NPDES Permit Application 2002

Sheet1BP Products North America Inc. - Whiting RefineryWastewater & Water Treatment Additive DataAdditive NameDemand Trac 480Zinc Chloride - 50%Phosphoric Acid - 75%BPC 68160BPC 67525BPC 68970BPC 65500BPC 67280BPC 67385BPC 68095BPC 67375Sodium Hypochlorite - 12.5%BPC 67015BPC 60005BPW 75890BPB 59396Sodium Bisulfite - 40%BPB 59455BPB 59460BPB 59470Guardion 9405Praestol 187KPraestol K122LPraestol K122LPraestol K230FLPraestol K260FLPraestol K260FLPraestol K260FLPraestol A304OL71-D5 PLUS AntifoamFerriclearFerriclearPhosphoric Acid Solution50% CausticST70BPB 55715BT-3000BT-4000SUR-GARD 1700Nalco 352 Neutraling AmineNalco 73202Nalco 8306 PLUSSulfuric Acid50% CausticSodium Hypochlorite - 12.5%Sodium Bisulfite - 40%BPB 59466BPC 65610BPB 59316Potassium PermanganatePotassium PermanganatePotassium PermanganateHydrochloric Acid - 31%BPW 76453BPW 76030BPW 76030Cronox 245 ESStabrom 909Zetag 7875 FS25SPC 880Magnafloc E 30Magnafloc LT7996Zetag 7848BPB59430CL2OUT1100BPC 6000530% sol HCL50 wt% sol NAOHBPB 59455BPB 59470Elimin-OxTriAct 1800SupplierBaker PetroliteVopak (commodity chemical)Vopak (commodity chemical)Baker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteK. A. SteelBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteAlexander Chemical (commodity chem.)Baker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteDegussa StockhausenDegussa StockhausenDegussa StockhausenDegussa StockhausenDegussa StockhausenDegussa StockhausenDegussa StockhausenDegussa StockhausenONDEO NalcoEaglebrookEaglebrookPCS Purified PhosphatesOld World Industries, Inc.ONDEO NalcoBaker PetroliteONDEO NalcoONDEO NalcoONDEO NalcoONDEO NalcoONDEO NalcoONDEO NalcoMarsulexOld World Industries, Inc.K. A. SteelAlexander Chemical (commodity chem.)Baker PetroliteBaker PetroliteBaker PetroliteCarus Chemical CompanyCarus Chemical CompanyCarus Chemical CompanyVopak (commodity chemical)Baker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteBaker PetroliteCibaBakerPetroliteCibaCibaCibaBaker PetroliteBaker PetroliteBaker PetroliteBP AmocoBPAmocoBaker PetroliteBaker PetroliteNalco CompanyNalco CompanyExisting or NewExisting / New for SBS UnitExisting / New for SBS UnitExisting / New for SBS UnitExistingExisting / New for SBS UnitExisting / New for SBS UnitExistingExisting / New for SBS UnitExistingExistingExistingExisting / New for SBS UnitExisting / New for SBS UnitExistingExistingExistingExisting for Utilities, new for PIBExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingExistingNewExistingExistingNewNewNewNewNewNewNewNewNewNewNewNewNewNewNewNewNewNewNew (similar to ST70 already approved)NewNewNewNewExistingReplacement for Nalco 1700Replacement for Nalco 352OutfallOutfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 002Outfall 002Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 001Outfall 002Outfall 002Outfall 002Outfall 002Outfall 002Outfall 001Outfall 001Point of InjectionCooling Towers (#1 - #6) & SBS UnitCooling Towers (#1 - #6) & SBS UnitCooling Towers (#1 - #6) & SBS UnitCooling Towers (#1 - #6)Cooling Towers (#1 - #6) & SBS UnitCooling Towers (#1 - #6) + PIB plant + Administration Building Cooling Tower + SBS UnitRaw Water to Cooling TowersCooling Towers (#1 - #6) & SBS UnitPIB Cooling TowerPIB Cooling TowerAdministration Building Cooling TowerCooling Towers (#1 - #6) + PIB plant + SBS UnitCooling Towers (#1 - #6) + PIB plant + Administration Building Cooling Tower + SBS UnitRaw Water to Lime SoftenersHot Lime SoftenersBoiler Feed WaterHot Lime Softener Effluent and condensate drum treatment at PIBSteam condensate systemSteam condensate systemBoiler Feed WaterZeolite Resin @ Water Treating PlantDAF influentActivated Sludge prior to ClarificationActivated sludge thickening prior to DAFDAF influentActivated Sludge prior to rotary drumThickened oily sludge prior to filter press dewateringThickened scrubber solids prior to filter press dewateringIncinerator Scrubber EffluentAeration Basin & Clarifier inletsAcitvated Sludge Plant ClarifiersIncinerator Scrubber EffluentActivated Sludge PlantBarscreen and/or Oil/Water Separator effluent and/or Activated Sludge PlantWWTP Effluent Recycle to Cooling TowersBoiler Feed WaterCogen Boiler BlowdownCogen Boiler BlowdownCogen Boiler Feed WaterCogen Boiler Feed WaterCogen Cooling TowerCogen Cooling TowerCooling Towers (#1 - #6)SBS Unit TowerWWTP Intake# 6 Separator EffluentSteam Condensate SystemCooling Towers (#1 - #6)Boiler Feed WaterActivated Sludge Recycle LineSpent phenolic causticActivated Sludge Plant InfluentCooling Towers (#1 - #6)DAF influentDesalter Brine EffluentDAF influentCooling Towers (#1 - #6)WWTP Effluent Recycle to Cooling TowersThickened oily sludge prior to filter press dewatering.Incinerator Scrubber EffluentDAF influentDAF influentDAF influentSRU/VRU steam condensate systemWWTP Effluent Recycle to Cooling TowersPipestillsOTCW Heat exchanger inletOTCW Heat exchanger outletSteam condensate systemSteam condensateDemin plant effluentDemin plant effluent and WCE deaerator effluentFeed Rate352,896 grams/day63,231 grams/day59,575 grams/day140,037 grams/day5711 grams/day (annual average)4,356 grams/day34,214 mg/l1641 grams/day (average daily use)50,340 grams/day15,609 grams/day4378 grams/day3,716,613 grams/day3822 grams/day155,760 grams/day540,763 grams/day22,843 grams/day231,432 grams/day + 6,300 grams/day at PIB322,060 grams/day3,403 grams/day107,047 grams/day114,635 grams/day167,750 grams/day27,850 grams/day238,970 grams/day302,515 grams/day37,040 grams/day101,535 grams/day14,500 grams/day36,775 grams/day47,727 grams/day486,864 grams/day127,600 grams/day481,760 gram/day7,200,800 grams/day (as needed)101,364 grams/day209,091 grams/day41,364 grams/day40,454 grams/day19,772 grams/day38,864 grams/day96,384 grams/day37,545 grams/day1,625,867 grams/day30,000 grams/day (estimated)2,117,900,000 grams/day550,380,000 grams/day49,164 grams/day155,431 grams/day232,221 grams/day24,700 grams/day121,120 grams/day189,250 grams/day1,934,135 grams/day167,750 grams/day217,562 grams/day167,750 grams/day27,252 grams/day101,364 grams/day101,535 grams/day36,775 grams/day302,515 grams/day302,515 grams/day302,515 grams/day36,015 grams/day101,364 grams/day23,364 grams/day505 lbs/day248 lbs/day4,831 grams/day1,606 grams/day160 grams/day1300 grams/dayWater Treatment Concentration5.0 - 7.0 mg/l (active residual)1.5 mg/l6.5 mg/l2.0 mg/l1 - 3 mg/l100 - 200 mg/l5.0 mg/l1.0 mg/l5 mg/l4 - 6 mg/l as orthophosphate8 mg/l0.2 0.5 mg/l free available chlorine30 mg/l3 - 4 mg/l15 mg/l0.8 mg/l2.0 mg/l (40% Sodium bisulfite)13.4 mg/l15 mg/l9.94 mg/l (annual average)dosage based on size of bed2.3 mg/l9.3 mg/l3.3 mg/l4.18 mg/l0.5 mg/l1.4 mg/l0.2 mg/l0.52 mg/lconc varies w/ current conditions50 mg/l56.2 mg/l2.4 mg/l47.6 mg/l0.30 mg/l6.0 mg/l5.0 mg/l5.0 mg/l5.0 mg/l10.0 mg/l35 mg/l8.0 mg/l21.6 mg/l30.0 mg/l4.4 mg/l as product and 1.0 mg/l free available chlorine2.8 mg/l8.5 mg/l4 - 5 mg/l7.0 mg/l4.8 mg/l530 mg/l0.3 mg/l75 mg/l3 mg/l191 mg/l2.3 mg/l3.45 mg/l0.30 mg/l1.4 mg/l0.52 mg/l4.18 mg/l4.18 mg/l4.18 mg/l12 mg/l0.30 mg/l3 - 4 mg/l300,000 mg/l500,000 mg/l13.4 mg/l9.94 mg/l (annual average)no residual1000 mg/l132 mg/l>1000 mg/l177 mg/l3318 mg/l18.6 mg/l8.3 mg/l16,479 mg/l152 mg/l400 mg/l194 mg/lFathead Minnow 24h/LC50>10,000 mg/lCerodaphnia 48h/LC50285 mg/l2875 mg/l483 mg/l1.57 mg/l224 mg/l6.4 mg/l68 mg/l150 mg/l1.75 mg/l1.75 mg/l1.75 mg/l1.75 mg/l1.75 mg/l1.75 mg/l11.0 mg/l1.57 mg/l891 mg/l0.42 mg/l0.25 mg/l11.0 mg/l0.25 mg/l0.25 mg/l0.25 mg/l68 mg/lDaphnia Magna 48h/LC 505.0 mg/l333 mg/l11 mg/l224 mg/l15.3 mg/l130 mg/l4.2 mg/l>1000 mg/l331 mg/l>1000 mg/l5.0 mg/l4.8 mg/l11,000 mg/l250-400 mg/lDaphnia Magna 24h/EC50144 mg/l>1000 mg/lDaphnia Magna 24h/LC005 - 40 mg/l96 mg/lDaphnia Magna 96h/LC005 - 40 mg/lRainbow Trout 96h/LC5025 mg/l27 mg/l1.94 mg/l310 mg/l4.5 mg/l>1000 mg/l384 mg/l>1000 mg/l140 mg/l1.94 mg/l543 mg/l0.6 mg/l1.3 mg/l1.3 mg/l187 mg/l>1000 mg/l360 mg/l200 mg/lBluegill Sunfish 96h/LC50>173 mg/l24 mg/l5.3 mg/l>1000 mg/l5.3 mg/l500 mg/l0.9 mg/l3.8 mg/l>1000 mg/l190 mg/lLepomis macrochrius 48 hr/LC502.7 mg/l2.7 mg/l2.7 mg/lAcartia tonsa 48h/LC504.0 mg/l31.4 mg/lPimephales promelas 48h/LC5011.0 mg/l11.0 mg/l11.0 mg/l11.0 mg/l11.0 mg/l11.0 mg/l31.4 mg/lPimephales promelas 96h/LC50; 180 mg/l CaCO316.3 mg/l0.69 mg/lPimephales promelas 96h/LC50; 100 mg/l CaCO30.75 mg/l127 mg/lThreespone stickleback 96h/LC50127 mg/l756 mg/lThreespone stickleback 96h/LC50 (aerated)756 mg/lZebra-fish (Brachydanio rerio) 96h/LC50122 mg/lFlannelmouth sucker 96h/LC501940 mg/lCoho salmon 96 h/LC50>1000 mg/lChinook salmon 96h/LC50>1000 mg/lChinook salmon 216h/LC005 - 40 mg/l>2250 mg/kgMosquito Fish 24h/LC50138 mg/l138 mg/lScenedesmus subspicatus 72h/EC501.9 mg/l6,000 mg/lMallard Duck LD501036 mg/kg>5633 ppmFreshwater Invertebrates & Fish Acute EC50/LC5050 - 100 mg/l25 - 100 mg/l> 500 mg/l10 - 50 mg/l10 - 50 mg/l>1000 mg/l> 500 mg/l10 - 50 mg/lFreshwater Algae Static Acute EC501 - 10 mg/l1 - 10 mg/l>1000 mg/l1 - 10 mg/lFreshwater Biodegradability 28 Day OECD 301D50%30 - 50%20 - 40%30 - 50%Freshwater Biodegradability 5 Day/2.0mg/l71%Freshwater Biodegradability 5 Day/3.8mg/l55%Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's > 7.0Relationship of toxicity to pHEffective pH range: 8.0 - 8.3Effective pH range: 7.0 - 8.8Effective pH range: 7.0 - 8.8Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 7.0 - 8.8Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 7.5 - 8.2Effective pH range: 7.5 - 8.2Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Toxicity does not change with pH.Toxicity increases outside the pH range of 5 - 10.Toxicity decreases with increasing pH.See above.Toxicity decreases with increasing pH.Toxicity decreases with increasing pH.Toxicity decreases with increasing pH.Toxicity does not change with pH.Toxicity does not change with pH.Toxicity increases with increasing pH.Effective pH range: 7.0 - 8.8Toxicity increases outside the pH range of 5 - 10.Effective pH range: 7.0 - 8.8Effective pH range: 8.0 - 8.3Effective pH range: 7.5 - 8.2Effective pH range: 7.5 - 8.2Effective pH range: 7.5 - 8.2Effective pH range: 7.0 - 10.0Effective pH range: 7.0 - 10.0Effective pH range: 7.0 - 10.0Effective pH range: 7.5 - 8.2Effective pH range: 1 - 14Effective pH range: 1 - 14. Toxicity of cationic polymers decrease at pH's>7.0Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC.Effective pH range: 7.0Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 8.0 - 8.3Effective pH range: 7.5 - 8.2nonenoneRelationship of toxicity to water hardnessEffective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Toxicity does not change with water hardness.Toxicity increases with increasing water hardness.Toxicity increases with increasing water hardness.See above.Toxicity does not change with hardness.Toxicity does not change with hardness.Toxicity does not change with water hardness.Toxicity does not change with water hardness.Toxicity increases slightly with increasing water hardness.Toxicity does not change with hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Toxicity increases with increasing water hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity decreases with increasing water hardness and increasing TOC. Toxicity decreases with increasing humic acid concentration.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.Effective hardness 150 - 160 mg/l as CaCO3. Literature indicates that toxicity generally increases with decreasing hardness.nonenoneN Octanol-Water Partition Coefficient5.51.70.10.10.180.222.462.31.7

&LFor IND000810861&CPage &P&RRevised 11/03/2006Digital Business Client User:g/l

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