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PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November Concrete in Biological Treatment Plants needs Protection Dr Ylva Edwards

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Page 1: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Concrete in Biological Treatment Plants needs

Protection

Dr Ylva Edwards

Page 2: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Outline

WR project 27 (2009/2010)• Method• Results• Conclusions and recommendations

WR project 34 (2010)• Different products• Comparison• Suggested test program

Page 3: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Biological treatment plants in Europe

www.compostnetwork.info

Page 4: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Examples of concrete damage

FLOORin reception hall for food waste

RECEPTION TANKin biogas plant

Page 5: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Methodology (WR 27)

• Survey (some 20 plants)

• Chemical analysis(10 plants)

• Analysis of concrete and reinforcement(3 plants)

Page 6: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Biological treatment plants

Leachate, food waste:

• pH 4, acetic acid…..• Phosphates• Chlorides• …….• 70°C

Page 7: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Result: analysis of concrete and reinforcement MICROSCOPY

ATLEVERKEN

8,7x6,4 mm

Page 8: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Result: analysis of concrete and reinforcement

BORLÄNGE

Page 9: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Result: analysis of concrete and reinforcementMICROSCOPY – SEM/EDS

Calcium Phosphorus

Leached zone: Calcium phosphate

Page 10: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Actions made / tested for preventing concrete damage and reinforcement corrosion

• Plastic lining paint• MMA technology based

surface coating products• Protection with stainless

steel• Epoxy treatment• Mastic asphalt (PGJA)

Page 11: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Conclusions and Recommendations, WR 27

• Concrete does not have sufficient resistance to food waste.

• Surface protection is needed.• New metods are required for testing surface protection

products in their ”proper” environment.

WR 34

• New Requirements specifications for surface protection of concrete in biologica treatment plants!

Page 12: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Page 13: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Chemical resistanceMethod ?

EN 1504-2 / EN 13529

Tes ng liqui d in Annex:

•Organic acids: ace c aci d and propionic acid 50/50

Class III (the best):

•28 days with pressure

•Hardness before and a er •≥ 50%

Test apparatus

Page 14: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Abrasion resistance / wear

ASTM 4060• Load 500 g, 1000 g

• Wheel C-10, C-17, H 22…

• Cycles 500, 1000

Taber Abraser

Type of surface protection to be tested Wheel type

All types of surface, general handling CS 10

Flooring with pedestriantraffic CS 17

Flooring with vehicular traffic H 22

Page 15: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Abrasion resistance / wear

EN 1504-2

• ISO 5470-1 (Taber test)• H22

• 1000 cycles

• 1000 gram

• < 3000 mgOR

• EN 13813 (Floor screeds)

• eg EN 13892-5 (steel wheeland load 2000 N)

Taber Abraser

Page 16: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Comparing different products......

Test results are difficul t to compa r e,

such as:

• Chemical resistance: Reported resistant, but…?

• Abrasion: Taber, but parameters…?

Page 17: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Proposal for Testing program

• Membrane (free films)• Functional testing on the system

• Suitable parts depending on type of coating and environment!

• Based on similar for bridges, (Swedish TRA, EOTA/ETAG, EN, ISO..)

• Waterproofing membranes / systems, protection and repair of concrete structures/ Floor screeds……

Page 18: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Proposal for Testing programChemical resistance

• Special testing liquid: 2 % acetic acid, pH just below 4, + 0,5% chlorides + 0,2% phosphate…..

• Storage temperature: 23°C, 40°C, 70°C

• Time: 28 d? (EN 1504-2, EN 13529)

Properties to compare?

• Tensile strength• Tensile bond,• Concrete analysis

Page 19: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

Proposal for Testing programAbrasion resistance

•ISO 5470-1 (ASTM 4060 Taber test)

•For floor s: wh eel type H-22 or according to EN 13892

•Room temperature

Page 20: Concrete in Biological Treatment Plants needs Protectionpda-europe.org/documents/13_SCRI_YEdwards.pdfASTM 4060 •Load 500 g, 1000 g •Wheel C-10, C-17, H 22… •Cycles 500, 1000

PDA Europe 2010 Annual Conference – It’s Time to… Polyurea – Sitges, 15-17 November

2011Laboratory

Yet to be evaluated:• Chemical resistance• Abrasion resistance

Field

Test sites and follow-up in the field