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Hazardous Materials for First Responders 4 th Edition Chapter 1 — Introduction to Hazardous Materials

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Page 1: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Hazardous Materials for First Responders

4th Edition

Chapter 1 — Introduction to Hazardous Materials

Page 2: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Learning Objective 1

Distinguish between hazardous materials incidents and other emergencies.

1–1

Page 3: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

What makes a hazardous materials incident different?

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image to

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Page 4: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

How are hazardous materials incidents different from other types of emergencies?

1–3

Page 5: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Discuss the roles of Awareness-Level and Operations-Level responders.

Learning Objective 2

1–4

Page 6: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

There are six levels of training according to NFPA® standards.

1–5

Awareness OperationsHaz Mat

Technician

Haz Mat Branch Officer

Haz Mat Incident

Commander

Private Sector

Specialist

Page 7: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

There are five levels of training according to OSHA standards.

1–6

Awareness OperationsHaz Mat

Technician

Haz Mat Branch Officer

On Scene Incident

Commander

Page 8: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

First responder roles vary by training level.

1–7

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Page 9: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

What are Awareness-Level personnel’ s responsibilities at a hazardous materials incident?

What are Operations-Level personnel’ s responsibilities at a hazardous materials incident?

1–8

Page 10: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Describe the various types of hazardous materials hazards.

Learning Objective 3

1–9

Page 11: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

There are two main definitions of hazardous exposure.

1–10

Acute

Acute health effects

Chronic

Chronic health effects

Page 12: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Instantly freeze

materials

Liquefied gas

Cryogen

Cold temperatures can present unique dangers when working with cryogenic and liquefied gases.

1–11

(Continued)

Page 13: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

DISCUSSION QUESTION

What are some examples of cryogenic materials?

1–12

Page 14: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Cryogenic and liquefied gases can boil into a much larger vapor cloud.

1–13

Courtesy of Steve Irby, Owasso Fire Department

Page 15: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

WARNING!

Any clothing saturated with a cryogenic material may be removed immediately. This actions is particularly important if the vapors are flammable or oxidizers. A first responder could not escape flames from clothing-trapped vapors if they were to ignite.

1–14

Page 16: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

ExamplesRequire extreme caution

Increase heat

effects

Elevated temperature materials can ignite flammable and combustible materials.

1–15

Page 17: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

The U.S. DOT definition of elevated-temperature material.

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Page 18: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Radiological Hazards exist at specific types of incidents.

1–17

Page 19: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Each type of ionizing radiation has a different penetrating power.

1–18

Page 20: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

What are the four types of ionizing radiation? Describe each briefly.

1–19

Page 21: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Radiation

• Asphyxiation

• Chemical

– Toxic/Poisonous

– Corrosives

Health Hazards Vary

1–20

(Continued)

Page 22: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Corrosives comprise the largest usage class in the industry.

1–21

(Continued)

Page 23: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

The likelihood and severity of an adverse health effect resulting from a chemical exposure are dependent upon which factors?

What is the difference between an acid and a base?

1–22

Page 24: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Irritants

• Convulsants

• Carcinogens

• Sensitizers/Allergens

• Etiological/Biological

• Mechanical

Health Hazards Vary

1–23

Page 25: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Microorganisms that may cause severe, disabling disease or illness.

1–24

Virus

Ricin

Bacteria

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Page 26: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Explosions present specific hazards.

1–25Co

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Page 27: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

Describe the different types of etiological hazards.

What four hazards can be caused by an explosion?

1–26

Page 28: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Explain each of the routes of entry.

Learning Objective 4

1–27

Page 29: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

One route of entry is through inhalation.

1–28

Page 30: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

DISCUSSION QUESTION

What types of hazardous products may be inhaled into the body?

1–29

Page 31: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

A second route of entry is through ingestion.

1–30

Page 32: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

A third route of entry is through skin contact.

1–31

Page 33: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

What are the three main routes of entry as defined by the CDC?

Why is it important to know these?

1–32

Page 34: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Describe the U.S., Canadian, and Mexican hazardous materials regulations and definitions.

Learning Objective 5

1–33

Page 35: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Department of Transportation (DOT)

• Environmental Protection Agency (EPA)

• Comprehensive, Environmental Response, Compensation and Liability Act (CERCLA)

• Superfund Amendments and Reauthorization Act (SARA)

United States Haz-Mat Regulations

1–34

(Continued)

Page 36: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Environmental Planning and Community Right-to-Know Act (EPCRA)

• Resource Conservation and Recovery Act (RCRA)

• Toxic Substances Control Act (TSCA)

• Department of Labor (DOL)

1–35

United States Haz-Mat Regulations

(Continued)

Page 37: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

DISCUSSION QUESTION

What is a process?

1–36

Page 38: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Nuclear Regulatory Commission (NRC)

• Department of Homeland Security (DHS)

• Consumer Product Safety Commission (CPSC)

• Department of Energy (DOE)

United States Haz-Mat Regulations

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(Continued)

Page 39: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Department of Defense Explosives Safety Board (DDESB), Department of Defense (DoD)

• Bureau of Alcohol, Tobacco, Firearms, and Explosives (ATF), Department of Treasury

• Department of Justice (DOJ)

United States Haz-Mat Regulations

1–38

Page 40: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

DISCUSSION QUESTION

What are dangerous goods?

1–39

Page 41: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Transport Canada (TC)

• Environment Canada

• Health Canada

• Canadian Nuclear Safety Commission (CNSC)

Canadian Regulations and Definitions

1–40

Page 42: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Secretaría de Comunicaciones y Transportes (SCT)

• Secretaría de Medio Ambiente y Recursos Naturales (SEMARNAT)

• Secretaría del Trabajo y Previsión Social (STPS)

Mexican Regulations and Definitions

1–41

Page 43: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

REVIEW QUESTION

What are the main agencies involved in the regulation of hazardous materials in the U.S., Canada, and Mexico?

1–42

Page 44: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Discuss hazardous materials incident statistics.

Learning Objective 6

1–43

Page 45: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Hazardous materials incidents trends can be measured.

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Page 46: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

DISCUSSION QUESTION

Which mode of transportation is MOST likely to have a haz mat transportation incident?

1–45

Page 47: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

Summary

• First responders must understand their roles and limitations at haz mat emergencies.

• Numerous government agencies and government regulations play important roles in how hazardous materials are manufactured, used, transported, and disposed of. (Continued)

1–46

Page 48: Chapter 1 Introduction to Hazardous Materialsrolla.k12.mo.us/.../Fire_and_Rescue_Technology/Haz-Mat_Chapter_01.… · Chapter 1 —Introduction to ... hazardous materials incident?

• Haz mat incidents typically involve certain types of materials, but first responders must be prepared to deal with any emergencies.

Summary

1–47