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KIT – Universität des Landes Baden-Württemberg und nationales Forschungszentrum in der Helmholtz-Gemeinschaft www.kit.edu Engler-Bunte-Institute, Fuel Technology Institute for Technical Chemistry, Gasification Technology Thomas Kolb / Mark Eberhard IEA Bioenergy: Task 33 Thermal Gasification of Biomass Task meeting, May 11 th 2015, Ponferrada, Spain Country Activities GERMANY

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KIT – Universität des Landes Baden-Württemberg undnationales Forschungszentrum in der Helmholtz-Gemeinschaft www.kit.edu

Engler-Bunte-Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

Thomas Kolb / Mark Eberhard

IEA Bioenergy: Task 33 Thermal Gasification of Biomass

Task meeting, May 11th 2015, Ponferrada, Spain

Country Activities GERMANY

2IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

February 2012 Linde Engineering Dresden GmbH aquires Carbo-V® IP January 2013 Linde has elaborated numerous technical corrections of Carbo-V process design

Linde and Forest BtL (Finnland) sign agreement to apply Carbo-V process to provide Syngas for downstream Biodiesel and Naphta | Kemi, Finnland

February 2014 ForestBtL / VAPO / NER300 canceled the project

Update May 2015 | Sven Petersen no news in project pipeline

3IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

The B-XTL BioTfueL-Projekt

R&D Technologies licensors Fuels producers

Bio-dieselBio-jetfuel

8 years partnership to realize a RD&D programme to develop a complete B-XTL process chain

Total Project Budget 180 M€ / Comissioning January 2017

From R&D to marketFrom field to wheel

4IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

Coal

Petcoke

Wood

Straw, Residues

Feedstocks Pretreatment Gasification Gas Treatment

Torrefaction

Synthesis

GaselTM

Fischer-Tropsch

Synthesis and productupgrading

Biodiesel, Biojetfuel

CO-Shift

Acid Gas Removal

Fine Purification

Milling

Liquid Feeds a. Residues

BioTfueL-B-XTL Project Process chain 2nd. Generation Biodiesel und Biojetfuel

PRENFLOTM

PDQ

15 MWth 35 bar

Multi Purpose Gasifierfrom TK IS

CCS/EOR option

CO2

Multi Floor Torrefaction from TK IS

5IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

BioTfueL demo plants: Two multiple scale demo plants will be located in France

• to get scale-up data• to validate various scheme/configurations

Labo FT

Venette site (France) Dunkirk Site (France)

Gasifier WGS AGR Low H2S

Torrefaction Micro-pilot FT AXENS

15 MWth 10 % of syngas << 10 %

Multi scale demo plants

Dem

onst

ratio

nBioTfueL-ProjektBioTfueL main figures & objectives

15 MWth

3 t/h 3 t/h

6IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

PRENFLO PDQ Features• Single-line capacity up to 1,200 MWth

• Dry powder feed (coal/biomass)• Horizontal co-annular burners• Long-life steam cooled reactor screen• Direct water quench• Compact gasification system

BioTfueL-Project PRENFLO PDQ Integration in the BioTfueL process chain

Torre-faction

Gas Con-ditioning

Fischer-Tropsch

Synthesis

Biomass2. Gen.

Fossil fuels

JetfuelDiesel

PRENFLOTM

PDQ

GasifierChamber

Direct Water Quench

Multi Purpose Gasifier

Saturated Syngas

Feed

Gasel™

7IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

SWU Stadtwerke Ulm CHP Demo Plant

Source: R. Rauch, SGG Gasification Seminar 2012

Up date April. 2014

Plant Constructor AGO and SWU settlement out-of-court

Retrofit an additional gas cleaning to reduce nitrogen oxides in flue gas

Commissioning in Mai 2014

Up date May 2015

Plant is in operation still not full electrical power generation In 2014 average 300 h/month in operation In 2015 average 500 h/month in operationPlant design is 600 h/month

8IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

Successfull integration of „hot gas cleaning“ and verificationof specified clean gas values in ppb

Hot commissioning of the process chain gasifier / hot gas cleaning /synthesis

9 h stable process chain operation with model fuel(Monoethylenglycol + 20% Straw coke from bioliq I)

9 h &12 h stable process chain operation withWood oil

ca. 124 h gasifier operation with slurry

ca. 85 t slurry converted into syngas

Production of > 200 l raw petrol

100h champaigne for the process chainin autumn 2015

State of the bioliq®-Project

9IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

18.11.2014 bioliq®: Complete Process Chain Is RunningHigh-quality Fuels from Residual Biomass – Plant Commissioning Ceremony with Representatives of the Federation and State – KIT President: Another Module for the Energiewende

State of the bioliq®-Project

10IEA Task 33: May 2015, Ponferrada, Spain | Mark Eberhard

Engler-Bunte Institute, Fuel TechnologyInstitute for Technical Chemistry, Gasification Technology

Mass, Species and Energy balances