APPENDIX I

POSTERS and OTHER PRESENTATIONS

POSTER PRESENTATIONS

Phase equilibria / Modeling

P. J. Smits, J. Gregerowicz, J. W. Shaw, Th. de Loos and J. de Swaan Arons, Complex phase behavior in three-component model reservoir fluids. Unusual retrograde condensation of the heavy liquid phase

C. J. Gregg, F. P. Stein and M. Radosz, Phase equilibria of associating mono- and ditelechelic polyisobutylenes in sub- and supercritical polar and non-polar fluids

N. Van Nhu and F. Kohler, The mixture methane + ethane: Excess properties and phase equilibria calculated from a generalized van der Waals equation of state

G. A. Iglesias-Silva, J. C. Hostle and K. R. Hall, (JE Modelfor multicomponent mixtures

G. X. Jin, A. van Pelt and J. V. Sengers, Critical fluctuations and classical equations of state

M. Gencaslan, P. H. E. Meijer, M. Keskin, and A. H L. Levelt, Closed loops in phase diagrams

P. H. E. Meijer, Generalized Korteweg equatiOns for phase separation near the critical point in binary gas-liquid mixtures

J. R Boulton and F. P. Stein, The constant pressure heat capacity of supercritical mixtures: Carbon dioxide / Acetone

H. A. Matos, M. A. Costa, E. G. de Azevedo and M. N. da Ponte, Ternary phase eqUilibria involving ethylene, 1,8-cineole and d-limonene at 288 and 298 K

P. J. Pereira and M. N. da Ponte, Phase equilibriafor the system carbon dioxide +glycidol in the supercritical region

S. Platin, E. o. Ozer, U. Akman and O. Hortaesu, Equilibrium and extraction studies on the spearmint oil - carbon dioxide system

Spectroscopy / Reactions / Transport

H. Oehel and G. M. Schneider, Near-infrared spectroscopic investigations on phase behavior and dimerization of dodecanoic acid, hexadecanoic acid, d-valerolactam and e­caprolactam in supercritical chlorotrijluoromethane

V. K. Popov, J. A. Banister and M. Poliakoff, Probing supercriticalfluid mixtures using acoustic and photoacoustic methods

775

776

C. B. Roberts, J. Zhang, J. F. Brennecke and J. E. Chateauneut: Laser flash photolysis investigation of diffusion controlled reactions in supercritical fluids

M. C. Bellissent-Funel, U. Buontempo, A. Filabozzi, M. Nardone, and F. P. Ricci, Structure of the He-Xe mixtures near 30 MPa demixing curve at 294 K

M. C. Bellissent-Funel, A. Filabozzi, M. Nardone, F. P. Ricci and M. A. Ricci, Quantum effects in the structure of dense supercritical flUid helium.

J. Luettmer-Strathmann and J. V. Sengers, Transport properties offluids in the critical region

J. A. Banister, M. Poliakoff and S. M. Howdle, Synthetic chemistry in a small-scale supercritical flUid flaw reactor.

M. L. S. Matos Lopes, C. A. Nieto de Castro and J. V. Sengers, Mutual diffusivity of liquid binary mixtures near a critical consolute point.

Computer Simulations

A. A. Chialvo, T award a molecular-based understanding of solute-induced local density, mixed-solute and entrainer effects in dilute near-critical mixtures

P. B. Balbuena, K P. Johnston and P. Rossky, Theory of the effect of a supercritical solvent on a chemical reaction

J. M. Seminario and P. Politzer, Effect of supercritical water on d: A combined DFT and MD approach

Natural Materials

F. Temelli, E. LeBlanc and L. Lu, Supercritical carbon dioxide extraction of oil from atlantic mackerel (Scomber scrombus) and evaluation of protein functionality

M. Goto, M. Sato and T. Hirose, Kinetic study for supercriticalfluid extraction of natural materials

P. C. Simoes and M. N. da Ponte, Mass transfer models in supercritical extraction of natural oils

P. J. P. Carmelo, M. N. da Ponte, Feasibility of super critical fluid extraction to deaCidification of olive oils without affecting their triglyceride content

E. Kiran and H. Balkan, High-pressure extraction and delignification of red spruce with binary and ternary mixtures of acetic acid, water, and carbon dioxide

A. s. Reis Machado, R M. Sardinha, E. G. de Azevedo, and M. N. da Ponte, High pressure de lignification of eucalyptus wood using carbon dioxide containing mixtures

777

J. A. P. Coelho, R L. Mendes, J. M. Novais, S. Cabral, F. Venancio, S. C. Frazao and A F. Palavra, Supercritical fluid extraction from Portuguese Rosemary with carbon dioxide

M. Baptista, AL. Cardoso, M. G. Bernardo-Gil and M. L. Beirao da Costa, SCF extraction of aroma compounds from coriander leaves and rosemary

N. Adasoglu, E. Bolat and S. Dincer, Supercritical fluid extraction of essential oils from lavender flowers

Special Topics

S. Sarra de, G. M. Rios, R Veyre and R Soria, Supercritical carbon dioxide extraction coupled with nanofiltration separation. Interest and preliminary studies

M. A. Zbiec, Application of supercritical fluid extraction for pesticide residue in food analysis

S. Pekyardimci and M. Balaban, Enzyme inactivation by supercritical carbon dioxide

G. Karakas, T. G. Somer, and T. Dogu, Conversion of heavy paraffins to carboxylic acids with carbon dioxide under supercritical conditions

U. Akman and A K Sunol, Supercritical exsorption. Simultaneous sorption and extraction under supercritical-jluid conditions

M. Canel, Extraction of solid fuels with water in sub and supercritical states

M. B. King, J. R Bolt, A Lyddiatt, D. Butler and T. J. Lu, On-going work with supercritical and marginally subcritical fluids at Birmingham, United Kingdom

E. S. Vayisoglu, D. Erbatur, N. G. Erbatur, B. Frere, K D. Bartle and C. E. Snape, Chromatographic and spectroscopic investigation of the supercritical toluene extracts of the maceral concentrates of coals.

OTHER (ORAL) PRESENTATIONS

A. Kruse, H. J. BIeyl and K H. Ebert, First results of the pyrolysis of tert-butylbenzene in supercritical water

Yu. B. Mel'nichenko, Criticalfluctuations in polymer solutions: crossover between tricritical and fluctuation regimes

APPENDIXll

LIST OF PARTICIPANTS

Par

tici

pant

s

(I)

Lom

ba;

(2)

Mer

oni;

(3)

Cum

min

gs;

(4)

Ebe

rt;

(5)

Frit

zer;

(6)

O'C

onne

ll;

(7)

Ric

ci;

(8)

Mel

'nic

henk

o; (

9) D

orey

; (1

0)

deL

oos;

(II

) B

runn

er; (

12)

Rot

h; (

13)

Pete

rs;

(14)

Ful

le;

(15)

Cli

ffor

d; (

16)

Sem

inar

io;

(17)

Ves

ovic

; (1

8) L

uettm

er-S

trat

hman

n;

(19)

Och

el;

(20)

Ast

rid

Kle

intje

ns;

(21)

Bub

ack;

(22

) va

n Pe

lt; (

23)

Giv

en;

(24)

Ste

in;

(25)

Chi

alvo

; (2

6) S

chne

ider

; (2

7) C

anel

; (2

8) G

regg

; (2

9) S

arra

de; (

30)

Tut

kun;

(31

) C

arm

elo;

(32

) O

rbey

; (3

3) A

daso

glu;

(34

) M

atos

; (3

5) O

. E

rbat

ur;

(36)

Sim

oes;

(37

) C

oelh

o; (

38)

Akm

an;

(39)

Mei

jer;

(40

) Pl

atin

; (4

1) N

avar

o; (

42)

Ber

nard

o-G

il; (

43)

Zbi

ec;

(44)

Kru

se;

(45)

Bra

nd;

(46)

Pet

er;

(47)

Bal

buen

a; (

48)

Popo

v; (

49)

Ves

ovic

; (5

0) P

inhe

iro;

(51

) Sa

ndle

r; (

52)

Peky

ardi

mci

; (5

3) J

. Sen

gers

; (54

) B

alka

n; (

55)

Page

; (5

6) G

okm

enog

lu;

(57)

Tem

elli;

(58

) H

eide

man

n; (

59)

Ari

n; (

60)

Kin

g; (

61)

Lev

elt

Sen

gers

(A

nnek

e);

(62)

G.

Erb

atur

; (6

3)

Bol

at;

(64)

Got

o; (

65)

Cal

imli;

(66

) V

an N

hu;

(67)

Mac

hado

; (6

8) G

onca

lves

; (6

9) E

squi

vel;

«7

0)

Deb

ened

etti;

(71

) Pe

reir

a;

(72)

Xio

ng;

(73)

Rob

erts

; (7

4) S

mits

; (7

5) B

anis

ter;

(76

) H

owdl

e; (

77)

Ant

a; (

78)

Kap

lan;

(79

) L

emer

t; (

80)

L. K

lein

tjens

; (8

\)

Kir

an;

(82)

Kar

akas

; (8

3) H

orta

csu;

(84

) G

enca

rsla

n; (

85)

Sim

sek;

(86

) E

rol;

(87)

Pan

agio

topo

ulos

; (8

8) A

vara

nas;

(89

) L

opes

; (9

0) K

eski

n.

(Mis

sing

from

the

pic

ture

are

Akg

erm

an, D

emir

ciog

lu, H

all,

Lee

, Pan

do, R

ados

z, R

enun

cio

and

Suno

l).

LIST OF ALL PARTICIPANTS

Canada

R. A. HEIDEMANN

Feral TEMELLI

France

Stephane SARRADE

Germany

Gerd BRUNNER

Michael BUBACK

Klaus EBERT

DirkFULLE

Andrea KRUSE

Yuri B. MEL'NICHENKO

HenningOCHEL

Siegfried PETER

University oj Calgary, Chemical Engineering Department, Calgary, Alberta T2 NIN4, CANADA

University oj Alberta, Department oj Foods Science and Nutrition, Edmonton, Alberta, CANADA T6G 2MB

Laboratoire de Genie des Procedes, Universite Montpellier II - USTL -CC023, Place Eugene Bataillon, 34095 Montpellier Cedex 05, FRANCE

Technische Universitiit Hamburg-Harburg, AB Veifahrenstechnik II, Eicsendoifer Strasse 3B, 27077 Hamburg, GERMANY

Institute for Physikalische Chemie, Universitiit Gottingen, Tammannstrasse 6, D-37077 Gottingen, GERMANY

Institute for Heisse Chemie, Kernjorschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, GERMANY

Inst. for Physikalische Chemie d. Universitiit Gottingen, Tammannstr. 6, 37077 Gottingen, GERMANY

Kernjorschungszentrum Karlsruhe, Institute for Heisse Chemie Postfach 3640, H7602I Karlsruhe, GERMANY

Max Planck Institute jor Polymer Research, Postfach 314B, 55021 Mainz, GERMANY

Lehrstuhl for Physikalische Chemie II, Ruhr Universitiit Bochum, Universitaetsstr. 150 D-447BO Bochum 1, GERMANY

Institute for Technische Chemie II, Universitiit Erlangen- Nurnberg, Egerlandstr. 3, D-B520-Erlangen, GERMANY

783

784

Gerhard M. SCHNEIDER

Nguyen VAN NHU

Greece

Antonis A VRANAS

Italy

Alberto MERONl

Francesco Paolo RICCI

Netherlands

Ludo A. L. KLEINTJENS,

Theodoor Willem de LOOS

Comelis J. PETERS

Peter Jan SMITS

Portugal

Maria G. BERNARDO-GIL

Ruhr-Universitiit Bochum, Lehrstuhlfor Physikalische Chemie 11, D-44780 Bochum, GERMANY

Institutfor Thermo-und Fluiddynamik, Ruhr Universitiit Bochum, 44780 Bochum, GERMANY

Department of Chemistry, Aristotle University, 54006, Thessaloniki, GREECE

Dipartimento di Fisica, Universita Degli Studi di Milano, Via Celoria, 16, 20133 Milano, ITALY

Departimento di Fisica, Universita degli Studi di Roma "La Sapienza", PIazzale AldoMoro, 2,0015 Roma, ITALY

DSM Reseach, P.G. Box 18, 6160MD Geleen The NETHERLANDS

Laboratory of Applied Thermodynamics and Phase Equilibria, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The NETHERLANDS

Delft University of Technology, Applied Thermodynamics and Phase Equilibria, Julianalaan 136, 2628 BL Delft, The NETHERLANDS

Laboratory of Applied Thermodynamics and Phase Equlibria, Technical University of Delft, Julianalaan 136, 2628 BL Delft, The NETHERLANDS

Department of Chemical Engineering, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL

Paulo J. P. CARMELO

Jose A. P. COELHO

Maria M. L. T. ESQUIVEL

Maria M. B. P. GONCALVES

Manuel L. S. M. LOPES

Ana S. R. MACHADO

Henrique A. S. MATOS

Paulo J. A. PEREIRA

Lidia M. V. PINHEIRO

Pedro M. C. SIMOES

Spain

Juan Antonio ANT A

Enrique LOMBA

Concepcion PANDO

Juan A. Rodriguez RENUNCIO

785

Department oj Chemistry Lab-108, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL

Department oj Chemical Engineering, Instituto Superior Tecnico, Complexo -1, Av. Ravisco Pais, 1096 Lisboa Codex, PORTUGAL

Department oj Chemical Engineering, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL

Department ojChemistry, Faculd.ade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL

Department oj Chemistry, Faculty oj Sciences, University ojLisbon, Campo Grande, Edificio Cl, Piso 5, 1700 Lisboa, PORTUGAL

Centro de Tecnologia Quimica e Biologica, Rua da Quinta Grande 6, Apartado 127, 2780 Oeiras, PORTUGAL

Centro Quimico Estrutural, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL

Department oj Chemistry- Lab. 108, Faculd.ade de Ciencias e Tecnologia, Universid.ade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL

Faculdade de Farmacio de Lisboa, Universidade de Lisboa, Avenida das Forcas Armadas, 1600, Lisboa, PORTUGAL

Department ojChemistry, Universidade Nova de Lisboa 2825 Monte de Caparica, PORTUGAL

Instituto de Quimica Fisica Rocasolano, CSIC, Calle Serrano 119, E-28006Madrid, SPAIN

Instituto de Quimica Fisica Rocasolano, CSIC, Calle Serrano 119, E-28006Madrid, SPAIN

Facultad de Quimica, Universidad Complutense, E-28040Madrid, SPAIN

Facultad de Quimica, Universitad Complutense, E-28040 Madrid, SPAIN

786

Turkey

Nalan ADASOGLU

S. Ugur AKMAN

GonencARIN

Hiilya BALKAN

EsenBOLAT

Ayla CALIMLI

Muammer CANEL

Mustafa DEMIRCIOGLU

GayeERBATUR

Oktay ERBATUR

Murat Ismet EROL

Mustafa GENCASLAN

Oner HORTACSU

Giirkan KARAKAS

Mustafa KESKlN

OrliNAVARO

HasanORBEY

Yildiz Technical University, Chemical &Metallurgical Faculty, Chemical Engineering Department, Sisli, Istanbul, TURKEY

Department of Chemical Engineering, Bogazici University, Bebek 80815, Istanbul, TURKEY

Chemical Engineering Department, Gazi University, Maltepe, Ankara, TURKEY

SEKA, Research & Development DiviSion, lzmit, Kocaeli, TURKEY

Chemical & Metallurgical Engineering Faculty, Chemical Engineering Department, Yildiz Technical University, Sisli, Istanbul., TURKEY

Department of Chemical Engineering, Ankara University, 06100, Tandogan, Ankara, TURKEY

Department of Chemistry, Ankara University, Besevler­Ankara, TURKEY

Department of Chemical Engineering, Ege University 35100 Bornova, lzmir, TURKEY

Department of Chemistry, Cukurova University, Adana 01330, TURKEY

Department of Chemistry, Cukurova University, Adana 01330, TURKEY

Department of Chemical Engineering, Ankara University, 06100 Tandogan, Ankara, TURKEY

Department of Physics, Erciyes University, 38039 Kayseri, TURKEY

Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY

Department of Chemical Engineering, Middle East Technical University, Inonil Bu/vari, 06531 Ankara, TURKEY

Department of Physics, Gaziosmanpasa University, Tokat, TURKEY

Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY

Department of Chemical Engineering, Middle East Technical University, Ankara, TURKEY

Sule PEKY ARDIMCI

Sevan PLATIN

Emir Huseyin SIMSEK

Osman TUTKUN

United Kingdom

James A. BANISTER

Anthony A. CLIFFORD

Steve HOWDLE

Muammer KAPLAN

Michael B. KING

Velisa VESOVIC

United States

Aydin AKGERMAN

Perla Beatriz BALBUENA

Jennifer Irene BRAND

Ariel Augusto CHIAL VO

787

Department of Chemistry, Ankara University, 06100 Tandogan, Ankara, TURKEY

Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY

Department of Chemical Engineering, Ankara University, 06100 Tandogan, Ankara, TURKEY

Chemical Engineering Division, TUBITAK - Marmara Research Center, P.K 21, 41470 Gebze- Kocaeli, TURKEY

Department of Chemistry, University of Nottingham, Nottingham Park, Nottingham NG7 2RD, UNITED KINGDOM

School of Chemistry, UniverSity of Leeds, Leeds LS2 9JT, UNITED KINGDOM

Department of Chemistry, University of Nottingham, Nottingham Park, Nottingham NG72RD, UNITED KINGDOM

Department ofChemisry, Nottingham University, Nottingham NG7 2RD, UNITED KINGDOM

School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2IT, UNITED KINGDOM

IUPAC Transport Properties Centre, Department of Chemical Engineering and Chemical Tech. Imperial College, London SW7 2AZ, UNITED KINGDOM

Texas A&M University, Chemical Engineering Department, College Station, Texas 77843-3122, USA

Department of Chemical Engineering, University of Texas, Austin, Texas 78712, USA

Department of Chemical Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588-0126, USA

Department of Chemical Engineering, UniverSity of Virginia, Charlottesville, VA 22903-2442, USA

788

Peter T. CUMMINGS University of Virginia, Department of Chemical Engineering, Charlottesville, VA 22903-2442, USA

Pablo G. DEBENEDETTI Princeton University, Chemical Engineering Department, Princeton, NJ 08544-5263, USA

Cameron DOREY Department of Chemistry, University of Central Arkansas, Conway, AR 72035, USA

James A. GIVEN NIST, Thermophysics Division, Gaithersburg, MD 20899, USA

Zeliha GOKMENOGLU Department of Chemical Engineering, University of Maine, Orono, Maine 04469, USA

Christopher James GREGG Department of Chemical Engineering, Lehigh University Bethlehem, PA 18015, USA

Kenneth Richard HALL Department of Chemical Engineering, Texas A &M University, College Station, Texas 77843, USA

Erdogan KIRAN Department of Chemical Engineering, University of Maine, Orono, Maine 04469-5737, USA

Lloyd L. LEE School of Chemical Engineering and Materials SCience, University of Oklahoma, Norman, OK 73019, USA

Richard Milo LEMERT Department of Chemical Engineering, University of Toledo, Toledo, Ohio 43606-3390, USA

Jutta LVETTMER-STRATHMANN Institute of Physical Science & Technology, University of Maryland, College Park, MD 20742-2431, USA

Mark A. McHUGH The Johns Hopkins University, Chemical Engineering Department,Baltimore, MD 21218, USA

Paul H. E. MEIJER PhysiCS Department, The Catholic University of America, Washington, D.C. 20064, USA

John P. O'CONNELL University of Virginia, Department of Chemical Engineering, Charlottesville, VA 22903-2442, USA

Steven H. PAGE NIST, Building 222/ B156, Gaithersburg, MD 20899, USA

A. Z. P ANAGIOTOPOULOS Cornell University, School of Chemical Engineering, Ithaca, New York 14853-5201, USA

Antonius van PELT Institute for Physical Science and Techn., University of Maryland, !PST Bldg. Room 2112, College Park, MD 20742-2431, USA

Maciej RADOSZ Corporate Research, Exxon Research & Engineering Co., Annandale, New Jersey 08801, USA

Christopher B. ROBERTS Department of Chemical Engineering, University of Notre Dame, Notre Dame, IN 46556, USA

Stanley I. SANDLER

Jorge M. SEMINARIO

J. M. H. LEVELT SENGERS

Jan V. SENGERS

Fred P. STEIN

Aydin K. SUNOL

YanXIONG

Non-Nato Countries

Harald Paulson FRITZER

Motonobu GOTO

V. K. POPOV

Michal ROTH

Maria Alexandra ZBIEC

University of Delaware, Chemical Engineering Department, Newark, DE 19716, USA

Department of Chemistry, University of New Orleans, New Orleans, Louisiana 7014B, USA

Thermophysics Division, NIST, Gaithersburg, MD 20B99, USA

789

Institute for Physical Science & Technology, University of Maryland, College Park, MD 20742, USA

Department of Chemical Engineering, Lehigh University, Bethlehem, PA IBOI5, USA

Department of Chemical Engineering, University of South Florida, Tampa, Florida 33620, USA

Department of Chemical Engineering, University of Maine, 5737 Jenness Hall, Orono, Maine 04469-5737, USA

Institute of Physical & Theoretical Chemistry, Graz University of Technology, Rechbauerstrasse 12, A-BOlO Graz, A USTRlA

Department of Applied Chemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto B60, JAPAN

Advanced Laser Technologies Dept., Scientific Research Center for Technological Lasers, Russian Academy of Sciences, Troitzk, Moscow Region, 742092, RUSSIA

Institute of Analytical Chemistry, Academy of Sciences of the Czech Republic, Vavery 97,61142 Brno, The CZECH REPUBLIC

Institute of Biotechnology of the Agricultural & Food Industry, Rakowiecka 36, Warsaw 02-532, POLAND

INDEX

Absorption equilibrium 678, 743, 745, 746, 753

Activation volume 465, 467

Activity coefficient models 153

Absorption spectroscopy 499, 500

Adsorption/desorption phenomena 670, 678,744

Alkanes 77,78,88,127,128,130,141,144

Alkanols 129,130

Alkylbenzenes 130

Alumina 707, 709-711, 714-716

Anti-solvent process 719, 725-728, 754

Argon 731

Association 129

Attractive mixtures 300, 301, 370, 439-442, 444

Axial dispersion coefficients 685

BACK 170

Barotropic phenomena 740

Binary interaction parameter 151, 159

Binary mixtures 13,49,75,100,118,127,132, 354, 570

Binodal 69, 567, 581, 593 Bioerodible polymers 723, 725

Bridge fimction 367

Butane 574, 608

Butanol 76

C-H activation 534, 535

Capacity ratio 103,106, 619

Carbon dioxide 78, 81, 88, 92-94, 100-106, 110, 112, 244, 247, 248, 251, 260, 261, 263-266, 278, 442-444, 510, 527-536, 595, 641-650, 731, 741, 742, 746-751

Carbon monoxide 509

Carboxylic acids 130

Carnahan-Starling 52, 110, 165, 167, 169, 262, 613

Ceramics 595, 707-717, 723

791

Chemical potential 370,417,424

Chitosan 565

Chromatography 653, 654

Classification of phase behavior 75,96, 98-102, 118, 119, 120

Closed solubility loop 99

Closure relation 292, 367

Cloud point 570, 591, 599, 601-607, 609, 610, 614,615

Combining rules 150,178,

Compressibility 3-6,10,20-21,93,147,216, 22~231,23~23~25~292,29~29~29~ 30~

303, 304, 342, 343, 345, 353, 358, 398, 399, 406, 439-441, 720, 753

Computer simulation 8, 29, 149, 163, 288, 354, 439, 442-444

Controlled drug delivery 719, 723-725

Copolymer 494,545,546,594,599,601-605, 608-611,613-616

Correlation fimction 5-7,10,17-18,164,191, 212,232,273,277,280,289,290,291,292,294, 296, 299, 300, 301, 302, 305, 306, 307, 330, 344, 37~ 38~ 40~401, 40~ 40~ 439-444

Correlation length 6-8,10,18,231,232,238, 242,247,254,288,291,292,302,327,333,334, 34~ 38~39~401,444

Corrosion 702

Cosolvent effect 103,574

Critical behavior 3-18,51,98,231,233,236, 249, 251, 252, 254, 263, 264, 279, 287, 288, 289, 294, 295, 298, 317, 337, 340, 341, 343, 344, 345, 346, 354, 590

Critical criteria 44

Critical divergences 3-6,9, 14-17,20-21, 196, 22~ 32~ 33~ 34~34~35~35~ 35~ 440

Critical end points 15,21,34,51,63, 68, 85, 88, 98,106,107, 120, 128, 600

Critical exponents 4, 7,8-11. 150, 237, 238, 241,255,292,294,295,327,337,343,345,354, 357

792

Critical fluctuations 5-6,10,231-233,239,240, 24~ 24~ 32~ 331, 33~ 34~ 351, 355

Critical lines 13-14,24-26,51,63, 68, 98, 118, 138, 248

Critical mixture curve 599-601

Critical phenomena 3, 65, 98, 164, 325

Critical point 3-7,39, 61, 66, 72,93, 148, 187, 23~ 23~ 32~ 42~ 593

Crystallization 99, 106, 556, 740, 754

Destruction 697

Devolatilization 619

Dielectric properties 93, 711

Diffusion coefficient 250, 252, 687, 739, 740

Diffusion effects 457, 470, 491

Diffusivity 231, 241, 245, 248, 249

Dilute mixtures 19-29, 193, 196, 200, 208, 288, 439-444

Dimerization 108

Dinitrogen complexes 531

Drying processes 740, 754

Dyeing of fibers 108, 556, 740, 754

Effective diffusivities 687

Eicosene 79

Electrolytes 36,199,210,217,313

Enhancer 103

Enhancement factor 369

Entrainer 103, 677

Environment 669, 754

Enzymatic reactions 456, 458

Equations of state 62,147,183,185,194,197, 274, 299, 589, 620, 763

cubic equations of state 147, 156, 177, 178, 180, 187

extended virial equations of state 147, 157-161

Peng-Robinson equation of state 53, 62, 149,161,178

Redlich-Kwong equation of state 110, 148, 149, 161, 178,202

Van der Waals equation of state 148, 235, 243

virial equations of state 147,151,157-161, 164,202

Estrone 482

Ethane 79,92, 101,263-266,281,530,534, 731, 749,751

Ethylene 86, 87, 530, 533

Excess enthalpy 266

Excess number 370

Experimental techniques 764, 766

Extended classical theory 124

Extraction 697

Extractive effect 103, 106

Film deposition 595, 707, 708, 715, 716

Film stability 731-738

Flory-Huggins model 569

Fluctuation solution theory 191,211,215

Fluid phase equilibria 65, 75, 95, 118, 264, 589, 590,591

Fluid phases 91-112, 118, 481, 499, 739-757

Food applications 769-770

Fractionation 592,599,604,605, 608, 610, 611, 616,619

Fugacity 194

Functional groups 129

Gas-gas equilibrium 81,98

Geothermal energy 740, 755

Gibbs ensemble 288,389,406,418

Gibbs free energy 566

Gibbs stability criterion 39, 60

Gibbs triangle 69

Gibbs-Duhem integration 421

Gillan's method 374

Ginzburg number 243, 256

Glass transition 554, 555

Global phase diagrams 51,52, 63, 100

Group contribution methods 162, 163

Helium 81,430, 731

Helmholtz free energy 232, 233, 235, 236, 242, 252-256, 258, 260, 262, 761

Hexane 79

Hierarchical reference theory 325, 347

High pressure 91-112,425,499,550,592, 641-650, 731

High pressure cells 95-97, 527-531, 590, 647

Homologous series 141

Hydrogen 430,529,531-532,731

Hydrogen bonding 129,402,406,507,602,603, 605, 607-609, 611, 614, 616

Hydrogen chloride 506

Hydrothermal synthesis 740

Hypernetted chain 313, 365

Infrared spectroscopy 504, 514, 527, 530-536

Inorganic materials 596, 707-717

Integral equation calculations 328, 341, 344, 371, 441, 442

Integral equations 164,287,288,289,290,295, 307, 308, 313, 315, 328, 365, 439, 441, 442, 444, 762

Interfacial tension 731-738, 740

Intermolecular interactions 601

Intermolecular potential 276, 414

Ionic fluids 426

Isopycnic conditions 740

Kinetic theory 275, 276, 277

Kinetics 754

Kirkwood-Buff theory 191,215,367,440,441, 712-716 fluctuation integrals 368

Krichevskii parameter 369

Labik's method 376

Lennard-Jones potential 414

mixtures 430-433 Lever rule 72

Light scattering 232, 244, 249, 256, 579, 590, 591, 647-649

Liquid crystalline polymers 727, 728

Liquid crystals 748

Liquid-gas equilibrium see vapor-liquid equil.

Liquid-liquid equilibrium 98

Liquid-liquid-vapor equilibria 15-16, 65, 68, 70-81, 98-102, 120

Long range 289, 291, 292, 298, 300, 301, 302, 303, 307, 388, 389

Lower critical end point (LCEP) 68, 79, 80, 83,120 .

Lower critical solution temperature (LCST) 8~ 9~ 56~ 56~ 571, 57~ 600

Macromolecular phase separations 541, 565, 57~ 58~ 59~ 591, 594

793

Mass transfer coefficients 686, 740, 745, 751

Materials processing 594,595,707,708,715, 716, 719-728

Mean-field lattice-gas model 164, 589, 634-637

Metal-nitrous oxide complexes 533

Methane 79

Mixing rules 110-111,148,150,154,159, 177-181, 183, 185, 187, 614

Mobile phase 653, 656, 658, 659

Moderator 103,105,106,743,745,746

Modifiers 659-661, 663, 668, 743

Modar-process 699, 701, 702

Molecular dynamics 163,164,288,387,388, 39~ 39~ 401, 402, 40~ 43~ 442-444

Molecular fluids 167, 168,211,304,305,307, 394, 395, 406

Molecular interactions 163,211,439,441-444

Molecular simulation 163, 164, 387, 388, 389, 390, 401, 406, 411, 763

Monte Carlo simulation 163,164,287,288, 294,295,300,307,401,406,411,415

Multi-component mixtures 53, 66, 112, 154-156,159,180,214,592,646-648

N aphthelene 86

Near-critical mixtures 13-34,191,223, 439-444, 648

Near-critical solvents 19-36,127,128,129,130, 132, 141

Near-infrared spectroscopy 107, 504

Neutron scattering 232, 256

Nitrogen 96, 531, 731

Nitrous oxide 533

Non-classical dihydrogen complexes 531-532

Non-ideal mixtures 177, 181

Oil sands and oil shales 740

Optical fiber 528

Optical high-pressure cells 95, 96, 500, 502, 531, 562, 580, 590, 647

Organometallic photochemistry 527-537

Ornstein-Zernike equation 191,212,217,289, 329,341,350,366,441,442

Osmotic susceptibilities 15, 18

794

Overloading 655, 656, 662, 663

Oxidation 697

Oxides 707-717

Packed column 657. 659

Partial molar properties 27-28. 36. 192. 198. 222. 631. 63~ 63~ 67~ 753

Partial molar volwne 368. 465

Particle formation 596,708,719,723-728,753, 754

Partition coefficients 103.106.619. 620, 622. 631, 637, 745

Pelargonic acid 731

Pendant-drop method 731

Peng-Robinson equation of state 53, 62. 149. 161, 178

Pentane 78,574

Percus-Yevick 313. 365

Performance 595,596

Perturbed hard chain theory (PHCT) 168-170,172

pH 708, 710, 711. 713-717

Phase behavior 16.65.91-112. 118. 178. 180, 185. 187. 451. 591. 593. 594. 641-650

Phase diagrams 13, 65, 91-112, 118, 599, 600, 619,726

Phase equilibria 65,91-112,118,146,177,178. 411. 731. 745

Phase rule 66. 123

Phase separation kinetics 541.579. 740

Phase transformations 72

Phase transitions 91-112.233,234

Picard's method 372

Plait point 248. 251, 252

Polar fluids 154. 161. 170

Poly-aromatic hydrocarbons 136. 137. 144

Poly (dimethyl siloxane) 561

Poly (ethylene-co-acrylic acid) 599

Poly (ethylene-co-methyl acrylate) 599

Poly (ethylene terephthalate) 558

Poly (methyl methacrylate) 557

Poly (vinyl alcohol) 565

Polycarbonate 559

Polyethylene 87. 491. 493. 520. 541. 559. 563. 573, 574, 576. 593. 594. 597. 602-604. 608. 613. 621

Polypropylene 541. 576

Polystyrene 545. 552. 557. 571, 572. 574. 576, 597

Polymer gels 589. 597

Polymeri~r~tion 53~ 55~59~ 619

Polymer modification 541

Polymerproces,sing 541.589.599.619

Polymer properties 554. 589

Polymer solutions 257. 427. 541. 565. 569. 589. 768

Polymer swelling 556. 597. 632. 634. 636

Polymerization 455.461.491.518.520,541. 542-554

Preparative chromatography 654. 658. 660. 668

Pressure jump techniques 541.579

Production-scale chromatography 654

Propane 81. 136

Prostaglandins 658. 659, 661

Protein powders 719.726.727

P, T -projection 70

P,T,x diagram 69,120.570

Quadruple point 121

Quaternary systems 105

Quantitative spectroscopy 107.499.509.512. 514

R134a 262

Raman spectroscopy 527-529

Rapid expansion 592.596.707.708.715.716, 719-725. 753

Reaction equilibriwn 699

Reaction rate 56. 699

Reactions 56.449.487.512.527-537,564.683. 754

Recycling 541. 564. 589. 598. 658. 742. 743

Redlich-Kwong equation of state 52. 54. 56. 62. 110. 148. 149. 161. 178

Renormalizationgroup 164.236,239,245, 255. 258. 331

Repulsive mixtures 370. 398. 439-442. 444

Residence time 300

Sanchez-Lacombe model 541 576

Scale-up 655. 662. 743. 755

Scaling law 236. 237. 252, 327. 342. 343. 345. 354.357

Selectivity 103, 105, 106,206,481, 484, 489, 619 743,745

Separation factor 103, 106

Short range 287, 289, 291, 301, 302, 303, 304, 388,390

Simple fluids 307, 394, 396, 406

Soil 673, 697, 754

Solid-fluid equilibria 87, 106, 120, 202, 678

Solid matrices 595, 669

Solid-liquid-Ii quid-vapor equilibria 68,84, 121

Solid-liquid-vapor equilibria 15, 65, 85, 87, 107, 121, 138

Solubility 15,87,106, lJO, 193, 200, 565, 570, 641, 676, 707-717, 745

Solute retention 631, 633, 642

Solute-solute interactions 439, 440, 442-444

Solute-solvent 287, 289, 301, 302, 303, 388, 389, 400,401

Solvent-solvent 289, 301, 303, 400

Spectroscopic process control 512, 522

Specific heat capacity 236, 237, 239, 253, 260, 261,265

Spices 740, 742

Spinodal 217,313, 316, 342, 343, 567, 581, 582, 591, 720

Stability criterion 39, 40, 42

Stationary phase 653, 656, 657

Statistical associating fluid theory (SAFn 171,172,541,576,589,598,610,613-615,619, 620

Statistical mechanics 163,191, 2lJ, 287, 289, 387

Stearic acid 731

Stereoregularity 546

Stereoregulation 672

Sterilization offood 754

Structure factor 232,233,237

Supercritical anti solvent (SAS) 620, 621

Supercritical aqueous solutions 222, 288, 307, 389, 399, 401, 707-717, 754

Supercritical extraction 206,592,619,669, 675, 690, 731

Supercritical fluid chromatography 92, 98, 103, 631-639, 641-646, 653, 740, 742-753, 765

Capacity ratio 740, 745, 750

Density programmed 747

Detectors 746

Diffusion coefficients 749-751

Efficiency 746

Gradient techniques 745, 749

HETP values 746, 751, 749

Resolution 745

Retention time 745

Retention volume 745

795

Supercritical fluid extraction 91, 98, 103, 433,592, 645-650, 670, 680, 702, 740, 741-743, 755

Coal 742

Countercurrent distillation 743

Decaffeination of coffee and tea 740, 742, 743

Hops 740, 742

Membrane technologies 743

Supercritical fluids 91-112, 196, 200, 231, 243, 287, 288, 289, 293, 300, 307, 308, 387, 388, 390, 398, 400, 406, 425, 449, 482, 527, 541, 543, 551, 561,570,598, 619, 739, 741, 753, 761

Supercritical processing 541,594, 596, 707, 708, 715, 716, 719-728, 743

Supercritical solubility 15,32-34,707-717

Supercritical water 4,24,91,281,401,402,452 697, 707-717, 754

Supercritical water oxidation (SCWO) 697, 698, 699, 702

Surface tension 731-738, 740

T acticity 546

Ternary mixtures 103, 434, 574, 575, 622

Tertiary oil recovery 740, 755

Test particles 417

Tetradecane 81

Thermal conductivity 233, 238-240, 243, 244, 246, 248, 250, 251, 274, 276, 277, 279, 280, 281

Thermal diffusivity 233, 239, 240, 246-248

Thermodynamic properties 93, 192, 197, 208, 211, 232, 233, 236, 252, 254, 258, 260-265, 287, 289, 290, 294, 298, 299, 303, 387, 631, 739, 740

Thermodynamics 631-639, 711, 712

Time-resolved spectroscopy 524

Tobacco expansion 754

Tocopherols 658, 661, 662, 663

Transition-state theory 462

Transport properties 93,231,273,274,278, 279, 281, 388, 396, 398, 400, 739

Tricritical phenomena 60, 63, 99, lJ8, 123, 124

796

Tricritical points 61,62,63, 123, 124, 129

Tridecane 81

Triglycerides 127

Triphenylmethane 81

T-x projections 70

Upper critical end point (UCEP) 68, 78-84, 120

Upper critical solution temperature (UCST) 84, 98-102, 567, 568, 571, 575, 593, 600

Van der Waals equation of state 148

Van Konynenburg and Scott classification 75,99,117,118,120

Vapor-liquid equilibrium 98, 177, 178, 183, 261-262,265, 641-650

Virial equations of state 147, 151, 157-161, 164,202

Viscosity 233, 238, 239, 241, 245, 246, 248, 249, 274, 275, 276, 277, 279, 280, 281, 390, 396, 397, 400, 560-563, 731, 739

Waste treatment 91, 598, 669, 697, 740, 754

Water 4, 24, 30, 31, 32, 76, 81, 281, 288, 305, 389,401-406,415,425,452,697, 698, 707-717, 754

Weekly attractive mixtures 370

Wet air oxidation 697, 698, 699

Wiener-Hopf decomposition 377

Wood 564, 742

~on 81, 52~ 532