1 0.02 ± 0.00073 na na NLS 3.36 0.05 Ok




–~ – D10 4 1.5 ± 0.24 1.3 1.2 0.012 ± 0.0046 na na NLS 3.59 0.19 Ok

–~ – D11 4 5.7 ± 0.39 4.7 1.2 0.0054 ± 0.00039 na na NLS 3.68 0.24 ‐

52 Terbuthylazin D1 4 1.3 ± 0.33 0.92 1.4 0.043 ± 0.025 na na NLS 4.74 0.29 ‐

–~ – D2 4 1.3 ± 0.22 0.94 1.3 0.058 ± 0.025 na na NLS 4.43 0.21 Ok




–~ – D6 4 1.8 ± 0.58 1.1 1.7 0.092 ± 0.073 na na NLS 4.47 0.37 Ok



–~ – D9 4 0.36 ± 0.061 0.27 1.3 0.02 ± 0.0073 na na NLS 4.37 0.18 Ok

–~ – D10 4 9 ± 2.5 6.8 1.3 0.39 ± 0.27 na na NLS 4.34 0.32 Ok

–~ – D11 3 2.8 ± 0.05 1.8 1.5 0.0047 ± 0.000066 na na NLS 3.93 0.24 ‐

53 Diazinon D1 3 0.47 ± 0.062 0.2 2.4 0.011 ± 0.00065 na na NLS 4.59 0.11 ‐

–~ – D2 4 0.12 ± 0.0074 0.1 1.2 0.027 ± 0.0022 na na NLS 5.13 0.07 Ok




–~ – D6 3 nr nr 0.15 na nr ns na na na na na ‐



–~ – D9 3 0.031 ± 0.012 0.023 1.3 0.012 ± 0.0087 na na NLS 5.21 0.35 ‐

–~ – D10 3 0.056 ± 0.0054 0.051 1.1 0.015 ± 0.0022 na na NLS 5.13 0.09 ‐


54 Carbendazim D1 4 4.7 ± 0.21 4.8 0.96 0.073 ± 0.0088 na na max 4.40 0.11 ‐









–~ – D10 3 1 ± 0.26 0.99 1 nr nr na na ns na na ‐

–~ – D11 4 6.1 ± 0.79 4.7 1.3 0.026 ± 0.0078 na na NLS 4.33 0.28 ‐

26


b CW:MAXc EFd CAS:0


j slogKAOCk QFl


55 Metolachlor D1 3 0.57 ± 0.16 0.48 1.2 nr nr na na ns na na ‐

–~ – D2 4 0.57 ± 0.14 0.39 1.5 0.047 ± 0.029 na na NLS 4.68 0.29 Ok




–~ – D6 4 0.63 ± 0.17 0.41 1.5 0.049 ± 0.032 na na NLS 4.66 0.31 Ok



–~ – D9 3 0.13 ± 0.003 0.11 1.1 0.016 ± 0.00079 na na NLS 4.71 0.05 ‐

–~ – D10 4 0.75 ± 0.22 0.49 1.5 0.088 ± 0.07 na na NLS 4.77 0.37 Ok


56 Chlorpyrifos D1 3 0.28 ± 0.02 0.21 1.3 0.14 ± 0.0097 na na NLS 5.92 0.10 ‐

–~ – D2 4 0.069 ± 0.0057 0.087 0.8 0.43 ± 0.096 na na max 6.47 0.11 Ok




–~ – D6 4 0.097 ± 0.023 0.072 1.4 0.27 ± 0.14 na na NLS 6.21 0.25 Ok



–~ – D9 4 0.041 ± 0.0031 0.034 1.2 0.68 ± 0.13 na na NLS 6.83 0.10 Ok



57 Propiconazole D1 4 3.6 ± 0.12 1.3 2.7 0.049 ± 0.00065 na na NLS 4.36 0.10 ‐

–~ – D2 4 1 ± 0.34 0.74 1.4 0.14 ± 0.052 na na NLS 4.90 0.22 Ok




–~ – D6 4 1.2 ± 0.12 0.97 1.2 0.13 ± 0.013 na na NLS 4.81 0.08 Ok



–~ – D9 4 0.62 ± 0.28 0.41 1.5 0.11 ± 0.061 na na NLS 4.87 0.32 Ok

–~ – D10 4 0.63 ± 0.22 0.65 0.96 0.12 ± 0.064 na na max 4.96 0.27 Ok


58 Tebuconazole D1 4 3.2 ± 0.15 2.6 1.2 0.044 ± 0.0022 na na NLS 4.37 0.10 ‐

–~ – D2 4 1.2 ± 0.35 0.88 1.4 0.069 ± 0.046 na na NLS 4.53 0.32 Ok




–~ – D6 4 1.2 ± 0.27 0.92 1.3 0.088 ± 0.045 na na NLS 4.62 0.25 Ok



–~ – D9 3 0.5 ± 0.092 0.47 1.1 0.047 ± 0.018 na na NLS 4.60 0.19 ‐

–~ – D10 4 1.2 ± 0.45 0.87 1.4 0.12 ± 0.12 na na NLS 4.68 0.44 Ok

–~ – D11 3 3.2 ± 0.21 1.6 2 0.0051 ± 0.00021 na na NLS 3.91 0.24 ‐

27

S12. Profiles of dissolved and AOC based concentrations in the Danube stretch

Plots of freely dissolved concentrations (∆: Cw:0, ng L–1, right y–axis) and accessible concentrations

expressed on amorphous organic carbon basis (○ : CAS:0/fAOC, mg kg–1, left y–axis) versus the locations on the

x‐axis. The locations are ordered in downstream direction but the distance on the x‐axis does not reflect

the actual distance, neither do the connecting lines represent the concentrations in between them. Open,

gray and black filled markers indicate fAOC <0.001, fAOC ≥0.001 but <0.002 or fAOC ≥0.002, respectively.

Data for a location marked with a “+” passed the MR‐EPS quality criterion, QF is “Ok” (see S11 last column).

Numbers in the first column refer to the contaminant No used throughout the manuscript e.g. S3A and B

and S11 etc.

No PCB

1

2

3

4

+ ++

+

+

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.02

0.04

0.06

0.08

0

0.05

0.1

0.15Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

1 - PCB 28

+ ++

+

+

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.02

0.04

0.06

0.08

0.1

0

0.05

0.1

0.15Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

2 - PCB 52

++

+ + +

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.005

0.01

0.015

0.02

0

0.02

0.04

0.06

0.08Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

3 - PCB 101

++

+ + +

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.0005

0.001

0.0015

0.002

0.0025

0.003

0

0.01

0.02

0.03Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

4 - PCB 118

28

5

7

OCB

8

9

10

12

+

++

+

+

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.005

0.01

0.015

0.02

0.025

0

0.1

0.2

0.3

0.4Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

6 - PCB 153

++

++

+

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.002

0.004

0.006

0.008

0

0.1

0.2

0.3

0.4Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

7 - PCB 180

+

++ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.1

0.2

0.3

0

0.01

0.02

0.03

0.04

0.05

0.06Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

8 - Pentachlorobenzene

+

+

+

++

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.05

0.1

0.15

0.2

0.25

0

0.05

0.1

0.15

0.2

0.25Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

9 - Hexachlorobenzene

+

+

+

+

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.002

0.004

0.006

0.008

0.01

0

0.01

0.02

0.03Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

10 - 2,4-DDE

+ + + + ++ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.2

0.4

0.6

0

1

2

3 Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

12 - 4,4-DDE

29

11

12

PAH

16

19

20

21

+

+ +

+

+ + +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.05

0.1

0.15

0.2

0

0.2

0.4

0.6 Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

11 - 2,4-DDD

+

+ +

+

++ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.2

0.4

0.6

0.8

0

0.5

1

1.5

2

2.5Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

13 - 4,4-DDD

++ +

+ ++

+D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

5

10

15

0

0.2

0.4

0.6

0.8Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

16 - Acenaphthylene

++

+ ++

+ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

10

20

30

40

50

60

0

5

10

15

20Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

19 - Phenanthrene

+ ++

++

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

1

2

3

4

5

0

0.5

1

1.5

2

2.5Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

20 - Anthracene

+ ++ +

+ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

5

10

15

20

0

5

10

15

20

25

30Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

21 - Fluoranthene

30

22

25

26

28

29

30

+ ++ +

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

2

4

6

8

10

12

0

5

10

15

20Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

22 - Pyrene

+ + + +

+ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

0

5

10

15Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

25 - Benz[a]anthracene

+ + + +

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.2

0.4

0.6

0.8

1

0

5

10

15Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

26 - Chrysene

+ + + +

+

+ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

0

0.5

1

1.5

2Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

28 - Retene

++ + +

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.05

0.1

0.15

0.2

0.25

0

2

4

6

8

10

12Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

29 - Benzo[b]fluoranthene

+ + ++

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.02

0.04

0.06

0.08

0.1

0

1

2

3

4

5

6Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

30 - Benzo[k]fluoranthene

31

31

35

MUSK

40

41

OPFR

43

44

+ + ++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.05

0.1

0.15

0

1

2

3

4

5Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

31 - Benzo[a]pyrene

+ + ++

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.01

0.02

0.03

0.04

0.05

0

2

4

6Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

35 - Benzo[ghi]perylene

++

+D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

0

0.1

0.2

0.3Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

40 - Galaxolide (HHCB)

+ + ++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

0

0.1

0.2

0.3Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

41 - Tonalide (AHTN)

+ + + +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

10

20

30

40

50

0

1

2

3

4

5Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

43 - Tris(1-chloro-2-propyl) phosphate

++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

1

2

3

4

5

6

0

5

10

15

20

25

30Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

44 - Tris(1,3-dichloro-2-propyl) phosphate

32

45

46

47

48

Polar pesticides

49

51

+ +

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.2

0.4

0.6

0.8

1

1.2

0

0.2

0.4

0.6

0.8Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

45 - Triisobutylphosphate

+

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.02

0.04

0.06

0.08

0.1

0.12

0

0.5

1

1.5

2

2.5

3Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

46 - Tri-n-butylphosphate

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.02

0.04

0.06

0.08

0.1

0.12

0

0.02

0.04

0.06

0.08

0.1

0.12Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

47 - Triphenyl phosphate

+

++

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.005

0.01

0.015

0

0.2

0.4

0.6

0.8

1Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

48 - Tri(2-ethylhexyl) phosphate

+

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

2

4

6

8

0

0.02

0.04

0.06Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

49 - Atrazine

+ +

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

2

4

6

8

10

12

0

0.01

0.02

0.03Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

51 - Isoproturon

33

52

53

55

56

57

58

+ ++

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

2

4

6

8

10

0

0.05

0.1

0.15

0.2

0.25Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

52 - Terbuthylazin

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.1

0.2

0.3

0.4

0.5

0

0.01

0.02

0.03

0.04

0.05 Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

53 - Diazinon

+ ++

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.2

0.4

0.6

0.8

1

0

0.01

0.02

0.03

0.04

0.05 Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

55 - Metolachlor

++

+

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.05

0.1

0.15

0.2

0.25

0.3

0

0.2

0.4

0.6

0.8Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

56 - Chlorpyrifos

++

+ +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

2

0

0.05

0.1

Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

57 - Propiconazole

+ + +

D1

D2

D3

D4

D5

D6

D7

D8

D9

D10

D11

0

0.5

1

1.5

2

2.5

3

0

0.05

0.1

Amorphous OC

Pore water

CAS:0/f

AOC(m

g kg

1)

CW:0 (n

g L1)

58 - Tebuconazole

34

S13. Concentrations in surfacea and sediment poreb water a] Third Danube Survey 2013, Vukovar‐Belgrade stretch between D3 and D9, i.e. river kilometers 1297 and 1154, respectively.

b] Median of pore water concentrations over all locations (present study, Danube river (Serbia) 2012)

Pore‐water concentrations 2012a Danube survey 2013

percentile percentile passive Grab sampling

12.5% median 87.5% sampling median average

No Contaminant ng L‐1 ng L‐1 ng L‐1 ng L‐1 ng L‐1 ng L‐1

1 PCB 28 0.016 0.028 0.038 0.044 ‐ ‐

2 PCB 52 0.019 0.036 0.046 0.053 ‐ ‐

3 PCB 101 0.0074 0.0083 0.013 0.022 ‐ ‐

4 PCB 118 0.00093 0.0012 0.002 0.003 ‐ ‐

5 PCB 138 0.005 0.0098 0.014 0.019 ‐ ‐

6 PCB 153 0.0083 0.014 0.018 0.025 ‐ ‐

7 PCB 180 0.0021 0.0036 0.0048 0.005 ‐ ‐

8 Pentachlorobenzene 0.041 0.087 0.23 0.084 ‐ ‐

9 Hexachlorobenzene 0.052 0.096 0.18 0.041 ‐ ‐

10 2,4‐DDE 0.003 0.0045 0.0062 0.003 ‐ ‐

11 2,4‐DDD 0.035 0.062 0.12 0.051 ‐ ‐

12 4,4‐DDE 0.048 0.069 0.12 0.054 ‐ ‐

13 4,4‐DDD 0.071 0.19 0.39 0.049 ‐ ‐

14 Naphthalene 9.6 18 49 5.2 8.45 9.3

15 Biphenyl 1.1 4.3 9.2 1.2 ‐ ‐

16 Acenaphthylene 1.9 3.5 11 3.1 ‐ ‐

17 Acenaphthene 1.3 3.4 9.7 1.9 ‐ ‐

18 Fluorene 4.2 16 34 4.8 ‐ ‐

19 Phenanthrene 6.3 9.7 22 15 ‐ ‐

20 Anthracene 0.79 1.3 3 0.39 2.45 1.98

21 Fluoranthene 2.4 4.6 13 2.5 2.9 3.2

22 Pyrene 1.6 3 8.5 2.2 ‐ ‐

23 Benzo[b]fluorene 0.16 0.37 0.85 ‐ ‐ ‐

24 Benzo[ghi]fluoranthene 0.07 0.16 0.29 ‐ ‐ ‐

25 Benz[a]anthracene 0.13 0.44 0.87 0.091 ‐ ‐

26 Chrysene 0.11 0.29 0.54 0.14 ‐ ‐

27 Triphenylene 0.17 0.26 0.4 ‐ ‐ ‐

28 Retene 0.21 0.35 0.94 ‐ ‐ ‐

29 Benzo[b]fluoranthene 0.039 0.087 0.16 0.041 2.4 2.4

30 Benzo[k]fluoranthene 0.012 0.032 0.067 <0.023 ‐ ‐

31 Benzo[a]pyrene 0.0091 0.034 0.092 <0.046 2.3 2.3

32 Benzo[e]pyrene 0.056 0.097 0.19 0.044 ‐ ‐

33 Benzo[j]fluoranthene 0.029 0.06 0.11 0.015 ‐ ‐

34 Perylene 0.034 0.045 0.08 ‐ ‐ ‐

35 Benzo[ghi]perylene 0.011 0.021 0.035 <0.017 2 7.5

36 Dibenz[a,h]anthracene 0.0019 0.004 0.0078 <0.013 ‐ ‐

37 Indeno[1,2,3‐cd]pyrene 0.0077 0.018 0.031 <0.021 3.1 3.1

38 Coronene 0.0015 0.0027 0.0035 ‐ ‐ ‐

39 Benzo‐Naphtho‐Thiophene 0.034 0.082 0.16 ‐ ‐ ‐

35

Pore‐water concentrations 2012a Danube survey 2013

percentile percentile passive Grab sampling

12.5% median 87.5% sampling median average

No Contaminant ng L‐1 ng L‐1 ng L‐1 ng L‐1 ng L‐1 ng L‐1

40 Galaxolide (HHCB) 0.24 0.6 1.5 16 ‐ ‐

41 Tonalide (AHTN) 0.14 0.22 0.57 2 ‐ ‐

42 Cashmeran (DPMI) 0.28 0.49 0.89 0.43 ‐ ‐

43 Tris(1‐chloro‐2‐propyl) phosphate 8.7 12 51 22 81.5 160

44 Tris(1,3‐dichloro‐2‐propyl) phosphate 1.7 2.1 2.8 2.7 11 10.8

45 Triisobutylphosphate 0.064 0.3 0.87 44 21 20.25

46 Tri‐n‐butylphosphate 0.035 0.043 0.053 4 3.2 2.9

47 Triphenyl phosphate 0.023 0.069 0.091 0.43 ‐ ‐

48 Tri(2‐ethylhexyl) phosphate 0.0045 0.0083 0.011 <0.26 ‐ ‐

49 Atrazine 1.2 2.8 6 3.40 6.00 5.5

50 Chlortoluron 4.6 5.1 5.6 0.60 3.95 3.75

51 Isoproturon 3.4 5.4 7.7 0.44 0.85 4.02

52 Terbuthylazin 0.95 1.6 5.1 1.32 5.00 4.2

53 Diazinon 0.04 0.088 0.34 0.30 ‐ ‐

54 Carbendazim 2.1 3.8 5.2 0.02 5.80 4.8

55 Metolachlor 0.35 0.57 0.69 1.22 ‐ ‐

56 Chlorpyrifos 0.045 0.069 0.19 0.19 ‐ ‐

57 Propiconazole 0.63 1 2.4 2.79 ‐ ‐

58 Tebuconazole 0.94 1.2 3.2 2.46 ‐ ‐

36

S14. Concentrations in surface water versus pore‐water

Markers indicate: PCB, CBz, DDx; PAH; musks; OPFR and polar pesticides.

The solid line represents unity and the dotted lines confine a factor two higher and lower, which is about

equaling the average 75% inner quartile range (±~2) of the pore water concentrations over all stations. . Note

that the pH in water (Liška, et al., 2015) and sediment (S2) are all in the pH range where the reported polar

pesticides are neutral (S3B).

Marker colors and lines descriptions apply as in Figure S14A

Carbendazim

0.001

0.01

0.1

1

10

100

0.001 0.01 0.1 1 10 100

CW:W

(surface water) ng L‐1

CW:0 (porewater) ng L‐1

Freely dissolved in surface‐ versus in pore‐water

A

Carbendazim

0.001

0.01

0.1

1

10

100

0.001 0.01 0.1 1 10 100

CW:G(grab sampling) ng L‐1

CW:0 (porewater) ng L‐1

Grab sampling surface water versus pore‐water

Dominantly in the

dissolved phase

Dominantly in

the non‐ dissolved phase

B

37

S15. Ratio of CW in surface and pore water versus KOW

Markers indicate: PCB, CBz, DDx; PAH; musks; OPFR and polar pesticides. The solid line represents unity, and the dotted

lines represent a factor of two higher and lower, equaling the average 75% inner range (±~2) of the pore water concentrations over all

stations. Note that the pH in water (Liška, et al., 2015) and sediment (S2) are all in the pH range the reported polar pesticides are

neutral (S3B).

Marker colors and lines descriptions apply as in Figure S15A

Carbendazim

0.001

0.01

0.1

1

10

100

1000

1 2 3 4 5 6 7 8 9

Ratio

CW:W

and CW:0

Log KOW

Ratio freely dissolved in surface‐ and in pore‐water verusus log KOW

A

Carbendazim

0.001

0.01

0.1

1

10

100

1000

1 2 3 4 5 6 7 8 9

RatioCW:Gand CW:0

Log KOW

Ratio grab sampling and pore‐water versus log KOW

Dominantly in the non‐

dissolved phase

B

38

S16. Relationships of dissolved and AOC based concentration

In the left‐hand graph the freely dissolved concentration is plotted versus the releasable

concentration expressed on amorphous organic carbon (AOC) basis. The ratio (CAS/fAOC/CW:0)

equals the KAOC. In the right‐hand graph the logKAOC are plotted versus the AOC fraction (fAOC)

in the sediment. Error par represents sd. The dotted horizontal line indicates the weighted

average logKAOC across all locations, see S17. Numbers in the graph indicate location.

1

2

3

4

5

6

7

8

9

10

110

0.005

0.01

0.015

0.02

0.025

0 0.1 0.2 0.3 0.4 0.5

CW:0(ng L

‐1)

CAS/fAOC (mg kg‐1)

PCB 153

Y = 0.056(±0.0038) X , R2 = 0.96

1

2 34

5

67

8

910

11

6.5

7

7.5

8

8.5

0 0.001 0.002 0.003

KAOC( L kg

‐1)

fAOC

PCB 153

1

2345

6

7

8

10

110

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

0 10 20 30

CW:0(ng L

‐1)


Benzo[ghi]perylene

Y = 0.0064(±0.00083) X , R2 = 0.88

1

2

34

5

67

8 1011

7

7.5

8

8.5

9

0 0.001 0.002 0.003

KAOC( L kg

‐1)

fAOC

Benzo[ghi]perylene

1

23

4

5

6

7

8

9

10

11

0

0.5

1

1.5

2

2.5

0 0.5 1

CW:0(ng L

‐1)


Galaxolide (HHCB)

Y = 3.1(±0.37) X , R2 = 0.89

12

34

5

6 7

8 9

10

11

4.5

5

5.5

6

6.5

0 0.001 0.002 0.003

KAOC( L kg

‐1)

fAOC

Galaxolide (HHCB)

39

S17. LogKAOC, average, median and weighted average

No Compound n Avg Median s WAvgb sWAvg

1 PCB 28 11 6.23 6.30 0.18 6.25 0.12

2 PCB 52 11 6.28 6.28 0.09 6.28 0.06

3 PCB 101 11 6.73 6.75 0.20 6.71 0.09

4 PCB 118 11 7.02 7.03 0.22 7.03 0.11

5 PCB 138 11 7.34 7.28 0.17 7.28 0.07

6 PCB 153 11 7.26 7.23 0.15 7.20 0.07

7 PCB 180 11 7.79 7.72 0.21 7.71 0.07

8 Pentachlorobenzene 8 5.19 5.28 0.29 5.27 0.29

9 Hexachlorobenzene 11 6.04 6.01 0.28 5.91 0.17

10 2,4‐DDE 10 6.49 6.50 0.14 6.48 0.11

11 2,4‐DDD 10 6.45 6.42 0.17 6.35 0.17

12 4,4‐DDE 11 6.70 6.72 0.08 6.70 0.06

13 4,4‐DDD 11 6.49 6.47 0.21 6.41 0.17

14 Naphthalene 8 4.60 4.57 0.37 4.54 0.29

15 Biphenyl 9 5.09 5.02 0.33 5.23 0.24

16 Acenaphthylene 11 4.68 4.60 0.29 4.62 0.19

17 Acenaphthene 9 3.87 4.54 2.45 5.14 0.54

18 Fluorene 11 4.69 4.84 0.62 4.49 0.55

19 Phenanthrene 10 5.36 5.42 0.52 5.71 0.63

20 Anthracene 11 5.55 5.53 0.32 5.61 0.25

21 Fluoranthene 10 6.14 6.21 0.28 6.28 0.17

22 Pyrene 10 6.17 6.23 0.28 6.32 0.17

23 Benzo[b]fluorene 10 6.36 6.43 0.35 6.33 0.24

24 Benzo[ghi]fluoranthene 11 6.78 6.74 0.29 6.82 0.13

25 Benz[a]anthracene 10 7.05 7.05 0.17 7.19 0.12

26 Chrysene 10 7.05 7.01 0.24 7.31 0.22

27 Triphenylene 11 6.73 6.74 0.23 6.79 0.14

28 Retene 11 6.19 6.21 0.33 6.19 0.11

29 Benzo[b]fluoranthene 10 7.64 7.60 0.18 7.75 0.17

30 Benzo[k]fluoranthene 10 7.66 7.64 0.21 7.90 0.26

31 Benzo[a]pyrene 10 7.63 7.64 0.24 7.73 0.19

32 Benzo[e]pyrene 10 7.51 7.51 0.17 7.64 0.19

33 Benzo[j]fluoranthene 10 7.56 7.57 0.25 7.63 0.22

34 Perylene 10 7.87 7.89 0.33 8.05 0.31

35 Benzo[ghi]perylene 10 8.16 8.16 0.31 8.25 0.31

36 Dibenz[a,h]anthracene 10 8.13 8.09 0.21 8.31 0.23

37 Indeno[1,2,3‐cd]pyrene 10 8.20 8.20 0.37 8.27 0.26

38 Coronene 10 8.77 8.67 0.29 8.85 0.22

39 Benzo‐Naphtho‐Thiophene 10 6.91 6.88 0.21 7.11 0.20

40 Galaxolide (HHCB) 11 5.40 5.36 0.20 5.41 0.24

41 Tonalide (AHTN) 11 5.52 5.35 0.50 5.32 0.18

42 Cashmeran (DPMI) 9 6.11 5.89 0.60 5.85 0.38

43 Tris(1‐chloro‐2‐propyl) phosphate 9 4.68 4.81 0.61 4.42 0.59

44 Tris(1,3‐dichloro‐2‐propyl) phosphate 6 6.67 6.59 0.48 6.31 0.26

45 Triisobutylphosphate 7 5.72 5.81 0.74 5.80 0.39

46 Tri‐n‐butylphosphate 7 7.14 6.97 0.49 6.98 0.31

47 Triphenyl phosphate 5 5.90 5.69 0.62 5.62 0.48

48 Tri(2‐ethylhexyl) phosphate 6 7.72 7.67 0.23 7.73 0.17

49 Atrazine 3 3.78 3.83 0.22 3.89 0.14

50 Chlortoluron 1 3.58 3.58 ‐ 3.58 ‐

51 Isoproturon 5 3.45 3.39 0.18 3.35 0.09

52 Terbuthylazin 6 4.38 4.40 0.26 4.35 0.23

53 Diazinon 4 5.02 5.13 0.29 5.04 0.21

54 Carbendazim 2 4.37 4.37 0.05 4.39 0.02

55 Metolachlor 4 4.71 4.70 0.05 4.71 0.01

56 Chlorpyrifos 4 6.36 6.34 0.39 6.41 0.38

57 Propiconazole 5 4.78 4.87 0.24 4.67 0.23

58 Tebuconazole 6 4.45 4.56 0.29 4.40 0.19 b weighted average with 1/s2 as weighting factor

40

S18. LogKAOC plotted versus logKOW for all data

On the y‐axis the weighted average logKAOC (S11) was plotted versus the logKOW as listed in A‐C. Markers

indicate: PRC, PCB, CBz, DDx; PAH; musks; OPFR and polar pesticides. Note that for polar

pesticides logKOW and logKAOC could be applied without correction to a pH‐ specific logDOW and logDAOC as these

compounds all were in the neutral form (>99%, S3B) at the pH prevailing in the sediment (S2).

Carbendazim

1

2

3

4

5

6

7

8

9

1 2 3 4 5 6 7 8 9

log KAOC

log KOW

logKAOC versus logKOW

41

S19. Testing compliance with the WFD EQS for priority substances

Pore‐water concentrations (CW:0) of priority substances were compared with the annual average (AA) EQS (EU

WFD, 2013)† for total water (middle section of the table). The table shows both the average of all locations as

well as the 88% percentile.

Equilibrium passive sampler concentrations (CP:0) were converted to lipid based concentrations using lipid‐

polymer partition coefficients (Smedes, 2018)‡ which were subsequently expressed on tissue basis with 0.01 or

0.05 lipid fraction (flip), to represent mollusks or fish respectively (Deutsch, et al., 2014)§. These biota tissue

data are listed in the right–hand section of the table next to the corresponding Biota–EQS (EU WFD, 2013)1

Water AA . Biota

Nr Priority Average 88%perc.a EQS Average 88%perc. EQS flip b

substance ng L‐1 water µg kg‐1 tissue

2 Anthracene 1.7 3.0 100

3 Atrazine 3.4 6.0 600

9 ΣDDx 0.4 0.6 25

9 Chlorpyrifos 0.11 0.19 30

12 Tri(2‐ethylhexyl)phosphate 0.008 0.011 1300

15 Fluoranthene 6.0 c 13 c 6.3 34 71 30 0.01

16 Hexachlorobenzene 0.1 0.18 50 4.6 8.4 10 0.05

19 Isoproturon 5.5 7.7 300

22 Naphthalene 26 49 2000

26 Pentachlorobenzene 0.15 0.23 7

28 Benzo[a]pyrene 0.04 0.09 0.17 7 15 5 0.01

a) The 88% percentile equals the upper boundary of the 75% inner quartile, essentially representing the

second highest result.

b) For representing concentrations in mollusks (0.01) or fish (0.05) the passive sampling data were converted

using the listed tissue lipid fraction.

c) Light and dark gray shaded results were higher than half the EQS or exceeded the EQS, respectively.

† EU WFD, 2013. Directive 2013/39/EU of the European Parliament and of the Council of 12 August 2013 amending Directives 2000/60/EC and 2008/105/EC as regards priority substances in the field of water policy. Off. J. Eur Union. L226, 1‐17.

‡ Smedes, F., Rusina, T.P., Beeltje, H., Mayer, P., 2017. Partitioning of hydrophobic organic contaminants between polymer and lipids for two silicones and low density polyethylene. Chemosphere. 186, 948‐957.

§ Deutsch, K., Leroy, D., Belpaire, C., den Haan, K., Vrana, B., Clayton, H., Hanke, G., Ricci, M., Held, A., Gawlik, B., Babut, M., Perceval, O., Lepom, P., Heiss, C., Koschorreck, J., O’Toole, S., Valsecchi, S., Polesello, S., Carere, M., ten Hulscher, D., Verbruggen, E., Dulio, V., Green, N., Viñas, L., Bellas, J., Lilja, K., Bignert, A., Whitehouse, P., Sumner, K., Law, R., Brant, J., Leverett, D., Merrington, G., 2014. Guidance document no. 32 on biota monitoring (the implementation of EQS biota) under the water framework directive. Common implementation strategy for the Water Framework Directive (2000/60/EC). Technical Report ‐ 2014 ‐ 083.

42

S20. PCB concentrations measured in fish and derived from sediment passive sampling

The box and whisker plots below compare fish PCB data from (Janković, et al., 2011) (yellow) with passive

sampling results in sediment, converted to fish tissue (blue). The 2006 fish data from (Janković, et al., 2011)

included 10 species with data for a variable number of individuals. To avoid dominance of abundantly analyzed

species data from individuals were averaged per species. These averages were used to create the box and

wisker‐plots for fish (yellow) in the graph below. Due to absence of data on lipid fractions no lipid normalization

could be performed what may have caused some larger variation for fish tissue

Conversion of passive sampling data to fish tissue equivalents was done as indicated in S19 and section 3.9 but

using a lipid fraction of 0.02 as the average of typical values in the included fish species (Janković, et al., 2011).

The actual average lipid fraction, however, is not likely to be much different than 0.02. Further note that no

adjustments for trophic levels were made.

0.125

0.25

0.5

1

2

4

8

16

32

64

Cfishin ng g

‐1lipid

PCB 28 PCB 52 PCB 101 PCB 138 PCB 153 PCB 180

Min or max outlier

43

S21. Graphs of CW versus CAS with NLS results and CTot

On the following pages desorption isotherms from multi–ratio equilibrium passive sampling were provided. Each

page contains the isotherms for one contaminant and all locations. The results of nonlinear regression (NLS using

Eq. (6) are plotted as explained for Fig. 2 of the main manuscript. On the x-axis the concentration released by the

sediment, estimated from passive sampler uptake at equilibrium (CEXT), is plotted. The y-axis shows the freely

dissolved pore water concentration (CW) in the equilibration with the various sampler–sediment ratios. The

isotherm connects the original CW (CW:0) in unexposed sediment and the maximal releasable concentration (CAS:0)

as determined by NLS. The vertical line in the graph represents the total concentration in the sediment (CTOT).

Not for all contaminants CTOT exceeded the LOD. Concentrations of polar pesticides were not determined in total

sediment. Open circle markers indicate enhanced uncertainty connected to low yields of recovery internal

standards likely due to volatilization or degradation. Also a textline in the graph indicates to how many data points

that applies.

The below scheme further clarifies how to read the graphs.

CW:0CTot

0

0.6

1.2

1.8

2.4

0 60 120 180 240 300

Cw

ng L

-1

CEXT µg/kg

Pyreneat Ritopek (D9)

RSQ = 0.907

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Šangaj (D6)

RSQ = 0.928

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

PCB 101at Ritopek (D9)

RSQ = 0.978

Freely dissolved concentration determined by NLS CW:0

Tota l concentration in sediment us ing Soxhlet extraction

Isotherm; inverse of

sediment‐water partition coefficient

Line shows standard error

Releasable concentration ca lculated by NLS (CAS) with standard error

Non‐releasable fraction

Sediment capacity too low,large extrapolation,high standard error in CW:0

Data points scatter

NLS cannot optimizeto a sensible isotherm,CW:0 can s till be estimated

44

S21 – 1 PCB 28

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg

PCB 28at Apatin (D1)

RSQ = 0.950

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1CEXT µg/kg

PCB 28at Labudnjača (D2)

RSQ = 0.997

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

PCB 28at Neštin (D3)

RSQ = 0.997

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1

CEXT µg/kg

PCB 28at Begeč (D4)

RSQ = 0.991

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

PCB 28at Ratno Ostrvo (D5)

RSQ = 0.999

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0.03

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1CEXT µg/kg

PCB 28at Šangaj (D6)

RSQ = 0.950

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

PCB 28at Knićanin (D7)

RSQ = 0.999

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

PCB 28at Belegiš (D8)

RSQ = 0.995

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.974

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg

PCB 28at Dubravica (D10)

RSQ = 0.997

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 0.0008 0.0016 0.0024 0.0032 0.004

Cw

ng L

-1

CEXT µg/kg

PCB 28at Ram (D11)

RSQ = 0.970

45

S21 – 2 PCB 52

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg


RSQ = 1.000 CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.032 0.064 0.096 0.128 0.16

Cw

ng L

-1CEXT µg/kg


RSQ = 1.000

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999 CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1CEXT µg/kg


RSQ = 0.979

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg


RSQ = 1.000CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.994

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 1.000

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.0006 0.0012 0.0018 0.0024 0.003

Cw

ng L

-1

CEXT µg/kg

PCB 52at Ram (D11)

RSQ = 0.997

46

S21 – 3 PCB 101

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.977

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1CEXT µg/kg


RSQ = 1.000

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 1.000

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.978

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999CW:0

CAS

CTot

0

0.00012

0.00024

0.00036

0.00048

0.0006

0 0.0004 0.0008 0.0012 0.0016 0.002

Cw

ng L

-1

CEXT µg/kg

PCB 101at Ram (D11)

RSQ = 0.953

47

S21 – 4 PCB 118

CW:0

CAS

CTot

0

0.00024

0.00048

0.00072

0.00096

0.0012

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.929

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1CEXT µg/kg


RSQ = 1.000

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0.002

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.00028

0.00056

0.00084

0.00112

0.0014

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.0006

0.0012

0.0018

0.0024

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.979

CW:0

CAS

CTot

0

0.00028

0.00056

0.00084

0.00112

0.0014

0 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.00024

0.00048

0.00072

0.00096

0.0012

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0002

0.0004

0.0006

0.0008

0.001

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0.002

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.993

CW:0

CAS

CTot

0

0.0006

0.0012

0.0018

0.0024

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.000024

0.000048

0.000072

0.000096

0.00012

0 0.0004 0.0008 0.0012 0.0016 0.002

Cw

ng L

-1

CEXT µg/kg

PCB 118at Ram (D11)

RSQ = 0.992

48

S21 – 5 PCB 138

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.975

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.993

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.00006

0.00012

0.00018

0 0.001 0.002 0.003 0.004 0.005

Cw

ng L

-1

CEXT µg/kg

PCB 138at Ram (D11)

RSQ = 0.976

49

S21 – 6 PCB 153

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.006

0.012

0.018

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.975

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1CEXT µg/kg


RSQ = 0.937

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.991

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.00008

0.00016

0.00024

0.00032

0 0.0022 0.0044 0.0066 0.0088 0.011

Cw

ng L

-1

CEXT µg/kg

PCB 153at Ram (D11)

RSQ = 0.994

50

S21 – 7 PCB 180

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.998

CW:0

CAS

CTot

0

0.0006

0.0012

0.0018

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.995

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1CEXT µg/kg


RSQ = 0.963

CW:0

CAS

CTot

0

0.0006

0.0012

0.0018

0.0024

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997 CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.999CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.985

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg


RSQ = 0.997

CW:0

CAS

CTot

0

0.000006

0.000012

0.000018

0.000024

0 0.0008 0.0016 0.0024 0.0032 0.004

Cw

ng L

-1

CEXT µg/kg

PCB 180at Ram (D11)

RSQ = 0.792

51

S21 – 8 Pentachlorobenzene

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 0.01 0.02 0.03 0.04 0.05

Cw

ng

L-1

CEXT µg/kg

Pentachlorobenzeneat Apatin (D1)

RSQ = 0.796

CW:0

CAS

CTot

00 0.026 0.052 0.078 0.104 0.13

Cw

ng L

-1CEXT µg/kg

Pentachlorobenzeneat Labudnjača (D2)

RSQ = 0.359

3 point(s) (o) possiblyaf f ected by ev aporation

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Neštin (D3)

RSQ = 0.849

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Begeč (D4)

RSQ = 0.994

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.008 0.016 0.024 0.032 0.04

Cw

ng

L-1

CEXT µg/kg

Pentachlorobenzeneat Ratno Ostrv o (D5)

RSQ = 0.998


CAS

0

0.016

0.032

0.048

0.064

0.08

0 0.032 0.064 0.096 0.128 0.16C

wn

g L-1

CEXT µg/kg

Pentachlorobenzeneat Šangaj (D6)

RSQ = 0.508


CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Knićanin (D7)

RSQ = 0.965

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Belegiš (D8)

RSQ = 0.992

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.024 0.048 0.072 0.096 0.12

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Ritopek (D9)

RSQ = 0.985

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Dubravica (D10)

RSQ = 0.855CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.0016 0.0032 0.0048 0.0064 0.008

Cw

ng L

-1

CEXT µg/kg

Pentachlorobenzeneat Ram (D11)

RSQ = -2.578

52

S21 – 9 Hexachlorobenzene

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.03 0.06 0.09 0.12 0.15

Cw

ng

L-1

CEXT µg/kg

Hexachlorobenzeneat Apatin (D1)

RSQ = 0.532CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1CEXT µg/kg

Hexachlorobenzeneat Labudnjača (D2)

RSQ = 0.772


CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Neštin (D3)

RSQ = 0.987

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Begeč (D4)

RSQ = 0.994

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.032 0.064 0.096 0.128 0.16

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Ratno Ostrv o (D5)

RSQ = 0.998


CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.08 0.16 0.24 0.32 0.4C

wng

L-1

CEXT µg/kg

Hexachlorobenzeneat Šangaj (D6)

RSQ = 0.781


CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Knićanin (D7)

RSQ = 0.995

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Belegiš (D8)

RSQ = 0.964

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Ritopek (D9)

RSQ = 0.985

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Dubravica (D10)

RSQ = 0.945

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Hexachlorobenzeneat Ram (D11)

RSQ = 1.000

53

S21 – 10 2,4‐DDE

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.0022 0.0044 0.0066 0.0088 0.011

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Apatin (D1)

RSQ = 0.949CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg

2,4-DDEat Labudnjača (D2)

RSQ = 0.999 CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Neštin (D3)

RSQ = 0.999

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Begeč (D4)

RSQ = 0.999

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Ratno Ostrvo (D5)

RSQ = 1.000

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1CEXT µg/kg

2,4-DDEat Šangaj (D6)

RSQ = 0.970

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.024 0.048 0.072 0.096 0.12

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Knićanin (D7)

RSQ = 1.000

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.0022 0.0044 0.0066 0.0088 0.011

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Belegiš (D8)

RSQ = 1.000

0

0.0008

0.0016

0.0024

0.0032

0.004

0

Cw

:0ng

L-1

CEXT µg/kg

2,4-DDEat Ritopek (D9)

RSQ = 0.993

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Dubravica (D10)

RSQ = 0.996

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

2,4-DDEat Ram (D11)

Insufficient or no data

54

S21 – 11 2,4‐DDD

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Apatin (D1)

RSQ = 0.976

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1CEXT µg/kg

2,4-DDDat Labudnjača (D2)

RSQ = 1.000CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Neštin (D3)

RSQ = 0.963

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Begeč (D4)

RSQ = 0.672 CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.028 0.056 0.084 0.112 0.14

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Ratno Ostrvo (D5)

RSQ = 0.992

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1CEXT µg/kg

2,4-DDDat Šangaj (D6)

RSQ = 0.959

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Knićanin (D7)

RSQ = 0.896

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Belegiš (D8)

RSQ = 0.984CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Ritopek (D9)

RSQ = 0.947

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Dubravica (D10)

RSQ = 0.982

CW:0

CAS

CTot

0

40000

80000

120000

160000

0 0.0006 0.0012 0.0018 0.0024 0.003

Cw

ng L

-1

CEXT µg/kg

2,4-DDDat Ram (D11)

RSQ = 0.970

55

S21 – 12 4,4‐DDE

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Apatin (D1)

RSQ = 0.998

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1CEXT µg/kg

4,4-DDEat Labudnjača (D2)

RSQ = 0.999

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Neštin (D3)

RSQ = 0.996

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Begeč (D4)

RSQ = 0.999

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Ratno Ostrvo (D5)

RSQ = 1.000

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 0.28 0.56 0.84 1.12 1.4

Cw

ng L

-1CEXT µg/kg

4,4-DDEat Šangaj (D6)

RSQ = 0.997

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Knićanin (D7)

RSQ = 1.000

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Belegiš (D8)

RSQ = 1.000CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Ritopek (D9)

RSQ = 0.987

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Dubravica (D10)

RSQ = 0.998 CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.0026 0.0052 0.0078 0.0104 0.013

Cw

ng L

-1

CEXT µg/kg

4,4-DDEat Ram (D11)

RSQ = 0.910

56

S21 – 13 4,4‐DDD

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Apatin (D1)

RSQ = 0.290

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1CEXT µg/kg

4,4-DDDat Labudnjača (D2)

RSQ = 0.934

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Neštin (D3)

RSQ = 0.924

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Begeč (D4)

RSQ = 0.893

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Ratno Ostrvo (D5)

RSQ = 0.977CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1 2 3 4 5

Cw

ng L

-1CEXT µg/kg

4,4-DDDat Šangaj (D6)

RSQ = 0.767

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Knićanin (D7)

RSQ = 0.792

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Belegiš (D8)

RSQ = 0.835

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 0.32 0.64 0.96 1.28 1.6

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Ritopek (D9)

RSQ = 0.819

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Dubravica (D10)

RSQ = 0.659

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.0014 0.0028 0.0042 0.0056 0.007

Cw

ng L

-1

CEXT µg/kg

4,4-DDDat Ram (D11)

RSQ = 0.906

57

S21 – 14 Naphthalene

CW:0

CAS

CTot

0

48

96

144

192

0 0.8 1.6 2.4 3.2 4

Cw

ng

L-1

CEXT µg/kg

Naphthaleneat Apatin (D1)

RSQ = -10.697


CTot

0

8

16

24

32

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Naphthaleneat Labudnjača (D2)


2 point(s) (o) possiblyaffected by degradation

CW:0

CAS

CTot

0

6

12

18

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Neštin (D3)

RSQ = 0.915

CW:0

CAS

CTot

0

14

28

42

56

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Begeč (D4)

RSQ = 0.971

CW:0

CAS

CTot

0

8

16

24

32

40

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Ratno Ostrvo (D5)

RSQ = 0.719

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1C

wng

L-1

CEXT µg/kg

Naphthaleneat Šangaj (D6)



CW:0

CAS

CTot

0

2

4

6

8

10

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Knićanin (D7)

RSQ = 0.896

CW:0

CAS

CTot

0

12

24

36

48

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Belegiš (D8)

RSQ = 0.967

CW:0

CAS

CTot

0

4

8

12

16

0 3 6 9 12 15

Cw

ng

L-1

CEXT µg/kg

Naphthaleneat Ritopek (D9)

RSQ = 0.825


CW:0

CAS

CTot

0

2.2

4.4

6.6

8.8

11

0 1.4 2.8 4.2 5.6 7

Cw

ng

L-1

CEXT µg/kg

Naphthaleneat Dubrav ica (D10)

RSQ = 0.679


CW:0

CAS

CTot

0

4

8

12

16

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Naphthaleneat Ram (D11)

RSQ = 0.080

58

S21 – 15 Biphenyl

CW:0

CAS

CTot

0

2.6

5.2

7.8

10.4

0 0.32 0.64 0.96 1.28 1.6

Cw

ng

L-1

CEXT µg/kg

Bipheny lat Apatin (D1)

RSQ = -0.573


CTot

0

0.4

0.8

1.2

1.6

2

0 0.6 1.2 1.8 2.4 3

Cw

ng

L-1CEXT µg/kg

Bipheny lat Labudnjača (D2)

Insuf f icient or no data

CW:0

CAS

CTot

0

0.6

1.2

1.8

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Biphenylat Neštin (D3)

RSQ = 0.940

CW:0

CAS

CTot

0

1

2

3

4

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Biphenylat Begeč (D4)

RSQ = 0.996

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Biphenylat Ratno Ostrvo (D5)

RSQ = 0.863

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

2

0 0.6 1.2 1.8 2.4 3C

wng

L-1

CEXT µg/kg

Bipheny lat Šangaj (D6)

Inconsistent?3 point(s) (o) possiblyaf f ected by ev aporation

CW:0

CAS

CTot

0

0.28

0.56

0.84

1.12

1.4

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Biphenylat Knićanin (D7)

RSQ = 0.909

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

6

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg

Biphenylat Belegiš (D8)

RSQ = 0.891

CW:0

CAS

CTot

0

0.28

0.56

0.84

1.12

1.4

0 1 2 3 4 5

Cw

ng

L-1

CEXT µg/kg

Bipheny lat Ritopek (D9)

RSQ = 0.981


CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Bipheny lat Dubrav ica (D10)

RSQ = 0.843


CW:0

CAS

CTot

0

2.2

4.4

6.6

8.8

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Biphenylat Ram (D11)

RSQ = 0.914

59

S21 – 16 Acenaphthylene

CW:0

CAS

CTot

0

3

6

9

12

0 0.3 0.6 0.9 1.2 1.5

Cw

ng

L-1

CEXT µg/kg

Acenaphthy leneat Apatin (D1)

RSQ = 0.948


CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 2.8 5.6 8.4 11.2 14

Cw

ng L

-1CEXT µg/kg

Acenaphthyleneat Neštin (D3)

RSQ = 0.812

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Begeč (D4)

RSQ = 0.960

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

4

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Ratno Ostrvo (D5)

RSQ = 0.996 CW:0

CAS

CTot

0

1

2

3

4

5

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Acenaphthy leneat Šangaj (D6)

RSQ = 0.563


CW:0

CAS

CTot

0

0.6

1.2

1.8

2.4

3

0 0.8 1.6 2.4 3.2 4C

wng

L-1

CEXT µg/kg

Acenaphthyleneat Knićanin (D7)

RSQ = 0.976

CW:0

CAS

CTot

0

3

6

9

12

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Belegiš (D8)

RSQ = 0.970

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Ritopek (D9)

RSQ = 0.897

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

2

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Dubravica (D10)

RSQ = 0.986

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Acenaphthyleneat Ram (D11)

RSQ = 0.413

60

S21 – 17 Acenaphthene

CW:0

CAS

CTot

0

8

16

24

32

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Apatin (D1)

RSQ = -0.097


CTot

0

0.8

1.6

2.4

3.2

0 0.4 0.8 1.2 1.6 2

Cw

ng

L-1CEXT µg/kg

Acenaphtheneat Labudnjača (D2)

Insuf f icient or no data

CW:0

CAS

CTot

0

2

4

6

8

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Neštin (D3)

RSQ = 0.458

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Begeč (D4)

RSQ = 0.875

CW:0

CAS

CTot

0

2

4

6

8

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Ratno Ostrvo (D5)

RSQ = 0.988

CTot

0

0.8

1.6

2.4

3.2

0 0.6 1.2 1.8 2.4 3C

w:0

ng L

-1

CEXT µg/kg

Acenaphtheneat Šangaj (D6)

No NLS solution possible

CW:0

CAS

CTot

0

0.28

0.56

0.84

1.12

1.4

0 0.32 0.64 0.96 1.28 1.6

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Knićanin (D7)

RSQ = 0.935

CW:0

CAS

CTot

0

2.2

4.4

6.6

8.8

0 0.24 0.48 0.72 0.96 1.2

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Belegiš (D8)

RSQ = 0.994

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Ritopek (D9)

RSQ = 0.995

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 0.24 0.48 0.72 0.96 1.2

Cw

ng L

-1

CEXT µg/kg

Acenaphtheneat Dubravica (D10)

RSQ = 0.689

0

0.2

0.4

0.6

0.8

1

0

Cw

:0ng

L-1

CEXT µg/kg

Acenaphtheneat Ram (D11)

No NLS solution possible

61

S21 – 18 Fluorene

CW:0

CAS

CTot

0

8

16

24

32

0 1 2 3 4 5

Cw

ng

L-1

CEXT µg/kg

Fluoreneat Apatin (D1)

RSQ = 0.628


CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 0.8 1.6 2.4 3.2 4

Cw

ng

L-1

CEXT µg/kg

Fluoreneat Labudnjača (D2)

RSQ = 0.469


CW:0

CAS

CTot

0

4

8

12

16

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Neštin (D3)

RSQ = 0.782

CW:0

CAS

CTot

0

2.4

4.8

7.2

9.6

12

0 0.32 0.64 0.96 1.28 1.6

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Begeč (D4)

RSQ = 0.952

0

6

12

18

0 1 2 3

Cw

:0n

g L-1

CEXT µg/kg

Fluoreneat Ratno Ostrv o (D5)

RSQ = 0.083

CW:0

CAS

CTot

0

10

20

30

40

0 0.6 1.2 1.8 2.4 3C

wn

g L

-1

CEXT µg/kg

Fluoreneat Šangaj (D6)

RSQ = 0.970


CW:0

CAS

CTot

0

4

8

12

16

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Knićanin (D7)

RSQ = 0.899

CW:0

CAS

CTot

0

8

16

24

32

40

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Belegiš (D8)

RSQ = 0.162

CW:0

CAS

CTot

0

1

2

3

4

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Ritopek (D9)

RSQ = 0.699

CW:0

CAS

CTot

0

0.6

1.2

1.8

2.4

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Dubravica (D10)

RSQ = 0.698CW:0

CTot

0

1.4

2.8

4.2

5.6

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Fluoreneat Ram (D11)

RSQ = -0.417

62

S21 – 19 Phenanthrene

CW:0

CAS

CTot

0

6

12

18

24

0 6 12 18 24 30

Cw

ng

L-1

CEXT µg/kg

Phenanthreneat Apatin (D1)

RSQ = 0.553


CW:0

CAS

CTot

0

1.6

3.2

4.8

6.4

0 6 12 18 24 30

Cw

ng

L-1

CEXT µg/kg

Phenanthreneat Labudnjača (D2)

RSQ = 0.869


CW:0

CAS

CTot

0

4

8

12

16

0 40 80 120 160 200

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Neštin (D3)

RSQ = 0.758

CW:0

CAS

CTot

0

2.2

4.4

6.6

8.8

0 3.2 6.4 9.6 12.8 16

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Begeč (D4)

RSQ = 0.743

0

2.2

4.4

6.6

8.8

0 0.4 0.8 1.2 1.6 2

Cw

:0n

g L-1

CEXT µg/kg

Phenanthreneat Ratno Ostrv o (D5)

RSQ = 1.000

CW:0

CAS

CTot

0

1.8

3.6

5.4

7.2

0 6 12 18 24 30C

wn

g L

-1

CEXT µg/kg

Phenanthreneat Šangaj (D6)

RSQ = 0.964


CW:0

CAS

CTot

0

2.8

5.6

8.4

11.2

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Knićanin (D7)

RSQ = 0.839

CW:0

CAS

CTot

0

12

24

36

48

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Belegiš (D8)

RSQ = 0.645

CW:0

CAS

CTot

0

1.4

2.8

4.2

5.6

0 40 80 120 160 200

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Ritopek (D9)

RSQ = 0.997

CW:0

CAS

CTot

0

2.2

4.4

6.6

8.8

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Dubravica (D10)

RSQ = -0.201 CW:0

CAS

CTot

0

1.8

3.6

5.4

7.2

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Phenanthreneat Ram (D11)

RSQ = -1.993

63

S21 – 20 Anthracene

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 1 2 3 4 5

Cw

ng

L-1

CEXT µg/kg

Anthraceneat Apatin (D1)

RSQ = 0.901


CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

2

0 1.4 2.8 4.2 5.6 7

Cw

ng

L-1

CEXT µg/kg

Anthraceneat Labudnjača (D2)

RSQ = 0.817


CW:0

CAS

CTot

0

0.6

1.2

1.8

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Neštin (D3)

RSQ = 0.813

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Begeč (D4)

RSQ = 0.960

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Ratno Ostrvo (D5)

RSQ = 0.852

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 1.2 2.4 3.6 4.8 6C

wn

g L

-1

CEXT µg/kg

Anthraceneat Šangaj (D6)

RSQ = 0.976


CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Knićanin (D7)

RSQ = 0.960

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Belegiš (D8)

RSQ = 0.958

CW:0

CAS

CTot

0

0.28

0.56

0.84

1.12

1.4

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Ritopek (D9)

RSQ = 0.918

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Dubravica (D10)

RSQ = 0.962

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Anthraceneat Ram (D11)

RSQ = 0.776

64

S21 – 21 Fluoranthene

CW:0

CAS

CTot

0

4

8

12

16

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Apatin (D1)

RSQ = 0.940

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 14 28 42 56 70

Cw

ng L

-1CEXT µg/kg

Fluorantheneat Labudnjača (D2)

RSQ = 0.985

CW:0

CAS

CTot

0

1.4

2.8

4.2

5.6

0 80 160 240 320 400

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Neštin (D3)

RSQ = 0.359

CW:0

CAS

CTot

0

1

2

3

4

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Begeč (D4)

RSQ = 0.592

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Ratno Ostrvo (D5)

RSQ = 0.356

CW:0

CAS

CTot

0

1

2

3

4

5

0 14 28 42 56 70

Cw

ng L

-1CEXT µg/kg

Fluorantheneat Šangaj (D6)

RSQ = 0.878

CW:0

CAS

CTot

0

0.6

1.2

1.8

2.4

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Knićanin (D7)

RSQ = 0.993

CW:0

CAS

CTot

0

4

8

12

16

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Belegiš (D8)

RSQ = 0.937

CW:0 CTot

0

0.8

1.6

2.4

3.2

0 80 160 240 320 400

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Ritopek (D9)

RSQ = 0.912

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Dubravica (D10)

RSQ = 0.919

CW:0

CAS

CTot

0

1.2

2.4

3.6

4.8

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Fluorantheneat Ram (D11)

RSQ = 0.952

65

S21 – 22 Pyrene

CW:0

CAS

CTot

0

2.4

4.8

7.2

9.6

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Pyreneat Apatin (D1)

RSQ = 0.936

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 12 24 36 48 60

Cw

ng L

-1CEXT µg/kg

Pyreneat Labudnjača (D2)

RSQ = 0.987

CW:0

CAS

CTot

0

1

2

3

4

0 80 160 240 320 400

Cw

ng L

-1

CEXT µg/kg

Pyreneat Neštin (D3)

RSQ = 0.278

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Pyreneat Begeč (D4)

RSQ = 0.586

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 3.2 6.4 9.6 12.8 16

Cw

ng L

-1

CEXT µg/kg

Pyreneat Ratno Ostrvo (D5)

RSQ = 0.575

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 12 24 36 48 60

Cw

ng L

-1CEXT µg/kg

Pyreneat Šangaj (D6)

RSQ = 0.896

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Pyreneat Knićanin (D7)

RSQ = 0.991

CW:0

CAS

CTot

0

2.4

4.8

7.2

9.6

12

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Pyreneat Belegiš (D8)

RSQ = 0.952CW:0

CTot

0

0.6

1.2

1.8

2.4

0 60 120 180 240 300

Cw

ng L

-1

CEXT µg/kg

Pyreneat Ritopek (D9)

RSQ = 0.907

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Pyreneat Dubravica (D10)

RSQ = 0.979

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

4

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Pyreneat Ram (D11)

RSQ = 0.972

66

S21 – 23 Benzo[b]fluorene

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Apatin (D1)

RSQ = 0.898CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1.6 3.2 4.8 6.4 8

Cw

ng L

-1CEXT µg/kg

Benzo[b]fluoreneat Labudnjača (D2)

RSQ = 0.749 CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Neštin (D3)

RSQ = 0.180

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0.3

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Begeč (D4)

RSQ = 0.652

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Ratno Ostrvo (D5)

RSQ = 0.680CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1.6 3.2 4.8 6.4 8

Cw

ng L

-1CEXT µg/kg

Benzo[b]fluoreneat Šangaj (D6)

RSQ = 0.355

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Knićanin (D7)

RSQ = 0.971

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Belegiš (D8)

RSQ = 0.915CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Ritopek (D9)

RSQ = 0.738

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Dubravica (D10)

RSQ = 0.260

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluoreneat Ram (D11)

RSQ = 0.990

67

S21 – 24 Benzo[ghi]fluoranthene

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Apatin (D1)

RSQ = 0.930

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Benzo[ghi]fluorantheneat Labudnjača (D2)

RSQ = 0.992

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Neštin (D3)

RSQ = 0.871

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Begeč (D4)

RSQ = 0.871

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Ratno Ostrvo (D5)

RSQ = 0.834

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Benzo[ghi]fluorantheneat Šangaj (D6)

RSQ = 0.941

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Knićanin (D7)

RSQ = 0.942 CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Belegiš (D8)

RSQ = 0.969

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Ritopek (D9)

RSQ = 0.854

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Dubravica (D10)

RSQ = 0.990

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]fluorantheneat Ram (D11)

RSQ = 0.970

68

S21 – 25 Benz[a]anthracene

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Apatin (D1)

RSQ = 0.829

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 12 24 36 48 60

Cw

ng L

-1CEXT µg/kg

Benz[a]anthraceneat Labudnjača (D2)

RSQ = 0.962

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 60 120 180 240 300

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Neštin (D3)

RSQ = -0.050

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Begeč (D4)

RSQ = 0.575

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0.3

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Ratno Ostrvo (D5)

RSQ = 0.531CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 12 24 36 48 60

Cw

ng L

-1CEXT µg/kg

Benz[a]anthraceneat Šangaj (D6)

RSQ = 0.984

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Knićanin (D7)

RSQ = 0.853

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Belegiš (D8)

RSQ = 0.892

CW:0CTot

0

0.08

0.16

0.24

0.32

0.4

0 60 120 180 240 300

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Ritopek (D9)

RSQ = 0.828

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Dubravica (D10)

RSQ = 0.614

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Benz[a]anthraceneat Ram (D11)

RSQ = 0.916

69

S21 – 26 Chrysene

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 2.8 5.6 8.4 11.2 14

Cw

ng L

-1

CEXT µg/kg

Chryseneat Apatin (D1)

RSQ = 0.927CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Chryseneat Labudnjača (D2)

RSQ = 0.984

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 24 48 72 96 120

Cw

ng L

-1

CEXT µg/kg

Chryseneat Neštin (D3)

RSQ = 0.440

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Chryseneat Begeč (D4)

RSQ = 0.669

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Chryseneat Ratno Ostrvo (D5)

RSQ = 0.732

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Chryseneat Šangaj (D6)

RSQ = 0.990

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Chryseneat Knićanin (D7)

RSQ = 0.871

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Chryseneat Belegiš (D8)

RSQ = 0.920

CW:0 CTot

0

0.06

0.12

0.18

0.24

0 24 48 72 96 120

Cw

ng L

-1

CEXT µg/kg

Chryseneat Ritopek (D9)

RSQ = 0.893

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Chryseneat Dubravica (D10)

RSQ = 0.689

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 0.24 0.48 0.72 0.96 1.2

Cw

ng L

-1

CEXT µg/kg

Chryseneat Ram (D11)

RSQ = 0.924

70

S21 – 27 Triphenylene

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Apatin (D1)

RSQ = 0.949

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0.3

0 2 4 6 8 10

Cw

ng L

-1CEXT µg/kg

Triphenyleneat Labudnjača (D2)

RSQ = 0.992

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Neštin (D3)

RSQ = 0.874

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Begeč (D4)

RSQ = 0.918

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Ratno Ostrvo (D5)

RSQ = 0.881CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 2.4 4.8 7.2 9.6 12

Cw

ng L

-1CEXT µg/kg

Triphenyleneat Šangaj (D6)

RSQ = 0.920

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 2 4 6 8 10

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Knićanin (D7)

RSQ = 0.909

CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Belegiš (D8)

RSQ = 0.988

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Ritopek (D9)

RSQ = 0.847

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Dubravica (D10)

RSQ = 0.914

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Triphenyleneat Ram (D11)

RSQ = 0.971

71

S21 – 28 Retene

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Reteneat Apatin (D1)

RSQ = 0.999 CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1CEXT µg/kg

Reteneat Labudnjača (D2)

RSQ = 0.984

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Reteneat Neštin (D3)

RSQ = 0.995

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Reteneat Begeč (D4)

RSQ = 0.996

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Reteneat Ratno Ostrvo (D5)

RSQ = 0.902

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 2 4 6 8 10

Cw

ng L

-1CEXT µg/kg

Reteneat Šangaj (D6)

RSQ = 0.962

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Reteneat Knićanin (D7)

RSQ = 0.999

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Reteneat Belegiš (D8)

RSQ = 0.990

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Reteneat Ritopek (D9)

RSQ = 0.717

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Reteneat Dubravica (D10)

RSQ = 0.979

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

Reteneat Ram (D11)

RSQ = 0.509

72

S21 – 29 Benzo[b]fluoranthene

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Apatin (D1)

RSQ = 0.935

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Benzo[b]fluorantheneat Labudnjača (D2)

RSQ = 0.978

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 28 56 84 112 140

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Neštin (D3)

RSQ = 0.763

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Begeč (D4)

RSQ = 0.903

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 2 4 6 8 10

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Ratno Ostrvo (D5)

RSQ = 0.824

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 10 20 30 40 50

Cw

ng L

-1CEXT µg/kg

Benzo[b]fluorantheneat Šangaj (D6)

RSQ = 0.987

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Knićanin (D7)

RSQ = 0.905

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Belegiš (D8)

RSQ = 0.878

CW:0 CTot

0

0.016

0.032

0.048

0.064

0.08

0 26 52 78 104 130

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Ritopek (D9)

RSQ = 0.919

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Dubravica (D10)

RSQ = 0.754

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

Benzo[b]fluorantheneat Ram (D11)

RSQ = 0.618

73

S21 – 30 Benzo[k]fluoranthene

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Apatin (D1)

RSQ = 0.959

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 3.2 6.4 9.6 12.8 16

Cw

ng L

-1CEXT µg/kg

Benzo[k]fluorantheneat Labudnjača (D2)

RSQ = 0.997

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Neštin (D3)

RSQ = 0.665

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Begeč (D4)

RSQ = 0.808

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Ratno Ostrvo (D5)

RSQ = 0.737

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 4 8 12 16 20

Cw

ng L

-1CEXT µg/kg

Benzo[k]fluorantheneat Šangaj (D6)

RSQ = 0.891

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Knićanin (D7)

RSQ = 0.852

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Belegiš (D8)

RSQ = 0.924

CW:0

CTot

0

0.006

0.012

0.018

0.024

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Ritopek (D9)

RSQ = 0.875

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Dubravica (D10)

RSQ = 0.752

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Benzo[k]fluorantheneat Ram (D11)

RSQ = 0.839

74

S21 – 31 Benzo[a]pyrene

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Apatin (D1)

RSQ = 0.812


CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Benzo[a]pyreneat Labudnjača (D2)

RSQ = 0.951 CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 22 44 66 88 110

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Neštin (D3)

RSQ = 0.167

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Begeč (D4)

RSQ = 0.739

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0.03

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Ratno Ostrvo (D5)

RSQ = 0.489

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Benzo[a]pyreneat Šangaj (D6)

RSQ = 0.967

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Knićanin (D7)

RSQ = 0.900

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Belegiš (D8)

RSQ = 0.859

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 24 48 72 96 120

Cw

ng

L-1

CEXT µg/kg

Benzo[a]py reneat Ritopek (D9)

RSQ = -5.418

1 point(s) (o) possiblyaf f ected by degradation

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 2 4 6 8 10

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Dubravica (D10)

RSQ = -0.121


CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Benzo[a]pyreneat Ram (D11)

RSQ = 0.024


75

S21 – 32 Benzo[e]pyrene

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Apatin (D1)

RSQ = 0.959

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Benzo[e]pyreneat Labudnjača (D2)

RSQ = 0.988

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 24 48 72 96 120

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Neštin (D3)

RSQ = 0.817

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Begeč (D4)

RSQ = 0.879CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Ratno Ostrvo (D5)

RSQ = 0.808

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Benzo[e]pyreneat Šangaj (D6)

RSQ = 0.898

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Knićanin (D7)

RSQ = 0.858

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Belegiš (D8)

RSQ = 0.957CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 24 48 72 96 120

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Ritopek (D9)

RSQ = 0.941

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Dubravica (D10)

RSQ = 0.850

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0.03

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Benzo[e]pyreneat Ram (D11)

RSQ = 0.824

76

S21 – 33 Benzo[j]fluoranthene

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Apatin (D1)

RSQ = 0.943CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Benzo[j]fluorantheneat Labudnjača (D2)

RSQ = 0.961

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 16 32 48 64 80

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Neštin (D3)

RSQ = 0.934

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Begeč (D4)

RSQ = 0.968

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Ratno Ostrvo (D5)

RSQ = 0.810

CW:0

CAS

CTot

0

0.024

0.048

0.072

0.096

0.12

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Benzo[j]fluorantheneat Šangaj (D6)

RSQ = 0.841

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Knićanin (D7)

RSQ = 0.678

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Belegiš (D8)

RSQ = 0.955CW:0

CTot

0

0.012

0.024

0.036

0.048

0.06

0 12 24 36 48 60

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Ritopek (D9)

RSQ = 0.934

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Dubravica (D10)

RSQ = 0.806

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Benzo[j]fluorantheneat Ram (D11)

RSQ = 0.787

77

S21 – 34 Perylene

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Peryleneat Apatin (D1)

RSQ = 0.748


CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Peryleneat Labudnjača (D2)

RSQ = 0.995 CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Peryleneat Neštin (D3)

RSQ = 0.928

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 2.2 4.4 6.6 8.8 11

Cw

ng L

-1

CEXT µg/kg

Peryleneat Begeč (D4)

RSQ = 0.923

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Peryleneat Ratno Ostrvo (D5)

RSQ = 0.771

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 4 8 12 16 20

Cw

ng L

-1CEXT µg/kg

Peryleneat Šangaj (D6)

RSQ = 0.975

CW:0

CAS

CTot

0

0.028

0.056

0.084

0.112

0.14

0 14 28 42 56 70

Cw

ng L

-1

CEXT µg/kg

Peryleneat Knićanin (D7)

RSQ = 0.928

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Peryleneat Belegiš (D8)

RSQ = 0.920CW:0

CTot

0

0.012

0.024

0.036

0.048

0.06

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Peryleneat Ritopek (D9)

RSQ = 0.961


CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Peryleneat Dubravica (D10)

RSQ = 0.825


CW:0

CAS

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1

CEXT µg/kg

Peryleneat Ram (D11)

RSQ = 0.629


78

S21 – 35 Benzo[ghi]perylene

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 2.4 4.8 7.2 9.6 12

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Apatin (D1)

RSQ = 0.948

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Benzo[ghi]peryleneat Labudnjača (D2)

RSQ = 0.993

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 26 52 78 104 130

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Neštin (D3)

RSQ = 0.855

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Begeč (D4)

RSQ = 0.850

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0.02

0 1.6 3.2 4.8 6.4 8

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Ratno Ostrvo (D5)

RSQ = 0.811

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0.03

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Benzo[ghi]peryleneat Šangaj (D6)

RSQ = 0.920

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Knićanin (D7)

RSQ = 0.848 CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Belegiš (D8)

RSQ = 0.931

CW:0CTot

0

0.004

0.008

0.012

0.016

0.02

0 22 44 66 88 110

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Ritopek (D9)

RSQ = 0.958

CW:0

CAS

CTot

0

0.0024

0.0048

0.0072

0.0096

0.012

0 3 6 9 12 15

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Dubravica (D10)

RSQ = 0.573

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Benzo[ghi]peryleneat Ram (D11)

RSQ = 0.254

79

S21 – 36 Dibenz[a,h]anthracene

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Apatin (D1)

RSQ = 0.888 CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Dibenz[a,h]anthraceneat Labudnjača (D2)

RSQ = 0.980

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Neštin (D3)

RSQ = 0.577

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Begeč (D4)

RSQ = 0.571 CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Ratno Ostrvo (D5)

RSQ = 0.678

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1CEXT µg/kg

Dibenz[a,h]anthraceneat Šangaj (D6)

RSQ = 0.877

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0 1.6 3.2 4.8 6.4 8

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Knićanin (D7)

RSQ = 0.517

CW:0

CAS

CTot

0

0.002

0.004

0.006

0.008

0.01

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Belegiš (D8)

RSQ = 0.770

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Ritopek (D9)

RSQ = 0.884

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0.002

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Dubravica (D10)

RSQ = 0.409CW:0

CAS

0

0.00012

0.00024

0.00036

0.00048

0.0006

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1

CEXT µg/kg

Dibenz[a,h]anthraceneat Ram (D11)

RSQ = 0.184

80

S21 – 37 Indeno[1,2,3‐cd]pyrene

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Apatin (D1)

RSQ = 0.947

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 10 20 30 40 50

Cw

ng L

-1CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Labudnjača (D2)

RSQ = 0.989

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 28 56 84 112 140

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Neštin (D3)

RSQ = 0.857

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Begeč (D4)

RSQ = 0.930

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Ratno Ostrvo (D5)

RSQ = 0.705

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 8 16 24 32 40

Cw

ng L

-1CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Šangaj (D6)

RSQ = 0.920

CW:0

CAS

CTot

0

0.0028

0.0056

0.0084

0.0112

0.014

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Knićanin (D7)

RSQ = 0.917

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0.04

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Belegiš (D8)

RSQ = 0.878

CW:0CTot

0

0.004

0.008

0.012

0.016

0 26 52 78 104 130

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Ritopek (D9)

RSQ = 0.936

CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 3.2 6.4 9.6 12.8 16

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Dubravica (D10)

RSQ = 0.511CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Indeno[1,2,3-cd]pyreneat Ram (D11)

RSQ = 0.923

81

S21 – 38 Coronene

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Coroneneat Apatin (D1)

RSQ = 0.921

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Coroneneat Labudnjača (D2)

RSQ = 0.991

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 20 40 60 80 100

Cw

ng L

-1

CEXT µg/kg

Coroneneat Neštin (D3)

RSQ = 0.888

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Coroneneat Begeč (D4)

RSQ = 0.667

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0.002

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Coroneneat Ratno Ostrvo (D5)

RSQ = 0.739 CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0.004

0 6 12 18 24 30

Cw

ng L

-1CEXT µg/kg

Coroneneat Šangaj (D6)

RSQ = 0.928

CW:0

CAS

CTot

0

0.0006

0.0012

0.0018

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Coroneneat Knićanin (D7)

RSQ = 0.690

CW:0

CAS

CTot

0

0.0008

0.0016

0.0024

0.0032

0 2.4 4.8 7.2 9.6 12

Cw

ng L

-1

CEXT µg/kg

Coroneneat Belegiš (D8)

RSQ = 0.860

CW:0

CAS

CTot

0

0.0004

0.0008

0.0012

0.0016

0 16 32 48 64 80

Cw

ng L

-1

CEXT µg/kg

Coroneneat Ritopek (D9)

RSQ = 0.951

CW:0

CAS

CTot

0

0.0002

0.0004

0.0006

0.0008

0.001

0 2.6 5.2 7.8 10.4 13

Cw

ng L

-1

CEXT µg/kg

Coroneneat Dubravica (D10)

RSQ = 0.420

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Coroneneat Ram (D11)


82

S21 – 39 Benzo‐Naphtho‐Thiophene

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Apatin (D1)

RSQ = 0.908

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1CEXT µg/kg

Benzo-Naphtho-Thiopheneat Labudnjača (D2)

RSQ = 0.982

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 6 12 18 24 30

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Neštin (D3)

RSQ = 0.205

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Begeč (D4)

RSQ = 0.705

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Ratno Ostrvo (D5)

RSQ = 0.805

CW:0

CAS

CTot

0

0.02

0.04

0.06

0.08

0.1

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Benzo-Naphtho-Thiopheneat Šangaj (D6)

RSQ = 0.978

CW:0

CAS

CTot

0

0.012

0.024

0.036

0.048

0.06

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Knićanin (D7)

RSQ = 0.936

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 1.2 2.4 3.6 4.8 6

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Belegiš (D8)

RSQ = 0.932

CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Ritopek (D9)

RSQ = 0.866

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Dubravica (D10)

RSQ = 0.727

CW:0

CAS

CTot

0

0.008

0.016

0.024

0.032

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Benzo-Naphtho-Thiopheneat Ram (D11)

RSQ = 0.857

83

S21 – 40 Galaxolide (HHCB)

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Apatin (D1)

RSQ = 0.990

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg

Galaxolide (HHCB)at Labudnjača (D2)

RSQ = 0.973

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Neštin (D3)

RSQ = 0.911

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Begeč (D4)

RSQ = 0.917

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0.4

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Ratno Ostrvo (D5)

RSQ = 0.863CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1CEXT µg/kg

Galaxolide (HHCB)at Šangaj (D6)

RSQ = 0.928

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Knićanin (D7)

RSQ = 0.982

CW:0

CAS

CTot

0

0.4

0.8

1.2

1.6

2

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Belegiš (D8)

RSQ = 0.979

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Ritopek (D9)

RSQ = 0.795

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Dubravica (D10)

RSQ = 0.985

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg

Galaxolide (HHCB)at Ram (D11)

RSQ = 0.977

84

S21 – 41 Tonalide (AHTN)

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Apatin (D1)

RSQ = 0.966

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1CEXT µg/kg

Tonalide (AHTN)at Labudnjača (D2)

RSQ = 0.961

CW:0

CAS

CTot

0

0.06

0.12

0.18

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Neštin (D3)

RSQ = 0.999

CW:0

CAS

CTot

0

0.08

0.16

0.24

0.32

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Begeč (D4)

RSQ = 0.999

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0.2

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Ratno Ostrvo (D5)

RSQ = 0.993CW:0

CAS

CTot

0

0.12

0.24

0.36

0.48

0.6

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg

Tonalide (AHTN)at Šangaj (D6)

RSQ = 1.000

CW:0

CAS

CTot

0

0.04

0.08

0.12

0.16

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Knićanin (D7)

RSQ = 0.995

CW:0

CAS

CTot

0

0.8

1.6

2.4

3.2

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Belegiš (D8)

RSQ = 0.999

CW:0

CAS

CTot

0

0.06

0.12

0.18

0.24

0.3

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Ritopek (D9)

RSQ = 0.994

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Dubravica (D10)

RSQ = 1.000

CW:0

CAS

CTot

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1

CEXT µg/kg

Tonalide (AHTN)at Ram (D11)

RSQ = 0.997

85

S21 – 42 Cashmeran (DPMI)

CW:0

CAS

0

0.6

1.2

1.8

2.4

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Apatin (D1)

RSQ = 0.788CW:0

CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.32 0.64 0.96 1.28 1.6

Cw

ng L

-1CEXT µg/kg

Cashmeran (DPMI)at Labudnjača (D2)

RSQ = 0.832CW:0

CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Neštin (D3)

RSQ = 0.916

CW:0

CAS

0

0.2

0.4

0.6

0.8

1

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Begeč (D4)

RSQ = -1.177

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Ratno Ostrvo (D5)

RSQ = 0.611

CW:0

CAS

CTot

0

0.2

0.4

0.6

0.8

1

0 0.3 0.6 0.9 1.2 1.5

Cw

ng L

-1CEXT µg/kg

Cashmeran (DPMI)at Šangaj (D6)

RSQ = 0.603

CW:0

CAS

CTot

0

0.28

0.56

0.84

1.12

1.4

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Knićanin (D7)

RSQ = -2.512

CW:0

CAS

CTot

0

0.24

0.48

0.72

0.96

1.2

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Belegiš (D8)

RSQ = 0.417

CW:0

CAS

CTot

0

0.16

0.32

0.48

0.64

0.8

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Ritopek (D9)

RSQ = -0.202

CW:0

CAS

0

0.06

0.12

0.18

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Dubravica (D10)

RSQ = 0.912

CW:0

CAS

0

0.12

0.24

0.36

0.48

0.6

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Cashmeran (DPMI)at Ram (D11)

RSQ = 0.358

86

S21 – 43 Tris(1‐chloro‐2‐propyl) phosphate

CW:0

CAS

0

6

12

18

24

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Apatin (D1)

RSQ = 0.949

CW:0

CAS

0

12

24

36

48

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Labudnjača (D2)

RSQ = 0.664CW:0

CAS

0

3

6

9

12

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Neštin (D3)

RSQ = 0.647

CW:0

CAS

0

3

6

9

12

15

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Begeč (D4)

RSQ = 0.489

CW:0

CAS

0

4

8

12

16

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Ratno Ostrvo (D5)

RSQ = 0.758

CW:0

CAS

0

20

40

60

80

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Šangaj (D6)

RSQ = 0.948

CW:0

CAS

0

3

6

9

12

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Knićanin (D7)

RSQ = 0.567 CW:0

CAS

0

4

8

12

16

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Belegiš (D8)

RSQ = 0.740CW:0

CAS

0

3

6

9

12

15

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Ritopek (D9)

RSQ = 0.123

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Dubravica (D10)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tris(1-chloro-2-propyl) phosphateat Ram (D11)


87

S21 – 44 Tris(1,3‐dichloro‐2‐propyl) phosphate

0

0.6

1.2

1.8

2.4

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Apatin (D1)


CW:0

CAS

0

0.6

1.2

1.8

2.4

0 1.4 2.8 4.2 5.6 7

Cw

ng L

-1CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Labudnjača (D2)

RSQ = 0.976

CW:0

CAS

0

0.6

1.2

1.8

2.4

0 10 20 30 40 50

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Neštin (D3)

RSQ = 0.998

CW:0

CAS

0

0.6

1.2

1.8

2.4

3

0 4 8 12 16 20

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Begeč (D4)

RSQ = 0.967

CW:0

CAS

0

0.6

1.2

1.8

2.4

0 40 80 120 160 200

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Ratno Ostrvo (D5)

RSQ = 0.981

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Šangaj (D6)


CW:0

CAS

0

0.4

0.8

1.2

1.6

2

0 3.2 6.4 9.6 12.8 16

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Knićanin (D7)

RSQ = 0.956

CW:0

CAS

0

0.4

0.8

1.2

1.6

2

0 8 16 24 32 40

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Belegiš (D8)

RSQ = 0.986

CW:0

CAS

0

0.4

0.8

1.2

1.6

2

0 1.8 3.6 5.4 7.2 9

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Ritopek (D9)

RSQ = 0.920

0

0.6

1.2

1.8

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Dubravica (D10)

Insufficient or no dataCW:0

CAS

0

1.6

3.2

4.8

6.4

0 1 2 3 4 5

Cw

ng L

-1

CEXT µg/kg

Tris(1,3-dichloro-2-propyl) phosphateat Ram (D11)

RSQ = -32.697

88

S21 – 45 Triisobutylphosphate

0

0.06

0.12

0.18

0.24

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Apatin (D1)


0

0.028

0.056

0.084

0.112

0.14

0 40000008000000120000001600000020000000

Cw

ng L

-1CEXT µg/kg

Triisobutylphosphateat Labudnjača (D2)

Insufficient or no data CW:0

CAS

0

0.08

0.16

0.24

0.32

0.4

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Neštin (D3)

RSQ = 0.879

CW:0

CAS

0

0.08

0.16

0.24

0.32

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Begeč (D4)

RSQ = 0.842

CW:0

CAS

0

0.08

0.16

0.24

0.32

0.4

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Ratno Ostrvo (D5)

RSQ = 0.944

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1CEXT µg/kg

Triisobutylphosphateat Šangaj (D6)


CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Knićanin (D7)

RSQ = 0.864

CW:0

CAS

0

0.2

0.4

0.6

0.8

1

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Belegiš (D8)

RSQ = 0.909

CW:0

CAS

0

0.02

0.04

0.06

0.08

0.1

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Ritopek (D9)

RSQ = 0.432

CW:0

CAS

0

0.24

0.48

0.72

0.96

1.2

0 0.032 0.064 0.096 0.128 0.16

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Dubravica (D10)

RSQ = 0.972

CW:0

CAS

0

0.016

0.032

0.048

0.064

0.08

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Triisobutylphosphateat Ram (D11)

RSQ = -7.181

89

S21 – 46 Tri‐n‐butylphosphate

0

0.06

0.12

0.18

0.24

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Apatin (D1)


CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg

Tri-n-butylphosphateat Labudnjača (D2)

RSQ = 0.951CW:0

CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.26 0.52 0.78 1.04 1.3

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Neštin (D3)

RSQ = 0.888

CW:0

CAS

0

0.024

0.048

0.072

0.096

0.12

0 0.18 0.36 0.54 0.72 0.9

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Begeč (D4)

RSQ = 0.298

CW:0

CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Ratno Ostrvo (D5)

RSQ = 0.594

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1CEXT µg/kg

Tri-n-butylphosphateat Šangaj (D6)


CW:0

CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.8 1.6 2.4 3.2 4

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Knićanin (D7)

RSQ = 0.681

0

0.04

0.08

0.12

0.16

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Belegiš (D8)


CW:0

CAS

0

0.008

0.016

0.024

0.032

0.04

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Ritopek (D9)

RSQ = 0.993

CW:0

CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Dubravica (D10)

RSQ = 0.970 CW:0

CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.22 0.44 0.66 0.88 1.1

Cw

ng L

-1

CEXT µg/kg

Tri-n-butylphosphateat Ram (D11)

RSQ = 0.984

90

S21 – 47 Triphenyl phosphate

0

0.008

0.016

0.024

0.032

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Apatin (D1)

Insufficient or no dataCTot

0

0.004

0.008

0.012

0.016

0 0.28 0.56 0.84 1.12 1.4

Cw

ng L

-1CEXT µg/kg

Triphenyl phosphateat Labudnjača (D2)


CW:0

CAS

CTot

0

0.016

0.032

0.048

0.064

0.08

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Neštin (D3)

RSQ = 0.367

CW:0

CAS

CTot

0

0.006

0.012

0.018

0.024

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Begeč (D4)

RSQ = 0.767 CW:0

CAS

0

0.006

0.012

0.018

0.024

0.03

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Ratno Ostrvo (D5)

RSQ = 0.846

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1CEXT µg/kg

Triphenyl phosphateat Šangaj (D6)


0

0.006

0.012

0.018

0.024

0.03

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Knićanin (D7)


0

0.024

0.048

0.072

0.096

0.12

0 0.01 0.02 0.03 0.04

Cw

:0n

g L-1

CEXT µg/kg

Tripheny l phosphateat Belegiš (D8)

RSQ = 0.357

CTot

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Ritopek (D9)


CW:0

CAS

0

0.02

0.04

0.06

0.08

0.1

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Dubravica (D10)

RSQ = 0.798

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Triphenyl phosphateat Ram (D11)


91

S21 – 48 Tris(2‐ethylhexyl) phosphate

CW:0

CAS

0

0.0028

0.0056

0.0084

0.0112

0.014

0 8000001600000240000032000004000000

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Apatin (D1)

RSQ = 0.523

CW:0

CAS

0

0.002

0.004

0.006

0.008

0.01

0 8000001600000240000032000004000000

Cw

ng L

-1CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Labudnjača (D2)

RSQ = 0.995

CW:0

CAS

CTot

0

0.004

0.008

0.012

0.016

0 0.6 1.2 1.8 2.4 3

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Neštin (D3)

RSQ = 0.927

CW:0

CAS

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Begeč (D4)

RSQ = 0.995

0

0.004

0.008

0.012

0.016

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Ratno Ostrvo (D5)


0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Šangaj (D6)


CW:0

CAS

CTot

0

0.0016

0.0032

0.0048

0.0064

0.008

0 0.4 0.8 1.2 1.6 2

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Knićanin (D7)

RSQ = 0.869

CW:0

CAS

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Belegiš (D8)

RSQ = 0.995 CW:0

CAS

0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.12 0.24 0.36 0.48 0.6

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Ritopek (D9)

RSQ = 0.869

CW:0

CAS

0

0.002

0.004

0.006

0.008

0.01

0 0.14 0.28 0.42 0.56 0.7

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Dubravica (D10)

RSQ = 0.908

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tri(2-ethylhexyl) phosphateat Ram (D11)


92

S21 – 49 Atrazine

CW:0

CAS

0

0.8

1.6

2.4

3.2

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

Atrazineat Apatin (D1)

RSQ = 0.065 CW:0

CAS

0

0.24

0.48

0.72

0.96

1.2

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1CEXT µg/kg

Atrazineat Labudnjača (D2)

RSQ = 0.124

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Atrazineat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Atrazineat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Atrazineat Ratno Ostrvo (D5)


CAS

0

0.6

1.2

1.8

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1CEXT µg/kg

Atrazineat Šangaj (D6)

RSQ = -17.144

0

0.4

0.8

1.2

1.6

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg

Atrazineat Knićanin (D7)


0

0.08

0.16

0.24

0.32

0.4

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

Atrazineat Belegiš (D8)


CW:0

CAS

0

0.6

1.2

1.8

2.4

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1

CEXT µg/kg

Atrazineat Ritopek (D9)

RSQ = 0.751

CW:0

CAS

0

1.4

2.8

4.2

5.6

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg

Atrazineat Dubravica (D10)

RSQ = 0.640

CW:0

CAS

0

1.6

3.2

4.8

6.4

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Atrazineat Ram (D11)

RSQ = 0.390

93

S21 – 50 Chlortoluron

CW:0

CAS

0

1.2

2.4

3.6

4.8

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Apatin (D1)

RSQ = 0.845

0

1.6

3.2

4.8

6.4

0 0.002 0.004 0.006 0.008 0.01

Cw

ng L

-1CEXT µg/kg

Chlortoluronat Labudnjača (D2)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Ratno Ostrvo (D5)


CW:0

CAS

0

1.4

2.8

4.2

5.6

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1CEXT µg/kg

Chlortoluronat Šangaj (D6)

RSQ = 0.950

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Knićanin (D7)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Belegiš (D8)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Ritopek (D9)


0

0.6

1.2

1.8

2.4

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Dubravica (D10)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlortoluronat Ram (D11)


94

S21 – 51 Isoproturon

CW:0

CAS

0

2.2

4.4

6.6

8.8

0 0.003 0.006 0.009 0.012 0.015

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Apatin (D1)

RSQ = 0.865

CW:0

CAS

0

1.2

2.4

3.6

4.8

6

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1CEXT µg/kg

Isoproturonat Labudnjača (D2)

RSQ = 0.988

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Ratno Ostrvo (D5)


CW:0

CAS

0

1.2

2.4

3.6

4.8

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1CEXT µg/kg

Isoproturonat Šangaj (D6)

RSQ = 0.999

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Knićanin (D7)


0

0.12

0.24

0.36

0.48

0.6

0 0.008 0.016 0.024 0.032 0.04

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Belegiš (D8)


0

0.12

0.24

0.36

0.48

0.6

0 0.0016 0.0032 0.0048 0.0064 0.008

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Ritopek (D9)


CW:0

CAS

0

0.4

0.8

1.2

1.6

0 0.0026 0.0052 0.0078 0.0104 0.013

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Dubravica (D10)

RSQ = 0.899

CW:0

CAS

0

1.4

2.8

4.2

5.6

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Isoproturonat Ram (D11)

RSQ = 0.990

95

S21 – 52 Terbuthylazin

CW:0

CAS

0

0.4

0.8

1.2

1.6

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Apatin (D1)

RSQ = 0.804

CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1CEXT µg/kg

Terbuthylazinat Labudnjača (D2)

RSQ = 0.868

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Ratno Ostrvo (D5)


CW:0

CAS

0

0.6

1.2

1.8

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1CEXT µg/kg

Terbuthylazinat Šangaj (D6)

RSQ = 0.585

0

0.16

0.32

0.48

0.64

0.8

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Knićanin (D7)


0

0.02

0.04

0.06

0.08

0.1

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Belegiš (D8)


CW:0

CAS

0

0.08

0.16

0.24

0.32

0.4

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Ritopek (D9)

RSQ = 0.796

CW:0

CAS

0

2

4

6

8

10

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Dubravica (D10)

RSQ = 0.696

CW:0

CAS

0

0.8

1.6

2.4

3.2

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Terbuthylazinat Ram (D11)

RSQ = 0.999

96

S21 – 53 Diazinon

CW:0

CAS

0

0.12

0.24

0.36

0.48

0.6

0 0.0024 0.0048 0.0072 0.0096 0.012

Cw

ng L

-1

CEXT µg/kg

Diazinonat Apatin (D1)

RSQ = 0.991

CW:0

CAS

0

0.028

0.056

0.084

0.112

0.14

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1CEXT µg/kg

Diazinonat Labudnjača (D2)

RSQ = 0.994

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Diazinonat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Diazinonat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Diazinonat Ratno Ostrvo (D5)


CW:0

CAS

0

0.06

0.12

0.18

0.24

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1CEXT µg/kg

Diazinonat Šangaj (D6)

RSQ = -14.544

0

0.0024

0.0048

0.0072

0.0096

0.012

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1

CEXT µg/kg

Diazinonat Knićanin (D7)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Diazinonat Belegiš (D8)


CAS

0

0.008

0.016

0.024

0.032

0.04

0 0.0028 0.0056 0.0084 0.0112 0.014

Cw

ng L

-1

CEXT µg/kg

Diazinonat Ritopek (D9)

RSQ = 0.668

CW:0

CAS

0

0.016

0.032

0.048

0.064

0.08

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1

CEXT µg/kg

Diazinonat Dubravica (D10)

RSQ = 0.969

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Diazinonat Ram (D11)


97

S21 – 54 Cabendazim

CW:0

CAS

0

1.2

2.4

3.6

4.8

0 0.018 0.036 0.054 0.072 0.09

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Apatin (D1)

RSQ = 0.977

CW:0

CAS

0

1

2

3

4

0 400000800000120000016000002000000

Cw

ng L

-1CEXT µg/kg

Carbendazimat Labudnjača (D2)

RSQ = 0.940

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Ratno Ostrvo (D5)


CW:0

CAS

0

0.8

1.6

2.4

3.2

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1CEXT µg/kg

Carbendazimat Šangaj (D6)

RSQ = 0.949

0

0.6

1.2

1.8

2.4

3

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Knićanin (D7)


0

0.8

1.6

2.4

3.2

4

0 0.014 0.028 0.042 0.056 0.07

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Belegiš (D8)


CW:0

CAS

0

1

2

3

4

0 100000200000300000400000500000

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Ritopek (D9)

RSQ = 0.953

CW:0

CAS

0

0.24

0.48

0.72

0.96

1.2

0 120000240000360000480000600000

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Dubravica (D10)

RSQ = 0.879

CW:0

CAS

0

1.4

2.8

4.2

5.6

0 0.006 0.012 0.018 0.024 0.03

Cw

ng L

-1

CEXT µg/kg

Carbendazimat Ram (D11)

RSQ = 0.825

98

S21 – 55 Metolachlor

CW:0

CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Apatin (D1)

RSQ = 0.868CW:0

CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1CEXT µg/kg

Metolachlorat Labudnjača (D2)

RSQ = 0.734

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Ratno Ostrvo (D5)


CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1CEXT µg/kg

Metolachlorat Šangaj (D6)

RSQ = 0.722

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Knićanin (D7)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Belegiš (D8)


CAS

0

0.04

0.08

0.12

0.16

0 0.004 0.008 0.012 0.016 0.02

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Ritopek (D9)

RSQ = 0.994

CW:0

CAS

0

0.2

0.4

0.6

0.8

1

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Dubravica (D10)

RSQ = 0.374

0

0.04

0.08

0.12

0.16

0.2

0 1800 3600 5400 7200 9000

Cw

ng L

-1

CEXT µg/kg

Metolachlorat Ram (D11)


99

S21 – 56 Chlorpyrifos

CW:0

CAS

0

0.08

0.16

0.24

0.32

0 0.032 0.064 0.096 0.128 0.16

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Apatin (D1)

RSQ = 0.953 CW:0

CAS

0

0.02

0.04

0.06

0.08

0.1

0 0.1 0.2 0.3 0.4 0.5

Cw

ng L

-1CEXT µg/kg

Chlorpyrifosat Labudnjača (D2)

RSQ = 0.944

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Ratno Ostrvo (D5)


CAS

0

0.024

0.048

0.072

0.096

0.12

0 0.06 0.12 0.18 0.24 0.3

Cw

ng L

-1CEXT µg/kg

Chlorpyrifosat Šangaj (D6)

RSQ = 0.843

0

0.0028

0.0056

0.0084

0.0112

0.014

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Knićanin (D7)


0

0.0012

0.0024

0.0036

0.0048

0.006

0 0.022 0.044 0.066 0.088 0.11

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Belegiš (D8)


CAS

0

0.012

0.024

0.036

0.048

0.06

0 0.16 0.32 0.48 0.64 0.8

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Ritopek (D9)

RSQ = 0.952

CW:0

CAS

0

0.016

0.032

0.048

0.064

0.08

0 0.08 0.16 0.24 0.32 0.4

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Dubravica (D10)

RSQ = -1.760

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Chlorpyrifosat Ram (D11)


100

S21 – 56 Propiconazole

CW:0

CAS

0

0.8

1.6

2.4

3.2

4

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Apatin (D1)

RSQ = 1.000

CW:0

CAS

0

0.24

0.48

0.72

0.96

1.2

0 0.032 0.064 0.096 0.128 0.16

Cw

ng L

-1CEXT µg/kg

Propiconazoleat Labudnjača (D2)

RSQ = 0.853

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Ratno Ostrvo (D5)


CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1CEXT µg/kg

Propiconazoleat Šangaj (D6)

RSQ = 0.986

0

0.008

0.016

0.024

0.032

0.04

0 0.03 0.06 0.09 0.12 0.15

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Knićanin (D7)


0

0.004

0.008

0.012

0.016

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Belegiš (D8)


CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.024 0.048 0.072 0.096 0.12

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Ritopek (D9)

RSQ = 0.589

CW:0

CAS

0

0.16

0.32

0.48

0.64

0.8

0 0.028 0.056 0.084 0.112 0.14

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Dubravica (D10)

RSQ = 0.804

0

0.2

0.4

0.6

0.8

1

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Propiconazoleat Ram (D11)


101

S21 – 58 Tebuconazole

CW:0

CAS

0

0.8

1.6

2.4

3.2

0 0.01 0.02 0.03 0.04 0.05

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Apatin (D1)

RSQ = 0.997

CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.016 0.032 0.048 0.064 0.08

Cw

ng L

-1CEXT µg/kg

Tebuconazoleat Labudnjača (D2)

RSQ = 0.737

0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Neštin (D3)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Begeč (D4)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Ratno Ostrvo (D5)


CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.02 0.04 0.06 0.08 0.1

Cw

ng L

-1CEXT µg/kg

Tebuconazoleat Šangaj (D6)

RSQ = 0.836

0

0.08

0.16

0.24

0.32

0.4

0 0.04 0.08 0.12 0.16 0.2

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Knićanin (D7)


0

0.2

0.4

0.6

0.8

1

0 0.2 0.4 0.6 0.8 1

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Belegiš (D8)


CAS

0

0.12

0.24

0.36

0.48

0.6

0 0.012 0.024 0.036 0.048 0.06

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Ritopek (D9)

RSQ = 0.792

CW:0

CAS

0

0.28

0.56

0.84

1.12

1.4

0 0.028 0.056 0.084 0.112 0.14

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Dubravica (D10)

RSQ = 0.241

CW:0

CAS

0

0.8

1.6

2.4

3.2

0 0.0012 0.0024 0.0036 0.0048 0.006

Cw

ng L

-1

CEXT µg/kg

Tebuconazoleat Ram (D11)

RSQ = 0.997

danube sediments of serbia v15v1 as is v16 only for suppinfo42 cashmeran (dpmi) 33704‐61‐9 musk...

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