cheminform abstract: synthesis of trifluoromethanesulfinamidines and -sulfanylamides

ChemInform 2009, 40, issue 17 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Thio compounds P 0440 Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides. — Base-medi- ated treatment of the silanes (I) and (XII) with aminosulfur trifluorides and subsequent reaction with amines allows simple access to fluorinated sulfinamidines and sulfanylamides. Depending on the electronic nature of amine and conditions used, amidines or amides are formed. — (FERRY, A.; BILLARD*, T.; LANGLOIS, B. R.; BACQUE, E.; J. Org. Chem. 73 (2008) 23, 9362-9365; Inst. Chim. Biochim. Mol. Supramol., CNRS, Univ. Lyon 1, F-69622 Lyon, Fr.; Eng.) — Jannicke 17- 062

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Page 1: ChemInform Abstract: Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides

www.cheminform.wiley-vch.de

Thio compoundsP 0440 Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides. — Base-medi-

ated treatment of the silanes (I) and (XII) with aminosulfur trifluorides and subsequent reaction with amines allows simple access to fluorinated sulfinamidines and sulfanyl-amides. Depending on the electronic nature of amine and conditions used, amidines or amides are formed. — (FERRY, A.; BILLARD*, T.; LANGLOIS, B. R.; BACQUE, E.; J. Org. Chem. 73 (2008) 23, 9362-9365; Inst. Chim. Biochim. Mol. Supramol., CNRS, Univ. Lyon 1, F-69622 Lyon, Fr.; Eng.) — Jannicke

17- 062

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