cheminform abstract: aromatic iodination using n-iodosaccharin in room temperature ionic liquids

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ChemInform 2011, 42, issue 31 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Halogen compounds Q 0090 DOI: 10.1002/chin.201131065 Aromatic Iodination Using N-Iodosaccharin in Room Temperature Ionic Liquids. — The process can be applied to various arenes including those which are only mod- estly activated. In contrast to the water-soluble [bmim]BF4, the use of [bmim]NTf2 allows simple removal of the saccharin by-product by washing and the recovered ionic liquid can be reused. Anthracene, pyrene and naphthalene fail to react. — (BAILEY, L.; HANDY*, S. T.; Tetrahedron Lett. 52 (2011) 18, 2413-2414, http://dx.doi.org/10.1016/j.tetlet.2011.03.010 ; Dep. Chem., Middle Tenn. State Univ., Murfreesboro, TN 37132, USA; Eng.) — Mais 31- 065

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Page 1: ChemInform Abstract: Aromatic Iodination Using N-Iodosaccharin in Room Temperature Ionic Liquids

Halogen compoundsQ 0090 DOI: 10.1002/chin.201131065

Aromatic Iodination Using N-Iodosaccharin in Room Temperature Ionic Liquids. — The process can be applied to various arenes including those which are only mod-estly activated. In contrast to the water-soluble [bmim]BF4, the use of [bmim]NTf2 allows simple removal of the saccharin by-product by washing and the recovered ionic liquid can be reused. Anthracene, pyrene and naphthalene fail to react. — (BAILEY, L.; HANDY*, S. T.; Tetrahedron Lett. 52 (2011) 18, 2413-2414, http://dx.doi.org/10.1016/j.tetlet.2011.03.010 ; Dep. Chem., Middle Tenn. State Univ., Murfreesboro, TN 37132, USA; Eng.) — Mais

31- 065

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