by - usgsupper alamosa river, southwestern colorado by dana j. bove1 , anna b.wilson1 , thomas h....
TRANSCRIPT
U.S. DEPARTMENT OF THE INTERIOR
U.S. GEOLOGICAL SURVEY
Geology, alteration, and rock and water chemistryof the Iron, Alum, and Bitter Creek areas,
Upper Alamosa River, southwestern Colorado
By
Dana J. Bove 1 , Anna B.Wilson1 , Thomas H. Barry2 , Ken Hon 1 , Jeffrey Kurtz3 , R.E. Van Loenen1 , and W.S. Calkin4
Open-File Report 96-039
1996
This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey (USGS) editorial standards or with the North American Stratigraphic Code. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although these data have been used by the USGS and have been successfully imported into various software programs, no warranty, expressed or implied, is made by the USGS as to how successfully or accurately the data can be imported into any specific application software running on any secific hardware platform. The fact of distribution shall not constitute any such warranty, and no responsibility is assumed by the USGS in connection therewith.
'U.S. Geological Survey, Denver, Colorado 2Auburn University, Auburn, Georgia 3Geostat Systems, Golden, Colorado 4Golden, Colorado
FIGURES
1. Plot showing the pH of stream and spring water samples and the associated rockalteration assemblage that largely influences water chemistry. Open diamond indicates the median pH value. Alteration assemblages defined on plate 5.
2. Plot showing the conductivity of stream and spring water samples and the associated rock alteration assemblage that largely influences water chemistry. Open diamond indicates the geometric mean. Alteration assemblages defined on plate 5.
3. Plot showing total iron analyses of stream and spring water samples and the associated rock alteration assemblage that largely influences water chemistry. Open diamond indicates the geometric mean. Alteration assemblages defined on plate 5.
4. Plot showing aluminum analyses of stream and spring water samples and the associated rock alteration assemblage that largely influences water chemistry. Open diamond indicates the geometric mean. Alteration assemblages defined on plate 5.
5. Plot showing sulfate analyses of stream and spring water samples and the associated rock alteration assemblage that largely influences water chemistry. Open diamond indicates the geometric mean. Alteration assemblages defined on plate 5.
6. Plot showing total of base metals (Zn+Cu+Cd+Ni+Co+Pb in ppm; Ficklin metals) from stream and spring water samples and the alteration assemblage that largely influences water chemistry. Open diamond indicates the geometric mean. Open diamond
7. Ficklin plot showing variations in aqueous base metals concentrations (Zn+Cu+Cd+Ni+Co+Pb) for waters within the study area.
TABLES
1. Original geochemical data fro rock samples taken in the Iron, Alum, and Bitter Creek study area. Analyses include major and trace elements with sulfur, CO2 and H2O
2. Inductively coupled plasma-atomic emission spectrometry (ICP-AES) data for rock samples taken in the Iron, Alum, and Bitter Creek study area.
3. Stream, spring, and adit water geochemical data from sites in the Iron, Alum, and Bitter Creek study area.
4. Water sample map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado Dana J. Bove, Thomas H. Barry, and Anna B. Wilson
PLATES
1. Geologic map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado Dana J. Bove, Anna B. Wilson, Jeffrey Kurtz, Ken Hon, and R.E. Van Loenen
2. Rock sample sites in the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado Dana J. Bove, Anna B. Wilson, Ken Hon, Jeffrey Kurtz, and R.E. Van Loenen
3. Alteration assemblage data for selected rock sample sites in the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado Dana J. Bove, Anna B. Wilson, Ken Hon, Jeffrey Kurtz, and R.E. Van Loenen
4. Water sample map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado Dana J. Bove, Thomas H. Barry, and Anna B. Wilson
5. Alteration map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado, with pH and conductivity dataDana J. Bove, Thomas H. Barry, Anna B. Wilson, Jeffrey Kurtz, Ken Hon, and R.E. Van Loenen
6. Alteration map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado, with selected water geochemical dataDana J. Bove, Thomas H. Barry, Anna B. Wilson, Jeffrey Kurtz, Ken Hon, and R.E. Van Loenen
7. Alteration map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern Colorado, with Ficklin plot dataDana J. Bove, Thomas H. Barry, Anna B. Wilson, Jeffrey Kurtz, Ken Hon, and R.E. Van Loenen
8. Rock and water geochemical data from the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern ColoradoDana J. Bove, Anna B. Wilson, W.S. Calkin, Thomas H. Barry, Jeffrey Kurtz, Ken Hon, and R.E. Van Loenen
9. Sulfate, aluminum, and iron loading map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern ColoradoDana J. Bove, Anna B. Wilson, Thomas H. Barry, Ken Hon, Jeffrey Kurtz, and R.E. Van Loenen
11
10. Copper, zinc, and manganese loading map of the Iron, Alum, and Bitter Creek areas, Upper Alamosa River, Southwestern ColoradoDana J. Bove, Anna B. Wilson, Thomas H. Barry, Ken Hon, Jeffrey Kurtz, and R.E. Van Loenen
in
INTRODUCTION
The geology of altered and mineralized areas in the vicinity of the Summitville Mine, in the southwest San Juan Mountains, Colorado, have been studied to understand contributions of individual drainages to downstream acid and metal contamination in the Alamosa River. Studies in these largely unmined and essentially anthropomorhically undisturbed areas also offer a unique opportunity to understand the interrelationship between specific rock and alteration types and the local stream and spring geochemistry. As implied by the creek names, water in the Iron, Alum, and Bitter Creek (IABC) study area can be highly degraded (pH <2 and conductivity > 2,000) and drains from intensely altered and highly pyritized basins.
Field work for this study was conducted mainly during July and August of 1994; however, some geologic mapping was undertaken during the summer and fall of 1993. Published reports on the study area include: Bove, 1994; Bove and others 1995; Calkin, 1967; Kirkham and others, 1995; Lipman, 1974; Miller and McHugh, 1994; and Barry, in press.
The purpose of this report is to present data with related methodologies from our ongoing study in the following tables (table 1-4), maps (Plates 1-10), and figures (figs. 1-6), and to briefly summarize the relationship between geology, alteration and water geochemistry as discerned by this data.
METHODOLOGY
Rock sample geochemical data by various analytical methods are presented in tables 1 and 2. Seventy-two samples were analyzed for 10 major elements, 6 trace elements, H2O+ and H2O", and CO2 (table 1); sulfur determinations were made on 15 of these samples (table 1). Major elements were analyzed by wavelength-dispersive X-ray fluorescence (Taggart and others, 1987). Trace elements (Rb, Sr, Zr, Y, Nb, and Ba) were determined by energy dispersive X-ray fluoresence (Johnson and King, 1987). Total H2O was calculated by combustion at 950 °C with Karl Fisher titration (Jackson and others, 1987) of H2O; H2O"(moisture) was determined by the sample procedure at 110°C and H2O+ was determined by difference (Jackson and others, 1987). Total S was analyzed for using a Leco SRI32 automated sulfur analyser. In addition, 113 rock samples were analyzed utilizing 40-element inductively coupled plasma-atomic emission spectrometry (ICP-AES; Lichte and others, 1987)(table 2). Rock sample site locations are shown on Plate 2.
Rock geochemical data for over 1,900 samples collected in the study area by Inspiration Development Company during the late 1970's is presented on Plate 8. Samples were analyzed by emission spectrometry in Inspiration Development S afford Talco Laboratory in 1979. Data from this study was generously provided by W.S. Calkin, who has spent many years studying the geology and mineralization of the area.
Due to the difficulty of accurately identifying alteration mineral assemblages in the field, 242 whole rock samples were analyzed by X-ray diffraction (XRD) utilizing a Phillips APD- 3600 diffractometer equipped with MDI Inc. JADE software. Coded alteration assemblage information for individual rock samples is shown on Plate 3. The term "sericite" as used in this study is defined as a fine-grained (typically < 10 microns), highly birefringent micaceous
mineral. A review of mineralogical work and XRD data on sericite polytypes can be found in Brindley (1980) and Srodon and Eberl (1984).
A total of 60 water samples (Plate 4) were collected during August 9-31, 1995, including 30 spring samples, 28 stream samples, and 2 adit samples; more detailed methodology is described by Barry (Auburn University, Alabama, masters thesis, in press). Spring samples were taken at the uppermost extent of the tributary where seepage first appears. Stream samples were collected as close to the center of the primary flow as possible, and adit samples were taken as near as possible to the primary emanation. Water samples were collected in polyethylene bottles that were previously rinsed in 10 percent HCL. Six bottles of sample water were collected at each site. These included 1) a 500-mL raw unacidified sample, 2) and 3) two acidified 125-mL samples of raw and filtered water, 4) a 60-mL filtered and acidified sample for Fe+2 analysis,5) a 60-mL filtered and unacidified sample, and 6) a 60-mL H-O isotope sample (neither filtered or acidified). Filtered samples passed through a 0.45 /zm filter, and acidified samples had __acid added to pH < 2.
At each site, pH, temperature, conductivity, and dissolved oxygen were measured and recorded. At the beginning of each day, the pH meter (Orion model 230A) and the conductivity pen (Oakton TDS TESTR with ATC) were calibrated; they were also checked and calibrated (if necessary) at each sample site with known solutions. Water temperature was measured by a standard conventional thermometer, and dissolved oxygen content was determined colorometrically.
Anions were determined on the raw unacidified samples using an ion chromatograph (Fishman and Pyen, 1979) and Fe+2 analysis was conducted using a Hach DR/2000 spectrophometer. Major, minor, and trace elements were determined according to standard methods of the USGS utilizing inductively coupled plasma-atomic emission spectrometry (ICP- AES; Lichte and others, 1987) and inductively coupled plasma-mass spectrometry (ICP-MS).
Total aqueous metal load values as shown in Plates 9 and 10 is a method of measuring the cumulative effects of metals on streams. Load is the total metal concentration times the stream flow. To be truly quantitative, the stream chemistry samples and streamflow measurements should be taken simultaneously. However, stream flow rates for this study were based on estimated measurements by Robert Kirkham (unpublished data) of the Colorado State Geological Survey during field studies from late July to late August 1993; unfortunately, estimates made during the sampling period in 1994 have been determined to be unreliable. Careful comparison of the rainfall for the years 1993 and 1994 indicates that the flow rates were likely to be similar during both years. Consequently, metal loading values from this study are not rigorously comparable as the stream flow was measured the previous year (1993), and the values should be used in relative, not absolute, terms. Even with the uncertainty of streamflow values, the loads very nearly matched 1993 metal loading values along the Alamosa calculated by Walton-Day and others, 1995.
DISCUSSION OF MAP PLATES 4-10
Several maps have been created to depict the interrelationship between specific alteration assemblages and the local water chemistry. Plate 4 shows water sample site locations and
differentiates between stream, spring, or adit samples. Plate 5 includes the pH and specific conductance data from this study superimposed upon the alteration map of the IABC basins. Figures 1 and 2 and table 4 show the relationship between specific alteration assemblages and water pH and conductivity.
Water analyzed from the Alum Creek area, which marks one of the main centers of alteration (quaitz-sericite-pyrite) and mineralization within the IABC basins, is by far the most degraded within the study area, with pH values commonly less than 2.5 and conductivity as high as 2,000 to 10,000 microsiemens per centimenter (/^s/cm). The extensive zone of quaitz-sericite- pyrite (QSP) altered rock in Alum Creek and the associated stockwork veining and sparse molybdenite mineralization is related to an extremely weak molybdenum-copper porphyry system at depth.
Iron Creek at its headwaters appears to be a relatively healthy stream and is known to be a habitat for trout. The first significant influx of degraded water originates from a tributary draining altered and pyritized rock in the saddle between Cropsy and Lookout Mountains. Sheepshead delimits the western extent of intensely hydrothermally altered rocks in the study area. Just to the east of Sheepshead, a prominently altered basin is drained by a tributary with water averaging a pH of about 4.0 and conductivity of about 300 us/cm.
Water quality along Bitter Creek is most adversely affected from relatively acidic water draining from the three altered basins on the north side of Bitter Creek, below and flanking Elephant Mountain.
Plate 6 shows the relationship between the concentrations of iron, aluminum, and sulfate in the waters to the underlying alteration assemblages. Figures 3-5 and table 4 show that the QSP, QSP-K, QSP-PX and argillic alteration assemblages (see map legend for explanation of units), have the highest concentrations of iron, aluminum, and sulfate. Areas of fresh and propylitically altered rock produce waters with the lowest concentration of iron, aluminum, and sulfate.
Plate 7 relates the variations in aqueous base metal concentrations (given as the sum of base metals Zn, Cu, Cd, Co, Ni, and Pb) as a function of pH (Ficklin plot; Ficklin and others, 1992) for waters from the study area. As observed on this map, waters plotting in the high-acid and high metal field (figure 7) are primarily restricted to Alum Creek area. Fresh and propylitically altered rocks yield waters that generally plot in the near-neutral, low-metal fields on the Ficklin diagram (figure 7). Figure 6 demonstrates the show the relationship between the various alteration assemblages and the sum of the Ficklin base metals.
Plate 8 shows Cu, Pb, and Zn concentrations from over 1,900 rock samples from Inspiration Development Company, with thematically shaded aqueous values for Pb, Zn, Cu, and pH. Several important observations can be made from this plate: Metals within the study area are roughly zoned, with Pb and Zn concentrated marginal to, or around, anomalous zones of Cu. This zonation is most readily observed in the Alum Creek area, and in the area southwest of South Mountain, the latter denoted by strongly elevated Pb and Zn. The anomalous zone of Pb- Zn southwest of South Mountain undoubtedly lies on the margin of a zone of highly elevated Cu concentrated just northeast of South Mountain at the Summitville mine site. Second, the highest aqueous metal concentrations correlate positively with the lowest pH values. As a result, the Alum Creek area, center of a large zone of QSP-altered rock, abundant pyrite, and anomalous
metal concentrations, has the highest aqueous concentrations of Pb, Zn, and Cu and lowest pH values in the study area. Conversely, a stream draining weakly altered rock containing elevated Pb and Zn concentrations in the area southwest of South Mountain has a relatively high pH and low associated metal concentrations.
Plates 9 and 10 depict the metal loading (in milligrams per second (mg/s)) for sulfate, aluminum, total iron, copper, zinc, and manganese. To analyze the loads, the area was divided into IABC drainage basins (the heavy solid black lines). The first sample, closest to the mouth of the creek is arbitrarily assigned the first order. The next samples upstream are second order and so forth. Generally, the metals at the highest order are carried on down stream and the effects are cumulative. For instance, if two third order streams each carry 30 mg/s then, when those streams join, the second order stream would carry at least 60 mg/s. The stream could carry much more than 60 mg/s if there was additional degraded water from other sources. Generally, the loads increase downstream. If chemical reaction, dilution, or precipitation occur, the load could decrease.
Iron Creek has low metal contents in its upper reaches but as the pH drops and there is anomalous copper in the rocks, and the metal load increases. Load increases dramatically at the third order sample (TMT44) downstream from the copper anomaly even though the stream flow is relatively low. A spring at TMT43 contributes a small amount of metals but before the stream reaches the Alamosa River (TMT42) some sulfate has been removed from the system and iron has increased. As expected, adding the load from Iron Creek to that measured in Alamosa River (AR49.5) is somewhat less than the load at AR49.4.
Alum Creek has low streamflow, low metal content, and low loads in its upper reaches (fourth order and above). Although there are local high concentrations of metals in the eastern most third order sample the flow is so low that the load is negligible. The western third order stream however, carries much more volume and shows the effects of the Cu and Zn anomalies. Low pH combined with anomalous metal concentrations combine to produce anomalous loads. Adding the load of TMT25 to AR49.4 is somewhat less than that at AR48.1. As there has been plenty of opportunity for at least four side streams to contribute metals, this is good correlation.
Low flows in upper Bitter Creek limit the load of the streams. Effects of a copper anomaly can be seen in third order sample TMT16 and second order sample TMT18. Although the concentrations of metals are very high above those sites, the stream flow is relatively low. A small amount of metal is picked up the remainder of the way to the mouth of Bitter Creek. Again, the contributions from Bitter Creek add to the Alamosa River's load at AR46.9. Very little additional metal is added to the Alamosa River before it's confluence with Wightman Fork. Wightman Fork adds nearly three times the metal load to the River. Why this is the case isn't clear: It may be because mining disturbed the basin, but it may also be due to the naturally higher presence of metals in this drainage.
REFERENCES
Barry, T.H., in press, The geochemistry of natural waters draining hydrothermally altered and mineralized terrains in the upper Alamosa River basin, Colorado: Auburn, Alabama, Auburn University unpublished masters thesis dissertation, 253p.
Bove, D.J., 1994, Preliminay report on the geology of hydrothermally altered areas within theupper Alamosa River basin, Colorado: U.S. Geological Survey Open-File Report 94-224, 12 p.
Bove, D.J., Barry, T.H., Kurtz, J., Hon, K., Wilson, A.B., Van Loenen, R.E., and Kirkham, R.M., 1995, Geology of hydrothermally altered areas within the upper Alamosa River basin, Colorado, and probable effects on water quality, in Posey, H.H., Pendleton, J.A., and Van Zyl, D., eds., Proceedings-Summitville Forum '95, January 17-20, 1995: Fort Collins Publication 38, p. 35-41.
Brindley, G.W., 1980, The X-ray identification and crystal structures of clay minerals: Mineralogical Society of London, Monograph 5.
Calkin, W.S., 1967, Geology, alteration, and mineralization of the Alum Creek area, San Juan volcanic field, Colorado: Golden, Colorado School of Mines, Ph. D. thesis dissertation 177 p.
Ficklin W.H., Plumlee, G.S, Smith, K.S., and McHugh, J.B., 1992, Geochemical classification of mine drainages and natural drainages in mineralilzed areas, in Kharaka, Y.K., and Maest, A.S. eds., Water-rock interaction: Seventh International Symposium on Water-Rock Interaction, Park City, Utah, July 13-18, 1992, Proceedings, v. 1: Rotterdam, A.A., Balkema, p. 381-384.
Fishman, J.J., and Pyen, G., 1979, Determination of selected anions in water by ionchromatography: U.S. Geological Survey Water Resources Investigation 79-101, 30 p.
Jackson, L.L., Brown, F.W., and Neil, S.T., 1987, Major and minor elements requiring individual determination, classical whole rock analysis, and rapid rock analysis: in Methods for Geochemical Analysis (ed. P.A. Baedecker), U.S. Geological Survey Bulletin 170, p. Gl- G23.
Johnson, R.G., and King, B.L., 1987, Energy dispersive X-ray flourescence spectrometry: in Methods for Geochemical Analysis (ed. P.A. Baedecker), U.S. Geological Survey Bulletin 170, p. F1-F4.
Kirkham, R. M. Lovekin, J. R., and Sares, M. A., 1994, Sources of acidity and heavy metals in the Alamosa River Basin, outside of the Summitville mining area, Colorado, in Posey,
H.H., Pendleton, J.A., and Van Zyl, D., eds., Proceedings Summitville Forum '95, January 17-20, 1995: Fort Collins Publication 38, p. 42-56.
Lichte, F.E., Golightly, D.W., and Lamothe, P.J., 1987, Inductively coupled plasma-atomicemission spectrometry: in Methods for Geochemical Analysis (ed. P.A. Baedecker), U.S. Geological Survey Bulletin 170, p. B1-B10.
Lipman, P.W., 1974, Geologic map of the Platoro caldera area southeastern San Juan Mountains, Colorado: U.S. Geological Survey Miscelllaneous Investigation Series Map 1-828, scale 1:48,000.
Miller, W. R., and McHugh, J. B., 1994Natural acid drainage from altered areas within andadjacent to the Upper Alamosa River Basin, Colorado, U.S. Geological Survey Open File Report 94-144, 47 p.
Srodon J., and Eberl, D.D., 1984, Dlite, in Bailey, S.W., ed., Reviews in Mineralogy, Micas, Volume 13, Mineralogical Society of America, p. 495-539.
Taggart, J.E., Jr., Lindsay, J.R., Scott, B.A., Vivit, D.V., Bartel, A.J., and Stewart, K.C., 1987, Analysis of geologic materials by wavelength-dispersive X-ray fluorescence spectrometry: in Methods for Geochemical Analysis (ed. P.A. Baedecker, U.S. Geological Survey Bulletin 170, p. El-El 9.
Walton-Day, Ortiz, R.F., and von Guerard, P.B., 1995, Sources of water having low pH and elevated metal concentrations in the upper Alamosa River from the headwaters to the outlet of Terrace Reservoir, south-central Colorado, April-September, 1993, in Posey, H.H., Pendleton, J.A., and Van Zyl, D., eds., Proceedings-Summitville Forum '95, January 17-20, 1995: Fort Collins Publication 38, p. 160-170.
Tab
le 1
. O
rigin
al g
eoch
emic
al d
ata
for r
ock
sam
ples
take
n in
the
Iron
, Alu
m, a
nd B
itter
Cre
ek a
reas
. M
ajor
ele
men
ts a
naly
zed
by w
avel
engt
h di
sper
sive
X
RF,
and
trac
e el
emen
ts b
y en
ergy
dis
pers
ive
XR
F. S
ee m
etho
ds f
or d
etai
led
anal
ytic
al d
escr
iptio
ns.
[See
alte
ratio
n m
ap (
plat
e 5)
and
geo
logi
c m
ap (
plat
e 1)
for
exp
lana
tion
of u
nits
. R
b, S
r, Z
r, Y
, Nb,
and
Ba
are
repo
rted
in p
arts
per
mill
ion:
rem
aind
er o
f sa
mpl
es a
re in
wei
ght p
erce
nt
FeT
O3
is to
tal F
e ex
pres
sed
as F
e203
. Su
lfur
in a
ll al
uniti
zed
sam
ples
dev
oid
of p
yrite
was
cal
cula
ted
as S
O3.
In p
yriti
zed
(alu
nite
-fre
e) s
ampl
es, a
ll su
lfur
was
con
vert
ed to
FeS
2. N
.d. i
s no
t det
erm
ined
. A
ltera
tion
asse
mbl
age
conf
irm
ed b
y X
RD
. Py
rite
con
tent
est
imat
ed v
isua
lly.]
Fiel
d ID
Lab
Num
ber
Ass
embl
age
PD01
PD
02SD
07SD
17SD
19SD
21A
SD21
BSD
34SD
45SD
46A
SD52
SD54
ASD
54B
SJ14
SJ35
SJ38
SJ39
SJ49
SJ51
SJ76
SJ79
SJ81
SJ82
SJ84
SK01
SK06
SK09
SK12
SK13
SK23
SK25
SK26
SK27
SK30
SK35
ASK
42A
SK42
BSK
43B
SK43
CSK
44SK
47A
D57
3713
D57
3714
D57
3719
D57
3723
D57
3724
D57
3725
D57
3726
D57
3728
D57
3734
D57
3735
D57
3737
D57
3738
D57
3739
D57
3748
D57
3756
D57
3758
D57
3759
D57
3763
D57
3764
D57
3772
D57
3773
D57
3775
D57
3776
D57
3777
D57
3778
D57
3779
D57
3781
D57
3782
D57
3783
D57
3793
D57
3795
D57
3796
D57
3797
D57
3799
D57
3802
D57
3808
D57
3809
D57
3810
D57
3811
D57
3812
D57
3813
PR
OP
FR
ES
HQ
AQ
SP-K
QA
QSP
QA
QSP
-KQ
SPQ
SP-K
PR
OP
PR
OP
PR
OP
QSP
FR
ES
HQ
SPP
RO
PW
-AS
PRO
PPR
OP
FR
ES
HQ
SP-K
PR
OP
PR
OP
PR
OP
PRO
PP
RO
PF
RE
SH
? W-A
SQ
SPQ
SPP
RO
PF
RE
SH
PR
OP
FR
ES
HC
HL
-PA
RG
AR
GP
RO
P?
Roc
k un
it
Tm
dT
md
Tsu
Tm
dT
suT
su?
Tsu
?T
md
Tad
Tad
Tpd
Tad
Tad
-fin
e ph
ase
Tm
dT
riT
dp?
Tdp
Tsd
Tdp
Tsu
Tdp
Tsu
Tds
Tm
dT
md
Tm
dT
rp?
Tsu
Tsu
Tsu
Trp
?T
md
Tm
dT
rp?
Tdp
Tad
Tsu
Tsu
Tsu
Tsu
Tsu
Pyri
te c
onte
nt
spar
se
abun
dant
ab
unda
nt
abun
dant
sp
arse
abun
dant
spar
se
mod
erat
e sp
arse
SiO
,A
120
3F
eT0
3M
gOC
aON
a2O
K,O
58.5
061
.80
80.3
064
.70
58.2
069
.20
62.6
069
.90
68.7
073
.80
60.3
061
.70
58.3
069
.40
70.0
071
.20
63.1
065
.10
59.2
053
.00
65.3
059
.30
64.5
061
.70
59.0
056
.30
53.8
052
.60
64.0
073
.20
71.2
069
.80
61.0
061
.40
60.8
063
.70
67.3
088
.20
73.8
058
.30
70.5
0
16.1
015
.70
6.92
19.0
015
.10
17.9
015
.30
17.3
015
.30
16.1
015
.40
15.4
016
.50
17.0
014
.80
16.0
016
.40
15.3
015
.30
17.8
015
.00
19.1
014
.10
16.2
015
.80
16.0
015
.00
17.3
013
.80
15.1
018
.00
17.5
016
.00
15.9
015
.90
16.1
016
.40
3.78
17.3
016
.10
12.2
0
6.83
5.73
0.15
3.45
0.17
0.69
0.27
1.95
4.81
0.52
6.31
6.31
7.63
3.22
2.81
1.63
5.34
4.65
8.89
9.28
3.98
7.66
4.07
6.05
7.21
8.45
8.80
10.3
07.
161.
450.
611.
196.
225.
456.
364.
892.
422.
430.
176.
764.
88
2.64
2.06
0.07
1.11
0.07
1.10
0.07
0.52
0.24
0.83
1.53
1.93
2.54
0.45
0.77
0.43
1.51
1.54
1.96
3.53
1.10
0.13
1.29
1.65
3.07
3.73
4.39
4.28
5.19
0.15
0.48
0.87
2.32
2.39
2.25
0.68
0.26
0.07
0.07
1.48
2.51
4.24
3.86
0.24
0.08
0.32
0.24
0.41
0.10
0.28
0.07
4.60
3.64
3.82
0.16
1.90
0.07
3.04
0.42
0.67
6.33
2.11
0.19
3.39
3.19
4.86
4.88
5.81
7.24
0.50
0.23
0.10
0.29
3.08
3.95
4.78
2.64
1.81
0.05
0.10
5.95
n.i6
3.45
3.13
0.19
0.11
0.85
0.11
0.63
0.11
0.15
0.11
3.21
3.80
4.16
0.11
4.18
0.22
3.71
2.39
4.04
3.49
2.71
0.35
3.80
4.12
3.46
3.37
2.92
3.20
0.11
0.11
0.36
0.11
3.61
3.76
3.20
3.28
3.19
0.11
0.11
3.00
ail
3.68
3.92
1.25
5.63
2.79
3.94
2.06
3.88
4.12
3.93
3.65
4.32
3.62
4.50
4.11
4.39
3.86
4.89
3.41
2.21
4.31
3.68
3.26
3.42
3.73
3.25
2.71
2.31
1.27
3.06
4.48
4.65
4.27
3.82
3.62
3.66
4.68
0.17
0.08
3.36
2.^3
oo
Tab
le 1
. (c
ont'd
)
Fiel
d ID
PD01
PD02
SD07
SD17
SD19
SD21
ASD
21B
SD34
SD45
SD46
ASD
52SD
54A
SD54
BSJ
14SJ
35SJ
38SJ
39SJ
49SJ
51SJ
76SJ
79SJ
81SJ
82SJ
84SK
01SK
06SK
09SK
12SK
13SK
23SK
25SK
26SK
27SK
30SK
35A
SK42
ASK
42B
SK43
BSK
43C
SK44
SK47
A
TiO
,P2
0,
MnO
LO
I925
CC
O,
FeO
T
OT
AL
H2O
H,0
+H,
O-T
OT
AL
SR
bSr
0.91
0.78
0.94
1.13
0.86
1.19
0.96
1.12
0.66
0.78
0.83
0.74
0.94
0.95
0.41
0.74
0.68
0.75
0.92
1.10
0.62
1.18
0.57
0.74
0.93
1.05
1.02
1.25
1.15
0.88
1.00
1.14
0.82
0.74
0.84
0.49
0.49
0.77
0.54
0.97
0.86
0.38
0.31
0.24
0.11
0.28
0.17
0.32
0.12
0.40
0.10
0.34
0.32
0.40
0.10
0.18
0.19
0.34
0.26
0.50
0.47
0.29
0.55
0.26
0.32
0.37
0.37
0.34
0.51
0.53
0.39
0.16
0.11
0.32
0.30
0.31
0.22
0.21
0.16
0.25
0.36
0.16
0.12
0.09
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.11
0.18
0.19
0.01
0.05
0.01
0.07
0.08
0.25
0.16
0.07
0.01
0.09
0.14
0.13
0.17
0.16
0.19
0.10
0.01
0.01
0.01
0.12
0.16
0.13
0.21
0.01
0.01
0.01
0.12
0.05
1.65
1.29
7.87
4.07
16.90
3.98
13.30
4.31
4.74
3.32
3.13
0.81
1.58
3.42
0.51
4.19
0.16
4.11
4.80
1.61
3.57
7.36
3.98
2.11
0.90
1.81
4.26
0.65
5.76
4.45
3.05
3.75
1.74
1.26
1.30
2.81
2.71
3.55
6.87
2.43
5.76
0.01
0.70
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
1.59
0.22
0.15
0.01
0.01
0.01
0.01
0.01
0.01
0.30
1.10
0.01
2.37
0.15
0.22
0.51
1.90
0.01
0.01
0.01
0.01
0.01
0.01
0.22
0.15
0.81
0.01
0.01
0.01
2.02
0.01
3.65
2.79
0.03
0.17
0.03
0.04
0.05
0.20
0.18
0.08
2.68
2.44
2.94
0.08
0.68
0.07
1.87
1.77
1.13
4.28
0.88
0.14
1.62
2.06
3.68
3.87
4.19
4.49
2.99
0.12
0.14
0.19
2.69
2.46
0.49
0.32
0.15
0.02
2.72
0.62
1.83
1.35
2.48
3.75
5.14
3.01
4.12
3.69
2.31
3.23
1.60
0.87
1.59
3.27
0.40
2.63
1.46
3.15
3.75
1.96
2.55
3.23
1.95
1.94
1.11
1.86
3.13
1.09
5.31
3.27
2.66
3.30
1.90
1.43
1.36
2.22
1.71
1.61
6.43
1.27
3.68
1.68
1.20
2.41
3.24
5.05
2.45
4.04
3.02
1.87
2.94
1.06
0.67
1.28
2.93
0.31
2.59
1.14
2.39
2.79
1.82
2.10
3.08
1.70
1.58
1.03
1.68
2.90
0.98
4.22
2.77
2.45
2.58
1.50
1.17
1.15
1.41
1.04
1.45
6.14
0.93
3.26
0.15
0.15
0.07
0.51
0.09
0.56
0.08
0.67
0.44
0.29
0.54
0.20
0.31
0.34
0.09
0.04
0.32
0.76
0.96
0.14
0.45
0.15
0.25
0.36
0.08
0.18
0.23
0.11
1.09
0.50
0.21
0.72
0.40
0.26
0.21
0.81
0.67
0.16
0.29
0.34
0.42
n.d.
n.d.
2.68 n.d.
5.95
0.22
4.45
0.71
3.43
0.05 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
5.76 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
1.35 n.d.
n.d.
n.d.
n.d.
108 98 7
235 7
166 7
116
104
102
100
132 94 120
102
130 95 142 88 42 98 79 84 80 116 98 55 55 30 57 130
134
138 83 97 86 104
n.d. 7 83 59
760
590
740 53 420
182
210 54 55 16 710
550
660
110
510
280
540
250
320
850
580
660
425
530
680
640
400
900
440
455
210
315
550
670
540
415
415
n.d.
1000 650 45
Tab
le 1
. (c
ont'd
)
Fiel
d ID
Zr
Y
N
b B
a Fe
S2
SO3
PD01
PD02
SD07
SD17
SD19
SD21
ASD
21B
SD34
SD45
SD46
ASD
52SD
54A
SD54
BSJ
14SJ
35SJ
38SJ
39SJ
49SJ
51SJ
76SJ
79SJ
81SJ
82SJ
84SK
01SK
06SK
09SK
12SK
13SK
23SK
25SK
26SK
27SK
30SK
35A
SK42
ASK
42B
SK43
BSK
43C
SK44
SK47
A
240
230
255
390
245
315
225
178
176
176
210
198
200
270
180
172
150
285
255
166
140
210
146
215
194
245
154
136
220
215
215
300
345
250
265
205
210
n.d.
245
260
124
22 20 7 31 10 36 29 26 21 18 21 16 18 34 7 15 17 23 34 22 12 22 10 23 21 26 22 26 24 13 23 21 27 21 25 27 18 n.d. 18 28 14
11 13 10 22 14 20 11 10 10 10 10 11 7 13 13 12 12 15 13 7 10 7 12 14 12 11 11 7 12 7 11 15 11 11 11 7 7n.d. 7 10 7
830
790
345
190
480
405
440
710
142
560
720
760
710
1500
1150 475
810
860
830
630
1050 600
620
890
720
590
750
690
375
770
355
820
780
960
780
770
850
n.d.
180
790
470
n.d.
n.d.
0.00 n.d.
0.00
0.41
0.00
1.33
6.40
0.09 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
10.7
5n.
d.n.
d.n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
2.52 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
10.00
n.d.
22.2
10.00
16.61
0.00
0.00
0.00 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n,d.
n.d.
n.d.
n,d.
n.d.
0.00 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n,d.
n.d.
n.d.
n.d.
n.d.
n.d.
0.00 n.d.
n.d.
n.d.
n.d.
Tab
le 1
. (c
ont'd
)
Fiel
d ID
La
b N
umbe
rA
ssem
blag
e
SK47
BSK
47C
SK49
ASK
49B
SK49
CSK
49D
SK54
ASK
54B
SK55
ASK
55B
SK60
SK61
SK64
ASK
64B
SK66
ASK
66B
SK67
BSK
68SK
69A
SK69
DSK
71SK
73B
SK74
ASK
74B
SK79
ASR
04SR
20SR
21SR
24SR
30SR
33A
D57
3814
D57
3815
D57
3816
D57
3817
D57
3818
D57
3819
D57
3821
D57
3822
D57
3823
D57
3824
D57
3826
D57
3827
D57
3829
D57
3830
D57
3832
D57
3833
D57
3834
D57
3836
D57
3837
D57
3838
D57
3840
D57
3842
D57
3843
D57
3844
D57
3847
D57
3852
D57
3858
D57
3859
D57
3860
D57
3861
D57
3862
QSP
SILI
CSI
LIC
SILI
CQ
SP-K
QA
AR
CPR
OP
W-A
SQ
SP-K
QSP
-KW
-AS
QSP
W-A
SA
RC
QSP
AR
CQ
SPPR
OP
QSP
-KQ
AFR
ESH
PRO
PW
-AS
FRE
SHQ
SPPR
OP
PRO
P
Roc
k un
it
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tm
dTs
dTm
dT
md
Tad
Tm
dT
adT
su Tsu
Tsu
Tad
Tds
Tsu
Tsu
Tdp
Tds
Tds
Tds Tsl
Tad
Tad
Pyri
te c
onte
nt
abun
dant
mod
erat
e
spar
se
abun
dant
abun
dant
mod
erat
e
abun
dant
mod
erat
e
Si0
2A
l,0
3F
eT03
MgO
CaO
Na,
OK
,O
57.3
054
.50
96.4
096
.20
96.4
073
.00
52.4
071
.40
58.6
070
.40
63.5
070
.40
61.5
064
.60
72.9
068
.30
69.2
065
.90
60.3
066
.00
69.9
063
.60
71.4
045
.20
67.4
067
.10
72.6
069
.20
66.9
060
.50
61.4
0
18.1
017
.60
0.78
0.79
0.58
16.9
017
.10
18.1
016
.30
15.8
017
.70
18.0
016
.50
19.2
015
.70
18.9
014
.20
20.6
018
.50
20.1
017
.90
15.3
014
.90
19.3
015
.00
13.4
015
.30
15.1
020
.70
15.3
015
.80
6.72
8.37
0.27
0.53
0.22
0.51
0.27
0.21
9.45
2.26
5.22
0.97
5.25
1.54
0.50
1.17
3.43
0.94
6.77
1.01
0.39
5.29
1.43
1.34
4.22
3.51
0.78
2.64
0.50
6.08
6.17
4.10
3.09
0.07
0.07
0.07
0.24
0.07
0.19
1.31
0.49
0.93
0.76
2.61
1.21
1.33
0.48
0.37
0.07
0.79
0.60
0.35
1.77
0.80
0.07
1.21
1.44
0.55
0.76
0.38
2.41
1.95
0.21
6.23
0.05
0.06
0.05
0.23
0.18
0.26
2.72
0.12
0.11
0.07
0.18
0.04
0.12
0.23
0.13
0.20
0.04
0.13
0.22
3.16
0.13
0.19
2.05
2.50
0.32
2.21
0.12
3.40
4.11
0.11
3.22
0.11
0.11
0.11
0.57
0.33
0.19
2.46
0.54
0.11
0.11
1.98
0.11
0.11
0.48
2.81
0.11
0.11
0.15
0.21
3.71
0.11
0.52
3.45
2.18
2.54
4.19
0.58
3.76
3.65
4.15
1.83
0.07
0.08
0.10
1.85
4.16
0.67
2.50
2.83
3.91
3.78
4.71
5.31
4.18
2.90
4.90
0.07
4.79
1.12
4.67
3.69
3.23
4.65
4.08
4.48
3.63
4.07
4.69
3.46
3.35
Tab
le 1
. (c
ont'd
)
Fiel
d ID
SK47
BSK
47C
SK49
ASK
49B
SK49
CSK
49D
SK54
ASK
54B
SK55
ASK
55B
SK60
SK61
SK64
ASK
64B
SK66
ASK
66B
SK67
BSK
68SK
69A
SK69
DSK
71SK
73B
SK74
ASK
74B
SK79
ASR
04SR
20SR
21SR
24SR
30SR
33A
Ti0
2M
nOL
OI9
25C
CO
,Fe
OT
OT
AL
H2O
H20
+H,
O-T
OT
AL
SR
bSr
1.20
1.06
1.09
0.95
1.21
1.11
0.78
1.08
0.97
1.32
0.92
0.70
0.78
1.02
0.72
1.13
0.56
1.04
1.22
1.31
0.81
0.68
0.69
0.78
0.53
0.56
0.66
0.46
1.46
0.73
0.71
0.42
0.47
0.09
0.07
0.07
0.34
0.44
0.45
0.35
0.08
0.41
0.14
0.31
0.20
0.07
0.40
0.14
1.26
0.23
0.34
0.32
0.32
0.26
0.42
0.24
0.24
0.17
0.22
0.19
0.30
0.34
0.08
0.17
0.01
0.01
0.01
0.01
0.01
0.01
0.27
0.01
0.01
0.01
0.08
0.02
0.03
0.01
0.01
0.01
0.02
0.01
0.01
0.11
0.01
0.01
0.08
0.06
0.01
0.03
0.01
0.12
0.14
6.91
1.82
0.48
0.63
0.66
4.43
20.20
6.09
4.41
4.73
6.53
4.25
5.40
5.68
3.78
5.12
3.56
8.39
6.76
7.75
4.21
1.27
5.99
22.50
1.13
2.44
2.09
0.35
3.41
2.41
1.54
0.01
0.77
0.01
0.01
0.01
0.01
0.01
0.01
1.10
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.55
0.01
0.01
0.01
1.60
0.01
0.01
0.01
1.27
0.58
1.10
3.95
0.06
0.04
0.04
0.04
0.03
0.03
2.96
0.16
0.20
0.13
1.24
0.19
0.09
0.14
0.11
0.07
0.16
0.04
0.05
2.13
0.05
0.07
1.44
1.70
0.10
0.59
0.06
2.58
2.52
4.76
2.09
0.57
0.58
0.53
4.12
6.38
4.83
3.45
4.51
3.89
4.05
3.46
4.98
3.57
4.53
1.94
7.73
3.53
7.27
2.76
1.33
4.11
6.86
1.18
2.14
2.53
0.38
3.18
2.08
1.47
4.14
1.92
0.53
0.49
0.53
3.22
6.18
4.36
2.67
3.35
3.19
3.83
2.40
3.52
2.71
4.09
1.16
7.37
2.86
5.56
3.69
1.09
3.57
6.75
0.86
1.63
1.80
0.38
2.81
1.77
1.19
0.62
0.17
0.04
0.09
0.04
0.90
0.20
0.47
0.78
1.16
0.70
0.22
1.06
1.46
0.86
0.44
0.78
0.36
0.67
1.71
0.07
0.24
0.54
0.11
0.32
0.51
0.73
0.04
0.37
0.31
0.28
3.30 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
3.97 n.d.
2.70 n.d.
0.06
0.31
2.06 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
0.04 n.d.
102 32 7 7 7 60 24 24 56 112
134
114
134
152
124 66 126 18 130 31 134 94 114 11 106
114 77 106
116 97 82
30 940
122
102 83 395
1300 930
540
225
230 73 220
560 28 690
290
1050 54 520
360
550
730
1200 460
225
194
530
178
510
580
Tab
le 1
. (c
ont'd
)
Fiel
d ID
Z
r Y
N
b B
a Fe
S2
SO3
SK47
BSK
47C
SK49
ASK
49B
SK49
CSK
49D
SK54
ASK
54B
SK55
ASK
55B
SK60
SK61
SK64
ASK
64B
SK66
ASK
66B
SK67
BSK
68SK
69A
SK69
DSK
71SK
73B
SK74
ASK
74B
SK79
ASR
04SR
20SR
21SR
24SR
30SR
33A
178
186
200
144
196
196
142
310
265
365
320
255
260
355
150
205
136
250
205
240
160
170
375
146
120
124
156
200
295
178
168
28 20 21 12 17 27 11 32 25 32 38 17 23 35 20 31 12 7 14 24 12 20 21 7 7 10 12 7 27 22 20
10 10 10 7 12 7 7 12 13 20 14 12 13 18 13 12 14 10 13 12 11 11 14 7 7 10 14 14 11 12 11
820
810
166
1100 540
660
950
750
700
1500 960
780
1100
1300 410
900
870
2000 890
485
840
770
780
650
670
870
620
1150 600
1700 960
6.16 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
7.41 n.d.
5.04 n.d.
0.11
0.00
3.85 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
0.07 n.d.
n.d.
0.00 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
0.00 n.d.
0.00 n.d.
0.00
0.00
0.00 n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
n.d.
0.00 n.d.
n.d.
Tab
le 2
. 40
ele
men
t IC
P-A
ES g
eoch
emic
al d
ata
for r
ock
sam
ples
take
n in
the
Iron
, Alu
m, a
nd B
itter
Cre
ek a
reas
. X
RF,
and
trac
e el
emen
ts b
y en
ergy
dis
pers
ive
XR
F. S
ee m
etho
ds f
or d
etai
led
anal
ytic
al d
escr
iptio
ns.
[See
alte
ratio
n m
ap (
plat
e 5)
and
geo
logi
c m
ap (
plat
e 1)
for
exp
lana
tion
of u
nits
. A
ltera
tion
asse
mbl
age
conf
irm
ed b
y X
RD
.]
FIE
LD
ID
L
ab n
umbe
rR
ock
unit
Ass
embl
age
EPD
2AE
PD3A
EPD
3CSA
01SA
03SA
11SA
14SD
07SD
13A
SD13
CSD
17SD
19SD
21A
SD21
BSD
34SD
35B
SD38
SD40
ASD
43A
SD45
SD46
ASD
56A
SD57
ASD
57B
SD57
CSD
58SD
59B
SJ03
SJ13
SJ14
SJ15
SJ20
SJ22
SJ24
SJ26
SJ27
SJ37
SJ45
SJ46
SJ49
SJ54
SJ69
SJ7
2SJ
80
D57
3710
D57
3711
D57
3712
D57
3715
D57
3716
D57
3717
D57
3718
D57
3719
D57
3721
D57
3722
D57
3723
D57
3724
D57
3725
D57
3726
D57
3728
D57
3729
D57
3730
D57
3731
D57
3733
D57
3734
D57
3735
D57
3740
D57
3741
D57
3742
D57
3743
D57
3744
D57
3745
D57
3746
D57
3747
D57
3748
D57
3749
D57
3750
D57
3751
D57
3752
D57
3753
D57
3754
D57
3757
D57
3761
D57
3762
D57
3763
D57
3766
D57
3770
D57
3771
D57
3774
Tsl
Tsl
Tsl
Tsl
Tsl
?T
slT
slT
suT
suT
suT
md
Tsu
Tsu
?T
su?
Tm
dT
md
Tm
dV
ein
Tm
dT
adT
adT
md
Vei
nT
md
Tm
dT
md
Tm
dT
apT
dpT
md
Tsu
Tsu
Tsu
Tsu
? Tsu
Tsu
Tm
dT
md
Tsd
Tsu
Tad
Tsu
Bre
ccia
SIL
ICA
RG
SIL
ICA
RG
QSP
-KQ
AW
-AS
QA SIL
ICSI
LIC
QSP
-KQ
AQ
SPQ
AQ
SP-K
QSP
-KQ
SP-K
SIL
ICC
HL
-PQ
SPQ
SP-K
QSP
VE
INQ
SPQ
SPQ
SPQ
SPQ
SP-K
SIL
ICQ
SPW
-AS
W-A
SA
RG
SIL
ICSI
LIC
SIL
ICQ
SPQ
SPQ
SPW
-AS
CH
L-P
QSP
QA
QSP
AL
%
-SC
A
%-S
FE
%
-SK
%
-SM
G
%-S
NA
%
-SP
%
-SIT
%
-S
9.10
1.40
1.70
8.70
8.50
8.20
8.80
3.50
0.44
1.40
9.80
7.60
8.60
6.10
9.30
8.40
7.20
5.40
7.90
8.20
8.20
7.80
2.80
6.10
8.70
8.80
6.20
8.90
0.54
8.70
9.10
9.40
7.20
1.10
0.55
1.90
8.80
8.90
7.50
7.80
8.90
6.80
6.40
7.60
0.05
0.04
0.07
0.15
0.06
0.34
0.54
0.16
0.08
0.28
0.05
0.24
0.18
0.31
0.07
0.08
0.05
0.04
1.20
0.22
0.04
0.09
0.83
0.11
0.08
0.17
0.06
0.04
0.08
0.11
2.40
0.20
0.17
0.10
0.09
0.30
0.16
0.09
0.07
0.31
0.36
0.07
0.13
0.13
1.10
1.10
0.61
4.50
6.70
0.43
1.50
0.07
0.30
0.10
2.50
0.10
0.48
0.16
1.40
2.80
5.50
4.60
4.50
3.60
0.35
1.60
1.70
0.35
0.56
0.33
1.20
4.90
0.12
2.30
6.00
4.40
0.44
0.28
0.25
0.24
0.14
5.00
5.70
3.30
5.20
0.21
5.7
0
3.20
0.11
0.07
0.11
0.02
2.80
1.20
3.40
0.96
0.08
0.13
4.50
2.20
3.20
1.70
3.20
3.60
2.80
2.40
3.00
3.40
3.10
3.60
0.76
2.70
3.90
3.40
2.00
3.60
0.05
3.50
4.00
1.80
0.11
0.14
0.07
0.25
2.90
3.70
3.30
3.70
1.50
2.60
1.1
0
2.20
0.01
0.01
0.01
0.03
0.45
0.01
0.24
0.01
0.01
0.02
0.69
0.02
0.70
0.04
0.33
0.71
0.54
0.18
1.90
0.15
0.50
0.57
0.33
0.31
0.48
0.18
0.03
0.38
0.02
0.28
0.32
0.30
0.02
0.02
0.02
0.01
0.13
0.53
0.56
0.92
1.60
0.28
o.oi
0.22
0.04
0.03
0.03
0.02
0.04
1.30
2.40
0.23
0.02
0.03
0.08
0.69
0.18
0.60
0.13
0.07
0.03
0.09
2.80
0.20
0.05
0.05
0.02
0.04
0.04
0.14
0.17
0.08
0.01
0.10
1.40
3.40
0.08
0.07
0.01
0.06
0.46
0.09
0.07
1.80
3.70
0.13
0.82
0.31
0.14
0.04
0.10
0.24
0.21
0.19
0.08
0.08
0.09
0.26
0.04
0.12
0.06
0.12
0.04
0.04
0.13
0.04
0.12
0.18
0.04
0.06
0.04
0.01
0.02
0.10
0.18
0.05
0.06
0.03
0.14
0.03
0.19
0.09
0.11
0.38
0.14
0.10
0.09
0.11
0.16
0.01
0.11
0.13
0.57
0.47
0.49
0.13
0.52
0.14
0.20
0.13
0.10
0.80
0.21
0.12
0.56
0.32
0.37
0.08
0.22
0.08
0.28
0.07
0.24
0.23
0.03
0.12
0.36
0.24
0.04
0.31
0.51
0.15
0.50
0.77
0.75
0.52
0.20
0.12
0.11
0.09
0.08
0.38
0.31
0.09
0.34
0.19
Tab
le 2
.
FIEL
D I
D
EPD
02A
EPD
03A
EPD
03C
SA01
SA03
SA11
SA14
SD07
SD13
ASD
13C
SD17
SD19
SD21
ASD
21B
SD34
SD35
BSD
38SD
40A
SD43
ASD
45SD
46A
SD56
ASD
57A
SD57
BSD
57C
SD58
SD59
BSJ
03SJ
13SJ
14SJ
15SJ
20SJ
22SJ
24SJ
26SJ
27SJ
37SJ
45SJ
46SJ
49SJ
54SJ
69SJ
72SJ
80
(con
t'd) MN
PPM
-S 13 26 13 10 260 7 85 19 9 13 94 6
110 30 100 84 99 46
1000 19 82 82 230 28 66 14 9 41 21 43 210 51 6 30 47 36 16 65 78 570
880 32 31 29
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
AS
PPM
-S 18 22 18 43 13 <10
<10
11<10
120 12 10 10 10 10 31
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
}M-S 82 860
440
220
320
250
700
300
580
870
400
180
470
190
630
650
420
160
260
130
530
320 45 91 560
540
380 48 620
1500 45 34 480
800
1300 260
350 50 29 230 40
1500 160
330
BE PPM
-S 1 < 1
< 1
< 1 2 < 1 1
< 1
< 1
< 1 3 < 1 1 < 1 1 2 2 1 2 1 2 2 1 1 2 < 1
< 1 2 < 1 1 2 1 < 1
< 1
< 1
< 1
< 1 2 1 2 1 1
< 1
< 1
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
70 21 69 39 74 41 74 48 72 160 69 69 27 18 41 72 52 23 84 16 74 32 22 56 71 54 47 48 40 27 71 67 63 44 47 110 81 54 21 78 38 51 46 34
1 1 16 27 5 1 2 7 13 13 18 13 5 3 21 24 15 1 20 16 11 22 6 2
Tab
le 2
. (c
ont'd
)
FIEL
D ID
CR
PPM
-S
EPD
02A
EPD
03A
EPD
03C
SA01
SA03
SA11
SA14
SD07
SD13
ASD
13C
SD17
SD19
SD21
ASD
21B
SD34
SD35
BSD
38SD
40A
SD43
ASD
45SD
46A
SD56
ASD
57A
SD57
BSD
57C
SD58
SD59
BSJ
03SJ
13SJ
14SJ
15SJ
20SJ
22SJ
24SJ
26SJ
27SJ
37SJ
45SJ
46SJ
49SJ
54SJ
69SJ
72SJ
80
CU
PPM
-SE
U P
PM-S
G
A P
PM-S
GE
PPM
-SH
O P
PM-S
LA
PPM
-SL
IPPM
-S
MO
PPM
-S
NB
PPM
-S
ND
PPM
-S
NIP
PM-S
19 8 12 6 22 3 3 13 5 22 9 9 22 18 7 10 12 8 15 10 13 9 3 7 10 7 14 14 8 14 5 17 6 5 79 89 11 11 10 9 6 8 2 6
5 12 7 37 63 1 15 1 3 <1
39 134 11 4 8 22 53 72 14 3 13 59 10 7 2 22 29 5 10 46 19 1 4 3 6 14 16 45 66 12
0 12 27 12
2 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
20 5 13 18 20 9 18 8 7 6 21 12 23 18 23 19 15 9 18 17 19 20 2.8 14 19 23 12 21 2.8 20 19 20 21 4 5 8 20 23 14 18 18 17 10 16
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
39.0
14.0
52.0
22.0
39.0
23.0
44.0
34.0
48.0
81.0
39.0
38.0
12.0 9.0
23.0
38.0
26.0
13.0
45.0 7.0
44.0
17.0
12.0
33.0
41.0
28.0
28.0
26.0
23.0
14.0
36.0
35.0
34.0
24.0
41.0
79.0
45.0
27.0
11.0
44.0
18.0
28.0
40.0
18.0
13 6 7 68 11 <2
<2
<2
<2
<2 3 <2
<2
<2
20 6 3 <2 7 <2 9 12 <2 2 <2
<2 7 2 <2
<2 7 2 18 <2
<2
<2
<2
<2 2 3 9 <2 8 <2
<2
<2
<2 4 <2
<2
<2
<2
<2
<2
<2
<2
<2 3 <2 4 18 12 3 7 3 <2 2 <2
<2
<2 2 <2
<2
<2
<2
<2
<2
<2 3 2 3 <2
<2
<2
18 58 <2
<2
23 10 11 11 16 10 15 6 <4 9 16 10 20 13 15 11 11 6 16 9 13 13 4 11 18 16 7 15 4 13 16 21 16 6 <4
<4
12 12 9 20 14 10 11 11
37 9 20 21 38 21 37 12 18 68 34 31 16 13 20 36 28 12 42 11 33 16 12 26 32 28 22 24 19 14 39 31 33 20 13 29 39 25 12 36 19 22 19 18
<2
<2
<2
10 18 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2 4 10 8 12 7 <2
<2 6 <2
<2
<2 2 13 <2
<2 8 13 <2
<2
<2 2 <2
14 14 7 13 <2
<2
<2
Tab
le 2
.
FIEL
D ID
EPD
02A
EPD
03A
EPD
03C
SA01
SA03
SA11
SA14
SD07
SD13
ASD
13C
SD17
SD19
SD21
ASD
21B
SD34
SD35
BSD
38SD
40A
SD43
ASD
45SD
46A
SD56
ASD
57A
SD57
BSD
57C
SD58
SD59
BSJ
03SJ
13SJ
14SJ
15SJ
20SJ
22SJ
24SJ
26SJ
27SJ
37SJ
45SJ
46SJ
49SJ
54SJ
69SJ
72SJ
80
(con
t'd) PB
PPM
-S 60 96 63 86 21 200 25 53 170 62 17 62 21 160 18 7 30 44 16 78 10 29 23 7 34 21 260 11 16 11 17 6 20 15 46 500
140 21 16 24 29 35 21 1860 96 63 86 21 200 25 53 170 62 17 62 21 160 18 7 30 44 16 78 10 29 23 7 34 21 260 11 16 11 17 6 20 15 46 500
140 21 16 24 29 35 21 18
7 5 5 5 16 3 7 5 3 13 21 5 18 11 15 10 9 6 10 9 10 12 4 10 11 11 3 15 1.4 14 14 13 6
1.4
1.4
1.4 15 16 15 11 11 8 6 10
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
1300 390
820
1800 45
1400 490
610
600
1700 50 440
170
210 36 61 32 21 320 42 14 34 34 19 63 380
840 37 660
110
620
470
1500 560
1000
2200 11
014
0 99 260
340 23
1400 600
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
11 6 15 5 8 <4 8 7 6 16 18 9 6 6 7 11 12 <4
12 9 9 12 5 6 9 20 11 9 6 8 7 <4 4 <4
16 13 19 20 10 23 6 6 <4 4
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
100 25 43 110
120 96 37 42 12 59 130
110
170
120
170 96 90 61 96 81 93 110 29 68 100
110 58 140 18 130
110
220
210 39 12 52 120 93 79 90 99 67 95 120
rf-S 88 2 4 3 13 5 16 <2 3 8 8 3 5 4 4 6 6 3 21 4 7 6 5 5 8 8 <2
10 3 4 25 3 <2
<2
<2 2 4 6 4 17 8 4 <2 4
YB
PPM
-S 8 <1
< 1
< 1 1 < 1 2 < 1
< 1 1 < 1
< 1 1 < 1
< 1
< 1
< 1
< 1 2 < 1
< 1 1 < 1
< 1 1 1 < 1 1 < 1
< 1 2 < 1
< 1
<1
< 1
<1
< 1
< 1
<1 2 <
1<
1<
1<
1
ZN
PPM
-S 3 2 <2 17 17 <2
46 2 9 2 18 2 8 3 14 16 14 120
120 10 7 18 12 6 19 <2 2 12 7 4 30 11 3 2 3 <2
31 12 15 41 130 11 6 16
Tab
le 2
. (c
ont'd
)
FIE
LD
ID
La
b nu
mbe
rR
ock
unit
Ass
embl
age
AL
%
-SC
A
%-S
FE
%-S
K
%-S
MG
%
-SN
A
%-S
b-S
SJ81
SK06
SK07
SK09
SK13
SK17
SK18
SK19
ASK
19B
SK20
SK21
ASK
21B
SK22
ASK
22B
SK23
SK25
SK26
SK28
SK35
ASK
35B
SK35
CSK
35D
SK42
ASK
42B
SK43
BSK
43C
SK47
ASK
47B
SK47
CSK
49A
SK49
BSK
49C
SK49
DSK
52SK
54A
SK54
BSK
60SK
61SK
63SK
64A
SK64
BSK
65B
SK66
ASK
66B
SK67
BSK
67C
D57
3775
D57
3779
D57
3780
D57
3781
D57
3783
D57
3784
D57
3785
D57
3786
D57
3787
D57
3788
D57
3789
D57
3790
D57
3791
D57
3792
D57
3793
D57
3795
D57
3796
D57
3798
D57
3802
D57
3803
D57
3804
D57
3805
D57
3808
D57
3809
D57
3810
D57
3811
D57
3813
D57
3814
D57
3815
D57
3816
D57
3817
D57
3818
D57
3819
D57
3820
D57
3821
D57
3822
D57
3826
D57
3827
D57
3828
D57
3829
D57
3830
D57
3831
D57
3832
D57
3833
D57
3834
D57
3835
Tsu
Tmd
Ferr
icre
teT
ad Tsu
Tsu
Tds
9 9 Tds
9 9 Tds
Tds
Tsu Tad
Tmd
Tsu
Tdp
Tsu
Tsu
Tsu
Tad
Tsl
Tsl
Tsl
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu
Tsu Tm
dTs
dTm
dTm
dTm
dFe
rric
rete
Tad
Tmd
Tad
Tmd
QSP
-KPR
OP
W-A
SPR
OP
9 QSP
-KW
-AS
QSP
-KQ
SP-K
AR
CQ
SP-K
QSP
-KQ
A9 W
-AS
QSP
QSP
W-A
SPR
OP
CH
L-P
QA
QSP
FRE
SHC
HL-
PA
RC
AR
C9 Q
SP9 SI
LIC
SILI
CSI
LIC
QSP
-KQ
SPQ
AA
RC
QSP
-KQ
SP-K
QSP
W-A
S9 Q
SP9 W
-AS
W-A
S
TI
%-S
9.30
8.30
5.60
7.90
7.30
9.00
8.50
8.00
10.0
01.
609.
509.
408.
905.
907.
409.
609.
009.
408.
408.
904.
407.
908.
508.
702.
109.
606.
8010
.00
9.40
0.41
0.37
0.32
9.10
8.30
9.10
8.40
9.70
9.40
7.50
8.50
9.60
0.49
7.90
10.0
07.
608.
40
0.10
3.50
0.27
4.20
0.36
0.26
0.18
0.08
0.22
0.08
0.20
0.06
0.09
0.08
0.14
0.07
0.22
3.60
3.40
3.00
0.08
0.07
1.90
1.40
0.03
0.06
0.12
0.17
4.40
0.05
0.04
0.04
0.18
0.08
0.14
0.17
0.08
0.05
0.06
0.13
0.02
0.00
0.09
0.17
0.10
0.16
5.80
6.00
14.0
06.
205.
100.
200.
400.
340.
370.
170.
680.
280.
482.
801.
000.
440.
835.
104.
405.
103.
802.
003.
301.
701.
900.
093.
605.
205.
800.
190.
380.
180.
370.
690.
170.
134.
300.
656.
903.
701.
0041
.00
0.38
0.85
2.60
9.60
2.70
2.50
1.90
2.10
1.00
1.00
1.90
2.50
2.50
0.10
2.50
2.10
2.60
1.50
2.40
3.70
3.70
2.20
3.10
2.10
1.10
3.40
3.10
4.00
0.14
0.06
2.00
3.80
1.60
0.05
0.06
0.07
1.50
3.20
3.30
0.55
3.20
3.00
3.00
3.60
4.00
2.30
3.20
2.30
3.90
1.40
0.08
2.20
0.37
2.50
3.00
0.10
0.21
0.17
0.32
0.01
0.19
0.02
0.01
0.01
0.10
0.30
0.53
0.54
1.40
1.10
0.02
0.30
0.43
0.17
0.00
0.01
1.60
2.60
1.90
0.02
0.02
0.01
0.14
0.27
0.01
0.11
0.62
0.48
0.53
1.50
0.72
0.02
0.80
0.31
0.24
1.50
0.35
2.50
1.20
2.30
0.19
0.08
0.98
0.55
0.69
0.02
0.14
0.32
0.91
0.66
0.14
0.37
0.05
1.60
2.50
2.40
0.49
0.06
2.50
2.40
0.06
0.03
0.06
0.10
2.50
0.01
0.01
0.02
0.55
0.20
0.38
0.25
0.07
0.05
0.08
1.50
0.09
0.14
0.05
0.47
2.20
3.40
0.20
0.16
0.35
0.14
0.22
0.22
0.12
0.14
0.18
0.10
0.16
0.19
0.12
0.10
0.13
0.05
0.03
0.20
0.13
0.17
0.06
0.03
0.08
0.08
0.05
0.08
0.06
0.20
0.20
0.02
0.02
0.01
0.15
0.05
0.21
0.18
0.19
0.06
0.05
0.14
0.08
0.18
0.02
0.17
0.06
0.12
0.18
0.63
0.25
0.66
0.21
0.19
0.08
0.08
0.10
0.04
0.09
0.05
0.05
0.06
0.11
0.19
0.25
0.58
0.54
0.63
0.05
0.13
0.27
0.32
0.50
0.36
0.50
0.80
0.66
0.53
0.38
0.63
0.69
0.12
0.47
0.65
0.33
0.16
0.17
0.21
0.32
0.03
0.21
0.22
0.16
0.25
Tab
le 2
. (c
ont'd
)
FIEL
D ID
SJ81
SK
06
SK07
SK
09
SK13
SK
17
SK18
SK
19A
SK
19B
SK
20
SK21
A
SK21
B
SK22
A
SK22
B
SK23
SK
25
SK26
SK
28
SK35
A
SK35
B
SK35
C
SK35
D_
SK
42A
oo
SK
42B
SK
43B
SK
43C
SK
47A
SK
47B
SK
47C
SK
49A
SK
49B
SK
49C
SK
49D
SK
52
SK54
A
SK54
B
SK60
SK
61
SK63
SK
64A
SK
64B
SK
65B
SK
66A
SK
66B
SK
67B
SK
67C
1813
00 180
1300 780 19 25 39 72 25 82 7 19 14 13 37 76 330
960
480 23 31
1600 45 88 13
390
700
1300 38 32 57 24 23 33 13 75 73 79 590
160 28 200 90 41
1200
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
< 10
< 10
< 10
< 10 17 < 10
<10
< 10
< 10 12 < 10
<10
<10
< 10
<10
< 10
< 10
< 10
< 10
< 10
<10
< 10
<10
< 10 15 < 10
< 10 12 <10 11 10 <10 48 <10
< 10
< 10
<10
< 10 14 <10
< 10
170
< 10
< 10 16 < 10
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
<8
32
159
0 2
620
378
0 2
380
177
0 1
460
<1
410
269
0 <
136
0 <
157
0 <
151
0 <
117
0 <
121
0 <
130
0 <
136
0 1
790
273
2
770
260
227
0 <1
110
2750
2110
248
0 <1
180
<182
234
0 1
810
2160
<11200
< 1
570
<167
0 1
500
163
<1
690
<185
3
760
249
285
1
1200
291
<1
390
2880
190
141
1
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
48 75 33 51 40 30 26 29 48 58 41 35 32 23 34 23 42 72 79 70 47 22 73 62 32 61 46 76 61 37 8 30 24 63 72 75 52 67 58 63 96 5 81 35 53 49
22 28 4 28 5 <1
<1
<1
< 1
<1 1 < l
< 1
12 <1
<1
<1
23 19 79 11 3 7 4 2 < 1
12 21 23 < 1
< 1 3 < 1
< 1
<1 < 1
17 32 18 7 <1
< 1 9 44
Tab
le 2
. (c
ont'd
)
FIEL
D I
D
SJ81
SK06
SK07
SK09
SK13
SK17
SK18
SK19
ASK
19B
SK20
SK21
ASK
21B
SK22
ASK
22B
SK23
SK25
SK26
SK28
SK35
ASK
35B
SK35
CSK
35D
SK42
ASK
42B
SK43
BSK
43C
SK47
ASK
47B
SK47
CSK
49A
SK49
BSK
49C
SK49
DSK
52SK
54A
SK54
BSK
60SK
61SK
63SK
64A
SK64
BSK
65B
SK66
ASK
66B
SK67
BSK
67C
4 49 13 120
270 6 73 37 12 5 9 11 14 6 18 71 17 6 15 20 4 7 2 3 5 4 3 4 3 5 4 5 1 2 26 9 22 12 14 15 22 0.7 16 0.7 35 6
37 93 150 92 20 7 10 46 15 54 3 14 21 43 37 4 2 36 44 33 20 2 15 9 15 <1
20 23 76 5 2 10 5 6 2 13 150 14 18 65 6 75 5 5 25 100
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
22 21 15 19 23 21 21 19 22 2.8 23 13 7
2.8 17 24 24 22 21 21 9 31 20 17 5 18 18 26 23 2.8 4
2.8 20 19 19 16 21 10 13 18 22 24 17 22 17 19
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
23.0
43.0
21.0
28.0
21.0
16.0
15.0
15.0
22.0
30.0
23.0
16.0
16.0
11.0
20.0
13.0
25.0
41.0
45.0
38.0
30.0
12.0
42.0
37.0
21.0
33.0
23.0
41.0
35.0
24.0 5.0
19.0
14.0
35.0
38.0
39.0
26.0
38.0
30.0
33.0
55.0 4.0
49.0
18.0
33.0
24.0
4 9 17 8 9 37 3 3 7 3 8 4 <2
<2
<2 2 6 12 10 15 <2
<2 8 6 3 5 8 8 3 4 4 2 13 <2
<2
12 12 2 <2 5 4 <2 3 4 6 10
<2
<2
<2
<2
<2
<2
<2
<2
<2 4 <2 6 <2
<2
13 <2
<2
<2
<2
<2 5 <2
<2
<2 4 2 <2
<2
<2
<2 3 <2
<2
<2
<2
<2
<2
12 580 3 <2
<2 4 <2
<2
<2
14 22 19 17 13 12 11 10 12 <4
11 11 11 7 11 12 14 18 23 20 5 13 18 18 9 22 14 22 17 6 5 8 20 16 17 22 14 13 12 14 16 <4
14 12 13 12
26 37 14 29 23 20 12 24 36 24 19 23 18 13 15 13 23 38 39 37 20 10 37 30 11 30 23 43 34 17 2.8 13 13 30 36 36 24 31 28 30 44 2.8 35 22 23 26
9 29 2 46 58 <2
<2
<2
<2
<2
<2
<2
<2 7 <2
<2 4 7 12 42 6 <2 4 3 3 <2 6 11 12 <2
<2
<2
<2
<2
<2
<2
13 3 32 13 <2
<2
<2
<2
12 24
to o
Tab
le 2
. (c
ont'd
)
FIE
LD
ID
SJ81
SK06
SK07
SK09
SK13
SK17
SK18
SK19
ASK
19B
SK20
SK21
ASK
21B
SK22
ASK
22B
SK23
SK25
SK26
SK28
SK35
ASK
35B
SK35
CSK
35D
SK42
ASK
42B
SK43
BSK
43C
SK47
ASK
47B
SK47
CSK
49A
SK49
BSK
49C
SK49
DSK
52SK
54A
SK54
BSK
60SK
61SK
63SK
64A
SK64
BSK
65B
SK66
ASK
66B
SK67
BSK
67C
PBPP
M-S
SC
PPM
-S
SNPP
M-S
SR
PPM
-S
TA
PPM
-S
TH
PPM
-SU
PPM
-SV
PPM
-S
W P
PM-S
Y P
PM-S
YB
PPM
-SZ
N P
PM-S
30 13 20 11 72 140
130
510
650
230
270
1700 990
1100 14
0 44 28 33 17 15 28 17 21 18 19 21 13 15 15 76 43 82 12 22 20 18 29 44 32 47 60 13 35 41 16 15
13 20 8 23 15 11 10 7 12 1.4 10 5 5 3 8 16 13 14 14 15 4 18 5 5 3 3 14 20 17 2
1.4
1.4 12 9 9 3 14 9 12 12 14 3 10 14 6 16
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5 9 <5
19 <5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
490
660
230
430
450
750
240
970
1100
1100 460
1100 470
260
270
140
310
1100 550
530
450
110
440
440
630
860 44 24 970
120
110 77 400
360
1300 750
180 72 290
220
590
210 29 700
300
190
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
6 13 12 5 6 <4 6 7 5 <4 8 6 8 5 9 5 9 9 13 8 7 9 8 8 <4 6 <4 6 7 5 <4 5 <4
19 5 7 12 10 10 13 17 7 13 <4
20 5
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
<10
0<
100
160
200
280
210
150
170
100 72 100 17 92 77 99 70 93 150
110
140
120
150 58 79 39 40 42 48 140
240
170 18 21 20 160 66 230
190
130 77 98 110
130
120 98 110 58 140
10 25 4 19 7 3 2 5 6 <2 4 <2
<2
<2 2 <2 3 24 26 21 2 16 26 16 <2 6 4 7 19 <2
<2
<2 2 4 3 <2 8 2 4 6 9 <2 5 4 6 3
1 7
2 96
<1
451
92<
1 97
<1
26<
1 27
<1
17<
1 48
<1
42<
1 15
<1
18<
1 11
<1
12<
1 22
<1
9<
1 17
2 12
02
120
2 28
0<
1 11
<1
43
120
1 84
<1
2<
1 <
2<
1 16
1 29
2 18
0<
1 3
<1
4<
1 8
<1
9<
1 9
<1
<2
<1
4<
1 14
0<
1 21
<1
52<
1 91
<1
15<
1 13
<1
13<
1 21
<1
12<
1 61
Tab
le 2
. (c
ont'd
)
FIE
LD
ID
SK69
ASK
69D
SK70
ASK
71SK
74A
SK74
BSK
81A
SK82
ASK
86A
SK86
BSR
11SR
13B
SRI 5
SRI 8
SR19
SR20
SR24
SR46
SR47
SR57
SR58
CSR
60SR
64
Lab
num
ber
D57
3837
D57
3838
D57
3839
D57
3840
D57
3843
D57
3844
D57
3848
D57
3849
D57
3850
D57
3851
D57
3853
D57
3854
D57
3855
D57
3856
D57
3857
D57
3858
D57
3860
D57
3863
D57
3864
D57
3865
D57
3866
D57
3867
D57
3868
Roc
k un
itTs
uTs
uTs
uTa
dT
su Tsu
Tsu
Tsu
Tsu
Tsu Tsl
Tsl
Tmd
Tsl
Tsl
Tds
Tsl
Tsl
Tpd
Tmd
Tm
dTs
uTs
u
Ass
embl
age
QSP
AR
GQ
SP-K
QSP
QSP
-KQ
AW
-AS
CH
L-P
QSP
-KW
-AS
AR
GQ
SP-K
QSP
-KA
RG
QSP
W-A
SQ
SPA
RG
QA
QSP
QSP
QSP
QSP
AL
%-S
9.90
11.0
08.
409.
507.
709.
809.
509.
9010
.00
9.40
7.90
9.50
8.20
6.80
6.30
7.90
11.0
07.
602.
408.
408.
109.
607.
90
CA
%
-S0.
030.
100.
100.
150.
090.
140.
130.
250.
050.
430.
110.
060.
070.
230.
090.
250.
090.
030.
220.
050.
030.
100.
02
FE
%-S
5.20
0.75
0.49
0.24
0.98
0.94
7.40
8.00
1.50
5.60
8.70
5.50
2.70
3.20
1.00
0.57
0.37
3.30
8.30
2.20
2.10
0.52
2.20
K
%-S
3.90
0.93
2.70
3.70
2.50
3.60
1.70
2.30
4.40
2.50
0.15
2.80
2.00
0.35
2.30
2.60
3.50
0.03
0.66
3.30
3.00
3.60
2.50
MG
%
-S0.
500.
380.
640.
230.
480.
013.
102.
700.
462.
400.
020.
460.
220.
010.
310.
340.
250.
010.
100.
530.
070.
330.
45
NA
%
-S0.
140.
220.
140.
240.
080.
492.
201.
600.
120.
870.
040.
070.
420.
790.
031.
900.
560.
020.
080.
060.
100.
250.
44
P %
-S0.
100.
160.
110.
120.
100.
200.
110.
200.
020.
210.
180.
160.
100.
140.
040.
070.
070.
050.
320.
080.
080.
030.
02
TI
%-S
0.15
0.35
0.17
0.17
0.08
0.21
0.26
0.39
0.31
0.27
0.78
0.69
0.19
0.28
0.11
0.15
0.56
0.47
0.64
0.36
0.08
0.15
0.75
Tab
le 2
. (c
ont'd
)
FIE
LD
ID
MN
PPM
-S
AG
PPM
-S
AS
PPM
-S
AU
PPM
-S
B P
PM-S
B
A P
PM-S
B
E P
PM-S
B
I PPM
-S
CD
PPM
-S
CE
PPM
-S
CO
PPM
-SSK
69A
15
0 <
2
10
<8
- 53
1
< 10
<
2
22
32SK
69D
80
<
2
< 10
<
8 -
520
1 <
10
<2
80
<1
SK70
A
130
<2
<10
<
8 -
680
2 <
10
<2
52
<1
SK71
36
<
2
<10
<
8 -
460
<1
< 10
<
2
38
<1
SK74
A
60
<2
< 10
<
8 -
350
1 <
10
<2
49
<1
SK74
B
15
<2
<10
<
8 -
55
<1
< 10
<
2
81
5SK
81A
18
00
<2
<10
<
8 -
130
1 <
10
<2
48
32SK
82A
22
00
<2
< 10
<
8 -
74
1 <
10
<2
51
36SK
86A
16
0 <
2
< 10
<
8 -
2100
1
< 10
<
2
19
<1
SK86
B
990
<2
< 10
<
8 -
630
1 <
10
<2
35
9SR
11
10
<2
<10
<
8 -
100
<1
<10
<
2
57
33SR
13B
14
0 <
2
17
<8
- 40
1
< 10
<
2
40
23SR
15
33
<2
<10
<
8 -
620
1 <
10
<2
37
3SR
18
10
<2
<10
<
8 -
55
<1
< 10
<
2
31
11SR
19
63
<2
<10
<
8 -
1200
1
< 10
<
2
59
1SR
20
36
<2
<10
<
8 -
600
2 <
10
<2
62
<1
SR24
27
<
2
<10
<
8 -
590
2 <
10
<2
21
<1
SR46
7
<2
<10
<
8 -
47
<1
<10
<
2
25
6SR
47
250
<2
45
<8
- 16
0 1
<10
<
2
93
10SR
57
53
<2
11
<8
- 22
0 2
< 10
<
2
81
4SR
58C
14
<
2
12
<8
- 46
<
1 <
10
<2
5 8
SR60
15
<
2
<10
<
8 -
180
1 <
10
<2
36
<1
SR64
66
<
2
<10
<
8 -
63
2 <
10
<2
19
7to
to
Tab
le 2
. (c
ont'd
)
FIE
LD
IDSK
69A
SK69
DSK
70A
SK71
SK74
ASK
74B
SK81
ASK
82A
SK86
ASK
86B
SR11
SR13
BSR
I 5SR
I 8SR
I 9SR
20SR
24SR
46SR
47SR
57SR
58C
SR60
SR64
CR
PPM
-S 11 0.7
0.7 25 6 11 0.7
0.7 2 3 11 2 13 3 4 14 29 2 33 12 4 13 8
CU
PPM
-S 39 6 4 12 8 5 36 21 18 40 51 23 13 22 8 4 5 12 18 18 14 15 19
EU
PPM
-S
GA
PPM
-SG
EPP
M-S
HO
PPM
-S
LA
PPM
-SL
IPPM
-S
MO
PPM
-SN
BPP
M-S
N
DPP
M-S
N
IPPM
-S<
2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
21 32 18 22 17 23 25 25 25 21 14 19 17 11 13 16 26 13 40 19 18 22 19
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
<4
10.0
44.0
31.0
23.0
28.0
39.0
24.0
25.0
11.0
18.0
30.0
20.0
18.0
18.0
42.0
40.0 9.0
12.0
58.0
46.0 4.0
18.0
10.0
<2 9 3 2 4 <2
17 9 5 17 120 9 7 11 <2 3 <2
44 <2 8 38 3 3
<2
<2
<2
<2 4 <2
<2
<2 5 18 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2 8 <2
<2
12 16 13 14 11 14 12 12 14 13 17 20 14 11 15 11 20 15 9 16 10 13 22
11 37 28 16 24 44 29 31 9 23 32 21 23 15 20 26 12 12 30 38 2.8 20 12
22 <2
<2
<2
<2 3 4 5 <2 4 25 3 3 3 <2
<2
<2
<2 6 <2
<2
<2 3
Tab
le 2
. (c
ont'd
)
FIE
LD
IDSK
69A
SK69
DSK
70A
SK71
SK74
ASK
74B
SK81
ASK
82A
SK86
ASK
86B
SR11
SR13
BSR
I 5SR
I 8SR
I 9SR
20SR
24SR
46SR
47SR
57SR
58C
SR60
SR64
PB P
PM-S
SC
PPM
-S
SN P
PM-S
SR
PPM
-S
TA P
PM-S
T
H P
PM-S
28 96 32 31 310 23 16 15 87 29 70 19 27 120 17 29 24 11 19 23 110 29 20
15 11 11 15 7 7 19 20 16 16 7 16 11 4 3 6 14 5 9 18 6 14 10
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
<5
43 540
410
290
620
1200 95 11
0 58 210
1900 24 230
2000 39 21
016
077
014
00 24 36 62 46
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40 <40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<40
<4 9 <4 9 18 11 6 5 4 6 4 <4 8 4 23 14 5 <4 18 14 <4 15 4
U P
PM-S
V
PPM
-S<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00<1
00
160 81 63 140 60 180
210
240
170
170
180
220
230
150 27 51 240 80 130
160
100
150
170
W P
PM-S
Y P
PM-S 2 4 5 2 7 6 6 7 3 9 <2 4 13 3 9 5 3 <2 2 7 <2 8 <2
YB
PPM
-S[-S c 1
cl cl c 1
cl cl c 1
cl c 1
cl c 1
c 1
cl c 1 1 cl c 1
cl cl c 1
cl 1 c 1
ZN P
PM-S 16 15 25 12 25 <2
110
150 58 290 3 79 12 2 14 15 3 3 31 6 <2 3 46
to
Tab
le 3
. W
ater
geo
chem
ical
dat
a fo
r the
Iro
n, A
lum
, and
Bitt
er C
reek
are
as.
[Maj
or io
ns u
sed
filte
red
ICP-
AES
unl
ess
belo
w li
mit;
if b
elow
lim
it us
ed IC
P-M
S da
ta.
Ani
ons
repo
rted
from
unf
ilter
ed d
ata.
Tra
ce e
lem
ents
from
filte
red
ICP-
MS
data
. Se
e m
etho
dolo
gy s
ectio
n fo
r mor
e de
tails
uS
/cm
is m
icro
siem
ens
per c
entim
eter
.]
Sam
ple
# T
ype
Lat
(dec
)Lo
ng, (
dec)
pH
Sp. C
ond
(uS/
cm)
Dis
.O2(
mg/
l)
Tem
p(°C
) Fe
2+(m
g/l)
Fe
-Tot
(ppm
) A
l3+
(ppm
)K
1+(p
pm)
TM
T-0
8T
MT
-09
TM
T-1
0TM
T-11
TM
T-1
2T
MT
-13
TM
T-1
4T
MT
-15
TM
T-1
5ST
MT
-16
TM
T-1
7T
MT
-18
TM
T-1
9T
MT
-20
TMT-
21T
MT
-22
TM
T-2
3T
MT
-24
TM
T-2
5T
MT
-26
TM
T-2
7T
MT
-28
TM
T-2
9T
MT
-30
TMT-
31T
MT
-32
TM
T-3
3T
MT
-34
TM
T-3
5T
MT
-36
TM
T-3
7T
MT
-38
TM
T-3
9T
MT
-40
TMT-
41T
MT
-42
TM
T-4
3T
MT
-44
TM
T-4
5T
MT
-46
TM
T-4
7T
MT
-48
TM
T-4
9T
MT
-50
TMT-
51T
MT
-52
stre
amsp
ring
spri
ngsp
ring
spri
ngst
ream
spri
ngst
ream
stre
amst
ream
spri
ngst
rean
adit
spri
ngsp
ring
spri
ngsp
ring
stre
amst
ream
stre
amad
itsp
ring
spri
ngsp
ring
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
spri
ngst
ream
spri
ngsp
ring
spri
ngst
ream
stre
am5,
ling
spri
ngst
ream
37.4
0927
194
37.4
1515
861
37.4
0910
778
37.4
1095
778
37.4
1123
972
37.3
9495
2537
.401
7586
137
.404
6530
637
.404
6530
637
.403
8458
337
.403
8477
837
.399
2075
37.3
8962
917
37.3
9790
806
37.3
9844
694
37.4
0416
722
37.4
1266
056
37.3
8808
111
37.3
8493
056
37.3
7722
889
37.3
7634
694
37.3
8829
278
37.3
8821
722
37.3
8720
806
37.3
9010
2537
.393
9758
337
.394
9091
737
.396
2027
837
.390
7183
337
.390
3836
137
.392
1886
137
.389
4425
37.3
8767
667
37.3
8792
083
37.3
8549
222
37.3
7221
833
37.3
7688
611
37.3
8183
167
37.3
7634
7537
.384
1288
937
.387
6388
937
.389
2838
937
.385
4980
637
.389
3038
937
.392
1630
637
.395
1961
1
-106
.571
206
-106
.570
856
-106
.556
136
-106
.562
142
-106
.548
454
-106
.551
935
-106
.552
559
-106
.554
632
-106
.554
632
-106
.570
584
-106
.568
092
-106
.555
924
-106
.561
549
-106
.591
343
-106
.586
854
-106
.589
9-1
06.5
8611
1-1
06.5
6286
-106
.566
061
-106
.582
049
-106
.567
889
-106
.581
25-1
06.5
8219
3-1
06.5
8850
6-1
06.5
8658
1-1
06.5
8952
6-1
06.5
8408
-106
.581
241
-106
.578
072
-106
.578
424
-106
.571
764
-106
.573
567
-106
.572
517
-106
.574
107
-106
.570
746
-106
.583
325
-106
.593
948
-106
.602
218
-106
.614
325
-106
.623
632
-106
.615
437
-106
.622
674
-106
.607
511
-106
.599
356
-106
.599
929
-106
.604
109
7.37
6.21
6.85
6.41
3.03
3.38
6.24
3.16
2.91
3.42
3.34
3.64
6.71
2.59
4.69
6.17
6.13
3.59
2.83
3.23 6.6
2.84
2.34
6.94 6.4
5.44
3.01
2.74
2.88
3.22
3.63
2.28
2.38
2.76
2.79
3.44
2.91 3.5
4.75
4.22
3.37
2.94
3.43
4.93 2.3
3.5
50 40 20 710
570
450
380
980
870
160
550
240
760
1380 20 30 90 400
1720
530
270
1430
2540 20 10 20 560
1130
960
1390 90
1086
052
4016
4016
3038
086
031
059
050 45
011
5042
040 3870
370
7 3 7 0 ? 7 4 5 ? 7 5 9 0.1
>12 7 7 6 4 >12 7 >12 4 >12 6 3.1
3.1
5.3
12.2 10 13 4.7
8.9
12.4
9.8
10.1
7.1
9.8
9.9
10.9
5.1
13.9
10.7
7.9
7.7
3.2
10.4
10 5 4.7
8.5
9.1
8.7
8.5
13.3 ? 7.1
8.2
10.6
7.2
13.1
8.7 4 6 8.6
10.5
16.1
5.1
5.4
6.4
3.1
n.d. 3.1
5.3
12.2 10 13 4.7
8.9
12.4
9.8
10.1
7.1
9.8
9.9
10.9
5.1
13.9
10.7
7.9
7.7
3.2
10.4
0.01
0.01
0.01 36 13.5
5.65 0 54 23 1 25 4.25
10.4 2
0.05
0.01
0.01 3.9
95.5
2.16
0.62 135 5
0.01 ltd
0.02
20.5
48.5 13 44 0.07
1590 99 126.
512
34.
226 3.
225
.50.
01 1.3
1.5
2.5
0.02 575
1.6
1.3
0.09
22.
640 18 8.
20.
52 66 42 1.4
34 5.1
7.5 54 0.06
0.08
<0.
035.
216
03.
40.
57 130
150
0.07 n.d
1.2
22 100
36 53 0.16
1900
1000
200
170
9.3 39 4.7
31 0.05 2.1 28 5.9
0.42 850
3.4
0.15
0.06
30.
370.
02 8 6.3
0.62 16 25 2.5
6.2 4
0.00
719
0.02
50.
02<
0.00
77.
661 8
0.03
170 66 0.01 ltd
0.32 18 27 21 27 2.2
390
200
70 61 9.7 14 7.2
2.6
1.3
3.9
21 5.2
0.14
340
5.5
1.5
1.4
0.48 38 4.9
8.2 11 20 17 1.1 12 5.7
28 0.68
0.12
0.55 1 13 27 8.5
7.6 11 2.5
0.4
n.d
0.3
0.49 14 12 53 0.49 130
83 23 25 4.8
4.3
3.5 19 1 8.4
98 9.5
0.54 2.9 4
0.2
0.22 1 1.9
2.1
1.3
0.74 2 1.6
0.57 1.6
1.2
2.1
0.38
0.31 2.4
0.65 2 2.5
1.7
0.76 1.2
0.02 2.3
n.d
1.3
1.1
1.4
1.7
2.3
0.48 4.8
0.1
2.7
2.6 2 3.6
1.1
1.9
0.33 1.1
1.4
1.1 1
0.15 1.2
to
Sam
ple
#
TM
T-0
8T
MT
-09
TM
T-1
0T
MT
-11
TM
T-1
2T
MT
-13
TM
T-1
4T
MT
-15
TM
T-1
5ST
MT
-16
TM
T-1
7T
MT
-18
TM
T-1
9T
MT
-20
TM
T-2
1T
MT
-22
TM
T-2
3T
MT
-24
TM
T-2
5T
MT
-26
TM
T-2
7T
MT
-28
TM
T-2
9T
MT
-30
TM
T-3
1T
MT
-32
TM
T-3
3T
MT
-34
TM
T-3
5T
MT
-36
TM
T-3
7T
MT
-38
TM
T-3
9T
MT
-40
TM
T-4
1T
MT
-42
TM
T-4
3T
MT
-44
TM
T-4
5T
MT
-46
TM
T-4
7T
MT
-48
TM
T-4
9T
MT
-50
TM
T-5
1T
MT
-52
Typ
e
stre
amsp
ring
spri
ngsp
ring
spri
ngst
ream
spri
ngst
ream
stre
amst
ream
spri
ngst
ream
adit
spri
ngsp
ring
spri
ngsp
ring
stre
amst
ream
stre
amad
itsp
ring
spri
ngsp
ring
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
spri
ngst
ream
spri
ngsp
ring
spri
ngst
ream
stre
amsp
ring
spri
ngst
ream
Lat
. (d
ec)
37.4
0927
194
37.4
1515
861
37.4
0910
778
37.4
1095
778
37.4
1123
972
37.3
9495
2537
.401
7586
137
.404
6530
637
.404
6530
637
.403
8458
337
.403
8477
837
.399
2075
37.3
8962
917
37.3
9790
806
37.3
9844
694
37.4
0416
722
37.4
1266
056
37.3
8808
111
37.3
8493
056
37.3
7722
889
37.3
7634
694
37.3
8829
278
37.3
8821
722
37.3
8720
806
37.3
9010
2537
.393
9758
337
.394
9091
737
.396
2027
837
.390
7183
337
.390
3836
137
.392
1886
137
.389
4425
37.3
8767
667
37.3
8792
083
37.3
8549
222
37.3
7221
833
37.3
7688
611
37.3
8183
167
37.3
7634
7537
.384
1288
937
.387
6388
937
.389
2838
937
.385
4980
637
.389
3038
937
.392
1630
637
.395
1961
1
Lon
g, (
dec)
-106
.571
2058
-106
.570
8561
-106
.556
1358
-106
.562
1419
-106
.548
4544
-106
.551
935
-106
.552
5594
-106
.554
6317
-106
.554
6317
-106
.570
5839
-106
.568
0917
-106
.555
9244
-106
.561
5492
-106
.591
3431
-106
.586
8539
-106
.589
8997
-106
.586
1111
-106
.562
8603
-106
.566
0606
-106
.582
0494
-106
.567
8889
-106
.581
25-1
06.5
8219
31-1
06.5
8850
64-1
06.5
8658
06-1
06.5
8952
61-1
06.5
8407
97-1
06.5
8124
14-1
06.5
7807
22-1
06.5
7842
39-1
06.5
7176
44-1
06.5
7356
67-1
06.5
7251
72-1
06.5
7410
67-1
06.5
7074
61-1
06.5
8332
5-1
06.5
9394
83-1
06.6
0221
83-1
06.6
1432
5-1
06.6
2363
17-1
06.6
1543
67-1
06.6
2267
44-1
06.6
0751
14-1
06.5
9935
64-1
06.5
9992
94-1
06.6
0410
92
Mn(
ppm
) C
a :
0.02
40.
013
0.04
6 30.
371
0.01
33.
5 30.
13 1.7
0.59
0.89
0.14
0.01
20.
0096
0.00
21.
25.
60.
780.
89 1.7
0.13
0.00
2n.
d.0.
002
0.02
92.
42.
38.
80.
049 45 24 5.1
5.2
0.68 1.
10.
41 1.7
0.7 3 71 1.7
0.00
510.
160.
69
z+(p
pm)
Na
8.4
9.1
2.3 81 11 25 46 72 51 3.5 37 19 96 4
0.8
3.5 12 30 63 15 36 13 4.3
2.3
n.d. 2.6
1.5 16 25 120
2.3
150
120 50 58 18 11 13 72 2.8 15 100 21 2.5
4.9 13
1+(p
pm)
Si
2.4
2.4 3
5.1
4.8
3.6
6.9
5.7
3.6
2.3
5.1
3.4
5.5
3.3
1.3
1.9
2.2
2.8
3.7 3
2.8
2.9
2.4
2.8
n.d. 1.9
1.4
1.9
3.1
5.7
1.3 2
1.9
3.5
3.5 4
2.4
3.7
6.6
1.8
3.6
6.3
3.4
1.7
2.1
2.7
^/V
YI^
,^
vr\
f2
(ppm
) oL
/4 (^
3.9
3.8
8.8 15 21 15 9.6 19 10 11 19 15 10 30 3.6 12 2.5 18 35 18 4.4 41 38 15 n.d. 14 27 29 24 32 16 39 30 33 35 17 18 11 15 5.4 14 23 13 8.5 37 12
-) (p
pm)
11 8.8
2.5
343
163
183
177
433
479
53 262
101
321
328
4.8
3.2 21 167
1024 83 11
710
1040
71.
0n.
d. 8.7
197
323
400
847 25
1340
047
9018
6010
90 146
310
170
306
23 138
1050
161 12
9250 12
1
Cr
(ppm
)
<0.
10.
140.
27 0.58
0.55
0.34
0.52 0.43
0.39
0.21
0.42
0.14 0.
70.
380.
140.
23 1.0
0.42
0.62
0.32 0.
3<
11.
10.
19 0.18
0.22
0.43
0.36
0.38
0.18 3.6 2.5 1
0.76
0.30
0.40
0.27 0.47
0.14 0.36 2.
2<
0.1
0.19 3.
60.
240.
22
F(p
pm)
P0
4(3
-)(p
pm)
0.07
<
1<
0.05
<
10.
23
< 1
1.2
<1
0.32
<
10.
54
< 1
0.57
<
12.
4 <
10.
5 <
10.
15
<1
0.39
<
10.
15
<1
0.76
<
10.
40
< 1
< 0.
05
< 1
< 0.
05
< 1
< 0.
05
< 1
0.33
<
11.
8 <
10.
49
< 1
0.37
<
11.
8 <
10.
88
< 1
< 0
.05
< 1
0.06
<
10.
06
< 1
0.49
<
10.
61
< 1
1.5
<1
0.07
<
18.
4 <
106.
9 <
11.
4 <
12.
2 <
10.
32
< 1
0.22
<
10.
27
< 1
0.6
<1
0.07
<
10.
63
< 1
1.2
<1
0.48
<
1<
0.0
5 <
12.
7 <
10.
31
< 1
0.16
<
1
Pbp
pb
<0.
4<
0.1
0.1
<0.
4<
0.1
<0.
40.
6 1.2
0.5
0.6 0.1
0.1
<0.
4<
0.4
<0.
3<
0.4
<0.
41.
2 2.4
<0.
4<
0.4
<0.
4<
0.3
<0.
4<
0.1
<0.
11.
70.
82.
6 0.3 26
<0.
44.
3 3.2
<0.
1<
0.4
<0.
3<
0.4
<0.
4<
0.4
<0.
4<
0.4
<0.
4<
0.1
<0.
4<
0.1
Znp
pb 6.7 <6 7
30 50 91 <2
150
180
67 120 51 3
310 4.1
6.1 <2
89 550
90 94 610
420
<2
<6
50 240
270
590 10
2700
2400 53
056
0 6019
0 45 29 21 110
1500 94 <
215
075
6
Sam
ple
# T
ype
to
TM
T-0
8T
MT
-09
TM
T-1
0T
MT
-11
TM
T-1
2T
MT
-13
TM
T-1
4T
MT
-15
TM
T-1
5ST
MT
-16
TM
T-1
7T
MT
-18
TM
T-1
9T
MT
-20
TM
T-2
1T
MT
-22
TM
T-2
3T
MT
-24
TM
T-2
5T
MT
-26
TM
T-2
7T
MT
-28
TM
T-2
9T
MT
-30
TM
T-3
1T
MT
-32
TM
T-3
3T
MT
-34
TM
T-3
5T
MT
-36
TM
T-3
7T
MT
-38
TM
T-3
9T
MT
-40
TM
T-4
1T
MT
-42
TM
T-4
3T
MT
-44
TM
T-4
5T
MT
-46
TM
T-4
7T
MT
-48
TM
T-4
9T
MT
-50
TM
T-5
1T
MT
-52
stre
amsp
ring
spri
ngsp
ring
spri
ngst
ream
spri
ngst
ream
stre
amst
ream
spri
ngst
ream
adit
spri
ngsp
ring
spri
ngsp
ring
stre
amst
ream
stre
amad
itsp
ring
spri
ngsp
ring
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
spri
ngst
ream
spri
ngsp
ring
spri
ngst
ream
stre
amsp
ring
spri
ngst
ream
Lat.
(dec)
37.4
0927
194
37.41515861
37.4
0910
778
37.4
1095
778
37.41123972
37.3
9495
2537.40175861
37.40465306
37.40465306
37.4
0384
583
37.40384778
37.3992075
37.38962917
37.3
9790
806
37.3
9844
694
37.40416722
37.41266056
37.38808111
37.38493056
37.3
7722
889
37.37634694
37.3
8829
278
37.38821722
37.38720806
37.3
9010
2537
.393
9758
337.39490917
37.39620278
37.39071833
37.39038361
37.39218861
37.3
8944
2537.38767667
37.3
8792
083
37.38549222
37.3
7221
833
37.3
7688
611
37.38183167
37.3
7634
7537
.384
1288
937
.387
6388
937
.389
2838
937.38549806
37.38930389
37.39216306
37.3
9519
611
Long
, (dec)
-106.5712058
-106.5708561
-106.5561358
-106.5621419
-106
.548
4544
-106.551935
-106
.552
5594
-106.5546317
-106.5546317
-106.5705839
-106.5680917
-106
.555
9244
-106.5615492
-106
.591
3431
-106
.586
8539
-106.5898997
-106.5861111
-106
.562
8603
-106.5660606
-106
.582
0494
-106.5678889
-106.58125
-106.5821931
-106.5885064
-106
.586
5806
-106.5895261
-106
.584
0797
-106
.581
2414
-106
.578
0722
-106
.578
4239
-106
.571
7644
-106.5735667
-106
.572
5172
-106.5741067
-106
.570
7461
-106
.583
325
-106.5939483
-106.6022183
-106
.614
325
-106
.623
6317
-106
.615
4367
-106
.622
6744
-106.6075114
-106
.599
3564
-106
.599
9294
-106
.604
1092
Cuppb 3 23 4.5 1 1.8
19<0
.9 47 200
3.0 12 5.4
<0.9 96 <1 1
<0.9 12 220
30 19 6513
00<0
.95
4.2
250 52 130 3.4
2000
1100 170
220 24
3.0 29
<0.9 3 21 110 20 0.9
1800 10 0.79
Cdppb
0.9
<0.4
<0.4 0.7
<0.4 0.9
0.7 0.7 2
<0.4
<0.4
<0.4 0.5 2
<0.8 1
0.7 1 6.7
0.8
0.9 15 14
0.8
<0.4
<0.4 6.1
2.2
5.7
<0.4 29 24 8.1 6.8
<0.4 0.5
<0.8 0.6
0.9
0.9
5.4 1
0.7 1.8
0.6
<0.4
Nipp
b
<1
<0.5 0.6
5.2 4.3
9.6 2 16 20
4.0 11 4.9
5.6 31 0.3
<1
<1
9.2 78 14 4.0
110
110
<1 0.7
15 17 31 722
280
180 68 75 12 26 8.6
12 2 13 130 12 <1
180
7.2 1
Coppb
0.59 0.4
0.98 27 13 28 0.3 56 66
6.4 27 12
5.0
77 0.6
<0.1 0.2 16 150
29 3.3
210
200
<0.1
0.61 37 66 67 150 2.6
530
330
130
150 22 53 14 24 4.0
34 420 27
0.92 390
19 0.3
Moppb
<0.2
<0.1 0.3
<0.2
<0.1
<0.2
<0.2
<0.1 0.3
<0.2
<0.1
<0.1 0.4
<0.2
<0.1
<0.2
<0.2
<0.2 0.8
<0.2 0.5
<0.2 0.3
<0.2
<0.1
<0.1
0.70
<0.2
0.4
<0.1 130
200.
771
<0.1
<0.2
<0.1
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2 0.9
<0.2
<0.1
Gppb
<2
<0.
9<
0.9
<2
<0.
9 <
2
<2
<0.
9 2<
2<
0.9
<0.
9 <
2
<2
<0.
7<
2<
2<
27.
5<
2<
2 4 17 <2
<0.
90.
9<
2 2 2<
0.9 54 23 6 6.5
<0.
9 <
2
0.8
<2
<2
<2
<2
<2
<2
31
<2
<0.
9
As
ppb
Sb p
pb
Ag
ppb
<0.
9 <
0.1
<0.
1
<0.
9<
1<
0.9
<0.
9<
1<
0.9
<0.
9 1<
1
27<
0.9
<0.
9 <
0.9
<0.
9 <
0.9
5.3
<0.
9 1 1 1<
0.9
<1 2 1
<0.
9 2 <1 44 29 9.0 6.4
<1
<0.
9<
0.9
<0.
9<
0.9
<0.
9<
0.9
<0.
9<
0.9 60
<0.
9
0.2
0.1 0.5
0.1
0.1
0.4 0.1
0.3
0.2
<0.
1 0.
2 0.
7 0.
1 0.3
0.1 0.1
0.2
<0.
10.
2 <
0.1
<0.
10.
3 <
0.1
0.3
Srp
pb 60 46 1249
0 4213
030
034
034
044 78 88
1700 89 12 27 11
011
023
073 14
014
018
016 17 53 110
140
550 16
290
230
190
230
140
91 160
160 19 130
540
130 24 530
94 110
Sam
ple
#T
MT
-53
TM
T-5
4T
MT
-55
TM
T-5
6T
MT
-57
TM
T-5
8T
MT
-59
TM
T-6
0T
MT
-61
TM
T-6
2T
MT
-63
TM
T-6
4T
MT
-65
Typ
est
ream
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
Lat
. (d
ec)
37.3
9593
472
37.4
0391
278
37.4
0990
778
37.4
1552
056
37.4
0369
944
37.4
0360
694
37.3
9055
944
37.4
1079
278
37.4
0180
861
37.4
0373
694
37.3
9733
861
37.3
9046
694
37.3
9522
444
Lon
g, (
dec)
-106
.606
0078
-106
.598
0164
-106
.606
0814
-106
.606
9056
-106
.614
4556
-106
.615
3781
-106
.606
3675
-106
.623
0367
-106
.626
9361
-106
.646
7539
-106
.649
4178
-106
.607
4139
-106
.615
4733
pH
Sp. C
ond.
(uS
/cm
) D
is7.
285.
324.
466.
39 7.2
7.16
3.75
7.22
3.64
7.29
7.26
6.77
5.02
100 80 280 30 70 70 300 60 260 50 50 120
160
. 02
(mg/
1)
Tem
p (°
C)
Fe2
+ (m
g/1)
Fe
-Tot
(pp
m)
Al *
* (p
pm)
Mg
2+(p
pm)
K1.
11 3.8
3.8
4.2
12.8
17.8
15.1 7.8
6.7
9.6
10.7 7.5 15
1.11 3.
83.
84.
212
.817
.815
.1 7.8
6.7
9.6
10.7 7.5 15
0.07
0.03 8.
40.
020.
020.
012.
430.
33 5.2
0.06
0.05
0.46 3.
8
0.24
0.11 7.
7<
0.03
0.04
0.07
64.
50.
51 4.7
0.23
0.14
0.74 3.3
0.07
30.
11.
30.
020.
020.
014
6.3
0.05
74.
20.
039
0.02
60.
020.
63
2.1
0.76 1.
20.
39 1.1 1
3.1
1.3 1
0.87
0.74 2.
62.
4
u(p
pm)
1.4
7.2
2.2
0.68 1.
40.
32 1.6
0.74
10.
22 0.5
0.61
0.28
00
Sam
ple
#T
MT
-53
TM
T-5
4T
MT
-55
TM
T-5
6T
MT
-57
TM
T-5
8T
MT
-59
TM
T-6
0T
MT
-61
TM
T-6
2T
MT
-63
TM
T-6
4T
MT
-65
Typ
est
ream
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
Lat
. (d
ec)
37.3
9593
472
37.4
0391
278
37.4
0990
778
37.4
1552
056
37.4
0369
944
37.4
0360
694
37.3
9055
944
37.4
1079
278
37.4
0180
861
37.4
0373
694
37.3
9733
861
37.3
9046
694
37.3
9522
444
Lon
g, (
dec)
-106
.606
0078
-106
.598
0164
-106
.606
0814
-106
.606
9056
-106
.614
4556
-106
.615
3781
-106
.606
3675
-106
.623
0367
-106
.626
9361
-106
.646
7539
-106
.649
4178
-106
.607
4139
-106
.615
4733
Mn
(ppm
) C
a0.
024
0.03
2 10.
0006
0.06
50.
0098
0.27
0.01
80.
082
0.02
0.01
10.
270.
19
2+(p
pm)
Na
1+(p
pm)
Si'
12 4.7
9.5 3
6.2
6.1 15 5.3
5.4
7.8
5.8 11 13
4.8
4.8 11 3.5
4.7
3.2
4.5
7.7
2.7
3.3
3.2
2.6
3.7
(ppm
) SO
4 (
) (p
pm)
Cl
(ppm
)11 21 20 8.1
9.5
4.7 13 2.9 10 5.1
3.8
3.8
5.8
32 29 83 2.3 21 21 94
2.1 65 1.5
1.1
41 63
0.27
0.40
0.23
0.13
0.27 0.25
0.18 1.
1<
0.1
<0.
10.
260.
200.
14
F(p
pm)
P0
4(3
-)(p
pm)
Pbp
pb0.
10.
53<
0.05
0.11
0.06 0.26
0.06 0.
1<
0.05
0.05
0.08
0.16
<0.
05
<1
<0.
1<
1 <
0.4
< 1
< 0.
4<
1 <
0.4
< 1
< 0.
3<
1 <
0.1
< 1
< 0.
4<
1 <
0.4
<1
<
0.1
< 1
< 0.
4<
1 <
0.4
< 1
< 0.
3<
1 <
0.4
Znp
pb 1073
0 <2
120 3.3 32 <2
24 <6
<2
12 16 <2
to
Sam
ple
#T
MT
-53
TM
T-5
4T
MT
-55
TM
T-5
6T
MT
-57
TM
T-5
8T
MT
-59
TM
T-6
0T
MT
-61
TM
T-6
2T
MT
-63
TM
T-6
4T
MT
-65
Typ
est
ream
spri
ngsp
ring
spri
ngst
ream
stre
amst
ream
spri
ngsp
ring
stre
amst
ream
stre
amst
ream
Lat
. (d
ec)
37.3
9593
472
37.4
0391
278
37.4
0990
778
37.4
1552
056
37.4
0369
944
37.4
0360
694
37.3
9055
944
37.4
1079
278
37.4
0180
861
37.4
0373
694
37.3
9733
861
37.3
9046
694
37.3
9522
444
Lon
g, (
dec)
-106
.606
0078
-106
.598
0164
-106
.606
0814
-106
.606
9056
-106
.614
4556
-106
.615
3781
-106
.606
3675
-106
.623
0367
-106
.626
9361
-106
.646
7539
-106
.649
4178
-106
.607
4139
-106
.615
4733
Cup
pb 0.5
<0.
9<
0.9
<0.
9 126
<0.
946 19
<0.
9 1<
114
Cdp
pb<
0.4
0.6
0.6 1
<0.
8<
0.4
0.7
0.6
<0.
40.
60.
6<
0.8 1
Nip
pb4
16 <1 2 0.4
6.2 1
5.5
<0.
5<
1 1 1.8
<1
Cop
pb 0.5
9.2
0.1
0.53 0.
2 100.
40 15 0.3
0.3
1.1 1.3
0.2
Mop
pb<
0.1
<0.2
<0.
2<
0.2
<0.
1<
0.1
<0.2
<0.2 0.2
<0.
2<
0.2
<0.
1<
0.2
Qrp
pb<
0.9
<2
<2
<2
<0.
7<
0.9
<2
<2
<0.
9<
2<
2<
0.7
<2
Asp
pb <1 2
<0.
9<
0.9
<0.
9<
1<
0.9
7.0 <1
<0.
9<
0.9
<0.
9<
0.9
Sbp
pb<
0.1
<0.
10.
2<
0.1
<0.
1<
0.1
<0.
10.
7<
0.1
<0.
1<
0.1
<0.
10.
2
Srppb 47
140 33
69
91
130
40
62
48
65
140
200
100
Tab
le 4
. G
eom
etri
c m
ean
of w
ater
s dr
aini
ng s
peci
fic
alte
ratio
n as
sem
blag
es.
N r
epre
sent
s nu
mbe
r of
sam
ples
. Se
e pl
ate
5 fo
r de
scri
ptio
n of
alte
ratio
n as
sem
blag
es.
Not
e: p
H d
enot
es m
edia
n va
lue.
Alt
erat
ion
asse
mbl
age
N PH Sp. C
ond.
(uS
/cm
)Fe
-Tot
(pp
m)
Al3
+(p
pm)
Mg
^ (P
Pm)
K1+
(ppm
)
Mn
(ppm
)C
a^C
ppm
)N
a1+
(ppm
)Si
4+(p
pm)
S04
("-)
(ppm
)C
r (p
pm)
F- (
ppm
)P
04 ("
-) (p
pm)
Pb (
ppb)
Zn (p
pb)
Cu(
ppb
Cd
(ppb
)N
i (pp
b)C
o (p
pb)
Mo
(ppb
)C
r (p
pb)
Zn+C
u+C
d+Pb
+C
o+N
i
AR
G 3
2.59
597.
7926
.81
9.67
1.02
0.38
0.05
3.66
2.28
21.1
333
1.44
0.64
0.34
0.70
0.18
40.2
353
.78
1.36
15.7
530
.23
0.26
3.93
185.
47
F 2
6.56
24.4
90.
070.
010.
472.
350.
002.
842.
3113
.42
1.79
0.21
0.04
0.70
0.28
2.92
0.79
0.89
0.70
0.07
0.14
1.40
5.96
PRO
P Q
A+
SIL
Q
SP
»QS
P-K
15
6.77
87.8
10.
250.
061.
500.
510.
029.
143.
354.
8113
.69
0.19
0.08
0.70
0.24
5.57
2.45
0.63
1.02
0.53
0.14
1.09
15.1
9
1
5.44
20.0
01.
200.
320.
301.
300.
002.
601.
9014
.00
8.70
0.18
0.06
0.70
0.07
4.20
5.00
0.28
0.70
0.61
0.07
0.63
10.8
6
4
2.78
1914
.95
187.
0465
.08
27.5
11.
056.
1954
.31
2.91
30.2
014
03.8
90.
911.
900.
701.
3366
2.23
215.
067.
3473
.04
144.
101.
216.
5111
20.6
0
QSP
-K 13
3.22
591.
9711
.48
10.3
85.
760.
880.
8311
.98
2.51
20.3
222
5.02
0.39
0.44
0.84
0.55
148.
9635
.40
2.03
18.6
339
.33
0.26
2.10
276.
02
QSP
-PX
W
-AS
+ F
W-A
S »
PR
OP
2
3.04
923.
3652
.65
20.0
018
.44
1.79
3.24
60.6
04.
5313
.78
455.
420.
411.
100.
700.
7716
4.32
96.9
51.
1817
.89
60.7
90.
141.
1235
6.25
2
6.63
119.
1610
.20
0.09
4.27
1.38
0.37
13.6
53.
9111
.49
29.2
80.
400.
530.
700.
1714
.49
2.12
0.44
1.77
5.14
0.20
0.94
29.3
9
5
4.46
206.
631.
881.
292.
431.
840.
439.
984.
9614
.82
77.3
10.
330.
230.
700.
1646
.71
1.01
0.48
5.81
5.65
0.11
1.02
69.9
4
FE T
OT
AL
mg/
1C
ON
DU
CT
IVIT
Y
o
Sv^T
^o
pH
NJ
OJ
*.
L/l
O
N
-J
OO
&TT
O
100000
10000
1000
100
10
-
-
-
K>
A*
ARC
F
^0
A
PROP
*
A*ww
%
!4
QA-SIL
V
QSP
4*+
* ^
^̂
QSP-K QSP-PX
0W-AS
F
*
40
* 4
W-AS
PROP
1000
100
10
0.1
0.01
0.001
10000
1*a, a,
£ 1000
100
10a
SI
ALTERATION TYPE
fig. 4
-
"
"
_
tO
ARC
^ &4
F
^
f^ C^
PROP
4
QA-SIL
V
QSP
A4> o*
4
QSP-K QSP-PX
4
0
W-AS
F
*
4
W-AS
PROP
ALTERATION TYPE
fig. 5
-
-
*o
*ARC
O
F
t
I 4
PROP QA-SIL
."
QSP
OA 4
»>
**
QSP-K
4
QSP-PX
^
O
W-AS
F
*
»«o
/W-AS
PROP
ALTERATION TYPE
fig. 6
33
MODIFIED FIKCLIN PLOT (FICKLIN AND OTHERS, 1992)
10
0.
o.oi
0.001
-High acid,^ high metal
High acid, mod. metal
Aci^ I Near-neutral, moderate metal, moderate metal^
^fckV._ _ I _ *_T_ _
High acid, low metal
Acid, low metal
«++ +*Near-neutral, low metal
-10123456789
pH
34