beharra springs deep-1 exploration and appraisal
TRANSCRIPT
Plan WAA 4120 ENV PLN
CDN/ID 18065953
BEHARRA SPRINGS DEEP-1 EXPLORATION AND APPRAISAL Environment Plan Summary Under the Petroleum and Geothermal Energy Resources Act 1967, an EP and EP Summary is required to be prepared, approved and implemented for applicable activities. The purpose of the EP is to provide an outline of the activities associated with BSD-1 along with a description of the environmental management measures to mitigate any potential environmental impacts from those activities. This document provides a public summary of the EP that has been submitted to DMIRS for assessment.
Review record
Rev Date Reason for issue Reviewer/s Consolidator Approver
0 14/02/2019 Final for Submission to DMIRS AF DG
1 18/03/2019 Final for Submission to DMIRS AF DG
2 22/05/2019 Updated Chemical Disclosure AF DG
3 27/05/2019 Updated Chemical Disclosure AF DG
4 05/09/2019 Updated Chemical Disclosure CB DG
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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Table of contents
1. Introduction 4
1.1 Background 4
1.2 Scope 4
1.3 Nominated Operator 4
2. Definitions/Acronyms 4
3. Description of Activity 5
3.1 Location of Project 5
3.2 Timeframe and Schedule 6
3.3 Overview of Activities 6
3.3.1 Site preparation operations 6 3.3.2 Drilling operations 6 3.3.3 Well test operations 6 3.3.4 Well Handover 6
4. Description of the Environment 6
4.1 Regional Landform and Climate 6
4.2 Geology and Soils 7
4.2.1 Geomorphology 7 4.2.2 Soils 7
4.3 Hydrology 7
4.3.1 Surface Water and Drainage 7 4.3.2 Groundwater 7 4.3.3 Yarragadee Aquifer 7 4.3.4 Superficial Aquifer 8
4.4 Vegetation 8
4.4.1 Environmentally Sensitive Areas 8 4.4.2 Ecological Communities 8
4.5 Weeds and Pathogens 8
4.6 Fauna 9
4.7 Socio-economic Environment 10
4.7.1 Land Use and Economic Environment 10
4.8 Natural Heritage 10
4.9 Indigenous and Non-Indigenous Cultural Heritage 10
4.9.1 Native Title Applications 10 4.9.2 Ethnology 10 4.9.3 Archaeology 10
5. Environmental Management Strategies 11
6. Implementation strategy 15
6.1 Management System Overview 15
6.2 Environment Plan Review 15
7. Consultation 15
7.1 Ongoing Consultation 16
8. References 17
Table of figures
Figure 3.1: Regional Map 5
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List of tables
Table 4-1: Significant Fauna Species Known or Likely to occur within 5km of the BSD-1 well location 9
Table 5-1 Summary of Environmental Hazards and their associated Aspects and Management and Mitigation measures 12
Table 8.1: Stakeholder Consultation Undertaken 16
List of appendices
Appendix A Chemical Disclosure 18
A.1. Drilling Fluid Chemical Disclosure 18
A.2. Cement and Spacer (Alternate) Chemical Disclosure 45
A.4. Drilling Fluid for Conductor Installation 54
A.5. SDS 59
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1. Introduction
1.1 Background
Beach Energy Limited acquired Lattice Energy Resources (Perth Basin) Pty Ltd previously named Origin Energy Resources Limited on 31 January 2018. Lattice is the majority owner and the nominated operator of the Beharra Springs Gas Facility within petroleum production license L11. Within L11, Beach Energy is proposing to drill an exploration and appraisal well named Beharra Springs Deep-1.
1.2 Scope
This scope of this EP summary covers the following activities:
• Site preparation operations,
• Drilling operations,
includes completion or decommissioning of the well,
• Well test operations,
Includes final suspension of the well.
1.3 Nominated Operator
The nominated operator of the activity is:
Beach Energy Limited
25 Conyngham St,
Glenside SA 5065,
Phone: (08) 8338 2833,
www.beachenergy.com.au
Attention: Head of Environment
2. Definitions/Acronyms
Definitions of terms used in this document:
Term/Acronym Definition/Expansion
ALARP As Low as Reasonably Practicable
Beach Energy Beach Energy Limited being the sole owner of Lattice
BSD-1 Beharra Springs Deep-1
DIA Department of Indigenous Affairs
DoW Department of Water
DPLH Department of Planning, Lands and Heritage
EP Environment Plan
EPBC Act Commonwealth Environment Protection and Biodiversity Conservation Act 1999
ERP Emergency Response Plan
ESA Environmentally Sensitive Areas
FCT Floristic Community Type
HES Health, Safety and Environment
HSEMS Health, Safety Environment Management System
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Term/Acronym Definition/Expansion
Lattice Lattice Energy Resources (Perth Basin) Pty Ltd being the title holder and nominated operator of the L-11 production licence
LOWC Loss of Well Control
NGER Act National Greenhouse and Energy Reporting Act 2007
Origin Origin Energy Resources Limited
OSCP Oil Spill Contingency Plan
PGER€R Petroleum and Geothermal Energy Resources (Environment) Regulations
PTW Permit to Work
VSP Vertical Seismic Profiling
WMP Well Management Plan
WSM Well Site Managers
3. Description of Activity
3.1 Location of Project
The BSD-1 well location is within the locality of Arrowsmith, in the Shire of Irwin, located 20km south of Dongara and 350km north of Perth (Figure 3.1). The BSD-1 well location is approximately 260m from the Beharra Springs Gas Facility (coordinates for the Beharra Springs Gas Facility are:-29.463; 115.140 [WGS84]).
Figure 3.1: Regional Map
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3.2 Timeframe and Schedule
Activities covered under the EP are planned to commence in May / June 2019 and are anticipated to be complete in Q4 2019.
3.3 Overview of Activities
3.3.1 Site preparation operations
Prior to the start of drilling operations, the site must be prepared and properly equipped. Activities undertaken during site preparation operations include the following:
• Vegetation clearing and preparation of access tracks and drill site,
• Well site construction - comprising levelling, sheeting and preparation of surfaces to support compressive loads and limit erosion to the existing landscape,
• Conductor installation,
• Construction of lined mud sump, turkey’s nest, Vertical Seismic Profiling (VSP) pit and well cellar,
• Installation of the drilling flare pit (or possibly the well test flare pit),
3.3.2 Drilling operations
Following site preparation operations, drilling operations may commence. Activities associated with drilling operations includes:
• Mobilisation of the drilling package, ancillary services, site office, personnel and supplies,
• Conducting the exploration drilling activities,
• Evaluating the well, completion and suspension or decommissioning of the well,
• Demobilisation of the drilling package, ancillary services, site office, personnel and supplies.
3.3.3 Well test operations
Once drilling activities are complete and hydrocarbons are flowing from the reservoir, the properties of the reservoir are tested. Well testing involves the following activities:
Construction of the well test flare pit (if not done during site preparation operations),
Mobilisation of the well test package, ancillary services, site office, personnel and supplies,
Conduct the well test operations to evaluate the well,
Demobilisation of the well test package, ancillary services, site office, personnel and supplies.
3.3.4 Well Handover
Upon completion of the drilling and well testing activities, the well / well site will be handed over to and managed under a care and maintenance regime (dependent on the well status).
4. Description of the Environment
4.1 Regional Landform and Climate
The BSD-1 well location is located within the coastal highlands of the Mid West region of WA within the Lesueur Sandplain subregion of the Geraldton Sandplains Bioregion (Department of the Environment 2012). The Geraldton Sandplains Bioregion (Interim Biogeographic Regionalisation for Australia, Version 7) is composed mainly of proteaceous scrub-heaths, rich in endemics, on the sandy earths of an extensive, undulating, lateritic sandplain mantling Permian to Cretaceous strata (Department of Conservation and Land Management 2002).
The BSD-1 well location has a ground elevation of ~51m AHD.
The regional climate is classified as dry Mediterranean with cool wet winters and hot dry summers. The mean monthly minimum temperature recorded for Geraldton ranges from 8.9°C in August to 19.2°C in February and the mean monthly maximum temperature ranges from 19.5°C in July to 32.6°C in February (Bureau of Meteorology 2018).
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The average annual rainfall is 440 mm with the majority of rainfall occurring during the winter months (Bureau of Meteorology 2018). A strong south-west sea breeze is a part of summer weather conditions. The winds arrive between 10:00 am and 12:00 pm and can reach 30 knots. The winds during the winter months are more variable and influenced by the cold fronts coming in from the Indian Ocean.
4.2 Geology and Soils
The BSD-1 well location lies within the sedimentary Perth Basin. This basin lies onshore and offshore, and extends for about 700km along the southern portion of the west coast of Western Australia. The basin is bounded to the east by the Darling Fault, which extends the full length of the basin. The onshore portion of the basin averages 65km in width and extends from the southern coast to Geraldton in the north. The dominant feature in the northern section of the Perth Basin is the Dandaragan Trough, in which up to 20km of sediments have been deposited.
4.2.1 Geomorphology
The BSD-1 well location is situated in the geomorphic unit ‘Eneabba Plain’ (Playford et al. 1976). This unit is a low-lying area between the Spearwood Dune System and the Gingin Scarp. The plain is restricted to the area north of Cockleshell Gully. The plain consists of a series of shoreline, lagoon and dune deposits of early Pleistocene to possibly late Tertiary age, which locally have high concentrations of heavy minerals. These deposits are associated with a series of low alluvial fans fronting the Gingin Scarp (Playford et al. 1976). The streams have ill-defined channels and form ephemeral lakes.
4.2.2 Soils
The BSD-1 well location is situated in the northern agricultural region of West Midlands and the soil-landscape zone is ‘Geraldton Coastal’ code 221 (Schoknecht et al. 2004). This soil landscape zone is characterised by low hills of Tamala limestone and recent calcareous and siliceous dunes with alluvial plains and sand sheets. Soils are mainly shallow and deep sands with some loamy and sandy earths.
The soil systems that overlap the BSD-1 well location as identified by the Department of Primary Industries and Regional Development (2018) are classified as:
• Beharra System (221Be): Level to very gently inclined drainage depressions, swamps and associated dunes at low positions in the landscape; Yellow and pale deep sands, some sandy duplexes, loams and wet soils
• Correy System (221Cy): Broad sandy alluvial fan of the lower Arrowsmith River. Pale deep sands predominate, with grey shallow sandy duplexes, moderately deep sandy gravels and yellow deep sands less common.
4.3 Hydrology
4.3.1 Surface Water and Drainage
The BSD-1 well location is situated in the Arrowsmith River surface water sub-catchment of the West Midlands Region (DoA 2007; DoW 2017). This sub-catchment is 183,326 ha and predominately flows in an east to west direction into the Dandaragan Plateau across the Urella Fault. The Arrowsmith Region has a well developed dendritic drainage system which discharges into swamps and lakes of the interdunal depressions of the Eneabba Plain (Earth Tech 2002).
The closest rivers to the BSD-1 well location are the Irwin River and the Arrowsmith River. The Irwin River drains the Lockier River, Sand Plain Creek and numerous other smaller and intermittent drainage lines, prior to entering the Indian Ocean at Dongara. The poorly defined drainage lines of the Arrowsmith River flow in a westerly direction to the south of L11 prior to turning north-west to enter the terminal swamps and lakes of the Arrowsmith Lake area.
4.3.2 Groundwater
The larger aquifers located beneath the Arrowsmith Surface catchment Management Zone are the Leederville-Parmelia and Yarragadee Aquifers and the smaller aquifers include the Cattamarra and Eneabba-Lesueur Aquifers which are located west of the catchment (Earth Tech 2002).
4.3.3 Yarragadee Aquifer
The major aquifer which underlies the BSD-1 well location is the Yarragadee Aquifer. The formation is multi-layered with groundwater occurring within beds of fine to course-grained sandstone confined between thick sequences of shale and siltstone. The water table is fairly deep ranging up to as much as 150m below the surface.
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The water table comes to the ground surface in the Hill River valley where the aquifer is artesian around Hill River Spring. Springs, swamps and lakes such as Beharra Spring are areas of evaporative discharge (Earth Tech 2002).
4.3.4 Superficial Aquifer
The superficial aquifer on the Swan Coastal Plain consists of Quaternary and late Tertiary sediments which extend from Geraldton in the north to Busselton in the south. There are several principal formations within this aquifer including the Tamala Limestone. The aquifer consists mainly of quartz sands, calcareous sands and limestone in the Tamala Limestone. The groundwater level is close to the surface in the south and in the centre but may be as much as 60m below the surface, below the crests of the Tamala Limestone dunes along the coast. The average salinity is 4 224mg/L and is hypersaline underneath the coastal lakes in the Perth area. The aquifer is developed for the Perth water supply but it is not a significant aquifer in the Dongara to Geraldton area where the groundwater salinity is generally non-potable.
Shallow groundwater lenses are located within the Tamala Limestone forming an unconfined aquifer in which the groundwater is mainly recharged from local rainfall (IRC Environment 2004).
The groundwater monitoring wells at the gas production facility are installed in the superficial aquifer which is predominately sand. The most recent groundwater monitoring event conducted by Senversa show standing water levels ranging from 10.89m below ground surface and 15.88m below ground surface (Senversa 2018) equivalent to an elevation of between 26.43 and 26.84m AHD. The inferred groundwater flow direction is to the west (Senversa 2017 and Senversa 2018)
4.4 Vegetation
The vegetation system present in the Beharra Springs area is the Eridoon system. A vegetation system consists of a particular series of plant communities recurring in sequence and mosaic pattern linked to topographical, pedological and / or geological features (Beard 1976).
The Eridoon system occupies “a flat coastal plain between the coastal limestone deposits and the Pleistocene shoreline”. On the plains and slopes of dunes the vegetation consists of scattered Eucalyptus todtiana and other small trees, an open layer of tall shrubs and a closed heath layer of small shrubs, usually dominated by Conospermum spp. On the sandhills the tree layer disappears and Banksia hookeriana and Xylomelum angustifolium become dominant. In winter wet depressions, the height of the heath reduces to 30cm with scattered Xanthorrhoea spp., while in wet areas Melaleuca thyoides and Melaleuca lanceolata to Melaleuca rhaphiophylla dominate. Occasionally these areas also have Casuarina obesa and Eucalyptus camaldulensis (Beard 1976).
4.4.1 Environmentally Sensitive Areas
The closest designated Environmental Sensitive Area (ESA) is located 6.9km south-west of the BSD-1 well location, outside of petroleum production license L11.
4.4.2 Ecological Communities
The dominant vegetation communities within petroleum production license L11 are described below (WEC 2009a). Several other woodland and thicket communities are also present:
• Floristic community type (FCT) 4a, Species rich Woodlands and Heaths on grey sand in the eastern portion of the Eneabba sandplain. Common species in FCT 4a include Conospermum boreale subsp. boreale, Ecdeiocolea monostachya, Eremaea beaufortioides, Hakea polyanthema (P3) and Banksia candolleana.
• FCT 3b - Low Woodland to Thicket of Banksia attenuata and B. menziesii over mixed shrubs dominated by myrtaceous species on brown or yellow sand on lower to mid slopes and plains.
4.5 Weeds and Pathogens
Previous surveys of vegetation within petroleum production license L11 have recorded four weed species as being present thus have the potential to be present within proximity of the BSD-1 well location. These are:
• Ursinia anthemoides (South African marigold),
• Arctotheca calendula (Capeweed),
• Echium plantagineum (Paterson's curse), and
• Hypochaeris glabra (Smooth catsear).
Of these four-weed species, only one, Paterson’s curse, is a declared pest under the Biosecurity and Agriculture Management Act 2007 (DPIRD 2017).
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In addition to indicating Cenchrus ciliaris (buffell grass) may be present within proximity of the BSD-1 well location.
Dieback (Phytophthora cinnamomi) infestations, a soil borne pathogen, have been recorded in the wider area but not within the vicinity of the BSD-1 well location. One infestation is located on private property and the other is in a gravel pit at the end of Mt Adams Road (HSA 2003). The environmental conditions such as low rainfall, sandy calcareous soils which provide good water drainage and unsuitable pH reduces the risk of dieback infestation at the BSD-1 well location.
4.6 Fauna
A search of the DPaW Nature Map database for a 5km buffer around the BSD-1 well location returned records for one threatened fauna species as listed in Table 4-1 below.
The EPBC Act Protected Matters search conducted for the BSD-1 well location identified six listed threatened species (4 birds and 2 mammals) and eight listed migratory species as known or likely to occur within a 5km buffer around the BSD-1 well location. The results of this search are summarised in Table 4-1.
Table 4-1: Significant Fauna Species Known or Likely to occur within 5km of the BSD-1 well location
Species Conservation Status
Federal WA(DPaW, 2017)
NatureMap 2018
Calyptorhynchus latirostris (Carnaby’s Black-Cockatoo) Endangered Endangered
EPBC protected matters search
Calidris ferruginea (Curlew Sandpiper) Critically Endangered & Migratory
International Agreement
Calyptorhynchus latirostris (Carnaby’s Black-Cockatoo) Endangered Threatened
Leipoa ocellata (Malleefowl) Vulnerable & Migratory
Vulnerable
Numenius madagascariensis (Eastern Curlew) Critically Endangered Critically Endangered & International Agreement
Dasyurus geoffroii (Western Quoll) Vulnerable Vulnerable
Parantechinus apicalis (Dibbler) Endangered Endangered
Apus pacificus (Fork-tailed Swift) Migratory International
Agreement
Padion haliaetus (Osprey) Migratory
Motacilla cinereal (Grey Wagtail) Migratory International
Agreement
Actitis hypoleucos Migratory International
Agreement
Calidris acuminate (Sharp-tailed Sandpiper) Migratory International
Agreement
Calidris melanotos (Pectoral Sandpiper) Migratory International
Agreement
The ecological survey undertaken by Hart, Simpson and Associates (2000) noted that the area surrounding the facility provides a relatively simple fauna habitat of a low but dense and diverse heath dominated by shrubs of the Proteaceae, Myrtaceae and Epacridaceae and perennial herbs such as sedges. The 2018 survey (Mattiske Consulting Pty Ltd 2018) determined that vegetation within the surveyed area was not suitable for nesting of Carnaby’s Black Cockatoos. Eucalyptus todtiana, which was observered to be the most common tree in the 2018 survey area, was observed to grow to a maximum of four metres and did not provide suitable hollows for
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nesting. However, the 2018 survey noted that a range of species from the genera - Banksia spp., Hakea spp. and Grevillea spp. was present and considered suitable foraging habitat for Carnaby’s Black Cockatoo.
4.7 Socio-economic Environment
4.7.1 Land Use and Economic Environment
The major land uses in the region are grazing of native pastures in the north and in the south a mixture of grazing and cropping of cereals. The areas surrounding petroleum production license L11 are favored for honey production and wildflower picking. While commercial flower harvesting is not permitted within nature reserves and national parks, there are extensive areas surrounding the Yardanogo Nature Reserve where this occurs. The favoured species are the Acorn (or hookers) Banksia (Banksia hookeriana), with picking taking place from late July to early September (DEC 2008).
Oil and gas exploration and production has occurred extensively in the area. Facilities that are in close proximity to BSD-1 include:
• Triangle operated Arrowsmith Stabilisation Plant ~14.2kms to the WNW,
• Mitsui operated Hovea Production Facility (currently shut-in) ~18.5kms to the NW,
• Mitsui operated Xyris Production Facility ~17.8kms to the NNW,
• Mitsui operated Dongara Production Facility (currently sht-in) ~25.76kms to the NW.
• RCMA Australia operated Jingemia Oil Production Facility ~18km to the NW.
In addition to oil and gas, the industries contributing to the economic development of the Shire include mineral sands, Rock Lobster and aquaculture (abalone), olive growing and production and general farming.
4.8 Natural Heritage
There are no Natural Heritage places within 5km of the BSD-1 well location. The closest Natural Heritage Property, the Beekeepers-Lesueur-Coomallo Area and Nambung National Park, is approximately 13km away from the BSD-1 well location and is located outside of petroleum production license L11.
The Arrowsmith Lake Area is on the Register of the National Estate and is located approximately 6.9km away from the BSD-1 well location.
The closest conservation / nature reserve, Yardanogo Nature Reserve, is located approximately 5km from the BSD-1 well location.
4.9 Indigenous and Non-Indigenous Cultural Heritage
No cultural heritage sites listed on the Register of the National Estate occur within petroleum production license L11 (DPLH 2017).
4.9.1 Native Title Applications
A search of the National Native Title Tribunal database (http://www.ntv.nntt.gov.au/ntv.asp) on 30 November 2018 reveals one registered Native Title applications applicable to the BSD-1 well location being the Southern Yamatiji People application (WC2017/002).
4.9.2 Ethnology
Previous ethnographic surveys within the region (including petroleum production license L11) involved searches of ethnographic databases, consultation with the relevant Aboriginal community and field surveys. Consultation revealed that the Ejarno Spring (10km north north-west of the BSD-1 well location) and the chain of smaller springs stretching southward to the Beharra Spring are places of Aboriginal significance to the Moore River (Mogumber) group (O’Connor 2001).
4.9.3 Archaeology
Previous archaeological studies within petroleum production license L11 by Quartermaine Consultants involved searches of the state Aboriginal archaeological site register (maintained by the Department of Indigenous Affairs, DIA) and field surveys.
No Aboriginal archaeological sites were recorded within petroleum production license L11, and thus are not expected to be present at / or surrounding the BSD-1 well location.
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5. Environmental Management Strategies
A risk assessment of the aspects that will and may occur during operations was undertaken using Beaches risk assessment methodology which follows Australian Standard AS/NZS ISO 31000:2009: Risk management – Principles and guidelines. Hazards and their associated aspects and their associated management and mitigation measures are detailed bellow in Table 5-1.
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Table 5-1 Summary of Environmental Hazards and their associated Aspects and Management and Mitigation measures
Aspect Hazard Management and Mitigation Measures
Physical Interaction - Soil and Vegetation Spread non-indigenous species (weed / pathogens)
Unplanned disturbance to vegetation
Damage heritage sites / artefacts
Tops soil windrows <2m
Construction fill verified as having low weed/dieback risk
Weed/dieback management requirements
Induction
Demarcation of clearing area
Desktop heritage evaluation
Consultation
Heritage monitors during disturbance of the top-soil
Heritage artefact identification procedure
Atmospheric Emissions Disturbance to sensitive fauna / relevant stakeholders Emissions are monitored and reported
Complaints management system
Pilot flame is used during flaring to keep flame alive
NGERS reporting
Extraction of Groundwater Damage to vegetation due to drawdown of shallow groundwater
Ground water licenses
Meter calibration and monitoring
Physical Interaction – Fauna Injury or fatality to terrestrial fauna Fauna exclusion and egress
Site inspections
Speed limits
Induction
Fire habitat and vegetation loss,
fauna injury / fatality, and
contamination (in the event petroleum facilities are damaged).
Hot works exemption
Emergency Response Plan
Permit to Work (PTW)
Induction
Consultation
Fire breaks
Erosion / Contamination surface water run-off
Unplanned disturbance to vegetation / soil contamination
HSE Inspection
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Aspect Hazard Management and Mitigation Measures
Mud sump and turkey nest design
Accidental release of drilling fluid Surface spill resulting in contamination of soil / useable groundwater aquifers; or contamination and subsequent toxic effects to vegetation.
Subsurface spill resulting in contamination of useable groundwater aquifers.
Rig Inspection
Surface casing cemented across all useable freshwater aquifers
Bund construction
Chemical disclosure (Appendix A)
Low toxicity drilling fluid
Site will be manned 24 hour a day
Monitoring of groundwater bore
Emergency Response Plan
Fugitive discharges are monitoring and reported
Accidental release of solid waste Attraction and / or injury of protected fauna species within the vicinity of the BSD-1 well location.
Appropriate rubbish bins and waste segregation
Appropriately licensed waste contractor
Waste register
Induction
Accidental release of Hydrocarbons or Hazardous Materials (excluding Loss of Well Control [LOWC])
Contamination of soil / groundwater
Contamination and subsequent toxic effects to vegetation
Spill protection during refuelling.
Chemical and hazardous liquid material storage
Groundwater sampling
Well Testing - equipment pressure testing
Well Testing - Emergency Shut Down
Induction
Spill Kits
OSCP
Emergency Response Plan
Accidental Release of Hydrocarbons – LOWC
Atmospheric Emissions
Contamination of soil / groundwater
Contamination and subsequent toxic effects to vegetation
WMP
HSE Management Plan / bridging document
Groundwater sampling
Induction
Spill Kits
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Aspect Hazard Management and Mitigation Measures
OSCP
Blow out control equipment and expertise
ERP
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6. Implementation strategy
To meet the requirements of Regulation 15(1) of the PGER(E)R, Implementation Strategy for the EP, this Section describes the implementation strategy - the systems, practices, and procedures used to ensure that the environmental impacts and risks of the activities are continuously reduced to ALARP, and the environmental performance objectives and standards detailed in Section 5 are achieved.
As described in Section 1.3, Beach Energy will operate under its subsidiary company’s (Lattice) management system which is currently in-force at the Beharra Springs Gas Facility.
6.1 Management System Overview
Lattice’s Health, Safety Environment Management System (HSEMS) is comprised of three tiers of documentation as follows:
• HSE Policy - defines the strategic objectives for the effective control of and continuing improvement to health, safety, and environmental issues throughout operations
• HSE Management Standards - 20 standards which interpret support and detail the intent and performance requirements of the HSE Policy and form the basis for development and application of HSE Plans within the organisation
• HSE Directives - detail minimum requirements, the responsibilities and the business guidance that is needed to implement the HSE Policy and HSE Management Standards. A Directive document is either implemented as the guiding document or (where further information about the implementation process is required at a Divisional or Business level) a procedure is developed to detail application of the Directive.
The HSEMS establishes clear guidelines for personnel involved in this activity to achieve and maintain the standards set out in the EP.
6.2 Environment Plan Review
Regulation 18 of the PGER(E)R requires that Beach Energy submit a proposed revision of the accepted EP:
• before the commencement of a new activity,
• or any significant modification, change of a new stage of an existing activity,
• before, or as soon as practicable after, the occurrence of any significant new environmental impact or risk, or significant increase in an existing environmental impact or risk which occurred or is to occur.
Additionally, Regulation 20 of PGER(E)R requires that Beach Energy submit a proposed revision of the EP five years from the date when the EP is accepted by the Minister.
7. Consultation
Minimising and mitigating the potential environmental impacts associated with the BSD-1 well exploration and appraisal activities is assisted by the engagement of key stakeholders to ensure all issues are identified and addressed. Beach Energy completed a scoping exercise to determine which authorities, persons and organisations were considered to be relevant.
Given the isolated location of the BSD-1 well location, limited stakeholders were identified but include:
• Department of Mines, Industry Regulation and Safety,
• Department of Water and Environmental Regulation,
• Shire of Irwin,
• Yamatji Marlpa Aboriginal Corporation,
• Sothern Yamatji people (Traditional Land Owners).
A summary of the consultation with these stakeholders is include as Table 7.1.
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Table 7.1: Stakeholder Consultation Undertaken
Stakeholder Date Summary of Consultation Objections / claims raised Beach Energy response
DMIRS 20 November 2018 Met with DMIRS to verify clearing permit requirements and provide an update on the project
Acknowledged that it was the operator’s responsibility to confirm approval requirements but acknowledged Beach Energy’s understanding that exemptions for clearing for exploration activities were not incorrect.
None required
Shire of Irwin 6 February 2019 Provide an overview of Beach Energy’s
overall operations around Australia and the proposed drilling operations for the Beharra Springs Deep-1 well south of Dongarra.
No objections or concerns were raised by the Council officials in relation to the proposed drilling operations.
N/a
Yamatji Marlpa Aboriginal Corporation (YMAC)
16 January 2019 To provide information on the project and seek feedback and engagement on the project.
Requested if the well was a conventional or unconventional well
Beach Energy confirmed that the exploration well is a conventional vertical well and no hydraulic stimulation of the target formation is planned.
Southern Yamatji (Traditional Owners)
16 January 2019 YMAC forwarded project information to the Southern Yamatji people
None provided N/a
DWER 9 January 2019 Provided site location map, groundwater monitoring locations, and groundwater level and inferred flow maps.
Described site layout water requirements for the program and proposed the use of existing monitoring bores to meet groundwater monitoring requirements.
Acknowledged information and stated they would review and provide comment.
None provided to date
N/a
7.1 Ongoing Consultation
Beach Energy will continue to engage with identified key stakeholders for the duration of the project.
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8. References
1. Beard, J.S. 1976. Vegetation of the Dongara Area, Western Australia. Map and Explanatory Memoir, 1:250,000 Series, Vegmap Publications, Perth.
2. Bureau of Meteorology. 2018. Climate statistics for Australian locations. Available online from: http://www.bom.gov.au/climate/averages/tables/cw_008051.shtml.
3. Department of Conservation and Land Management. 2002. Bioregional Summary of the 2002 Biodiversity Audit for Western Australia - Geraldton Sandplain 3 (GS3 - Lesueur Sandplain subregion). Available online from https://www.dpaw.wa.gov.au/images/documents/about/science/projects/waaudit/geraldton_sandplains03_p293-313.pdf
4. Department of Parks and Wildlife. 2017. Conservation Codes - For Western Australian Flora and Fauna. Available online from: https://www.dpaw.wa.gov.au/images/documents/plants-animals/threatened-species/Listings/conservation_code_definitions.pdf
5. Department of Primary Industries and Regional Development. 2018. Soil-landscape systems Western Australia.
6. Department of Water and Environmental Regulation. 2018. Landfill Waste Classification and Waste Definitions 1996 (as amended 2018). Available online from: https://www.der.wa.gov.au/images/documents/our-work/licences-and-works-approvals/WasteDefinitions-revised.pdf
7. Department of Water. 2016. Measuring the taking of water guidelines. Department of Water, Western Australia. Available online from https://www.water.wa.gov.au/__data/assets/pdf_file/0005/8186/109923.pdf
8. Earth Tech Engineering. 2002. West Midlands Hydrology Project Stage One Report: The Impact of Hydrological Issues on Biodiversity and Agriculture in the West Midlands Region.
9. Hart, Simpson & Associates Pty Ltd. 2000. Three Wells Beharra Gas Field Ecological Survey. Report prepared for Origin Energy Resources Limited.
10. Hart, Simpson & Associates Pty Ltd. HSA 2003. Flora and Fauna Assessment of the North Perth Basin Drilling Program (Redback-1 and Tarantula-1 Well Sites, L11). Report prepared for Origin Energy Resources Limited.
11. IRC Environment. 2004. Denison 3D Seismic Survey Public Environmental Review.
12. Mattiske Consulting Pty Ltd 2018. Flora and Fauna Survey. Deep Well Sites, Beharra Springs. Prepared for Beach Energy. Reference BEP1801/034/18, December 2018.
13. O’Connor, R.O. 2001. Report on an Ethnographic Survey of the Proposed Hibbertia 3D and Ularino 2D Seismic Programmes. Report prepared for Origin Energy Resources Limited.
14. Playford, P.E., A.E. Cockbain and G.H. Low. 1976. Geology of the Perth Basin Western Australia. Geological Society of Western Australia, Bulletin 124.
15. Schoknecht, N., Tille, P. And Purdie, B. 2004. Soil-Landscape Mapping in South- Western Australia. Resource Management Technical Report 280. Department of Agriculture, Perth.
16. Senversa. April 2017. Detailed Site Investigation Beharra Springs Gas Plant. Report prepared for Origin Energy. Reference 12588_rpt01-rev3
17. Senversa. 2018. December 2018 Groundwater Monitoring Results and 2018 Annual Review. Report prepared for Beach Energy limited. Reference 16849-003.
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Appendix A Chemical Disclosure
A.1. Drilling Fluid Chemical Disclosure
A. SYSTEM DETAILS:
OPERATOR: Beach Energy
PROJECT / WELL NAME: BSD-1
SYSTEM: Drilling Fluids, HT Logging Pill & Completion Brine
TOTAL VOLUME OF SYSTEM (m3): *3180m3
* includes 100% Contingency volume
B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Water N/A Base Fluid Bore water sourced onsite 81.04% N
Barite / Newbar Newpark Weighting Agent
Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data: Toxicity data avaailable for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021
0.37% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Bentonite / NewGel NT / API Bentonite
Newpark Viscosifier
The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. Toxicity Data: Toxicity data avaailable for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021
1.97% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Potassium Chloride Newpark
Shale swelling inhibition (smectite & illite clays)
Acute Toxicity: LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse) LD50 (Intravenous): 117 mg/kg (mouse) LDLo(Ingestion): 20 mg/kg (man) LDLo (Intraperitoneal):900 mg/kg (guinea pig) LDLo (Intravenous): 77 mg/kg (guinea pig) LDLo (Subcutaneous): 2120 mg/kg (frog) TDLo(Ingestion): 60 mg/kg/days (woman) Ecotoxicty Data: In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictalurus punctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronic reproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronic aquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerations the background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for further investigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulation potential for the substance. Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. Mobile in Soil: No impact if small amount is released to the soil. OCNS Rated E - 24330, Exp 11/03/2021
2.49% Y
Calcium Carbonate (including various grades) Circal 60/16, Circal Y, Circal 1000, Stonedust, Limestone LSC
Newpark Bridging & Weighting Agent
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects. Acute Toxicity: LD50 (Ingestion): 6450 mg/kg (rat) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. This product does not bioaccumulate
5.59% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Calcium Carbonate (including various grades) Omyacarb 10, 20 & 40
Newpark Bridging & Weighting Agent
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects. Acute Toxicity: LD50 (Ingestion) = 6450 mg/kg (rat). Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects. Biodegradation/Bioaccumulation: Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle. This product does not bioaccumulate
0.15% Y
Salt (Sodium Chloride all grades)
Newpark Weighting Agent
Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
5.97% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
NewZan D/Xanthan gum
Newpark Vicosifier
Acute Toxicity: LD50 (oral) > 1000 mg/kg (mouse) LD50 (oral) > 45,000 mg/kg (rat) LD50 (oral) > 20,000 mg/kg (dog) LD50 (intraperitoneal): > 50 mg/kg (mouse) LD50 (intravenous): 100-250 mg/kg (mouse) This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
OCNS Rated E - 26280, Exp 22/02/2021
0.42% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
NewPac LV / Drispac SL
Newpark Fluid Loss
Acute Toxicity: Toxicity data available for ingredients: SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat) Ecotoxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
NewPac LV - OCNS Rated E - 28129, Exp 18/05/2021
0.65% Y
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FlexFirm KA Newpark Provides shale inhibition
Toxicological Information: Acute toxicity Information available for the product: No known toxicological effects from this product. Based on available data, the classification criteria are not met. Skin Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possible burns. Sensitization This product is not classified as causing skin or respiratory sensitisation. Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in breathing difficulties. STOT – single exposure Aspiration This product does not present an aspiration hazard. Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodular lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principal symptoms of silicosis are coughing and breathlessness. STOT – repeated exposure Reproductive Insufficient data available to classify as a reproductive toxin. Carcinogenicity Insufficient data available to classify as a carcinogen. This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1). However, there is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis. Therefore, preventing the onset of silicosis will also reduce the cancer risk. Mutagenicity Insufficient data available to classify as a mutagen. Ecotoxicity Information: The ecotoxicity of potassium silicate has not been tested. The following data is reported for chemically similar sodium silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance of water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm.
Toxicity The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similar Sodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm. Persistence and degradability This material is not persistent in aquatic systems. Mobility in soil Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable from natural dissolved silica. Bioaccumulative potential Neither silica nor potassium will appreciably bio-concentrate up the food chain.
0.24%
Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
LC-Lube Newpark
Well Bore Strengthening
Toxicological information
Conclusion/Summary : No known significant effects or critical hazards.
Ecological information
Other adverse effects : Toxicity No known significant effects or critical hazards.
Persistence and degradability Not available.
Other adverse effects: No known significant effects or critical hazards
OCNS Rated E - 3922, Exp 02/12/2021
0.11%
Y
NDFT 376 & NDFT 377
Newpark LCM / Well Bore Strengthening
Acute toxicity This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral Toxicity (LD50) - > 5000 mg/kg (rat), Dermal Toxicity (LD50) > 2000 mg/kg (rabbit),
0.01% Y
AvaPolymer 5050 Newpark
Encapsulating Agent - provides shale inhibition
Constituent 1 – (60%) ATEmix (oral) 27,000.00 mg/kg ATEmix (dermal) 2,002.00 mg/kg Constituent 2 - (40%) Oral Toxicity (LD50) - 16000 mg/kg (guinea pig) Dermal Toxicity (LD50) - > 2000 mg/kg (rabbit) TDLo (oral) 140 mg/kg (rat) Ecotoxicity: This product has an
CEFAS OCNS Gold rating. Registration number 27397
0.15% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Caustic Soda Newpark
pH control-prevents bacteria & corrosion.
Toxicity Data: Toxicity Data available for the ingredients: SODIUM HYDROXIDE (1310-73-2): LD50 (Intraperitoneal): 40 mg/kg (mouse) LDLo (Ingestion): 1.57 mg/kg (human) SILICA, AMORPHOUS (7631-86-9): LD50 (ingestion): 3160 mg/kg (rat) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
OCNS category and registration number E - 24316
0.10% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Sodium Sulphite Newpark Oxygen Scavenger
Acute Toxicity: LD50 (Ingestion): 820 mg/kg (mouse) LD50 (Intraperitoneal): 950 mg/kg (mouse) LD50 (Intravenous): 175 mg/kg (mouse) LDLo (Ingestion): 2825 mg/kg (rabbit) LDLo (Intravenous): 400 mg/kg (cat) LDLo (Subcutaneous): 600 mg/kg (rabbit) SODIUM CARBONATE (497-19-8) LC50 (inhalation) 800 mg/m³/2 hours (guinea pig) LD50 (ingestion) 4090 mg/kg (rat) LD50 (intraperitoneal) 117 mg/kg (mouse) LD50 (subcutaneous) 2210 mg/kg (mouse) SODIUM SULPHATE (7757-82-6) LD50 (ingestion) 5989 mg/kg (mouse) LD50 (intravenous) 1220 mg/kg (rabbit) LDLo (intravenous) 1220 mg/kg (mouse) TDLo (ingestion) 14 g/kg (mouse - 8-12 days pregnant) TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category and registration number E - 26232
0.12% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Soda Ash Newpark pH / Hardness control
Toxicity: LD50 (Ingestion): 4090 mg/kg (rat) LC50 (Inhalation): 800 mg/m3/2 hours (guinea pig) LD50 (Intraperitoneal): 117 mg/kg (mouse) LD50 (Subcutaneous): 2210 mg/kg (mouse) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out. OCNS category and registration number E - 26180
0.10% Y
Sodium Bicarbonate Newpark pH Buffer, Contamination Treatment
Acute Toxicity: LD50 (Ingestion): 3360 mg/kg (mouse) LC50 (inhalation): 4.74 mg/L (rat) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Ecotoxicity Data: LC50 (Oncorhynchus mykiss), 96 h, 7.700 mg/l LC50 (Lepomis macrochirus), 96 h, 7.100 mg/l EC50 (Crustaceans, Daphnia magna) 48 h, 4.100 mg/l LOEC (Crustaceans, Daphnia magna) 48 h, 3.100 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. OCNS category and registration number E - 26175
0.03% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Idcide-20 Newpark
Biocide/Prevents bacterial contamination of the mud
Toxicity: Toxicity data available for ingredient:
TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8)
LD50 (ingestion) 248 mg/kg (rat)
TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)
Ecotoxicity: 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):
LC50 (Rainbow Trout) = 119 mg/L/96 hr
LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr
EC50 (Daphnia Magna) = 19 mg/L/48 hr
LC50 (Brown Shrimp) = 340 mg/L/96 hr
LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr
LC50 (Sheepshead Minnow) = 94 mg/L/96 hr
LC50 (Jevenile Plaice) = 86 mg/L/96 hr
Waste Water management EC50 (Activated Sludge) = 24 mg/L/3 hr
Persistence and degradability: This product is readily biodegradable.
http://www.inchem.org/documents/ehc/ehc/ehc218.htm
0.09% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Citric Acid Newpark pH Buffer
Acute Toxicity: LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 290 mg/kg (rat) LD50 (Intravenous): 42 mg/kg (mouse) LDLo (Ingestion): 7000 mg/kg (rabbit) Ecotoxicity: LC50 (Leuciscus idus melanotus): 440 mg/L - 48 h LC 50 Daphnia magna (Water flea) - 1.535 mg/L - 24 h Biodegradation/Bioaccumulation: Readily Biodegradability. Does not bioaccumulate. If citric acid is released to water, it is expected to biodegrade rapidly. May be toxic to fish at moderately high levels (120 ppm is fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which may cause oxygen depletion in large spills. Citric acid occurs naturally in many plants.
OCNS category and registration number E - 24317
0.03% Y
Magnesium Oxide Newpark pH Indicator This product is expected to be of low toxicity.
OCNS category and registration number E - 28127 0.05% Y
TEA Newpark
Polymer stabiliser which effectively reduces the degradation of polymers at high temperatures
CONSTITUENT 1 (>60%) Oral Toxicity (LD50) 2200 mg/kg (rabbit), Dermal Toxicity (LD50) > 20 mL/kg (rabbit) CONSTITUENT 2 (10 - 30%) Oral Toxicity (LD50) 620 uL/kg (rat), Dermal Toxicity (LD50) > 20 mL/kg (rabbit) CONSTITUENT 3 (<10%) Component is naturally occuring and not intrinsically hazardous. Environment In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
0.08% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Driscal D Newpark
High temperature fluid loss control agent
LCLo (Inhalation): 300 ug/m3/10 years (human), LDLo (Intratracheal): 200 mg/kg (rat) LDLo (Intravenous): 20 mg/kg (dog), TCLo (Inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)
0.01% Y
Gagetrol Newpark HT Fluid Loss
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. Low toxicity - low irritant. Under normal conditions of use, adverse health effects are not anticipated. OCNS category and registration number Gold - 27759
0.23% Y
Defoam-AP400 Newpark
Defaomer suitable for High Temperatures
Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Low toxicity - low irritant. This product has the potential to irritate mucous membranes. Use safe work practices to avoid eye or skin contact and inhalation. Due to the low vapour pressure of this product, an inhalation hazard is not anticipated with normal use. Chronic exposure to some glycols may result in liver and kidney damage. Health hazard summary 11.1 Information on toxicological effects Toxicity data POLYETHYLENE GLYCOL (25322-68-3) LD50 (ingestion) 33750 mg/kg (rat)
0.03% Y
TOTAL 100.02% TOTAL 100.02%
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AVADEFOAM NS Newpark Defaomer suitable for WBM
CONSTITUENT 1 (95%) - Acute toxicity - Acute oral toxicity (LD50): 9380 mg/kg [Rat].
Ecological Information : Ecotoxicity in water (LC50): 100 mg/l 96 hours [Fish]. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.
CONSTITUENT 2 (5%) - Acute toxicity -Dermal LD50 Albino rabbit - > 2000 mg/kg, 14 days At this dose no death occurred. LD50 Oral Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no death occurred. Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Tall Oil Fatty Acids
EC50 Bacteria (Pseudomonas putida) > 10000 mg/l, 16 hr
Aquatic Algae EL50 > 1000 mg/l, 72 hr Growth rate; OECD 201
Green algae (Selenastrum capricornutum)
Crustacea EL50 Water flea (Daphnia magna) > 1000 mg/l, 48 hr OECD 202
Fish LL50 Zebra danio (Danio rerio) > 10000 mg/l, 96 hr Biodegradability:- Percent degradation (Aerobic biodegradation)
Tall Oil Fatty Acids 88 - 100 % CO2 Evolution Test
Species: Activated sewage sludge Test Duration: 28 d Product Information : Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915
Product Information : Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915
0.05% y
Barite / Newbar Newpark See Above 4.16% y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
TrueScav HD Newpark
Oxygen Scavenger Non-sulphur based,
Constituent 1 – (>99%) The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 5,005.00 mg/kg Oral LD50 > 5 g/kg ( Rat ) Ecotoxicity The environmental impact of this product has not been fully investigated. Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. Persistence/Degradability: Possibly hazardous short term degradation products are not likely; However, long term degradation products may arise.
0.20% y
NDFT 376 & 377 Newpark LCM / Well Bore Strengthening
See Above 8.50% y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Calcium Chloride (94%) Powder
Newpark Weighting Agent
Based on available data, the classification criteria are not met.
Toxicity Data available for the ingredients: Acute Toxicity: CALCIUM CHLORIDE ANHYDROUS (10043-52-4) LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
0.01% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
MEG Newpark Agent to free differentially stuck pipe
Toxicity Data: Toxicity data avaailable for ingredient: ETHYLENE GLYCOL (107-21-1) LC50 (inhalation) 10 876 mg/kg (rat) LD50 (ingestion) 1650 mg/kg (cat) LD50 (skin) 9530 ug/kg (rabbit) LDLo (ingestion) 398 mg/kg (human) TCLo (inhalation) 10,000 mg/m³ (human - cough) TDLo (ingestion) 5500 mg/kg (child - anaesthesia) Ethylene glycol will mainly exist in the vapour phase in the ambient atmosphere where it will be degraded by reaction with hydroxyl radicals. Expected to be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces. Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms. Ecotoxicity LC50 (Aquatic species): >100mg/L/96hrs. Non hazardous to aquatic organisms. Safework Australia Exposure Standards: http://hsis.ascc.gov.au/DocumentationES.aspx?ID=722 http://hsis.ascc.gov.au/DocumentationES.aspx?ID=271 CICADS Available: http://inchemsearch.ccohs.ca/inchem/jsp/search/search.jsp?inchemcasreg=1&Coll=inchemall&serverSpec=charlie.ccohs.ca%3A9900&QueryText1=107-21-1&QueryText2=&Search.x=52&Search.y=10
2.73% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Strata-Vanguard Newpark Bridging Agent
Toxicity Data: Toxicity data avaailable for ingredient: CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) POLYETHYLENE (9002-88-4) LDLo (ingestion) 3000 mg/kg (rat) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human) This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. This product has low mobility in soil.
0.12% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Frac Attack Newpark Prevent lost circulation
Toxicity Data: Toxicity data avaailable for ingredient: CALCIUM HYDROXIDE (1305-62-0) LD50 (ingestion) 7300 mg/kg (mouse) CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human) The manufacturer reports that this product is harmful to aquatic life.
1.30% Y
AVAPERM NF Newpark
Prevent swelling clays by blocking the site for water hydration.
An equivalent product to AVAPERM NF has been registered on the CEFAS Offshore Chemical Notification Scheme with a ‘Gold’ rating & Registration # 24780 Skin corrosion/irritation: Not corrosive (B.40 Bis - Reg. 440/2008/EC). Skin contact: Harmful and irritant. Eye contact: Irritant. Inhalation: Irritant. Ingestion: Harmful. Acute oral toxicity on rats (LD50): > 500 < 1000 mg/kg.* (based on components) Following information is confidential: Biodegradation Seawater test OECD 306 75 % Bioaccumulation OECD 117 LogPow ≤ 1.36 EC 50 (Skeletonema costatum) 54.4 mg/l LC50 (Acartia tonsa) 52.4 mg/l LC50 (Scophthalmus maximus juvenile) >51.0 mg/l
4.15% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
JK-161 LV / JK-261 / JK-261HP
Newpark
Encapsulating Agent - provides shale inhibition
TOXICOLOGICAL INFORMATION: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401). ECOLOGICAL INFORMATION: (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
0.75% Y
Driscal D Newpark
High temperature fluid loss control agent
LCLo (Inhalation): 300 ug/m3/10 years (human), LDLo (Intratracheal): 200 mg/kg (rat) LDLo (Intravenous): 20 mg/kg (dog), TCLo (Inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)
0.25% Y
DSCO™ Defoam Newpark Defoamer
Constituent 1 – (>60%)
Oral Toxicity: An oral LD50 300 - 57000 mg/kg (range)
This product is not expected to bioaccumulate
Constituent 2 – (remainder)
No Hazard
0.01 Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
SAPP Newpark
Deflocculate or disperse bentonite muds or fluids with high levels of low gravity solids.
Acute Toxicity: Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Ingestion of large quantities may also result in serious disturbances in calcium metabolism. LD50 (Ingestion): 2650 mg/kg (mouse) LD50 (Intraperitoneal): 1 g/kg (mouse) LD50 (Intravenous): 59 mg/kg (mouse) LD50 (Subcutaneous): 480 mg/kg (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category (actual or equivalent chemical) and Registration number. E-2449
0.13% Y
Calcium Carbonate (including various grades Circal 60/16, Circal Y, Circal 1000, Omyacarb 10, 20 & 40, Stonedust, Limestone LSC
Newpark
Bridging agent & loss circulation material
Calcium Carbonate (including various grades Circal 60/16, Circal Y, Circal 1000, Omyacarb 10, 20 & 40, Stonedust, Limestone LSC
0.99% Y
FlexFirm KA Newpark
Inhibits dispersion of drilled shale cuttings
See Above 0.45% Y
SPA Newpark
High temperature fluid loss control agent
Toxicity (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis Bahia = 48HR LC50 = 16.2 mg/L. Menidia Beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia Costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia Tonsa = 48hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
0.10% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
QUICKSEAL F / M / C
Newpark Lost circulation material
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated Acute Toxicity: Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats). Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats). Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat). Low toxicity to aquatic organisms. This product is readily biodegradable. This product is not expected to bioaccumulate.
0.02% Y
AvaGreenLube Newpark Lubricant
LC50 (Fish) 48 h: > 10000 μg / L LC50 (Mollusc ) 48 h: > 10000 μg /L LC50 (Amphibious) 48 h: > 7600 μg/L Low potential for bío-accumulation in aquatic organisms or terrestrial even after repeated exposure
0.40% Y
Zinc Oxide Newpark H2S Scavenger
Acute toxicity Information available for the product: This product is expected to be of low toxicity. Based on available data, LC50 (Inhalation): 2500 mg/m³ (mouse) ZINC OXIDE (1314-13-2) LD50 (intraperitoneal) 240 mg/kg (rat) LDLo (oral) 500 mg/kg (human) TCLo (inhalation) 600 mg/m³ (human) LD50 (Oral): 7950 mg/kg (mouse) Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This product is not readily biodegradable
0.06% Y
Salt (Sodium Chloride all grades)
Newpark Weighting Agent
See Above 0.64% Y
Gagetrol Newpark HT Fluid Loss Addtive
See Above 0.28% Y
Magnesium Oxide Newpark Ph Buffer See Above 0.03% Y
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
TEA Newpark
Polymer stabiliser which effectively reduces the degradation of polymers at high temperatures
See Above 0.03% Y
Polydrill Newpark
High temperature fluid loss control agent
Oral Toxicity - (LD50) > 5000 mg/kg (rat)
0.20% Y
Geovis Newpark
High temperature viscosifier
Oral Toxicity - (LD50) - > 5000 mg/kg (rat) 0.15% Y
Microflow Newpark Stimulation Additive
Constituent 1 – (15-50%)
Oral Toxicity: An oral LD50 in mice of 3600 mg/kg
Constituent 2 – (20-60%)
No Hazard
This product is not expected to bioaccumulate.
0.22% Y
Total
*Contingent chemicals are highlighted grey. 51.10%
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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C. Chemical List (Chemicals within fluid system identified in Table B)
Chemicals Name CAS number Mass fraction (%)
Water 7732-18-5 81.20%
Bentonite 1302-78-9 1.93%
Potassium Chloride 7447-40-7 2.49%
Potassium Silicate 1312-76-1 0.24%
Calcium Carbonate 471-34-1 5.68%
Sodium Chloride 7647-14-5 5.98%
Barium Sulphate 7727-43-7 0.33%
Sodium carboxymethy Cellulose 9004-32-4 0.57%
Xanthan Gum 11138-66-2 0.42%
Polyvinylalcohol 9002-89-5 0.11%
Acrylamide, Sodium Acrylate Copolymer 25987-30-8 0.15%
Quartz (Silica Crystalline) 14808-60-7 0.12%
Sodium Hydroxide 1310-73-2 0.15%
Sodium Carbonate 497-19-8 0.15%
Sodium Sulphite 7757-83-7 0.12%
Sodium Sulphate 7757-82-6 0.12%
Sodium Bicarbonate 144-55-8 0.003%
Citric Acid, Anhydrous 77-92-9 0.025%
Sodium Glycolate 2836-32-0 0.025%
Triethanolamine 102-71-6 0.001%
Magnesium Oxide 1309-48-4 0.059%
Hexahydro-1,3,5-tris(2-hydroxyethyl)-S-triazine 4/04/4719 0.049%
Ethanol, 2,2'-oxybis-, 68909-77-3 0.032%
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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C. Chemical List (Chemicals within fluid system identified in Table B)
Chemicals Name CAS number Mass fraction (%)
Poly (oxy-1,2-ethanediyl) 68909-09-1 0.027%
Acetic Acid 64-19-7 0.009%
TOTAL 100.03%
Water 7732-18-5 84.88%
Octan-2-Ol 123-96-6 0.05%
Cellulose 9004-34-6 1.32%
Calcium Chloride 10043-52-4 0.01%
Sodium Chloride 7647-14-5 0.64%
Ethylene Glycol 107-21-1 2.73%
Quartz (Silica Crystalline) 14808-60-7 0.29%
2-Propenenitrile, polymer with 1,3-butadiene Rubber 9003-18-3 0.04%
Zinc Oxide 1314-13-2 0.06%
Natural Rubber 9006-04-6 0.03%
Polyisoprene 9003-31-0 0.03%
Rubber - SBR elastomers (derived from recycled automotive tyres) 9003-55-8 0.03%
Diatomaceous Earth 68855-54-9 0.02%
Fuller's earth 8031-18-3 0.01%
D-glucurono-6-deoxy-l-manno-d-glucan, Acetate, calcium magnesium potassium sodium Salt 595585-15-2 0.15%
Calcium Carbonate 1317-65-3 0.99%
Tall Oil Fatty Acid 61790-12 0.006%
Polyethylene 9002-88-4 0.01%
Cristobalite 14464-46-1 0.08%
Isopropyl Alcohol 67-63-0 0.11%
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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C. Chemical List (Chemicals within fluid system identified in Table B)
Chemicals Name CAS number Mass fraction (%)
Calcium Oxide 1305-78-8 0.04%
Organic fibres 9004-34-6 0.03%
Calcium Hydroxide 1305-62-0 0.03%
Methyl Oxirane Polymer 9003-11-6 0.06%
Magnesium oxide 1309-48-4 0.02%
Triethanolamine 102-71-6 1.66%
Hydrochloric acid 7647-01-0 0.21%
Zinc Oxide 1314-13-2 0.006%
Hexamethylenediamine 124-09-4 0.45%
Formic Acid 64-18-6 0.23%
Carboxymethyl starch 9057-06-1 0.28%
Dazomet (iso)[tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione] 533-74-4 0.02%
Disodium Pyrophosphate 7758-16-9 0.13%
Acrylamide, Sodium Acrylate Copolymer 25987-30-8 0.10%
Sulphonated organic polymer 28210-41-5 0.15%
Barium Sulphate 7727-43-7 4.16%
Methyl esters of fatty acids 68990-52-3 0.40%
Sweet Orange Oil 68647-72-3 0.36%
TOTAL 100.00%
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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A.2. Cement and Spacer (Alternate) Chemical Disclosure
A. SYSTEM DETAILS:
OPERATOR: Beach Energy
PROJECT / WELL NAME: BSD-1
SYSTEM: Pre-job Cement System
TOTAL VOLUME OF SYSTEM: CEMENT Blend: 118,230 gal
B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
D013 EH Schlumberger D013 EH Retarder
Acute Toxicity: Aromatic polymer sulfonated derivative: LD50 oral (Rat) >40g/kg. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any
known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to
algae, or invertebrates. Toxicity to Fish: LC50: aromatic polymer sulfonated derivative = 7300 mg/L
0.004%
Yes
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Barite / Newbar
Newpark Weighting Agent
Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data: Toxicity data avaailable for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021
2.280%
Yes
Beharra Springs Deep-1 Exploration and Appraisal Environmental Plan Summary CDN/ID 18064337
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Bentonite / NewGel NT / API Bentonite
Newpark Viscosifier
The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. Toxicity Data: Toxicity data avaailable for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021
3.376%
Yes
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
D047 Schlumberger AntiFoam Agent
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Readily biodegradeable, bioaccumulation is unlikley.
0.052%
Yes
D065 Schlumberger Dispersant
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Product not readily biodegradeable. Bioaccumulation is unlikely.
0.056%
Yes
D066 Schlumberger Silica
Acute Toxicity: Quartz, Crystalline Silica: LD50 Oral (Rat): = 500 mg/kg Chronic Toxicity: Product contains no components known to be sensitizing or mutagens. Crystalline silica dust is listed by IARC as Group 1 carcinogen. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: This product is not considered toxic to algae, fish, or invertebrates Biodegregation/Bioaccumulation: Not applicable- Inorganic chemical
5.492%
Yes
D075 Schlumberger Extender
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Contains no substance considered to be bioaccumulating or toxic
0.053%
Yes
D080 Schlumberger Dispersant
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: Toxic to aquatic life with long lasting effects. Sodium polynaphthalene sulfonate: EC50 (48 hours) 1.8 mg/l Product is not considered toxic to fish or invertebrates. Product is not biodegradable. Bioaccumulation is unlikely.
0.343%
Yes
D081 Schlumberger Retarder
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Does not bioaccumulate
0.031%
Yes
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
D110 WH Schlumberger D110 WH
Retarder
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Product is biodegradable, does not bioaccumulate.
0.553%
Yes
D161 Schlumberger Retarder
Acute Toxicity: Sodium Pentaborate Ld50 Dermal: >2 g/kg LC50 Inhalation: > 2.03 mg/L Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product is or contains a chemical which is a known or suspected reproductive hazard. Not known to cause birth defects or have a deleterious effect on a fetus. Ecotoxicity: Sodium Pentaborate: Toxicity to Fish: LC50: = 600 mg/L (96 h) Toxicity to Invertebrates: EC50= 86 mg/L (48 h) Biodegregation/Bioaccumulation: The organic portion of this material is not biodegradable. Contains no substance considered to be bioaccumulating or toxic.
0.460%
Yes
D168 Schlumberger Fluid Loss Additive
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Product may cause sensitization of susceptible persons. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Product is biodegradable, does not bioaccumulate.
0.076%
Yes
D175A Schlumberger AntiFoam Agent
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Contains no substance considered to be bioaccumulating or toxic.
0.031%
Yes
D182 Schlumberger Spacer
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Bioaccumulation is unlikely.
0.125%
Yes
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
D194 Schlumberger
Retarder
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Contains no substance considered to be bioaccumulating or toxic.
0.053%
Yes
D255 Schlumberger Mid-Range FLAC D255
Acute Toxicity: 2-methylpropan-2-ol LD50 Oral (Rat): > 2200 mg/kg Ld50 Dermal (Rabbit): >2 g/kg LC50 Inhalation (Rat): > 10000 ppm, (4h) Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: 2-methylpropan-2-ol Toxicity to Fish: LC50(Pimpehales promelas): = 6130-6700 mg/L (96 h) Toxicity to Algae: EC50 (Desmodesmus subspicatus): >1000 mg/L (120 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 4607-6577 mg/L (48 h) Biodegregation/Bioaccumulation: Not readily biodegradeable. Does not bioaccumulate
0.084%
Yes
D256 Schlumberger Mid-Range liquid FLAC D256
Acute Toxicity: None. Chronic toxicity Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Not readily biodegradeable, bioaccumulation is unlikely.
0.092%
Yes
D600G Schlumberger
Gas Control Agent
Acute Toxicity: 1,4-Dioxane (Impurity) LD50 Oral (Rat): > 4200 mg/kg Ld50 Dermal (Rabbit): >7600mg/kg LC50 Inhalation (Rat): > 46 mg/L (2h) Chronic Toxicity: May cause allergic reactions in very susceptible persons. Contains a known or suspected carcinogen. Is not known to have reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: 1,4-Dioxane (impurity) Toxicity to Fish: LC50(Pimpehales promelas): = 9850 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 163 mg/L (48 h) Biodegregation/Bioaccumulation: Not readily biodegradeable. Does not bioaccumulate
1.574%
Yes
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
D901 Schlumberger Cement
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulaiton: Not applicable, inorganic chemical
26.66%
Yes
D907 Schlumberger Cement
Acute Toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulaiton: Not applicable, inorganic chemical
15.692%
Yes
Water Schlumberger Water None 44.491% Yes
Total 100.00%
C. Chemical List
Chemicals within products in Part B CAS number Maximum Mass fraction in System (%)
Portland cement 65997-15-1 ~ 66
Water (Including Mix Water Supplied by Client)* 7732-18-5 ~ 12
Crystalline silica (impurity) 14808-60-7 ~ 9
Barium sulfate 7727-43-7 ~ 5
Bentonite 1302-78-9 ~ 3
Styrene butadiene copolymer 9003-55-8 ~ 1
Sulfuric acid, calcium salt 7778-18-9 ~ 1
Sodium polynaphthalene sulfonate 9008-63-3 < 1
Calcium glucoheptonate 17140-60-2 < 1
Polypropylene glycol 25322-69-4 < 1
Sulfurous acid, monosodium salt, polymer 40104-76-5 < 1
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C. Chemical List
Chemicals within products in Part B CAS number Maximum Mass fraction in System (%)
2-Propenoic acid, ammonium salt, polymer with 2- methyl-2-[(1-oxo-2-propeny)amino]-1-propanesulfonic acide moniammonium salt and 2-propenamide
99716-31-1 < 1
Sodium lignosulfonate 8061-51-6 < 1
Propane-1,2-diol 57-55-6 < 0.1
Polysaccharide biopolymer 72121-88-1 < 0.1
Sodium pentaborate 12007-92-0 < 0.1
Sodium chloride (impurity) 7647-14-5 < 0.1
C12-15 alcohol ethyoxylated 68131-39-5 < 0.1
Calcium lignosulfonate 8061-52-7 < 0.1
Silicic acid, sodium salt 1344-09-8 < 0.1
Alkyl glyceryl ether sulfonate 246867-88-9 < 0.1
2-Propenoic acid, polymer with 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid and 2-propenamide, ammonium salt.
1857271-55-6 < 0.1
Sodium sulfate 7757-82-6 < 0.1
Dimethyl siloxanes and silicones 63148-62-9 < 0.1
Vinylamide/vinylsulfonated polymer 110897-64-8 < 0.1
Pentasodium EDTMP 7651-99-2 < 0.01
2-methylpropan-2-ol 75-65-0 < 0.01
Sodium gluconate 527-07-1 < 0.01
Sorbitan stearate 1338-41-6 < 0.01
Tartaric Acid 87-69-4 < 0.01
Calcium chloride 10043-52-4 < 0.01
Sodium dodecyl sulphate 151-21-3 < 0.01
1,4-Dioxane (Impurity) 123-91-1 < 0.01
Sodium hydroxide 1310-73-2 < 0.01
Polyoxyethylene (40) stearic acid (monoester) 9004-99-3 < 0.01
Silicon Dioxide 7631-86-9 < 0.01
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C. Chemical List
Chemicals within products in Part B CAS number Maximum Mass fraction in System (%)
2-bromo-2-nitropropane-1,3-diol 52-51-7 < 0.001
Phosphonic acid (impurity) 13598-36-2 < 0.001
Phosphoric acid (impurity) 7664-38-2 < 0.001
2-Propenamid (impurity) 79-06-1 < 0.001
3,3'-methylenebis[5-methyloxazolidine] 66204-44-2 < 0.001
Sorbic acid 110-44-1 < 0.0001
5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one 55965-84-9 < 0.0001
Total 100.00%
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A.4. Drilling Fluid for Conductor Installation
A. SYSTEM DETAILS:
OPERATOR: Beach Energy
PROJECT / WELL NAME: BSD-1
SYSTEM: Drilling Fluid for Conductor Installation
TOTAL VOLUME OF SYSTEM (m3): 120m3
B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
Water N/A Base Fluid N/a 99.62% N/A
Quik-gel Gold Baroid / Halliburton
Viscosifier
Toxicity
Constituent 1: Bentonite
LD50 Oral > 5000 mg/kg (Rat) > 2000 mg/kg (Rat)
LD50 Dermal >2000 mg/kg
LC50 Inhalation > 5.27 mg/L (Rat) >200 mg/L (Rat) 1h
Constituent 2: Crystalline silica, quartz
LD50 Oral > 15,000 mg/kg (Human)
LD50 Dermal -No data available
LC50 Inhalation - No data available
Constituent 3: Crystalline silica, cristobalite
LD50 Oral >15,000 mg/kg (Human)
LD50 Dermal -No data available
LC50 Inhalation - No data available
Constituent 4: Crystalline silica, tridymite
LD50 Oral >15,000 mg/kg (Human)
LD50 Dermal -No data available
0.31% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
LC50 Inhalation - No data available
Ecotoxicity
Constituent 1: Bentonite
Toxicity to Algae
EC50 (72h) > 100 mg/L (freshwater algae)
Toxicity to Fish
TLM 96 10,000 ppm (Oncorhynchus mykiss)
LC50 (96h) 16,000 - 19,000 mg/L (Oncorhynchus mykiss)
LC50(24h)2800–3200 mg/L (black bass, warmouth bass, blue gill and sunfish)
Toxicity to Invertebrates
EC50 (96h) 81.6 mg/L (Metacarcinus magister)
EC50 (96h) 24.8 mg/L (Pandalus danae)
EC50 (48h) > 100 mg/L (Daphnia magna)
Constituent 2: Crystalline silica, quartz
Toxicity to Fish
LL0 (96h) 10,000 mg/L (Danio rerio) (similar substance)
Toxicity to Invertebrates
LL50 (24h) > 10,000 mg/L (Daphnia magna) (similar substance)
Constituent 3: Crystalline silica, cristobalite
Toxicity to Fish
LL0 (96h) 10,000 mg/L (Danio rerio) (similar substance)
Toxicity to Invertebrates
LL50 (24h) > 10,000 mg/L (Daphnia magna) (similar substance)
Constituent 4: Crystalline silica, tridymite
Toxicity to Fish
LL0 (96h) 10,000 mg/L (Danio rerio) (similar substance)
Toxicity to Invertebrates
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
LL50 (24h) > 10,000 mg/L (Daphnia magna) (similar substance)
Chronic effects: Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).
Aside from Crystalline silica, quartz the remaining constituents are inorganic and biodegradability does not pertain to inorganic substances. No information available regarding the biodegradability of crystalline silica, quartz. No information is available regarding bioaccumulation or mobility in soil for these the constituents in this product.
This product does not contain any known or suspected endocrine disruptors
Quikmud II Baroid / Halliburton
Additive
Toxicity
LD50 Oral > 5000 mg/kg (rat) similar substance
LD50 Dermal >2000 mg/kg-bw (rabbit) (similar substance)
LC50 Inhalation > 5.2 mg/L (rat, 4 h, vapor) (similar substance)
Ecotoxicity
Toxicity to Algae
EC50 (72h) > 1,000 mg/L (Skeletonema costatum)
ErL50 (72h) > 1000 mg/L (Pseudokirchneriella subcapitata)
EbL50 (72h) > 1000 mg/L (Pseudokirchneriella subcapitata)
NOELR (72h) 1000 mg/L (Pseudokirchneriella subcapitata)
Toxicity to Fish
LC50 (96h) > 10,000 mg/L (Scophthalmus maximus)
LL50 (96h) > 1000 mg/L (Oncorhynchus mykiss)
Toxicity to Invertebrates
LC50 (48h) > 10,000 mg/L (Acartia tonsa)
EC50 (48h) 1100 mg/L (Daphnia pulex)
LC50 (48h) 0.12 mg/L (Daphnia magna)
EL50 (48h) > 1000 mg/L (Daphnia magna)
The product is readily biodegradeable 40% @ 28 days
The products bioaccumulation potential is has a Log Pow Weighted Average 7.5
0.035% Y
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B. PRODUCT LIST
Trade name Supplier Purpose Toxicity & Eco toxicity Info % Product in system fluid
SDS Attached
This product does not contain any known or suspected endocrine disruptors
Pac-r Baroid / Halliburton
Fluid Loss Additive
No data available to indicate product or components present at greater than 0.1% are chronic health hazards.
Contains no hazardous substances in concentrations above cut-off values according to the competent authority
Toxicity
LD50 Oral 16000mg/kg (16000mg/kg) Guinea pig.
LD50 Oral> 27gm/kg (27000mg/kg) Mouse
LD50 Oral > 27gm/kg (27000mg/kg) Rabbit
LD50 Skin > 2gm/kg (2000mg/kg) Rabbit
LC50 Inhalation > 5800mg/m3/4H (5800mg/m3) Rat
LD50 Oral 27000mg/kg (27000mg/kg) Rat
Ecotoxicity
Toxicity to Fish
96hr LC50 (rainbow trout): >100 mg/L
96hr LC50 (bluegill sunfish): >100 mg/L
Toxicity to Invertebrates
48hr EC50 (Daphnia) 87,26 mg/l
This product does not contain any known or suspected endocrine disruptors
This is an OCNS Non-charmable product – OCNS Category E (Low toxicity)
0.031% Y
Total 100.00%
C. Chemical List (Chemicals within fluid system identified in Table B)
Chemicals Name CAS number Mass fraction (%)
Water 7732-18-5 99.61%
Bentonite 1302-78-9 0.295%
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C. Chemical List (Chemicals within fluid system identified in Table B)
Chemicals Name CAS number Mass fraction (%)
Crystalline silica, quartz 14808-60-7 0.015%
Crystalline silica, cristobalite 14464-46-1 0.003%
Crystalline silica, tridymite 15468-32-3 0.003%
Hydrotreated light petroleum distillate 64742-47-8 0.035%
Cellulose derivative 9004-32-4 0.031%
Total 100.00%
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A.5. SDS
NEWPARKDRILLING FLUIDS
SAFETY DATA SHEET
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 Product identifier
Product name BENTONITE POWDER / RHEOBEN
Synonym(s) BENTONITE (API 13A SECTION 9) • NEWGEL • RHEOBEN • MAXIGEL
1.2 Uses and uses advised against
Use(s) DRILLING FLUID
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +618 9410 8200
Fax +618 9410 8299
Website www.newpark.com
1.4 Emergency telephone number(s)
Emergency 1800 127 406 (Australia); +64 3 3530199 (International)
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
GHS classification(s) Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
2.2 Label elements
Signal word WARNING
Pictogram(s)
Hazard statement(s)
H373 May cause damage to organs through prolonged or repeated exposure.
Prevention statement(s)
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
Response statement(s)
P314 Get medical advice/attention if you feel unwell.
Storage statement(s)
None allocated.
Disposal statement(s)
P501 Dispose of contents/container in accordance with relevant regulations.
2.3 Other hazards
No information provided.
BENTONITE POWDER / RHEOBENPRODUCT NAME
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
QUARTZ (CRYSTALLINE SILICA) 2 to 10%14808-60-7 238-878-4
BENTONITE 90 to 98%1302-78-9 215-108-5
SODA ASH 2 to 4%- -
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
First aid facilities Eye wash facilities and safety shower should be available.
Chronic exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Page 2 of 6
SDS Date: 29 Jan 2015
BENTONITE POWDER / RHEOBENPRODUCT NAME
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packaging are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties BROWN POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling point1100°C to 1200°C (Fusion Point)Melting pointNOT RELEVANTEvaporation rateNOT RELEVANTpHNOT RELEVANTVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT RELEVANTVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT RELEVANTPartition coefficientNOT RELEVANTAutoignition temperatureNOT RELEVANTDecomposition temperatureNOT RELEVANTViscosityNOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT RELEVENTOdour threshold
Page 3 of 6
SDS Date: 29 Jan 2015
BENTONITE POWDER / RHEOBENPRODUCT NAME
9.2 Other information~ 0.9 kg/LBulk density
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are notmet.
Skin Not classified as a skin irritant. Contact may result in mild irritation and dermatitis.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitization The available data is not considered sufficient for classification as a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product is not expected to present an aspiration hazard.
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1).However there is sufficient information to conclude that the relative risk of lung cancer is increased inpersons with silicosis. Therefore preventing the onset of silicosis will also reduce the cancer risk.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
The main component/s of this product are not anticipated to cause any adverse effects to plants or animals.
12.3 Bioaccumulative potentialNo information provided.
Page 4 of 6
SDS Date: 29 Jan 2015
BENTONITE POWDER / RHEOBENPRODUCT NAME
13. DISPOSAL CONSIDERATIONS
Waste disposal Reuse where possible. No special precautions are normally required when handling this product.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S22 Do not breathe dust.Safety phrases
Xn HarmfulHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).
Additional information
Page 5 of 6
SDS Date: 29 Jan 2015
BENTONITE POWDER / RHEOBENPRODUCT NAME
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Included bulk density. 2.1
Converted to GHS. 2.0
Standard SDS Review 1.1
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:29 January 20152.1
Page 6 of 6
SDS Date: 29 Jan 2015
AVADEFOAM NS
EN
SAFETY DATA SHEET
Issue Date 18-Apr-2017 Revision Date 28-Mar-2019 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY1
Product identifier
Product Name AVADEFOAM NS
Product Code NDF00251
Other means of identification
Pure substance/mixture Mixture
Recommended use of the chemical and restrictions on use
Recommended Use Defoamer
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number +(61)-290372994 (Australia); +(64)-98010034 (New Zealand)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
_____________________________________________________________________________________________
UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Other hazards General HazardsNo information available
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Not applicable
Mixture
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing media Water. Carbon dioxide (CO2).
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Chemical name CAS No Weight-%
Non-hazardous ingredients Proprietary
_____________________________________________________________________________________________
UGHS Page 2 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Wash thoroughlyafter handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials None known
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
_____________________________________________________________________________________________
UGHS Page 3 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Liquid
Other Information Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Liquid Density 0.95-0.97 g/cm3
Bulk density No information available
Particle Size No information available
Particle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity No information available.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Appearance liquid Odor Slight.
Color clear Odor threshold No information available
Property Values Remarks • Method pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point > 100 °C
Evaporation rate No data available
Flammability (solid, gas) Not applicable
Flammability Limit in Air No information available
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density 0.95-0.97
Water solubility Insoluble in water
Solubility(ies) No data available
Partition coefficient No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
_____________________________________________________________________________________________
UGHS Page 4 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials None known.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 10,010.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity95 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
_____________________________________________________________________________________________
UGHS Page 5 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 95 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
_____________________________________________________________________________________________
UGHS Page 6 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Does not comply
IECSC Complies
KECL Complies
PICCS Does not comply
AICS Complies
NZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 18-Apr-2017
Revision Date 28-Mar-2019
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Disclaimer
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
_____________________________________________________________________________________________
UGHS Page 7 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
_____________________________________________________________________________________________
UGHS Page 8 / 8
SAFETY DATA SHEET EC 1272/2008 Regulation
AVAGREEN LUBE
Rev. 4 – January 2016 Pagina: 1/8
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY
1.1. Substance Identification
Product Name: AVAGREEN LUBE 1.2. Substance Use
Application: Ecological lubricant for drilling fluids
1.3. Company Identification
Name: Newpark Drilling Fluids S.p.A.
Address: Via Salaria 1313/C
City/Country: 00138 ROMA (Italy)
Phone numbers: +39 06 885611386 / +39 06 885611324 / +39 06 8856111
Fax: +39 06 8889363
1.4. Emergency Phone Numbers
+39 06 885611386 +39 06 885611324 +39 06 8856111
1.5. Responsible Person E-Mail Address
e-mail: [email protected]
2. HAZARDS IDENTIFICATION
2.1. Substance/Mixture Classification
Indication of hazards specific for human health and environment:
THE SUBSTANCE/MIXTURE IS NOT CLASSIFIED AS DANGEROUS IN ACCORDANCE TO FOLLOWING REGULATIONS
Classification according to EC Regulation n. 1272/2008 - (CLP)
- - - - - - NOT CLASSIFIED AS DANGEROUS IN ACCORDANCE TO FOLLOWING REGULATIONS
2.2. Label Elements
Label according to EC Regulation n. 1272/2008 (CLP)
Hazards Identification: - - - NOT CLASSIFIED AS DANGEROUS IN ACCORDANCE TO FOLLOWING REGULATIONS
Precautionary Statements:
Disposal
2.3. Other Hazards
- - -
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 2/8
3. COMPOSITION / INFORMATION ON INGREDIENTS
3.1. Chemical Properties of Substance or Mixture
Composition: Substance
Contains: As per following table
Molecular Formula: - - -
EC Number: - - -
CAS Number: - - -
UN Number: - - -
REACH Number: - - -
3.2. Information on ingredients
Name CAS No. EC No. Quantity Classification Symbols Hazard
Statements
Methyl esters of fatty acids
68990-52-3 273-606-8 100% - - - - - - - - -
4. FIRST AID MEASURES
4.1. Description of First Aid Measures
General information: In case of diseases, get medical attention. Show to the doctor this Material Safety Data Sheet
After inhalation: At room temperature or normal handling the risk of inhalation of vapors is negligible
After skin contact: Take off contaminated clothing and shoes. Wash thoroughly with plenty of water; use, if available, mild soap. Seek immediate medical attention if irritation, swelling or redness develops and persists
After eye contact: It may cause irritation. Immediately remove any contact lenses. Immediately flush eyes with running water for at least 15-20 minutes while holding eyelids open. If irritation, blurred vision or swelling persist, consult a medical specialist
After swallowing: In case of disease contact a physician
Other information: N.a.
4.2. Main symptoms and effects, both acute and delayed
Symptoms: N.a.
4.3. Indication of any immediate medical attention and special treatment needed
Medical surveillance: Medical surveillance during job not required. In case of disease or accident, consult immediately a doctor and show him this MSDS
Special intervention means: N.a.
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 3/8
5. FIREFIGHTING MEASURES
5.1. Extinguishing Media
Precautions in case of fire: In case of fire respect following instructions:
Suitable extinguishing media: In case of fire use: foam, dry chemical, carbon dioxide
Unsuitable extinguishing media:
Avoid the use of water jets on the burning product; could cause splattering and spread the fire. Simultaneous use of foam and water on the same surface as water destroys the foam. Use water spray to cool fire exposed surfaces and to protect personnel in fire fighting
Hazards arising from combustion: In case of incomplete combustion can form smoke and carbon monoxide. Acrolein thermal decomposition
Special firefighting equipment: In case of fire wear a full face positive pressure self-contained breathing apparatus and protective suit
Others: N.a.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions
Protective equipment: Wear personal protective equipment (PPE)
Emergency procedures:
Remove personnel not involved from the spill. Warn emergency crews. Avoid skin contact and contact with eyes by wearing appropriate personal protective equipment. Respiratory protection: respiratory protection will be necessary only in special cases, such as: oil mist
6.2. Environmental Precautions
Containment media: Confine the spill immediately with floating barriers
Containment methods:
Small spills: can be dried with paper towels. The normal antistatic working clothes are usually adequate. For large spills: Recover by skimming or pumping using explosion-proof equipment, or contain spilled liquid with sand, or other non-combustible absorbent such as sand, earth, vermiculite, diatomaceous earth and place into containers. In the case in which the situation cannot be completely assessed, or if there is a risk of oxygen deficiency, use only SCBA
Additional information: N.a.
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 4/8
7. HANDLING AND STORAGE
7.1. Precautions for Handling
Handling precautions:
Wear proper personal protective equipment. Avoid contact with eyes, skin and clothes. Avoid breathing vapor or mist. Do not swallow. Wash hands after handling. If handling at elevated temperatures or with high speed mechanical equipment, vapors or mists can form and require a well ventilated workplace. Keep the product in cool, well ventilated area away from heat sources and exposure direct sunlight. Electrical equipment and fittings must comply with local regulations regarding fire prevention materials of this type
7.2. Precautions for Storage
Storage conditions: MATERIALS AND COVERINGS SUITABLE: Carbon steel, stainless steel, Teflon. The compatibility with plastic materials may vary; It is advisable to check before use
Storage area specifications: TEMPERATURE loading / unloading: environment STORAGE TEMPERATURE: Store in closed containers at temperatures between 10°C and 40°C
Containers specifications:
EMPTY CONTAINER WARNING: Do not pressurize, cut etc. or expose container to heat, flame or sparks; containers may explode causing injury or death. Not groped to clean since residue is difficult to remove. Empty drums should be drained, capped and sent to reconditioning according to current regulations
Incompatibility: N.a.
7.3. Particular Uses:
Particular uses: N.a.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure Limits
TLVCeling: - - -
TLVTWA: - - -
TLVSTEL: - - -
Biological limit: - - -
8.2. Professional Exposure Controls
Plant protections: General ventilation recommended
Collective protections: Provide adequate ventilation
Individual protections:
Respiratory:
When concentrations in air may exceed the exposure limit, and where engineering, work procedures and other means to limit exposure are not adequate, they are necessary means of respiratory protection: masks against vapor and dust/mist
Eyes: Where only incidental contact is likely, wear safety glasses with side shields
Hand: In cases of prolonged contact, use gloves resistant to oils and solvents. No protection is ordinarily required under normal conditions of use
Body: Protective standard clothing
8.3. Environmental Exposure Controls
Exposure Scenarios: N.a.
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 5/8
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General Information
Form: Liquid
Appearance: Liquid
Color: Yellow
Odor: Sweet vegetables
Olfactory threshold: N.a.
9.2. Information about Health, Safety and Environment
pH: Not applicable
Melting point: N.a.
Pour point: ASTM D 97 : < - 13°C
Boiling temperature: > 300°C
Flash point: 180°C
Flammability (solid, gas): N.a.
Auto ignition temperature: 260°C
Decomposition temperature: N.a.
Danger of explosion: N.a.
Upper flammability limit: N.a.
Lower flammability limit: N.a.
Vapor pressure: < 0.01 Pa a 20°C
Density at 20°C: 0.91 – 0.92
Apparent density (20°C): N.a.
Relative density: N.a.
Vapor density: N.a.
Evaporation rate: N.a.
Solubility in water (20°C): < 1%
Distribution coefficient (n-Octanol): 20 - 25 (approx)
Viscosity: 30 (approx)
9.3. Other information
Other information: N.a.
10. STABILITY AND REACTIVITY
10.1. Reactivity
Stability: Keep away from heat sources, open flames, direct sunlight and other sources of ignition
10.2. Chemical Stability
Incompatible materials: Avoid contact with acids and bases and strong oxidizing agents. This may result in the evolution of harmful and flammable gases or vapors
Possibility of dangerous reactions: Hazardous polymerization will not occur
10.3. Hazardous Decomposition Products
Other information: Under normal conditions of storage and use, you should not generate dangerous decomposition products. The high temperature, above 150°C, may result in the development of acrolein
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 6/8
11. TOXICOLOGICAL INFORMATION
11.1. Acute Toxicity
Substance Toxicity
Oral toxicity: N.a.
Inhalation toxicity: N.a.
Dermal toxicity: N.a.
11.2. Corrosively
Skin: N.a.
Eyes: N.a.
11.3. Primary Irritability
Skin: After long-term exposure can be a risk of irritation
Eyes: It is possible an irritation of the mucous membranes
11.4. Harmfulness
Ingestion: Rinse your mouth and drink plenty of water. Seek medical advice immediately
Inhalation: No data available
11.5. Sensitization
Skin: Not skin sensitizer. Were not observed skin allergies
Eyes: N.a.
12. ECOLOGICAL INFORMATION
12.1. Toxicity
Toxicity in the water: LC50 (Fish) 48 h: > 10000 μg / L LC50 (Mollusc ) 48 h: > 10000 μg /L LC50 (Amphibious) 48 h: > 7600 μg/L
Toxicity in the air: N.a.
Toxicity in the soil: N.a.
12.2. Persistence and Degradability
Other information: 70% 28 days (method OECD 301 B)
12.3. Bio cumulative Potential
Other information: Low potential for bío-accumulation in aquatic organisms or terrestrial even after repeated exposure
12.4. Mobility in Soil
Other information: It is not volatile and are not expected to persist in the environment
12.5. Results of PBT e vPvB Assessment
PBT: This product is not, or does not contain a substance classified as PBT or vPvB
vPvB: This product is not, or does not contain a substance classified as PBT or vPvB
12.6. Other Adverse Effects
Other information: Spills can cause the formation of film on water surfaces causing physical damage to organisms, limiting the exchange of oxygen
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 7/8
13. DISPOSAL CONSIDERATIONS
13.1. Product Disposal Methods
Advices Dispose of in accordance with local and national regulations
Waste code: N.a.
13.2. Methods of Disposal of packaging
Advices: Dispose of in accordance with local and national regulations
Other information: N.a.
14. TRANSPORT INFORMATION
14.1. Land/Rail Transport (ADR/RID)
UN Number: No dangerous good under transport regulations
UN shipping norms: N.a.
Hazard class: N.a.
Packaging group: N.a.
Dangers for the environment: N.a.
14.2. Maritime Transport (IMDG)
IMDG Class: No dangerous good under transport regulations
Marine pollutant: N.a.
14.3. Air Transport (ICAO-TI and IATA-DGR)
ICAO Class: No dangerous good under transport regulations
IATA Class: N.a.
14.4. Bulk Transport
Annex II of MARPOL73/78: No dangerous good under transport regulations
IBC Code: N.a.
15. REGULATORY INFORMATION
15.1. Health, Safety and Environment Regulations/Legislation Specific for the Substance or Mixture
D.Lgs. 3/2/1997 n. 52 (Classification, packaging and labeling of hazardous substances)
D.Lgs. 14/3/2003 n. 65 (Classification, packaging and labeling of hazardous mixtures)
D.Lgs. 2/2/2002 n. 25 (Risks due to chemical agents during the work)
D.M. Lavoro 26/02/2004 (Professional exposure limits)
D.M. 03/04/2007 (Implementation of the Directive n. 2006/8/CE)
CE Regulation n. 1907/2006 (REACH)
CE Regulation n.1272/2008 (CLP)
CE Regulation n.790/2009 (Adequacy to technical progress to CLP Regulation)
CE Regulation n. 453/2010 (Modification of REACH Regulation)
CE Regulation n.790/2009 (adaptation to technical and scientific progress of CLP Regulation)
CE Regulation nº 453/2010 (Modification of REACH Regulation)
SAFETY DATA SHEET
- AVAGREEN LUBE -
Rev. 4 – January 2016 Pagina: 8/8
16. OTHER INFORMATION
16.1. Main Bibliographic Sources
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition – Van Nostrand Reinold
Istituto Superiore di Sanità - Inventario Nazionale Sostanze Chimiche
ACGIH - Threshold Limit Values - 2009 edition
16.2. Declarations
This sheet completes the technical bulletin without to substitute it. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
This material safety datasheet only contains information relating to health and safety. The product has to be used in applications consistent with Newpark Drilling Fluids S.p.A. technology. Individuals handling this product should be informed of the safety precautions and should have access to this information.
This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU.
This MSDS cancels and replaces any preceding release.
16.3. Abbreviations and Acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
GHS: Globally Harmonized System of Classification and Labeling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
ACGIH: American Conference of Industrial Hygienists
EC50: median effective concentration
LC50: median lethal concentration
LD50: median lethal dose
NOEC: no observable effect concentration
PNEC: predicted no-effect concentration
PBT: persistent, bio accumulative, toxic chemicals
vPvB: very persistent, very bio accumulative chemicals
TLV-TWA: Threshold limit value – Time weighted average; professional exposure limit average on 8 hours
TLV-STEL: Threshold limit value – Short Term exposure limit ; professional exposure limit at short term
TLV–C : Threshold limit value – Ceiling
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) F003132 - SDS CODE
INHIBITOR IN DRILLING FLUIDSUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the safety data sheet
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
AVAPERM NFProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word WARNING
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Harmful if swallowed.H302Harmful in contact with skin.H312Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335
Hazard statement(s)
Pictograms
Acute Toxicity: Oral: Category 4Acute Toxicity: Skin: Category 4Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Systemic Toxicity (Single Exposure): Category 3
GHS classification
2.1 Classification of the substance or mixture
Page 1 of 7
SDS Date: 08 Apr 2014
AVAPERM NFPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501
Disposal statement(s)
Store in a well-ventilated place. Keep container tightly closed (applies if the substance is volatile so as togenerate a hazardous atmosphere).
P403 + P233
Store locked up.P405
Storage statement(s)
IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin or eye irritation occurs: Get medical advice/ attention.P332 + P337 + P313Take off contaminated clothing and wash before re-use.P362
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Identification Classification Content
HYDROGENATED HEXANEDINITRILECHLORIDE
Not Available 35 to 70%
WATER CAS: 7732-18-5EC: 231-791-2
30 to 65%
Ingredient Notes This product is mixture of 30-50% Hexanedinitrile, 5-20% Hydrochloric acid (as pH corrector) andwater. Hydrochloric acid is used to neutralise hexanedinitrile to become the salt with slightly alkali(pH 9-11).
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
First aid facilities Eye wash facilities and safety shower are recommended.
See Section 11 for more detailed information on health effects and symptoms.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment needed
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
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AVAPERM NFPRODUCT NAME
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in Section 8 of this SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.
7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.
8.2 Exposure controls
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AVAPERM NFPRODUCT NAME
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties LIQUIDAppearancePUNGENT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point100°C (Approximately)Boiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9 to 10pHNOT AVAILABLEVapour density1.00 to 1.10Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Incompatible withIsocyanates, aldehydes, ketones, anhydrides, phenols, nitrates, halogenated compounds.
May evolve toxic gases (carbon/ nitrogen oxides, hydrocarbons) when heated to decomposition.
10.6 Hazardous decomposition products
Hazardous polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 Reactivity
Carefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Eye Irritant. Contact may result in irritation, lacrimation, pain and redness.
Inhalation Irritant. Over exposure to vapours may result in respiratory irritation, nausea, dizziness and headache. Highlevel exposure may result in drowsiness and breathing difficulties.
Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis.
Ingestion Harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain, diarrhoea,headache, dizziness and drowsiness with large quantities.
Harmful - irritant. This product has the potential to cause adverse health effects with over exposure. Usesafe work practices to avoid eye or skin contact and inhalation. Over exposure may result in irritation to theeyes, skin and respiratory system.
Health hazardsummary
11.1 Information on toxicological effects
Toxicity data No LD50 data available for this product.
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AVAPERM NFPRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
This product is registered on Offshore Chemical Notification Scheme Gold, Gold, Gold for HQ Band 17.5", 12.25" and 8.5"respectively.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potential
No information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarger amounts, contact the manufacturer for additional information. Prevent contamination of drains orwaterways as aquatic life may be threatened and environmental damage may result.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
DG class
Subsidiary risk(s) None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated
14.3 Transport hazard classes
None AllocatedNone AllocatedNone Allocated14.4 Packing group
None AllocatedHazchem code
14.6 Special precautions for user
None Allocated14.5 Environmental hazards
None Allocated
None Allocated
None Allocated
None AllocatedNone Allocated
None Allocated14.2 UN proper shipping name
14.1 UN number
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R21/22 Harmful in contact with skin and if swallowed.R36/37/38 Irritating to eyes, respiratory system and skin.
Risk phrases
S1/2 Keep locked up and out of reach of children.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS45 In case of accident or if you feel unwell seek medical advice immediately (show the label
where possible).
Safety phrases
Xi IrritantXn Harmful
Classifications
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SDS Date: 08 Apr 2014
AVAPERM NFPRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.EUROPE:EINECS (European Inventory of Existing Chemical Substances)All components are listed on EINECS, or are exempt.
Inventory listing(s)
16. OTHER INFORMATION
The manufacturer indicates the product is mixture of 30-50% Hexanedinitrile, 5-20% Hydrochloricacid (as pH corrector) and water. Hydrochloric acid is used to neutralise hexanedinitrile to becomethe salt with slightly alkali (pH 9-11).
AMINE: CAUTION THIS PRODUCT CONTAINS AN AMINE. DO NOT ADD NITRITES or otherNITROSATING AGENTS to this product due to the potential for NITROSAMINE formation.Nitrosamines are potent carcinogens and some have been shown to cause severe acute (heart,brain, blood, liver - kidney) damage as well as chronic effects (reproductive effects, liver - lung andkidney tumours).
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACEEXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hourwork period of normal intensity, under normal climatic conditions and where a 16 hour breakbetween shifts exists to enable the body to eliminate absorbed contaminants. In the followingcircumstances, exposure standards must be reduced: strenuous work conditions; hot, humidclimates; high altitude conditions; extended shifts (which increase the exposure period and shortenthe period of recuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures;protective equipment used and method of application. Given that it is impractical to prepare aChemAlert report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
Page 6 of 7
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AVAPERM NFPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Initial SDS Creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier ofthe product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:08 April 20141
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SDS Date: 08 Apr 2014
AVAPOLYMER 5050
EN
SAFETY DATA SHEET
Issue Date 12-Apr-2017 Revision Date 02-Aug-2017 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name AVAPOLYMER 5050
Product Code NDF00252
Other means of identification
Pure substance/mixture Mixture
Recommended use of the chemical and restrictions on use
Recommended Use shale stabilizer
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Other hazards
_____________________________________________________________________________________________
UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
May be harmful in contact with skin
General HazardsNo information available
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Not applicable
Mixture
Additional informationThe product contains no substances which at their given concentration, are considered to be hazardous to health
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing mediaWater spray (fog). Carbon dioxide (CO2).
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
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UGHS Page 2 / 8
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials None known
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
_____________________________________________________________________________________________
UGHS Page 3 / 8
Individual protection measures, such as personal protective equipment
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Solid
Other Information Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available
Particle Size No information available
Particle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity Stable.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Appearance powder Odor Slight.
Color No information available Odor threshold No information available
Property Values Remarks • Method pH 8.0 - 11.0 20 g/L solution
Melting point / freezing point No data available
Boiling point / boiling range No data available
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Flammability Limit in Air No data available
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density No data available
Water solubility Soluble in water
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity Not applicable
Dynamic viscosity Not applicable
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UGHS Page 4 / 8
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials None known.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 27,000.00 mg/kg
ATEmix (dermal) 2,002.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity40 % of the mixture consists of ingredient(s) of unknown acute oral toxicity40 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
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UGHS Page 5 / 8
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
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_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
NZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 12-Apr-2017
Revision Date 02-Aug-2017
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONTWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
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UGHS Page 7 / 8
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
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UGHS Page 8 / 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) BARITE (API 13A SECTION 7) • NEWBAR • RHEOBAR
DRILLING FLUID ADDITIVE • WEIGHTING AGENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
BARITE POWDERProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word WARNING
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Storage statement(s)None allocated.
Get medical advice/attention if you feel unwell.P314Response statement(s)
Do not breathe dust/fume/gas/mist/vapours/spray.P260Prevention statement(s)
May cause damage to organs through prolonged or repeated exposure.H373Hazard statement(s)
Pictogram(s)
Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2GHS classification(s)
2.1 Classification of the substance or mixture
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BARITE POWDERPRODUCT NAME
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
QUARTZ (CRYSTALLINE SILICA) <3%14808-60-7 238-878-4
BARIUM SULPHATE >89%7727-43-7 231-784-4
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
First aid facilities Eye wash facilities should be available.
Chronic exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
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BARITE POWDERPRODUCT NAME
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from foodstuffs. Ensure containers are adequately labelled, protected from physicaldamage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Barium sulphate SWA (AUS) -- 10 -- --
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties OFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling point> 1300°CMelting pointNOT RELEVANTEvaporation rate8.2 (20% Slurry)pHNOT RELEVANTVapour density4.20Specific gravityINSOLUBLESolubility (water)NOT RELEVANTVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT RELEVANTPartition coefficientNOT RELEVANTAutoignition temperatureNOT RELEVANTDecomposition temperatureNOT RELEVANTViscosity
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BARITE POWDERPRODUCT NAME
9.1 Information on basic physical and chemical properties NOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT RELEVENTOdour threshold
9.2 Other information~1.5 kg/LBulk density
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites).
May evolve toxic gases (sulphur oxides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity No known toxicity data is available for this product. Based on available data, the classification criteria are notmet.
Skin Not classified as a skin irritant. Contact may result in mild irritation and dermatitis.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitization The available data is not considered sufficient for classification as a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product is not expected to present an aspiration hazard.
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1).However there is sufficient information to conclude that the relative risk of lung cancer is increased inpersons with silicosis. Therefore preventing the onset of silicosis will also reduce the cancer risk.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Fish toxicity: LC50 (Rainbow trout) = 7500 ppm/96 hour.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.3 Bioaccumulative potentialNo information provided.
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BARITE POWDERPRODUCT NAME
12.5 Other adverse effects
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S22 Do not breathe dust.S45 In case of accident or if you feel unwell seek medical advice immediately (show the label
where possible).
Safety phrases
Xn HarmfulHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
Additional information
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BARITE POWDERPRODUCT NAME
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Included bulk density. 2.2
Amended Product Name and Synonyms. 2.1
Converted to GHS. 2.0
Standard SDS Review 1.1
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Page 6 of 7
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BARITE POWDERPRODUCT NAME
SDS date:
[ End of SDS ]
Revision:29 January 20152.2
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SDS Date: 29 Jan 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) CALCIUM CHLORIDE ANHYDRATE
CONCRETE CONDITIONER • DESICCANT • DUST CONTROL AGENT • FOOD ADDITIVE • INDUSTRIALAPPLICATIONS
Use(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
CALCIUM CHLORIDE POWDER 94-97%Product name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word WARNING
Disposal statement(s)None allocated.
Storage statement(s)None allocated.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
If eye irritation persists: Get medical advice/attention.P337 + P313
Response statement(s)
Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes serious eye irritation.H319Hazard statement(s)
Pictogram(s)
Serious Eye Damage / Eye Irritation: Category 2AGHS classification(s)
2.1 Classification of the substance or mixture
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CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
No information provided.2.3 Other hazards
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
CALCIUM CHLORIDE ANHYDROUS 94 to 97%10043-52-4 233-140-8
SODIUM CHLORIDE 1 to 5%7647-14-5 231-598-3
WATER 1%7732-18-5 231-791-2
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
Page 2 of 6SDS Date: 17 Apr 2015
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CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 1600°CBoiling point772°CMelting pointNOT RELEVANTEvaporation rate7.0 to 9.0pHNOT AVAILABLEVapour density2.15Specific gravity590 kg/m³ (Approximately)Solubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
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CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid contact with incompatible substances.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calciumoxide. May react exothermically with water (i.e. releasing heat).
May evolve toxic gases (chlorides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients:CALCIUM CHLORIDE ANHYDROUS (10043-52-4):LD50 (Ingestion): 1000 mg/kg (rat)LD50 (Intraperitoneal): 210 mg/kg (mouse)LD50 (Intravenous): 42 mg/kg (mouse)LD50 (Subcutaneous): 823 mg/kg (mouse)LDLo (Ingestion): 1384 mg/kg (rabbit)LDLo (Intravenous): 150 mg/kg (guinea pig)LDLo (Subcutaneous): 249 mg/kg (cat)TDLo (Intravenous): 20 mg/kg/1 hour (woman)SODIUM CHLORIDE (7647-14-5):LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Intraperitoneal): 2602 mg/kg (mouse)LD50 (Intravenous): 645 mg/kg (mouse)LD50 (Skin): > 10000 mg/kg (rabbit)LD50 (Subcutaneous): 3000 mg/kg (mouse)LDLo (Ingestion): 8000 mg/kg (rabbit)LDLo (Intravenous): 300 mg/kg (guinea pig)LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)
Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.
Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Insufficient data available to classify as a carcinogen.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
Page 4 of 6SDS Date: 17 Apr 2015
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CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R36 Irritating to eyes.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S22 Do not breathe dust.S24 Avoid contact with skin.
Safety phrases
Xi IrritantHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
Page 5 of 6SDS Date: 17 Apr 2015
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CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Additional information
[ End of SDS ]
Page 6 of 6SDS Date: 17 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) CALCIUM CARBONATE • STONE DUST
BRIDGING AGENT • WEIGHTING AGENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
LIMESTONE LSC/L80Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
QUARTZ (CRYSTALLINE SILICA) <1%14808-60-7 238-878-4
CALCIUM CARBONATE >96%471-34-1 207-439-9
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
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LIMESTONE LSC/L80PRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
No fire or explosion hazard exists.5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
If spilt, collect and reuse where possible. Contain spillage, then collect and place in suitable containers for disposal. Avoid generatingdust.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- --
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Page 2 of 6SDS Date: 16 Apr 2015
Version No: 2.1
LIMESTONE LSC/L80PRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Wear a Class P3 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate)respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties OFF-WHITE POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point825°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts.
Polymerization will not occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6SDS Date: 16 Apr 2015
Version No: 2.1
LIMESTONE LSC/L80PRODUCT NAME
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. LD50 (Ingestion): 6450 mg/kg (rat).
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation and rash.
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration Not relevant.
Chronic exposure to respirable silica may result in pulmonary fibrosis (silicosis). However, given the lowlevels present, over exposure is not anticipated.
STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficientrespirable silica in this product to be classified as a carcinogen.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated tocause adverse environmental effects.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances. Dissolved calcium carbonate dissociates into calcium and carbonate ions.Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle.
12.4 Mobility in soil
Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 16 Apr 2015
Version No: 2.1
LIMESTONE LSC/L80PRODUCT NAME
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6SDS Date: 16 Apr 2015
Version No: 2.1
LIMESTONE LSC/L80PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 16 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) AGRICULTURAL LIME • CALCIUM CARBONATE • CHALK • LIMESTONE • OMYACARB 10 • OMYACARB 2• OMYACARB 20 • OMYACARB 40
BRIDGING AGENT • DRILLING FLUID ADDITIVE • WEIGHTING AGENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
OMYACARBProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
<1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
>96%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Page 1 of 6SDS Date: 02 Jun 2015
Version No: 2.2
OMYACARBPRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
No fire or explosion hazard exists.5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
If spilt, collect and reuse where possible. Contain spillage, then collect and place in suitable containers for disposal. Avoid generatingdust.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- --
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Page 2 of 6SDS Date: 02 Jun 2015
Version No: 2.2
OMYACARBPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties OFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point825°CMelting pointNOT RELEVANTEvaporation rateNOT RELEVANTpHNOT AVAILABLEVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT RELEVANTVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT RELEVANT% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts.
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization will not occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6SDS Date: 02 Jun 2015
Version No: 2.2
OMYACARBPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation and rash.
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration Not relevant.
Chronic exposure to respirable silica may result in pulmonary fibrosis (silicosis). However, given the lowlevels present, over exposure is not anticipated.
STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficientrespirable silica in this product to be classified as a carcinogen.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated tocause adverse environmental effects.
12.2 Persistence and degradabilityDissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in thewater and the carbonate will become part of the carbon cycle.
12.4 Mobility in soil
Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 02 Jun 2015
Version No: 2.2
OMYACARBPRODUCT NAME
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6SDS Date: 02 Jun 2015
Version No: 2.2
OMYACARBPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 02 Jun 2015
Version No: 2.2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) SODIUM HYDROXIDE SOLID
MANUFACTURE OF CHEMICALS • REAGENT • SCRUBBING AGENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
CAUSTIC SODAProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word DANGER
Store locked up.P405Storage statement(s)
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P301 + P330 + P331IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.P303 + P361 + P353IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310Specific treatment is advised - see first aid instructions.P321Wash contaminated clothing before reuse.P363
Response statement(s)
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes severe skin burns and eye damage.H314Hazard statement(s)
Pictogram(s)
Skin Corrosion/Irritation: Category 1AGHS classification(s)
2.1 Classification of the substance or mixture
Page 1 of 7SDS Date: 17 Apr 2015
Version No: 2.4
CAUSTIC SODAPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
SODIUM HYDROXIDE >99%1310-73-2 215-185-5
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator where an inhalationrisk exists. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.
Causes severe skin burns and eye damage.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededCORROSIVE POISONING TREATMENT: Immediate treatment preferably in a hospital is mandatory. In treating corrosive poisoning,DO NOT INDUCE VOMITING; DO NOT ATTEMPT GASTRIC LAVAGE; and DO NOT ATTEMPT TO NEUTRALISE THE CORROSIVESUBSTANCE. Vomiting will increase the severity of damage to the oesophagus as the corrosive substance will again come in contactwith it. Attempting gastric lavage may result in perforating either the oesophagus or stomach. Immediately dilute the corrosivesubstance by having the patient drink milk or water. If the trachea has been damaged tracheostamy may be required. Foroesophageal burns begin broad-spectrum antibiotics and corticosteroid therapy. Intravenous fluids will be required if oesophageal orgastric damage prevents ingestion of liquids. Long-range therapy will be directed toward preventing or treating oesophageal scars andstrictures.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve flammable hydrogen gas in contact with some metals. Direct contact with water can produce a violentexothermic reaction.
5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
2X2 Fine Water Spray.X Wear liquid-tight chemical protective clothing and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire. Use carbon dioxide or suitable dry chemical extinguisher. Do NOT usewater.
5.1 Extinguishing media
Page 2 of 7SDS Date: 17 Apr 2015
Version No: 2.4
CAUSTIC SODAPRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Allow only trained personnel wearing appropriateprotective equipment to be involved in spill response. Avoid accidents, clean up immediately. Increase ventilation. Avoid walkingthrough spilled product as it is slippery when spilt. Isolate the danger area. Use clean, non-sparking tools and equipment. Shut off allpossible sources of ignition.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Mechanically collect as much of the spill as possible. Absorb with sand, earth or clay. Transfer to suitable, labelled, corrosion-resistantcontainers and dispose of promptly as hazardous waste. Spill on areas other than pavement, dirt or sand may be handled by removingthe affected soils and placing into approved containers.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such asdamage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Store away fromaluminium, tin, zinc and alloys (bronzes), chrome and lead. Protect from damp and kept apart from acids, halogenated hydrocarbons,nitroparaffins, etc. The floor must be waterproof and anti-slip. A water supply or source must be provided in the place of storage.Emergency showers and eye-washes must be available. Special conditions: Prevent the product from becoming damp or erated.Hygroscopic product. Becomes carbonated in contact with the air or moisture.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommendedprocedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and groundingequipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid prolonged or repeated exposure. Do notsmoke, eat or drink when handling product. Product can react violently with water and acids. Caustic solution generates heat whenfurther diluted with water. Concentrations greater than 40%, the heat generated can raise temperatures above the boiling pointresulting in sporadic, violent eruptions or spattering. Emergency showers and eye-washes must be available. When used in its variousapplications, the product must be prevented from coming into uncontrolled direct contact with other products such as acids andmetals. Never neutralise the solid product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium hydroxide (peak limitation) SWA (AUS) -- 2 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
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PPE
Eye / Face Wear a faceshield and dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Wear coveralls and rubber boots and a PVC apron.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear an Air-linerespirator or a Full-face Class P3 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE DELIQUESCENT PEARLSAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1390°CBoiling point318°CMelting pointNOT AVAILABLEEvaporation rate13.5 (1 % solution)pHNOT AVAILABLEVapour density2.12Specific gravity1110 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityHighly exothermal reaction with strong acids. Reacts dangerously with acetic acid, allyl chloride, chlorine trifluoride, chloroform,methylic alcohol, chloronitrotoluene, chlorosulphonic acid, glyoxal, cyanohydrin, hydrochloric acid, hydrofluoric acid, hydroquinone,nitric acid, sulphuric acid and oleum, nitropropane, phosphorous, propiolactone, phosphorous pentoxide, tetrachlorobenzene,tetrahydrofuran, etc. Caustic soda forms salts with nitromethane and nitroparaffins that explode on impact. Heat is generated whenmixed with water. Spattering and boiling can occur. Caustic soda solution reacts readily with various reducing sugars (ie: fructose,glactose, maltose, dry whey solids) to produce carbon monoxide. Caustic soda forms salts with nitromethane and nitroparaffins thatexplode on impact. Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen.
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Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen. When the product decomposes, toxic sodiumoxide gases are evolved.
10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Acute toxicity Highly corrosive. This product has the potential to cause serious adverse health effects. Use safe workpractices to avoid eye or skin contact and inhalation. Over exposure may result in severe burns withcorrosive tissue damage. Upon dilution, the potential for corrosive effects may be reduced.
SODIUM HYDROXIDE (1310-73-2):LD50 (Intraperitoneal): 40 mg/kg (mouse)LDLo (Ingestion): 1.57 mg/kg (human)
Skin Causes severe burns. Contact may result in irritation, redness, pain, rash, dermatitis and possible burns.
Eye Causes severe burns. Contact may result in irritation, lacrimation, pain, redness and corneal burns withpossible permanent eye damage.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.
STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin. The substance is not expected to besystemically available in the body under normal handling and use conditions and for this reason it can bestated that the substance will not reach the foetus nor reach male and female reproductive organs. Thesubstance is not expected to be systemically available in the body under normal handling and use conditionsand for this reason additional testing is considered unnecessary.
Carcinogenicity Insufficient data available to classify as a carcinogen. Systemic carcinogenicity is not expected to occurbecause the substance is not expected to be systemically available in the body under normal handling anduse conditions.
Mutagenicity Insufficient data available to classify as a mutagen. Both the in vitro and the in vivo genetic toxicity testsindicated no evidence of mutagenic activity. Furthermore the substance is not expected to be systemicallyavailable in the body under normal handling and use conditions and for this reason additional testing isconsidered unnecessary (EU RAR, 2007).
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
EC50 Ceriodaphnia: 40 mg/L.
No other valid studies available. The hazard of NaOH for the environment is caused by the hydroxyl ion (pH effect). For this reason theeffect of NaOH on the organisms depends on the buffer capacity of the aquatic or terrestrial ecosystem (see also 3.1.2). Also thevariation in acute toxicity for aquatic organisms can be explained for a significant extent by the variation in buffer capacity of the testmedium. LC50 values ranged between 33 and 189 mg/L.
12.2 Persistence and degradabilityReadily biodegradable. NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-. High water solubilityand low vapour pressure indicate that NaOH will be found predominantly in aquatic environment. This implies that it will not adsorb onparticulate matter or surfaces. Atmospheric emissions as aerosols are rapidly neutralized by carbon dioxide and the salts will bewashed out by rain.
12.4 Mobility in soil
High water solubility and mobility
12.5 Other adverse effects
WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11(goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expectedto reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
12.3 Bioaccumulative potentialDoes not bioaccumulate. Considering its high water solubility, NaOH is not expected to bioconcentrate in organisms. In addition,sodium is a naturally-occurring element that is prevalent in the environment and to which organisms are exposed regularly, for whichthey have some capacity to regulate the concentration in the organism.
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13. DISPOSAL CONSIDERATIONS
Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required). The product can be neutralisedusing highly diluted hydrochloric acid, which should be added very slowly by specialised personnel wearingproper protection. Never neutralise the solid product.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group II
8 8
II II
814.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
SODIUM HYDROXIDE, SOLID
1823
SODIUM HYDROXIDE, SOLID
1823 1823
SODIUM HYDROXIDE, SOLID
No information provided14.5 Environmental hazards
2XHazchem code
EMS F-A, S-B
8A1GTEPG
14.6 Special precautions for user
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R35 Causes severe burns.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S1/2 Keep locked up and out of reach of children.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS37/39 Wear suitable gloves and eye/face protection.S45 In case of accident or if you feel unwell seek medical advice immediately (show the label
where possible).
Safety phrases
C CorrosiveHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
Additional information
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PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 7 of 7SDS Date: 17 Apr 2015
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1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) 2-HYDROXY-1,2,3-PROPANETRICARBOXYLIC ACID • CITRIC ACID ANHYDROUS • CITRIC ACIDMONOHYDRATE
INDUSTRIAL APPLICATIONSUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
CITRIC ACIDProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word WARNING
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335
Hazard statement(s)
Pictogram(s)
Specific Target Organ Systemic Toxicity (Single Exposure): Category 3Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2A
GHS classification(s)
2.1 Classification of the substance or mixture
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No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statement(s)
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321Take off contaminated clothing and wash before re-use.P362
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
CITRIC ACID >99%77-92-9 201-069-1
WATER <1%7732-18-5 231-791-2
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Acute: Irritating to the eyes and skin. Delayed: No information available.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
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CITRIC ACIDPRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure containers areadequately labelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE CRYSTALLINE POWDERAppearanceODOURLESSOdourCOMBUSTIBLEFlammability174°CFlash point175°C (Decomposes)Boiling point153°CMelting pointNOT AVAILABLEEvaporation rate
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CITRIC ACIDPRODUCT NAME
9.1 Information on basic physical and chemical properties 2.2 (0.1M Solution)pHNOT AVAILABLEVapour density1.665Specific gravity1330 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient345°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and alkalis (e.g. sodium hydroxide).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Based on available data, the classification criteria are not met.LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Intraperitoneal): 290 mg/kg (rat)LD50 (Intravenous): 42 mg/kg (mouse)LDLo (Ingestion): 7000 mg/kg (rabbit)
Skin Irritating to the skin. Contact may result in irritation, redness, rash and dermatitis.
Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns withprolonged contact.
Sensitization This product is not classified as causing skin or respiratory sensitisation. However, citric acid has thepotential to cause allergic effects.
Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing.
STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Insufficient data available to classify as a carcinogen.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
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12. ECOLOGICAL INFORMATION
12.1 Toxicity
LC50 (Leuciscus idus melanotus): 440 mg/L/48hrs.LC50 (Daphnia magna (Water flea)): 1.535 mg/L/24hrs.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
WATER: If citric acid is released to water, it is expected to biodegrade rapidly. May be toxic to fish at moderately high levels (120 ppmis fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which maycause oxygen depletion in large spills. Citric acid occurs naturally in many plants.
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Neutralise with lime, anion exchanger or similar. For small amounts, absorb with sand or similar and disposeof to an approved landfill site. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R36/37/38 Irritating to eyes, respiratory system and skin.Risk phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS37/39 Wear suitable gloves and eye/face protection.
Safety phrases
Xi IrritantHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 5 of 6SDS Date: 17 Apr 2015
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CITRIC ACIDPRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Additional information
[ End of SDS ]
Page 6 of 6SDS Date: 17 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) DEFOAM E • DEFOAM-A (I)
COMPLETION FLUID • DRILLING FLUIDUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
DEFOAM A (I)Product name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word WARNING
Keep away from heat/sparks/open flames/hot surfaces. No smoking.P210Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Combustible liquid.H227Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335May cause drowsiness or dizziness.H336
Hazard statement(s)
Pictogram(s)
Flammable Liquids: Category 4Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Systemic Toxicity (Single Exposure): Category 3Specific Target Organ Systemic Toxicity (Single Exposure): Category 3
GHS classification(s)
2.1 Classification of the substance or mixture
Page 1 of 7SDS Date: 28 Apr 2016
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DEFOAM A (I)PRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Store in a well-ventilated place. Keep cool. Keep container tightly closed.P403 + P233 + P235Store locked up.P405
Storage statement(s)
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321If skin or eye irritation occurs: Get medical advice/ attention.P332 + P337 + P313Take off contaminated clothing and wash before re-use.P362In case of fire: Use appropriate media for extinction.P370 + P378
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>98%123-96-6 204-667-0OCTAN-2-OL
Remainder7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
Page 2 of 7SDS Date: 28 Apr 2016
Version No: 2.2
DEFOAM A (I)PRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal. Eliminate all sources of ignition.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C1 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear nitrile or neoprene gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
Page 3 of 7SDS Date: 28 Apr 2016
Version No: 2.2
DEFOAM A (I)PRODUCT NAME
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties CLEAR LIQUIDAppearanceSLIGHT ODOUROdourCLASS C1 COMBUSTIBLEFlammability88°C (cc)Flash point180°CBoiling point-39°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpH4.5 (Air = 1)Vapour density0.87Specific gravityINSOLUBLESolubility (water)1 mm Hg @ 33°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information100 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Eye Irritant. Contact may result in irritation, lacrimation, pain and redness.
Inhalation Irritant. Over exposure may result in irritation of the nose and throat, coughing and headache. High levelexposure may result in nausea, dizziness and drowsiness.
Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis.
Ingestion May be harmful. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, dizziness anddrowsiness. Aspiration or inhalation may cause chemical pneumonitis and pulmonary oedema.
May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure.Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in centralnervous system (CNS) effects.
Health hazardsummary
11.1 Information on toxicological effects
Toxicity data No LD50 data available for this product.
Page 4 of 7SDS Date: 28 Apr 2016
Version No: 2.2
DEFOAM A (I)PRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Incinerate where available. For small amounts, absorb with sand, vermiculite or similar and dispose of to anapproved landfill site.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 TransportHazard Class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R36/37/38 Irritating to eyes, respiratory system and skin.R67 Vapours may cause drowsiness and dizziness.
Risk phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS36 Wear suitable protective clothing.
Safety phrases
Xi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 5 of 7SDS Date: 28 Apr 2016
Version No: 2.2
DEFOAM A (I)PRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
WORK PRACTICES - SOLVENTS: Organic solvents may present both a health and flammabilityhazard. It is recommended that engineering controls should be adopted to reduce exposure wherepracticable (for example, if using indoors, ensure explosion proof extraction ventilation is available).Flammable or combustible liquids with explosive limits have the potential for ignition from staticdischarge. Refer to AS 1020 (The control of undesirable static electricity) and AS 1940 (The storageand handling of flammable and combustible liquids) for control procedures.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a report whichwould encompass all possible scenarios, it is anticipated that users will assess the risks and applycontrol methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 6 of 7SDS Date: 28 Apr 2016
Version No: 2.2
DEFOAM A (I)PRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 7 of 7SDS Date: 28 Apr 2016
Version No: 2.2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) DEFOAMER
DEFOAM IN DRILLING FLUIDSUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
DEFOAM AP 400Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Identification Classification Content GHS Risk
POLYETHYLENE GLYCOL CAS: 25322-68-3EC: 500-038-2
45 to 60%Not Available Not Available
OCTAN-2-OL CAS: 123-96-6EC: 204-667-0
40 to 55%Not Available Not Available
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
Page 1 of 6
SDS Date: 20 Aug 2014
DEFOAM AP 400PRODUCT NAME
First aid facilities No information provided.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area wherepossible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Page 2 of 6
SDS Date: 20 Aug 2014
DEFOAM AP 400PRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties CLEAR COLOURLESS LIQUIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8 (5% solution)pHNOT AVAILABLEVapour density1.00Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6
SDS Date: 20 Aug 2014
DEFOAM AP 400PRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness.
Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, withcoughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapourpressure, an inhalation hazard is not anticipated with normal use.
Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.
Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.
Low toxicity - low irritant. This product has the potential to irritate mucous membranes. Use safe workpractices to avoid eye or skin contact and inhalation. Due to the low vapour pressure of this product, aninhalation hazard is not anticipated with normal use. Chronic exposure to some glycols may result in liver andkidney damage.
Health hazardsummary
11.1 Information on toxicological effects
Toxicity data POLYETHYLENE GLYCOL (25322-68-3)LD50 (ingestion) 33750 mg/kg (rat)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
ATMOSPHERE: Vapour phase glycols are expected to degrade fairly rapidly by reaction with hydroxyl radicals (eg half-life 32 hoursfor propylene glycol). Removal from air by rainfall is possible. WATER: Should degrade relatively rapidly via biodegradation. SOIL: Ifreleased to soil, relatively rapid biodegradation should also occur. Leaching to groundwater may occur.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarger amounts, contact the manufacturer for additional information. Prevent contamination of drains orwaterways as aquatic life may be threatened and environmental damage may result.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6
SDS Date: 20 Aug 2014
DEFOAM AP 400PRODUCT NAME
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACEEXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hourwork period of normal intensity, under normal climatic conditions and where a 16 hour break betweenshifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances,exposure standards must be reduced: strenuous work conditions; hot, humid climates; high altitudeconditions; extended shifts (which increase the exposure period and shorten the period ofrecuperation).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6
SDS Date: 20 Aug 2014
DEFOAM AP 400PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Initial SDS Creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:20 August 20141
Page 6 of 6
SDS Date: 20 Aug 2014
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 1/9
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information
Product Name : Driscal® D Polymer Material : 1112534, 1016818
EC-No.Registration number
Chemical name CAS-No. EC-No.
Index No.
Legal Entity Registration number
2-Acrylamido-2-Methylpropane Sulfonic Acid, Sodium Salt
5165-97-9 225-948-4
Chevron Phillips Chemicals International NV 01-2119495270-39-0016
Company : Chevron Phillips Chemical Company LP
Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380
Local : Chevron Phillips Chemicals International N.V.
Airport Plaza (Stockholm Building) Leonardo Da Vincilaan 19 1831 Diegem Belgium SDS Requests: (800) 852-5530 Technical Information: (832) 813-4862 Responsible Party: Product Safety Group Email:[email protected]
Emergency telephone:
Health:
866.442.9628 (North America) 1.832.813.4984 (International) Transport:
CHEMTREC 800.424.9300 or 703.527.3887(int'l)
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 2/9
Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Mexico CHEMTREC 01-800-681-9531 (24 hours) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Argentina: +(54)-1159839431
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
Classification of the substance or mixture REGULATION (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Label elements
Labeling (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
SECTION 3: Composition/information on ingredients
Synonyms : High Temperature Polymer
Contains no hazardous ingredients according to GHS. :
Remarks : Contains no hazardous ingredients according to GHS.
SECTION 4: First aid measures
General advice : No hazards which require special first aid measures. If inhaled : If unconscious, place in recovery position and seek medical
advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye
irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to
an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : Not applicable Autoignition temperature : No data available
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 3/9
Specific hazards during fire fighting
: Risks of ignition followed by flame propagation or secondary explosions can be caused by the accumulation of dust, e.g. on floors and ledges.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if necessary.
Further information : Standard procedure for chemical fires. Use extinguishing
measures that are appropriate to local circumstances and the surrounding environment.
Fire and explosion protection
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Hazardous decomposition products
: No data available.
SECTION 6: Accidental release measures
Personal precautions : Avoid dust formation. Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities. Methods for cleaning up : Pick up and arrange disposal without creating dust. Clean up
promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.
Additional advice : Contaminated surfaces will be extremely slippery. Avoid
spillage on floor as the product can become very slippery when wet. Sweep up to prevent slipping hazard. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
SECTION 7: Handling and storage
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and
drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.
Advice on protection against fire and explosion
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Storage
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 4/9
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
SECTION 8: Exposure controls/personal protection
Engineering measures
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a supplied-air NIOSH approved respirator unless
ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.
Hand protection : The suitability for a specific workplace should be discussed
with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : General industrial hygiene practice.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance
Form : Powder Physical state : Solid
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 5/9
Color : White Odor : No odor Odor Threshold : No data available
Safety data
Flash point : Not applicable
Lower explosion limit : No data available
Upper explosion limit : No data available
Oxidizing properties : No
Autoignition temperature : No data available
Thermal decomposition : No data available
Molecular weight : Not applicable
pH : Not applicable
Pour point : No data available
Boiling point/boiling range : No data available
Vapor pressure : No data available
Relative density : 1,44
Density : No data available
Water solubility : Soluble
Partition coefficient: n-octanol/water
: Pow: < 3
Viscosity, kinematic : No data available
Relative vapor density : No data available
Evaporation rate : No data available
SECTION 10: Stability and reactivity
Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 6/9
Conditions to avoid : Generation of Dusts. Thermal decomposition : No data available
Hazardous decomposition products
: No data available
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Driscal® D Polymer Further information : The product contains no substances classified as hazardous
to health in concentrations which should be taken into account.
SECTION 12: Ecological information
Elimination information (persistence and degradability) Bioaccumulation : Accumulation in aquatic organisms is unlikely.
Biodegradability : Taking into consideration the properties of several ingredients,
the product is estimated not to be readily biodegradable according to OECD classification.
Ecotoxicology Assessment
Additional ecological information
: This material is not expected to be harmful to aquatic organisms.
SECTION 13: Disposal considerations
The information in this SDS pertains only to the product as shipped.
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste
disposal facility.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
SECTION 14: Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 7/9
bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
Major Accident Hazard Legislation
: 96/82/EC Update: 2003 Directive 96/82/EC does not apply
Water contaminating class (Germany)
: nwg not water endangering
: nwg not water endangering
Notification status
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 8/9
Europe REACH : On the inventory, or in compliance with the inventory Switzerland CH INV : On the inventory, or in compliance with the inventory United States of America (USA) TSCA
: On TSCA Inventory
Canada DSL : All components of this product are on the Canadian DSL
Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : This product contains one or more substances that
have been notified under New Substances Notification laws. However, only CPChem and other independent notifiers are approved to be the importers of record.
SECTION 16: Other information
NFPA Classification : Health Hazard: 0 Fire Hazard: 2 Reactivity Hazard: 0
Further information
Legacy SDS Number : 244990
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions.
The information in this SDS pertains only to the product as shipped.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of
Government Industrial Hygienists LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical Substances
LOAEL Lowest Observed Adverse Effect Level
DSL Canada, Domestic Substances List
NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substances List
NIOSH National Institute for Occupational Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals
EC50 Effective Concentration NOAEL No Observable Adverse Effect Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health
0
2
0
SAFETY DATA SHEET
Driscal® D Polymer
Version 1.13 Revision Date 2017-09-05
SDS Number:100000066569 9/9
Scenario Tool Administration
EOSCA European Oilfield Specialty Chemicals Association
PEL Permissible Exposure Limit
EINECS European Inventory of Existing Chemical Substances
PICCS Philippines Inventory of Commercial Chemical Substances
MAK Germany Maximum Concentration Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act.
IARC International Agency for Research on Cancer
TLV Threshold Limit Value
IECSC Inventory of Existing Chemical Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory
UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System
LC50 Lethal Concentration 50%
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 1/11
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information
Product Name : Drispac® Plus Regular and Superlo® Polymer Material : 1016814, 1016815
Use : Drilling Mud Additive Company : Chevron Phillips Chemical Company LP
Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380
Emergency telephone: Health:
866.442.9628 (North America) 1.832.813.4984 (International) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: +800 CHEMCALL (+800 2436 2255) China:+86-21-22157316 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
Classification of the substance or mixture
This product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labels contain all the information as required by the standard.
Emergency Overview
Warning
Form: Powder Physical state: Solid Color: off-white Odor: Mild OSHA Hazards : Combustible dust
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 2/11
Classification : Combustible dust
Labeling
Signal Word : Warning
Hazard Statements : May form combustible dust concentrations in air.
Potential Health Effects
Physical Hazards : Mechanical processing may form combustible dust concentrations in air and thermal processing at elevated temperatures may generate simple hydrocarbons and carbon oxides.
Carcinogenicity:
IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
ACGIH No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
SECTION 3: Composition/information on ingredients
Synonyms : None Established
Molecular formula : Mixture
Component CAS-No. Weight %
Sodium Carboxymethylcellulose 9004-32-4 95 - 99
Saturated monocarboxylic acid, calcium salt
Proprietary 1 - 5
SECTION 4: First aid measures
General advice : No hazards which require special first aid measures. If inhaled : If unconscious place in recovery position and seek medical
advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye
irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 3/11
an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : Not applicable Autoignition temperature : Not applicable
Specific hazards during fire fighting
: Risks of ignition followed by flame propagation or secondary explosions can be caused by the accumulation of dust, e.g. on floors and ledges.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if necessary.
Further information : Standard procedure for chemical fires. Use extinguishing
measures that are appropriate to local circumstances and the surrounding environment.
Fire and explosion protection
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Hazardous decomposition products
: No data available.
SECTION 6: Accidental release measures
Personal precautions : Avoid dust formation. Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities. Methods for cleaning up : Pick up and arrange disposal without creating dust. Clean up
promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.
Additional advice : Dust deposits should not be allowed to accumulate on
surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
SECTION 7: Handling and storage
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and
drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 4/11
Advice on protection against fire and explosion
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Storage
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
SECTION 8: Exposure controls/personal protection
Ingredients with workplace control parameters
US
Ingredients Basis Value Control parameters Note
Saturated monocarboxylic acid, calcium salt
ACGIH TWA 10 mg/m3 URT irr, eye irr, skin irr, A4,
A4 Not classifiable as a human carcinogen eye irr Eye irritation skin irr Skin irritation
URT irr Upper Respiratory Tract irritation
Engineering measures
Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a NIOSH approved respirator that provides protection
when working with this material if exposure to harmful levels of airborne material may occur, such as:. Wear a supplied-air NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.
Hand protection : The suitability for a specific workplace should be discussed
with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Eye wash bottle with pure water. Safety glasses.
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 5/11
Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : General industrial hygiene practice.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance
Form : Powder Physical state : Solid Color : off-white Odor : Mild Odor Threshold : No data available
Safety data
Flash point : Not applicable
Lower explosion limit : Not applicable
Upper explosion limit : Not applicable
Oxidizing properties : No
Autoignition temperature : Not applicable
Thermal decomposition : No data available
Molecular formula : Mixture
Molecular weight : Not applicable
pH : Not applicable
Pour point : No data available
Boiling point/boiling range : No data available
Vapor pressure : Not applicable
Relative density : Not applicable
Density : 1.5 g/cm3
Water solubility : Completely Soluble
Partition coefficient: n-octanol/water
: No data available
Solubility in other solvents : No data available
Viscosity, kinematic : No data available
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 6/11
Relative vapor density : Not applicable
Evaporation rate : No data available
Dust deflagration index Kst : > 0.0 m.b_/s
SECTION 10: Stability and reactivity
Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions
Conditions to avoid : Generation of Dusts. Thermal decomposition : No data available
Hazardous decomposition products
: No data available
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Drispac® Plus Regular and Superlo® Polymer Acute oral toxicity : LD50: > 5,000 mg/kg
Species: Rat Method: Acute toxicity estimate
Acute inhalation toxicity
Sodium Carboxymethylcellulose
: LC50: > 5800 mg/m3Exposure time: 4 h Species: Rat
Drispac® Plus Regular and Superlo® Polymer Acute dermal toxicity : LD50: > 2,000 mg/kg
Species: Rabbit Method: Acute toxicity estimate
Drispac® Plus Regular and Superlo® Polymer Skin irritation : No skin irritation
Drispac® Plus Regular and Superlo® Polymer Eye irritation : No eye irritation
Drispac® Plus Regular and Superlo® Polymer Aspiration toxicity : No aspiration toxicity classification.
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 7/11
Drispac® Plus Regular and Superlo® Polymer Further information : No data available.
SECTION 12: Ecological information
Elimination information (persistence and degradability) Biodegradability : Taking into consideration the properties of several ingredients,
the product is estimated to be biodegradable according to OECD classification.
Ecotoxicology Assessment
Additional ecological information
: This material is not expected to be harmful to aquatic organisms.
SECTION 13: Disposal considerations
The information in this SDS pertains only to the product as shipped.
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste
disposal facility.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
SECTION 14: Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 8/11
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
SARA 311/312 Hazards : Fire Hazard
CERCLA Reportable Quantity
: This material does not contain any components with a CERCLA RQ.
SARA 302 Reportable Quantity
: This material does not contain any components with a SARA 302 RQ.
SARA 302 Threshold Planning Quantity
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 304 Reportable Quantity
: This material does not contain any components with a section 304 EHS RQ.
SARA 313 Ingredients : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 9/11
Ozone-Depletion Potential
: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).
US State Regulations
Pennsylvania Right To Know : No components are subject to the Pennsylvania Right to Know
Act. New Jersey Right To Know : No components are subject to the New Jersey Right to Know
Act. California Prop. 65 Ingredients
: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
Notification status
Europe REACH : On the inventory, or in compliance with the inventory United States of America TSCA : On the inventory, or in compliance with the inventory Canada DSL : On the inventory, or in compliance with the inventory Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : On the inventory, or in compliance with the inventory Korea KECI : On the inventory, or in compliance with the inventory Philippines PICCS : On the inventory, or in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 10/11
SECTION 16: Other information
NFPA Classification : Health Hazard: 0
Fire Hazard: 2 Reactivity Hazard: 0
Further information
Legacy SDS Number : 240200
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions.
The information in this SDS pertains only to the product as shipped.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of
Government Industrial Hygienists LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical Substances
LOAEL Lowest Observed Adverse Effect Level
DSL Canada, Domestic Substances List
NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substances List
NIOSH National Institute for Occupational Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals
EC50 Effective Concentration NOAEL No Observable Adverse Effect Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure Scenario Tool
OSHA Occupational Safety & Health Administration
EOSCA European Oilfield Specialty Chemicals Association
PEL Permissible Exposure Limit
EINECS European Inventory of Existing Chemical Substances
PICCS Philippines Inventory of Commercial Chemical Substances
MAK Germany Maximum Concentration Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act.
IARC International Agency for Research on Cancer
TLV Threshold Limit Value
IECSC Inventory of Existing Chemical TWA Time Weighted Average
0
2
0
SAFETY DATA SHEET
Drispac® Plus Regular and Superlo® Polymer
Version 2.1 Revision Date 2016-06-01
SDS Number:100000014006 11/11
Substances in China
ENCS Japan, Inventory of Existing and New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory
UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System
LC50 Lethal Concentration 50%
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1093242, 1016819 - MATERIAL NUMBERSynonyms
DEFOAMER ● DEFOAMING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
DSCO DEFOAMProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>60%25322-69-4 500-039-8POLYPROPYLENE GLYCOL
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 08 Jun 2018
Version No: 2ofPage 1 6
DSCO DEFOAMPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
SDS Date: 08 Jun 2018
Version No: 2ofPage 2 6
DSCO DEFOAMPRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls. In a laboratory situation,wear a laboratory coat.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCLEAR TO LIGHT AMBER LIQUIDAppearanceSLIGHT ODOUROdourCLASS C2 COMBUSTIBLEFlammability185°CFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.00Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising properties
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsAcute toxicity
11.1 Information on toxicological effects
SDS Date: 08 Jun 2018
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DSCO DEFOAMPRODUCT NAME
are not anticipated.
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
300 - 57000 mg/kg(range)
-- --POLYPROPYLENE GLYCOL
Not classified as a skin irritant. Contact may cause temporary mild skin irritation.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 08 Jun 2018
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DSCO DEFOAMPRODUCT NAME
None allocated.Hazchem code
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.NEW ZEALAND: NZIoC (New Zealand Inventory of Chemicals)All components are listed on the NZIoC inventory, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 08 Jun 2018
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DSCO DEFOAMPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 08 Jun 2018
Version No: 2ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) POTASSIUM SILICATE POWDER
DRILLING AIDUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
FLEXFIRM KAProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word WARNING
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Harmful if swallowed.H302Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335May cause damage to organs through prolonged or repeated exposure.H373
Hazard statement(s)
Pictogram(s)
Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2Specific Target Organ Systemic Toxicity (Single Exposure): Category 3Acute Toxicity: Oral: Category 4Serious Eye Damage / Eye Irritation: Category 2ASkin Corrosion/Irritation: Category 2
GHS classification(s)
2.1 Classification of the substance or mixture
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FLEXFIRM KAPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statement(s)
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Get medical advice/attention if you feel unwell.P314Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin or eye irritation occurs: Get medical advice/ attention.P332 + P337 + P313Take off contaminated clothing and wash before re-use.P362
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
0.1 to 1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
99%1312-76-1 215-199-1POTASSIUM SILICATE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
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FLEXFIRM KAPRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point
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9.1 Information on basic physical and chemical properties NOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate11.3 (50 % solution) (Approximately)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:Harmful if swallowed.
Information available for the ingredient(s):
IngredientOral Toxicity
(LD50)Dermal Toxicity
(LD50)Inhalation Toxicity
(LC50)
1600 mg/kg (rat) -- --POTASSIUM SILICATE
Skin Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns.
Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possibleburns.
Sensitization Not classified as causing skin or respiratory sensitisation.
Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing. High level exposure may result in breathing difficulties.
STOT – singleexposure
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularSTOT – repeated
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is a body ofevidence supporting the fact that increased cancer risk would be limited to people already suffering fromsilicosis.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
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FLEXFIRM KAPRODUCT NAME
Aspiration Not classified as causing aspiration.
lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
exposure
12. ECOLOGICAL INFORMATION
12.1 Toxicity
The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similarSodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour mediantolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hourmedian tolerance for Amphipoda of 160 ppm.
12.2 Persistence and degradabilityThis material is not persistent in aquatic systems.
12.4 Mobility in soil
Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable fromnatural dissolved silica.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNeither silica nor potassium will appreciably bio-concentrate up the food chain.
13. DISPOSAL CONSIDERATIONS
Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Xi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 5 of 7SDS Date: 23 Oct 2015
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FLEXFIRM KAPRODUCT NAME
R22 Harmful if swallowed.R36/37/38 Irritating to eyes, respiratory system and skin.R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S22 Do not breathe dust.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Safety phrases
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Additional information
Page 6 of 7SDS Date: 23 Oct 2015
Version No: 2.3
FLEXFIRM KAPRODUCT NAME
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 7 of 7SDS Date: 23 Oct 2015
Version No: 2.3
Frac-Attack
Safety Data Sheet
Product Identifier Frac-Attack
Other Means ofIdentification
None
Other Identification None
Recommended Use
Product Family Mixture
Emergency Phone No.
SECTION 1. IDENTIFICATION
Secure Energy ServicesSuite 3600, 205 - 5 Avenue SW, Calgary, Alberta, T2P 2V7, www.secure-energy.com
Supplier Identifier
Loss circulation material.
CANUTEC, (613) 996-6666, 24/7
Restrictions on Use None known.
Date of Preparation February 13, 2017
Label Elements
SECTION 2. HAZARD IDENTIFICATION
Signal Word:WarningHazard Statement(s):H315 Causes skin irritation.H335 May cause respiratory irritation.H290 May be corrosive to metals.H350 May cause cancer.Precautionary Statement(s): Prevention:P202 Do not handle until all safety precautions have been read and understood.P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P264 Wash hands and skin thoroughly after handling.P271 Use only outdoors or in a well-ventilated area.P280 Wear protective gloves/protective clothing/eye protection/face protection. Response:P312 Call a POISON CENTRE or doctor if you feel unwell.P302 + P352 IF ON SKIN: Wash with plenty of water.P332 + P313 If skin irritation occurs: Get medical advice/attention.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P308 + P313 IF exposed or concerned: Get medical advice or attention.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.P308 + P313 IF exposed or concerned: Get medical advice or attention. Storage:P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Disposal:P501 Dispose of contents and container in accordance with local, regional, national and internationalregulations.
Classification
Corrosive to metals - Category 1; Skin irritation - Category 2; Serious eye damage - Category 1; Carcinogenicity -Category 1A; Specific target organ toxicity (single exposure) - Category 3; Aquatic hazard (Acute) - Category 3
Classified according to Canada's Hazardous Products Regulations (WHMIS 2015) and the US Hazard CommunicationStandard (HCS 2012).
Date of Preparation: Page of 0701February 13, 2017
Product Identifier: Frac-Attack
P332 + P313 If skin irritation occurs: Get medical advice/attention.P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P308 + P313 IF exposed or concerned: Get medical advice or attention.P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.P308 + P313 IF exposed or concerned: Get medical advice or attention. Storage:P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Disposal:P501 Dispose of contents and container in accordance with local, regional, national and internationalregulations.
Other Hazards
No additional information available.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Proprietary Proprietary None> 91
Calcium hydroxide 1305-62-0 None8
Silica, quartz 14808-60-7 None< 1
Notes
*Proprietary: Respirable Dust**The specific chemical identity of this material is being withheld as a trade secret. It will be provided in accordance withthe provisions of 29CFR Part 1910.1200 (i). In the event of a medical emergency, it will be provided to the treatingphysician or nurse through utilization of the listed emergency telephone number (337) 785-0000, (888)656-0001
Inhalation
Remove to fresh air. Get medical advice or attention if you feel unwell or are concerned.
Skin Contact
Wash thoroughly with soap and water. Get medical advice or attention if you feel unwell or are concerned.
Eye Contact
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If eye irritation persists, getmedical advice or attention.
Ingestion
Do not induce vomiting. Slowly dilute with 1 – 2 glasses of water or milk and seek medical attention. Never giveanything by mouth to an unconscious person.
First-aid Comments
Get medical advice or attention if you feel unwell or are concerned.
Special Instructions
Not available.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
Not available.
Target Organs
Respiratory system, digestive system, eyes.
Most Important Symptoms and Effects, Acute and Delayed
If in eyes: may cause pain and minor eye irritation with contact.If swallowed: ingestion can cause irritation to the gastrointestinal tract.If inhaled: may irritate mucus membranes of the nose, throat and upper respiratory tract.
Date of Preparation: Page of 0702February 13, 2017
Product Identifier: Frac-Attack
Not available.
Extinguishing Media
Suitable Extinguishing Media
Dry chemical, carbon dioxide, alcohol foam, water spray Use extinguishing media for surrounding fire.
Unsuitable Extinguishing Media
Not available.
Specific Hazards Arising from the Product
Not available.Not available.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.No special equipment is required. Wear equipment suitable for surrounding fire.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
Wear appropriate PPE as outlined in section 8.
Environmental Precautions
Not available.
Methods and Materials for Containment and Cleaning Up
Sweep or scoop and collect material for reuse.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
It is good practice to: avoid breathing product; avoid skin and eye contact and wash hands after handling.
Conditions for Safe Storage
Store in clean, cool, well ventilated area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Silica, quartz 0.025 mg/m3(R) A2
Notestablished
0.1 mg/m3(R)
Notestablished
Notestablished
Notestablished
Calcium hydroxide 5 mg/m3 Notestablished
5 mg/m3 Notestablished
Notestablished
Notestablished
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
No information available.
Chemical resistant gloves are suggested but not necessary. Clean, body covering clothing.Not available.
Safety glasses.
General ventilation is usually adequate. Provide eyewash and safety shower if contact or splash hazard exists.
Date of Preparation: Page of 0703February 13, 2017
Product Identifier: Frac-Attack
pH Not available
Appearance Brown - grey powder.
Partition Coefficient,n-Octanol/Water (Log Kow)
Not available
Odour Not available
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point Not available
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) 2.10
Upper/Lower Flammability orExplosive Limit
Not available (upper); Not available (lower)
Solubility Practically insoluble in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Basic Physical and Chemical Properties
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
Incompatible materials.
Incompatible Materials
Strong oxidizing agents (e.g. perchloric acid).Not available.
Hazardous Decomposition Products
Fluorine, oxygen difluoride, chlorine, trifluoride, hydrofluoric acid.
Possibility of Hazardous Reactions
Hazardous polymerization will not occur.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
LC50: No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion; inhalation; skin contact; eye contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Date of Preparation: Page of 0704February 13, 2017
Product Identifier: Frac-Attack
LC50: No information was located.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
May cause pain and minor eye irritation with contact.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
May irritate mucus membranes of the nose, throat and upper respiratory tract.
Skin Absorption
No information was located.
Ingestion
Ingestion can cause irritation to the gastrointestinal tract.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Silica (Quartz) is a possible human carcinogen.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
LD50 (dermal): No information was located.
Key to Abbreviations
IARC = International Agency for Research on Cancer. Group 1 = Carcinogenic to humans.ACGIH® = American Conference of Governmental Industrial Hygienists. A2 = Suspected human carcinogen.NTP = National Toxicology Program. Known carcinogen = Known human carcinogen.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
Silica, quartz Not available 500 mg/kg (rat) Not available
Calcium hydroxide Not available 7340 mg/kg (rat) Not available
Chemical Name IARC ACGIH® NTP OSHA
Silica, quartz Group 1 A2 Known carcinogen Not Listed
Calcium hydroxide Not Listed Not designated Not Listed Not Listed
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Acute Aquatic Toxicity
Date of Preparation: Page of 0705February 13, 2017
Product Identifier: Frac-Attack
No information was located.
No information was located.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 CrustaceaErC50 AquaticPlants
ErC50 Algae
Silica, quartz Not available Not available Not available Not available
Calcium hydroxide Not available 49.1 mg/L (Daphniamagna (water flea);48-hour)
Not available 184.6 mg/L(Pseudokirchneriellasubcapitata (algae);72-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction. The requiredhazard evaluation of the waste and compliance with the applicable hazardous waste laws are the responsibility of theuser. Store product for disposal as described under Storage in Section 7 of this safety data sheet. Dispose of or recycleempty containers through an approved waste management facility.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG regulations. Not regulated under US DOT Regulations.
Special Precautions Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
CEPA - National Pollutant Release Inventory (NPRI)
Not specifically listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
Not available.
Safety, Health and Environmental Regulations
SECTION 16. OTHER INFORMATION
SDS Prepared By Safety Committee
Phone No. 403-264-1588
Date of Preparation February 13, 2017
Revision Indicators Not applicable.
February 13, 2017Date of Last Revision
Date of Preparation: Page of 0706February 13, 2017
Product Identifier: Frac-Attack
Key to Abbreviations ACGIH® = American Conference of Governmental Industrial HygienistsAIHA® = AIHA® Guideline Foundation. DSL = Domestic Substances ListHSDB® = Hazardous Substances Data BankIARC = International Agency for Research on CancerIDLH = Immediately Dangerous to Life and HealthNDSL = Non-Domestic Substances ListNFPA = National Fire Prevention AssociationNIOSH = National Institute for Occupational Safety and HealthNTP = National Toxicology ProgramOSHA = US Occupational Safety and Health AdministrationPEL = Permissible Exposure LimitREL = Recommended Exposure LimitRTECS® = Registry of Toxic Effects of Chemical SubstancesSTEL = Short Term Exposure LimitTSCA = Toxic Substances Control ActTWA = Time Weighted Average
References CHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS).HSDB® database. US National Library of Medicine. Available from Canadian Centre forOccupational Health and Safety (CCOHS). NIOSH Pocket Guide database. National Institutefor Occupational Safety and Health. Available from Canadian Centre for Occupational Healthand Safety (CCOHS). Registry of Toxic Effects of Chemical Substances (RTECS®) database.Dassault Systèmes/BIOVIA (“BIOVIA”). Available from Canadian Centre for OccupationalHealth and Safety (CCOHS).
Additional Information No additional information is available
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neitherthe above named supplier nor any of its subsidiaries assumes any liability whatsoever for theaccuracy or completeness of the information contained herein. Final determination of suitabilityof any material is the sole responsibility of the user. All materials may present unknownhazards and should be used with caution. Although certain hazards are described herein, wecannot guarantee that these are the only hazards that exist.
Secure Energy Services expressly disclaims all expressed or implied warranties ofmerchantability and fitness for a particular purpose with respect to the product provided.
Revision Indicators Not applicable.
Date of Preparation: Page of 0707February 13, 2017
Product Identifier: Frac-Attack
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s)
DRILLING AIDUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
GAGETROLProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%9057-06-1 -CARBOXYMETHYL STARCH
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation Due to product form / nature of use, an inhalation hazard is not anticipated.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
First aid facilities No information provided.
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
Page 1 of 6SDS Date: 02 Jun 2015
Version No: 2.2
GAGETROLPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Use engineering controls to eliminate potential dust exposure.8.2 Exposure controls
Page 2 of 6SDS Date: 02 Jun 2015
Version No: 2.2
GAGETROLPRODUCT NAME
PPE
Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties OFF-WHITE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5 (4 % solution)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.
Skin Not classified as a skin irritant. Contact may result in mild irritation.
Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation.
Sensitization This product is not known to be a skin or respiratory sensitiser.
11.1 Information on toxicological effects
Page 3 of 6SDS Date: 02 Jun 2015
Version No: 2.2
GAGETROLPRODUCT NAME
No known effects from this product.STOT – singleexposure
Aspiration Not relevant.
No known effects from this product.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal No special precautions are required for the disposal of this product.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 4 of 6SDS Date: 02 Jun 2015
Version No: 2.2
GAGETROLPRODUCT NAME
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
Additional information
Page 5 of 6SDS Date: 02 Jun 2015
Version No: 2.2
GAGETROLPRODUCT NAME
[ End of SDS ]
Page 6 of 6SDS Date: 02 Jun 2015
Version No: 2.2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) DIUTAN GUM
VISCOSITY MODIFIERUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
GEOVISProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
D-GLUCURONO-6-DEOXY-L-MANNO-D-GLUCAN,ACETATE, CALCIUM MAGNESIUM POTASSIUM SODIUMSALT
>50%595585-15-2 -
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
First aid facilities No information provided.
Page 1 of 6
SDS Date: 10 Nov 2014
GEOVISPRODUCT NAME
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
Page 2 of 6
SDS Date: 10 Nov 2014
GEOVISPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE TO TAN POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNON VOLATILEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficient351°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information0 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Page 3 of 6
SDS Date: 10 Nov 2014
GEOVISPRODUCT NAME
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.
Skin Not classified as a skin irritant. Contact may result in mild irritation. The hydrophilic nature of the notifiedpolymer in powder form can contribute to mechanical irritation and collection in the eyes when dust isgenerated.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness. The hydrophilicnature of the notified polymer in powder form can contribute to mechanical irritation and collection on the skinwhen dust is generated.
Sensitization This product is not known to be a skin or respiratory sensitiser.
No known effects from this product. The hydrophilic nature of the notified polymer in powder form cancontribute to mechanical irritation and collection in the airways when dust is generated.
STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
No known effects from this product.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
The notified polymer is not toxic to fish (rainbow trout), aquatic invertebrates (daphnia magna) and marine invertebrates (acartia tonsa)under test conditions.
12.2 Persistence and degradabilityConsidered readily biodegradable.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo experimental results provided. However, based on the molecular weight, water solubility and Kow value the notified polymer is notexpected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6
SDS Date: 10 Nov 2014
GEOVISPRODUCT NAME
None AllocatedHazchem code
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6
SDS Date: 10 Nov 2014
GEOVISPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:10 November 20142
Page 6 of 6
SDS Date: 10 Nov 2014
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) IDCIDE 20
BIOCIDE • DRILLING FLUID ADDITIVE • WATER TREATMENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
IDCIDE-20Product name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word WARNING
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Specific treatment is advised - see first aid instructions.P321If skin irritation or rash occurs: Get medical advice/attention.P333 + P313Take off contaminated clothing and wash before re-use.P362
Response statement(s)
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes skin irritation.H315May cause an allergic skin reaction.H317Causes serious eye irritation.H319
Hazard statement(s)
Pictograms
Skin Sensitization: Category 1Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2A
GHS classification
2.1 Classification of the substance or mixture
Page 1 of 7
SDS Date: 28 Jul 2014
IDCIDE-20PRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Storage statement(s)None allocated.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Identification Classification Content GHS Risk
TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE
CAS: 55566-30-8EC: 259-709-0
18 to 25%Not Available Not Available
WATER CAS: 7732-18-5EC: 231-791-2
RemainderNot Available Not Available
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities should be available.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides, sulphur oxides and phosphates when heated todecomposition.
5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area wherepossible.
6.1 Personal precautions, protective equipment and emergency procedures
Page 2 of 7
SDS Date: 28 Jul 2014
IDCIDE-20PRODUCT NAME
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear a faceshield and splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Not required under normal conditions of use.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties COLOURLESS TO PALE YELLOW LIQUIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 100°CBoiling point< 0°CMelting pointAS FOR WATEREvaporation rate3.0 to 3.5pHNOT AVAILABLEVapour density1.08Specific gravitySOLUBLESolubility (water)
Page 3 of 7
SDS Date: 28 Jul 2014
IDCIDE-20PRODUCT NAME
9.1 Information on basic physical and chemical properties 18 mm Hg @ 20°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information> 60 % (Water)% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).
May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Eye Irritant. Contact may result in irritation, lacrimation, pain and redness.
Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, withcoughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapourpressure, an inhalation hazard is not anticipated with normal use.
Skin Irritant. Contact may result in irritation. May cause sensitisation by skin contact.
Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain anddiarrhoea.
May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure.Upon dilution, the potential for adverse health effects may be reduced.
Health hazardsummary
11.1 Information on toxicological effects
Toxicity data TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8)LD50 (ingestion) 248 mg/kg (rat)TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)
Page 4 of 7
SDS Date: 28 Jul 2014
IDCIDE-20PRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):LC50 (Rainbow Trout) = 119 mg/L/96 hrLC50(Bluegill Sunfish) = 93 mg/L/ 96 hrEC50 (Daphnia Magna) = 19 mg/L/48 hrLC50 (Brown Shrimp) = 340 mg/L/96 hrLC50 (Mysid Shrimp ) = 9.5 mg/L/96 hrLC50 (Sheepshead Minnow) = 94 mg/L/96 hrLC50 (Jevenile Plaice) = 86 mg/L/96 hr
Waste Water managementEC50 (Activated Sludge) = 24 mg/L/3 hr
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarger amounts, contact the manufacturer for additional information. Prevent contamination of drains orwaterways as aquatic life may be threatened and environmental damage may result.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
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IDCIDE-20PRODUCT NAME
R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.
Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S23 Do not breathe gas/fumes/vapour/spray (where applicable).S24/25 Avoid contact with skin and eyes.S36 Wear suitable protective clothing.
Safety phrases
Xi IrritantHazard codes
16. OTHER INFORMATION
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 6 of 7
SDS Date: 28 Jul 2014
IDCIDE-20PRODUCT NAME
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:28 July 20142
Page 7 of 7
SDS Date: 28 Jul 2014
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) JK - 161 LV • LOW MOLECULAR WEIGHT PHPA • PARTIALLY HYDROLYZED POLYACRYLAMIDE •PHPA
ENCAPSULATING AGENT • HIGH PERFORMANCE WBMUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
JK-161 LVProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
ACRYLAMIDE, SODIUM ACRYLATE COPOLYMER >90%25085-02-3 607-529-1
WATER Remainder7732-18-5 231-791-2
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.
Page 1 of 6SDS Date: 17 Apr 2015
Version No: 1.3
JK-161 LVPRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Acrylamide SWA (AUS) -- 0.03 -- --
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
Page 2 of 6SDS Date: 17 Apr 2015
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JK-161 LVPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE GRANULAR SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.8Specific gravity10 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6SDS Date: 17 Apr 2015
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JK-161 LVPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401).
Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.
Eye Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not classified to be a skin or respiratory sensitiser. However, allergic reactions are possible.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product is not classified as causing aspiration.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive This product is not classified as a reproductive toxin.
Carcinogenicity This product may contain trace amounts of residual acrylamide, which is classified as a probable humancarcinogen (IARC Group 2A). However, due to the very low levels present, adverse health effects are notanticipated with normal use.
Mutagenicity This product is not classified as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
(10000 ppm test concentration) (EPA-821-R-02-012)Mysidopsis bahia = 48hr LC50 = 16.2 mg/L.Menidia beryllina = 48hr LC50 = 34.2 mg/L.Scophthalmus Maximus = 96hr LC50 > 1000 mg/L.Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L]Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L]Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg
12.2 Persistence and degradabilityNot readily biodegradable (by OECD criteria).
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialBased on its structural properties, the polymer is not biologically available. Accumulation in organisms is not to be expected.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 17 Apr 2015
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JK-161 LVPRODUCT NAME
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
ACRYLIC - ACRYLAMIDE RESINS: These resins are generally of low toxicity. Toxicity increases withpresence of significant concentrations of acrylic - acrylamide monomers. These monomers havebeen linked with the development of skin sensitisation.
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6SDS Date: 17 Apr 2015
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ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 17 Apr 2015
Version No: 1.3
Identification of the material and supplier
Safety Data Sheet
LC-LUBE™ FINE
1 .LC-LUBE™ FINE
Powder.
CHEMTREC Emergency Telephone Numbers (Australasia Geomarket):- Australia: (02) 9037 2994- New Zealand: 9801 0034- PNG: +(61) 2 9037 2994------------------------------------ UK: +(44) 870-820-0418- USA: +(1) 703-527-3887 (CHEMTREC International 24 hour)
Product identifier
Product type
Emergency telephone number
:
:
:
Supplier's details : Baker HughesLevel 14, 216 St Georges TerracePerthWestern Australia 6000
Tel: +618 9215 0601Fax: +618 9215 0698
Product code : 5188DF
ADG : -
Identified uses : Lost Circulation Material
Hazards identification2 .Not classified.Classification of the
substance or mixture:
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
Other hazards which do not result in classification
: Handling and/or processing of this material may generate a dust which can cause mechanical irritation of the eyes, skin, nose and throat.
GHS label elements
Supplemental label elements
: Not applicable.
Precautionary statements (Code)
:
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 1/9
LC-LUBE™ Fine
Composition/information on ingredients3 .
Natural graphite 60 - 100 7782-42-5
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
CAS number : 7782-42-5
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Substance
% (w/w)
First aid measures4 .
Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.Get medical attention if symptoms occur.
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes.
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation respiratory tract irritation,coughing
No specific data.
No specific data.
:
:
:
Eye contact : irritation,redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 2/9
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Firefighting measures5 .
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
carbon dioxide,carbon monoxide
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Hazchem code : -
Accidental release measures6 .
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labelled waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing dust. Put on appropriate personal protective equipment.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Handling and storage7 .
Advice on general occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid breathing dust.
:
Precautions for safe handling
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 3/9
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Handling and storage7 .Conditions for safe storage,including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.
:
Exposure controls/personal protection8 .
Natural graphite Safe Work Australia (Australia, 1/2014). TWA: 3 mg/m³ 8 hours. Form: Respirable dust
Ingredient name Exposure limits
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn,unless the assessment indicates a higher degree of protection: safety glasses with side-shields. If operating conditions cause high dust concentrations to be produced,use dust goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas,vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker exposure or environmental releases.
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 4/9
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Physical and chemical properties9 .
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Solid. [Powder.]
>2000°C (>3632°F)
2.25
Not available.
0.18 kPa (1.33 mm Hg)
Insoluble in the following materials: cold water.
Odourless.Odour
pH
Grey. to Black. [Dark]Colour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: Not applicable.
Not available.
6.5 to 10.5 [Conc. (% w/w): 10% - (H2O)]
Viscosity Not available.
Not available.Odour threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
::
:
:
:
:
Appearance
Boiling point : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Not available.
Decomposition temperature : >250°C (>482°F)
Stability and reactivity10 .
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Not available.
:
:
:Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Toxicological information11 .
Acute toxicity
Conclusion/Summary : No known significant effects or critical hazards.
Carcinogenicity
Mutagenicity
Conclusion/Summary : No known significant effects or critical hazards.
Irritation/Corrosion
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Eyes : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Sensitisation
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Information on toxicological effects
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 5/9
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Toxicological information11 .Conclusion/Summary : No known significant effects or critical hazards.
Teratogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : No known significant effects or critical hazards.
Information on likely routes of exposure
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes.
:Eye contact
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation respiratory tract irritation,coughing
No specific data.
No specific data.
:
:
:
Eye contact : irritation,redness
Potential chronic health effects
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Name Category
Not available.
Aspiration hazard
Name Result
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 6/9
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Toxicological information11 .Fertility effects : No known significant effects or critical hazards.
Ecological information12 .
Other adverse effects : No known significant effects or critical hazards.
Toxicity
Persistence and degradability
Not available.
: No known significant effects or critical hazards.
Disposal considerations13 .Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Transport information14 .
- -
- -
Not regulated. - -
Not regulated.
Not regulated.
Hazchem code-
-
-
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
No.
No.
No.
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
Not regulated. - -
No. Hazchem code-
ADR/RID
International transport regulations
-
IMDG -
-IATA
-
Regulatory information
UN number Proper shipping name Transport hazard class(es)
PG* Label
ADG
PG* : Packing group
Additional information**
ADR/RID Class
ADG Class
IMDG Class
IATA Class
Regulatory information
Environmental hazards
Additional information**: A • in the Hazchem code indicates that Alcohol Resistant Foam is the preferred extinguishing medium. If not available, use the extinguishing medium indicated by the number in the Hazchem code.
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 7/9
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Regulatory information15 .
All components are listed or exempted.Australia inventory (AICS) :
Standard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
Not regulated.
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
References : National Code of Practice for the Control of Workplace Hazardous Substances.National Code of Practice for the Labelling of Workplace Substances. National Code of Practice for the Preparation of Material Safety Data Sheets. Approved Criteria for Classifying Hazardous Substances.
Other information16 .History
Date of printing
Date of issue/Date of revision
Version
Disclaimer
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References : Not available.
Key to abbreviations : ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United Nations
2
Procedure used to derive the classification
Classification Justification
Not classified.
6 September 2017.
6 September 2017
24 February 2016
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 8/9
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Other information16 .To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 6 September 2017 Date of previous issue : 24 February 2016 Version : 2 9/9
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) CALCINED MAGNESIA • MAGNESIA • MAGOXI16 / 27 - PRODUCT CODE
DRILLING FLUID ADDITIVE • PH INDICATORUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
MAGNESIUM OXIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
CALCIUM OXIDE <3.5%1305-78-8 215-138-9
MAGNESIUM OXIDE >94%1309-48-4 215-171-9
SILICA, AMORPHOUS <2.5%7631-86-9 231-545-4
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Page 1 of 6
SDS Date: 29 Jan 2015
MAGNESIUM OXIDEPRODUCT NAME
First aid facilities Eye wash facilities and safety shower should be available.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve magnesium oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure product is adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium oxide SWA (AUS) -- 2 -- --
Fumed silica (respirable dust) SWA (AUS) -- 2 -- --
Magnesium oxide (fume) SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
Page 2 of 6
SDS Date: 29 Jan 2015
MAGNESIUM OXIDEPRODUCT NAME
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE GRANULESAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point3600°CBoiling point2800°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density3.6 - 3.7Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information0 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6
SDS Date: 29 Jan 2015
MAGNESIUM OXIDEPRODUCT NAME
10.5 Incompatible materials
Incompatible (violently) with interhalogens (e.g. bromine pentafluoride, chlorine trifluoride) and phosphorus pentachloride. May igniteor explode when heated with aluminium powder. Also incompatible with acids (e.g. nitric acid) and dampness as material hydrates.
May evolve magnesium oxides when heated to decomposition.10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.
Skin Contact may result in irritation, redness, rash and dermatitis.
Eye Contact may result in irritation, lacrimation, pain and redness.
Sensitization This product is not classified as causing skin or respiratory sensitisation.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration Not relevant.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive This product is not classified as a reproductive toxin.
Carcinogenicity This product is not classified as a carcinogen.
Mutagenicity This product is not classified as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal For small amounts, cover with moist sand, vermiculite or similar to avoid dust hazard and dispose of to anapproved landfill site. Contact the manufacturer/supplier for additional information if disposing of largequantities (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6
SDS Date: 29 Jan 2015
MAGNESIUM OXIDEPRODUCT NAME
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6
SDS Date: 29 Jan 2015
MAGNESIUM OXIDEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:29 January 20152
Page 6 of 6
SDS Date: 29 Jan 2015
Safety Data Sheet
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: MONOETHYLENE GLYCOL
Other name(s): Ethylene glycol; MEG; 1,2-Ethanediol; 1,2-Dihydroxyethane.
Recommended Use of the Chemicaland Restrictions on Use
Coolant and antifreeze; heat transfer agent; brake fluids; solvent; humectant.
Supplier: Ixom Operations Pty Ltd
ABN: 51 600 546 512
Street Address: Level 8, 1 Nicholson StreetEast Melbourne Victoria 3002Australia
Telephone Number: +61 3 9906 3000
Emergency Telephone: 1 800 033 111 (ALL HOURS)
Please ensure you refer to the limitations of this Safety Data Sheet as set out in the "Other Information" section at the end of this Data Sheet.
2. HAZARDS IDENTIFICATION
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transportby Road and Rail; NON-DANGEROUS GOODS.
This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL.
Classification of the chemical:Acute Oral Toxicity - Category 4Specific target organ toxicity (single exposure) - Category 3Specific target organ toxicity (repeated exposure) - Category 2
SIGNAL WORD: WARNING
Product Name: MONOETHYLENE GLYCOL
Hazard Statement(s):H302 Harmful if swallowed.H335 May cause respiratory irritation.H373 May cause damage to organs through prolonged or repeated exposure.
Issued: 26/11/2018Substance No: 000030116701
Precautionary Statement(s):
Prevention:P260 Do not breathe mist, vapours, spray.P264 Wash hands thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P271 Use only outdoors or in a well-ventilated area.
Version: 5
Response:P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P312 Call a POISON CENTER or doctor/physician if you feel unwell.P314 Get medical advice/attention if you feel unwell.
Page 1 of 7
Safety Data Sheet
Storage:P403+P233 Store in a well-ventilated place. Keep container tightly closed.P405 Store locked up.
Disposal:P501 Dispose of contents and container in accordance with local, regional, national, international regulations.
Poisons Schedule (SUSMP): S6 Poison.
3. COMPOSITION AND INFORMATION ON INGREDIENTS
Components CAS Number Proportion Hazard Codes
Ethylene glycol 107-21-1 100% H302 H373
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (e.g. phone Australia 131 126; New Zealand 0800 764 766) or adoctor.
Inhalation:Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosenremaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fullyrecovered. If patient finds breathing difficult and develops a bluish discolouration of the skin (which suggests a lack ofoxygen in the blood - cyanosis), ensure airways are clear of any obstruction and have a qualified person give oxygenthrough a face mask. Apply artificial respiration if patient is not breathing. Seek immediate medical advice.
Skin Contact:If skin contact occurs, remove contaminated clothing and wash skin with running water. If irritation occurs seekmedical advice.
Eye Contact:If in eyes, wash out immediately with water. In all cases of eye contamination it is a sensible precaution to seekmedical advice.
Product Name: MONOETHYLENE GLYCOL Issued: 26/11/2018
Ingestion:Rinse mouth with water. If swallowed, do NOT induce vomiting. Never give anything by the mouth to an unconsciouspatient. Seek immediate medical assistance.
Substance No: 000030116701
Indication of immediate medical attention and special treatment needed:Treat symptomatically. Following ingestion admission to hospital should be the first priority. Gastric lavage or emesisshould be performed as soon as possible to minimise absorption and is recommended within four hours of ingestion.Gastric lavage or emesis should not be attempted unless medical expertise or adequate facilities are available.Ethanol may be given intravenously as an antidote to prevent build-up of toxic metabolites and increase excretion ofunchanged ethylene glycol by the kidneys. Uraemia, pulmonary oedema and metabolic acidosis can occur anddialysis, preferably haemodialysis, may be employed to treat these complications and to remove ethylene glycol andits metabolites from the blood. Ethylene glycol can cause central nervous system depression and metabolic acidosis.Consider removal by gastric lavage. Blockade of the diacid/hydroxyacid metabolites may follow competitive inhibitionof alcohol dehydrogenase with ethanol or 4-methyl pyrazole. Consider maintenance of a plasma ethanol level of 100mg/dL to 150 mg/dL.
Version: 5
5. FIRE FIGHTING MEASURES
Page 2 of 7
Safety Data Sheet
Suitable Extinguishing Media:Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder).
Unsuitable Extinguishing Media:Water jet.
Specific hazards arising from the chemical:Combustible liquid.
Special protective equipment and precautions for fire-fighters:On burning will emit toxic fumes, including those of oxides of carbon . Fire fighters to wear self-contained breathingapparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Heating can causeexpansion or decomposition of the material, which can lead to the containers exploding. If safe to do so, removecontainers from the path of fire. Keep containers cool with water spray.
6. ACCIDENTAL RELEASE MEASURES
Emergency procedures/Environmental precautions:Clear area of all unprotected personnel. Shut off all possible sources of ignition. If contamination of sewers orwaterways has occurred advise local emergency services.
Personal precautions/Protective equipment/Methods and materials for containment and cleaning up:Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eyecontact and breathing in vapours. Work up wind or increase ventilation. Contain - prevent run off into drains andwaterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers ordrums for disposal. Wash area down with excess water.
7. HANDLING AND STORAGE
Classified as a C2 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with therequirements of AS 1940. Refer to State Regulations for storage and transport requirements.
This material is a Scheduled Poison S6 and must be stored, maintained and used in accordance with the relevantregulations.
Product Name: MONOETHYLENE GLYCOL
Precautions for safe handling:Avoid skin and eye contact and breathing in vapour. Keep out of reach of children. When using do not eat, drink orsmoke.
Issued: 26/11/2018Substance No: 000030116701
Conditions for safe storage, including any incompatibilities:Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from sources of heat or ignition. Storeaway from foodstuffs. Store away from incompatible materials described in Section 10. Keep containers closed whennot in use - check regularly for leaks.
Version: 5
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Page 3 of 7
Ethylene glycol (vapour): 8hr TWA = 52 mg/m3 (20 ppm), 15 min STEL = 104 mg/m3 (40 ppm), SkEthylene glycol (particulate): 8hr TWA = 10 mg/m3, Sk
Safety Data Sheet
As published by Safe Work Australia Workplace Exposure Standards for Airborne Contaminants.
TWA - The time-weighted average airborne concentration of a particular substance when calculated over aneight-hour working day, for a five-day working week.
STEL (Short Term Exposure Limit) - the airborne concentration of a particular substance calculated as atime-weighted average over 15 minutes, which should not be exceeded at any time during a normal eight hour workday. According to current knowledge this concentration should neither impair the health of, nor cause unduediscomfort to, nearly all workers.
`Sk' (skin) Notice - absorption through the skin may be a significant source of exposure. The exposure standard isinvalidated if such contact should occur.
These Workplace Exposure Standards are guides to be used in the control of occupational health hazards. Allatmospheric contamination should be kept to as low a level as is workable. These workplace exposure standardsshould not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not ameasure of relative toxicity.
Appropriate engineering controls:Ensure ventilation is adequate and that air concentrations of components are controlled below quoted WorkplaceExposure Standards. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter confinedspaces where vapour may have collected. Keep containers closed when not in use.
If in the handling and application of this material, safe exposure levels could be exceeded, the use of engineeringcontrols such as local exhaust ventilation must be considered and the results documented. If achieving safe exposurelevels does not require engineering controls, then a detailed and documented risk assessment using the relevantPersonal Protective Equipment (PPE) (refer to PPE section below) as a basis must be carried out to determine theminimum PPE requirements.
Individual protection measures, such as Personal Protective Equipment (PPE):The selection of PPE is dependent on a detailed risk assessment. The risk assessment should consider the worksituation, the physical form of the chemical, the handling methods, and environmental factors.
OVERALLS, SAFETY SHOES, SAFETY GLASSES, GLOVES, RESPIRATOR.
Wear overalls, safety glasses and impervious gloves. Use with adequate ventilation. If determined by a riskassessment an inhalation risk exists, wear an organic vapour respirator meeting the requirements of AS/NZS 1715and AS/NZS 1716. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminatedclothing and other protective equipment before storage or re-use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Product Name: MONOETHYLENE GLYCOL
Physical state:
Issued: 26/11/2018
Liquid
Substance No: 000030116701
Colour: Colourless
Version: 5
Odour: Odourless
Page 4 of 7
Odour Threshold: Not available
Safety Data Sheet
Molecular Formula: CH2OHCH2OH
Solubility: Miscible in water.
Specific Gravity: 1.12 @20°C
Relative Vapour Density (air=1): 2.2
Vapour Pressure (20 °C): 0.01 kPa
Flash Point (°C): 111 (Closed cup)
Flammability Limits (%): 1.8-12.8
Autoignition Temperature (°C): 410
Boiling Point/Range (°C): 198
pH: Not available
Viscosity: 21 cP @20°C
Partition Coefficient: log Pow = -1.36
Freezing Point/Range (°C): -12
10. STABILITY AND REACTIVITY
Reactivity: Reacts with strong oxidising agents.
Chemical stability: Stable under normal conditions of use.
Possibility of hazardousreactions:
None known.
Conditions to avoid: Excessive heat will lead to accelerated oxidative degradation. Avoid exposure tohumidity.
Incompatible materials: Incompatible with strong oxidising agents, aluminium, perchloric acid.
Hazardous decompositionproducts:
Oxides of carbon.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and theproduct label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Ingestion: Initial symptoms following a large dose (>100ml) are those of alcohol intoxicationprogressing to vomiting, headache, stupor, convulsions and unconsciousness.Respiratory system involvement may occur 12 - 24 hours after ingestion.Symptoms may include hyperventilation and rapid shallow breathing. Death mayoccur from respiratory failure or pulmonary oedema.
Eye contact: A mild eye irritant.
Skin contact: Contact with skin will result in mild irritation. Will have a degreasing action on theskin. Repeated or prolonged skin contact may lead to irritant contact dermatitis.Can be absorbed through the skin. Effects can include those described for'INGESTION'.
Product Name: MONOETHYLENE GLYCOL Issued: 26/11/2018
Inhalation:
Substance No: 000030116701
Breathing in vapour will produce respiratory irritation. Breathing in vapour canresult in headaches, dizziness, drowsiness, and possible nausea.
Version: 5
Acute toxicity:Oral LD50 (rat): 4700 mg/kg
Page 5 of 7
Safety Data Sheet
Skin corrosion/irritation: Mild irritant (rabbit).
Serious eye damage/irritation: Mild irritant (rabbit).
Respiratory or skinsensitisation:
No information available.
Chronic effects: Available evidence from animal studies indicate that repeated or prolonged exposure to thismaterial could result in effects on the central nervous system, liver and kidneys .
Aspiration hazard: No information available.
Estimated minimum lethal dose (human) following ingestion of ethylene glycol is thought to be 1.4ml/kg. High dosesof ethylene glycol in rats and mice have resulted in reproductive and developmental toxicity following exposure by theoral and inhalation (respirable aerosol) routes. These particular data sets are not considered relevant to normalindustrial use but do emphasise the need for care in handling.Data from animal and human studies to date do not provide evidence that exposure to ethylene glycol has mutagenicor carcinogenic effects.
12. ECOLOGICAL INFORMATION
Ecotoxicity Avoid contaminating waterways.
Persistence/degradability: Expected to be readily biodegradable.
Bioaccumulative potential: This product shows a low bioaccumulation potential.
Mobility in soil: No information available.
96hr LC50 (fish): >10,000 mg/L (marine water); 8050 mg/L (fresh water).
13. DISPOSAL CONSIDERATIONS
Disposal methods:Refer to Waste Management Authority. Dispose of material through a licensed waste contractor. Normally suitable forincineration by an approved agent.
14. TRANSPORT INFORMATION
Road and Rail TransportNot classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transportby Road and Rail; NON-DANGEROUS GOODS.
Marine TransportNot classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)for transport by sea; NON-DANGEROUS GOODS.
Product Name: MONOETHYLENE GLYCOL
Air TransportNot classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) DangerousGoods Regulations for transport by air; NON-DANGEROUS GOODS.
Issued: 26/11/2018Substance No: 000030116701
15. REGULATORY INFORMATION
Version: 5
Classification:This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL.
Page 6 of 7
Safety Data Sheet
Classification of the chemical:Acute Oral Toxicity - Category 4Specific target organ toxicity (single exposure) - Category 3Specific target organ toxicity (repeated exposure) - Category 2
Hazard Statement(s):H302 Harmful if swallowed.H335 May cause respiratory irritation.H373 May cause damage to organs through prolonged or repeated exposure.
Poisons Schedule (SUSMP): S6 Poison.
This material is listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
Product Name: MONOETHYLENE GLYCOL Issued: 26/11/2018
Supplier Safety Data Sheet; 11/ 2018.`Registry of Toxic Effects of Chemical Substances'. Ed. D. Sweet, US Dept. of Health & Human Services: Cincinatti,2018.
Substance No: 000030116701
This safety data sheet has been prepared by Ixom Operations Pty Ltd (Toxicology & SDS Services).
Version: 5
Reason(s) for Issue:5 Yearly Revised Primary SDSChange in Handling & Storage RequirementsChange in Hazardous Chemical Classification
This SDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of thematerial and general guidance on how to safely handle the material in the workplace. Since Ixom Operations Pty Ltdcannot anticipate or control the conditions under which the product may be used, each user must, prior to usage,assess and control the risks arising from its use of the material.
If clarification or further information is needed, the user should contact their Ixom representative or Ixom OperationsPty Ltd at the contact details on page 1.
Ixom Operations Pty Ltd's responsibility for the material as sold is subject to the terms and conditions of sale, a copyof which is available upon request.
Page 7 of 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) MICRO FLOW
DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
MICROFLOWProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word WARNING
Keep away from heat/sparks/open flames/hot surfaces. No smoking.P210Keep container tightly closed.P233Ground/bond container and receiving equipment.P240Use explosion-proof electrical/ventilating/lighting equipment.P241Use only non-sparking tools.P242Take precautionary measures against static discharge.P243Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Flammable liquid and vapour.H226Causes serious eye irritation.H319May cause drowsiness or dizziness.H336
Hazard statement(s)
Pictogram(s)
Flammable Liquids: Category 3Specific Target Organ Systemic Toxicity (Single Exposure): Category 3Serious Eye Damage / Eye Irritation: Category 2A
GHS classification(s)
2.1 Classification of the substance or mixture
Page 1 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store in a well-ventilated place. Keep cool.P403 + P235Store locked up.P405
Storage statement(s)
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.P303 + P361 + P353IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Call a POISON CENTER or doctor/physician if you feel unwell.P312If eye irritation persists: Get medical advice/attention.P337 + P313In case of fire: Use appropriate media for extinction.P370 + P378
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
ISOPROPYL ALCOHOL 15 to 50%67-63-0 200-661-7
SWEET ORANGE OIL 20 to 60%68647-72-3 614-678-6
Ingredient Notes Terpenes (Sweet Orange Oil) may appear as CAS# 94266-47-4.
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities should be available.
Irritating to the eyes. Vapours may cause drowsiness and dizziness.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. Eliminate all ignition sources includingcigarettes, open flames, spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones, etc when handling. Earthcontainers when dispensing fluids.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
Page 2 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
•3Y• Alcohol Resistant Foam is the preferred firefighting medium. Else use;3 Normal Foam (protein based foam that is not alcohol resistant).Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should bebunded and have appropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Isopropyl alcohol SWA (AUS) 400 983 500 1230
8.1 Control parameters
Exposure standards
Biological limits
Ingredient Determinant BEISampling Time
ISOPROPYL ALCOHOL 40 mg/LEnd of shift atend of workweek
Acetone in urine
Reference: ACGIH Biological Exposure Indices
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilatedareas. Vapours are heavier than air and may travel some distance to an ignition source and flash back.Maintain vapour levels below the recommended exposure standard.
8.2 Exposure controls
Page 3 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear nitrile or neoprene gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties CLEAR TO OPAQUE MILKY WHITE LIQUIDAppearanceCITRUS ODOUROdourFLAMMABLEFlammability25°CFlash point154.4°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.917 - 0.977Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressure6.1 %Upper explosion limit0.7 %Lower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information55 - 75 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 4 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Acute toxicity May be harmful if swallowed. Oral Toxicity: An oral LD50 in mice of 3600 mg/kg has been reported forisopropanol.
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in irritation, rash and dermatitis.
Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness.
Sensitization This product is not classified as causing skin or respiratory sensitisation.
Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposuremay result in nausea, dizziness and drowsiness.
STOT – singleexposure
Aspiration This product is not classified as causing aspiration.
Not classified as causing organ damage from repeated exposure. However, chronic exposure to somesolvents have been reported to cause adverse effects to the central nervous system (CNS), liver and kidney.
STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Isopropyl alcohol is not classifiable as to its carcinogenicity to humans (IARC Group 3).
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Not expected to be dangerous to the aquatic environment.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
Relatively volatile and would therefore readily evaporate from dry soil and surfaces.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information if disposing of large quantities (if required).Prevent contamination of drains and waterways as aquatic life may be threatened and environmentaldamage may result.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
14. TRANSPORT INFORMATION
Page 5 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group III
3 3
III III
314.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
FLAMMABLE LIQUID, N.O.S.
1993
FLAMMABLE LIQUID, N.O.S.
1993 1993
FLAMMABLE LIQUID, N.O.S.
Not a Marine Pollutant14.5 Environmental hazards
•3YHazchem code
EMS F-E, S-E
3A1GTEPG
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R10 Flammable.R36 Irritating to eyes.R67 Vapours may cause drowsiness and dizziness.
Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S2 Keep out of reach of children.S7 Keep container tightly closed.S16 Keep away from sources of ignition - No smoking.S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Safety phrases
F FlammableXi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 6 of 7
SDS Date: 12 Jan 2015
MICROFLOWPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Standard SDS Review. 2.1
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:12 January 20152.1
Page 7 of 7
SDS Date: 12 Jan 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
NDFT 377Synonym(s)
LOST CIRCULATION MATERIALUse(s)1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
NDFT 376Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%9004-34-6 232-674-9ORGANIC FIBRE(S)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
Ingestion
None allocated.First aid facilities
SDS Date: 21 Jun 2017
Version No: 1.1ofPage 1 6
NDFT 376PRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
SDS Date: 21 Jun 2017
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NDFT 376PRODUCT NAME
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 to 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
SDS Date: 21 Jun 2017
Version No: 1.1ofPage 3 6
NDFT 376PRODUCT NAME
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.
Acute toxicity
Information available for the ingredient(s):
IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity
(LC50)
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hoursORGANIC FIBRE(S)
Not classified as a skin irritant. Skin irritation is not anticipated under normal conditions of use.Skin
Not classified as an eye irritant. Eye irritation is not anticipated under normal conditions of use.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Reuse or recycle where possible. Alternatively, ensure product is covered with moist soil to prevent dustgeneration and dispose of to an approved landfill site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 21 Jun 2017
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NDFT 376PRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
None allocated.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
None allocated.Safety phrases
None allocated.Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Classifications
16. OTHER INFORMATION
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions andwhere a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants.In the following circumstances, exposure standards must be reduced: Strenuous work conditions;hot, humid climates; high altitude conditions; extended shifts (which increase the exposure periodand shorten the period of recuperation).
COMBUSTIBLE - EXPLOSIVE CARBONACEOUS DUST: Carbonaceous/organic dusts have thepotential, with dispersion, to present an explosion hazard if an ignition source exists. All equipmentused to handle, transfer or store this product MUST BE cleaned thoroughly prior to cutting, welding,drilling or exposure to any other form of heat or ignition sources. If bulk stored, containers should beventilated on a routine basis to avoid vapour accumulation (where applicable, eg for flocculants).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 21 Jun 2017
Version No: 1.1ofPage 5 6
NDFT 376PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Prepared by
[ End of SDS ]
SDS Date: 21 Jun 2017
Version No: 1.1ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) POLY DRILL
ADDITIVE • DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
POLYDRILLProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%- -SULPHONATED ORGANIC POLYMER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
First aid facilities Eye wash facilities and safety shower should be available.
Page 1 of 6SDS Date: 02 Jun 2015
Version No: 2.2
POLYDRILLPRODUCT NAME
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
Page 2 of 6SDS Date: 02 Jun 2015
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POLYDRILLPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties RED BROWN POWDERAppearanceCHARACTERISTIC ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash point> 370°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 9 (150 g/L)pHNOT AVAILABLEVapour density1.8Specific gravity320 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:
11.1 Information on toxicological effects
Page 3 of 6SDS Date: 02 Jun 2015
Version No: 2.2
POLYDRILLPRODUCT NAME
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.
Information available for the ingredient(s):
IngredientOral Toxicity
(LD50)Dermal Toxicity
(LD50)Inhalation Toxicity
(LC50)
> 5000 mg/kg (rat) -- --SULPHONATED ORGANIC POLYMER
Skin Not classified as a skin irritant. Contact may result in mild irritation.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
No known effects from this product.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
No known effects from this product.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityThis product is not readily biodegradable.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 02 Jun 2015
Version No: 2.2
POLYDRILLPRODUCT NAME
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 5 of 6SDS Date: 02 Jun 2015
Version No: 2.2
POLYDRILLPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 02 Jun 2015
Version No: 2.2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) KCL • MURIATE OF POTASH • POTASH • SYLVITE
DRILLING FLUID ADDITIVE • FERTILISER • INHIBITORUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
POTASSIUM CHLORIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
POTASSIUM CHLORIDE >97%7447-40-7 231-211-8
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Page 1 of 6SDS Date: 16 Apr 2015
Version No: 2.1
POTASSIUM CHLORIDEPRODUCT NAME
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
Page 2 of 6SDS Date: 16 Apr 2015
Version No: 2.1
POTASSIUM CHLORIDEPRODUCT NAME
PPE
Eye / Face At high dust levels, wear dust-proof goggles.
Hands With prolonged use, wear PVC or rubber or cotton gloves.
Body With prolonged use, wear coveralls.
Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point773°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.0Specific gravity340 g/L @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible (potentially explosive) with oxidising agents (e.g. hypochlorites).
May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization will not occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity May be harmful if swallowed. Oral Toxicity: An oral LD50 in rats of 2600 mg/kg was reported for potassiumchloride. Additional toxicity data for potassium chloride:LD50 (Intraperitoneal): 620 mg/kg (mouse)LD50 (Intravenous): 117 mg/kg (mouse)LDLo (Ingestion): 20 mg/kg (man)
11.1 Information on toxicological effects
Page 3 of 6SDS Date: 16 Apr 2015
Version No: 2.1
POTASSIUM CHLORIDEPRODUCT NAME
LDLo (Intraperitoneal): 900 mg/kg (guinea pig)LDLo (Intravenous): 77 mg/kg (guinea pig)LDLo (Subcutaneous): 2120 mg/kg (frog)TDLo (Ingestion): 60 mg/kg/days (woman)
Skin Not classified as a skin irritant. Contact may result in mild irritation and rash.
Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, andpotassium is rapidly excreted by the body, however this product does have the potential to causecardiovascular disorders.
STOT – singleexposure
Aspiration Not relevant.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictaluruspunctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronicreproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronicaquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerationsthe background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for furtherinvestigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulationpotential for the substance.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No impact if small amount is released to the soil.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialDoes not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 16 Apr 2015
Version No: 2.1
POTASSIUM CHLORIDEPRODUCT NAME
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6SDS Date: 16 Apr 2015
Version No: 2.1
POTASSIUM CHLORIDEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 16 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) QUICKSEAL
DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
QUICKSEAL (F,M,C)Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
CELLULOSE 100%9004-34-6 232-674-9
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
Page 1 of 6
SDS Date: 13 Feb 2015
QUICKSEAL (F,M,C)PRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.Difficult to extinguish once burning.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach ofchildren.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
Page 2 of 6
SDS Date: 13 Feb 2015
QUICKSEAL (F,M,C)PRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties YELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 - 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrateand sodium nitrite.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6
SDS Date: 13 Feb 2015
QUICKSEAL (F,M,C)PRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats).Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats).Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat).
Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.
Eye Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness andlacrimation.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Low toxicity to aquatic organisms.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Reuse where possible. No special precautions are normally required when handling this product.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6
SDS Date: 13 Feb 2015
QUICKSEAL (F,M,C)PRODUCT NAME
None AllocatedHazchem code
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 5 of 6
SDS Date: 13 Feb 2015
QUICKSEAL (F,M,C)PRODUCT NAME
DescriptionRevision
Standard SDS Review. 2.3
Standard SDS Review. 2.2
Provided Ingredient CAS No. 2.1
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:13 February 20152.3
Page 6 of 6
SDS Date: 13 Feb 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) FLOSSY SALT • HALITE • NACL • SODIUM CHLORIDE
CHLORIDE SOURCE • DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SALTProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
SODIUM CHLORIDE >98%7647-14-5 231-598-3
INORGANIC SALT(S) <0.8%- -
WATER <0.8%7732-18-5 231-791-2
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Page 1 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SALTPRODUCT NAME
First aid facilities No information provided.
Under normal conditions of use, adverse health effects are not anticipated. This product is generally considered to be of low toxicity.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate fire protection systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Page 2 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SALTPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties TRANSLUCENT TO WHITE GRANULES OR POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point801°CMelting pointNOT AVAILABLEEvaporation rate7 (1% Solution)pHNOT AVAILABLEVapour density2.163Specific gravity357 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).
May evolve toxic gases when strongly heated.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
Page 3 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SALTPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Skin): > 10000 mg/kg (rabbit)
Skin Not classified as a skin irritant. Contact may result in mild irritation and rash.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
LC50 (water flea) is 2122 mg/L/48 hours;LC50 (fathead minnow) is 6.57 g/L/96 hours.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SALTPRODUCT NAME
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 5 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SALTPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 17 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) DISODIUM DIHYDROGEN PYROPHOSPHATE • DISODIUM PYROPHOSPHATE
ACIDIFIER • BUFFERING AGENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SAPPProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
DISODIUM PYROPHOSPHATE 100%7758-16-9 231-835-0
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
First aid facilities Eye wash facilities and safety shower should be available.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
Page 1 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SAPPPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (phosphorus oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Nuisance dust SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
Page 2 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SAPPPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point> 600°CMelting pointNOT AVAILABLEEvaporation rate4 - 5 (10% Solution)pHNOT AVAILABLEVapour density1.35 - 1.41Specific gravity119 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (phosphorus oxides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Page 3 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SAPPPRODUCT NAME
Acute toxicity Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.Ingestion of large quantities may also result in serious disturbances in calcium metabolism.
LD50 (Ingestion): 2650 mg/kg (mouse)LD50 (Intraperitoneal): 1 g/kg (mouse)LD50 (Intravenous): 59 mg/kg (mouse)LD50 (Subcutaneous): 480 mg/kg (mouse)
Skin Low to moderate irritant. Prolonged or repeated contact may result in irritation and rash.
Eye Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization Not classified as causing skin or respiratory sensitisation.
Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive This product is not classified as a reproductive toxin.
Carcinogenicity This product is not classified as a carcinogen.
Mutagenicity This product is not classified as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialDoes not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
Page 4 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SAPPPRODUCT NAME
None AllocatedHazchem code
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 5 of 6SDS Date: 17 Apr 2015
Version No: 2.1
SAPPPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 17 Apr 2015
Version No: 2.1
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) SODA ASH DENSE • SODIUM CARBONATE
DRILLING AIDUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SODA ASHProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word WARNING
No information provided.2.3 Other hazards
Disposal statement(s)None allocated.
Storage statement(s)None allocated.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
If eye irritation persists: Get medical advice/attention.P337 + P313
Response statement(s)
Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes serious eye irritation.H319Hazard statement(s)
Pictogram(s)
Serious Eye Damage / Eye Irritation: Category 2AGHS classification(s)
2.1 Classification of the substance or mixture
Page 1 of 6
SDS Date: 29 Jan 2015
SODA ASHPRODUCT NAME
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
SODIUM CARBONATE >97%497-19-8 207-838-8
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities should be available.
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
Page 2 of 6
SDS Date: 29 Jan 2015
SODA ASHPRODUCT NAME
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.533Specific gravity170 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
Page 3 of 6
SDS Date: 29 Jan 2015
SODA ASHPRODUCT NAME
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity No known toxicological effects from this product. Based on available data, the classification criteria are notmet. Acute Oral Toxicity: 4090 mg/kg (rat).Acute Inhalation Toxicity: 800 mg/m3/2 hours (guinea pig).
Skin Contact may result in irritation, redness, rash and dermatitis.
Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns withprolonged contact.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure. However, over exposure may result in irritationof the nose and throat, with coughing.
STOT – singleexposure
Aspiration Not relevant.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive This product is not classified as a reproductive toxin.
Carcinogenicity This product is not classified as a carcinogen.
Mutagenicity This product is not classified as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Page 4 of 6
SDS Date: 29 Jan 2015
SODA ASHPRODUCT NAME
Waste disposal Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R36 Irritating to eyes.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S22 Do not breathe dust.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Safety phrases
Xi IrritantHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6
SDS Date: 29 Jan 2015
SODA ASHPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:29 January 20152
Page 6 of 6
SDS Date: 29 Jan 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) BAKING SODA • BICARBONATE OF SODA • CARBONIC ACID, MONOSODIUM SALT • MONOSODIUMCARBONATE • SODIUM ACID CARBONATE • SODIUM HYDROGEN CARBONATE
PH CONTROLUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SODIUM BICARBONATEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
SODIUM BICARBONATE >99%144-55-8 205-633-8
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).
First aid facilities Eye wash facilities should be available. Eye wash facilities and safety shower are recommended.
No adverse health effects expected if the product is handled in accordance with the SDS and the product label.4.2 Most important symptoms and effects, both acute and delayed
Page 1 of 6
SDS Date: 06 Jan 2015
SODIUM BICARBONATEPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packages are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Bicarbonate (total dust) SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
Page 2 of 6
SDS Date: 06 Jan 2015
SODIUM BICARBONATEPRODUCT NAME
PPE
Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rate8 (1% Solution)pHNOT AVAILABLEVapour density2.533Specific gravity170 g/L @ 25°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. Sodium bicarbonate can neutralise the gastric juices in the stomach. During neutralisation,carbon dioxide gas is evolved and may cause stretching of the stomach, and with very large doses possibledamage or rupture.
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.
11.1 Information on toxicological effects
Page 3 of 6
SDS Date: 06 Jan 2015
SODIUM BICARBONATEPRODUCT NAME
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration Not relevant.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive This product is not classified as a reproductive toxin.
Carcinogenicity This product is not classified as a carcinogen.
Mutagenicity This product is not classified as a mutagen.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Notexpected to bioaccumulate.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Page 4 of 6
SDS Date: 06 Jan 2015
SODIUM BICARBONATEPRODUCT NAME
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
Additional information
Page 5 of 6
SDS Date: 06 Jan 2015
SODIUM BICARBONATEPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:06 January 20152
Page 6 of 6
SDS Date: 06 Jan 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) SODIUM SULFITE
ANTIOXIDANT • FOOD PRESERVATIVE • LABORATORY REAGENT • PAPER INDUSTRY •PHOTOGRAPHIC DEVELOPER • REDUCING AGENT • WATER TREATMENT
Use(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SODIUM SULPHITEProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word DANGER
Storage statement(s)None allocated.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310Rinse mouth.P330
Response statement(s)
Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Harmful if swallowed.H302Causes serious eye damage.H318Contact with acids liberates toxic gasAUH031
Hazard statement(s)
Pictogram(s)
Acute Toxicity: Oral: Category 4Serious Eye Damage / Eye Irritation: Category 1
GHS classification(s)
2.1 Classification of the substance or mixture
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SODIUM SULPHITEPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>97%7757-83-7 231-821-4SODIUM SULPHITE
<2.5%7757-82-6 231-820-9SODIUM SULPHATE
<0.1%497-19-8 207-838-8SODIUM CARBONATE
<0.1%7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgenthospital treatment is likely to be needed. If swallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower are recommended.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
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SODIUM SULPHITEPRODUCT NAME
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aFull-face Class P3 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE CRYSTALLINE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5pHNOT AVAILABLEVapour density2.6Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limit
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SODIUM SULPHITEPRODUCT NAME
9.1 Information on basic physical and chemical properties NOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources. Sensitive to air and moisture.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (sulphur oxides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityContact with acids liberates toxic gas.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:Harmful if swallowed.
Information available for the ingredient(s):
IngredientOral Toxicity
(LD50)Dermal Toxicity
(LD50)Inhalation Toxicity
(LC50)
820 mg/kg (mouse) -- --SODIUM SULPHITE
5989 mg/kg (mouse) -- --SODIUM SULPHATE
4090 mg/kg (rat) > 2000 mg/kg (rabbit) 800 mg/m³/2 hoursSODIUM CARBONATE
Skin Not classified as a skin irritant. Contact may result in mild irritation, redness, rash and dermatitis.
Eye Causes serious eye damage. Contact may result in irritation, lacrimation, pain and redness.
Additional ingredient toxicity value(s):
SODIUM SULPHITE (7757-83-7)LD50 (intraperitoneal) 950 mg/kg (mouse)LD50 (intravenous) 175 mg/kg (mouse)LDLo (intravenous) 400 mg/kg (cat)LDLo (oral) 2825 mg/kg (rabbit)LDLo (subcutaneous) 600 mg/kg (rabbit)
SODIUM SULPHATE (7757-82-6)LD50 (intravenous) 1220 mg/kg (rabbit)LDLo (intravenous) 1220 mg/kg (mouse)TDLo (oral) 14 g/kg (mouse - 8-12 days pregnant)TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)
SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)
11.1 Information on toxicological effects
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SODIUM SULPHITEPRODUCT NAME
Sensitisation Not classified as causing skin or respiratory sensitisation. Some individuals are hypersensitive to sulphites,and may experience asthma like symptoms (wheezing and shortness of breath) immediately followingexposure.
Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing.STOT – singleexposure
Aspiration Not classified as causing aspiration.
Not classified as causing organ damage from repeated exposure.STOT – repeatedexposure
Reproductive Not classified as a reproductive toxin.
Carcinogenicity Not classified as a carcinogen.
Mutagenicity Not classified as a mutagen.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait untilreaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite(reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorb withsand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewer withlarge excess of water.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 TransportHazard Class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
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SODIUM SULPHITEPRODUCT NAME
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R22 Harmful if swallowed.R31 Contact with acids liberates toxic gas.R41 Risk of serious damage to eyes.
Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S25 Avoid contact with eyes.S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container
or label.
Safety phrases
T ToxicXi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for ahazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure.The best protection is to enclose operations and/or provide local exhaust ventilation at the site ofchemical release. Isolating operations can also reduce exposure. Using respirators or protectiveequipment is less effective than the controls mentioned above, but is sometimes necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a report whichwould encompass all possible scenarios, it is anticipated that users will assess the risks and applycontrol methods where appropriate.
Additional information
Page 6 of 7SDS Date: 04 Aug 2016
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SODIUM SULPHITEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 7 of 7SDS Date: 04 Aug 2016
Version No: 2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) SODIUM POLYACRYLATE
DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SPAProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%- -ACRYLATE - ACRYLAMIDE COPOLYMER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities Eye wash facilities and safety shower should be available.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
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SPAPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.As with many solids, any dust that is generated may be explosive if mixed with air in critical proportions and in the presence of asource of ignition.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Acrylamide SWA (AUS) -- 0.03 -- --
8.1 Control parameters
Exposure standards
No Biological Limit Value allocated.Biological limits
Page 2 of 6SDS Date: 02 Jun 2015
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SPAPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties CREAM GRANULAR SOLIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.8Specific gravity10 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information5 - 10 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation, rash anddermatitis.
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure.STOT – singleexposure
Aspiration This product is not classified as causing aspiration.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Insufficient data available to classify as a carcinogen. This product may contain trace amounts of residualacrylamide, which is classified as a probable human carcinogen (IARC Group 2A). However, due to the verylow levels present, adverse health effects are not anticipated with normal use.
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
(10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis Bahia = 48HR LC50 = 16.2 mg/L. Menidia Beryllina = 48hr LC50 =34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia Costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L]Acartia Tonsa = 48hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
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No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
ACRYLIC - ACRYLAMIDE RESINS: These resins are generally of low toxicity. Toxicity increases withpresence of significant concentrations of acrylic - acrylamide monomers. These monomers havebeen linked with the development of skin sensitisation.
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6SDS Date: 02 Jun 2015
Version No: 2.2
SPAPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 6 of 6SDS Date: 02 Jun 2015
Version No: 2.2
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) STRATA VANGUARD
DRILLING FLUID ADDITIVEUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
STRATA-VANGUARDProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
CRISTOBALITE <5%14464-46-1 238-455-4
QUARTZ (CRYSTALLINE SILICA) <2%14808-60-7 238-878-4
2-PROPENENITRILE-1,3-BUTADIENE RUBBER <50%9003-18-3 618-357-1
NATURAL RUBBER <50%9006-04-6 232-689-0
POLYISOPRENE <50%9003-31-0 618-362-9
SBR ELASTOMERS <50%9003-55-8 618-370-2
CELLULOSE <30%9004-34-6 232-674-9
DIATOMACEOUS EARTH, FLUX CALCINED <15%68855-54-9 272-489-0
FULLERS EARTH <10%8031-18-3 617-052-0
LIMESTONE (CALCIUM CARBONATE) <10%1317-65-3 215-279-6
POLYETHYLENE <3%9002-88-4 618-339-3
MAGNESIUM OXIDE <1%1309-48-4 215-171-9
3.1 Substances / Mixtures
Page 1 of 6
SDS Date: 06 Jan 2015
STRATA-VANGUARDPRODUCT NAME
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
No fire or explosion hazard exists.5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
Page 2 of 6
SDS Date: 06 Jan 2015
STRATA-VANGUARDPRODUCT NAME
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- --
Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --
Cristobalite SWA (AUS) -- 0.1 -- --
Magnesium oxide (fume) SWA (AUS) -- 10 -- --
Quartz (respirable dust) SWA (AUS) -- 0.1 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aPowered Air Purifying Respirator (PAPR) with Class P3 (Particulate) filter or a Full-face Class P3(Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties TAN COLOURED POWDERAppearanceMILD ODOUROdourNON FLAMMABLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate6.3 (5% Suspension)pHNOT AVAILABLEVapour density2.1Specific gravityINSOLUBLESolubility (water)1 mm Hg @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
Page 3 of 6
SDS Date: 06 Jan 2015
STRATA-VANGUARDPRODUCT NAME
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid contact with incompatible substances.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid). Also incompatible with oxygen difluoride, chlorine and trifluoride.
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity No known toxicological effects from this product. Based on available data, the classification criteria are notmet.
Skin Not classified as a skin irritant. Contact may result in mechanical irritation.
Eye Not classified as an eye irritant. Contact may result in mechanical irritation.
Sensitization This product is not known to be a skin or respiratory sensitiser.
No known effects from this product.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
Adverse health effects associated with silica, such as the development of silicosis (lung fibrosis), is notanticipated unless chronic (i.e. prolonged and repeated) exposure to silica quartz dust occurs.
STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is insufficientrespirable silica in this product to be classified as a carcinogen.
Mutagenicity No evidence of mutagenic effects.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradabilityNot applicable.
12.4 Mobility in soil
This product has low mobility in soil.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Page 4 of 6
SDS Date: 06 Jan 2015
STRATA-VANGUARDPRODUCT NAME
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
Additional information
Page 5 of 6
SDS Date: 06 Jan 2015
STRATA-VANGUARDPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Standard SDS Review. 1.3
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:06 January 20152
Page 6 of 6
SDS Date: 06 Jan 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) RHEOCHEM TRIETHANOLAMINE
CHEMICAL INTERMEDIATE • LABORATORY REAGENT • SOLVENTUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
TRIETHANOLAMINEProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
Signal word DANGER
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Storage statement(s)None allocated.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTRE or doctor/physician.P310Get medical advice/attention if you feel unwell.P314
Response statement(s)
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes serious eye damage.H318May cause damage to organs through prolonged or repeated exposure.H373
Hazard statement(s)
Pictograms
Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
GHS classification
2.1 Classification of the substance or mixture
Page 1 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
No information provided.2.3 Other hazards
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient Identification Classification Content GHS Risk
TRIETHANOLAMINE CAS: 102-71-6EC: 203-049-8
>60%Not Available Not Available
DIETHANOLAMINE CAS: 111-42-2EC: 203-868-0
10 to <30%Acute Tox. 4, H302Skin Irrit. 2, H315Eye Dam. 1, H318STOT RE 2, H373
Xn;R22, Xi;R38,Xi;R41, Xn;R48/22
ETHANOLAMINE CAS: 141-43-5EC: 205-483-3
<10%Acute Tox. 4, H302Acute Tox. 4, H312Skin Corr. 1B, H314Acute Tox. 4, H332
Xn;R20/21/22,C;R34
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink.
First aid facilities No information provided.
Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area wherepossible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Page 2 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Store as a Class C2 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Diethanolamine (h) SWA (AUS) 3 13 -- --
Ethanolamine SWA (AUS) 3 7.5 6 15
Triethanolamine SWA (AUS) -- 5 -- --
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body Wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties CLEAR LIQUIDAppearanceMILD AMMONIACAL ODOUROdourCLASS C2 COMBUSTIBLEFlammability190°CFlash point
Page 3 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
9.1 Information on basic physical and chemical properties 335°CBoiling point12°CMelting point< 0.01 (n-Butyl acetate = 1)Evaporation rate10.5 (1 % Solution)pH4.80 (Air = 1)Vapour density1.12Specific gravitySOLUBLESolubility (water)< 1 kPa @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient375°CAutoignition temperatureNOT AVAILABLEDecomposition temperature450 cP @ 25°CViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Also incompatible withorganic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper, brassand aluminium.
May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Hazardous polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. LD50 (oral) = 2200 mg/kg (rabbit).
Skin Contact may result in mild irritation, redness, pain and rash.
Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact.
Sensitization Triethanolamine has been reported to cause allergic contact dermatitis in humans. It is not known to causerespiratory sensitisation.
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.
STOT – singleexposure
Aspiration This product is not expected to present an aspiration hazard.
Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3).
Mutagenicity Insufficient data available to classify as a mutagen.
11.1 Information on toxicological effects
Page 4 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityThe substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil,residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid.Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of toapproved landfill site. Contact the manufacturer for additional information.
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R41 Risk of serious damage to eyes.R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Risk phrases
S25 Avoid contact with eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS39 Wear eye/face protection.
Safety phrases
Xi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 5 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
DescriptionRevision
Converted to GHS. 2.0
Initial SDS creation 1.0
Revision history
Additional information
Page 6 of 7
SDS Date: 25 Jul 2014
TRIETHANOLAMINEPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:25 July 20142
Page 7 of 7
SDS Date: 25 Jul 2014
TrueScavÔ HD
EN
SAFETY DATA SHEET
Issue Date 29-Aug-2018 Revision Date 29-Aug-2018 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name TrueScavÔ HD
Product Code NDF00394
Other means of identification
Recommended use of the chemical and restrictions on use
Recommended Use oxygen scavenger
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Other hazards General HazardsNo information available
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UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
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NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Chemical Name CAS No Weight-%
Sodium Erythorbate 6381-77-7 >99
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment.
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
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NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Strong oxidizing agents
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
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NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Solid
Other Information Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Density No information available
Bulk density No information available
Particle Size No information available
Particle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity Stable under normal conditions.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Appearance powder Odor No information available.
Color white Odor threshold No information available
Property Values Remarks • Method pH 5 - 8
Melting point / freezing point 160 °C
Boiling point / boiling range No information available
Flash point No information available
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air No information available
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor pressure No data available
Vapor density No data available
Relative density 1.2-1.7
Water solubility Soluble in water
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity Not applicable
Dynamic viscosity Not applicable
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UGHS Page 4 / 8
_____________________________________________________________________________________________
NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials Strong oxidizing agents.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 5,005.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Sodium Erythorbate > 5 g/kg ( Rat ) - -
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation None known.
Serious eye damage/eye irritation None known.
Respiratory or skin sensitization None known.
Germ cell mutagenicity None known.
Carcinogenicity None known.
Reproductive toxicity None known.
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NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
STOT - single exposure None known.
STOT - repeated exposure None known.
Aspiration hazard Not applicable.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
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_____________________________________________________________________________________________
NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
NZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 29-Aug-2018
Revision Date 29-Aug-2018
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Disclaimer
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
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_____________________________________________________________________________________________
NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
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UGHS Page 8 / 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) NEWZAN D • XANTHAN GUM (BIOPOLYMER)
DRILLING FLUID ADDITIVE • VISCOSITY MODIFIERUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
XANTHAN GUM (P)Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
XANTHAN GUM >87%11138-66-2 234-394-2
WATER <13%7732-18-5 231-791-2
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
First aid facilities Eye wash facilities and safety shower should be available.
Page 1 of 6
SDS Date: 10 Feb 2015
XANTHAN GUM (P)PRODUCT NAME
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No exposure standards have been entered for this product.
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls
Page 2 of 6
SDS Date: 10 Feb 2015
XANTHAN GUM (P)PRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate)respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties LIGHT BEIGE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.5Specific gravityMISCIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Page 3 of 6
SDS Date: 10 Feb 2015
XANTHAN GUM (P)PRODUCT NAME
Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.
Skin Not classified as a skin irritant. Contact may result in mild irritation.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
No known effects from this product.STOT – singleexposure
Aspiration This product does not present an aspiration hazard.
No known effects from this product.STOT – repeatedexposure
Reproductive No evidence of reproductive effects.
Carcinogenicity No evidence of carcinogenic effects.
Mutagenicity No evidence of mutagenic effects.
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group None Allocated
None Allocated None Allocated
None Allocated None Allocated
None Allocated14.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
None Allocated
None Allocated
None Allocated
None Allocated None Allocated
None Allocated
No information provided14.5 Environmental hazards
None AllocatedHazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Page 4 of 6
SDS Date: 10 Feb 2015
XANTHAN GUM (P)PRODUCT NAME
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Risk phrases None allocated.
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
Safety phrases None allocated.
Hazard codes None allocated.
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
Page 5 of 6
SDS Date: 10 Feb 2015
XANTHAN GUM (P)PRODUCT NAME
DescriptionRevision
Added Synonym. 1.3
Standard SDS Review 1.2
Standard SDS Review 1.1
Initial SDS creation 1.0
Revision history
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
SDS date:
[ End of SDS ]
Revision:10 February 20151.3
Page 6 of 6
SDS Date: 10 Feb 2015
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Synonym(s) ZINC WHITE
SCAVENGERUse(s)
1.2 Uses and uses advised against
1.3 Details of the supplier of the product
Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD
Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA
Telephone +61 8 9410 8200
Fax +61 8 9410 8299
1800 127 406 (Australia); +64 3 3530199 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
ZINC OXIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS
2.2 Label elements
Signal word WARNING
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Storage statement(s)None allocated.
Collect spillage.P391Response statement(s)
Avoid release to the environment.P273Prevention statement(s)
Very toxic to aquatic life with long lasting effects.H410Hazard statement(s)
Pictogram(s)
Aquatic Toxicity (Chronic): Category 1GHS classification(s)
2.1 Classification of the substance or mixture
Page 1 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>99%1314-13-2 215-222-5ZINC OXIDE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
First aid facilities No information provided.
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve zinc oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipmentincluding Self Contained Breathing Apparatus (SCBA) when combating fire.
5.3 Advice for firefighters
2Z2 Fine Water Spray.Z Wear full fire kit and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
Page 2 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Zinc oxide (dust) SWA (AUS) -- 10 -- --
Zinc oxide (fume) SWA (AUS) -- 5 -- 10
8.1 Control parameters
Exposure standards
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties WHITE TO YELLOW-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point1975°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information
Page 3 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
9.2 Other informationNOT AVAILABLE% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with metals if heated and with acids (e.g. nitric acid).
May evolve zinc oxides when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Information available for the product:This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.
Information available for the ingredient(s):
IngredientOral Toxicity
(LD50)Dermal Toxicity
(LD50)Inhalation Toxicity
(LC50)
7950 mg/kg (mouse) -- 2500 mg/m³ (mouse)ZINC OXIDE
Skin Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.
Eye Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.
Sensitization This product is not known to be a skin or respiratory sensitiser.
Not classified as causing organ effects from single exposure. Inhalation of freshly formed zinc oxide fumesmay result in the development of a flu-like illness termed metal fume fever.
STOT – singleexposure
Aspiration Not relevant.
Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure
Reproductive Insufficient data available to classify as a reproductive toxin.
Carcinogenicity Insufficient data available to classify as a carcinogen.
Mutagenicity Insufficient data available to classify as a mutagen.
Additional ingredient toxicity value(s):
ZINC OXIDE (1314-13-2)LD50 (intraperitoneal) 240 mg/kg (rat)LDLo (oral) 500 mg/kg (human)TCLo (inhalation) 600 mg/m³ (human)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
12.2 Persistence and degradabilityThis product is not readily biodegradable.
Page 4 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Legislation Dispose of in accordance with relevant local legislation.
LAND TRANSPORT(ADG)
SEA TRANSPORT(IMDG / IMO)
AIR TRANSPORT(IATA / ICAO)
14.4 Packing Group III
9 9
III III
914.3 Transporthazard class
14.1 UN Number
14.2 ProperShipping Name
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
3077
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
3077 3077
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Marine Pollutant14.5 Environmental hazards
2ZHazchem code
EMS F-A, S-F
9C1GTEPG
14.6 Special precautions for user
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
14. TRANSPORT INFORMATION
15. REGULATORY INFORMATION
Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
Risk phrases
S60 This material and its container must be disposed of as hazardous waste.S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Safety phrases
N Dangerous for the environmentHazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Page 5 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Additional information
Page 6 of 7SDS Date: 02 Jun 2015
Version No: 2.2
ZINC OXIDEPRODUCT NAME
Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.
[ End of SDS ]
Page 7 of 7SDS Date: 02 Jun 2015
Version No: 2.2
Safety Data SheetAntifoam Agent D47
SDS no. D047
Version 2
Revision date 04/Feb/2016
Supersedes date 21/Feb/2014
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Antifoam Agent D47
Product code D047
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Antifoam in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
________________________________________________________________________________________
2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
3.2 Mixtures
Not Applicable
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
________________________________________________________________________________________
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
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Inhalation Please see Section 11. Toxicological Information for further information.
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which shall not be used for safety reasonsDo not use water jet.
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsWhen heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
________________________________________________________________________________________
Environmental exposure controlsAvoid release to the environment.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
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Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromopen flames, hot surfaces and sources of ignition. Store away from incompatibles, Strongoxidizing agents
Storage class Chemical storage.
Packaging material Use specially constructed containers only.
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
________________________________________________________________________________________
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________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Safety glasses with side-shields.
Hand protection Wear chemical resistant gloves such as nitrile or neoprene, Be aware that liquid maypenetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Suitable mask with particle filter P3(European Norm 143), At work in confined or poorly ventilated spaces, respiratoryprotection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash andemergency shower must be available at the work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Viscous
Odor No information available
Color Colorless
Odor threshold Not applicable
Physical state Liquid
Property Values Remarks pH No information available
pH @ dilution
Melting/freezing point < -35 °C / - 31 °F
Boiling point/range No information available
Flash point 229 °C / 444 °F PMCC ASTM D-93
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not Applicable
Flammability Limits in Air Not applicable
Upper flammability limit No information available
________________________________________________________________________________________
Lower flammability limit No information available
Vapor pressure No information available
Vapor density
Page 5 / 10
No information available
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
Explosive properties Not Applicable
Oxidizing properties None known.
9.2 Other information Pour point <0°C / 32 °F
Molecular weight No information available
VOC content(%) None
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep away from open flames, hot surfaces and sources of ignition.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Specific gravity No information available
Bulk density No information available
Relative density 1 @ 21.1°C.
Water solubility Insoluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
________________________________________________________________________________________
Kinematic viscosity 414-496 cst
Dynamic viscosity No information available
Log Pow
Page 6 / 10
Not determined
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure None known.
Routes of entry No route of entry noted.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
________________________________________________________________________________________
12.2 Persistence and degradability
Readily biodegradable.
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12.3 Bioaccumulative potential
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
Bioaccumulation is unlikely.
12.4 Mobility in soil
MobilityThe product is insoluble and floats on water.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 16 03 06 - organic wastes other than those mentioned in 16 03 05
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
________________________________________________________________________________________
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
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________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
14.5 Environmental hazard No
14.6 Special precautions Not Applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Germany, Water EndangeringClasses (VwVwS)
Hazardous to water/Class 1
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo Poison Schedule number allocated.
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.
International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
________________________________________________________________________________________
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
Page 9 / 10
New Zealand (NZIoC) Complies
________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047
Revision date 04/Feb/2016
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Nicola Anderson
Supersedes date 21/Feb/2014
Revision date 04/Feb/2016
Version 2
The following sections have beenrevised:
Updated according to GHS/CLP, No changes with regard to classification have been made.
________________________________________________________________________________________
Full text of H-Statements referred to under sections 2 and 3
This product is not classified as hazardous therefore no (H) hazard statements assigned.
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
Page 10 / 10
SDS no. D175A
Version 3
Revision date 19-Jun-2015
Supersedes date 19-May-2008
Safety Data SheetAntifoam Agent D175A
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Antifoam Agent D175A
Product code D175A
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
Norway Poison information centre: +47 22 59 13 00
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
________________________________________________________________________________________
Page 1 / 11
________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Precautionary Statements - EU (§28, 1272/2008) This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
ContainsNon-crystalline silica
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
Component EC-No. CAS-No Weight % -range
Classification(67/548)
Classification (Reg.1272/2008)
REACHregistration
numberNon-crystalline silica Listed Proprietary 1 - 5 Not classified 01-2119379499-16-x
xxx
CommentsNo classified ingredients, or those having occupational exposure limits, present above the level of disclosure.The product contains other ingredients which do not contribute to the overall classification.
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Getmedical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
________________________________________________________________________________________
Page 2 / 11
________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaExtinguish with carbon dioxide, dry chemical, foam or waterspray.
Extinguishing media which shall not be used for safety reasonsDo not use water jet.
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and materials for containment and cleaning up
________________________________________________________________________________________
Page 3 / 11
________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromopen flames, hot surfaces and sources of ignition. Keep at a temperature not exceeding 25°C Store away from incompatibles, Strong oxidizing agents UV or Ionising Radiation. Steel.
Storage class Chemical storage.
Packaging material Use specially constructed containers only.
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits Because this product is a liquid, the dust-related Workplace Exposure Limits for thecomponents do not apply.
Component EU OEL Austria Australia Denmark
Non-crystalline silica Not determined 4 mg/m3 TWA inhalablefraction
2mg/m3TWArespirabledust
Not determined
Component Malaysia France Germany Hungary
________________________________________________________________________________________
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Non-crystalline silica Not determined Not determined 4 mg/m3 TWA Not determined
Component New Zealand Italy Netherlands Norway
Non-crystalline silica Not Determined Not determined Not determined 1.5 mg/m3 TWArespirable dust
1.5 mg/m3 STELrespirable dust
Component Poland Portugal Romania Russia
Non-crystalline silica Not determined Not determined Not determined Not determined
Component Spain Switzerland Turkey UK
Non-crystalline silica Not determined 4 mg/m3 MAK0.3 mg/m3 MAK
Not determined 18 mg/m3 STELcalculated inhalable
dust7.2 mg/m3 STEL
calculated respirabledust
6 mg/m3 TWA inhalabledust
2.4 mg/m3 TWArespirable dust
Derived No Effect Level (DNEL)
Long term exposure systemic effects
Non-crystalline silica
Inhalation 4 mg/m³
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Safety glasses with side-shields.
Hand protection Use protective gloves made of:, polyvinyl alcohol or nitrile-butyl rubber gloves, Be awarethat liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Respirator with combination filter forvapor/particulate, Type A/P2, At work in confined or poorly ventilated spaces, respiratoryprotection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.
Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothingbefore re-use.
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solution
Odor Slight
Color Milky white.
Odor threshold Not applicable
Explosive properties Not Applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Physical state Liquid
Property Values Remarks pH ~ 5
pH @ dilutionMelting/freezing point ~ 0 °C / 32 °F
Boiling point/range 100 °C / 212 °F
Flash point Not Applicable
Evaporation rate (BuAc =1)Flammability (solid, gas) Not Applicable
Flammability Limits in AirUpper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure 2.3 kPa @ 20 °C
Vapor density No information available
Specific gravity ~ 1 @ 25 °C
Bulk density No information available
Relative density No information available
Water solubility Dispersible
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosityDynamic viscosity ~ 100 mPa s @ 25 °C
Log Pow No information available
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid heat, flames and other sources of ignition.
10.5 Incompatible materials
Strong oxidizing agents. UV or Ionising Radiation. Steel.
10.6 Hazardous decomposition products
See also section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
Component LD50 Oral LD50 Dermal LC50 Inhalation
Non-crystalline silica > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure None known.
Routes of entry No route of entry noted.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Component Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Non-crystalline silica = 5000 mg/L LC50 Brachydaniorerio 96 h
= 440 mg/L EC50Pseudokirchneriella subcapitata 72
h
= 7600 mg/L EC50 Ceriodaphniadubia 48 h
12.2 Persistence and degradability
The product is not expected to be biodegradable.
12.3 Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
12.4 Mobility in soil
MobilityDispersible in water.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 07 02 17 – Waste containing silicones other than those mentioned in 0702 16
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not Applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo Poisons Schedule number allocated
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Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.
International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Does not Comply
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Does not Comply
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Does not Comply
New Zealand (NZIoC) Complies
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Nicola Anderson
Supersedes date 19-May-2008
Revision date 19-Jun-2015
Version 3
The following sections have beenrevised:
Updated according to GHS/CLP, No changes with regard to classification have been made.
Full text of H-Statements referred to under sections 2 and 3
This product is not classified as hazardous therefore no (H) hazard statements assigned.
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Antifoam Agent D175A SDS no. D175A
Revision date 19-Jun-2015
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
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SDS no. D901
Version 5
Revision date 13-Apr-2016
Supersedes date 13-Mar-2012
Safety Data SheetCement Class A D901
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Cement Class A D901
Product code D901
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Skin sensitization Sub-Category 1B
Specific target organ toxicity(single exposure)
Category 3
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
Signal wordDANGER
Hazard statementsH315 - Causes skin irritationH318 - Causes serious eye damageH317 - May cause an allergic skin reactionH335 - May cause respiratory irritation
Precautionary Statements - EU (§28, 1272/2008) P280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/ physicianP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathingP501 - Dispose of contents/container in accordance with local regulations.
Supplementary precautionary statements P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP333 + P313 - If skin irritation or rash occurs: Get medical advice/ attentionP362 - Take off contaminated clothing and wash before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closed
ContainsPortland cement
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Component EC-No. CAS-No Weight % -range
Classification(67/548)
Classification (Reg.1272/2008)
REACHregistration
numberPortland cement 266-043-4 65997-15-1 60-100 Xi;R36/37/38
R41R43
Skin Irrit. 2 (H315) Skin Sens. 1B (H317) Eye Dam. 1 (H318) STOT SE 3 (H335)
No data available
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
3.2 Mixtures
Not Applicable
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. If swallowed, do notinduce vomiting - seek medical advice.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention if irritation persists.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get immediate medical attention.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaNon-combustible, Use extinguishing media appropriate for surrounding material.
Extinguishing media which shall not be used for safety reasonsNone known.
5.2 Special hazards arising from the substance or mixture
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Unusual fire and explosion hazards
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
None known.
Hazardous combustion productsReact with hydrofluoric acid (HF) forming toxic gas (SiF4), Thermal decomposition can lead to release of irritating gases andvapors.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Avoid breathing dust; if exposed to high dust concentration, leave areaimmediately. Avoid contact with the skin and the eyes.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil. Prevent entry into sewage.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.
Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. May cause sensitization of susceptible persons.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash thoroughly with soap and water after handling and beforeeating, drinking, or using tobacco. Do not eat, drink or smoke when using this product. Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moistureStore away from incompatibles, Powdered aluminum Acids Oxidizing agents
Storage class Chemical storage.
Packaging material Use specially constructed containers only. Bag with moisture barrier
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
Component EU OEL Austria Australia Denmark
Portland cement Not determined 5 mg/m3 TWA inhalablefraction
10mg/m3TWAinhalabledust
Not determined
Component Malaysia France Germany Hungary
Portland cement 10 mg/m3 TWA Not determined TWA 10mg/m3TWA
Component New Zealand Italy Netherlands Norway
Portland cement 10 mg/m3 TWA Not determined 10 mg/m3 TWA Not determined
Component Poland Portugal Romania Russia
Portland cement 6.0 mg/m3 TWA NDS2.0 mg/m3 TWA NDS
10 mg/m3 TWAparticulate matter
containing no Asbestosand <1% Crystalline
silica
10mg/m3TWAinhalablefraction, dust
Not determined
Component Spain Switzerland Turkey UK
Portland cement 4 mg/m3 TWA VLA-ED 5 mg/m3 TWA MAK Not determined 30 mg/m3 STELcalculated inhalable
dust12 mg/m3 STEL
calculated respirabledust
10 mg/m3 TWAinhalable dust
4 mg/m3 TWA respirabledust
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed.
Personal protective equipmentEye protection Wear dust resistant safety goggles where there is a danger of eye contact. It is good
practice to wear goggles when handling any chemical.
Hand protection Impervious gloves made of:, PVC disposable gloves, Leather gloves, Rubber gloves,Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment, Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181), At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash andemergency shower must be available at the work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Powder
Odor Odorless
Color Gray
Odor threshold Not applicable
Physical state Solid
Property Values Remarks pH No information available
pH @ dilution 11 - 13 @10% sol
Melting/freezing point Not Applicable
Boiling point/range Not Applicable
Flash point Not Applicable
Evaporation rate (BuAc =1) Not Applicable
Flammability (solid, gas) Not Applicable
Flammability Limits in AirUpper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density Not applicable
Specific gravity ~ 3
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
Explosive properties Not Applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
10. Stability and reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from moisture.
10.5 Incompatible materials
Acids. Powdered aluminum. Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation.
Ingestion Ingestion may cause irritation to mucous membranes.
Bulk density No information available
Relative density No information available
Water solubility Slightly soluble in water.
Solubility in other solvents No information available
Autoignition temperature Not Applicable
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Log Pow No information available
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
Unknown acute toxicity Not Applicable.
Component LD50 Oral LD50 Dermal LC50 Inhalation
Portland cement No data available No data available No data available
Sensitization May cause sensitization by skin contact.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Inhalation. Eye contact.
Routes of entry Inhalation. Skin contact. Eye contact.
Specific target organ toxicity(single exposure)
Category 3
Specific target organ toxicity(repeated exposure)
Not classified.
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not Applicable.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Component Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Portland cement No information available No information available No information available
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
12.4 Mobility in soil
MobilitySlightly soluble in water.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 10 13 14 , 15 01 01
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodeNot Applicable
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Standard for the Uniform Scheduling of Drugs and Poisons
Portland cementSchedule 4Schedule 6Schedule 5
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.
International inventories
USA (TSCA) Complies
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Cement Class A D901 SDS no. D901
Revision date 13-Apr-2016
European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Does not Comply
Japan (ENCS) Does not Comply
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes date 13-Mar-2012
Revision date 13-Apr-2016
Version 5
The following sections have beenrevised:
Updated according to GHS/CLP, No changes with regard to classification have been made.
Text of R phrases mentioned in Section 3R41 - Risk of serious damage to eyesR43 - May cause sensitization by skin contact
R36/37/38 - Irritating to eyes, respiratory system and skin
Full text of H-Statements referred to under sections 2 and 3
H315 - Causes skin irritationH318 - Causes serious eye damageH317 - May cause an allergic skin reactionH335 - May cause respiratory irritationH317 - May cause an allergic skin reaction
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
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SDS no. D907
Version 5
Revision date 01-Aug-2018
Supersedes Date: 05-Mar-2014
Safety Data SheetCement Class G D907
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Class G D907
Product code D907
Country Limitations This SDS is not for use in the European Union (EU).
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Skin sensitization Sub-Category 1B
Specific target organ toxicity - Single exposure Category 3
Environmental hazards Not classified
Physical Hazards Not classified
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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2.2 Label elements
Signal wordDANGER
Hazard StatementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation
Precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP362 - Take off contaminated clothing and wash before reuseP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsPortland Cement Clinker
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%Portland Cement Clinker 266-043-4 65997-15-1 60-100
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CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors React with hydrofluoric acid (HF) forming toxic gas(SiF4).
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5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Avoid dust formation. Avoid breathing dust; if exposed to high dustconcentration, leave area immediately. Avoid contact with the skin and the eyes.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.
Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. Persons susceptible to allergic reactions should not handle this product.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Protect from moistureStore away from incompatibles, Powdered aluminum Acids Oxidizing agents Hydrofluoricacid (HF)
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Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptPortland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA Not determined
Chemical Name India Indonesian Japan
Portland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL1 mg/m3 OEL
Chemical Name Kazakhstan Kuwait New Zealand
Portland Cement Clinker Not determined Not determined 10 mg/m3 TWA
Chemical Name Malaysia Philippines Russia
Portland Cement Clinker 10 mg/m3 TWA Not determined Not determined
Chemical Name Thailand Vietnam Turkey
Portland Cement Clinker Not determined Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts
Tightly fitting safety goggles Safety glasses with side-shields
Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Imperviousgloves made of: PVC disposable gloves Rubber gloves Frequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.Type P2/P3 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
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Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Powder
Odor Odorless
Color Gray or White
Odor threshold Not applicable
Explosive properties Not applicable
Oxidizing properties Not applicable
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) Not applicable
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
Physical state Solid
Property Values Remarks pH Not applicable
pH @ dilution 11 - 13 @10% sol
Melting / freezing point > 1250 °C / 2282 °F
Boiling point/range No information available
Flash point Not applicable
Evaporation rate (BuAc =1) Not applicable
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity ~ 3
Bulk density 0.9 - 1.5 g/cm³
Relative density 2.75 - 3.20
Water solubility 0.1-1.5 g/L @ 20 °C
Solubility in other solvents No information available
Autoignition temperature Not applicable
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow No information available
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10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from moisture. Avoid dust formation.
10.5 Incompatible materials
Acids. Powdered aluminum. Strong oxidizing agents. Hydrofluoric acid (HF).
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contactwith moist mucous membranes of the respiratory system can cause caustic conditionresulting in burns.
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Ingestion Ingestion may cause irritation to mucous membranes.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Portland Cement Clinker No data available No data available No data available
Sensitization May cause allergic skin reaction.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Inhalation. Eye contact.
Routes of entry Inhalation. Skin contact. Eye contact.
Specific target organ toxicity -Single exposure
Category 3
Specific target organ toxicity - Not classified.
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Repeated exposure
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates
Portland Cement Clinker No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradability
Portland Cement Clinker Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name Bioaccumulation
Portland Cement Clinker Product/Substance is inorganic
12.4 Mobility
MobilitySlightly soluble in water.
Mobility in soilNo information available.
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12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons
Portland Cement ClinkerSchedule 4Schedule 6Schedule 5
New Zealand Hazard Classification Classified
HSNO approval no. 6.5B, 6.3A, 8.3A
Group number HSR002544
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 05-Mar-2014
Revision date 01-Aug-2018
Version 5
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
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Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 3 *Flammability 1Physical hazard 0PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D110
Version 3
Revision date 06-Jun-2018
Supersedes Date: 20-Feb-2015
Safety Data SheetCement Retarder D110
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Retarder D110
Product code D110
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Thermal decomposition can lead to release of irritating gases and vapors
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
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Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
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6.4 Reference to other sections
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Cement Retarder D110 SDS no. D110
Revision date 06-Jun-2018
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Do not freeze Storeabove 0°C Store away from incompatibles, Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only. High density polyethylene (HDPE) drum
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical Use eye protection
according to EN 166, designed to protect against liquid splashes Tightly fitting safetygoggles
Hand protection Wear chemical resistant gloves such as nitrile or neoprene. Repeated or prolonged contactRubber gloves Neoprene NitrileBreak through time >480 minutesGlove thickness 0.5 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient
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ventilation wear suitable respiratory equipment Respirator with combination filter forvapour/particulate (EN 141) Type A/P2
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Opaque
Odor Sweet
Color Brown
Odor threshold Not applicable
Explosive properties None known
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
Physical state Liquid
Property Values Remarks pH 6 - 9
pH @ dilution No information available
Melting / freezing point -4 °C / 24.8 °F
Boiling point/range 100 °C / 212 °F
Flash point > 100 °C / > 212 °F
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity 1.14 20 °C
Bulk density No information available
Relative density No information available
Water solubility Soluble
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature >242°C / >467.6 °F
Kinematic viscosity No information available
Dynamic viscosity 1.5cst @ 40 °C
log Pow Does not bioaccumulate
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VOC content(%) None
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze. Store above 0°C.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
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Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact.
Routes of entry No route of entry noted.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishNot considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesNot considered toxic.
12.2 Persistence and degradability
Product is biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
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12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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Cement Retarder D110 SDS no. D110
Revision date 06-Jun-2018
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Complies
China (IECSC) Does not comply
Australia (AICS) Complies
Korean (KECL) Does not comply
New Zealand (NZIoC) Does not comply
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 20-Feb-2015
Revision date 06-Jun-2018
Version 3
This SDS has been revised in thefollowing section(s)
1, 2, 7, 8, 9, 10, 11, 15, 16No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1Flammability 1Physical hazard 0PPE E
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Cement Retarder D110 SDS no. D110
Revision date 06-Jun-2018
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.
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SDS no. D013
Version 2
Revision date 17-Nov-2015
Supersedes date 07-Mar-2014
Safety Data SheetRetarder D013
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Retarder D013
Product code D013
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.
Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which shall not be used for safety reasonsNone known.
5.2 Special hazards arising from the substance or mixture
Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Sulfur oxides, Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning upAvoid generating or breathing dust. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traceswith water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and storage
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
Storage precautions Keep away from open flames, hot surfaces and sources of ignition. Keep containers tightlyclosed in a dry, cool and well-ventilated place. Incompatible with oxidizing agents.
Storage class Chemical storage.
Packaging material Use specially constructed containers only.
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
NotesNo biological limit allocated
8.2 Exposure controls
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All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Safety glasses with side-shields.
Hand protection Use protective gloves made of:, Nitrile, Neoprene gloves, Rubber, Frequent change isadvisable.
Respiratory protection Use the indicated respiratory protection if the occupational exposure limit is exceededand/or in case of product release (dust), Effective dust mask, Type P2, At work in confinedor poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Powder
Odor Faint
Color Brown
Odor threshold Not applicable
Physical state Solid
Property Values Remarks pHpH @ dilution 8.6 @ 10 g/L
Melting/freezing point No information available
Boiling point/range Not Applicable
Flash point Not Applicable
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not Applicable
Flammability Limits in AirUpper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density Not applicable
Specific gravity 1.2@20°C
Bulk density 480kg/m3
Relative density No information available
Water solubility Soluble
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity Not Applicable
Dynamic viscosity . Not Applicable
Log Pow Does not bioaccumulate
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
Explosive properties Suspended dust may present a dust explosion hazard
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See also section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.
Eye contact Dust may cause mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility in soil
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MobilityThe product is water soluble, and may spread in water systems.
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: 07 0799; 16 03 06
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not Applicable
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14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC Code
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
Please contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Germany, Water EndangeringClasses (VwVwS)
Hazardous to water/Class 1
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.
International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes date 07-Mar-2014
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Retarder D013 SDS no. D013
Revision date 17-Nov-2015
Revision date 17-Nov-2015
Version 2
The following sections have beenrevised:
15. Regulatory Information, No changes with regard to classification have been made.
Full text of H-Statements referred to under sections 2 and 3
This product is not classified as hazardous therefore no (H) hazard statements assigned.
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
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SDS no. D065
Version 1
Revision date 18-Jun-2014
Supersedes date 10-May-2012
Safety Data SheetTIC* D65 Dispersant
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name TIC* D65 Dispersant
Product code D065
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary Statements - EU (§28, 1272/2008) This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Indication of dangerNot classified
ContainsFor the full text of the H-Statements mentioned in this Section, see Section 16.
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
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TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which shall not be used for safety reasonsNone known.
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Sulfur dioxide, Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning upSweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.
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6.4 Reference to other sections
________________________________________________________________________________________
TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromdirect sunlight. Protect from moisture
Storage class Chemical storage.
Packaging material Use specially constructed containers only. Pail with resealable inner polyethylene bag
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
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NotesNo biological limit allocated
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TIC* D65 Dispersant SDS no. D065
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8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation.
Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safety
goggles.
Hand protection Use protective gloves made of:, Nitrile, Neoprene gloves, Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Half mask with a particle filter P2 (EuropeanNorm EN 143 = former DIN 3181).
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Powder
Odor Faint
Color Tan
Odor threshold Not applicable
Physical state Solid
Property Values Remarks pH ~10
pH @ dilution 10 g/l
Melting/freezing point No information available
Boiling point/range Not applicable
Flash point Not Applicable
Evaporation rate (BuAc =1) Not Applicable
Flammability (solid, gas) Not Applicable
Flammability Limits in AirUpper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density Not applicable
Specific gravity 0.8 20 °C
Bulk density No information available
Relative density No information available
Water solubility Soluble
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TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
Explosive properties Suspended dust may present a dust explosion hazard
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from moisture. Keep away from direct sunlight.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See also section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
Solubility in other solvents No information available
Autoignition temperature Not Applicable
Decomposition temperature No information available
Kinematic viscosity Not Applicable
Dynamic viscosity No information available Not Applicable
Log Pow No information available
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TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity No information available.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Not readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
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TIC* D65 Dispersant SDS no. D065
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12.4 Mobility in soil
MobilityThe product is water soluble, and may spread in water systems.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 07 07 99
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
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TIC* D65 Dispersant SDS no. D065
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14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodeNot Applicable Please contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.
International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Beilin Li
________________________________________________________________________________________
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________________________________________________________________________________________
TIC* D65 Dispersant SDS no. D065
Revision date 18-Jun-2014
Supersedes date 10-May-2012
Revision date 18-Jun-2014
Version 1
The following sections have beenrevised:
Updated according to GHS/CLP.
Text of R phrases mentioned in Section 3Not classified
Full text of H-Statements referred to under sections 2 and 3
This product is not classified as hazardous therefore no (H) hazard statements assigned.Not classified
N/A - Not Applicable, N/D - Not Determined.
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
________________________________________________________________________________________
Page 10 / 10
Safety Data SheetCement Liquid Dispersant D80
SDS no. D080
Version 2
Revision date 22/Jan/2016
Supersedes date 22/Apr/2014
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Cement Liquid Dispersant D80
Product code D080
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards
Chronic aquatic toxicity Category 2
Physical Hazards Not classified
________________________________________________________________________________________
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Signal wordNone
Hazard statementsH411 - Toxic to aquatic life with long lasting effects
Precautionary statements P273 - Avoid release to the environmentP391 - Collect spillageP501 - Dispose of contents/container in accordance with local regulations.
ContainsSodium polynaphthalene sulfonate
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureHAZARDOUS SUBSTANCE. DANGEROUS GOODS.Classified as Hazardous according to the criteria of NOHSC.
3. Composition/information on ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
Component EC-No. CAS-No Weight % -range
Classification(67/548)
Classification (Reg.1272/2008)
REACHregistration
number
Sodiumpolynaphthalene
sulfonate
Polymer 9008-63-3 20-40 - Aquatic Chronic 2 (H411)
________________________________________________________________________________________
No data available
CommentsThe product contains other ingredients which do not contribute to the overall classification.
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________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which shall not be used for safety reasonsNone known.
________________________________________________________________________________________
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known based on information supplied.
Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Sulphur oxides.
5.3 Advice for firefighters
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Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
Hazchem code ADG3Z
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash hands before eating, drinking or smoking When using donot smoke, eat or drink. Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Store in originalcontainer. Do not freeze Store above 0°C Avoid contact with: Oxidizing agents Acids
________________________________________________________________________________________
Storage class Chemical storage.
Packaging material Store in PVC, PE, or stainless steel.
7.3 Specific end uses
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See Section 1.2.
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Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.No biological limit allocated
Component EU OEL Austria Australia Denmark
Sodium polynaphthalene sulfonate Not determined Not determined Not determined Not determined
Component Malaysia France Germany Hungary
Sodium polynaphthalene sulfonate Not determined Not determined Not determined Not determined
Component New Zealand Italy Netherlands Norway
Sodium polynaphthalene sulfonate Not Determined Not determined Not determined Not determined
Component Poland Portugal Romania Russia
Sodium polynaphthalene sulfonate Not determined Not determined Not determined Not determined
Component Spain Switzerland Turkey UK
Sodium polynaphthalene sulfonate Not determined Not determined Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation.
Personal protective equipmentEye protection Safety glasses with side-shields.
________________________________________________________________________________________
Hand protection Use protective gloves made of:, Neoprene, Nitrile, Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Type A/P2, At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.
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Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothingbefore re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Opaque
Odor Pungent
Color Dark brown
Odor threshold Not applicable
Explosive properties None known
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Physical state Liquid
Property Values Remarks pH 6 - 8
pH @ dilution
Melting/freezing point -2 °C / 28 °F
Boiling point/range 100 °C / 212 °F
Flash point No information available
Evaporation rate (BuAc =1)
Flammability (solid, gas) Not Applicable
Flammability Limits in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density >1 (air = 1)
Specific gravity 1.2 20 °C
Bulk density No information available Not applicable
Relative density No information available
Water solubility Soluble
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
________________________________________________________________________________________
Kinematic viscosity
Dynamic viscosity 60 mPa s
Log Pow
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No information available
________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze.
10.5 Incompatible materials
Oxidizing agents. Acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
Component LD50 Oral LD50 Dermal LC50 Inhalation
Sodium polynaphthalene sulfonate No data available No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity
________________________________________________________________________________________
This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Inhalation. Eye contact.
Routes of entry No route of entry noted.
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Specific target organ toxicity(single exposure)
Not classified
________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Specific target organ toxicity(repeated exposure)
Not classified.
Neurological effects None known.
Target organ effects None known.
Aspiration hazard Not Applicable.
12. Ecological information
12.1 Toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Toxicity to algaeToxic to aquatic life with long lasting effects. EC50 (48Hrs) of the polymer = 1.8mg/l.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Component Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Sodium polynaphthalene sulfonate No information available No information available No information available
12.2 Persistence and degradability
Product is not biodegradable.
12.3 Bioaccumulative potential
No bioaccumulation expected due to high molecular weight.
12.4 Mobility in soil
MobilityThe product is water soluble, and may spread in water systems.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
________________________________________________________________________________________
12.6 Other adverse effects.
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None known.
________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 07 07 99; 16 03 06
14. Transport information
14.1 UN Number
UN/ID No. (ADR/RID/ADN/ADG) UN3082
UN No. (IMDG) UN3082
UN No. (ICAO) UN3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Sodium polynaphthalene sulfonate)
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class 9
IMDG Hazard class 9
ICAO Hazard class/division 9
14.4 Packing group ADR/RID/ADN/ADG Packing group III
IMDG Packing group III
ICAO Packing group III
14.5 Environmental hazard Yes
________________________________________________________________________________________
14.6 Special precautions
Hazard identification no (ADR) 90
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EmS (IMDG) F-A, S-F
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Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Emergency action code 3Z
Tunnel restriction code (E)
Hazchem code ADG 3Z
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo Poisons Schedule number allocated
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
ADG Code – Australian Dangerous Goods Code.
Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values .
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemicalagents at work .
International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
15.2 Chemical Safety Report
No information available
________________________________________________________________________________________
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes date
Page 10 / 11
22/Apr/2014
________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080
Revision date 22/Jan/2016
Revision date 22/Jan/2016
Version 2
The following sections have beenrevised:
The following sections have been revised:, All sections, There have been changes withregard to classification.
________________________________________________________________________________________
Full text of H-Statements referred to under sections 2 and 3
H411 - Toxic to aquatic life with long lasting effects
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
Page 11 / 11
SDS no. D182
Version 2
Revision date 05-Apr-2017
Supersedes Date: 18-Jun-2014
Safety Data SheetMUDPUSH* II Spacer D182
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name MUDPUSH* II Spacer D182
Product code D182
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger New Zealand Limited94 Paraite RoadBell BlockNew PlymouthNew Zealand.
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsDust may form explosive mixture in air.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upSweep up and shovel into suitable containers for disposal. Take precautionary measures against static discharges. After cleaning,flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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7.1 Precautions for safe handling
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Material becomes slippery when wet. Use caution if wet.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromopen flames, hot surfaces and sources of ignition. Keep away from direct sunlight.Incompatible with oxidizing agents.
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields
Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Useprotective gloves made of: Rubber Neoprene Nitrile Frequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Powder
Odor Mild Sweet
Color Red brown
Odor threshold Not applicable
Explosive properties Suspended dust may present a dust explosion hazard
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
Physical state Solid
Property Values Remarks pHpH @ dilution ~8 650g/l (Soln)
Melting / freezing point No information available
Boiling point/range Not applicable
Flash point Not applicable Not applicable
Evaporation rate (BuAc =1) Not applicable
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density Not applicable
Specific gravity 1.3 @ 20 °C
Bulk density No information available
Relative density No information available
Water solubility Partly soluble Gels on contactwith water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature > 242 °C / 468 °F
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow No information available
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Keep away from open flames, hot surfaces and sources of ignition. Keep away from direct sunlight.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.
Eye contact Dust contact with the eyes can lead to mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry No route of entry noted.
Specific target organ toxicity - Not classified
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
Single exposureSpecific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility
MobilityPartly soluble. Gels on contact with water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
_____________________________________________________________________________________________
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
New Zealand hazard classification Not classified
HSNO approval no. Not required
Group number Not required
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MUDPUSH* II Spacer D182 SDS no. D182
Revision date 05-Apr-2017
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Does not comply
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 18-Jun-2014
Revision date 05-Apr-2017
Version 2
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
_____________________________________________________________________________________________
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SDS no. D255
Version 2
Revision date 04-Jan-2018
Supersedes Date: 21-Jan-2016
Safety Data SheetMid-Range FLAC D255
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Mid-Range FLAC D255
Product code D255
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger New Zealand Limited94 Paraite RoadBell BlockNew PlymouthNew Zealand.
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Mid-Range FLAC D255 SDS no. D255
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Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains2-methylpropan-2-ol
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Suspended dust may present a dust explosion hazard
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%2-methylpropan-2-ol 200-889-7 75-65-0 <5
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
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Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsDust may form explosive mixture in air.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia, Hydrogen cyanide (hydrocyanic acid).
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.
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Methods for cleaning upAvoid generating or breathing dust. Take precautionary measures against static discharges. Take up mechanically and collect in
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Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
suitable container for disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Donot breathe dust. Material becomes slippery when wet. Use caution if wet.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromopen flames, hot surfaces and sources of ignition. Avoid excessive heat for prolongedperiods of time. Keep away from direct sunlight. Incompatible with oxidizing agents. Strongacids.
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
Component Information
Chemical Name Arabic Australia Egypt2-methylpropan-2-ol 100 ppm TWA
303 mg/m3 TWA150ppmSTEL
455mg/m3STEL100ppmTWA
303mg/m3TWA
100 ppm TWA303 mg/m3 TWA
Chemical Name India Indonesian Japan
2-methylpropan-2-ol Not determined 100 ppm TWA303 mg/m3 TWA
150 mg/m3 OEL50 ppm OEL
Chemical Name Kazakhstan Kuwait New Zealand
2-methylpropan-2-ol 10 mg/m3 MAC Not determined 150 ppm STEL455 mg/m3 STEL
100 ppm TWA303 mg/m3 TWA
Chemical Name Malaysia Philippines Russia
2-methylpropan-2-ol 100 ppm TWA303 mg/m3 TWA
100 ppm TWA300 mg/m3 TWA
10 mg/m3 MAC
Chemical Name Thailand Vietnam Turkey
2-methylpropan-2-ol 100 ppm TWA Not determined Not determined
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8.2 Exposure controls
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Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety goggles
Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Imperviousgloves made of: Rubber gloves Butyl Neoprene Nitrile Frequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Granules
Odor None
Color White
Odor threshold Not applicable
Physical state Solid
Property Values Remarks pH Not applicable
pH @ dilution 4 - 9 @ 5 g/l
Melting / freezing point > 250 °C / 482 °F
Boiling point/range Not applicable
Flash point Not applicable Not applicable
Evaporation rate (BuAc =1) Not applicable
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density Not applicable
Specific gravity 1.15 - 1.35
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Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
Explosive properties Suspended dust may present a dust explosion hazard
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Keep away from direct sunlight. Avoid excessive heat for prolonged periods of time. Keep away from openflames, hot surfaces and sources of ignition.
10.5 Incompatible materials
Incompatible with oxidizing agents. Strong acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact Dust may cause mechanical irritation.
Bulk density ~ 0.20 - 0.40
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature >150°C / >302° F
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow No information available
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Mid-Range FLAC D255 SDS no. D255
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Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
2-methylpropan-2-ol = 2200 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) > 10000 ppm ( Rat ) 4 h
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact. Inhalation.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
2-methylpropan-2-ol 6130 - 6700 mg/L LC50 Pimephalespromelas 96 h
> 1000 mg/L EC50 Desmodesmussubspicatus 72 h
4607 - 6577 mg/L EC50 Daphniamagna 48 h = 933 mg/L EC50
Daphnia magna 48 h
12.2 Persistence and degradability
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Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
Not readily biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
log Pow<0
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
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Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
New Zealand hazard classification Not classified
HSNO approval no. Not required
Group number Not required
International inventories
USA (TSCA) Does not comply
Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Does not comply
China (IECSC) Complies
Australia (AICS) Does not comply
Korean (KECL) Does not comply
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 21-Jan-2016
Revision date 04-Jan-2018
Version 2
This SDS has been revised in the All sections No changes with regard to classification have been made.
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_____________________________________________________________________________________________
Mid-Range FLAC D255 SDS no. D255
Revision date 04-Jan-2018
following section(s)
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1Flammability 1Physical hazard 0PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
_____________________________________________________________________________________________
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SDS no. D256
Version 1
Revision date 21/Apr/2016
Supersedes date None
Safety Data SheetMid-Range liquid FLAC D256
1. Identification
1.1 Product identifier
Product name Mid-Range liquid FLAC D256
Product code D256
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications.
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
E-mail address [email protected]
Prepared byGlobal Regulatory Compliance - Chemicals (GRC - Chemicals) , Gulan Sun
1.4 Emergency Telephone Number
Emergency telephone (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666
2. Hazards identification
2.1 Classification of the substance or mixture
GHS - Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
Supplier Schlumberger Technology Corporation110 Schlumberger DriveSugar Land, Texas 77478, USATelephone: 1-281-285-7873
Schlumberger Canada, Ltd.200, 125 - 9th Avenue SECalgary, Alberta T2G 0P6, CanadaTelephone: 1-613-992-4624
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Mid-Range liquid FLAC D256 SDS no. D256
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2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Unknown acute toxicity Not Applicable.
3. Composition/information on Ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
CommentsNo classified hazards
4. First aid measures
4.1 First-Aid Measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Getmedical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
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Mid-Range liquid FLAC D256 SDS no. D256
Revision date 21/Apr/2016
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which shall not be used for safety reasonsNone known.
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
Contaminated surfaces will be extremely slippery.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
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Mid-Range liquid FLAC D256 SDS no. D256
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7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers in a dry, cool and well-ventilated place, out of direct sunlight. Protect fromfreezing Store away from incompatibles, Incompatible with oxidizing agents.
Packaging material Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters Exposure limits No classified ingredients, or those having occupational exposure limits, present
above the level of disclosure.
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation.
Personal protective equipmentEye protection Use tight-fitting safety goggles, if not available use safety glasses with side-shields.
Hand protection Use protective gloves made of:, Butyl, Gloves- Neoprene, Nitrile Unless Specified, Beaware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection All respiratory protection equipment should be used within a comprehensive respiratoryprotection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHARespiratory Protection Standard) or local equivalent.
If exposed to airborne mist/aerosol of this product, use at least a NIOSH-approved N95half-mask disposable or re-usable particulate respirator. In work environments containingoil mist/aerosol, use at least a NIOSH-approved P95 half-mask disposable or reuseableparticulate respirator. If exposed to vapors from this product use a NIOSH/MSHA-approvedrespirator with an Organic Vapor cartridge.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
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Mid-Range liquid FLAC D256 SDS no. D256
Revision date 21/Apr/2016
Appearance Clear
Color Light yellow
Odor Slight
Odor threshold Not applicable
Explosive properties No information available
Oxidizing properties No information available
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from freezing. Keep away from direct sunlight.
10.5 Incompatible materials
Incompatible with oxidizing agents.
10.6 Hazardous decomposition products
Physical state Liquid
Property Values Remarks pH 4-6
pH @ dilutionMelting/freezing point < 0 °C / 32 °F
Boiling point/range > 100 °C / 212 °F
Flash point No information available
Evaporation rate (BuAc =1) Similar to water.
Flammability (solid, gas) Not Applicable
Flammability Limits in AirUpper flammability limit No information available
Lower flammability limit No information available
Vapor pressure 2.3 kPa @ 20°C
Vapor density Similar to water.
Specific gravity 1.0 - 1.3
Bulk density No information available
Water solubility Miscible with water.
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Log Pow No information available
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Mid-Range liquid FLAC D256 SDS no. D256
Revision date 21/Apr/2016
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicityInhalation Breathing dried dust or spray mist may irritate respiratory tract.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Sensitization Repeated or prolonged contact may cause allergic reactions in very susceptible persons.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity No evidence of carcinogenic properties.
Reproductive toxicity No evidence of toxicity to reproduction.
Developmental toxicity Not known to cause birth defects or have a deleterious effect on a developing fetus.
Routes of exposure Skin contact. Eye contact. Inhalation.
Routes of entry No route of entry noted.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
Aspiration hazard Not Applicable.
12. Ecological information
12.1 Toxicity
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Not readily biodegradable.
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12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility in soil
The product is miscible with water. May spread in water systems.
12.5 Results of PBT and vPvB assessment
This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1 UN Number UN No. (DOT) Not regulated
UN No. (TDG) Not regulated
UN/ID No. (ADR/RID/ADN/ADG) Not regulated
UN No. (IMDG) Not regulated
UN No. (ICAO) Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) DOT Hazard class Not regulated
TDG Hazard class Not regulated
ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group DOT Packing group Not regulated
TDG Packing group Not regulated
ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions
________________________________________________________________________________________
Mid-Range liquid FLAC D256 SDS no. D256
Revision date 21/Apr/2016
Not Applicable
15. Regulatory information
International inventories
USA (TSCA) Complies
Canada (DSL) Complies.
European Union (EINECS and ELINCS) Complies
Philippines (PICCS) Does not Comply
Japan (ENCS) Does not Comply
China (IECSC) Does not Comply
Australia (AICS) Does not Comply
Korean (KECL) Does not Comply
New Zealand (NZIoC) Does not Comply
U.S. Federal and State Regulations
SARA 311/312 Hazard CategoriesNot a SARA 311/312 hazard.
State CommentsProposition 65: This product contains chemical(s) considered by the State of California's Safe Drinking Water and ToxicEnforcement Act of 1986 to cause cancer and/or reproductive toxicity.
2-Propenamid (impurity)developmental toxicitymale reproductive toxicitycarcinogen
Canadian Classification
This Safety Data Sheet has been prepared in compliance with the Hazardous Products Regulations.
16. Other information
Revision date 21/Apr/2016
Version 1
The following sections have beenrevised:
New issue
HMIS classification
Health 1Flammability 1Physical hazard 0PPE B
N/A - Not Applicable, N/D - Not Determined.
________________________________________________________________________________________
Mid-Range liquid FLAC D256 SDS no. D256
Revision date 21/Apr/2016
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
SDS no. D600G
Version 3
Revision date 15-Jul-2016
Supersedes date 04-Mar-2014
Safety Data SheetD600G GASBLOK* Gas Migration Control Additive
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name D600G GASBLOK* Gas Migration Control Additive
Product code D600G
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Gas control agent Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada001 613 996 6666- Brazil 0800 707 7022
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to (EC) No. 1272/2008
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
EU specific hazard statementsEUH208 - Contains mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one May produce an allergicreaction
Precautionary Statements - EU (§28, 1272/2008) This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Indication of dangerNot classified
ContainsDodecyl sulfate, sodium salt
1,4-Dioxane
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
3. Composition/information on ingredients
3.1 Substances
Not Applicable
3.2 Mixtures
Component EC-No. CAS-No Weight % -range
Classification(67/548)
Classification (Reg.1272/2008)
REACHregistration
numberDodecyl sulfate,
sodium salt205-788-1 151-21-3 >= 0.1<0.3 Xn: R22
Xi; R38, R41Acute Tox. 4 (H302)Skin Irrit. 2 (H315)
Eye damage. 1 (H318)Aquatic Chronic 3 (H412)
No data available
1,4-Dioxane 204-661-8 123-91-1 <=0.1 F; R11-19Xi; R36/37
Carc.Cat.3; R40R66
Eye Irrit. 2 (H319)Carc. 2 (H351)
STOT SE 3 (H335)Flam. Liq. 2 (H225)
(EUH066)(EUH019)
No data available
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First aid measures
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4.1 First-Aid Measures
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D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaExtinguish with carbon dioxide, dry chemical, foam or waterspray.
Extinguishing media which shall not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2 Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsHeating or fire can release toxic gas.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
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6. Accidental release measures
________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment.
6.3 Methods and materials for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide sufficient air exchange and/or exhaust in work rooms.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid frost. Keepaway from open flames, hot surfaces and sources of ignition. Keep at 39 - 86 °F/ 4 - 30°C
Incompatible with materials which react with water. Strong acids. Strong bases Strongoxidizing agents Strong reducing agents.
Storage class Chemical storage.
Packaging material Use specially constructed containers only.
7.3 Specific end uses
See Section 1.2.
8. Exposure controls/personal protection
8.1 Control parameters
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
Component EU OEL Austria Australia Denmark
Dodecyl sulfate, sodium salt Not determined Not determined Not determined Not determined
1,4-Dioxane 20 ppm TWA73 mg/m3 TWA
40 ppm STEL146 mg/m3 STEL
20 ppm TWA73 mg/m3 TWA
10ppmTWA36mg/m3TWAskin notation
10 ppm TWA36 mg/m3 TWA
Potential for cutaneousabsorption
K
Component Malaysia France Germany Hungary
Dodecyl sulfate, sodium salt Not determined Not determined Not determined Not determined
1,4-Dioxane 20 ppm TWA72.1 mg/m3 TWA
Skin notation
40ppmSTEL140mg/m3STEL
20 ppmTWA73 mg/m3TWA
20 ppm TWA73 mg/m3 TWA
73mg/m3TWA
Component New Zealand Italy Netherlands Norway
Dodecyl sulfate, sodium salt Not Determined Not determined Not determined Not determined
1,4-Dioxane 25 ppm TWA90 mg/m3 TWA
Known or presumedhuman carcinogen
Possibility of significantuptake through the skin
Not determined 20 mg/m3 5 ppm TWA18 mg/m3 TWA10 ppm STEL
36 mg/m3 STELCarcinogen
Skin
Component Poland Portugal Romania Russia
Dodecyl sulfate, sodium salt Not determined Not determined Not determined Not determined
1,4-Dioxane 50 mg/m3 TWA Skin20 ppm TWA
20ppmTWA73mg/m3TWA
10 mg/m3 MACSkin
Component Spain Switzerland Turkey UK
Dodecyl sulfate, sodium salt Not determined Not determined Not determined Not determined
1,4-Dioxane 20 ppm VLA-EDindicative limit value
inhalable fraction andvapor
73 mg/m3 VLA-EDindicative limit value
inhalable fraction andvapor
40 ppm STEL144 mg/m3 STEL
Skin20 ppm MAK
72 mg/m3 MAK
Not determined 100 ppm STEL366 mg/m3 STEL
Skin25 ppm TWA
91 mg/m3 TWA
8.2 Exposure controls
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All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to reduce exposureEnsure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safety
goggles.
Hand protection Use protective gloves made of:, Be aware that liquid may penetrate the gloves. Frequentchange is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Use a self contained positive pressureindividual breathing apparatus if vapor inhalation is a risk.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash andemergency shower must be available at the work place.
Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Viscous
Odor Slight
Color Milky white.
Odor threshold Not applicable
Physical state Liquid
Property Values Remarks pH 6 - 8
pH @ dilutionMelting/freezing point -2 °C / 28 °F
Boiling point/range > 100 °C / 212 °F
Flash point > 100 °C / 212 °F Closed cup
Evaporation rate (BuAc =1)Flammability (solid, gas) Not Applicable
Flammability Limits in Air Not applicable
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure <31.33 hPa @ 25 °C
Vapor density No information available
Specific gravity 1.02
Bulk density No information available
Relative density 1.01 g/cm³
Water solubility Dispersible
Solubility in other solvents No information available
Autoignition temperature Not Applicable
Decomposition temperature No information available
Kinematic viscosityDynamic viscosity 1000 mPa s
Log Pow Not determined
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
Explosive properties Not Applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep away from sources of ignition - No smoking. Heat, flames and sparks. Protect from moisture. Avoid frost. Do not freeze.
10.5 Incompatible materials
Incompatible with materials which react with water. Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents.
10.6 Hazardous decomposition products
See also section 5.2. Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides (COx). Sulfuroxides. Sodium oxides.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product information EUH208 - Contains mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and2-methyl-2H-isothiazol-3-one May produce an allergic reaction.
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation. Components of the product may beabsorbed into the body through the skin.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not Applicable.
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
Component LD50 Oral LD50 Dermal LC50 Inhalation
Dodecyl sulfate, sodium salt = 977 mg/kg ( Rat ) = 580 mg/kg ( Rabbit ) > 3900 mg/m3 ( Rat ) 1 h
1,4-Dioxane = 4200 mg/kg ( Rat ) = 5170mg/kg ( Rat )
= 7600 µL/kg ( Rabbit ) = 46 mg/L ( Rat ) 2 h
Sensitization Repeated or prolonged contact may cause allergic reactions in very susceptible persons.
Mutagenic effects This substance has no evidence of mutagenic properties.
Carcinogenicity Contains a component that may cause cancer.
Reproductive toxicity None known.
Routes of exposure Skin contact. Eye contact.
Routes of entry No route of entry noted.
Specific target organ toxicity(single exposure)
Not classified
Specific target organ toxicity(repeated exposure)
Not classified.
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
Ecotoxicity effects
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Component Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Dodecyl sulfate, sodium salt 5.8 - 7.5 mg/L LC50 Pimephalespromelas 96 h = 1.31 mg/L LC50Cyprinus carpio 96 h 10.8 - 16.6
mg/L LC50 Poecilia reticulata 96 h13.5 - 18.3 mg/L LC50 Poecilia
reticulata 96 h 6.2 - 9.6 mg/L LC50Pimephales promelas 96 h 10.2 -
22.5 mg/L LC50 Pimephalespromelas 96 h = 4.5 mg/L LC50
Lepomis macrochirus 96 h 4.2 - 4.8
= 117 mg/L EC50Pseudokirchneriella subcapitata 96
h 3.59 - 15.6 mg/L EC50Pseudokirchneriella subcapitata 96
h 30 - 100 mg/L EC50Desmodesmus subspicatus 96 h =
53 mg/L EC50 Desmodesmussubspicatus 72 h
= 1.8 mg/L EC50 Daphnia magna48 h
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
mg/L LC50 Lepomis macrochirus 96h 4.06 - 5.75 mg/L LC50 Lepomismacrochirus 96 h 9.9 - 20.1 mg/L
LC50 Brachydanio rerio 96 h = 7.97mg/L LC50 Brachydanio rerio 96 h =
4.2 mg/L LC50 Oncorhynchusmykiss 96 h = 4.62 mg/L LC50
Oncorhynchus mykiss 96 h 4.3 - 8.5mg/L LC50 Oncorhynchus mykiss
96 h 22.1 - 22.8 mg/L LC50Pimephales promelas 96 h 15 - 18.9
mg/L LC50 Pimephales promelas96 h 8 - 12.5 mg/L LC50
Pimephales promelas 96 h
1,4-Dioxane = 9850 mg/L LC50 Pimephalespromelas 96 h > 10000 mg/L LC50Lepomis macrochirus 96 h 10306 -
14742 mg/L LC50 Pimephalespromelas 96 h
No information available = 163 mg/L EC50 water flea 48 h
12.2 Persistence and degradability
Product is not biodegradable.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility in soil
MobilityAfter release, disperses through ground water.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
application specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: Waste Code: 07 02 99
14. Transport information
14.1 UN Number Not regulated
14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Standard for the Uniform Scheduling of Drugs and Poisons
Dodecyl sulfate, sodium saltSchedule 6
1,4-DioxaneSchedule 6
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
International inventories
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________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Does not Comply
Philippines (PICCS) Does not Comply
Japan (ENCS) Does not Comply
China (IECSC) Does not Comply
Australia (AICS) Does not Comply
Korean (KECL) Does not Comply
New Zealand (NZIoC) Does not Comply
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes date 04-Mar-2014
Revision date 15-Jul-2016
Version 3
The following sections have beenrevised:
The following sections have been revised:, 15. Regulatory Information.
Text of R phrases mentioned in Section 3R11 - Highly flammableR19 - May form explosive peroxidesR40 - Limited evidence of a carcinogenic effectR66 - Repeated exposure may cause skin dryness or cracking
R36/37 - Irritating to eyes and respiratory system
Full text of H-Statements referred to under sections 2 and 3
This product is not classified as hazardous therefore no (H) hazard statements assigned.
H319 - Causes serious eye irritationH335 - May cause respiratory irritationH351 - Suspected of causing cancerH225 - Highly flammable liquid and vaporEUH066 - Repeated exposure may cause skin dryness or crackingEUH019 - May form explosive peroxidesEUH208 - Contains mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one May produce an allergicreaction
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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
________________________________________________________________________________________
D600G GASBLOK* Gas MigrationControl Additive
SDS no. D600G
Revision date 15-Jul-2016
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
________________________________________________________________________________________
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SDS no. D081
Version 3
Revision date 27-Mar-2018
Supersedes Date: 05-Jun-2015
Safety Data SheetLiquid Retarder D81
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Liquid Retarder D81
Product code D081
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid breathing vapors ormists. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromdirect sunlight. Store away from incompatibles, Strong acids. Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Local exhaust ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety goggles
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employeetraining Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Use respirator withorganic vapor protection (A, brown) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
_____________________________________________________________________________________________
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solution
Odor Of burnt sugar / Slight
Color Dark brown
Odor threshold Not applicable
Explosive properties Not applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
Physical state Liquid
Property Values Remarks pH 8 - 9
pH @ dilution No information available
Melting / freezing point No information available
Boiling point/range No information available
Flash point Does not flash
Evaporation rate (BuAc =1) Not applicable
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure Not applicable
Vapor density No information available
Specific gravity 1.24 - 1.26 @ 27 °C
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature 400 °C / 752 °F
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity 350 mPa.s @ 20 °C
log Pow No information available
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep away from direct sunlight.
10.5 Incompatible materials
Strong oxidizing agents. Strong acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact. Inhalation.
Routes of entry No route of entry noted.
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.Listed on PLONOR list of OSPAR
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand hazard classification Not classified
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
HSNO approval no. Not required
Group number Not required
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 05-Jun-2015
Revision date 27-Mar-2018
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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Liquid Retarder D81 SDS no. D081
Revision date 27-Mar-2018
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
_____________________________________________________________________________________________
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SDS no. D194
Version 3
Revision date 12-Feb-2019
Supersedes Date: 03-Jun-2015
Safety Data SheetLiquid Trifunctional Additive D194
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Liquid Trifunctional Additive D194
Product code D194
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteriaThermal decomposition can lead to release of irritating gases and vapors
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety goggles
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employeetraining Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance No information available
Odor Mild
Color Brown
Odor threshold No information available
Explosive properties No information available
Oxidizing properties No information available
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
Physical state Liquid
Property Values Remarks pH 10
pH @ dilution No information available
Melting / freezing point -2 °C / 28.4 °F
Boiling point/range 104 °C / 219.2 °F
Flash point No information available
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure 14.2 mmHg @ 20 °C
Vapor density No information available
Specific gravity 1.30
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity <600 cst
Dynamic viscosity No information available
log Pow No information available
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Inhalation. Ingestion. Eye contact.
Routes of entry Ingestion. Inhalation.
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
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_____________________________________________________________________________________________
Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 03-Jun-2015
Revision date 12-Feb-2019
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
_____________________________________________________________________________________________
Page 9 / 10
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
_____________________________________________________________________________________________
Liquid Trifunctional Additive D194 SDS no. D194
Revision date 12-Feb-2019
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D161
Version 5
Revision date 11-Feb-2016
Supersedes date 25-Nov-2015
Safety Data SheetMulti-Temperature Cement Retarder D161
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name Multi-Temperature Cement Retarder D161
Product code D161
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
Denmark Poison Control Hotline (DK): +45 82 12 12 12
Germany +49 69 222 25285
Italy Centro Antiveleni Ospedale Niguarda Milan: +39 02 6610 1029
Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is onlyavailable to health professionals)
2. Hazards Identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Health hazards
Reproductive toxicity Category 2
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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_____________________________________________________________________________________________
Multi-Temperature Cement RetarderD161
SDS no. D161
Revision date 11-Feb-2016
Signal wordWARNING
Hazard statementsH361 - Suspected of damaging fertility or the unborn child
Precautionary statements P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP281 - Use personal protective equipment as requiredP308 + P313 - IF exposed or concerned: Get medical advice/attentionP280 - Wear protective gloves/protective clothing/eye protection/face protection
ContainsSodium pentaborate
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-% Regulation (EC) No1272/2008
REACHregistration
numberSodium pentaborate 234-522-7 12007-92-0 5-10 Rep. 2 (H361) 01-2119970731-3
5-XXXX
CommentsThe product contains other ingredients which do not contribute to the overall classification.
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_____________________________________________________________________________________________
Multi-Temperature Cement RetarderD161
SDS no. D161
Revision date 11-Feb-2016
4. First aid measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Oxides of phosphorus, Carbon oxides (COx).
5.3 Advice for firefighters
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Special protective equipment for fire-fighters
_____________________________________________________________________________________________
Multi-Temperature Cement RetarderD161
SDS no. D161
Revision date 11-Feb-2016
As in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Store away from heatand sources of ignition Avoid extreme temperatures Store above 0°C Store away fromincompatibles, Strong reducing agents. Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
7.3 Specific end uses
See Section 1.2.
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_____________________________________________________________________________________________
Multi-Temperature Cement RetarderD161
SDS no. D161
Revision date 11-Feb-2016
8. Exposure controls/personal protection
8.1 Control parameters
Chemical Name EU OEL Austria Australia Denmark
Sodium pentaborate Not determined Not determined Not determined Not determined
Chemical Name Malaysia France Germany Hungary
Sodium pentaborate Not determined Not determined Not determined Not determined
Chemical Name New Zealand Italy Netherlands Norway
Sodium pentaborate Not determined Not determined Not determined Not determined
Chemical Name Poland Portugal Romania Russia
Sodium pentaborate Not determined Not determined Not determined Not determined
Chemical Name Spain Switzerland Turkey UK
Sodium pentaborate Not determined Not determined Not determined Not determined
NotesNo biological limit allocated
Derived No Effect Level (DNEL)
Short term exposure local effectsSodium pentaborate
Inhalation 9.6 mg/m³
Long term exposure local effectsSodium pentaborate
Inhalation 9.6 mg/m³
Short term exposure systemic effectsSodium pentaborate
Inhalation 5.5 mg/m³
Long term exposure systemic effectsSodium pentaborate
Oral 258 mg/kg bw/day
Inhalation 5.5 mg/m³
Predicted No Effect Concentration (PNEC)Sodium pentaborate
Fresh Water 2.02 mg/L
Sea Water 2.02 mg/L
Soil 5.4 mg/kg soil dw
Impact on sewage treatment 10 mg/L
Intermittent release 13.7 mg/L
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist intowork environment.
Personal protective equipmentEye protection Safety glasses with side-shields.
Hand protection Repeated or prolonged contact Use protective gloves made of: PVC disposable glovespolyvinyl alcohol or nitrile-butyl rubber gloves Be aware that liquid may penetrate thegloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient
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ventilation wear suitable respiratory equipment, Respirator with a vapor filter (EN 141), Atwork in confined or poorly ventilated spaces, respiratory protection with air supply must beused.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash andemergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothingbefore re-use.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance Clear Aqueous solution
Odor Slight
Color Colorless
Odor threshold Not applicable
Explosive properties Not applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) None
Density No information available
Physical state Liquid
Property Values Remarks pH 6.9
pH @ dilutionMelting / freezing point ~0 °C / 32 °F
Boiling point/range 100 °C / 212 °F
Flash point No information available
Evaporation rate (BuAc =1)Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity 1.1 20 °C
Bulk density No information available
Relative density 1.073 - 1.077
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosityDynamic viscosity No information available
log Pow No information available
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CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid extreme temperatures. Do not freeze.
10.5 Incompatible materials
Strong oxidizing agents. Strong reducing agents.
10.6 Hazardous decomposition products
See also section 5.2.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort. May cause damage to organs through prolongedor repeated exposure.
Unknown acute toxicity Not applicable.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Sodium pentaborate No data available LD50 > 2000 mg/kg bw LC50 > 2.03 mg/l
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
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Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard.
Routes of exposure Skin contact. Eye contact. Ingestion.
Routes of entry Ingestion.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard No hazard from product as supplied.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Sodium pentaborate LC50: 600 mg/l 96h No information available LC50: 86 mg/l 48h
12.2 Persistence and degradability
The organic portion of this material is not biodegradable.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility in soil
MobilitySoluble in water.
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12.5 Results of PBT and vPvB assessment
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Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, butapplication specific Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 16 10 01 - aqueous liquid wastes containing dangerous substances
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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Germany, Water EndangeringClasses (VwVwS)
Hazardous to water/Class 1
Australian Standard for the Uniform Scheduling of Drugs and PoisonsAustralian Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) No poisons schedule number allocated
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG).
Dutch Mining Regulations: In accordance with Mining Regulations 9.2 and Chapter 4 of the Working Conditions Decree.
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)
The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)International inventories
USA (TSCA) Complies
European Union (EINECS and ELINCS) Complies
Canada (DSL) Does not Comply
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Does not Comply
Australia (AICS) Complies
Korean (KECL) Does not Comply
New Zealand (NZIoC) Does not Comply
Denmark Pr. no: 1288609
15.2 Chemical Safety Report
No information available
16. Other information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
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Multi-Temperature Cement RetarderD161
SDS no. D161
Revision date 11-Feb-2016
Supersedes date 25-Nov-2015
Revision date 11-Feb-2016
Version 5
This SDS has been revised in thefollowing section(s)
The following sections have been revised: 12. Ecological information
Text of R phrases mentioned in Section 3R61 - May cause harm to the unborn child
Full text of H-Statements referred to under sections 2 and 3
H361 - Suspected of damaging fertility or the unborn child
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
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SDS no. D066
Version 2
Revision date 13-Jul-2017
Supersedes date 20-Oct-2014
Safety Data SheetSilica Flour D66
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Silica Flour D66
Product code D066
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
Malaysian Local emergency number; +603 2161 7655
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards
Specific target organ toxicity - Repeated exposure Category 2
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
Signal wordWARNING
Hazard StatementsH373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP314 - Get medical advice/attention if you feel unwellP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsQuartz, Crystalline silica
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Chemical Name EC No CAS No Weight-%Quartz, Crystalline silica 238-878-4 14808-60-7 60-100
3.2 Mixtures
Not applicable
CommentsIARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz orcristobalite from occupational sources causes cancer in humans. IARC Classification Group I.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
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Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsReact with hydrofluoric acid (HF) forming toxic gas (SiF4).
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
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The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning upVacuum up. Avoid generating dust. Put into suitable containers for disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Donot breathe dust. For personal protection see section 8.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Provide appropriate exhaust ventilation at places where dust is formed. Keep airborneconcentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Store away fromincompatibles, React with hydrofluoric acid (HF) forming toxic gas (SiF4) Strong oxidizingagents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptQuartz, Crystalline silica 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined
Chemical Name India Indonesian Japan
Quartz, Crystalline silica Not determined 0.1 mg/m3 TWA Not determined
Chemical Name Kazakhstan Kuwait New Zealand
Quartz, Crystalline silica 1 mg/m3 MAC Not determined 0.1 mg/m3 TWAConfirmed carcinogen
Chemical Name Malaysia Philippines Russia
Quartz, Crystalline silica 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
Fibrogenic substanceglass;regulated under Quartz 1123,
1124
Chemical Name Thailand Vietnam Turkey
Quartz, Crystalline silica 0.025 mg/m3 TWA Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety goggles
Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Repeated orprolonged contact Use protective gloves made of: Nitrile Neoprene gloves Frequent changeis advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Suitable mask withparticle filter P3 (European Norm 143) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact. Eye wash andemergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Granules
Odor Odorless
Color Tan or White
Odor threshold Not applicable
Physical state Solid
Property Values Remarks pH Not applicable
pH @ dilution N/A
Melting / freezing point > 1700 °C / 3092 °F
Boiling point/range No information available
Flash point Not applicable
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
Explosive properties Not applicable
Oxidizing properties None known.
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
Hazardous ReactionsNone known.
10.4 Conditions to avoid
Avoid dust formation.
10.5 Incompatible materials
Hydrofluoric acid (HF). Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure No information available
Vapor density No information available
Specific gravity 2.50 - 2.70 @20 °C
Bulk density 1100- 1600 kg/m3
Relative density No information available
Water solubility Insoluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
log Pow No information available
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause respiratory irritation. Repeated or prolonged inhalation of crystallinesilica dust can cause delayed lung injury, and other diseases, including silicosis and lungcancer.
Eye contact Dust may cause mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Quartz, Crystalline silica = 500 mg/kg ( Rat ) No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC inGroup 1 as known to cause lung cancer in humans, if inhaled.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Category 2.
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
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Toxicity to algae
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
This product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates
Quartz, Crystalline silica No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
12.4 Mobility
MobilityThe product is insoluble and sinks in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
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Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)
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Silica Flour D66 SDS no. D066
Revision date 13-Jul-2017
The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes date 20-Oct-2014
Revision date 13-Jul-2017
Version 2
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.
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SDS no. D075
Version 4
Revision date 19-Sep-2018
Supersedes Date: 09-Apr-2014
Safety Data SheetSilicate Additive D75
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Silicate Additive D75
Product code D075
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
_____________________________________________________________________________________________
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsContact with metals may evolve flammable hydrogen gas.
Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills andsplashing during use. Do not breathe vapors or spray mist.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep at temperaturesabove > 32F /0°C Avoid contact with: Strong acids Metals Aluminum Zinc Steel
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
Packaging materials to be avoided Metal Aluminium Zinc Steel
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety goggles
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employeetraining Impervious gloves made of: PVC Rubber Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Chemical respiratorwith inorganic vapour cartridge (Grey B). At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
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_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solution
Odor Odorless
Color Colorless
Odor threshold Not applicable
Explosive properties No information available
Oxidizing properties No information available
9.2 Other information Pour point No information available
Molecular weight No information available
VOC content(%) No information available
Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
Physical state Liquid
Property Values Remarks pH 11
pH @ dilution No information available
Melting / freezing point - 1 °C / 30 °F
Boiling point/range 101 °C / 214 °F
Flash point Not applicable
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure <1 kPa
Vapor density No information available
Specific gravity 1.3 - 1.6 @ 20 °C
Bulk density No information available
Relative density No information available
Water solubility Soluble in water
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity 10-10000 mPa s
log Pow No information available
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Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
10. Stability and Reactivity
10.1 Reactivity
Contact with metals may evolve flammable hydrogen gas.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep at temperatures above > 32°F / 0°C.
10.5 Incompatible materials
Aluminum. Zinc. Metals. Strong acids. Steel.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
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Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
Routes of entry None known.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
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Not classified as PBT/vPvB by current EU criteria.
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Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
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Australian Standard for the Uniform Scheduling of Drugs and Poisons
_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
No poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Complies
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 09-Apr-2014
Revision date 19-Sep-2018
Version 4
This SDS has been revised in thefollowing section(s)
15, 16 There have been changes with regard to classification.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1Flammability 1Physical hazard 0PPE B
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_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075
Revision date 19-Sep-2018
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D168
Version 4
Revision date 23-Mar-2018
Supersedes Date: 19-Feb-2015
Safety Data SheetUNIFLAC* L D168
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name UNIFLAC* L D168
Product code D168
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors Nitrogen oxides (NOx), Sulphur oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Contaminated surfaces will be extremely slippery. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and Storage
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide sufficient air exchange and/or exhaust in work rooms.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store above freezingtemperature Store away from incompatibles, Oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsProvide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety goggles
Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employeetraining Impervious gloves made of: Butyl Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash andemergency shower must be available at the work place.
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_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solution
Odor Odorless
Color White - Light yellow
Odor threshold Not applicable
Explosive properties No information available
Oxidizing properties Not applicable
9.2 Other information Pour point -6°C / 21.2 °F
Molecular weight No information available
VOC content(%) None
Density 1.06 g/cm³ (20°C)
Comments
Physical state Liquid
Property Values Remarks pH 7 @ 20 °C
pH @ dilution 10 g/l
Melting / freezing point 0 °C / 32 °F
Boiling point/range 100 °C / 212 °F
Flash point Not applicable
Evaporation rate (BuAc =1) Similar to water.
Flammability (solid, gas) Not applicable
Flammability Limit in Air
Upper flammability limit Not applicable
Lower flammability limit Not applicable
Vapor pressure 2.34 kPa @ 20 °C
Vapor density No information available
Specific gravity 1.06 g/cm3 @ 20 °C
Bulk density No information available
Relative density No information available
Water solubility Miscible with water.
Solubility in other solvents No information available
Autoignition temperature 500 °C / 932 °F
Decomposition temperature 260 °C / 500 °F
Kinematic viscosity No information available
Dynamic viscosity 2000 - 4000 mPa s
log Pow No information available
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_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
The data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact. Inhalation.
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_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
Routes of entry No route of entry noted.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilityThe product is miscible with water. May spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated
IMDG/ANTAQ Hazard class Not regulated
ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
IMDG/ANTAQ Packing group Not regulated
ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
_____________________________________________________________________________________________
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Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
New Zealand Hazard Classification Not classified
HSNO approval no. Not applicable
Group number Not applicable
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies
Canada (DSL) Complies
Philippines (PICCS) Does not comply
Japan (ENCS) Complies
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Does not comply
New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 19-Feb-2015
Revision date 23-Mar-2018
Version 4
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
_____________________________________________________________________________________________
Page 9 / 10
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168
Revision date 23-Mar-2018
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
Page 10 / 10
SAFETY DATA SHEET
QUIK-GEL GOLD®
Revision Date: 31-Aug-2016 Revision Number: 10
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name QUIK-GEL GOLD®
Other means of Identification
Synonyms NoneHazardous Material Number: HM006323
Recommended use of the chemical and restrictions on use Recommended Use ViscosifierUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300
Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719
Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
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_____________________________________________________________________________________________QUIK-GEL GOLD® Revision Date: 31-Aug-2016
Classification of the hazardous chemical
Carcinogenicity Category 2 - H351
Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373
Label elements, including precautionary statements
Hazard pictograms
Signal Word Warning
Hazard Statements: H351 - Suspected of causing cancer if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Precautionary Statements
Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required
Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
ContainsSubstances CAS NumberCrystalline silica, quartz 14808-60-7Crystalline silica, cristobalite 14464-46-1Crystalline silica, tridymite 15468-32-3
Other hazards which do not result in classification None known
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 2 (H351)STOT RE 1 (H372)
Crystalline silica, cristobalite 14464-46-1 0.1 - 1% Carc. 2 (H351)STOT RE 1 (H372)
Crystalline silica, tridymite 15468-32-3 0.1 - 1% Carc. 2 (H351)STOT RE 1 (H372)
4. First aid measures
Description of necessary first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
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irritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure
Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireNot applicable
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationDo not reuse empty container. Use good housekeeping in storage and work areas to prevent accumulation of dust. Close containerwhen not in use. Keep from excessive heat. Product has a shelf life of 24 months.
Other GuidelinesNo information available
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8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits
Substances CAS Number Australia NOHSC ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Crystalline silica, cristobalite 14464-46-1 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Crystalline silica, tridymite 15468-32-3 TWA: 0.1 mg/m3 TWA: 0.05 mg/m3
Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 8.5-9.5 (3%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.5 - 2.6
Water Solubility Partly soluble
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Physical State: Powder Color Tan
Odor: Mild earthy Odor Threshold:
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No information available
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10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.
10.2. Chemical stability Stable
10.3. Possibility of hazardous reactions Will Not Occur
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Hydrofluoric acid.
10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure
Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No information available No data available
Crystalline silica,cristobalite
14464-46-1 > 15000 mg/kg (human) (similarsubstance)
No information available No data available
Crystalline silica,tridymite
15468-32-3 >15,000 mg/kg (Human) No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimental
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animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.
Exposure LevelsNo data available
Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the skin
Crystalline silica, cristobalite 14464-46-1 Non-irritating to the skin
Crystalline silica, tridymite 15468-32-3 Non-irritating to the skin
Substances CAS Number Serious eye damage/irritationCrystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible. No information available
Crystalline silica, cristobalite 14464-46-1 Mechanical irritation of the eyes is possible.
Crystalline silica, tridymite 15468-32-3 Mechanical irritation of the eyes is possible.
Substances CAS Number Skin SensitizationCrystalline silica, quartz 14808-60-7 No information available.
Crystalline silica, cristobalite 14464-46-1 No information available
Crystalline silica, tridymite 15468-32-3 No information available
Substances CAS Number Respiratory SensitizationCrystalline silica, quartz 14808-60-7 No information available
Crystalline silica, cristobalite 14464-46-1 No information available
Crystalline silica, tridymite 15468-32-3 No information available
Substances CAS Number Mutagenic EffectsCrystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Crystalline silica, cristobalite 14464-46-1 Not regarded as mutagenic.
Crystalline silica, tridymite 15468-32-3 Not regarded as mutagenic.
Substances CAS Number Carcinogenic EffectsCrystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.
Crystalline silica, cristobalite 14464-46-1 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.
Crystalline silica, tridymite 15468-32-3 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, this
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substance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.
Substances CAS Number Reproductive toxicityCrystalline silica, quartz 14808-60-7 No information available
Crystalline silica, cristobalite 14464-46-1 No information available
Crystalline silica, tridymite 15468-32-3 No information available
Substances CAS Number STOT - single exposureCrystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Crystalline silica, cristobalite 14464-46-1 No significant toxicity observed in animal studies at concentration requiring classification.
Crystalline silica, tridymite 15468-32-3 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposureCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Crystalline silica, cristobalite 14464-46-1 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Crystalline silica, tridymite 15468-32-3 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CAS Number Aspiration hazardCrystalline silica, quartz 14808-60-7 Not applicable
Crystalline silica, cristobalite 14464-46-1 Not applicable
Crystalline silica, tridymite 15468-32-3 Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity to Invertebrates
Crystalline silica,quartz
14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum
capricornutum)
LL0 (96 h) =10000 mg/L(Danio rerio)
No information available LL50 (24 h) >10000 mg/L(Daphnia magna)
Crystalline silica,cristobalite
14464-46-1 No information available LL0 (96 h) 10000 mg/L(Danio rerio)
No information available LL50 (24 h) >10000 mg/L(Daphnia magna)
Crystalline silica,tridymite
15468-32-3 No information available LL0 (96h) 10,000mg/L(Danio rerio) (similar
substance)
No information available LL50 (24h) > 10,000 mg/L(Daphnia magna) (similar
substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability arenot applicable to inorganic substances.
Crystalline silica, cristobalite 14464-46-1 The methods for determining biodegradability arenot applicable to inorganic substances.
Crystalline silica, tridymite 15468-32-3 The methods for determining biodegradability arenot applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Crystalline silica, quartz 14808-60-7 No information available
Crystalline silica, cristobalite 14464-46-1 No information available
Crystalline silica, tridymite 15468-32-3 No information available
12.4. Mobility in soil
Substances CAS Number Mobility
Crystalline silica, quartz 14808-60-7 No information available
Crystalline silica, cristobalite 14464-46-1 No information available
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Crystalline silica, tridymite 15468-32-3 No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods If practical, recover and reclaim, recycle, or reuse by the guidelines of an approved local reuse program. Should contaminatedproduct become a waste, dispose of in a licensed industrial landfill according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code
None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.
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Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply
Stolkhom Convention - Persistent Organic Pollutants: Does not apply
Rotterdam Convention - Prior Informed Consent: Does not apply
Basel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 31-Aug-2016
Revision Note
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
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Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
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End of Safety Data Sheet
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SAFETY DATA SHEET
QUIK MUD®
Revision Date: 01-Jul-2016 Revision Number: 6
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name QUIK MUD®
Other means of Identification
Synonyms NoneHazardous Material Number: HM005333
Recommended use of the chemical and restrictions on use Recommended Use Shale Inhibitor; ViscosifierUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
Classification of the hazardous chemical
Specific Target Organ Toxicity - (Single Exposure) Category 3 - H336
Label elements, including precautionary statements
Hazard pictograms
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Signal Word Warning
Hazard Statements: H336 - May cause drowsiness or dizziness
Precautionary Statements
Prevention P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP271 - Use only outdoors or in a well-ventilated area
Response P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER/doctor/physician if you feel unwell
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
ContainsSubstances CAS NumberHydrotreated light petroleum distillate 64742-47-8
Other hazards which do not result in classification None known
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Hydrotreated light petroleum distillate 64742-47-8 10 - 30% STOT SE 3 (H336)Asp. Tox. 1 (H304)
4. First aid measures
Description of necessary first aid measures
Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to preventaspiration. Rinse mouth. Never give anything by mouth to an unconscious person.
Symptoms caused by exposure
May cause headache, dizziness, and other central nervous system effects.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
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5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Use water spray to cool fire exposed surfaces.
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing beforereuse. Material is slippery underfoot.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use. Product has a shelf life of 12 months.
Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits
Substances CAS Number Australia NOHSC ACGIH TLV-TWAHydrotreated light petroleum distillate 64742-47-8 Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator
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is recommended:Organic vapor respirator with a dust/mist filter. (A2P2/P3)
Hand Protection Impervious rubber gloves. Polyvinylchloride gloves. Nitrile gloves.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 5
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range 105 °C / 221 °F
Flash Point No data available PMCC
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.1
Water Solubility Dispersible
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.
10.2. Chemical stability Stable
10.3. Possibility of hazardous reactions Will Not Occur
10.4. Conditions to avoid Keep away from heat, sparks and flame.
10.5. Incompatible materials Strong oxidizers. Contact with copper. Prolonged contact with aluminum. Mild steel.
10.6. Hazardous decomposition products Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure
Most Important Symptoms/EffectsMay cause headache, dizziness, and other central nervous system effects.
Physical State: Liquid Color White to off white
Odor: Mild hydrocarbon Odor Threshold:
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No information available
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Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Hydrotreated lightpetroleum distillate
64742-47-8 >5000 mg/kg-bw (rat) (similarsubstance)
>2000 mg/kg-bw (rabbit) (similarsubstance)
>5.2 mg/L (rat, 4 h, vapor)(similar substance)
Immediate, delayed and chronic health effects from exposure Inhalation May cause central nervous system depression including headache, dizziness, drowsiness,
incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.
Eye Contact Non-irritating to rabbit's eye
Skin Contact Not irritating to skin in rabbits.
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing, difficultybreathing, wheezing, coughing up blood and pneumonia, which can be fatal. May causecentral nervous system depression including headache, dizziness, drowsiness, muscularweakness, incoordination, slowed reaction time, fatigue blurred vision, slurred speech,giddiness, tremors and convulsions.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects Lung disorders.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationHydrotreated light petroleumdistillate
64742-47-8 Non-irritating to the skin (similar substances)
Substances CAS Number Serious eye damage/irritationHydrotreated light petroleumdistillate
64742-47-8 Non-irritating to rabbit's eye (similar substances)
Substances CAS Number Skin SensitizationHydrotreated light petroleumdistillate
64742-47-8 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Substances CAS Number Respiratory SensitizationHydrotreated light petroleumdistillate
64742-47-8 No information available
Substances CAS Number Mutagenic EffectsHydrotreated light petroleumdistillate
64742-47-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)
Substances CAS Number Carcinogenic EffectsHydrotreated light petroleumdistillate
64742-47-8 Did not show carcinogenic effects in animal experiments (similar substances)
Substances CAS Number Reproductive toxicityHydrotreated light petroleumdistillate
64742-47-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)
Substances CAS Number STOT - single exposureHydrotreated light petroleumdistillate
64742-47-8 May cause disorder and damage to the Central Nervous System (CNS) (similar substances)
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Substances CAS Number STOT - repeated exposureHydrotreated light petroleumdistillate
64742-47-8 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CAS Number Aspiration hazardHydrotreated light petroleumdistillate
64742-47-8 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,wheezing, coughing up blood and pneumonia, which can be fatal.
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity to Invertebrates
Hydrotreated lightpetroleum distillate
64742-47-8 EC50 (72h) > 1,000 mg/L(Skeletonema costatum)ErL50 (72h) > 1000 mg/L
(Pseudokirchneriellasubcapitata)
EbL50 (72h) > 1000 mg/L(Pseudokirchneriella
subcapitata)NOELR (72h) 1000 mg/L
(Pseudokirchneriellasubcapitata)
LC50 (96h) > 10,000mg/L (Scophthalmus
maximus)LL50 (96h) > 1000 mg/L(Oncorhynchus mykiss)
No information available LC50 (48h) > 10,000mg/L (Acartia tonsa)
EC50 (48h) 1100 mg/L(Daphnia pulex)
LC50 (48h) 0.12 mg/L(Daphnia magna)
EL50 (48h) > 1000 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Hydrotreated light petroleum distillate 64742-47-8 Readily biodegradable (40% @ 28d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Hydrotreated light petroleum distillate 64742-47-8 Log Pow Weighted Average7.5
12.4. Mobility in soil
Substances CAS Number Mobility
Hydrotreated light petroleum distillate 64742-47-8 No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
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_____________________________________________________________________________________________QUIK MUD® Revision Date: 01-Jul-2016
Transportation Information Australia ADG
UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code
None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product does not comply with EINECS
US TSCA Inventory All components listed on inventory or are exempt.
Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply
Stolkhom Convention - Persistent Organic Pollutants: Does not apply
Rotterdam Convention - Prior Informed Consent: Does not apply
Basel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 01-Jul-2016
Revision NoteSDS sections updated: 2
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_____________________________________________________________________________________________QUIK MUD® Revision Date: 01-Jul-2016
Full text of H-Statements referred to under sections 2 and 3H304 - May be fatal if swallowed and enters airwaysH336 - May cause drowsiness or dizziness
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
PAC™-R
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name PAC™-R
Other means of Identification
Synonyms: NoneProduct Code: HM003725
Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss Additive
Uses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300
Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719
Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111
E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous
_____________________________________________________________________________________________
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Revision Date: 21-Sep-2015 Revision Number: 21
_____________________________________________________________________________________________Goods according to the criteria of ADG.
Classification of the hazardous chemical
Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification Dust can form an explosive mixture in airThis substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not Classified
Risk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratoryirritation develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15minutes and get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure
No significant hazards expected.
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Revision Date: 21-Sep-2015PAC™-R
_____________________________________________________________________________________________
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid creating or inhaling dust. Avoid dust accumulations. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Slippery when wet. Use appropriate protective equipment.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Product has a shelf life of 36 months.
Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure Limits
Substances CAS Number Australia NOHSC ACGIH TLV-TWA
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls
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PAC™-R Revision Date: 21-Sep-2015
_____________________________________________________________________________________________
Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used inareas without good cross ventilation.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 6.5-9 (1%)
Freezing Point/Range No data available
Melting Point/Range No data available
Boiling Point/Range No data available
Flash Point 221 °C / 430 °F
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.6
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 400 °C / 752 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Bulk Density 40-55 lbs/ft3
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.
10.2. Chemical Stability Stable
10.3. Possibility of Hazardous Reactions Will Not Occur
10.4. Conditions to Avoid None anticipated
10.5. Incompatible Materials Strong oxidizers.
10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.
_____________________________________________________________________________________________
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PAC™-R
Color: White to off white
Revision Date: 21-Sep-2015
Odor: Odorless Odor Threshold: No information availablePhysical State: Solid Powder
_____________________________________________________________________________________________
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure
Most Important Symptoms/EffectsNo significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.
Eye Contact May cause mild eye irritation.
Skin Contact May cause mild skin irritation.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritation
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Eye damage/irritation
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Skin Sensitization
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Respiratory Sensitization
Contains no hazardous NA Not applicable
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PAC™-R Revision Date: 21-Sep-2015
_____________________________________________________________________________________________substances inconcentrations above cut-offvalues according to thecompetent authority
Substances CAS Number Mutagenic Effects
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Carcinogenic Effects
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Reproductive toxicity
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - single exposure
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - repeated exposure
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Aspiration hazard
Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
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Revision Date: 21-Sep-2015PAC™-R
_____________________________________________________________________________________________
Substances CAS Number Persistence and Degradability
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil Disperses rapidly in airSubstances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Special precautions during transport None
HazChem Code
None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.
Canadian DSL Inventory All components listed on inventory or are exempt.
_____________________________________________________________________________________________
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PAC™-R Revision Date: 21-Sep-2015
_____________________________________________________________________________________________
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 21-Sep-2015
Revision NoteSDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3None
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 8 / 8
Revision Date: 21-Sep-2015PAC™-R