collision process details control the hydrodynamics and heat transfer in fluidized bed reactors

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CHINA PARTICUOLOGY Vol. 3, Nos. 1-2, 2005 18 Conclusions Adhesion force distributions have to be measured and interpreted when meaningful results are expected for rough surfaces. We propose three different types of adhesion force distributions: a monomodal Weibull distribution, a bimodal Weibull distribution, when the contact geometry is well defined by distinct asperities, and a broad lognormal distributions for very rough surfaces with a wide variety of contact geometries. Experimental results on model sur- faces support these theoretical findings. These results are complemented by experimental studies on the influence of various parameters including humidity and contact time. These measurements show that the detachment of parti- cles from a substrate is not a static but a dynamic process originating from material transfer between the adhesion partners. MD-simulations for the alumina system indicate that this mass transfer occurs due to nano-fiber formation either between adsorbed water layers or surprisingly be- tween alumina partners in the absence of water. Acknowledgement Financial support of German Research Association (DFG) is gratefully acknowledged. References Götzinger, M. & Peukert, W. (2003). Dispersive forces of particle- surface interactions: direct AFM measurements and modelling. Powder Technol., 130, 102-109. Götzinger, M. & Peukert, W. (2004a). Adhesion force distributions on rough surfaces. Langmuir, 20, 5298-5303. Götzinger, M. & Peukert, W. (2004b). Adhesion forces of spherical alumina particles on ceramic substrates. J. Adhes., 80(3), 223-242. Hamaker, H. C. (1937). The London-van der Waals attraction between spherical particles. Physica, 1058-1072. Israelachvili, J. (1998). Intermolecular and Surface Forces (2 nd ed.). London: Academic Press. Krupp, H. (1967). Particle adhesion: theory and experiment. Adv. Colloid Interface Sci., 1, 111-239. Maurer, S., Mersmann, A. & Peukert, W. (2001). Henry coeffi- cients of adsorption predicted from solid Hamaker constants. Chem. Eng. Sci., 56(11), 3443-3453. Peukert, W., Mehler, C. & Götzinger, M. (2001). Application of adsorption and adhesion measurements for particle surface characterization. Part. Part. Syst. Char., 18, 229-234. Vogel, L. & Peukert, W. (2003). Breakage behaviour of different materials construction of a mastercurve for the breakage probability. Powder Technol., 129, 101-110. Weibull, W. (1951). A statistical distribution function of wide ap- plicability. J. Appl. Mech., 293-297. Zhou, H., Götzinger, M. & Peukert, W. (2003). The influence of particle charge and roughness on particle-substrate adhesion. Powder Technol., 135-136, 82-91. Manuscript received January 20, 2005 and accepted February 1, 2005. COLLISION PROCESS DETAILS CONTROL THE HYDRODYNAMICS AND HEAT TRANSFER IN FLUIDIZED BED REACTORS Masayuki Horio Department of Chemical Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184-8588 Japan E-mail: [email protected] Abstract In the '90s DEM simulation research was successful in exploring its potential in the simulation of fluidization phenomena and in its application to the design of fluidized-bed processes. Nevertheless, not much progress has been made regarding the realistic treatment of collision processes that are critical in determining macroscopic mode of fluidization. All through the second half of the '90s, the author investigated/demonstrated the issue by introducing different surface interactions caused by formation of liquid and/or solid bridges, van der Waals force and the existence of surface roughness. In the first part of the presentation these are to be summarized and the tasks remaining are discussed. In the second part, are pre- sented the results from a newly developed force-deformation meter to demonstrate the significance of the surface roughness and its elasto-plastic characteristics.

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Page 1: Collision process details control the hydrodynamics and heat transfer in fluidized bed reactors

CHINA PARTICUOLOGY Vol. 3, Nos. 1-2, 2005

18

Conclusions Adhesion force distributions have to be measured and

interpreted when meaningful results are expected for rough surfaces. We propose three different types of adhesion force distributions: a monomodal Weibull distribution, a bimodal Weibull distribution, when the contact geometry is well defined by distinct asperities, and a broad lognormal distributions for very rough surfaces with a wide variety of contact geometries. Experimental results on model sur-faces support these theoretical findings. These results are complemented by experimental studies on the influence of various parameters including humidity and contact time. These measurements show that the detachment of parti-cles from a substrate is not a static but a dynamic process originating from material transfer between the adhesion partners. MD-simulations for the alumina system indicate that this mass transfer occurs due to nano-fiber formation either between adsorbed water layers or surprisingly be-tween alumina partners in the absence of water.

Acknowledgement Financial support of German Research Association (DFG) is

gratefully acknowledged.

References Götzinger, M. & Peukert, W. (2003). Dispersive forces of particle-

surface interactions: direct AFM measurements and modelling. Powder Technol., 130, 102-109.

Götzinger, M. & Peukert, W. (2004a). Adhesion force distributions on rough surfaces. Langmuir, 20, 5298-5303.

Götzinger, M. & Peukert, W. (2004b). Adhesion forces of spherical alumina particles on ceramic substrates. J. Adhes., 80(3), 223-242.

Hamaker, H. C. (1937). The London-van der Waals attraction between spherical particles. Physica, 1058-1072.

Israelachvili, J. (1998). Intermolecular and Surface Forces (2nd ed.). London: Academic Press.

Krupp, H. (1967). Particle adhesion: theory and experiment. Adv. Colloid Interface Sci., 1, 111-239.

Maurer, S., Mersmann, A. & Peukert, W. (2001). Henry coeffi-cients of adsorption predicted from solid Hamaker constants. Chem. Eng. Sci., 56(11), 3443-3453.

Peukert, W., Mehler, C. & Götzinger, M. (2001). Application of adsorption and adhesion measurements for particle surface characterization. Part. Part. Syst. Char., 18, 229-234.

Vogel, L. & Peukert, W. (2003). Breakage behaviour of different materials construction of a mastercurve for the breakage probability. Powder Technol., 129, 101-110.

Weibull, W. (1951). A statistical distribution function of wide ap-plicability. J. Appl. Mech., 293-297.

Zhou, H., Götzinger, M. & Peukert, W. (2003). The influence of particle charge and roughness on particle-substrate adhesion. Powder Technol., 135-136, 82-91.

Manuscript received January 20, 2005 and accepted February 1, 2005.

COLLISION PROCESS DETAILS CONTROL THE HYDRODYNAMICS AND HEAT TRANSFER

IN FLUIDIZED BED REACTORS Masayuki Horio

Department of Chemical Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184-8588 Japan E-mail: [email protected]

Abstract In the '90s DEM simulation research was successful in exploring its potential in the simulation of fluidization phenomena

and in its application to the design of fluidized-bed processes. Nevertheless, not much progress has been made regarding the realistic treatment of collision processes that are critical in determining macroscopic mode of fluidization. All through the second half of the '90s, the author investigated/demonstrated the issue by introducing different surface interactions caused by formation of liquid and/or solid bridges, van der Waals force and the existence of surface roughness. In the first part of the presentation these are to be summarized and the tasks remaining are discussed. In the second part, are pre-sented the results from a newly developed force-deformation meter to demonstrate the significance of the surface roughness and its elasto-plastic characteristics.