coslight li-ion pouch power cell...
TRANSCRIPT
Zhu Hai Coslight Battery Co., Ltd
2017/03/21
Coslight Li-ion Pouch Power Cell Solution
Contents Coslight profile Coslight Li-ion pouch power cell solution
Li-ion pouch cell for power tool Li-ion pouch cell for EV
Coslight future R&D strategy on power cell
Coslight Confidential
About Coslight
HARBIN Headquarter
ZHUHAI Polymer
Established: 1987Year of Li-ion Business: 1998Major Business:
-Li-ion &Polymer Cell and Battery,-Lead Acid Battery, -EV &HEV, Backup Power System & Solution (Li-ion based) Register Capital: $USD 120mil2016 Revenue(Pouch): $USD 368milLand Area: Over 700,000m2
Building Area: Over 550,000m2
Employee: Over 15,000HK Stock Market: 1999, Code:1043
Coslight Confidential4
Coslight manufacture layout
Coslight Manufacture Base Layout
Delhi IndiaLand Area:100,000m3Staff numbers: 280
Zhuhai ChinaLand Area:160,000m3Staff numbers: 7,000
Shenzhen ChinaLand Area:80,000m3Staff numbers: 1,150
Tianjin ChinaLand Area:66,000m3Staff numbers: 350
Shenyang ChinaLand Area:110,000m3Staff numbers: 720
Headquarter HarbinLand Area:490,000m3Staff numbers: 5,200
5
Coslight Factory Information & Milestone
2016: Worldwide Top5 Li-ion pouch cell vendor Total capacity is over 5 billion Wh/year
2015: Enter China 1st batch “Vehicle Power Battery Company and Product List”
2007: Set up factory for Polymer Cell in Zhuhai(Zhuhai Coslight).
2006: Independent research and development LFP power cell.
2000: Start prismatic Li-ion cell production (Harbin Coslight)
1998: Started to Develop LIB
• Harbin Coslight
• Zhuhai Coslight
>1,000 R&D>15,000 Staffs
CE 2.5GWh/yrPower 2.5GWh/yr
>1,000,000 m2
Coslight Li-ion pouch cell capacity plan Zhuhai Coslight No.1 Industrial Park
Zhuhai Coslight No.2 Industrial Zone(Finished in 2018)
2.5
3.5
4.5
0.51
3
0
1
2
3
4
5
2016 2018 2020
Capa
city
(GW
h)
Coslight Li-ion pouch cell capacity plan
CE
Power
2020 2018 2017Coslight Confidential
Coslight Li-ion pouch cell developing strategy
8
Coslight pouch power tool cell- SpecificationNo Item Specification
1 Cell dimension 5.5*50*75mm (max Thickness*Width*Height)
2 Standard discharge cap Typical 2400mAh(min 2350mAh), Charge: 0.5C(1.2A),4.2V,0.05C(120mA) cut-off, Discharge: 0.2(480mA),2.5V cut-off, 1C=2400mA
3 Nominal voltage 3.6V
4 Impedance <15mΩ
5 Cell weight 40.0g max
6 Energy density 210Wh/kg, 430Wh/l
7 Standard charge cccv, 1.2A, 4.2V,120mA cut-off
8 Max charge cccv, 7.2A, 4.2V, 120mA cut-off (15~45oC)
9 Max continuous discharge 30A(@ RT)
10 Operating temperature(Surface temperature)
Charge: 0~50℃(recommended recharge release <45℃)
Discharge: -20 to 80℃(recommended re-dicharge release <60℃)
11 Storage temperature(Recovery 90% after storage) 1.5year -30~25℃, 3months -30~45℃, 1month -30~60℃
9
Coslight power tool cell- rate charge & discharge @RT
Charge rate CC ratio Charge time Temp. rise
3C 83.6% 33min 2oC
5C 82.5% 26min 5oC
8C 76.3% 22min 9oC
10C 72.6% 21min 12oC
13C 66.7% 20min 18oC
Discharge rate Capacity ratio Temp. rise
3C 94.3% 1oC
5C 91.4% 5oC
8C 90.2% 9oC
10C 88.1% 12oC
13C 86.6% 16oC
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No Li-plating @ 0degC 1.0C, 5degC 3.0C , 25degC 5C 20CLS• 0degC 1.0C/0.5C 20T
• 5degC 3.0C/1.0C 20T
• 25degC 5.0C/1.0C 20T
Coslight power tool cell- Li-plating check
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Minimal voltage at the beginning of -10oC 7C discharge is >3.0VCoslight power tool cell- -10oC discharge
No Minimal Voltage Discharge Time -10℃ 7C 3.0V RT 0.5C 3.0V Ratio1# 3.196V 375s 1714mAh 2381mAh 72%2# 3.185V 365s 1667mAh 2392mAh 70%
12
Coslight power tool cell- Cycle life
No. 1C/4C 3C/5C 0.5C/12.5C
500 cycles1# 103.63% 97.36% 108.56%
2# 104.33% 97.11% 107.77%
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Coslight pouch EV cell- SpecificationNo Item Specification
1 Cell dimension 6.3*174*238mm (max Thickness*Width*Height)
2 Standard discharge cap Typical 29.6Ah(min 29Ah), Charge: 0.5C,4.2V,0.05C cut-off, Discharge: 0.5C, 2.7V cut-off, 1C=29Ah
3 Rated discharge capacity Min 26.1Ah, Charge: 0.5C, 4.2V, cccv 0.05C cut-off, Discharge: 5C,2.7V cut-off
4 Nominal voltage 3.7V
5 Impedance <1.2mΩ
6 Cell weight 521g max
7 Energy density 215Wh/kg, 412Wh/l
8 Standard charge cccv, 0.5C, 4.2V, 0.05C cut-off
9 Max charge cccv, 2C, 4.2V, 0.05C cut-off
10 Max continuous discharge 5C
11 Operating temperature(Surface temperature)
Charge: 0~45℃
Discharge: -20 to 60℃
12 Storage temperature(Recovery 80% after storage) 7 year -30~25℃, 3 year -30~45℃, 1.5 year -30~60℃
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Coslight EV cell- rate charge & discharge @RT
Charge rate CC ratio Charge time Temp. rise
0.2C 98.9% 5h18min 0.61oC
0.5C 96.4% 2h11min 1.2oC
1C 92.6% 1h13min 2.0oC
2C 86.6% 45min 6.1oC
3C 82.8% 36min 12.4oC
Discharge rate Capacity ratio Temp. rise
0.5C 100% ~0oC
1C 97.6% 2.0oC
3C 94.7% 12oC
5C 90.4% 24oC
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Coslight EV cell- charge capability Continuous charge window @ different temp. Max pulse charge current @ 50%SOC.
-30°C -20°C -10°C 0°C 10°C 20°C 35°C 45°C 55°C
Continuous charge current N/A 0.05C 0.1C 0.3C 1.0C 2.0C 3.0C 3.0C 2.0C
20s Charge Current @50%SOC 0.2 C 0.5 C 1 C 3 C 4 C 6 C 9 C 10C 11 C
6.0C
5.0C4.0C
3.0C
2.0C
1.0C
0.5C
0.3C
0.2C
0.1C
0.05C
-30°C -20°C -10°C 0°C 10°C 20°C 35°C 45°C 55°C
OK
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-30°C -20°C -10°C 0°C 10°C 20°C 35°C 45°C 55°C20s Discharge Current @
50% SOC 2C 4C 7C 8C 10C 10C 14C 15C 17C
Temperature Test Condition Power Value (W)
25℃
50%SOC,10s, 2.5VCut off 1200
20%SOC,10s, 2.5VCut off 900
-30℃
50%SOC,10s, 2.3VCut off 105
20%SOC,10s, 2.3VCut off 65
Max pulse discharge current @ 50%SOC.Coslight EV cell- discharge capability
Coslight EV cell- Cycle life
Model 25℃1C/1C cycle number Remain capacity
CA60G4P0-29Ah 2500 ~84%
NCA+SiFurther improvement onenergy density, safety, powerdensity and cycle life
By 2020, gravimetric energy density reaches 300Wh/kg, cycle life is over 2000 .
Solid electrolyte
2016 2020 2025
PEO base SPE is under developing, cycle life is ~500 cycles
By 2025 with new polymer cycle life could reach 2000, gravimetric energy density > 400Wh/kg
As the power source of EV, Lithium-ion battery will take the leading role at least up to 2025. And by 2020, gravimetric energy density will reach 300Wh/kg compared with present ~230Wh/kg.
Coslight power cell future R&D strategy
Li-SAt present, Li-S system cycle life
is ~200 cycles
By 2028, Li-S system cycle life may reach 1500, gravimetric energy density > 500Wh/kg,
Solid polymer electrolyte battery introduction
19Coslight Confidential
Roll-to-roll manufacturing
Cu foil
Al foil
Solid polymer electrolyteLithium metal
High ED
High security
Flexibility
22.5
33.5
44.5
PEO LFP NCA LCOVolta
ge (V
)
Narrow electrochemical window
Obvious oxidationabove 4V
Ioni
c co
nduc
tivity
(s/c
m)
Temperature (°C)Low ionic conductivity
PEO
Merits Demerits
Coslight work on polymer solid-state battery
Design capacity: 480 mAh
Predicted life: 80%@500cycles
Nail test: No fire, no explosion
LFP/SPE/Li pouch sample cell
20Coslight Confidential
Nail test
Solid battery Liquid LIB
60
70
80
90
100
110
20
40
60
80
100
120
0 100 200 300 400 500 600
Coul
ombi
c Eff
icie
ncy
(%)
Capa
city
ratio
(%)
cycle numbers
Cycling testing at 60 °C, 0.5C/0.5CCapacity ratio Coulombic Efficiency
Strategies to improve the performance
21Coslight Confidential
LithiumSPE
Cu foil
NCM+SPEAl foil
Lithium + Passive filmSPE + Frame substrate
Cu foil
NCM+SPEAl foil
Cathode coating
Impr
ovem
ent
Passive film on lithiumAdd frame substrate in SPE
Thinner Lithium
Thicker cathode electrode Thinner SPE layer Higher energy density
Higher mechanical strength
Lower interface impedanceLithium dendrite inhibition
New polymer electrolyte Wider electrochemical window
Merits of Li-S battery
22Coslight Confidential
High capacityElemental prices (Feb, 2017)
Element Price US$/t) Price ratio Website
Sulfur 120 1 http://www.sunsirs.com
Cobalt 6000 50 http://www.lme.com/Nickel 11000 92 http://www.lme.com/
Low cost
High abundance High energy density
2500 2800
4201400
Gravimetric energydensity (Wh/kg)
Volumetric energydensity (Wh/L)
Li-S battery Li-ion battery (NCM/Graphite)
Coslight work on Li-S battery
23Coslight Confidential
1.6
2.1
2.6
0 400 800 1200
Volta
ge (V
)
Capacity (mA h/g)
Charge-discharge profile
406080
100
0 100 200
Capa
city
rete
nsio
n (%
)
Cycle number
25℃ 0.5C Cycling capability
C/S cathode: ~76 wt.% S content Specific capacity (coin cell): ~1200 mAh/g Cycling test (coin cell): ~200 cycles@80%
Technical direction: (1) Low-cost & large-scale C/S composite;(2) Novel high-performance binder material.
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Summary
• Coslight plans Li-ion pouch cell developing strategy based on CE, EV and PT
application;
• Coslight Li-ion pouch PT and EV battery of present generation shows
promising performance;
• Coslight future R&D strategy is based on NCA+Si, Solid-EL and Li-S system.
Zhuhai Coslight Battery Co., Ltd.No.209 Zhufeng Way,Xinqing Science and Technology ParkDoumen District,Zhuhai 519180,P.R.ChinaTel:+86-6199909Fax:+86-6199910www.cncoslight.com
THANKS
Coslight Confidential
Contacts info:Sales VP: 林文德/Eric Lin [email protected]&D : 李涛/Tony Li [email protected]