analysis and modelling of energy source …

171
1 ANALYSIS AND MODELLING OF ENERGY SOURCE COMBINATIONS FOR ELECTRIC VEHICLES A thesis submitted to the University of Manchester for the degree of Doctor of Philosophy In the faculty of Engineering and Physical Sciences November 2010 By Ali Milad Jarushi School of Electrical and Electronic Engineering

Upload: others

Post on 01-Oct-2021

0 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: ANALYSIS AND MODELLING OF ENERGY SOURCE …

1

ANALYSIS AND MODELLING OF ENERGY SOURCE

COMBINATIONS FOR ELECTRIC VEHICLES

A thesis submitted to the University of Manchester for the degree of

Doctor of Philosophy

In the faculty of Engineering and Physical Sciences

November 2010

By

Ali Milad Jarushi

School of Electrical and Electronic Engineering

Page 2: ANALYSIS AND MODELLING OF ENERGY SOURCE …

2

TABLE OF CONTENTS

LIST OF TABLES 7

LIST OF FIGURES 8

ABSTRACT 11

DECLARATION 12

COPYRIGHT STATEMENT 13

ACKNOWLEDGEMENTS 14

CHAPTER 1

ENERGY SOURCES FOR FUTURE ELECTRIC VEHICLES

15

1.1 Introduction 15

1.2 Environmental Problems and Motivation Factors 16

1.3 Overview of Electric Vehicle (EV) Battery Technologies

19

1.4 The ZEBRA Battery Technology 22

1.5 Supercapacitor system 28

1.6 Comparison of Energy Source Technologies 31

1.7 Vehicle Power-train Formats 32

1.8 The scope of the research study 34

1.9 Summary 35

CHAPTER 2

ELECTRIC VEHICLE SIMULATION MODEL

2.1 Introduction 37

Page 3: ANALYSIS AND MODELLING OF ENERGY SOURCE …

3

2.2 Modelling Techniques 38

2.3 EV Simulation Model 39

2.3.1 Overview. 39

2.3.2 Vehicle Parameters-Block 2 41

2.3.3 Vehicle road load and traction forces- Block

2. 42

2.3.4 Traction machine model- Block1. 44

2.3.5 ZEBRA Battery model 46

2.3.6 Battery state-of-charge (SOC) 48

2.4 The ZEBRA Battery Model 49

2.5 Vehicle Model Validation 53

2.6 Model Calibration 60

2.6.1 Acceleration Limits 60

2.6.2 Braking Torque Limits 62

2.7 Model Sensitivity 67

2.8 Summary 70

CHAPTER 3

MULTI-BATTERY OPERATION

71

3.1 Introduction 71

3.2 Faulted cell in a ZEBRA battery 72

3.3 ZEBRA Multi-battery system 73

3.3.1 Battery Management Unit (BMI) 74

3.3.2 Multi-Battery Server (MBS) 75

Page 4: ANALYSIS AND MODELLING OF ENERGY SOURCE …

4

3.4 Multi-battery model 76

3.4.1 Model Layout 76

3.4.2 The control scheme 76

3.5 Model Validation 79

3.5.1 Field data analysis 79

3.5.2 Model validation 81

3.6 Model analysis 85

3.6.1 Simulation of four batteries during various

faulted operations 85

3.6.2 Impact of cell failure on a two battery system - taxi performance

92

3.7 Summary 93

CHAPTER 4

COMBINATION OF BATTERY AND SUPERCAPACITOR

94

4.1 Introduction 94

4.2 Hybridisation of vehicle energy sources 95

4.3 Published supercapacitor simulation models 97

4.3.1 Combinations of passive elements 97

4.3.2 Supercapacitor models with varying

capacitance 101

4.4 The proposed supercapacitor model 103

4.4.1 Matlab/Simulink model 103

4.4.2 Parameter temperature considerations 106

4.4.3 Thermal model 107

Page 5: ANALYSIS AND MODELLING OF ENERGY SOURCE …

5

4.4.4 Matlab/Simulink supercapacitor model validation

109

4.5 Vehicle on-board energy management 114

4.5.1 Principle of energy storage 114

4.5.2 Recovered energy 114

4.5.3 Power-train losses 115

4.5.4 Control strategy 117

4.5.5 Phase compensating regulator design 117

4.6 Sizing of supercapacitor power buffer 123

4.6.1 Vehicle energy and power considerations 123

4.6.2 Supercapacitor size 123

4.6 4.6.3 Full model simulation results 127

4.7 Summary 134

CHAPTER 5

DOWNSIZIED AUXILIARY POWER UNIT IN A SERIES HYBRID POWER TRAIN CONFIGRATION

135

5.1 Introduction 135

5.2 Hybridization ratio and ICE/HPM generator rating 136

5.3 Proposed power-train 138

5.4 Series hybrid electric vehicle dynamic model representation

140

5.4.1 An ICE model 140

5.4.2 Optimisation of ICE 143

5.4.3 Power-train efficiency consideration 143

Page 6: ANALYSIS AND MODELLING OF ENERGY SOURCE …

6

5.5 Case studies and simulation results 144

5.5.1 Simulation results 149

5.5.2 Comparison between hybrid and conventional vehicle

152

5.6 Summary 153

CHAPTER 6

CONCLUSION AND RECOMMENDATION FOR FURTHER WORK

155

6.1 Conclusion 155

6.2 Contribution 157

6.3 Publications arising from this thesis study 157

6.4 Recommendation for further work 158

REFERENCES 159

Word count of main text: 36,884

Page 7: ANALYSIS AND MODELLING OF ENERGY SOURCE …

7

LIST OF TABLES

Table No. Title Page No.

Table 2.1 Edison Van data. 53 Table 2.2 Test of energy used. 62 Table 2.3 The regenerative torque is set to different limits. 62 Table 2.4 Test regenerative torque set-point vs. Energy used, Vcellmin=1.5V. 63 Table 2.5 SOC for different internal resistance using power profile. 67 Table 2.6 SOC for different battery internal resistance using a fixed

efficiency drive system. 67 Table 2.7 SOC for different internal resistance using efficiency map drive

system. 68 Table 3.1 Starting data of main parameters of the four batteries. 78 Table 3.2 The impact of different SOC of the third battery on the vehicle

performance. 86 Table 3.3 The impact of cell failure on the vehicle performance. 86 Table 3.4 Different cases of cell failure. 88 Table 3.5 Progressive cases of cell failures. 90 Table 3.6 The impact of cell failure on vehicle range. 91 Table 4.1 Thermal parameters for Maxwell 3000F cell supercapacitor. 107 Table 4.2 Example comparison of simulated and measured energies for the

charge-discharge current profile illustrated in Fig. 4.19. 111 Table 4.3 3.5 Tonne vehicle and power-train parameters for simulation

model. 123 Table 4.4 DESERVE ZEBRA battery parameters. 123 Table 4.5 Simulated range versus the voltage variation (DV). 128 Table 4.6 The range of the three currents with battery SOC. 129 Table 5.1 London taxi LTI TX4 specification of two made (Auto and

Manual) over NEDC. 144

Table 5.2 Actual and scaled 75kW Toyota Prius over NEDC. 144 Table 5.3 Summary of power requirements for proposed vehicle driving

profiles. 146 Table 5.4 Comparison of the simulation results between pure electric and

hybrid vehicle modes of Case 1. 149 Table 5.5 Comparison of the simulation results between pure electric and

hybrid vehicle modes of Case 2. 149

Table 5.6 Comparison of the simulation results between pure electric and hybrid vehicle modes of Case 3(inner city driving ECE 15). 151

Page 8: ANALYSIS AND MODELLING OF ENERGY SOURCE …

8

LIST OF FIGURES

Figure No. Title Page No.

Fig. 1.1 Transport and world total oil consumption. 17 Fig. 1.2 DEFRA study in United Kingdom. 17 Fig. 1.3 The Cell of ZEBRA battery. 22 Fig. 1.4 ZEBRA battery, Beta-alumina cells. 24 Fig. 1.5 Possible electrical equivalent circuit representations for ZEBRA

cells. 26 Fig. 1.6 Z5C standard battery. 26 Fig. 1.7 ZEBRA battery system. 26 Fig.1.8 Z5C battery performance. 27 Fig.1.9 Z5C Discharging. 27 Fig.1.10 Energy density and power density for different technologies 29 Fig .1.11 Maxwell supercapacitor. 29 Fig. 1.12 Comparison of battery energy and power density for different

technologies. 31 Fig. 1.13 Parallel hybrid-electric configuration. 33 Fig. 1.14 Series hybrid-electric vehicle power-train configuration. 33 Fig. 1.15 hybrid energy source, pure EV configuration. 34 Fig. 2.1 High level representation of electric vehicle simulation model. 40 Fig. 2.2 Velocity and gradient profiles for some driving cycles. 41 Fig. 2.3 Forces acting against the vehicle when starting and when in

motion 42 Fig. 2.4 The efficiency map as a 2-D Look-up table in the model. 44 Fig. 2.5 Several battery models. 46 Fig. 2.6 The layout of ZEBRA battery model. 49 Fig. 2.7 The flowchart of the model process. 49 Fig. 2.8 ZEBRA model in Simulink environment. 50 Fig. 2.9 The results of Look-up table for the internal resistance 50 Fig. 2.10 The results of Look-up table for open circuit voltage 50 Fig. 2.11 ZEBRA model over repetitive NEDC driving cycle. 51 Fig. 2.12 The measured power time profile for the SEV Edison Van used

for case (i) of the validation study. 53 Fig. 2.13 The calculated and measured SOC. 54 Fig. 2.14 The calculated and measured terminal voltage. . 54 Fig.2.15 Measured test data from the Edison Van. 56 Fig.2.16 SOC results for case (ii) the fixed efficiency drive system test

before calibration. . 57 Fig. 2.17 Terminal voltage results for case (ii) the fixed efficiency drive

system test before calibration. 57 Fig. 2.18 SOC results for case (iii) the efficiency map drive system test. 58 Fig. 2.19 Terminal voltage results for case (iii) the efficiency map test 59 Fig.2.20 Edison Van acceleration calculated from the vehicle measured

velocity data. 60 Fig. 2.21 Acceleration limiter to correct measurement. 60 Fig.2.22 The calibration of the acceleration. 61 Fig. 2.23 SOC when regerative torque limited to zero (no regen.). 62 Fig 2.24 SOC at different regenerative torque set-points. 63 Fig. 2.25 Results of regenerative torque set-points from 0 to 75 Nm. 64

Page 9: ANALYSIS AND MODELLING OF ENERGY SOURCE …

9

Fig. 2.26 SOC when the regerative torque set-point is 35Nm. 64 Fig. 2.27 SOC under a fixed efficiency drive system after calibration. 65 Fig. 2.28 Example of terminal voltage for fixed efficiency drives system

after calibration. 65 Fig. 2.29 SOC for different battery internal resistance. 67 Fig. 2.30 SOC for different battery internal resistance using a fixed

efficiency drive system. 68 Fig. 2.31 SOC for different internal resistance using efficiency map drive

system. 68 Fig. 3.1 A Multi-battery system. 73 Fig. 3.2 ZEBRA Z5C Management unit (BMI) system. 73 Fig. 3.3 BMI Operation in a vehicle Traction System. 74 Fig. 3.4 Operation scheme of the MBS and BMI’s. 74 Fig. 3.5 The layout of the multi-battery model. 76 Fig. 3.6 The battery parameters of four batteries in multi-battery model. 76 Fig. 3.7 MBI model using digital circuits. 77 Fig. 3.8 Flow chart of MBS operation. 77 Fig. 3.9 Currents measurements of four batteries exhibiting out of

balance. 79 Fig. 3.10 Measurement voltages across each battery. 79 Fig. 3.11 The SOC’s of the four batteries. 79 Fig. 3.12 Demand current profile. 81 Fig. 3.13 Simulated contactor states of the four batteries. 81 Fig. 3.14 Simulated and experimental voltage of battery 2. 82 Fig. 3.15 Simulated and experimental data of voltage of battery 3. 82 Fig. 3.16 Multi-battery model validation. 83 Fig. 3.17 Results of case (1). 85 Fig. 3.18 Results of case (2). 87 Fig. 3.19 The impact of cell failure on the vehicle performance (or

operation time). 88 Fig. 3.20 Results of case (3). 89 Fig. 3.21 The impact of progressive cell failure on the vehicle

performance. 90 Fig. 4.1 Traction System layout for a all-electric vehicle. 95 Fig. 4.2 Classical capacitor model. 97 Fig.4.3 A dynamic model for supercapacitor cell. 98 Fig. 4.4 Example of model layout using complex impedances. 98 Fig. 4.5 Approximation of Z(j ω ) via n RC circuits. 99 Fig. 4.6 Circuit scheme of Debye polarization cell. 100 Fig. 4.7 Equivalent circuit model for supercapacitor incorporating

variable capacitance. 101

Fig. 4.8 A simplified version of the model of Fig. 4.7 for power electronic circuit applications.

101

Fig. 4.9 Maxwell model presented in [135]. 102 Fig. 4.10 Maxwell model in Simpower Matlab. 103 Fig. 4.11 Details of the non-linear capacitance function block showing the

look up table. 104 Fig.4.12 Supercapacitor cell non-linear capacitance versus voltage

function determined from test. 105 Fig. 4.13 Reported supercapacitor parameter variation with temperature. 106 Fig. 4.14 Supercapacitor thermal equivalent circuit model. 107 Fig. 4.15 Comparison between published and simulation model results. 108 Fig. 4.16 Power circuit schematic of supercapacitor module test facility. 110

Page 10: ANALYSIS AND MODELLING OF ENERGY SOURCE …

10

Fig. 4.17 Picture gallery of supercapacitor module test facility. 110 Fig. 4.18 Maxwell 165F module DC voltage variation due to alternate

charge-discharge current from the W-L set. 111

Fig. 4.19 Maxwell 165F module DC voltage and current variation due to alternate charge-discharge current from the W-L set.

111

Fig. 4.20 Comparison of simulated and measured temperature of Maxwell module during repetitive cycle regime as Fig. 4.18.

112

Fig. 4.21 Electrical losses in the power-train. 114 Fig. 4.22 The converter gain for DC-to-DC converter. 115 Fig. 4.23 Regulated DC link voltage control scheme. 117 Fig. 4.24 Poles and zeros of the plant. 118 Fig. 4.25 Open-loop Bode plots of the plant. 119 Fig.4.26 Open-loop plant response. 119 Fig. 4.27 Poles and zeros of the system. 120 Fig. 4.28 Close-loop system response. 121 Fig. 4.29 Close-loop Bold plot of the system. 121 Fig. 4.30 ESERVE_ECE15 driving cycle. 124 Fig. 4.31 Connection scheme of three of Maxwell 165F supercapacitor

modules into 146V, 56 F bank. 126 Fig. 4.32 The case study of the combination. 126 Fig. 4.33 Terminal voltages of both energy sources. 127 Fig. 4.34 Currents of demand, battery, and supercapacitor. 127 Fig. 4.35 The range of the vehicle as the terminal voltage variation

tightened. 128 Fig. 4.36 The impact on the range when battery current limit is decreased. 129 Fig. 4.37 Voltages when battery current limit is 75A. 130 Fig. 4.38 Voltages when battery current limit is 50A. 131 Fig. 4.39 Voltages when battery current limit is 25A. 132 Fig. 5.1 Hybridisation of battery and ICE strategy in HEV. 135 Fig. 5.2 Method to split power between two energy sources. 135 Fig. 5.3 A series hybrid vehicle. 137 Fig. 5.4 The vehicle power-train in a series hybrid configuration format. 139 Fig. 5.5 Simulink ICE model. 140 Fig. 5.6 Example of ICE model outputs over typical NEDC driving cycle. 141 Fig. 5.7 Engine emission for different torques. 142 Fig. 5.8 Matlab/Simulink traction machine dynamic model. 143 Fig. 5.9 Reference duty profiles for the simulation study. 145 Fig. 5.10 Hybridization Ratio plot for Case 1 and 2. 147 Fig. 5.11 Power demand from each energy source component. 150 Fig. 5.12 Comparison between the all electric, hybrid (3 kW, 14.5 kW),

and pure conventional vehicle Cases over Sub-Urban NEDC. 152

Page 11: ANALYSIS AND MODELLING OF ENERGY SOURCE …

11

ABSTRACT

The objective of this research is to develop suitable models to simulate and analyse Electrical

Vehicle (EV) power-trains to identify and improve some of the deficiencies of EVs and

investigate new system architectures.

Although some electro-chemical batteries improvements have lately been achieved in

specific-energy, the power density is still low. Therefore, an efficient, cost-effective and

high power density support unit could facilitate EV competitiveness compared to

conventional internal combustion engine powered vehicles in the near future.

The Na-Ni-Cl2, or ZEBRA battery as it is most commonly known, has good energy and

power densities; it is very promising electro-chemical battery candidate for EV’s. The thesis

presents a detail simulation model for the ZEBRA technology and investigates its application

in an EV power-train with regard to state-of-charge and voltage transients. Unlike other

battery systems, the ZEBRA technology can sustain about 5-10% of failed cells. While this

is advantageous in single series string or single battery operation it is problematic when

higher numbers of batteries are connected in parallel. The simulation model is used to

investigate faulted operation of parallel battery configurations.

A non-linear capacitance versus voltage function is implemented for the supercapacitor

model which yields good energy and terminal voltage predictions when the supercapacitor is

cycled over dynamic regimes common to EV applications. A thermal model is also included.

Multiple energy source systems are modelled and studied in the form of an energy dense

ZEBRA battery connected in parallel with a power dense supercapacitor system. The

combination is shown to increase available power, reduce the maximum power demanded

from the battery and decrease battery internal power loss. Consequently, battery life would

be increased and more energy would be recovered from regenerative braking, enhancing the

energy conversion efficiency of the power-train.

A combination of ICE and ZEBRA battery is implemented as a range extender for London

taxi driving from Manchester to London. The hybridisation ratio of the system is discussed

and applied to fulfil the requirement with minimum emissions.

This study offers a suitable model for different energy sources, and then optimises the

vehicle energy storage combination to realize its full potential. The developed model is used

to assess different energy source combinations in order to achieve an energy efficient

combination that provides an improved vehicle performance, and, importantly, to understand

the energy source interconnection issues in terms of energy flow and circuit transients.

Page 12: ANALYSIS AND MODELLING OF ENERGY SOURCE …

12

DECLARATION

No portion of the work referred to in this thesis has been submitted in support of an

application for another degree or qualification of this or any other place of learning.

Page 13: ANALYSIS AND MODELLING OF ENERGY SOURCE …

13

COPYRIGHT STATEMENT

i. The author of this thesis (including any appendices and/or schedules to this thesis)

owns any copyright in it (the “copyright”) and he has given The University of

Manchester the right to use such Copyright for any administrative, promotional,

educational and/or teaching purposes.

ii. Copies of this thesis, either in full or in extracts, may be made only in accordance

with the regulations of the John Rylands University Library of Manchester. Details

of these regulations may be obtained from the Librarian. This page must form part

of any such copies made.

iii. The ownership of any patents, designs, trade marks and any and all other

intellectual property rights except for the Copyright (the “Intellectual Property

Rights”) and any reproductions of copyright works, for example graphs and tables

(“Reproductions”), which may be described in this thesis, may not be owned by the

author and may be owned by third parties. Such Intellectual Property Rights and

Reproductions cannot and must not be made available for use without the prior

written permission of the owner(s) of relevant Intellectual Property Rights and/or

Reproductions.

iv. Further information on the conditions under which disclosure, publication and

exploitation of this thesis, the Copyright and any Intellectual Property Rights and/or

Reproductions described in it may take place is available from the Head of School

or Electrical and Electronic Engineering (or the Vice-President) and the Dean of the

Faculty of Life Sciences, for Faculty of Life Sciences’ candidates.

Page 14: ANALYSIS AND MODELLING OF ENERGY SOURCE …

14

ACKNOWLEDGEMENTS

First and foremost, I would like to thank my supervisor Dr. N. Schofield for his invaluable

encouragement, support and guidance. Nigel, without your help the completion of this

thesis would have been even more difficult to say the least and I wish you the best in your

life.

I am very grateful to DESERVE Project, for helping me to get the field data to validate my

simulation model of this project and particularly I would like to acknowledge Mr. Jan for

his support and contributions

I wish to thank my family for their unstinting support and encouragement throughout the

pursuit of my doctorate.

Special thanks go to my friend Ahmed Al-Adasani for his cooperation during my study to

publish two papers and one IET Journal for review, wishing this cooperation will continue

in the future.

Finally, I would like to thank every one in the Power Conversion Group at Manchester

University who gave me help during my study. Their help and support has been much

appreciated.

Page 15: ANALYSIS AND MODELLING OF ENERGY SOURCE …

15

CHAPTER 1

ENERGY SOURCES FOR FUTURE ELECTRIC

VEHICLES

1.1 Introduction

Electric vehicles (EV’s) powered by electro-chemical batteries have been in existence

since the beginning of the automotive era. At the beginning of the 20th century, electrically

powered vehicles were more reliable, safe and better quality in terms of performance and

energy conversion efficiency [1, 2]. This early advantage quickly subsided with the

internal combustion engines (ICE) which addressed the range issue that was, and still is,

problematic with electric vehicles. Essentially, electro-chemical batteries can not match the

high energy density of ICE’s even with their poor energy conversion efficiency of below

20% [2, 3].

Although ICE emissions in general continue to reduce, carbon dioxide emissions have not

reduced significantly, this against a background of increasing number of vehicles. As a

result, the ICE is increasingly becoming a target of environmental issues; in particular, low

carbon related governmental policies. These environmental issues and concerns over

sustainable energy use are the key motivating factors in the development of alternative

energy sources and power-trains for road vehicles [4].

This thesis investigates the implementation of more than one energy source in an electric

vehicle power-train to alleviate the problems faced by the limited energy density of

existing state-of-art electro-chemical batteries.

The research is linked to a UK Technology Strategy Board (TSB), low carbon vehicles

Innovation Platform Project, “Develop high Energy battery and high power Supercaps for

Page 16: ANALYSIS AND MODELLING OF ENERGY SOURCE …

16

all Electric Range Van Evaluation (DESERVE)” [5]. “DESERVE” investigates the

combination of a modified Sodium-Nickel-chloride, or ZEBRA, battery and high power

supercapacitor system, and has provided some technical input to thesis in the form of test

data taken at the request of the author.

The electric vehicle simulation tool developed as part of this thesis study supported the

power-train design undertaken on the DESERVE project, providing a significant input to

the detailed understanding of vehicle power-train electrical dynamics and their impact and

considerations when combining multiple energy sources in various power-train

architectures. While there are a number of similar simulation platforms available, the ones

reviewed do not simulate the terminal transients in the same detail or have good correlation

of system energy and voltages.

An introduction to the environmental issues and motivating factors focussing this research

will be given in Chapter 1, followed by a background discussion of the ZEBRA battery

technology, supercapacitor systems and ICE’s. A number of vehicle power-train formats

will be presented, again as background, and clarify terminologies. Chapter 2 will introduce

the electric vehicle model that will be used throughout the remaining thesis. Chapter 3 will

discuss issues surrounding the multiple connections of traction batteries. Chapter 4 a

ZEBRA and supercapacitor power-train study, and Chapter 5 a ZEBRA battery and ICE

combination for inner city and inter city driving. Finally, Chapter 6 will conclude the

research study.

1.2 Environmental Problems and Motivation Factors

During the last decade of the 20th century climatic changes have been recognised by the

scientific and governmental communities, with many issues related to environmental

misuse by human beings. Global warming and traffic generated emission, particularly in

the cities are degrading air quality up to the point where the physical health of the local and

global population is directly threatened [4]. One of the largest sources of gas emissions so

called ‘green house' is transportation relies almost exclusively on fossil-fuels [4]. Transport

energy use continues to rise rapidly around the world, where it has been predicted to grow

by nearly 90% between 2000 and 2030; Energy use in transport will grow especially

quickly in the developing world due to the well known correlation between transportation

energy use and gross-domestic-product (GDP). Transport is also becoming the dominant

sector in terms of oil consumption, as illustrated in Fig. 1.1. It has accounted for nearly all

growth in oil use over the last two decades and this rate is expected to continue over the

next two decades [6]. The environmental impact of increased oil usage in transport will be

considerable, most notably for CO2 emissions.

Page 17: ANALYSIS AND MODELLING OF ENERGY SOURCE …

17

M

illio

n T

onn

es o

f Oil

Equ

ival

ent

(MT

OE

)

Total Transport

1971

19

76

1981

19

86

1991

19

96

2001

20

01

2011

20

16

2021

6000 5000 4000 3000 2000 1000

Fig 1.1 Transport and world total oil consumption [6].

In 2000, transport accounted for about 5 Giga tonnes (GT) of CO2 emission worldwide, or

21% of total energy related emissions. By 2030, transport CO2 is predicted to rise by 87%

to 9 GT, or 24% share of the total. This is only the CO2 developed directly by vehicles,

however the transportation share is closer to 28% if the CO2 released during fuel

production, processing and delivery to vehicles is included [6].

In 2007, the United Kingdom Department of the Environment, Food and Rural Affairs

(DEFRA) released a report discussing the emissions of greenhouse gases and carbon

dioxide. Overall, emissions still exceed domestic and Kyoto target goals, as illustrated in

Fig. 1.2 [7].

UK

Kyoto report 2001-2012

Basket of green house gases

2001-2012

Domestic Carbon dioxide

2001-2012

Carbon dioxide

Mill

ion

of

ton

ne

s

900 800 700 600 500 400 300 200 100

1990

19

92

1994

19

96

1998

20

00

2002

20

04

2006

20

08

2010

20

12

Fig. 1.2 DEFRA study in United Kingdom [7].

The major concern with road transport sector is that it relies heavily on oil and alternative

vehicular solutions appear some years away [4, 6-8].

Governments and industries have been aware of the implications of transportation emission

and fuel usage and efforts are being made to change the situation and to solve these

Page 18: ANALYSIS AND MODELLING OF ENERGY SOURCE …

18

challenges. It is becoming publically acceptable to force vehicle manufacturers to develop

less polluting engines and find alternative energy sources that are cleaner than the fossil

fuels used today, as a move to satisfying the Kyoto obligations [6-9]. Hence, there is a

trend in the transport industry to replace ICE’s with alternatively fuelled engines or to use

energy sources that are less polluting from well-to-wheel [10].

There are a wide variety of different technology and policy options for reducing

transportation oil use and CO2 emissions under consideration. One of these technologies is

fuel economy improvement; including improved vehicle design and new propulsion

systems for example all-electric, hybrid-electric and fuel cell vehicles. Other technologies

are alternative fuel; bio fuels and hydrogen to name prominent contenders [1-3, 11].

Electrical propulsion systems offer the best possibility for the exploitation of new energy

sources since the power-train has a high degree of flexibility allowing many energy

sources to be interfaced to a standardised electrical propulsion system [1-3], for, example,

a fixed speed ICE driven generator could in the future be replaced by a fuel cell system

should that technology mature to a sufficient level.

The ideal scenario is to develop an electric vehicle technological solution that is

compatible with existing ICE vehicles in terms of performance and range, such a vehicle

could gain a strong global presence for future transportation [1-3, 11], and will be the

subject of power-train study in Chapter5.

Of the multitude of solutions being proposed in this field, one could consider three aspects.

A comprehensive solution is the development of more electro-chemical advanced battery

technologies, i.e. increasing the energy capacity and power capability above technologies.

This is desirable for city applications, where commuting distances are short. Several new

battery technologies have been proposed, for example based on Lithium ion combinations,

to satisfy vehicle range requirements [11-14]. However, the interesting point here is to

study the impact of driving regimes on battery age, life cycle, and cell failure on the

vehicle performance. Note cell failure multi-cell system is discussed in Chapter 3.

The second aspect is to achieve higher autonomy than battery EV’s and higher efficiency

than conventional ICE-powered vehicles, thus producing vehicles having a lower

environmental impact. Vehicles that use such a combination of different energy storage

devices are commonly known as Hybrid Electric Vehicles (HEV’s). Many studies have

considered how to increase the efficiency and lower environmental impact by employing

downsized ICE and power buffer [15-20]. Note, the vehicle simulation model discussed in

Page 19: ANALYSIS AND MODELLING OF ENERGY SOURCE …

19

Chapter 2 is further developed in Chapter 5 and used to analyse the impact of a downsized

ICE employed in a range extension function for 2.5 tonne taxi.

The third interesting aspect is to reach higher energy conversion efficiencies, for example,

an electrical power-train should be able to recover regenerative braking energy, which is

otherwise wasted in case of pure ICE systems. Therefore, the integration of energy sources

that have high power density and are able to recover and release energy from braking and

other system transients is an important research area. This aspect of future vehicle power-

train development is the theme of the DESERVE project. Here, a new higher energy but

lower power density cell is used in conjunction with a supercapacitor system to improve

power-train energy conversion efficiency, DC supply stability and battery life [ 21].

1.3 Overview of Electric Vehicle (EV) Battery Technologies

The electro-chemical battery is a key technology for a future EV development. Some often

quoted drawbacks of existing state- of art batteries are that they are heavy, expensive, and

have limited energy storage capability. Currently, EV’s cannot compete in terms of range

between refuelling with their ICE counterpart. The time to refuel (recharge) is also not

comparable ranging from minutes for a typical ICE powered vehicle to hours for a suitably

sized traction battery (8 hrs for a Z5C- 21kWh ZEBRA). Improved overall energy

conversion efficiency and increasing battery cycle life are also key factors for the

commercial success of EV’s [22-24].

The automotive industry has, to-date, developed BEV’s that depends on one energy source,

electro-chemical batteries. These vehicles were initially based on lead-acid technologies

where the specific power capability has been increasing but the specific energy has only

slightly improved over the past 100 years. The technology has effectively reached a

fundamental threshold dictated by the chemical composition of the cells [1-3-24-28].

With the increased interest in EV’s, there has been a great deal of research and

development improvement of batteries, yielding new types of battery technologies with

energy densities higher than lead-acid. The introduction of new batteries with high energy

density has led to unexpected difficulties being encountered, such as the recharging time,

manufacturing infrastructure and support, and ultimately cost, all of which take time to

solve. The cost depends on the capacity of production and also the materials used in the

batteries. The use of other cheaper materials may have to be restricted for environmental

reasons, unless satisfactory routines for the use of these materials are established, such as

Cadmium. Generally, considerable progress has been reached in battery development. In

the past, a battery having a specific power of 100W/kg was seen as a good technology.

Page 20: ANALYSIS AND MODELLING OF ENERGY SOURCE …

20

Now it seems to be fully possible to reach over 500W/kg and figures such as 1000W/kg are

though to be possible [23-24, 29].

Regarding to lead-acid battery, although it is out-performed by many of other technologies,

it still remains a preferred option for many EV’s developments since the technology is well

understood, there is an established manufacturing and recycling base and hence cost

benefit. The battery also has relatively good charge acceptance during regenerative

braking. However, the drawbacks of this technology are low power and energy density,

and short life time when subject to vehicle type charge-discharge cycling. Hence, the

technology is virtually limited to small EV’s, for example folk-lift trucks, mobility

vehicles, and leisure vehicles.

In the short term, Nickel-Cadmium and Nickel-Metal Hydride batteries offer some

improvement in performance on lead-acid, albeit at a higher capital cost, which is off-set to

some extent by a longer battery life. It should be noted that Nickel-Cadmium is now not a

suitable candidate technology for electric vehicle application, since the material is not

classified as environmentally safe. The European end-of-life directive (2000/53/EC) has

limited the use of heavy metal (including Ni-Cds) in all vehicles ready for market after

July 2003 [12-14, 30].

The high temperature Sodium-Sulphur and Sodium-Nickel-Chloride (ZEBRA) batteries

offer significant performance improvement. The Sodium-Nickel-Chloride battery has more

advantages because it has a slightly lower operating temperature and better freezing

(200ºC) and short-circuit failure characteristic than the Sodium-Sulphur, favouring long

series chains of cells, and batteries for high (200-1200V) voltage application. These

batteries require a vacuum insulated case and good battery thermal management because

they operate with an internal temperature range from 250º to 350ºC. While these high

operating temperatures may initially suggest a major disadvantage, it must be noted that

the typical external battery case temperature is less than 30ºC when installed in a 20ºC

ambient. The ZEBRA battery has a good energy density typically 4 times that of the best

quoted lead-acid technology. Note the ZEBRA thermal management hardware is included

in the total battery mass. The technology has no self-discharge, relative low operating cost

and good cycle energy efficiency, as discussed later in Chapter 4. The ZEBRA technology

is discussed in detail in the next section.

Lithium based batteries offer both high energy and power densities, and appear the ideal

candidate for EV’s. However, they are still in the process of development and hence the

cost is relatively high. Moreover, their life cycle is dependent upon aging from the time of

manufacturing and not on the number of charge/discharge cycles, further temperature

Page 21: ANALYSIS AND MODELLING OF ENERGY SOURCE …

21

management for automotive temperature specifications (i.e.-40ºC to 100ºC) and cell

balancing requirements impact on overall fundamental cell energy and power densities[12,

14].

In the future, the metal-air batteries may offer some improvement in performance and re-

fuelling capability. The electrodes and/or electrolyte of these technologies are changed at

re-fuelling stations and recycled yielding a much faster charge time than for other

technologies. However, the special requirements for replacing the metal electrodes and/or

circulating the electrolyte are still under development, and have yet to fully demonstrated

and shown to be practical for road vehicle application [31, 32].

Reviewing world-wide progress, the Department of Energy (DOE) in the USA is involved

in a program called ‘Advanced Automotive Technologies’ (ATT), the aim of which to

develop advanced energy storage. The participants in the Partnership for a New Generation

of Vehicles (PNGV) are the leaders of this program as well as the others like Chrysler,

Ford, GM and representatives of the United States Council for automotive Research

(USCAR). High power batteries are developed for hybrid-electric vehicles (to be discussed

later) and high energy density batteries for pure EV’s. DOE supports an active program of

long-range R&D to develop advanced energy storage and related systems technologies that

will be necessary for the commercial viability of competitive all and hybrid-electric

vehicles. For electric vehicles, the US Advanced Battery Consortium (USABC) has a

contribution with DOE to develop high storage batteries such as Nickel-Metal Hydride and

Lithium-ion batteries [11-14, 23, 24]. In Japan, Toyota, Nissan, Honda and two battery

companies Lithium Battery Energy Storage Technology Research Association (LIBES)

and Panasonic EV Energy Co., are working together to develop new battery technologies.

Both Honda and Toyota use Nickel-Metal Hydride batteries while Nissan uses Lithium-ion

batteries for their current hybrid-electric fleets. In the UK, Beta Research and Development

Ltd; is a manufacturer of Sodium-Nickel Chloride (ZEBRA) batteries. They have recently

been acquired by GE in the USA specifically to make large high energy, high voltage

batteries for the recovery braking energy on large Inter-State rail power-trains, utilities

support, telecoms, and general UPS. Note, GE have re-named the ZEBRA the “NaMx”

battery [33]. The manufacturing rights to the ZEBRA technology were bought by MES-

DEA, Switzerland, in 2003, who have subsequently been bought by FIMM, and Italian

automotive components supplier. Hence, this battery technology is progressing into the

higher volume market.

Page 22: ANALYSIS AND MODELLING OF ENERGY SOURCE …

22

1.4 The ZEBRA Battery Technology

The ZEBRA battery was invented by Coetzer in 1978 at the CSIR in Pretoria, an Anglo-

American Corporation based in South Africa [37]. BETA Research and Development Ltd

continued the development in the UK and was integrated into the joint venture of Daimler

and the Anglo-American Corporation. The jointly founded company, AEG Anglo batteries

GmbH, started the pilot line production of ZEBRA batteries in 1994. Later, the ZEBRA

technology was acquired in total by MED-DEA, Stabio, Switzerland industrialised

production. The production capacity in 2004 was 2000 battery packs per year in a building

designed for a capacity of 30,000 battery packs per year. It is claimed that this has resulted

in cost reductions that make the life-cycle-cost of the ZEBRA battery less than those of

lead-acid batteries equitable energy density [21-23].

In the ZEBRA technology, the electrode material is a nickel powder and plain salt, the

electrolyte and separator is β’’-Al 2O3 -ceramic that conductive for Na+ ions but insulator

for electrons [34-38]. The ZEBRA battery operates at temperature range of +270ºC to

350ºC because the Sodium-ions conductivity has a reasonable value of ≥ 0.2Ω-1 cm-1 at

260ºC and is temperature-dependent with a positive gradient [34]. The basic cell structure

is shown in Fig. 1.9 [34-36].

Fig. 1.3 The Cell of ZEBRA battery [34].

The basic cell reaction is:

NaNiClNiNaCl ingdischingCh 22 2arg/arg + →←+

(1.1)

Due to the ceramic electrolyte in ZEBRA cell there is no side reaction, hence the charge

and discharge cycle is 100% charge (or 100% columbic) efficient, which means no charge

charging

discharging

Page 23: ANALYSIS AND MODELLING OF ENERGY SOURCE …

23

is lost, unlike all other electro-chemical technologies. The cathode has a porous structure

of nickel (Ni) and salt (NaCl) in a 50:50 mixture. This salt liquefies at 154ºC and, in the

liquid state; it is conductive for Sodium-ions. Features that are essential to the ZEBRA

technology are:

• Sodium-ion conductivity inside the cathode: the ZEBRA cells are produced in a

discharge state. The liquid salt (NaAlCl4) is vacuum-impregnated into the porous

Nickel-salt mixture which forms the cathode. The Sodium-ions are conducted between

the ceramic surface and the reaction zone inside the cathode bulk during charge and

discharge and makes all cathode material available for energy storage.

• Low resistive cell failure mode: The Ceramic is a brittle material and may have small

cracks during production. In case of large cracks, the liquid salt (NaAlCl4) becomes in

contact with the liquid Sodium (the melting point of which is 90ºC), the reaction is

described by:

AlNaClNaAlCl +→ 44 (1.2)

This reaction shorts the conductive current path between positive and negative so that

the cell goes to a low resistance. In case of small cracks, the salt and aluminium closes

the crack. Thus, the ZEBRA battery has some cell failure tolerance. It has been

established by Beta R&D that 5-10% of cells a series string may fail before the battery

can no longer be used. The battery controller detects cell failure, and adjusts all

operative parameters. The impact of cell failure in system containing a number of

parallel connected batteries ( to realise vehicle energy requirements) is discussed in

Chapter 3 and illustrated with consideration to 4- and 2- parallel battery system for 7.5

tonne and 2.5 tonne vehicle respectively.

• Over-charge reaction: the charge capacity of the ZEBRA cell is determined by the

quantity of salt (NaCl) available in the cathode. If the charge voltage continues to be

applied to the cell even when the cell is fully charged, the liquid salt (NaAlCl4)

supplies a sodium reserve following the reversible reaction:

234 222 NiClAlClNaNiNaAlCl ++↔+ (1.3)

This over-charge reaction requires a higher voltage than the normal charge, having

three advantages: (i) the current is stopped automatically because the open circuit

voltage increased and equalised the charger voltage, (ii) in event of cell failure, the

remaining cells can be over-charged in order to balance the voltage of the failed cells,

(iii) in case of down hill and the battery is fully charged, the battery has an over-charge

Page 24: ANALYSIS AND MODELLING OF ENERGY SOURCE …

24

capacity of up to 5% for regenerative breaking so the breaking behaviour of the vehicle

is unchanged [34].

• Over-discharged reaction: from the first charge, the cell has an extra of Sodium in the

anode compartment so that for an over-discharge tolerance, Sodium is available to

maintain current flow at a lower voltage; the reaction is same as for cell failure but runs

without ceramic failure.

In the ZEBRA cell design, the positive pole is connected to the current collector, which is a

hairpin shaped wire with an inside copper core for low resistivity and an outside Nickel

plating such that all material in contact with the cathode is consistent with cell chemistry.

The cathode material is a mixture of salt with nickel powder and trace of iron and

aluminium. This mixture is filled into the Beta-alumina tube, an example of which is

illustrated in Fig. 1.10 [34-36].

Beta alumina ceramic tube with compression bond seal.

(a) Circular or ‘slim line’ cross-section. (b) Cloverleaf or ‘monolith’ cross-section.

Fig. 1.4 ZEBRA battery, Beta-alumina cells[ 34,35].

For resistance reduction, the Beta-alumina tube can be formed to increase the surface area,

the so-called monolith cell, as illustrated in Fig. 1.4 (b). The tubes are surrounded and

supported to the cell case by a 0.1 mm thick steel sheet to form a capillary gap surrounding

the tube. In the early ZEBRA cell designs, the ceramic tube was a circular cross-section, as

illustrated in Fig.1.4 (a). For the DESERVE project, Beta R&D have reverted back to this

early cell design since it exhibits a higher energy density of around 20% on the

“cloverleaf” design but lower power density. For the DESERVE vehicle power-train, this

reduction in power-density is satisfied by the inclusion of a supercapacitor system, as will

discussed in Chapter 4. Since most vehicles manufacture require a balance of energy and

power densities, all current commercial ZEBRA cell designs utilise a “cloverleaf” cross-

section tube. A recent improvement has been introduced to the cell chemistry. The

Page 25: ANALYSIS AND MODELLING OF ENERGY SOURCE …

25

positive electrode in the monolith cell has been doped with iron, which is mentioned

above, exhibits a similar reaction to that of nickel [34-37]:

FeClNaNaClFe +↔+ 222 (1.4)

The new chemical composition gives a cell performance characteristic similar to that of

two independent cells, i.e. nickel and iron, connected in parallel, as illustrated in Fig. 1.5,

showing possible electrical equivalent circuit representations for the older ZEBRA cell

without iron doping (a) where ohmic effect described by Rd and Cd, waste energy is

modelled by Rw, and the new ZEBRA cell design with iron doping (b) [34, 37], the EOC’s

are the open circuit voltage for nickel and iron cells. The actual chemical reaction is an

aside as far this thesis research is concerned, but has an input in terms of the battery open-

circuit voltage characteristic with battery state-of-charge. This will be discussed in further

detail in Chapter 2, but to summaries, the open-circuit voltage of the iron-chloride (FeCl2)

component is 2.35V, while the nickel-chloride (NiCl2) component has a higher open-

circuit voltage of 2.58V. The combined cells are able to contribute a higher maximum

power [34, 38]. However, the battery internal resistance is now a more complex function

of current rate and SOC as will be discussed in Chapter 2.

The sodium is wicked to the top of the tube due to capillary force and wets it independent

of the sodium level in the anode compartment.

In Battery design, ZEBRA cells can be connected in parallel and in series. Different battery

types have been made with one to five parallel strings, up to 200 cells in series and 100-

500 cells in one battery pack. The battery Z5C, shown in Fig.1.6, has 216 cells connected

in one string which can provide open circuit voltage (EOC) of 557 V, two strings 108 cells

connected in parallel which can provide an EOC of 278V [34, 37].

Page 26: ANALYSIS AND MODELLING OF ENERGY SOURCE …

26

Rd

Cd

Rw

EOCNi Vterminal_Ni

(a) ZEBRA SL09 cell without iron doping.

Rd

Cd

Rw

EOCNi

Vterminal_Ni-Fe EOCFe

RFe

(b) ZEBRA ML1C and ML1D cell - with iron doping

Fig. 1.5 Possible electrical equivalent circuit representations for ZEBRA cells.

Ventilations Outer casing (Vacuum Insulated) Battery management

unit (BMI)

Circuit breaker

Fig. 1.6 Z5C standard battery [1.39].

In the ZEBRA Battery System Design, the battery has a management interface (BMI) that

can control the ohmic heater, the fan, the main circuit breaker which connected to positive

and negative poles of the battery, as shown in Fig. 1.6. The BMI measures and supervises

voltage, current, state-of-charge (SOC), insulation resistance of positive and negative to

ground and controls the charger, as shown schematically in Fig. 1.7 [34, 37].

Page 27: ANALYSIS AND MODELLING OF ENERGY SOURCE …

27

Fig. 1.7 ZEBRA battery system [34, 37].

A Multi Battery Server (MBS) is designed for up to 16 Z5C batteries connected in parallel,

yielding systems up to 285kWh/510kW [34, 37].

The ZEBRA battery has passed many stringent automotive safety testes. Tests, including

crash of an operative battery against a pole at 50km/h, over-charge, over-discharge, short

circuit, vibration, external fire and submersion of the battery in water, have been specified

and performed [34, 40, 41]. The ZEBRA battery has passed all those tests because it has

four barriers to safety, these are stated as: a barrier by chemistry, barrier by the cell case,

barrier by the thermal enclosure, and a barrier by the battery controller [40].

In terms of charging, the ZEBRA battery is charged with a current-voltage characteristic of

two regimes: the first is a normal charge at a 6 hour rate with an upper voltage limit of

2.67V per cell. The second regime is a fast charge at a 1hour rate with upper voltage limit

of 2.85V per cell; it is permitted up to 80% state-of-charge (SOC). During braking, the

regenerative is limited to 3.1V per cell and 60A per cell, as illustrated Fig. 1.8. The peak

power during discharge, defined as the power at 2/3rd’s OCV is independent of SOC and

gives a constant vehicle performance over the SOC range, as shown in Fig 1.9 [34, 37].

Fig. 1.8 Z5C battery performance [34].

Page 28: ANALYSIS AND MODELLING OF ENERGY SOURCE …

28

Fig. 1.9 Z5C Discharging [34].

1.5 Supercapacitor system

Supercapacitors are now being used in many applications where higher power densities

will be required. One of these applications is for load levelling in hybrid-electric vehicles

(HEV). Another high power application is in telecommunications, where short, high-power

pulses are required, and power smoothing in elevators [42- 46].

The supercapacitor (also known as an ultracapacitor), is one such technology, which is

often referred to as a double-layer capacitor, since charge is stored in two polarised liquid

layers formed when a potential exists between two electrodes immersed in an electrolyte. It

is an electro-chemical device. However, there are no chemical reactions involved in its

energy storage mechanism.

It is reported that such electro-chemical double-layer capacitors have been developed in

Japan using solid porous carbon on either side of a porous membrane containing a dilute

sulphuric acid electrolyte which is dispersed and in intimate contact with the high surface

area electrode material [43, 44, 47]. Supercapacitors can be viewed as two non-reactive

porous plates suspended within an electrolyte, with a voltage applied across the plates. The

applied potential on the positive plate attracts the negative ions in the electrolyte, while the

potential on the negative plate attracts the positive ions. This effectively creates two layers

of capacitive storage, one where the charges are separated at the positive plate, and another

at the negative plate. Capacitors store energy in the form of separated electrical charge.

Supercapacitors provide greater area for storing charge have closer separation than other

capacitor technologies, thus they have relatively high capacitance.

A conventional capacitor gets its area from plates of a flat, conductive material. To achieve

high capacitance, this material could be in great lengths, or sometimes have a texture

imprinted to increase surface area. A conventional capacitor separates its charged plates

with a dielectric material, sometimes a plastic or paper film, or a ceramic. These dielectrics

can only be made as thin as the available films or applied materials.

A supercapacitor gets its surface area from a porous carbon-based electrode material. The

porous structure of this material allows its surface area to approach 2000 m2/g, much

greater than that which can be accomplished using flat or textured films and plates.

Page 29: ANALYSIS AND MODELLING OF ENERGY SOURCE …

29

Supercapacitor charge separation distance is determined by the size of the ions in the

electrolyte which are attracted to the charged electrode. This charge separation (less than

10 angstroms) is much smaller than ones that can be accomplished using conventional

dielectric materials [50, 51].

The combination of extremely high surface area and small charge separation gives the

supercapacitor its outstanding capacitance relative to conventional capacitors.

The specific energy density of a capacitor or battery is the energy in Joules divided by the

capacitor or battery weight, and usually expressed as Watt-hour per kg (Wh/kg). The

critical characteristics of a supercapacitor are its energy density and power density (W/kg).

The energy density is dependent on the capacitance and maximum voltage, while the

power density is dependent on the equivalent series resistance (ESR) and maximum

voltage. Although supercapacitors have a low specific energy of 5.72Wh/kg, the rated peak

power capability is 17.5kW/kg [47-49]. A comparison between different technologies

regarding to energy density and power density is illustrated in Ragone plot of Fig. 1.10.

10 100 1000 10000 Power density (W/kg)

Ene

rgy

dens

ity

(Wh/

kg)

1000 100 10 1.0 0.1 0.01

Fig. 1.10 Energy density and power density for different technologies [52].

A supercapacitor cell basically consists of two electrodes, a separator, and an electrolyte. A

schematic diagram of the structure of a supercapacitor is presented in Fig. 1.11 (a).

Although it may be considered as a relatively simple layered system, it is only upon closer

consideration of the nature of each component that the real complexity is revealed.

The design of the electrodes is very important for Electro-chemical Double-Layer

Capacitance (EDLC) performance. The electrode does not only determine the capacitance

but also contributes to the equivalent series resistance (ESR). The electric charge stored in

the layer is proportional to the surface area of the electrode and reverses proportional to

thickness of the double layer. Optimizing the pore-size distribution of the electrodes

improves the high-rate charge/discharge characteristics [50, 51].

Page 30: ANALYSIS AND MODELLING OF ENERGY SOURCE …

30

Electrodes

Electrolyte Separator

60.4mm

138mm

Weight=0.51 kg

(a) Supercapacitor structure. (b) 3000F Maxwell cell.

191 mm

157mm

418mm

Weight=13.5 kg

(c) 165F 48V Maxwell module.

Fig. 1.11 Maxwell supercapacitor [49].

There are two main supercapacitor categories defined with respect to their electrode

materials

• Carbon based materials: many studies have been undertaken on carbon material as the

electrode [51]. Carbon is used as an electrode material very frequently due to low cost,

high surface area and its availability. Carbon is available as powders or fibres. Both

stability and conductivity of the activated high carbon area is decreased with increasing

surface area. Moreover, activated carbon with larger pores is more suitable for high

power applications. The accessible time to pores of various sizes was correlated with

the pore size distribution of the materials [53].

• Metal oxides: metal oxides are suitable for aqueous electrolytes; hence the nominal cell

voltage is limited to 1 V [53].

A simple capacitor is supposed to be capable of discharging and charging at high rates,

limited only by a small equivalent series resistance. However, based on high specific

area porous electrode materials, power limitations arise due to the complex distribution

of electrolyte internal resistance [54]. The main electrolyte technologies used are:

• Organic: the advantage of this kind of electrolyte is the higher working voltages

that can be achieved. However, organic electrolyte has a higher specific resistance

that reduces the maximum power. Fortunately, this reduction in power is

compensated for by the higher cell voltage.

Page 31: ANALYSIS AND MODELLING OF ENERGY SOURCE …

31

• Aqueous: the cost of aqueous electrolyte is much lower than organic electrolytes.

The unit cell voltage of this technology is limited to 1V; the main advantage of

aqueous electrolyte is higher conductance [53].

Separators are a key feature of the technology where is high porosity, high strength,

and ultra-thin manufacture are critical because the impedance of the electrolyte

separator is proportional to its thickness and inversely proportional to its porosity.

There are a number of polymeric separators now available. Although it is an expensive

element, it provides a low impedance and high strength with a thickness of 20~40µm

[47, 52].

Fig. 1.11 illustrates a typical commercial 300F, 2.7V supercapacitor cell from Maxwell

technologies (b) and a 48V, 165F pack that essentially equates to 18 of the 3000F cells in

series (c) [49]. Three of the 48V, 165F supercapacitor packs connected in simple series are

used in the DESERVE vehicle power-train, the sizing and characterisation of which is

discussed in Chapter 4.

1.6 Comparison of Energy Source Technologies

The choice of battery and supercapacitor technologies vehicles is difficult, and the

assessment criteria somewhat arbitrary. Data that has generally formed option and

impacted on the choice of battery for electric technology has been specific energy versus

specific power, so called Peukert data. For a pure electric vehicle, high battery energy is

generally required to fulfil the requirement for range between the recharging cycles.

With a hybrid-electric vehicle, and especially a parallel hybrid where the internal

combustion engine (ICE) has a relative low power, it is important that the battery can assist

the engine via the electrical traction machine when higher power is required. In this case, a

battery specified for high power is needed.

The safety issues should be considered in battery choice, as mentioned earlier, ZEBRA

battery has passed many stringent automotive safety testes including crash of an operative

battery against a pole at 50km/h, over-charge, over-discharge, short circuit, vibration,

external fire and submersion of the battery in water [34, 40, 41].

Specific energy performance data for various battery and supercapacitors are illustrated in

Fig. 1.12, showing energy and power densities (a) and (b) respectively and specific energy

and power (c) and (d) respectively, for comparison.

Page 32: ANALYSIS AND MODELLING OF ENERGY SOURCE …

32

0

50

100

150

200

0 50 100 150 200 250 300 350

Wh/l

Wh/

kg

Hawker Pb-acid

Maxwell SC

ZEBRA NaNiCl

SAFT NiMH

SAFT NiCd

SAFT Li-ion

1

10

100

1000

10000

100000

1 10 100 1000 10000 100000

W/l

W/k

g

Hawker Pb-acid

Maxwell SC

ZEBRA NaNiCl

SAFT NiMH

SAFT NiCd

SAFT Li-ion

(a) Energy density (b) Power density

1

10

100

1000

1 10 100 1000 10000 100000

W/l

Wh/

l

Hawker Pb-acid Maxwell SC

ZEBRA NaNiCl SAFT NiMH

SAFT NiCd SAFT Li-ion

1

10

100

1000

1 10 100 1000 10000 100000

W/kg

Wh

/kg

Hawker Pb-acid

Maxwell SC

ZEBRA NaNiCl

SAFT NiMH

SAFT NiCd

SAFT Li-ion

(c) Specific energy. (d) Specific power.

Fig. 1.12 Comparison of battery energy and power density for different technologies.

1.7 Vehicle Power-train Formats.

To overcome the problems of relatively low battery energy density (compared to ICE’s)

and limited peak power (of electro-chemical batteries) to the inception of alternative

vehicle power-train technologies, hybrid-electric vehicle (HEV) and fuel cell powered

vehicles (FCV) are being developed [2, 3, 23, 55-57]. ICE/battery hybrid EV’s are

commercially available, notably the Toyota Prius and Honda Insight, whole fuel cell

vehicles appear some way from commercialisation.

Hybrid-electric vehicles generally refer to ICE and battery combination vehicles where the

main design goals can be summarised as to:

• maximise fuel economy,

• minimise emissions,

• minimise system costs,

• retain good driving performance,

• satisfy all power demands.

The peak demand power could be satisfied by choosing either the ICE or battery as a main

energy source and the other as an auxiliary energy source. The vehicle energy source is a

Page 33: ANALYSIS AND MODELLING OF ENERGY SOURCE …

33

combination of energy and power-dense sources, where the energy dense source provides

energy to satisfy the requirements and the power-dense source provides the peak power for

acceleration and to sink regenerative braking energy thus alleviating the peak power

requirements from the energy-dense source [57-60].

Because an ICE’s natural output is mechanical power and any unnecessary energy

transformation is undesirable, ICE’s are usually applied in a parallel configuration where

two different energy sources, both with independent mechanical outputs that are combined

in parallel via a combinational gearbox to deliver energy to or accept energy from the

wheels, as shown in Fig. 1.13. It usually combines an internal combustion engine and an

electrical machine that is powered electrical via a source such as batteries or supercapacitor

[57, 61, 62]. For other candidate for main energy sources, such as Fuel cell, or secondary

batteries, series configuration is more suitable [23, 58].

The series hybrid-electric vehicle configuration employs a “down-sized” ICE operating at

or around a fixed speed point. The ICE output is mechanically disconnected from the

vehicle wheels and drives an electrical generator that supplies average energy to the

power-train DC-link. A battery usually provides the second energy source satisfying the

peak power demands and having some or no net energy contribution. Fig. 1.14 illustrates a

simple series hybrid-electric power-train configuration [23, 63].

The advantage of this combination is that the ICE has low fuel consumption and hence

emission and high conversion efficiency because it runs at its optimal speed and torque.

The disadvantage is lost energy due to the two stages of power conversion during the

transformation of the energy between the ICE and the wheels (ICE/generator and

generator/motor) [2, 3, 23]. However, this configuration lends itself to more advanced

power-train configurations where the ICE and associated generator may be replaced by the

fuel cell system, or alternatively fuelled (i.e. bio fuelled, hydrogen) energy converter [55,

57, 65].

Many other power-train configurations have been proposed to-date, but these are outside

the scope of this study. For this thesis, the series hybrid-electric vehicle configuration will

be studied in Chapter 5 where the down-sized ICE is employed in a range extending

function for a pure battery electric vehicle. Chapter 2 to 4 will consider pure electric

vehicles utilising more than one electrical based on-board energy sources, specifically high

energy ZEBRA batteries and supercapacitor power-train combinations, as illustrated in

Fig. 1.15.

Page 34: ANALYSIS AND MODELLING OF ENERGY SOURCE …

34

Battery

ICE

Fuel tank

Torque coupler

Transmission

Inverter TM.

Traction Machine

Differential

Fig.1.13 Parallel hybrid-electric configuration.

Inverter

Battery

Rectifier

T.M.

ICE G

Differential

Fig. 1.14 Series hybrid-electric vehicle power-train configuration.

Inverter

Supercapacitor bank

Battery

T.M. Differential

Traction Machine

Fig. 1.15 hybrid energy source, pure EV configuration.

1.8 The scope of the research study.

In this study, the works have been concentrated mainly on the energy sources that could be

combined with EV energy source which is a high-temperature sodium nickel chloride

(NaNiCl) ZEBRA battery. The study is mainly for energy sources modelling. They include

investigating the appropriate characterisation test methodology and the suitable modelling

Page 35: ANALYSIS AND MODELLING OF ENERGY SOURCE …

35

approach for ZEBRA battery alone or combined with another energy source, and then

optimise the energy storage combination to realize the full potential.

The vehicle model will be used to assess different energy source combinations to achieve

an energy efficient combination, to get good vehicle performance, but importantly, to

understand the energy source interconnection issues in terms of energy flow and circuit

transients.

This dynamic simulation of the power-train will be one of the novel features of this

research study, differentiating the work from other vehicle simulators, for example

ADVISOR, that tend to use more energy value models since global as apposed to dynamic

performance (i.e. speed, emissions energy) are the main calculable.

In the modelling works, the motivated aspects have been applied for several energy/power

sources technologies, i.e. ZEBRA battery, supercapacitor and ICE with PM generator are

concentrated in this study.

In introduction to the environmental issues and motivating factors focussing this research

is given in Chapter 1, followed by a background discussion of the ZEBRA battery

technology, supercapacitor systems and ICE’s. A number of vehicle power-train formats

are presented, again as background, and clarify terminologies. Chapter 2 will introduce the

electric vehicle model that will be used throughout the remaining thesis. Chapter 3 will

discuss issues surrounding the multiple connections of traction batteries. Chapter 4 a

ZEBRA and supercapacitor power-train study, and Chapter 5 a ZEBRA battery and ICE

combination for inner city and inter city driving. Finally, Chapter 6 will conclude the

research study.

1.9 Summary. Although the range of ICE vehicle is rapidly improved comparing with Electric vehicles

(EV’s), the environmental issue was, and still is, problematic with ICE emissions in

general continue to reduce, carbon dioxide emissions have not reduced significantly, this

against a background of an increasing number of vehicles.

The electro-chemical battery is a key technology for future EV development. ZEBRA

battery is one of the promising technologies in the UK, and recently it has been enquired

by GE in the USA under name of NaMx battery.

More than one energy source in an electric vehicle power-train, is an interesting

proposition especially if the combination aims to target the specific qualities of the energy

source, for example the energy density of electro-chemical battery and power density of

Page 36: ANALYSIS AND MODELLING OF ENERGY SOURCE …

36

supercapacitors or electro-mechanical flywheels. Here in Chapter one, an overview has

been given of some technologies such as ZEBRA and supercapacitor, the goal is to

investigate the problems faced by the limited energy density of existing state-of-art electro-

chemical batteries. In following Chapters, combinations of limited energy battery and a

high power density source are suggested; Chapter 2 will introduce the electric vehicle

model that will be used throughout the remaining thesis, while Chapter 3 will discuss

issues surrounding the multiple parallel connections of traction batteries. In Chapter 4, a

ZEBRA and supercapacitor power-train will be studied and a ZEBRA battery and ICE

combination for inner city and inter city driving discussed in Chapter 5.

Page 37: ANALYSIS AND MODELLING OF ENERGY SOURCE …

37

CHAPTER 2

ELECTRIC VEHICLE SIMULATION MODEL

2.1 Introduction.

The systems that are potentially high cost and require high research and development effort

could be simulated to reduce the cost. This is the case for EV components, since prior

background is very new and hence the production of EV components is expensive and

operational development time is long. To reduce cost, development time and processes,

and minimize the number of prototypes, the simulation of electric vehicle power-trains and

their associated energy source components is an essential step.

In this Chapter, a Matlab/Simulink model of EV power-train components is implemented

aiming to achieve the highest efficiency possible for different energy source combinations

in different power-trains. This requires models to calculate power consumption, power

losses, and energy use. The model included energy sources such a batteries and

supercapacitor, internal combustion engines (ICE). In addition, electrical traction machines

and converters form load elements in the power-train. Additional electric auxiliary sources

could be added to the model, for example a fuel cell range extender.

Today, the simulations of electric energy source components as well as other components

in the power-train are mostly dependent on characteristic functions of individual

components. However, the real behaviour is dependent on various parameters such as input

/output power, current, and voltage for each componenet, the component characteristic and

their interaction in a larger complex system. The developed model is studied and calibrated

Page 38: ANALYSIS AND MODELLING OF ENERGY SOURCE …

38

against real vehicle test data from large urban electric vehicles supplied by the DESERVE

consortium.

2.2 Modelling Techniques.

Modelling techniques can be classified into two categories:

• Steady-state and dynamic modelling This kind of model describes the behaviour of the system over a certain period of time.

Steady-state models show the behaviour of each component in the power-train from a high

level to be analysed over specify drive cycles. The technique is useful for developing the

power-train structures or power-train operation such as discussed in [65] where the vehicle

model is used to optimise power-train performance and to improve efficiency.

The dynamic model describes the transient behaviour of the system and analyses the

interactions between all components in the power-train including losses that might occur

during transient loads such as braking.

• Backward-facing and forward-facing modelling

The backward-facing model considers the desired vehicle speed as the input to the model

then determines operation according to that how the system reacts. Using the kinematical

relationships of the vehicle drive-train, i.e. the vehicle mass, tire, and road characteristics,

road incline and aerodynamics is calculated the mechanical torque to accelerate the vehicle

at the input demand speed. From this point and backward to the energy source components,

performance can be calculated [66, 67, 68].

On the other hand, Forward-facing modelling takes as inputs the driver commands and,

simulating the physical behaviours of each component, generates the vehicle performance

as outputs. This forward aspect is the best considered as using the present speed as an

initial input parameter to track the desired speed using a control [67, 68].

Generally, an effective and useful vehicle simulation tool should meet the following

requirements:

• accurate representation of vehicle dynamics and estimation of the performance for a

given driving cycle,

• including many different vehicle components, vehicle configurations, and

Page 39: ANALYSIS AND MODELLING OF ENERGY SOURCE …

39

• an open architecture to allow modification of any subsystem, including the ability to

create new component models from specific data.

There are many software packages available to simulate electric vehicles. Most software is

based on or able to communicate with Matlab /Simulink environments, such as ADVISOR

[2.4] and QSS-TB [69].

ADVISOR was initially developed by the National Renewable Energy Laboratory, USA,

in 1994, with many inputs from public, commercial and private sources. After some

development, the open access structure became restricted and commercialised. The

software claimed to facilitate understanding in the design electric vehicles and associated

components [68]. ADVISOR is developed as an analysis tool using fundamentally a

backwards-facing modelling technique. However, ADVISOR is lacking in some functions

needed for design; for example, it cannot be used for fast dynamic simulation due to the

fidelity of the individual model elements [68, 70].

PSIM is another software package used to simulate vehicle power system; it has been

developed to simulate power electronic switching and digital control in the vehicle systems

[71]. However, such detail becomes time cumbersome for large system simulation where

the time being simulated may run into many hours, for example, a full traction battery

discharging.

Modelica is another package used for vehicular system simulation; it is an object-oriented

modelling language. Modelica discussed in detail in [72], it is based on the physical

properties and chemical phenomena of components and, again, is unsuited to full vehicle

performance simulation and analysis.

2.3 EV Simulation Model.

2.3.1 Overview.

While there are a number of commercial simulation tools, the simulation model elements

must each have suitable resolution to model detailed dynamic operation, an important

consideration when assessing the specification requirements for the interconnection of

multiple electrical components and their associated interface power electronics.

Matlab/Simulink is a powerful and flexible programming tool specifically targeted to

technical computing tasks. It is based on Block diagram models and constitutes an

effective environment to construct complex, highly inter-related vehicle models.

The model developed as part of this thesis research, is based on the Matlab/Simulink

programming environment and simulates cases which could be presented for a number of

Page 40: ANALYSIS AND MODELLING OF ENERGY SOURCE …

40

vehicle power-train components. The components can be interconnected to investigate

alternative energy sources and power-train components proposed for electric vehicles, the

combination of which is undertaken to exploit their various attributes.

The simulation model is used to integrate separate components models into a complete

vehicle model that will approximate the behaviour of the system of interest. Resulting

simulations illustrate how component choices affect the overall performance of the system

beyond the particular aspect that motivated any particular selection and hence the

simulation tool greatly enhances the learning experience. The system model presents a set

of combinations which by appropriate selection, and sizing and configuring allows some

optimisation of the vehicle components to satisfy the performance requirements.

Further in the thesis the simulation model is used to study combinations of energy and

power-dense sources. The energy-dense sources are specified and operated to fulfil the

requirements for vehicle range, while the power-dense sources provides the peak power for

acceleration or to recover regenerative braking and to alleviate the peak power

requirements of the energy-dense source ( usually either an electro-chemical battery or

ICE).

There are many options of energy source combinations for electric vehicles, in this study

the ZEBRA battery is chosen to be modelled as the main energy-dense source, since this

technology is the chosen one of the DESERVE project and test data is readily available

against which to validate the model. Supercapacitors are simulated as a part of the model to

present a power-dense option. An ICE based on available Toyota Prius data is

implemented along with a brushless permanent generator set, data for which is available

via the thesis project supervisor.

A high level representation of the electric vehicle simulation model is illustrated in Fig 2.1

consisting of inputs, energy system models and output Blocks. The input parameters are

classified into three parts:

(i) the first one is drive-train, shown in Block 1. Here, a selection can be made from

the library of traction machine with auxiliary loads. In addition, management

ON/OFF switch is used for change of energy source combination.

(ii) Block 2 is a set of inputs including standard and developed vehicle velocity profiles,

vehicle parameters that are used for mechanical torque calculation. The various

parameter sets are selected from libraries for battery and supercapacitor

respectively.

(iii) Block 3 is the control scheme to control the energy flow between energy sources

components.

Page 41: ANALYSIS AND MODELLING OF ENERGY SOURCE …

41

(iv) Block 4 and 5 defines energy sources parameters, for the battery and supercapacitor

respectively such as number of cells, batteries, initial state-of-charge (SOC) etc. The

combination of energy source and their parameters are changeable depending on the

vehicle application.

(v) Finally, the output Blocks 6 and 7display detailed results such as currents, voltages,

dynamic state-of-charge, energy-in, energy-out, losses, and range.

Fig. 2.1 High level representation of electric vehicle simulation model.

2.3.2 Vehicle Parameters-Block 2 There are many parameters that need to be taking into account during simulation. In order

to evaluate the performance of the vehicle under different modes of operation and to

compare performance with different vehicle types, a standard basis for comparison is

required. For vehicle benchmarking, this usually the vehicle driving cycle which contains

typical road velocity profiles and gradient data, thus defining the various dynamic

conditions, i.e. acceleration, deceleration, and speed. Some driving cycles simulate urban

driving cycle and other cycles are used to simulate out of city or motorway driving. In this

model, a number of driving cycles are included in the main model library in Block 2 as

well as gradient profiles for each driving cycle, example of which are illustrated in Fig.

2.2.

Page 42: ANALYSIS AND MODELLING OF ENERGY SOURCE …

42

(a) Velocity driving cycle options. (b) Gradient options for each driving cycle.

Fig. 2.2 Velocity and gradient profiles for some driving cycles.

2.3.3 Vehicle road load and traction forces-Block 2. A simplified model of the road vehicle kinematics can be used to estimate the dynamic

tractive requirement of the vehicle drive-train, from which the individual component

specifications can be rated with-regard-to their peak and continuous duties. The vehicle

model accounts for the resultant forces acting against the vehicle when starting and when

in motion, as illustrated in Fig.2.3.

selected D. C.1

SEVNewc

SEV290808

NEDCnorm

NEDCenh

NEDC DESERVEMultiportSwitch

JAP11

HFET

FTP75

Edison

ECE15norm

ECE15enh

ECE15 DESERVE

SELECTED No.1

THETA 1

theta of SEVNewc1

theta of SEVNewc

theta of NEDCnorm

0

theta of NEDCenh

0

theta of HFET

0

theta of FTP75

0

theta of Edison

theta of ECE15norm

0

theta of ECE15deserve

0

theta of JAP11

0

theta od NEDCdeserve

0

MultiportSwitch

Divide

theta of ECE15enh

0

DC selection2

Selection No.1

Page 43: ANALYSIS AND MODELLING OF ENERGY SOURCE …

43

Fig. 2.3 Forces acting against the vehicle when starting and when in motion.

These forces can generally be considered as comprising of four main components:

• the force to overcome the tyre to road power loss, or rolling resistance,

θcosgmKF rr =

• the resistive force related to the road gradient, θsingm ,

• an aerodynamic resistance or drag force, 2

2

1vACF fda ρ= , and

• the transient force required to accelerate or retard the vehicle, dt

dvm .

The above components forces are summed to yield the total force required at the vehicle

wheels expressed as a function of the vehicle linear motion, i.e.:

dt

dvmFmgFF ard +++= θsin (2.1)

where: rK is the rolling resistance coefficient which includes tyre loss and is

approximated to be independent of speed and proportional to the vehicle normal reaction

force, m is the vehicle and payload mass, θ is the road gradient, g is the gravitational

constant, ρ is the density of the air, dC is the drag force coefficient, fA is the vehicle

frontal area, and v is the vehicle linear velocity.

Having determined the forces acting upon the vehicle, the road wheel torque can be

calculated from the equation of the motion:

dwf

www Frd

dt

dJT ⋅⋅+⋅=

ω

(2.2)

where: wJ , wω , wr are the wheel inertia, angular velocity and mean radius, respectively,

and fd is a distribution factor proportioning torque distribution on the rear axle. By way

FrFr

Page 44: ANALYSIS AND MODELLING OF ENERGY SOURCE …

44

of example, for a direct rear wheel drive scenario where it is assumed that there is an equal

share of the required tractive force between each rear wheel drive machine fd =0.5. For a

single on-board drive machine option df =1.0. If a gear stage is included in the drive-train,

the output torque of the traction machine is related to the road wheel torque by the total

transmission gear ratio, nt transmission efficiency, ηt, and the machine rotor inertia, mJ .

Here, the total gear ratio and efficiency include the contribution of the differential if

included. Incorporating these components into the equation of motion yields a general

expression for traction machine torque:

w

tt

mmm T

ndt

dJT

ηω 1+= (2.3)

Expressing the wheel and traction machine angular velocities in terms of the vehicle linear

velocity yields:

ww r

v=ω (2.4)

wtm r

vn=ω (2.5)

From which the machine torque equation can be expressed in terms of the vehicle linear

velocity by substituting equations (2.1), (2.2), (2.4), and (2.5) into equation (2.3):

f wt t w

m w t t w t t

d r mn J d vT r n r n d t

ηη η

+ + =

2( cos sin ) 0.5f w

r d ft t

d rk mg C A v

nθ θ ρ

η + + +

(2.6)

The parameters included in the equation depend on the vehicle type. In the model, the

vehicle library contains a number of vehicles options with their parameters. The

mechanical power needed to satisfy the prescribed vehicle velocity driving cycle is the

torque multiplied by the mechanical speed:

mmm TP ω.= (2.7)

2.3.4 Traction machine model-Block1. To find the total electrical power that taken from the energy system of the vehicle, it is

necessary to include all component losses in the power-train. In this model, the efficiency

Page 45: ANALYSIS AND MODELLING OF ENERGY SOURCE …

45

of the gear system and electrical machine are lumped together since this is as presented by

vehicle test data available from DESERVE. There are therefore three options available in

the model:

• a library of traction machine efficiency is built in the model as a 2-D array,

• a simple fixed efficiency option,

• a traction machine, inverter and gear stage specific efficiency map in 2-D array. The

machine operates as a motor in acceleration mode or as a generator in regenerative

mode, thus the energy flow considered and calculated from the efficiency map. An

example of the efficiency map. The efficiency map Look-up table as implemented in

the model is illustrated in Fig. 2.4.

According to the losses in the electrical machine, the electrical power input to the machine

inverter is greater than the mechanical power in motoring case and less than the

mechanical power in regenerating case. In Fig. 2.4, the positive torque Tpve (motoring case)

and negative Tnve (regenerating case) are differentiated as illustrated by equations (2.8) and

(2.9) respectively.

ηm

electric

PP =

(2.8)

η.melectric PP = (2.9)

where Pelectric is the demand electric power from traction machine, and η the specified

conversion efficiency at particular operating point to calculate the losses. Considering the

mechanical power requirements and traction machine, inverter and transmission losses, the

total traction power is added to other electrical system loads, such as auxiliaries etc., thus

calculating the total power required from the on-board energy systems:

loadssauxiliariemdemand PPP += (2.10)

LookupTable (2-D)

Power

-K-

Tnve

Tpve

Speed

Torque

Abs

|u|

%

100

Fig. 2.4 The efficiency map as a 2-D Look-up table in the model.

Page 46: ANALYSIS AND MODELLING OF ENERGY SOURCE …

46

2.3.5 ZEBRA Battery model

In electric vehicles, the battery model as the main energy source is a very important issue

on which to focus. As previously stated the main energy source that has been the focus in

this thesis is the ZEBRA battery. Many researchers have published papers describing a

wide range of battery models [73]. The battery is a key element in the energy source

system of electric vehicles; hence an accurate battery model is a very important for a

vehicle model as a whole to improve the total system energy efficiency predictions. The

battery model must be robust and model the battery chemical phenomena such as the

diffusion effects, ohmic resistance, self discharging and mass transport limitations so as to

predict accurate battery voltage, current, and state-of-charge (SOC). There are several

battery models, reported in the literature, aimed to reflect the battery characteristics. The

simplest battery model is shown in Fig. 2.5(a) consisting of an ideal voltage source (EO)

and a constant equivalent internal series resistance (ESR) [73, 74].

The model does not account for the variation of open-circuit voltage and resistance with

the variation of SOC and charge/discharge current. This model is widely used where the

energy of the battery is assumed to be unlimited and is hence not suitable in this study

because the energy calculation is very important. This simple model is improved and

becomes more dynamic if the non-linear characteristics of both open-circuit voltage and

internal resistance are considered [75].

The authors in [76, 77] described the equivalent circuit model, shown in Fig 2.5(b), as a

dynamic model where the parameters vary with SOC, temperature and direction of current.

In ADVISOR this model is called the internal resistance model and offers parameter for

many types of batteries except the ZEBRA. Moreover, the ESR SOC functions are limited

to 3 or 4 characteristics which subsequently limit simulation resolution. Also, voltage

predictions in the model show a maximum error of 12%, while energy prediction accuracy

is not stated.

Some authors present models that include capacitive element to represent dynamic battery

plate characteristics and to get smooth responses across the terminals [76]. Thevenin type

battery models are commonly used as shown in Fig. 2.5(c). All parameters including open-

circuit voltage EOC, internal resistance R, the overvoltage resistance RO, and the

capacitance of the parallel plates CO are constant. This is a disadvantage because the

parameters should vary with the battery condition.

Page 47: ANALYSIS AND MODELLING OF ENERGY SOURCE …

47

The resistance-capacitance model and Partnership for a New Generation Vehicle (PNGV)

model also use resistive capacitive combinations, as described in [76, 77] and are shown in

Fig. 2.5(d) and (e) respectively.

ESR= f (SOC)

EOC= f (SOC) + -

(a) Simple equivalent circuit

battery model. (b) More dynamic battery equivalent circuit model.

RO

R

EOC

CO

Rt= f (T,SOC) Re= f (T,SOC)

Rc= f (T,SOC)

Cc= f (T) Cb= f (T)

Ro C=1/Voc

Cc= τ/RP RP

(c) Thevenin battery model. (d) The resistance-capacitance model.

(e) PNGV model including capacitance.

Rd

EP Es

Rs

Rp

Cd

Cw

Rw

(f) Forth-order dynamic model. (g) Three branches battery model.

Fig. 2.5 Several battery models.

Another fourth-order dynamic model is proposed in the literature [79]. Here, the model

contains capacitance, resistance and two emf source elements, as shown in Fig. 2.5(f). The

RC branches describe ohmic effect Rd and Cd, waste energy is modelled by Rw and Cw,

while resistors Rd and Rs account for electrolyte reaction and self discharge respectively.

The model is complicated by the significant use of empirical data.

The authors in [79] convert the series equivalent circuit to parallel branches to describe the

charge and discharge efficiency over a wide frequency range. They state that battery

efficiency does not depend on current levels, but varies greatly with frequency. The model

is in three branches as shown in Fig. 2.5(g), but it could be simplified to one or two lumped

braches. It is stated in [79] that the model is not capable of accounting for the full

Rc Rb

Cb Ca

Ra

Cc

Page 48: ANALYSIS AND MODELLING OF ENERGY SOURCE …

48

frequency range of interest. Note, for typical EV systems the battery DC link current has a

very low power dynamic, typically less than 100Hz.

Finally, other approaches to battery modelling use computational intelligence techniques

such as artificial neural networks (ANN) to design a non-linear function for the battery

parameters. The tool is based on training data, so the model will be only an accurate over

the training range [76].

As mentioned, the ADVISOR software offers five battery models with validation date for

lead-acid and NiMH batteries [76], the ZEBRA battery is not included. In [80], the author

illustrated an equivalent circuit model of the ZEBRA battery to explore the electro-

chemical behaviour of the cell. The model is based on how the parameters are determined.

It found out that for example; the iron cell resistance is estimated based on nickel

resistance. However, actual nickel resistance is difficult with an increased Depth-of-

Discharge DOD.

Instead of modelling detailed chemical properties, the battery model used in this thesis is

based on electrical terminal data provided as part of the DESERVE program. The model

implements a detailed non-linear open-circuit emf characteristic that is only a function of

state of charge (SOC) and both discharge and charge resistances that are complicated

functions of SOC and the magnitude of charge/discharge current. Test were specified and

to Beta R&D who then carried at the test regime, collected and supplied the test data [82].

2.3.6 Battery state-of-charge (SOC)

The battery state-of-charge (SOC) describes the available capacity in relation to the

nominal capacity of the battery. SOC is the relative remaining stored charge (Ah) in the

battery and is usually expressed in percentage or per unit [83, 84]. The battery SOC is the

key quantity as it is a measure of the amount of electrical energy stored in or released from

the battery during charging or discharging respectively, effectively equating to a fuel gauge

in conventional vehicle SOC is calculated from:

total

actual

Q

QSOC=

(2.11)

where: Qactual is actual battery charge, and Qtotal is total battery charge.

This parameter is very important for any a successful energy management scheme, hence

an accurate calculation or measurement is required for SOC. Many techniques have been

Page 49: ANALYSIS AND MODELLING OF ENERGY SOURCE …

49

used for SOC calculation, the author in [85] determine SOC using fuzzy logic techniques,

while others use Peukert’s as in [86], and neural network as in [87]. Since the ZEBRA

technology is 100% columbic efficient (as discussed in Chapter 1), SOC can be accurately

measured by measuring and recording (data logging) amperes in, and out of the battery [5].

In most SOC calculations, the charge/discharge current is integrated over time and related

to battery nominal capacity. This study considers that the available capacity of the battery

changes as a function of charge/discharge current. Hence, SOC is tracked according to the

battery terminal current and calculated via:

3600

.'

Ah

dtISOCSOC ∫−

=

(2.12)

where SOC’ is the initial state-of-charge, I the charge/discharge current, and Ah the

capacity of the battery (Ampere-hour).

2.4 The ZEBRA Battery Model

The ZEBRA battery is modelled in the Matlab/Simulink environment using the look-up

table technique populated with experimental test data. The model is used to assess the

battery dynamics and to understand the interconnection issues in terms of energy flow,

circuit voltages and current transients. An overview of the ZEBRA battery model is

illustrated in Fig. 2.6, and the model execution process described in the flowchart of Fig.

2.7.

Fig. 2.8 illustrates the ZEBRA model in Simulink environment, showing a Look-up table

to calculate the internal resistance as function of SOC and current, and Lookup table to

calculate the open-circuit voltage as a function of SOC. The results of the Look-up table

for the internal resistance and the open-circuit voltage are illustrated in Fig. 2.9 and Fig.

2.10, respectively. Typical output results from the ZEBRA model in terms of power loss,

internal resistance, state-of- charge, open-circuit and terminal voltage when the battery is

discharged over NEDC driving cycles are illustrated in Fig. 2.11.

Page 50: ANALYSIS AND MODELLING OF ENERGY SOURCE …

50

Fig. 2.6 The layout of ZEBRA battery model.

Fig. 2.7 The flowchart of the model process.

Current demand

Discharging

charge ( disq )

Idtqdis ∫=

Rint Look-up table

Eoc Look-up table

The voltage drop on Rint

State of Charge (SOC)

The voltage of the battery is calculated

The result

Power profile (input data)

Power

demand

SOC

SOC & Current

Calculations

I

VOC

Look up table

Rint Look up table

+ -

Page 51: ANALYSIS AND MODELLING OF ENERGY SOURCE …

51

Voltage drop

3

Terminal Voltage

2

Eoc

1

change to ohms

0.001Rint=f(SOC, I) as Look up Table

Eoc=f (SOC) as Look up Table

Current (I)

3

No. of cells

2

SOC

1

Fig. 2.8 ZEBRA model in Simulink environment.

Fig. 2.9 The results of Look-up table for the internal resistance.

2.3

2.35

2.4

2.45

2.5

2.55

2.6

2.65

2.7

00.20.40.60.81

SOC

Eoc/

V .

Fig. 2.10 The results of Look-up table for open circuit voltage.

Page 52: ANALYSIS AND MODELLING OF ENERGY SOURCE …

52

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000-50

0

50

100

Time (s)

Current (A)

(a) Battery current.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000

1

2

3

4

5

6

7

8

9

Time (s)

Internal Resistance (ohm

s)

(b) Battery internal resistance.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000500

510

520

530

540

550

560

570

580

Open Circuit Voltage (V)

(c) Battery open circuit voltage.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000300

350

400

450

500

550

600

Time (s)

(d) Terminal voltage.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

SOC

(e) Battery state-of-charge.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000

1000

2000

3000

4000

5000

6000

7000

8000

9000

(f) Internal power loss.

Fig. 2.11 ZEBRA model over repetitive NEDC driving cycle.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

1 0

SOC

Vol

tage

(V

)

Vol

tage

(V

)

Res

ista

nce

(mΩ

)

Cur

rent

(A

)

Pow

er L

oss

(kW

)

8 4 0

600 300

600 300

9 0

100 50 0 -50

Page 53: ANALYSIS AND MODELLING OF ENERGY SOURCE …

53

For a typical ZEBRA Battery System Design, the ZEBRA battery has battery management

interface (BMI) that can control the ohmic heater (to raise the battery temperature to

280oC) and a cooling fan that force ventilates the battery during high rate charge/discharge.

The BMI also controls the main circuit contactors that connect the positive and negative

poles of the battery [34]. Therefore, the battery limits voltage and current transients by

opening the main control contactors, for example, when the battery terminal voltage

exceeds the maximum voltage during regenerative braking, or the battery is fully charged,

or when the battery voltage drops below the minimum level during high acceleration, or

when near zero SOC. Thus, contactors are also included in the model via a block that

implements management interface (BMI). The battery management interface unit controls

the voltage limits by disconnecting the battery using electromagnetic contactors. Moreover,

other operating limits are implemented in the model, such as the charging and discharging

current and state-of-charge limits to avoid deep discharge of the battery [35]. In large

vehicle applications, a number of high-energy traction batteries may be connected in

parallel are to obtain the required energy and power. In this multi-battery system, an

additional controller is needed to supervise the BMIs of each battery, this controller is

called the multi-battery server, or MBS. The MBS supervise the individual batteries in the

system via their respective BMIs and the vehicle system. This management unit will be

discussed in Chapter 3, which investigates the problems of unbalance in multiple battery

systems.

2.5 Vehicle Model Validation

The vehicle model was simulated and results generated based on a known vehicle driving

cycle taken from test. To validate the model the model results experimental measurements

were taken from one of the smith Electric Vehicle’s (SEV’s), Edison Van over an

approved SEV driving cycle as part of the DESERVE project. The Edison Van model

parameters are detailed in Table 2.1. The Edison Van is powered via two ZEBRA batteries

(2x76 Ah), each with an initial state-of-charge (SOC) of 92%.

The analysis was undertaken for three tests:

(i) using a measured DC link power profile as a demand input to the battery system

simulation model,

(ii) using vehicle measured speed and gradient profiles and employing a fixed

efficiency for the traction machine and inverter, and

(iii) using vehicle measured speed and gradient profiles and employing an efficiency

map for the traction machine and inverters.

Page 54: ANALYSIS AND MODELLING OF ENERGY SOURCE …

54

For test (i) the measured DC link power profile used as a demand input to the simulation is

illustrated in Fig.2.12. This power profile is actual road test data provided via the

DESERVE project [21]. The calculated and measured SOC and a time-zoomed example of

terminal voltage are shown in Fig. 2.13 and 2.14 respectively, showing good agreement.

The difference in end-SOC is 2% from measured and there is a ± 3.7% variation in

predicted terminal voltage. The energy used during this test was 33.69kWh, thus a range of

64.42km was calculated from the associated velocity profile.

Equation (2.6)

parameters Description Value Units

m Mass during test 3140 kg Cd Co-efficient of drag 0.4 - Af Frontal area 4 m2 Kr Co-efficient of rolling resistance 0.016 - nt Gear and deferential ratio 11.95:1 - rw Tyre radius 0.364 m ηt Machine efficiency 0.85 p.u.

Other model parameters

Ratio of regenerative to brake energy 0.75 - Controller efficiency 0.9 p.u. Final gearing efficiency 0.85 p.u. ZEBRA battery capacity 76 Ah (each) Number of batteries 2 - Nominal voltage 280 V Inverter-Max output current 350 A Inverter-Max regenerative current 150 A

Table 2.1 Edison Van data.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000-40

-30

-20

-10

0

10

20

30

40

50

60

Time (s)

Pow

er (kW

)

Fig. 2.12 The measured power time profile for the SEV Edison Van used for case (i) of the validation study.

Page 55: ANALYSIS AND MODELLING OF ENERGY SOURCE …

55

0 2000 4000 6000 8000 10000 120000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SO

C

SimulatedMeasured

Fig. 2.13 The calculated and measured SOC.

100 200 300 400 500 600 700 800 900 1000150

200

250

300

350

Time (s)

Volta

ge (V)

SimulatedMeasured

Fig. 2.14 The calculated and measured terminal voltage.

Page 56: ANALYSIS AND MODELLING OF ENERGY SOURCE …

56

Case (ii) and (iii) include the Edison Van vehicle kinematics and equations (2.6 to 2.7) to

calculate the required power over the measured velocity and gradient profiles. Again, this

data was provided via the DESERVE project [5], shown in Fig. 2.15. The velocity driving

cycle is added to the driving cycle library Block 2 and the gradient profile added to

gradient library Block 2. The mechanical torque is calculated and thus the required

mechanical power. For case (ii) a fixed efficiency traction system is used to calculate the

required electrical power from the battery system, while in case (iii), the traction system

efficiency map explained earlier is used, both elements being options in Block 1.

Results for case (ii), the fixed efficiency drive system, are illustrated in Fig. 2.16, showing

the calculated SOC. The end SOC is greater than actual SOC by 12%. It is clear that the

energy used is less than the previous test, the energy used in this test for driving the van for

64.42km is 30.64 kWh because of the mode termination due to minimum voltage. Fig.

2.17 shows an example of the simulated and measured terminal voltages showing a

difference of 15V. Case (iii) considered an efficiency map implementation for the drive

system. The final SOC’s are different by 20% as shown in Fig. 2.18 (a), because of that

and as expected, the energy used for the same distance is less which 26.64 kWh. The error

of the SOC difference is shown in Fig. 2.18 (b). The voltage difference is now worse than

for case (ii) at 20V because the efficiency is worse than for the fixed efficiency case which

leads to more power required from battery system; Fig. 2.19 compares measured and

predicted terminal voltage. From the three tests it can be concluded that less energy or an

underestimate of energy is made when using a fixed efficiency drive system and efficiency

map drive system a opposed to the actual measured power profile as the input. To address

these uncertainties further tests were requested from the DESERVE consortium and

simulations undertaken to determine the sensitivity of results to the various model

parameters.

Page 57: ANALYSIS AND MODELLING OF ENERGY SOURCE …

57

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000

5

10

15

20

25

30

Time (s)

Spee

d (m

/s)

(a) Velocity-time data

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000-0.25

-0.2

-0.15

-0.1

-0.05

0

0.05

0.1

0.15

0.2

Time (s)

grai

den

t (d

egre

e)

(b) Gradient-time data

Fig. 2.15 Measured test data from the Edison Van.

Page 58: ANALYSIS AND MODELLING OF ENERGY SOURCE …

58

0 2000 4000 6000 8000 10000 120000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SO

C

SimulatedMeasured

Fig. 2.16 SOC results for case (ii) the fixed efficiency drive system test before calibration.

100 200 300 400 500 600 700 800 900 1000150

200

250

300

350

Time (s)

Volta

ge (V)

SimulatedMeasured

Fig. 2.17 Terminal voltage results for case (ii) the fixed efficiency drive system test before calibration .

Page 59: ANALYSIS AND MODELLING OF ENERGY SOURCE …

59

0 2000 4000 6000 8000 10000 120000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SO

C

SimulatedMeasured

(a) Test result of SOC.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000

0.05

0.1

0.15

0.2

0.25

Time (s)

SO

C d

iffe

ren

ce

(b) Difference in simulated and measured SOC.

Fig. 2.18 SOC results for case (iii) the efficiency map drive system test.

Page 60: ANALYSIS AND MODELLING OF ENERGY SOURCE …

60

100 200 300 400 500 600 700 800 900 1000150

200

250

300

350

Time (s)

Volta

ge (V)

SimulatedMeasured

Fig. 2.19 Terminal voltage results for case (iii) the efficiency map test.

2.6 Model Calibration

2.6.1 Acceleration Limits During the validation test using the Edison Van driving cycle, the peak acceleration

calculated from the measured vehicle velocity data was 3.4m/s2, which is too high, being

representative of high performance cars such as the Jaguar XJ6 (4.5m/s2) and the Aston

Martin (6.5m/s2) [74]. The calculated vehicle acceleration is shown in Fig. 2.20. There are

many techniques that could be used to calibrate the measurements, such as scaling the

original data profile, or cutting off any data points above the highest acceleration possible

for the Edison Van used in this research. The author feels that scaling the original data

profile is inappropriate as it results in mitigating parts of the measured realistic speed

profile, and therefore the cut off of the unexpected and unrealistic peaks that are artefacts

of measurements is chosen for data analysis. After discussions with SEV and inspection of

their test data, it becomes clear that there was noise or other errors on the actual measured

velocity test data Thus, given the extent of the measured DC link power data, a speed

limiter was used in the model, as shown in Fig 2.21, to limit the acceleration to 0.75 m/s2

which, after discussion with SEV, was deemed acceptable for a 3.5 tonne van. The

calibrated and the measured acceleration results are now shown in Fig. 2.22

Page 61: ANALYSIS AND MODELLING OF ENERGY SOURCE …

61

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000-4

-3

-2

-1

0

1

2

3

4

Time (s)

3200 3250 3300 3350 3400 3450 3500-3

-2

-1

0

1

2

3

4

Time (s)

Acc

eler

atio

n (m

/s)

Simulated acceleration

Fig. 2.20 Edison Van acceleration calculated from the vehicle measured velocity data.

Fig. 2.21 Acceleration limiter to correct measurement.

A

ccel

era

tion

(m/s2 )

A

ccel

era

tion

(m/s2 )

Time (s)

Time (s)

Limiter

Torque Limiter

Page 62: ANALYSIS AND MODELLING OF ENERGY SOURCE …

62

3430 3440 3450 3460 3470 3480 3490 3500-2

-1

0

1

2

3

4

Time (s)

Calibrated Measured

Fig. 2.22 Calibration of vehicle acceleration.

2.6.2 Braking Torque Limits The actual torque is constrained by the vehicle drive system limits. In practice, the braking

torque cannot be simulated because the drive system strategy is unknown. So to justify

and validate the model, the regenerative torque is analysed to calibrate the model by setting

the matched braking torque of the real drive system. To analyze the torque calculation, the

following analysis measures the impact of the regenerative energy on the calculation result.

The first step in this test is to investigate the effect of the regenerative torque on the range

and energy used. Table 2.2 and Fig. 2.23 show that when regerative torque was not taking

into account and limited to zero, all the battery energy is discharged in a distance shorter

than expected. In the case of using regerative torque, less energy was used resulting in

greater distance, which is thus over estimated. Hence, minimum regenerative torque will

be used and a set point chosen to ensure that the energy calculation agrees with actual.

In Table 2.3, the limiter on the torque is set to different regenerative torque values. For no

regenerative torque, the energy used could not establish the expected range. If the

regenerative torque is increased gradually, more energy is gained, but the minimum

voltage terminated the model at range of 60.88km, as shown in Fig. 2.24.

To justify the measured and simulated energy use, the minimum voltage of the battery is

set to 1.5V/cell. Table 2.4 and Fig. 2.25 show results for regenerative torques ranging

A

ccel

erat

ion

(m/s2 )

Time (s)

Page 63: ANALYSIS AND MODELLING OF ENERGY SOURCE …

63

from 0 to 75 Nm. It is clear from Fig. 2.25, that the measured SOC matches the simulated

SOC when the regenerative torque is 35Nm, as shown in Fig. 2.26. On application of this

calibration, the simulated and measured SOC of a fixed drive-train, as well as efficiency

map drive-train, show a good agreement, as illustrated in Fig. 2.27. The terminal voltage

of the calibrated and measured data is shown in Fig. 2.28.

Test Input energy

(Ein) Output energy (Eout)

Net energy used

SOC Range (km)

Power profile 5.93 33.42 27.49 0.13 64.42 With regen. 8.87 30.64 21.78 0.216 67.66

Without regen. 0 29.32 29.32 0.1 60.75

Table 2.2 Test of energy used.

0 20 00 4 000 6 000 800 0 1000 0 120 000

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time /s

SO

C

measured soccalculated soc witho ut regen.calculated soc with regen.

Fig. 2.23 SOC when regenerative torque limited to zero (no regen.).

Regen. torque limit set-point

Ein Eout SOC Range

0 0 29.2 0.1 60.75 -5 0.28 28.89 0.115 60.88 -10 0.85 28.86 0.131 60.88 -15 1.4 28.85 0.145 60.88 -20 1.9 28.4 0.158 60.88 -30 2.8 28.84 0.183 60.88 -35 3.27 28.84 0.193 60.88

Table 2.3 The regenerative torque is set to different limits.

Simulated with Regen. Measured SOC Simulated without Regen.

Page 64: ANALYSIS AND MODELLING OF ENERGY SOURCE …

64

0 2000 4000 6000 8000 10000 120000

0.2

0.4

0.6

0.8

1

Time (s)

SOC

soc at regen.T=0measured socsoc at max. regen. T = -5 soc at max. regen.T = -10 soc at max. regen. T=-15soc at max. regen.T=-20soc at max. regen. T=-30soc at max. regen.T=-35

Fig. 2.24 SOC at different regenerative torque set-points.

Regen. torque

set-point Ein Eout SOC Range

0 0 29.2 0.1 60.75 -5 0.29 29.4 0.1 62.36 -10 0.88 29.9 0.1 63.25 -15 1.45 30.37 0.1 63.93 -20 1.99 30.66 0.105 64.42 -30 2.97 30.65 0.13 64.42 -35 3.4 30.65 0.14 64.42 -40 3.83 30.65 0.151 64.42 -60 5.2 30.64 0.18 64.42 -75 5.9 30.64 0.2 64.42

Table 2.4 Regen. torque set-point vs. Energy used, Vcellmin = 1.5V.

Page 65: ANALYSIS AND MODELLING OF ENERGY SOURCE …

65

0 2000 4000 6000 8000 10000 120000

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SOC

Measurement socSOC at max. regen. T=-75SOC at max. regen. T=-60SOC at max. regen. T=-40SOC at max. regen. T=-30SOC at max. regen. T=-20SOC at max. regen. T=-15SOC at zero regen.

Fig. 2.25 Results of regenerative torque set-points from 0 to 75 Nm.

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 110000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SOC

Calculated socMeasured soc

Fig. 2.26 SOC when the regerative torque set-point is 35Nm. .

Page 66: ANALYSIS AND MODELLING OF ENERGY SOURCE …

66

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 100000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SOC

Simulated SOCMeasured SOC

Fig. 2.27 SOC for a fixed efficiency drive system after calibration.

0 100 200 300 400 500 600 700 800 900 1000150

200

250

300

350

Time (s)

Vol

tage

(V)

Simulated Measured

Fig. 2.28 Example of terminal voltage variations for fixed

efficiency drive system after calibration.

Page 67: ANALYSIS AND MODELLING OF ENERGY SOURCE …

67

2.7 Model Sensitivity

The developed ZEBRA battery model uses a look-up table of open-circuit emf versus

battery SOC and a look-up table of internal resistances versus SOC and charge-discharge

current. To test the sensitivity of the model to resistance data, the look-up table is replaced

by a constant resistance that is varied from 4 to 12 mΩ. The model is then tested for three

cases; (i) the measured power profile, (ii) the measured velocity profile with a fixed

efficiency drive system, and (iii) the measured velocity profile with an efficiency map

characterised drive system.

In the first case (i), as the internal resistance is increasing, the power (energy) loss is

increasing, thus more energy is used, and vice versa, as the internal resistance is decreased

less energy is used for the same distance, as shown in Table 2.5 and Fig. 2.29. As a result,

if the internal resistances of look-up table are averaged, the calculated SOC shows a good

comparison with the measurement SOC. The internal resistance is a function of

discharging current and SOC, so different current demand gives different internal

resistance. In other words, if the model uses a fixed internal resistance, this value should

be changed as driving cycle changed. This is a weakness of other battery models for

example those available in ADVOSOR.

The second case (ii) is to test a fixed (single-value) efficiency drive system in the model

having a different fixed resistance instead of look-up table resistance. The results are

illustrated in Table 2.6 and Fig. 2.30.

The third case (iii) is to test an efficiency map drive system in the model having a different

fixed resistance instead of look-up table resistance. The results are illustrated in Table 2.7

and Fig. 2.31.

It can be concluded from the results of the last two cases that as the battery internal

resistance is decreased (which equates to less energy loss) the SOC difference between the

measured and simulated is greater. On the other hand, when the resistance is increased

(more energy loss), the SOC difference is decreased, and the terminal voltage goes under

the threshold of battery minimum voltage, which terminates the simulation.

Page 68: ANALYSIS AND MODELLING OF ENERGY SOURCE …

68

Internal resistance (mΩ) SOC Distance (km)

12 0.27 49.47 10 0.124 64.42 8.5 0.154 64.42 8 0.163 64.42 6 0.194 64.42 4 0.22 64.42

Look-up table 0.132 64.42

Table 2.5 SOC for different battery internal resistance using power profile.

0 2000 4000 6000 8000 10000 120000.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time/s

SOC

Rin=4Rin=6Rin=8Rin=8.5look-up tableRin=10Rin=12

Fig. 2.29 SOC for different battery internal resistance.

Internal resistance

(mΩ) SOC Distance (km)

8.5 0.86 3.27 8 0.3 64.42 6 0.33 64.42 4 0.36 64.42

Look-up table 0.27 64.42

Table 2.6 SOC for different battery internal resistance

using a fixed efficiency drive system.

Page 69: ANALYSIS AND MODELLING OF ENERGY SOURCE …

69

0 2000 4000 6000 8000 10000 120000.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s)

SO

C

Rin=6Rin=8Rin=4Look-up tableRin=8.5

Fig. 2.30 SOC for different battery internal resistance

using a fixed efficiency drive system.

Internal resistance

(mΩ) SOC Distance (km)

8.5 0.437 64.42 8 0.44 64.42 6 0.46 64.42 4 0.48 64.42

Look-up table 64.42

Table 2.7 SOC for different internal resistance using efficiency map drive system.

0 2000 4000 6000 8000 10000 120000.4

0.5

0.6

0.7

0.8

0.9

1

Time/s

SO

C

Rin=8.5Rin=8Rin=6Rin=4Look-up table

Fig. 2.31 SOC for different internal resistance using efficiency map drive system.

Page 70: ANALYSIS AND MODELLING OF ENERGY SOURCE …

70

2.8 Summary

The proposed electric vehicle simulation model has been described in detail. The model

integrates separate vehicle component models into a complete vehicle drive system model

that will approximate the behaviour of the system of interest. The vehicle model will show

how component choices affect the overall performance of the system beyond the particular

aspect that motivated the selection. The system model suggests a set of combinations by

selecting, sizing and configuring the components, and then allows graphical optimisation

of the control scheme to realise the target performance requirements. The model will be

used to investigate proposed combinations of energy and power dense sources in detail in

subsequent Chapters of this thesis.

The energy dense source is specified and operated to fulfil the requirements for vehicle

range, while the power dense source provides the peak power for acceleration or collecting

regenerative braking energy, thus alleviating the peak power requirements of the energy

dense source. There are many options of energy source combinations for electric vehicles,

however, in this study the ZEBRA battery technology is chosen to be modelled as the

energy dense source since it, along with lithium-ion based technologies, shows the greatest

electro-chemical energy density to-date. Supercapacitors are modelled and simulated in

subsequent Chapters and an ICE and generator are modelled as a range extender unit for

sub-urban and inter-city travel in Chapter 5.

Instead of relying on detail characterisation of battery chemistry, the battery model is

modelled based on its electrical terminal behaviour, implementing a detailed non-linear

characteristic of both discharge and charging resistance to model performance. The model

is calibrated and validated by measured data provided by the DESERVE project.

The model sensitivity to battery internal resistance has been studied, where it has been

concluded that as the look-up table implementation of internal resistance showed an

excellent agreement with measured results.

Page 71: ANALYSIS AND MODELLING OF ENERGY SOURCE …

71

CHAPTER 3

MULTI-BATTERY OPERATION

3.1 Introduction

In high energy/power vehicle applications, for example buses, lorries, off-road military

vehicles (tanks, armoured personnel carriers etc.), a number of batteries may have to be

connected in parallel to obtain the required energy levels or satisfy the peak power

demands, moreover to increase the fault tolerance capacity [88, 89].

The parallel connection makes the system venerable in the event of unbalance or faulted

operation that could occur at any time during the energy source lifetime. Unbalanced

operation occurs when the batteries are charged and discharged at different rates, or when

the respective battery cells are not equally charged. Long time operation with these small

cell differences can lead to a significant difference in SOC that could result a deep

discharge of some of the battery cells. Deep discharge affects the battery life and should

therefore be protected against. Another unbalanced operation could happen when the

batteries are not identical. In many electric vehicle systems, the on-board energy sources

are very well matched (electrically and chemically) because the systems are relatively low

volume. However, as automotive volumes increase, or battery share projects take off, the

matching of multiple parallel systems will become more difficult to manage.

Further, because the batteries are connected in parallel, the voltage of healthy and weak

batteries must be balanced, hence during the charging process the healthy batteries could

be overcharged possibility leading to a failure mode of the battery [90, 91].

Page 72: ANALYSIS AND MODELLING OF ENERGY SOURCE …

72

Chin-Sien et al., demonstrated that by using DC-to-DC converters that allow full control of

each battery independently, some batteries can be effective isolated and operation

independent of individual battery SOC [92].

Han-Sik Ban et al. proposed an unbalance current control to keep the internal resistance of

all cells constant over the battery demand profile. This was done by inserting an external

resistance and calculating the change of internal resistance using a micro processor [93].

However, such a system is only suited to multiple battery systems of relatively small

energy. On larger (vehicle) systems, the inclusion of series resistance is not a sensible

option.

Regardless of other battery technologies, if the ceramic of the ZEBRA battery fails, the cell

fails to an electrical short circuit. This means the battery technology favours high numbers

of series cells, i.e. high voltage (200-1000Vdc) systems, that is becoming a pre-requisite

for larger electric vehicle systems. Thus, the battery system can tolerate a number of cell

failures and can continue to operate; a feature that makes the ZEBRA battery a very robust

solution.

Giorgio M. et al. studied a parallel connection of 8 ZEBRA batteries to power an electric

bus, Europolis, as reported in [4], the study demonstrated that the ZEBRA system provided

the request of 12 hours operation as a daily mission in Lyon city under some fault

conditions.

In this Chapter, the ZEBRA multi-battery system is modelled. The model shows the

interconnection between the ZEBRA batteries and shows how the batteries share current

for different operational cases: viz. (i) different SOC and (ii) number of cell failures.

3.2 Faulted cell in a ZEBRA battery

As mentioned, the ZEBRA cell typically fails to electrical short circuit. Chemically, nickel

powder and salt (NaCl) which is mixed with NaAlCl4 are used as the cathode material.

This salt liquefies at 154ºC. In the liquid state, it is conductive for Na+ ions and acts as

separator for electrons. During operation, the Beta-alumina ceramic, β-Al 2O3, which is a

brittle material may develop a crack. In this case, the liquid salt, NaAlCl4, reacts with

sodium resulting in salt and aluminium [34]:

AlNaClNaNaAlCl +⇒+ 434 (3.1)

In the case of small cracks, the salt and aluminium close the crack in the β-Al 2O3, however

for larger or progressive cracks, the aluminium shorts the path of current between the

Page 73: ANALYSIS AND MODELLING OF ENERGY SOURCE …

73

positive and negative poles leading to that cell going to low resistance [34]. When the cell

fails, it can be gradual, depending on the current and other operating conditions, for

example a high discharge rate will soon take the cell down to complete failure. So a failing

cell does not take many cycles at all to stop contributing in the battery energy content.

In each sting of a ZEBRA battery, the limit on the number of allowed cell failures is the

reduction in energy content that can be accepted by the application, or in larger multiple

systems, the point when adjacent batteries start to significantly discharge into the failed

unit. The cell failure permissible is determined by the percentage of failed cells to the total

cells; which means higher voltage batteries can tolerate more cell failures. Generally, the

ZEBRA battery, has a tolerance of 5-10% of cell failures [34, 35, 94].

Each ZEBRA battery is fitted with a controller that keep the battery within the permitted

operating window in terms of SOC, maximum current, and voltages levels. In the parallel

connection, the controller manages the unbalanced system to maintain vehicle functionality

by disconnecting the weak battery in order to discharge other batteries to an equitable

level. In the charge mode, the battery cells could all polarise to the set charge voltage

because each battery has a separate charger which maintains the full charging voltage on

the batteries including those have or those don’t have cell failures. Then, a failed cell

would not be detected by an open circuit voltage test after charging unless the battery has a

rest or settling period of a few hours [95].

3.3 ZEBRA Multi-battery system

An example of a multi-battery system is illustrated in Fig. 3.1. Each individual battery

parameters are controlled by a Battery Management Interface (BMI). The battery is

connected to the system through a contactor or a circuit breaker. The specification of the

contactors should be that they can sustain a high current equitable to the full discharge

current [95].

In multi-battery systems, a Multi Battery Server (MBS), designed for up to 16 battery

packs, has to be connected in parallel to oversee the individual BMI’s[34]. The

communication between the MBIs and MBS manages the system operation by controlling

each battery contactors to connect or disconnect the battery from the system according to

the system requirements and battery health.

Page 74: ANALYSIS AND MODELLING OF ENERGY SOURCE …

74

Fig. 3.1 A Multi-battery system.

3.3.1 Battery Management Unit (BMI)

The BMI is the intelligence of the battery system and consists of an electronics unit with

integrated main circuit breakers used to monitor and control the battery operation. A

typical Battery Management Interface (BMI) is illustrated in Fig. 3.2.

Fig. 3.2 ZEBRA Z5C Battery Management unit (BMI).

The BMI controls the battery internal heater and cooling fan to maintain the ZEBRA

battery operating at a suitable temperature. The BMI also acts to control the battery

operating limits, for example as in Fig. 3.3, when the battery terminal voltage exceeds the

maximum specified during regenerative braking or when the terminal voltage drops under

the minimum level during high rates of discharge, i.e. vehicle acceleration. The BMI unit

controls these extreme voltage limits by disconnecting the battery via contactors that

isolates the battery [34, 35]. The operating limits are implemented in the MBI to avoid

battery damage [94].

Battery management unit (BMI)

Circuit breaker

Multi-Battery Server

MBS

BMI

BMI

Contactors

Resistor

ZEBRA 1

ZEBRA 2

Load

Page 75: ANALYSIS AND MODELLING OF ENERGY SOURCE …

75

Fig. 3.3 BMI Operation in a vehicle traction system.

3.3.2 Multi-Battery Server (MBS)

A controller is needed to supervise the BMIs of each battery and manage the operation of

the complete multi-battery system. This controller is called the multi-battery server

(MBS), and it operates as an interface between the individual battery systems via their

BMIs to the vehicle energy management system. MBS communicate with all BMIs on the

battery system and with the vehicle components.

Fig. 3.4 illustrates an overview of the multi-battery server in the vehicle energy

management hierarchy. As discussed, the ZEBRA battery could be operated with failed

cells, though with a reduced energy capacity and open circuit voltage. However, if parallel

batteries have a different number of failed cells, the terminal voltage of the batteries will be

unbalanced and hence their individual SOC will start to vary from ideal. The Simulink

model takes into account possible variations between batteries, and can be used to analyse

the performance of multiple battery systems in the case of various unbalanced operating

scenarios.

Fig. 3.4 Operational scheme of the MBS and BMI’s.

BMI

ZEBRA

Load

Idc Vdc

System voltage and current measurements

MBS Vehicle

control unit

BMI1

BMI2

BMI3

Page 76: ANALYSIS AND MODELLING OF ENERGY SOURCE …

76

3.4 Multi-battery model

Each battery model has been simulated using a the Matlab/Simulink tool as previously

discussed. To connect multiple batteries in parallel, the two battery models are converted

to a Matlab “simpower” system. In addition, to all software connection of voltage sources

in parallel, small series resistances are required between the different voltage sources, else

the simulation solver cannot converge. The value of this resistance is in micro ohms which

is much smaller than smallest battery internal resistance of more than 1 milli-ohm. Thus

this resistance can be considered as cable resistance.

3.4.1 Model Layout

The model of four ZEBRA batteries in the Matlab/Smulink environment is illustrated in

Fig. 3.5, showing each battery connected to the battery system via two contactors, the

upper one is controlled by a control signal applied from BMI. The demand current that is

calculated in the Simulink model is converted to an electrical signal using a controlled

current source available from the Simpower tool box. The parameters of the four batteries

including SOC, number of strings, number of cells in series, and battery capacity in Ah are

set from the battery parameter block, as shown in Fig. 3.6. The BMI of each battery is

linked to the model using digital circuits to monitor battery voltage, current and SOC,

allowing the battery to operate between chosen operational limits, as shown by the scheme

of Fig. 3.7. MBIs are mastered by MBS to control the overall system operation.

3.4.2 The control scheme

The MBS manages the unbalanced system to maintain vehicle functionality by

disconnecting the faulty battery or the lower SOC battery in order to discharge other

batteries to an equitable level. The MBS algorithm is implemented in the model maintains

the SOC of each battery at within a variation of not more than 5% SOC as recommended

by Beta R&D (although this could be changed). If the vehicle power demand could be

provided without the faulty battery, the MBS will disconnect the faulty battery, and the

power will thus be developed from the remaining healthy batteries. However, the faulty

battery remains disconnected until the difference in SOCs is less than 5%. Nevertheless, if

the vehicle demand is high, the MBS keeps all batteries connected to supply the demand.

Fig. 3.8 illustrates a flow chart of the MBS algorithm.

Page 77: ANALYSIS AND MODELLING OF ENERGY SOURCE …

77

Zebra Battery4

CR

NT

VT1

SO

C1

Con

n2

Co n

n1

Zebra Battery3CR

NT

VT1

SO

C1

Con

n2

Co n

n1

Zebra Battery2CR

NT

VT1

SO

C1

Con

n 2

Con

n1

Zebra Battery1CR

NT

VT1

SO

C1

Con

n 2 Con

n1

Voltages

Second Cotractor state

1

SOCs

MBS

Itotal

I4I3

I2I1

SOC4SOC3SOC2SOC1

s2

s1s4s3

Currents

i+

-

i+

-

i+

-

i+

-i+

-

Cotactors statess -

+

K-

g 12

g 12

g 12

g 12

g 12

g 12

g 12

g 12

Fig. 3.5 Layout of the multi-battery model.

initoal. SOC 1

1

initial SOC 4

-C-initial SOC 3

-C-

initial SOC 2

-C-

Time of the fault 2

0

Time of the fault 4

-C-Time of the fault 3

0

Time of the fault 1

-C-

No. faild cells 4

0No. faild cells 3

0

No. faild cells 1

0

No. faild cells 2

0

No. cells in series 4

108No. cells in series 3

108

No. cells in series 1

108

No. cells in series 2

108

NO. strings 4

2NO. strings 3

2

NO. strings 2

2

NO. strings 1

2

Ah 4

76Ah 3

76

Ah 2

76

Ah 1

76

BAT 4

int. SOC

NO. strings 4

Ah4

No. cells in series 4

No. faild cells4

time of fault

BAT 3

int. SOC

NO. strings3

Ah3

No. cells in series 3

No. faild cells3

time of fault

BAT 2

int. SOC

NO. strings2

Ah2

No. cells in series2

No. faild cells2

time of fault

BAT 1

int. SOC

NO. strings

Ah1

No. cells in series

No. faild cells

time of fault

Fig. 3.6 The battery parameters of four batteries in the multi-battery model.

Page 78: ANALYSIS AND MODELLING OF ENERGY SOURCE …

78

Min. Voltage/cell

3SOC of Battery

2

BMI Signal1

AND

AND

OR

OR

AND

AND

AND

max. Votage/cell

> 3.1

> 0

<= 0

> 0

<= 3.1

AND

SOC min

>= 0.1

SOC max

<= 1.1

>=

<

boolean boolean

boolean

boolean

boolean

boolean

boolean

boolean

boolean

boolean

boolean

Current Limits

<= 224 |u|

min Voltage/cell5

No. of cells4

SOC3

Battery Current2

Battery Terminal Voltage1

Fig. 3.7 MBI model using digital circuits.

Fig. 3.8 Flow chart of MBS operation.

Yes

I

demand

Yes

N

BMI

SOC

SOC1 SOC2

SOC16

Disconnect the faulty battery

I

demand

<< 20 A

If the difference >5%

Connect/reconnect all batteries

Page 79: ANALYSIS AND MODELLING OF ENERGY SOURCE …

79

The controller (MBS) signals are implemented in a Matlab function to satisfy the following

criteria:

(1) The battery is disconnected from the battery system if it’s SOC is less than

maximum SOC by 5% AND the demand current at that moment is less than 20A.

(2) The battery will be reconnected when the SOC becomes close to or equal to the

maximum SOC AND the demand current is less than 20A.

3.5 Model Validation

3.5.1 Field data analysis

Field measurement data of four ZEBRA batteries has been used to experimentally validate

the multi-battery model. In the first step of validation, the data is analysed and studied, as

illustrated by Fig. 3.9 showing the individual currents of four batteries. It is noticeable that

some currents equal zero at various times because the contactor of the relevant battery has

been opened by the MBS. Fig. 3.10 shows the voltages across each battery showing that

when the contactor is opened the voltage is battery open circuit voltage. From the SOC’s

illustrated in Fig. 3.11, it is clear to identify the switching states of the various contactors.

When the first battery SOC seems constant, it illustrates that that battery contactor is open

in response to the control signal from MBS.

Before analysing the measured data, it is worth pointing out that the individual battery

temperatures vary from 263 to 290 °C, which is not a significant variation for this

technology. Table 3.1 shows the starting data of SOC’s, terminal voltage, and

temperatures of four batteries. From the starting data, it clear that the second (No. 2)

battery has some failed cells. Although the cell failure is not clear from Fig.3.9 because

the demand current at starting time of the driving cycle is zero, Fig. 3.10 shows that the

voltage of the second battery is open circuit voltage by virtue of the open contactor.

During the driving cycle, two signals from the BMS switch off batteries 1 and 3.

Battery No. 1 2 3 4 SOC 99.9 99.9 99.9 99.9

Vt (V) 285.4 279 286.4 283.8 Temperature (C° ) 264.3 264.2 264.2 261.9

Table 3.1 Starting data of main parameters of the four batteries.

Page 80: ANALYSIS AND MODELLING OF ENERGY SOURCE …

80

0 1000 2000 3000 4000 5000 6000 7000-60

-40

-20

0

20

40

60

80

100

120

Time (s)

Cu

rren

t (A

)

Ibat. 1I bat. 2I bat. 3Ibat. 4

Fig. 3.9 Current measurements of four parallel batteries exhibiting out of balance.

0 1000 2000 3000 4000 5000 6000 7000210

220

230

240

250

260

270

280

290

300

310

time (s)

Vol

tage

(V)

Vbat.1Vbat. 2Vbat. 3Vbat. 4

Fig. 3.10 Measured voltages across each battery.

0 1000 2000 3000 4000 5000 6000 70000

0.2

0.4

0.6

0.8

1

Time (s)

Sta

te O

f C

har

ge (S

OC

)

SOC1SOC2SOC3SOC4

Fig. 3.11 The SOC’s of the four batteries.

Page 81: ANALYSIS AND MODELLING OF ENERGY SOURCE …

81

3.5.2 Model validation

For validation purposes, the model is run over the same drive cycle. The speed profile is

not provided in the given data; hence the currents of four batteries are summed to present

the demand current of the drive cycle, as shown in Fig. 3.12. Using the demand current as

an input to the four battery model, the MBS algorithm, which is based on the batteries’

SOC profiles, aims to control each of the four MBIs by sending a suitable command signal.

Each MBI responds by switching their respective contactors either ON or OFF. As a

result, the simulated contactor states for the four batteries are illustrated in Fig. 3.13.

In the test data, dynamics of the contactors has occurred at 3000 seconds, thus the result is

focused on this period of time to clarify the model result against the given test data. As an

example of the model and experimental results, two battery voltages are shown. The

voltage of battery 2, which had three failed cells at the beginning of the test, is shown in

Fig. 3.14. The applied MBS algorithm controls the MBI of battery 3 to switch the

contactors to the OFF position during the operation. The results of simulated and

experimental data for the voltage of battery 3 are shown in Fig. 3.15.

The contactor state data for the test MBS is not available, but the practical contactor states

can be inferred from the individual battery currents and SOC measurements. Thus, for

MBS validation, the responses of these measurements are compared with simulated results

by applying the proposed MBS algorithm. The results are illustrated in Fig. 3.16 showing

individual battery currents, SOC’s and contactor states, from which it is clear that the

model of the MBS controller matches the actual data with regard to disconnecting and

reconnecting battery 1. The result of the battery 2 contactor also shows good agreement.

The contactor is OFF at the beginning of the test but after 180 seconds it is reconnected.

Thus, the experimental data provides confidence in the model calibration.

Battery 3 is disconnecting early because both conditions are satisfied, in practice this event

could be referred to the delay of the contactors.

Page 82: ANALYSIS AND MODELLING OF ENERGY SOURCE …

82

0 1000 2000 3000 4000 5000 6000 7000 8000-200

-100

0

100

200

300

400

Time (s)

Th

e d

eman

d c

urr

ent

(A)

Fig. 3.12 Demand current profile.

0 1000 2000 3000 4000 5000 6000 7000 8000

0

1

Time (s)

Co

nta

cto

r st

ate

Contctors state of Bat. 1Contactors of state Bat. 2Contactors state of Bat. 3Contactors state of Bat. 4

Fig. 3.13 Simulated contactor states of the four batteries

Page 83: ANALYSIS AND MODELLING OF ENERGY SOURCE …

83

0 500 1000 1500 2000 2500 3000210

220

230

240

250

260

270

280

290

300

310

Time (s)

Vo

ltag

e (V

)

SimulatedMeasured

Fig. 3.14 Simulated and experimental voltage of battery 2.

0 500 1000 1500 2000 2500 3000210

220

230

240

250

260

270

280

290

300

310

Time (s)

Vo

ltag

e (V

)

SimulatedMeasured

Fig. 3.15 Simulated and experimental data of voltage of battery 3.

Page 84: ANALYSIS AND MODELLING OF ENERGY SOURCE …

84

Fig. 3.16 Multi-battery model validation.

0 500 1000 1500 2000 2500 3000-60

-40

-20

0

20

40

60

80

100

120

Time (s)

Curr

ent (A

)

Ibat.1Ibat.2Ibat.3Ibat.4

0 500 1000 1500 2000 2500 30000.6

0.65

0.7

0.75

0.8

0.85

0.9

0.95

1

Time (s)

SOC

SOC1SOC2SOC3SOC4

0 500 1000 1500 2000 2500 3000

OFF

ON

Time (s)

Con

tact

or s

tate

Contactor state of Bat. 1Contactor state of Bat. 2Contactor state of Bat. 3Contactor state of Bat. 4

CONT. 1 OFF

CONT. 2 ON CONT. 1 ON

CONT. 3 OFF

CONT. 1 ON

Page 85: ANALYSIS AND MODELLING OF ENERGY SOURCE …

85

3.6 Model analysis

The reasonable agreement between simulated and measured data gave sufficient

confidence in the utility of the multi-battery simulation model to consider different fault

scenarios related to potential unbalanced operation. These are considered and studied in

this section to investigate the impact of each scenario on vehicle performance in terms of

energy and range.

3.6.1 Simulation of four batteries during various faulted operations

The vehicle of the validation data is analysed under different scenarios. The scenarios

considered in this section are:

(1) The four batteries have different SOC’s.

(2) The second scenario is a fault condition: when a fault occurs during driving the

vehicle, this case could occur in different batteries and with different numbers of

cell failure.

(3) The third scenario considers both scenarios (1) and (2) in one operation.

(4) The last scenario considers when progressive cell failures occur in one battery

during operation.

(1) Case one.

Practically, this case could happen when the batteries are at different ages or when one of

the batteries is damaged and replaced with other which has a different SOC and the vehicle

is driven straight away. In the model, the third battery is assumed to have less SOC (0.9)

than the other batteries which are fully charged as shown in Fig. 3.17.

Page 86: ANALYSIS AND MODELLING OF ENERGY SOURCE …

86

1 0 0 0 2 0 0 0 3 0 0 0 4 0 0 0 5 0 0 0 6 0 0 0 7 0 0 0

0

0 .2

0 .4

0 .6

0 .8

1

T i m e ( s )

Swit

ch s

tate

S 1S 2

S 3S 4

0 1 0 0 0 2 0 0 0 3 0 0 0 4 0 0 0 5 0 0 0 6 0 0 0 7 0 0 00

0 . 1

0 . 2

0 . 3

0 . 4

0 . 5

0 . 6

0 . 7

0 . 8

0 . 9

1

T i m e (s )

SOC

S O C 1S O C 2S O C 3S O C 4

0 1 0 0 0 2 0 0 0 3 0 0 0 4 0 0 0 5 0 0 0 6 0 0 0 7 0 0 02 0 0

2 1 0

2 2 0

2 3 0

2 4 0

2 5 0

2 6 0

2 7 0

2 8 0

2 9 0

3 0 0

T i m e ( S )

Vol

tage

(V

)

V 1V 2V 3V 4

Fig. 3.17 Results for case (1).

Page 87: ANALYSIS AND MODELLING OF ENERGY SOURCE …

87

Table 3.2 shows the impact of different SOC of the third battery on the vehicle

performance; here the time spent in the journey represents the range.

SOC of 3rd battery

Time (s) SOC1 SOC2 SOC3 SOC4

1.0 6355 0.1 0.1 0.1 0.1 0.9 6221 0.1 0.1 0.1 0.1 0.8 6090 0.1 0.1 0.1 0.1 0.7 5882 0.1 0.1 0.1 0.1

Table 3.2 The impact of different SOC of the third battery on the vehicle performance.

(2) Case two.

The cell failure is simulated during driving. The fault might occur any time during driving,

this is very important on the system since the fault is simulated by a function of the number

of cells versus time. In this case, the fault time is considered as being at 3000s from the

beginning of the test. The number of failed cells that is implemented in this case is 5 cells

in each string (5 represent about 5% of cells in the battery) in the third battery. The case

results are illustrated in Fig. 3.18. The impact of failed cells on the vehicle performance is

shown in Table 3.3, where it is clear from that as more cells fail there is a greater impact

on range.

No. of cells/string

Time (s) SOC1 SOC2 SOC3 SOC4

0 6350 0.1 0.1 0.1 0.1 1 6327 0.1 0.1 0.1 0.1 3 6281 0.1 0.1 0.1 0.1 5 6229 0.1 0.1 0.1 0.1

Table 3.3 The impact of cell failure on the vehicle performance.

Page 88: ANALYSIS AND MODELLING OF ENERGY SOURCE …

88

500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000

0

0.5

1

Time (s)

Switc

h st

ate

S1S2

S3S4

0 1000 2000 3000 4000 5000 60000

0 .1

0 .2

0 .3

0 .4

0 .5

0 .6

0 .7

0 .8

0 .9

1

Time (s)

SOC

SOC1SOC2SOC3SOC4

0 1000 2000 3000 4000 5000 6000180

200

220

240

260

280

300

Time (s)

Vol

tage

(V)

V1

V2

V3V4

Fig. 3.18 Results of case (2).

The cell failure is investigated for different cases for all batteries, as shown in Table 3.4

and Fig. 3.19, showing the impact of the vehicle performance in terms of range (operation

time).

Page 89: ANALYSIS AND MODELLING OF ENERGY SOURCE …

89

No. of failed

cells in battery 1

No. of failed cells in battery

2

No. of failed cells in battery

3

No. of failed cells in battery

4

Time (s)

0 0 0 0 6350 0 0 0 1 6327 0 0 0 3 6281 0 0 0 5 6229 0 0 0 0 6350 0 0 1 1 6303 0 0 3 3 6206 0 0 5 5 6137 0 0 0 0 6350 0 1 1 1 6278 0 3 3 3 6127 0 5 5 5 5947 0 0 0 0 6350 1 1 1 1 6258 3 3 3 3 6048 5 5 5 5 5761

Table 3.4 Different cases of cell failure.

5700

5800

5900

6000

6100

6200

6300

6400

0 1 2 3 4 5

Number of faulted cells

Dri

vin

g ti

me

(s)

BAT3 BAT3+BAT4 BAT2+BAT3+BAT4 ALL BAT

Fig. 3.19 The impact of cell failure on the vehicle performance (or operation time).

(3) Case three.

This case considered a special case to present both different SOC and cell failure over the

driving cycle. At the beginning, the third battery has less SOC, and then at 3000 seconds

the battery succumbs to defects in 5 cells in each string. Fig. 3.20 illustrates the simulation

results showing battery contactor (switch) state, SOC and voltage.

Page 90: ANALYSIS AND MODELLING OF ENERGY SOURCE …

90

500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000-0.1

0

0.5

1

1.1

Time (s)

Swit

ch s

tate

S1S2S3

S4

0 1000 2000 3000 4000 5000 60000

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Time (s )

SOC

SOC1

SOC2SOC3SOC4

0 1000 2000 3000 4000 5000 6000200

210

220

230

240

250

260

270

280

290

300

Time (s)

Vol

tgae

(V)

V1V2V3V4

Fig. 3.20 Simulation results for case (3).

Page 91: ANALYSIS AND MODELLING OF ENERGY SOURCE …

91

It is clear that the switch of the third battery was OFF at the beginning of the test and then

reconnected after the SOC’s of all the batteries converge to the same state. The fault is

simulated to occur at time of 3000 s, so at this time the switch is opened again and remains

open until the SOC’s are approximately the same. Compared with the healthy system

operation which accomplished a driving for 6350 seconds, this case of operation could

accomplish 5850 seconds.

(4) Progressive cell failure.

When a cell fails in a battery, the remaining cells in the battery will be gradually

discharged depending on the discharge current; high discharge rates will soon take the

battery down to complete discharge. So a failing cell does not take many cycles at all to

stop contributing in the battery energy. Based on this fact, this case of failure is considered

where the maximum number of cells that fail progressively is about 10% of the total cells.

In this case, a model of progressive faults is implemented in the battery simulation. The

faults are gradual depending on the discharge current, hence the fault is simulated as a

function of discharge current rate. The results of this scenario, and its impact on the

vehicle performance, are illustrated in Table 3.5 and Fig. 3.21.

No. of failed cells Operation time (s)

0 6350

1 6314

2 6302

3 6279

4 6256

5 6231

Table 3.5 Progressive cell failures.

Page 92: ANALYSIS AND MODELLING OF ENERGY SOURCE …

92

6220

6240

6260

6280

6300

6320

6340

6360

0 1 2 3 4 5

No. of faulted cells

Driv

ing

tim

e (s

)

Fig. 3.21 The impact of progressive cell failures on the vehicle performance.

3.6.2 Impact of cell failure on a two battery system - taxi performance

To investigate the impact of cell failure on the range of a known electric vehicle over the

NEDC driving cycle test, simulations of various percentages of cell failure were studied

the results of which are presented in Table 3.6. The reference vehicle is a London taxi

powered by two ZEBRA batteries over repetitive NEDC. The total distance that full

capacity batteries can establish is 93.97 km in the simulation model and previously

published data [17].

Battery 1 No. of failed cells in battery 2 Range (km)

0 93.97

2 91.95

Full capacity

5 86.5

Table 3.6 The impact of cell failure on vehicle range.

The first case of cell failure considered is when two cells fail in one battery; here it is clear

that the BMI controlled the damaged battery by switching the contactors OFF in order to

discharge the healthy battery up to the level of the damaged one. It can be noted that the

MBS kept the battery OFF when two conditions are valid;

Page 93: ANALYSIS AND MODELLING OF ENERGY SOURCE …

93

(a) the SOC of the healthy battery is greater than the faulted battery, and

(b) the healthy battery can provide the load demand.

The range of the vehicle is slightly affected as shown in Table 3.6.

The second case is when the number of cell failures is the maximum allowed – i.e. five

cells. The performance of the vehicle is more affected than the first case, as would be

expected. The impact of the cell failure on vehicle range in the second case is that the

range is shorted by about 7 km.

3.7 Summary

Regardless to other batteries, the ZEBRA battery technology can operate with cell failures,

which tend to a short circuit due to the cell chemistry. This allows the string to continue

operation, a feature that makes the ZEBRA battery technology very robust. In this

Chapter, the multi-battery system has been modelled. The model shows the

interconnection between the ZEBRA batteries and illustrates how the batteries share

current for different faulted cases. The Simulink model takes into account the possible

variation between batteries and can be used to analyse the performance of multiple battery

systems in the case of various unbalance operating scenarios.

The MBS manages the unbalanced system to maintain vehicle functionality by

disconnecting the faulty battery or the lower SOC battery in order to discharge other

batteries to an equitable level.

Actual field test data of a four battery system has been used to validate the model. The

model simulations showed good agreement with the real test data. The model was hence

used to study different fault scenarios and to develop new fault management schemes.

Page 94: ANALYSIS AND MODELLING OF ENERGY SOURCE …

94

CHAPTER 4

COMBINATION OF BATTERY AND SUPERCAPACITOR

4.1 Introduction

As previously discussed, some of the deficiencies of EV power-train technologies are the

high cost of energy storage batteries, and their limited peak power. Any improvement in

such points will make EV’s a stronger cost competitive solution against conventional ICE

vehicles. In pure EV’s, the battery is exposed to high pulse of power during acceleration

and deceleration. Due to this continuous supply of power peaks to the vehicle traction

drive, more stress is applied to battery than need be, consequently, the lifetime of electr-

chemical batteries is reduced [96-98]. Further, during these rapid acceleration and

deceleration events, the braking energy is inefficiently captured by electro-chemical

batteries because they generally have a relatively slow charge acceptance capabilities,

resulting in only 40-50% of potential braking energy being recovered back into the battery

[5]. Therefore, a peak power buffer in conjunction with the electro-chemical battery is

advantageous to store and release transient energy, thus improving the energy efficiency of

the vehicle power-train and, perhaps more importantly, to level battery energy [96-98].

This Chapter will review published work relevant to battery and supercapacitor

combinations in multiple energy source systems for electric vehicles and then review

published simulation models for supercapacitors. A Matlab/Simulink model will then be

Page 95: ANALYSIS AND MODELLING OF ENERGY SOURCE …

95

presented, validated and subsequently used to design a supercapacitor power buffer for an

example urban electric vehicle.

4.2 Hybridisation of vehicle energy sources

The battery deficiencies mentioned here and in Chapters 1 and 2, have led various research

in the field of hybrid (or multiple) energy sources. Farkas et. al. in [99] presented some

possibilities for supplementing batteries with supercapacitors if the power capability of

battery technologies does not progress. Cegnar, et al. in [100] designed a HEV using a

supercapacitor as an energy source and relying on regenerative energy. For voltage

rigidity, he proposed high and low voltage supercapacitors combined with a boost DC-DC

converter. The results show the capability of the supercapacitor to capture large

regenerative currents that exceed 200A.

W. Lhomme et. al. in [101, 102] suggested supercapacitors in the energy source of a series

HEV, controlled via maximum control structure that composed of several inversion blocks

and two different management elements. The study concluded that the best compromise is

to use a battery and supercapacitor combination, though the share of energy or

specification thereof was not presented.

The topology that could offer improvement in terms of cost and power capability is a

hybridisation of a primary energy source to fulfil the requirements for vehicle range, and

an auxiliary power source to alleviate the peak power requirements of the primary energy

source, as will be discussed in this Chapter.

Supercapacitors are a strong candidate technology to play this role in vehicle applications

where braking and acceleration are prevalent. The supercapacitor has the features of high

power density, high cycle efficiency and long cycle life that complements those of electro-

chemical batteries [103-106].

Thus, by supplementing the battery with supercapacitors that assists acceleration, capture

and reuses braking energy, the energy efficiency of the vehicle power-train is improved

and makes the supercapacitor an excellent solution as complementary power delivery

device in a combination with high energy battery to form hybrid energy source system.

A combination of battery and supercapacitor could be directly connected as studied in

[107-109]. Even though this kind of connection does reduce high transient currents of the

battery, a static converter should interface the power connection between batteries and the

supercapacitor to be able to control supercapacitor energy content, maximise

supercapacitor stored energy, and to achieve higher supercapacitor convertion efficiencies

[108-110].

Page 96: ANALYSIS AND MODELLING OF ENERGY SOURCE …

96

Many studies suggest the design of intermediate power converters to control the power

flow between batteries and supercapacitors. R.M. Schupbach et al. in [111] present a

comparison between a Half-bridge, Cuk and SEPIC as three DC-DC converter formats for

hybrid electric vehicles. A wide input voltage DC-DC converter using a cascaded boost

converter is proposed by Todorovic et. al. in [112] to achieve a 2:1 voltage variation at the

primary energy source interface. The converter isolates the voltage of fuel cells and

supercapacitors and allows a wide voltage change on the fuel cell (typical of fuel cell

operation). Different control schemes to manage the power flow via DC-to-DC converters

in combinations of fuel cells and supercapacitors are discussed in [113] and in [114].

M. B. Camara et. al. in [121] demonstrated two buck-boost DC-to-DC converter designs

for supercapacitor and battery power management in hybrid electric vehicles controlled by

a polynomial control strategy. One of the topologies was proposed to simplify the control

strategy, decrease the supercapacitor current and to avoid converter saturation. J. Leuchter

et. al. modelled a complete hybrid power source system including photovoltaic, battery and

supercapacitor in [116]. An energy management unit controlled a bidirectional DC-to-DC

converter to stabilise the system DC bus and achieve a high efficiency. J.W. Dixon et. al.

demonstrated a IGBT buck-boost converter and supercapacitor for an electric vehicle in

[117] to decrease the loss of the system and take advantage of regenerative braking.

In this Chapter, a combination of a battery and supercapacitor as energy sources is studied

with a view to exploit their respective energy and power attributes in an all-electric vehicle

power-train, as illustrated in Fig. 4.1. The battery represents the primary energy source

and the supercapacitor the auxiliary power source. The primary energy source is specified

and operated to fulfil the requirements for vehicle range, while the auxiliary power source

provides transient energy to alleviate the peak power requirements of the vehicle drive

cycle demands.

Fig. 4.1 Traction system layout for a all-electric vehicle.

Trans Motor EM Controller & Converter

Energy Control System Battery

Charger

Supercap. System

POWER-TRAIN DRIVE-TRAIN

TRACTION SYSTEM

Page 97: ANALYSIS AND MODELLING OF ENERGY SOURCE …

97

Of the possible battery technologies proposed for battery and supercapacitor combinations,

the ZEBRA battery is chosen for the study reported in this Chapter since this is the chosen

technology of the DESERVE project [5]. The ZEBRA battery has an excellent specific

energy and a good specific power for braking and acceleration when compared with other

battery technologies. For the DESERVE project the partners have taken the basic ZEBRA

cell and redesigned it to be close to that of an earlier cell design having approximately 20%

higher energy density. However, the downside to this design change is that power density

is compromised, hence the combination of the higher energy ZEBRA with a supercapacitor

peak power buffer. The design specification for the supercapacitor power buffer is the

conclusion of this Chapter.

During the literature review, ZEBRA batteries and supercapacitors have previously been

combined by J. Dixon et. al., who demonstrated the combination in [118, 119]. The

practical tests presented showed an improvement in vehicle range and efficiency.

However, it noted that the mass of is supercapacitor bank used (132 cells of 2700 F) for a

vehicle of 1700 kg was a quite high. No consideration was made to substitute the

supercapacitor system mass with an equivalent battery mass and then reassess the range

implications. This is discussed in this Chapter thus, as with the vehicle model discussed

earlier, a case study aims to investigate that how the target vehicle performance in terms of

energy use and range could be improved with an optimum sizing of supercapacitor system.

4.3 Published supercapacitor simulation models

4.3.1 Combinations of passive elements

The impact of a supercapacitor system on the performance of any vehicle requires a

suitably detailed supercapacitor model in the overall vehicle system model. Hence, the

supercapacitor model and subsequent system design present important issues to evaluate

for varying operating conditions.

Based on the material structure of the supercapacitor and their limitations, many studies

have been published on supercapacitor behavioural models for supercapacitors that are to

be used in energy systems.

Many different circuit models have been proposed for supercapacitor, the most often

applied being the classical capacitor model [130, 131] where the supercapacitor is slowly

discharged over a few seconds, as illustrated in Fig. 4.2 showing the simplified equivalent

Page 98: ANALYSIS AND MODELLING OF ENERGY SOURCE …

98

circuit. This equivalent circuit may be considered the actual capacitor behaviour in a slow

discharge application.

Fig. 4.2 Classical capacitor model.

The classical equivalent circuit consists of the capacitance, C, the equivalent series

resistance (ESR), Rs, that represents the series internal resistance that occurs during

charging and discharging, and an equivalent parallel resistance (EPR) ), Rp, to represent the

path of leakage charge which, for supercapacitors, is a long-term effect.

This model for the supercapacitor is suited for slow charge-discharge applications in the

order of a few seconds. Although the model is used widely it fails to simulate all the

dynamics of the supercapacitor cell. That is because the capacitance of a supercapacitor is

generally not constant, and is strongly dependent on terminal voltage [132, 133].

Therefore, a more effective model for supercapacitors has been modelled recently [132,

134-139]. B. Vural in [132] has provided a dynamic model for supercapacitors, as

illustrated in Fig. 4.3. The equivalent circuit model simulates the behaviour of the

supercapacitor via three resistor-capacitor (RC) branches; RC2 represents the internal

energy distribution at the end of charge and dischrage, RsC1 represents immediate cell

behaviour, and the inductance L models internal connections. The internal self discharge

behaviour is modelled by Rp.

Fig. 4.3 A dynamic model for a supercapacitor cell [132].

Rp Rs

C

Page 99: ANALYSIS AND MODELLING OF ENERGY SOURCE …

99

Other published models focus on the influence of frequency on the electrode resistances

and capacitances. For example, the authors of [137] and [138] model the supercapacitor

using complex impedances the parameters of which are subsequently evaluated via

Electrochemical Impedance Spectroscopy (EIS), a common technique for characterising

electro-chemical devices, Magnitude and phase information of the various impedances are

obtained via a series of EIS tests from the capacitor under test. Model parameters are then

calculated from this data using, for example, curve-fitting routines. However, during

normal operation, voltage and temperature of the supercapacitor are likely to change

instantaneously and the dependence of the model parameters to these quantities should

therefore be considered, although they are often neglected in publications.

Fig. 4.4 Example of model layout using complex impedances [137].

An example of a model layout using complex impedances is illustrated in Fig. 4.4 showing

the supercapacitor series inductance (L), series resistance (Ri) and complex impedance

(Z(jω)). Although inclusion of the series inductance is not usually necessary for an electric

vehicle supercapacitor application (due to the transient time-base), it has to be included in

the model to avoid errors in the intermediate frequency branch of the spectrum, which

could influence the estimation of Ri. The parameter Z (jω) can be obtained as follows:

ωτωττ

ωjC

jjZ

)(coth(.)( = (4.1)

which contains only two independent parameters C which including L and Ri.

To obtain a suitable model for simulation, the frequency domain model has to be

transformed into the time domain thus providing a series expansion of RC circuits, as

shown in Fig. 4.5. The complex impedance Z(jω) can be approximated via a number “n”

of such RC circuits, which are fully described by two parameters [133, 138, 139],where, C

is the capacitance [F], in addition, R is calculated from the following equation:

][2

22Ω=

CnR n

n πτ

(4.2)

L Ri Z(jω)

Page 100: ANALYSIS AND MODELLING OF ENERGY SOURCE …

100

here, n is the number of RC circuits = 1, 2, 3… n, and nτ their respective time constant(s) .

Fig. 4.5 Approximation of Z(jω) via “n” RC circuits [137].

Reported experiments show that models consisting of ten or more RC circuits show good

agreement between simulated and measured data [138]. However, it is mentioned that the

self discharge resistance is not presented and this leads to a deviation of about 5% in the

experimental and simulation results.

R. M. Nelms et al. described another approach in [139] where the supercapacitor

characteristics is modelled using a Debye polarization cell, aI schematic of which is shown

in Fig. 4.6 [139].

In the model, the circuit elements are related to the chemical reactions that occurred in the

supercapacitor. In the supercapacitor, charge is stored in the double layer formed at the

interface between a large surface area material such as activated carbon and a liquid

electrolyte. R1 is the separator resistance and depends on the concentration and

conductivity of the electrolyte used in the supercapacitor. The Helmholtz double-layer

capacitance (Cd) is influenced by: the temperature, concentration of the electrolyte and the

surface area of the electrode material. The charge transfer resistance (Rct) and adsorption

capacitance (Ca) represents charge transfer due to Faradic reactions at the surface of the

electrode material and it is affected by temperature [139]. The result of this model

suggested that total capacitance is always less than the rated capacitance.

Fig. 4.6 Circuit scheme of Debye polarization cell [139].

R1

Cd

Ca Rct

Page 101: ANALYSIS AND MODELLING OF ENERGY SOURCE …

101

4.3.2 Supercapacitor models with varying capacitance

Despite being successful in many aspects, most reported supercapacitor models ignore

temperature and nonlinear capacitance, and some of them employ complex impedances.

The most recently published models have incorporated variable capacitance that depends

on the cell terminal voltage. That is, the capacitance has a voltage dependency that is

explained by the cell electric field distribution. For example, if the voltage across the

supercapacitor increases, the electric field caused by the voltage increases and attracts

more ions around the electrodes. The concentration of ions near the electrodes increases

which is manifested by increased capacitance [133, 135].

A model implementing the variable capacitance feature is described by Zubita et al in

[140]. The model uses three distinct RC time constants in three parallel branch networks,

plus a high resistance element modelling cell leakage, as illustrated in Fig. 4.7 [140].

The first or immediate branch, with the elements Ri, Ci0, and the voltage-dependent

capacitor Ci1 in (F/V), dominates the immediate behaviour of the supercapacitor in the

time range of seconds in response to a charge action. The second or delayed branch, with

parameters Rd and Cd, dominates the terminal behaviour in the range of minutes. Finally,

the third or long-term branch, with parameters Rl and Cl, determines the behaviour for

times longer than 10 min. To reflect the voltage dependence of the capacitance, the first

branch is modelled as a voltage-dependent differential capacitor. The differential capacitor

consists of a fixed capacitance Ci0 and a voltage-dependent capacitor Ci1Vci. A leakage

resistor Rp, parallel to the terminals, is added to represent the self-discharge leakage [140].

Fig. 4.7 Equivalent circuit model for supercapacitor

incorporating variable capacitance [140].

Page 102: ANALYSIS AND MODELLING OF ENERGY SOURCE …

102

The equivalent circuit model of Fig. 4.7 has been simplified by J. M. Marie in [135], as

illustrated in Fig. 4.8. The model is used in power electronic applications where

supercapacitors are used to provide peak powers for only a few seconds. This means that

the second, third branches and the leakage resistance can be neglected. The capacitance in

the model is voltage dependent and Marie claims that the model shows a good agreement

when using Maxwell 2600 F cells [135].

Fig. 4.8 A simplified version of the model of Fig. 4.7 for power electronic circuit

applications [135].

When comparing between the constant capacitance and voltage variable capacitance

models Vural concluded that both models show good agreement between experimental and

simulation results when operating at the higher voltage end of the supercapacitor voltage

limits [132]. However, for low operating voltages the error between experimental and

simulation results in the constant models is increased. Moreover, for operational times

greater than 30 minutes, the agreement of the constant capacitance is less accurate by about

10% [132]. The authors in [132, 135, 140] experimentally obtained the differential

capacitance as the capacitance varies linearly with the capacitor voltage. Based on the fact

that the supercapacitor is a nonlinear capacitance and voltage dependent device, Maxwell

Technologies have developed a supercapacitor model called the reduced order model,

consisting of a series circuit having series connected resistance and inductance,

series/parallel elements modelling the equivalent series resistance and terminal parasitic

elements, a voltage dependent capacitance and a leakage element, as illustrated in Fig. 4.9.

The model and laboratory cell characterisation for different cell sizes is presented in [135]

where the bulk capacitance is related to terminal voltage by the linearised equation and the

parameter values are as in [135]:

cvc VkCVC += 0)( (4.3)

The model presented in [135] has been implemented in the Simplorer software, but the

author only presented the simple varying capacitance case of Eqn. (4.3). Further, although

the author presented a thermal model for an individual cell, multiple cell systems

modelling was not reported.

Page 103: ANALYSIS AND MODELLING OF ENERGY SOURCE …

103

Fig. 4.9 Maxwell model presented in [135].

4.4 The proposed supercapacitor model

4.4.1 Matlab/Simulink model

In this study the Maxwell supercapacitor model of Fig. 4.9 is built in the Matlab/Simulink

environment using Matlab/Simpower toolbox components, but using a variable non-linear

capacitance function determined from test and implementing a thermal model as part of the

full cell model. The developed Matlab/Simulink model is illustrated in Fig. 4.10, showing

the main passive circuit components (as for Fig. 4.9), the bi-polar input/output current

demand, a variable non-linear capacitance function block, cell power loss calculation block

and cell/module thermal model. The non-linear capacitance function is implemented via a

look-up table of capacitance versus terminal voltage data embedded within the block, as

illustrated in Fig. 4.11 showing the block internal details as presented by Simulink.

Page 104: ANALYSIS AND MODELLING OF ENERGY SOURCE …

104

Fig. 4.10 Maxwell model in Simpower Matlab.

Fig. 4.11 Details of the non-linear capacitance function block showing the look-up table.

Non-linear capacitance

function

Demand current

Loss calculation for input to

thermal model

Thermal model

Page 105: ANALYSIS AND MODELLING OF ENERGY SOURCE …

105

Note, there are several ways to connect the Simulink part of the model with the electrical

circuits modelled in Simpower, such as a controlled current source and a controlled voltage

source. The controlled voltage source has been chosen in the model because it can be

easily implemented using the Simpower tool box in Matlab and it provides good results in

terms of simulation stability.

The controlled voltage source model the non-linear capacitance according to the equation:

dtC

titv ∫= )()(

(4.4)

Thus, current should be measured to calculate the voltage (signal) that controls the voltage

source. The variable capacitance look-up table uses the voltage to determine the

corresponding value of capacitance from the voltage versus capacitance data, as shown in

Fig. 4.12. Integration is then performed to calculate the voltage connected to the

controlled voltage source. The look-up table data is taken from a series of tests undertaken

on a supercapacitor system comprising of 3x 48 volt, 165 F supecapacitors connected in

series, as will be discussed later.

0 0.5 1 1.5 2 2.5 31500

2000

2500

3000

3500

Cap

acita

nce

(F

)

Terminal Voltage (V)

Fig. 4.12 Supercapacitor cell non-linear capacitance versus voltage

function determined from test.

Page 106: ANALYSIS AND MODELLING OF ENERGY SOURCE …

106

4.4.2 Parameter temperature considerations

To consider the use of a supercapacitor in any vehicular application, the thermal behaviour

of the supercapacitor must be understood, particularly with regard to cyclic loading and the

varying ambient temperatures associated with vehicle applications as already discussed. It

is reported in [142] that the Maxwell supercapacitor equivalent circuit parameters are

essentially unaffected by temperature, being stable in terms of capacitance change over the

specified operating range (which is between -40º to +65º C), as illustrated in Fig. 4.13(a)

[142]. This is attributed to the fact that the charge storage is not a chemical reaction, and is

one of the advantages of supercapacitors in low temperature applications compared to

electro-chemical batteries. Note however that the upper operating temperature of +65º C

could still be prohibitively low in some climates and would necessitate forced or liquid

cooling if the ambient is raised closed to this level. The resistance is slightly affected over

the operation range due to ion mobility within the electrolyte, although being relatively

stable over the 0º to +70º C range.

Other authors have considered the effected of temperature changes on supercapacitor

dynamics, as discussed in [132-134, 143], where the authors show that there is a slight

change in supercapacitor capacitance over the operated temperature range, as illustrated in

Fig 4.13(b). It is noticeable that the capacitance is almost stable at temperatures above

zero, while the resistance is affected at low temperature, but with a very shallow change at

temperatures above zero, as shown in Fig 4.13(b). Although the supercapacitor dynamics

are affected at low temperature, in this study the operated temperature range of the

supercapacitor system is assumed to be around a min. ambient temperature of 5oC. Hence,

the resistance and capacitance changes are assumed negligible.

Page 107: ANALYSIS AND MODELLING OF ENERGY SOURCE …

107

(a) Capacitance and resistance variation with temperature as reported in [142].

(b) Capacitance and resistance variation with temperature as reported in [134] and [143].

Fig. 4.13 Reported supercapacitor parameter variation with temperature.

4.4.3 Thermal model

During supercapacitor charging and discharging operation, power loss is dissipated in the

supercapacitor cell resulting in an increase in the cell temperature. The power loss

dissipation leads to heat absorption into the cell thermal capacity and conduction to the cell

outer surface via its thermal resistance. In the supercapacitor cell block model illustrated

in Fig. 4.10, the power loss in each resistive element is summed within a block and this

then input to the thermal equivalent circuit of each cell, as shown in Fig. 4.14. Here, the

total cell power loss represents the thermal the heat source and values for the cell thermal

resistance to ambient, Rth, and cell thermal capacitance, Cth, are taken from Maxwell

supercapacitor cell of 3000F data sheets, as given in Table 4.1 [135].

Temperature (ºC)

Page 108: ANALYSIS AND MODELLING OF ENERGY SOURCE …

108

Rth 3.2 ºC/W passive

Cth 588 J/ºC

Operating temperature -40ºC to +65ºC

Storage temperature -40ºC to +70ºC

Table 4.1 Thermal parameters for Maxwell 3000F cell supercapacitor [135].

Fig. 4.14 Supercapacitor thermal equivalent circuit model.

25º

Page 109: ANALYSIS AND MODELLING OF ENERGY SOURCE …

109

4.4.4. Matlab/Simulink supercapacitor model validation

The supercapacitor model was initially validated by comparing published constant current

discharge profiles for the Maxwell 3000 F cells obtained from [141] with data generated by

the model simulated with a constant current discharge demand, as illustrated in Fig. 4.15,

showing a good agreement between published and simulated data. The difference between

the published and simulated data is mainly at the lower voltage level which is acceptable

since the supercapacitor will not typically be discharged below 25% of the maximum DC

voltage level due to power electronic and control considerations.

0.5

1

1.5

2

2.5

3

0 30 60 90 120 150 180 210 240Time (s)

Vol

tage

(V

)

Maxwell

sim

Fig. 4.15 Comparison between published and simulation model results.

As part of the DESERVE project [5], 3x 48V Maxwell supercapacitor modules, each

comprising of 18, series connected, 3000F cells (total 165F per module), were purchased

for subsequent installation on the project vehicle. The nominal supercapacitor module

voltage of 48 arises from an upper operational limit of 2.6 to 2.7 V per cell. Tests carried

out on the Maxwell modules were used to develop the Matlab/Simulink model capacitance

versus terminal voltage characteristic of Fig. 4.12, validate the model energy calculations

and thermal model.

The 3x 48V modules, SC1, SC2 and SC3, were series connected and then connected to the

output of a Ward-Leonard (W-L) motor-generator set (DC) via DC contactors, as

illustrated in Fig. 4.16 showing the power circuit schematic of the supercapacitor module

test facility and their respective voltage, current and temperature measurements. A picture

150A

10A

50A 100A

200A

Page 110: ANALYSIS AND MODELLING OF ENERGY SOURCE …

110

gallery of the supercapacitor module test facility main components is illustrated in Fig.

4.17, showing the PC for Labview control of the W-L set, voltage, current and temperature

data acquisition (a), the W-L set brushed DC and induction machines for implementation

of a controlled DC supply (b), the 3x 48 Volt, 165 F Maxwell supercapacitor units (c) and

measurement PCBs for the interface of voltages, currents and temperatures to the Labview

data acquisition system (d).

Control of the field winding of the Ward-Leonard DC motor-generator results in a

controlled DC-voltage at the terminals of the 3x 48V supercapacitor module bank. Typical

current peaks are in the order of 200A, with a peak power capability from the W-L set of

25kW. To test the supercapacitor capacitance-voltage characteristic, the supercapacitor

bank was charged to some initial voltage level. A Labview based controller was then used

to control alternate charge-discharge currents to the supercapacitor bank from the W-L set

with two primary goals:

• to maintain neutral charge, or the DC-link charge-discharge voltage within a fixed

envelope, during a cycle, and

• to control repetitive cycles and hence an essentially constant internal loss in order to

assess the thermal impact on the combined supercapacitor bank.

A series of tests were carried out based on varying the initial voltage level and the

Matlab/Simulink model capacitance versus terminal voltage characteristic of Fig. 4.12

determined. An example is illustrated in Fig. 4.18 showing a Maxwell 165F module DC

voltage variation due to alternate charge-discharge currents from the W-L set. The test is

executed for approximately 2500 seconds whereon the supercapacitors are discharged and

the temperatures monitored back to ambient (total test time of around 10,000 seconds). It

should be noted that the module voltage transitions are maintained within a 7.5 to 27.5 V

envelope on a mean of 17.5V. Fig. 4.19 illustrates a zoom in on this test showing

approximately 3 cycles of data.

Table 4.2 presents example calculations for the case where the Matlab/Simulink

supercapacitor model is simulated with the same input charge-discharge current profile as

illustrated in Fig. 4.19. By taking the average values of current and voltage, the table

results show good correlation between calculated and measured supercapacitor input-

output energies.

Page 111: ANALYSIS AND MODELLING OF ENERGY SOURCE …

111

Fig. 4.16 Power circuit schematic of supercapacitor module test facility.

Fig. 4.17 Picture gallery of supercapacitor module test facility.

ISCT IDC

Fieldcontrol

SC1 T1

En1

T2

En2

T3

En3

DC

VSC1

VSC2

VSC3

VSCT VDC

SC2

SC3

ControlcontactorM1

ISCT IDC

Fieldcontrol

SC1 T1

En1

T2

En2

T3

En3

DC

VSC1VSC1

VSC2VSC2

VSC3VSC3

VSCT VDC

SC2

SC3

ControlcontactorM1

(a) PC for Labview control and data acquisition

(b) Ward-Leonard for controlled DC supply

(d) Measurement PCBs

(c) 3x 48 Volt, 165 F Maxwell supercapacitor units

Page 112: ANALYSIS AND MODELLING OF ENERGY SOURCE …

112

Fig. 4.18 Maxwell 165F module DC voltage variation due to alternate

charge-discharge currents from the W-L set.

Fig. 4.19 Maxwell 165F module DC voltage and current variation

due to alternate charge-discharge currents from the W-L set.

SC Energy Loss

(kWh)

SC Input Energy (kWh)

SC Ouput Energy (kWh)

SC Energy efficiency

(%)

Simulation model 0.45 17.34 16.89 97.40

Measured 0.41 17.00 16.59 97.60

Note: Energy efficiency is over cycle duration

Table 4.2 Example comparison of simulated and measured energies for the charge-

0

5

10

15

20

25

30

25 50 75 100 125 150

Time (s)

Mod

ule

volta

ge

(V)

.

-200

-150

-100

-50

0

50

100

150

Mo

dule

cur

rent

(A

) .

Voltage Current

0

5

10

15

20

25

30

0 250 500 750 1000 1250 1500 1750 2000 2250 2500

Time (s)

Mo

du

le v

olta

ge

(V)

.

Page 113: ANALYSIS AND MODELLING OF ENERGY SOURCE …

113

discharge current profile illustrated in Fig. 4.19.

The repetitive test cycles, as illustrated in Fig. 4.18, result in an essentially constant

internal loss within the supercapacitor modules. This constant loss is used to assess the

module thermal performance and also confirm the suitability of the thermal simulation

model discussed in Section 4.4.3. Fig. 4.20 illustrates a comparison of the simulated

supercapacitor module temperature and measured temperatures taken around the Maxwell

module, again showing good agreement. The laboratory ambient is also included

highlighting a near fixed ambient during test. The results of Fig. 4.20 illustrate that the

predicted temperature lies between the minimum and maximum measured temperatures,

being closer to the maximum, which would be expected due to the transducer placements.

Fig. 4.20 Comparison of simulated and measured temperature of Maxwell module during

repetitive cycle regime as Fig. 4.18.

20

25

30

35

40

45

0 500 1000 1500 2000 2500 3000

Time (s)

Te

mpe

ratu

re (

degr

ees

C)

.

Maximum recorded temperature

Minimum recorded temperature

Ambient temperature

Model predicted temperature

Page 114: ANALYSIS AND MODELLING OF ENERGY SOURCE …

114

4.5 Vehicle on-board energy management

4.5.1 Principle of energy storage The energy storage capacity for a supercapacitor can be described by equation 4.5 [125]:

E = 0.5CV2 [4.5]

where E is the stored energy in Joules [J], V is voltage of the supercapacitor and C is

capacitance [F]. The distinguishing feature of supercapacitors is their particularly high

capacitance. Another measure of supercapacitor performance is the ability to store and

release the energy rapidly. This is the power density, P, of a supercapacitor and is given

by:

R

VP

4

2

= [4.6]

where, R is the internal resistance of the supercapacitor (ESR) [126].

4.5.2 Recovered energy

Having multiple energy source systems in EV highlights the importance of coordinating

and arbitrating power sharing between the system components. One of the benefits of

combining battery and supercapacitor in the electric vehicle of a rail based application is

the ability to save more 30% of total energy and recover regenerative energy [144].

The proposed control strategy is based on the diversion all recovered energy to the

supercapacitor, to guarantee that the supercapacitor should be fully charged when the

vehicle is at standstill because the possible next step is only to accelerate. However, the

amount of regerative energy gets back to the system when the vehicle at maximum speed,

because the possible next step is to decelerate.

The propulsion system power-train infrastructure from the energy source to the traction

wheels must be bidirectional and the energy source has to be receptive to regenerative

energy. The recovered energy will be either transferred to the supercapacitor or to the

battery. The most efficient way is to transfer it to the supercapacitor to store the energy for

the next acceleration period.

To obtain whole regenerative energy from supercapacitor, the energy rating should be

higher. In order to determine the sufficient energy in the supercapacitor, all power losses

Page 115: ANALYSIS AND MODELLING OF ENERGY SOURCE …

115

should be taken into account. During regenerative braking, the kinetic energy of the

vehicle should be fully converted and captured by the energy system through DC link.

Practically, only 30% to 50% of this energy is recoverable due to electrical and mechanical

losses when transferring power from the supercapacitor to the wheels [24], as illustrated in

Fig. 4.21.

wheelsfrom capturedenergy

at wheels avaliableenergy . =regenη

[4.7]

.... .. convtractransregen ηηηη = [4.8]

The amount of regenerative energy is depends on many factors such as motor, deceleration

rate and receptiveness of the energy storage system. In a rapid deceleration event, the

magnitude of power would be high in short period of time, which means a motor of a high

power rating is needed to capture that power. For a maximum energy capture, the change

in kinetic energy should be equal storage energy.

Fig.4.21 Electrical losses in the power-train.

4.5.3 Power-train losses

The DC-to-DC converter is a device that transfers DC power of one voltage level to

another level. Practically there are some losses during the process. The converter gain is

the ratio of output to input voltage as shown in Fig. 4.22, it is clear that the gain is linear in

only the blue bit area, so working in this area, the converter could be modelled as a gain

Page 116: ANALYSIS AND MODELLING OF ENERGY SOURCE …

116

[21]. The loss could be calculated by setting the converter efficiency at a constant, the

losses, hence, could be determined.

Fig. 4.22 The converter gain for DC-to-DC converter [ 21].

The DC-to-DC converter losses is basically based on power transfer; supercapacitor power

(PSC) could be found based on the following:

Boost case: (power transfer from supercapacitor to DC link)

LbatSC PPP += . [4.9]

Buck case: (power transfer from DC link to Supercapacitor)

LbatSC PPP −= . [4.10]

To find out a supercapacitor current

SC

SCSC V

PI =

[4.11]

The losses are classified as:

• IGBT power losses which including Power silicon losses which calculated from the

turn, Conduction losses, Turn-off losses, Diode reverse recovery losses, and Diode

losses,

• Inductor losses, and

• Capacitor losses.

Page 117: ANALYSIS AND MODELLING OF ENERGY SOURCE …

117

The drive-train losses are that occur in the subsystems such the traction motor and the

transmission losses. The traction motor losses are the losses that occur during motoring and

generator. The traction motor is a brushless permanent magnet machine with an integrated

gear reduction and differential drive to the vehicle back-axle. The machine is controlled

via a three phase voltage source converter, the DC supply to which is provided by the

traction battery. In the vehicle model as mentioned earlier, the traction motor loss is

calculated from efficiency map.

4.5.4 Control strategy

Different control strategies have been proposed to manage energy in hybrid systems. The

control aims to make main energy source, which means battery, to work at a constant or

low fluctuation current much lower than the demand, and to make the supercapacitor,

which has ability to capture and release energy very rapidly, provides most demand

transient current. In energy point view, the role of the battery is to provide the mean energy

requirements of the traction drive system, while the supercapacitor current exhibits the

high frequency transients of the traction machine drive.

Based on the proposed control strategy, the supercapacitor should be fully charged when

the vehicle at standstill state because the possible next step is only to accelerate. However,

the amount of regerative energy gets back to the system when the vehicle at maximum

speed, because the possible next step is to decelerate.

4.5.5 Phase compensating regulator design To facilitate a design of a suitable control strategy and an optimal management of energy

and power transfer between the components of the vehicle that shown in Fig. 4.23 (a), a

controller objective should be classified. Here the objectives of the applied controller are:

• Track a demanded velocity profile for the vehicle,

• Maintain the DC link voltage within given bounds,

• Minimise battery current fluctuations.

DC link voltage control uses a voltage reference as energy management control parameter,

when the DC link voltage is subjected to load current as disturbance, the principle of this

method is to regulate DC link voltage within a tolerance band around a set point reference

Page 118: ANALYSIS AND MODELLING OF ENERGY SOURCE …

118

voltage so the DC link is controlled the dips and rises during acceleration and braking

respectively.

The control loop, presented in Fig. 4.23 (b), used to regulate DC link voltage for the

system. The controller is designed by driving analytical expressions of the system, and

applying classical control design techniques.

The controller has been applied to the system model using a DC-link voltage regulator

configuration to maintain the DC-link voltage within given bounds and fully

supercapacitor utilisation and reducing the transient demand from the battery.

In order to design the controller, a mathematical description of the plant must be

developed.

The current drawn by the traction drive (Iload) will act as a disturbance on the VDC

regulator. In the event of a load disturbance, causing a supercapacitor discharge, the

control loop will act to force VDC to a desired value by application of battery current to

recharge supercapacitor

Load

DC DC

Load

DC DC

ZEBRA System

I bat.

I SC

I Load

SC Bank

(a) System electrical schematic.

Regulator DC/DC

Converter SC

Bank

IL

_

+

Vsc

+ _

VDC|

(b) Control system schematic.

Fig.4.23 Regulated DC link voltage control scheme.

The supercapacitor voltage is modelled using the Laplace differential operator s:

( ) ( )sc

scscscDC sC

RsCsIsV

)1( +−=

[4.12]

Page 119: ANALYSIS AND MODELLING OF ENERGY SOURCE …

119

The capacitor will act as an integrator for low frequency components of current due to the

pole, located at the origin, therefore, a finite DC component of current will result in a

voltage ramp across the capacitor. The zero is located at 1.1364 rads-1, as shown in Figs.

4.24 and 4.25, for frequencies above that the gain will asymptotically become a constant

value of Rsc. The sign of the current is negative as the current polarity is defined as positive

for discharging.

For the supercapacitor voltage control loop, the supercapacitor current may be determined

from Fig 4.23 (a) where

Batloadsc III −= [4.13]

-1.2 -1 -0.8 -0.6 -0.4 -0.2 0 0.2-0.06

-0.04

-0.02

0

0.02

0.04

0.06Open loop Plant

Real Axis

Fig. 4.24 Poles and zeros of the plant.

The voltage across the supercapacitor may be expressed as equation

loadsc

scscBat

sc

scscDC I

sC

RsCI

sC

RsCV

)1()1( +−

+=

[4.14]

The first term describes the relationship between the VDC state and the battery current,

where the second term is associated with a disturbance Iload, therefore the supercapacitor

plant may be expressed in the transfer function as

s

sRC

RI

V scscsc

Bat

DC

+

=

1

[4.15]

Real axis

Imag

inar

y ax

is

Page 120: ANALYSIS AND MODELLING OF ENERGY SOURCE …

120

The plant gain is a constant for high frequencies, as shown in Fig. 4.25, which will lead to

undesired high frequency noise. The response of the open loop plant is shown in Fig. 4.26.

-40

-30

-20

-10

0

10

20

10-2

10-1

100

101

102

-90

-45

0

Open loop Plant

Fig. 4.25 Open-loop Bode plots of the plant.

0 500 1000 15000

5

10

15

20

25

30

Step Response

Am

plit

ude

Time (s)

Fig. 4.26 Open-loop plant response.

To overcome this phase compensating regulator is introduced of in the form of equation:

Mag

nitu

de

(dB

)

Frequency (rad/s)

Ph

ase

(deg

)

Page 121: ANALYSIS AND MODELLING OF ENERGY SOURCE …

121

DCerrbat V

as

bI

+= [4.16]

It is normally possible to adjust the system’s response sufficiently to achieve the required

performance [145]. The open-loop transfer function is given as:

)(

1

ass

sRC

RbV

V scscsc

DCerr

DC

+

+

= [4.17]

The location of supercapacitor zero is 1.1364 rads-1, so to provide higher frequency

attenuation, the location of the controller pole will set at 1.5 rads-1, for this value of a=1.5.

To select DC-link voltage controller bandwidth, the dominant closed loop time constant is

equal to the longest period of acceleration in the driving cycle; hence the longest

acceleration period of the driving cycle used is 30 seconds, then the close loop bandwidth

will be set to 0.03333 rads-1.

To set the bandwidth of the supercapacitor voltage regulator to 0.03333rads-1, the gain is

chosen as one i.e. 1=DCerr

DC

V

V, Thus:

( 1.1364 0.03333)1 0.016

0.03333(1.5 0.03333)

2.7495

jb

j j

b

− +=+

=

[4.18]

The poles and zeros of the controller is shown in Fig. 4.27, the response of the system is

shown in Fig. 4.28. The Bode plot of the close loop system is shown in Fig. 4.29.

-5 -4 -3 -2 -1 0 1-0.25

-0.2

-0.15

-0.1

-0.05

0

0.05

0.1

0.15

0.2

0.25

Real Axis

Real axis

Imag

inar

y ax

is

Fig. 4.27 Poles and zeros of the system.

Page 122: ANALYSIS AND MODELLING OF ENERGY SOURCE …

122

0 20 40 60 80 100 120 140 160 1800

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1Closed loop Plant + Controllers

Am

plit

ud

e

Time (s)

Fig. 4.28 Close-loop system response.

-50

-40

-30

-20

-10

0

Mag

nitu

de (dB

)

10-3

10-2

10-1

100

101

-90

-45

0

Pha

se (de

g)

Closed loop Plant + Controllers

Ph

ase

(d

eg

)

Frequency (rad/s)

Ma

gnitu

de

(dB

)

4.29 Close-loop Bode plot of the system.

The demanded DC link voltage may be controlled by taking desired DC voltage as voltage

reference, the desired signal is to control the level of energy in supercapacitor to match the

kinetic energy of the vehicle:

sc

UscDC C

mvVCV

)( 22| −=

[4.19]

where, VDC| is the regulated DC link voltage, CSC is the capacitance of the supercapacitor;

VU is the terminal voltage, and mv2 is the kinetic energy.

Page 123: ANALYSIS AND MODELLING OF ENERGY SOURCE …

123

According to the concept of the control, the regulated DC link voltage should be equal to

the upper bound when the vehicle is standstill for an expected acceleration.

In addition, the demanded DC link voltage should be equal to the lower bound When the

vehicle at full speed, so the regenerative should be captured in the supercapacitor from the

next expected step which is deceleration or breaking.

4.6 Sizing of supercapacitor power buffer To use supercapacitor as energy storage system and to avoid over sizing supercapacitor

and then additional costs, and mass of the vehicle, it is important to calculate the proper

size supercapacitor to capture most of available braking energy for any velocity profile

[146].

4.6.1 Vehicle energy and power considerations Design and sizing an supercapacitor to meet the propulsion demands for a given velocity

profile is obtained from the regenerative energy, as well as considering mass, volume, cost

and high efficiency. For the DESERVE project [5] a vehicle of 3.5 tonne is chosen as the

case study, the vehicle and power-train parameters shown in detailed in Table 4.3. The

main energy source is the DESERVE ZEBRA battery; its parameters are shown in Table

4.4, combined with a supercapacitor power buffer, the design of which is discussed here.

4.6.2 Supercapacitor size

Initial sizing calculations for the supercapacitor system were based on the simulation

results of a case study vehicle over the DESERVE_ECE15 driving cycle shown in Fig.

4.30. It is chosen to be an example of the velocity profile which being the supercapacitor

sized accordingly to recapture all of the available regenerative braking energy.

The maximum and minimum supercapacitor voltage should be calculated from the

convertor stage and battery voltage, as mentioned in [105], in Fig. 4.22 if the conversion

factor of dc converter is 4 or less; input to output relationship is linear [21]. In this case

study the battery voltage is 320V, to obtain the minimum voltage of the supercapacitor of

80 V, (i.e. 320/4).

For practical application it is acceptable discharging on 50% voltage drop from its nominal

value, therefore for supercapacitor with a nominal voltage decrease on half of its value is

acceptable [105], 80 V is considered to be the half of the maximum value, which means

Page 124: ANALYSIS AND MODELLING OF ENERGY SOURCE …

124

that the supercapacitor voltage VSC =160V. The upper and lower boundaries are 80, 160

respectively to grant the DC converter is linear.

Model parameter Description Value Units

n Gear and deferential ratio 11.95 -

Jm Machine inertia 5.70x10-4 kg/m2

Jw Wheel inertia 0.164 kg/m2

η Machine efficiency 1.0 p.u.

df Distribution factor 1 -

rw Tyre radius 0.364 m

m Mass during test 3500 kg

Kr Co-efficient of rolling resistance 0.0267 -

g Gravitational constant 9.80665 m/s2

ρ Density of the air 1.23 kg/m3

Cd Co- efficient of drag 0.31 -

Af Frontal area 1.75 m2

Table 4.3 3.5 Tonne vehicle and power-train parameters for simulation model.

Parameter Value Units

Capacity 76 Ah

Rated energy 21.2 kWh

Open circuit voltage 279 V

Total weight 195 kg

Max. discharge current 224 A

Cell type DESERVE cell -

No. of cells in series 120 cells

No. of strings in parallel 2 string

Table 4.4 DESERVE ZEBRA battery parameters.

Page 125: ANALYSIS AND MODELLING OF ENERGY SOURCE …

125

0

10

20

30

40

50

60

0 50 100 150 200

Time (s)

Speed (km

/h)

Fig.4.30 DESERVE_ECE15 driving cycle.

The kinetic energy of the vehicle is given by:

2

21

mvWk = [4.20]

The operation stored energy from the supercapacitor system is determined by its upper and

lower limits:

)(21 22

LUscsc VVCW −= [4.21]

If a 2:1 operational voltage variation is assumed, 75% of the supercapacitor stored energy

is available for the power-train, i.e.

)(83

43

21 22

UscUscsc VCVCW

=

= [4.22]

According to the control strategy, the total kinetic energy is recoverable, so the minimum

capacitance could be calculated from:

sck WW = [4.23]

Then:

)(3

82

U

Ksc

V

WC =

[4.24]

In case of the DESERVE_ECE15, the peak linear velocity is 14m/s, and the mass of

Edison van is 3500kg, the kinetic energy is equal to:

Page 126: ANALYSIS AND MODELLING OF ENERGY SOURCE …

126

MJW 343.0= [4.25]

So, the total capacitance ( )scC required is 35.7F.

In order to evaluate the performance of the vehicle model over DESERVE_ECE15 driving

cycle, the losses of all components in the power train are calculated and simulated to be

50%, then:

( )MJWsc 515.0()5.0343.0343.0 =×+= [4.26]

Then the ideal capacitance is calculated to be:

CSC=53.6F

The Maxwell supercapacitor systems were the only real technology that was near market in

terms of the TSB remits. All other technologies were being offered at individual cell level

and with very little to no technical support or applications track-record. Hence, Maxwell

supercapacitors were the chosen technology for the vehicle validation platform. Maxwell

supercapacitor cell (3000F) is chosen in this case study, in order to assemble the total

capacitance.

totalP

scell C

N

NC =

[4.27]

Ns is the number of cells in series, and NP is the number of cells in parallel. The number of

cells in parallel is determined after the first iteration of the calculation, if the first iteration

indicates that there is a inadequate capacitance for the requirement, the capacitance can be

changed either by putting more cell in parallel or by using larger cells [111]. Regarding to

that NP is equal to 1 in this case, thus Ns= 56 cells in series.

From various systems available from Maxwell, the 125V and 48V units were the most

likely contenders since these components are ready stock items that have some industry

track record. BMOD0165-48.6V [141] is chosen to provide the total capacitance, three of

(BMOD0165-48.6V),which consists of 18 cells connected in series, are connected in series

to provide a terminal voltage of 145.8V and a capacitance of 56F, as illustrated in Fig.

4.31.

Recalculating the available energy in the selected supercapacitor bank between the voltage

boundaries (145.8-80V):

)(5.0 22

. LUsc VVCW −= [4.28]

By considering the 50% losses, the available energy should be equal or more than the

needed energy:

Ksc WMJW ≥= 6.0 [4.29]

Page 127: ANALYSIS AND MODELLING OF ENERGY SOURCE …

127

Individual unit voltage measurements (red)

Total series current measurement (blue)

Individual unit voltage measurements (red)

Total series current measurement (blue)

Fig.4.31 Connection scheme of three of Maxwell 165 F supercapacitor

modules into 146V, 56 F bank.

The case study is illustrated in Fig. 4.32.

Fig.4.32 The case study of the combination.

4.6.3 Full model simulation results

Some results of terminal voltages of both energy sources are shown in Fig. 4.33, while Fig.

4.34 shows the demand current, ZEBRA battery and supercapacitor currents.

The terminal voltage variation is very important on the battery life as well as inverter

design. The variation of the voltage defined as the dip voltage that occurs regarding to

discharging current.

Page 128: ANALYSIS AND MODELLING OF ENERGY SOURCE …

128

800 850 900 95050

100

150

200

250

300

Times (S)

Vo

ltag

e (V

)

Battery VoltageSC Voltage

Fig.4.33 Terminal voltages of both energy sources.

800 850 900 950-200

-150

-100

-50

0

50

100

150

200

Times (s)

Cu

rren

ts (

A)

SC currentDemand currentBattery current

Fig. 4.34 Currents of demand, battery, and supercapacitor.

To illustrate the impact of tiding up that variation range of the vehicle of 3500kg van over

DESERVE_ECE15 driving cycle, the model evaluated in two operation modes; pure

battery operation and battery with supercapacitor operation mode. Additionally, to

illustrate the comparison and to show the impact clearly, the third case considered the

energy system mass and called extra battery. The case presents a pure battery which its

mass is equivalent to the proposed system; this can be done by adding the weight of the

Page 129: ANALYSIS AND MODELLING OF ENERGY SOURCE …

129

supercapacitor system (supercapacitor bank with DC-to-DC converter) to the original

battery mass.

The mass of the supercapacitor system is calculated as three modules of Maxwell

(BMOD0165-48.6V), each weight 14.2kg [141]. The average mass of DC-to-DC

converter is about 25 kg, and then the total mass of the system is 67.6kg. This number

represents 0.17 of the total mass which are two ZEBRA batteries each 195kg (as in Table

4.4].

Pure Battery Extra Battery Battery with SC

DV Range km SOC Range km SOC Range km SOC

1.4 85.8 0.1 93.7 0.1 93.2 0.1

1.2 73.3 0.24 85.8 0.26 93.2 0.1

1 57.4 0.4 66.5 0.4 71.7 0.3

0.9 26.5 0.74 30.9 0.74 55.5 0.4

0.8 1.2 0.99 1.5 0.99 33.1 0.7 Table 4.5 Simulated range versus the voltage variation (DV).

The result shown clearly as in Fig. 4.35 and Table 4.5 that in the case of battery and

supercapacitor combination, the range is improved as well as the energy in the battery is

used efficiently. It is clear that the combination of ZEBRA and supercapacitor can

improved the terminal voltage fluctuation by 1 volt/cell in the battery. In addition, the

energy loss in the battery system is decreased from 10.5 and 8.5 kWh in extra battery and

original battery respectively to 5.3 kWh in a combination case, hence the energy loss of the

power-train is decreased, and hence the efficiency of the system is improved.

0

10

20

30

40

50

60

70

80

90

100

0.8 0.9 1 1.1 1.2 1.3 1.4

Voltage variation (DV) per cell (V)

Ra

nge

(km

)

Battery Only

Extra Battery

Battery with SC

Fig. 4.35 The range of the vehicle as the terminal voltage variation is tightened.

Page 130: ANALYSIS AND MODELLING OF ENERGY SOURCE …

130

Reducing the voltage variation could be done by adjusting the battery current using a

current limiter on the battery current, as battery current is decreasing, more relief on

battery and more range improvement as shown clearly in Fig.4.36 and Table 4.6 where the

battery current is decreasing from 75A to 25A. In addition, the power loss in the battery

system is reduced from 5.1 at 75A to 3.4 kWh at 25A. The voltage variation in the cases

of 75, 50, and 25A are shown in Fig. 4.37-4.39.

Ibat.=75A

Ibat.=50A

Ibat.=25A

V∆

Range SOC Range SOC Range SOC

1.4 93.4 0.1 97.8 0.1 111.2 0.1

1.2 93.4 0.1 97.8 0.1 111.2 0.1

1 73.7 0.3 80.9 0.3 111.2 0.1

0.8 40.2 0.6 60.4 0.5 84.3 0.3

Table 4.6 The range of the three currents with battery SOC.

0

20

40

60

80

100

120

0.8 0.9 1 1.1 1.2 1.3 1.4

Voltage variation/cell (V)

Ran

ge(k

m)

Ibat=75AIbat=50AIbat=25A

)

Fig. 4.36 The impact on the range when battery current limit is decreased.

Page 131: ANALYSIS AND MODELLING OF ENERGY SOURCE …

131

0 2000 4000 6000 8000 10000 12000 14000 16000 180000

50

100

150

200

250

300

350

Time (s)

Vol

tage

(V)

Supercapacitor Voltage

Battery Voltage at 75A

(a) Variation in terminal voltages.

1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 20000

50

100

150

200

250

300

350

Time (s)

Vol

tage

(V

)

Battery Voltage at 75A

Supercapacitor Voltage

(b) Timed-zoom for battery and supercapacitor voltage.

Fig. 4.37 Voltages when battery current limit is 75A.

Page 132: ANALYSIS AND MODELLING OF ENERGY SOURCE …

132

0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2

x 104

0

50

100

150

200

250

300

350

Time (s)

Vol

tage

(V)

Battery Voltage at 50A

Supercapacitor Voltage

(a) Variation in terminal voltages.

1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 20000

50

100

150

200

250

300

350

Time (s)

Battery Voltage at 50A

Supercapacitor Voltage

(b) Timed-zoom for battery and supercapacitor voltage.

Fig. 4.38 Voltages when battery current limit is 50A.

Page 133: ANALYSIS AND MODELLING OF ENERGY SOURCE …

133

0 0.5 1 1.5 2 2.5

x 104

0

50

100

150

200

250

300

350

Time (s)

Vol

tage

(V)

Battery Voltage at 25A

Supercapacitor Voltage

(a) Variation in terminal voltages.

1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 20000

50

100

150

200

250

300

350

Time (s)

Vol

tage

(V

)

Battery Voltage at 25A

Supercapacitor Voltage

(b) Timed-zoom for battery and supercapacitor voltage.

Fig. 4.39 Voltages when battery current limit is 25A.

Page 134: ANALYSIS AND MODELLING OF ENERGY SOURCE …

134

4.7 Summary

The supercapacitor is simulated as nonlinear voltage dependent capacitance, the model is

validated. The impact of temperature on supercapacitor bank is simulated and tested in the

laboratory. The control strategy was based on that the recovered energy, which transferred

to the supercapacitor proposed and designed.

Based on the vehicle model, the supercapacitor system for 3500 kg van over the

DESERVE ECE15 driving cycle is sized. As a result of the combination of ZEBRA

battery and supercapacitor, the battery mass is downsized by a approximately 17%.

At a fixed mass of battery, the performance of the vehicle is improved by:

• Increasing battery life by decreasing battery current fluctuation, which means

decreasing discharge/ charge current that drawn from the battery.

• The range is extended by about 24%.

• Better energy utilisation.

• Reducing the voltage variation on the battery voltage that makes the inverter

design simpler and less loss.

Page 135: ANALYSIS AND MODELLING OF ENERGY SOURCE …

135

CHAPTER 5

DOWNSIZIED AUXILIARY POWER UNIT IN A SERIES HYBRID POWER-TRAIN CONFIGRATION

5.1 Introduction The electric vehicle model is used to investigate and analysis a hybridisation of main

energy sources, i.e. ZEBRA battery and an auxiliary power unit, for a series hybrid electric

vehicle. A dynamic model of ICE/PM generator is developed and used as auxiliary power

unit in the model to configure a series hybrid power-train.

The objective of this Chapter is to design an optimized and downsized ICE/PM generator

in a series hybrid power-train configuration. Vehicle performance, driving range, and

battery utilization over many driving cycles for different case studies are presented. In

series hybrid electric vehicle, the ICE is completely decoupled from the drive train and it

used only to generate electrical power to improve fuel economy, reduce harmful emissions

compared to conventional ICE, and also to extend the limited battery range. This kind of

configuration is attractive for large vehicles that perform large amounts of stop-and-go

driving, such as buses, taxis, and delivery trucks. This kind of vehicle is highly inefficient

and produces high levels of emissions because they have a large engine. A hybrid electric

vehicle, as mentioned in Chapter 1, is a contender vehicle power-train since they alleviate

some drawbacks experienced with all electric vehicles in terms of range while providing an

intermediate power-train in the move from conventional to an all electric rational.

Recently, power assist hybrid electric vehicles, such as parallel and series parallel gasoline

ICE hybrid vehicles have been promoted by automotive manufactures and suppliers as an

effective way to achieve driving range equal to conventional ICE vehicles with less fuel

consumptions and less emissions.

Page 136: ANALYSIS AND MODELLING OF ENERGY SOURCE …

136

5.2 Hybridization ratio and ICE/HPM generator rating One of the important design criteria of hybrid combustion engine vehicles is the relative

size of the battery and engine, as illustrated in Fig. 5.1.The Hybridization Ratio (HR) is to

measure how strongly the energy sources in the power-train is hybridized [147, 23]. In

other words, HR can be characterized in terms of battery and ICE/HPM generator ratings

(capability) or in terms of the percentage share of battery and ICE/HPM generator power,

which depends on the driving cycle peak and average power requirements.

Fig. 5.1 Hybridisation of battery and ICE strategy in HEV.

Far from conventional vehicle, it is essential in a hybrid vehicle to operate each power-

train component at optimal efficiency to improve the overall efficiency of the vehicle.

Generally, the combination of ICE and battery system aims to optimise ICE engine

performance in best efficiency operating region, moreover, as a result of that fuel

consumption and gas emission are reduced.

ICE provides constant power is one of scenarios to optimise operating region of ICE in the

hybrid vehicles. The ICE in this case can be smaller and more efficient, because it provides

only a constant power, while the dynamic power is provided from another source and it

provides only a constant power, as shown in Fig. 5.2.

Fig. 5.2 Method to split power between two energy sources [23]

Battery size

ICE size

Conventional ICE vehicle

Pure electric vehicle

% Hybridisation ratio

-20

-10

0

10

20

30

40

50

60

0 5 10 15 20

Time (s)

Pow

er (

kW)

= +

0

0.5

1

1.5

2

2.5

3

3.5

0 5 10 15 20

Time (s)

Pow

er (

kW)

-20

-10

0

10

20

30

40

50

60

0 5 10 15 20

Time (s)

Pow

er (

kW)

Page 137: ANALYSIS AND MODELLING OF ENERGY SOURCE …

137

By applying that concept in series hybrid vehicle, a small engine is used to rotate a

generator at a constant speed and power output level. This set is combined with battery

system. When vehicle power requirements increases (acceleration), additional power is

drawn from an on board energy storage and when power requirements decreases, the

energy storage system is recharged. By this kind of structure, vehicle can recapture

regenerative braking, and increase engine efficiency.

To size the battery and ICE/HPM generator in the proposed series hybrid power-train

configuration, some driving cycles should be considered. For example, by using the

simulation results of any driving cycle, the energy consumed during the driving cycle and

driving time are found out. Then a constant power source that could be used to produce all

energy consumed during the driving time can be calculated as in Equation (5.1). Where, E

presents the energy consumption and T is the driving cycle time. In this case, the constant

power source is considered the maximum allowable ICE/HPM generator output power in

SHEV configuration as shown in Equation (5.2).

tconsP

hrT

WhEtan)(

)( = (5.1)

PP ICEPMtcons (max)tan == (5.2)

Further, the peak power requirements by the traction motor during this driving cycle are

directly obtained from driving cycle power demand waveform. Then the minimum battery

power requirements to provide vehicle total power demand is calculated as in Equation

(5.3).

(max)(min) ICEPMpeakbat PPP −= (5.3)

Where, Pbat(min) presents the minimum battery power needed in the SHEV, Ppeak is the

driving cycle peak power demand and PICE/HPM(max) is the maximum allowable

engine/generator output power. Thus, from the previous discussion, the percentage HR

can be based on the battery and ICE/HPM generator full ratings as calculated as in

Equation (5.4).

( )bat

bat ICE / HPM(max)

P%HR . 100

P P= +

(5.4)

Page 138: ANALYSIS AND MODELLING OF ENERGY SOURCE …

138

5.3 Proposed Power-train Applying that concept in series hybrid vehicle, a small engine is used to rotate a generator

at a constant, efficient speed and power output level. This set is combined with battery

system.

In a series hybrid vehicle, illustrated in Fig. 5.3, the ICE is downsized power capability to

operate the ICE engine over the most optimum region of the engine power-speed

characteristic in terms of specific fuel consumption and emissions.

Fig. 5.3 A series hybrid vehicle.

Generally, ICE’s demonstrate low specific fuel consumption over a relatively small region

of their engine power-speed characteristic. They also demonstrate particularly high fuel

consumption and emissions during transient engine operation. Therefore, mechanically

decoupling the ICE from the vehicle power-train (and hence road speed) and operating the

engine at a fixed speed and output power offers the potential for reduced engine size, fuel

and emissions reduction.

Brushless permanent magnet generators having a secondary source of excitation are an

interesting topology for implementation in a series hybrid vehicle; it is used in this

topology as an auxiliary power unit. Because of their duel excitation these machines are

referred to as hybrid permanent magnet (HPM) generators [149, 150]. The HPM machine

is a direct engine mounted generator in a series hybrid electric vehicle and is used to

optimise the ICE size and performance by maintaining a fixed ICE power output via the

HPM excitation field control scheme proposed in [149]. Hence, the interest in on-board

auxiliary power units that would serve as an energy input to the vehicle power-train during

sub-urban or highway driving, providing the desired range extension function for urban all-

electric vehicles.

Page 139: ANALYSIS AND MODELLING OF ENERGY SOURCE …

139

A combination of ZEBRA battery, as a main energy/power source, and ICE, as an

auxiliary source, is one of the combinations to achieve a high efficiency system. ZEBRA

provides the dynamic power while ICE provides a constant power. In this kind of

configuration, the whole system efficiency will be improved because the battery system

captures all regenerative energy and the auxiliary source operates at optimum operation.

In this Chapter, a typical 2.5 tonne taxi is considered as the reference vehicle, the power-

train of which is studied in terms of maximum driving range per full fuel tank, fuel

consumption and emissions for prescribed inner city and highway driving routs in the UK.

ZEBRA is considered in the proposed series hybrid electric vehicle power-train to

supplement the vehicle with the all-electric energy during city driving, since there is an

increasing trend in several major European cities to designate parts of the downtown areas

as "emission free" zones due to vehicular derived airborne emission problems.

A detailed analysis of series hybrid power-train that consists of dual power and energy

source is required in order to optimise component specifications and energy management

strategies. For example, it is recognized in the literature [150-155] that, different energy

source combinations in EV’s and series hybrid electric vehicle’s have been analysed and

optimised for desired operating conditions. Such that, Zhancheng et al [151] summarizes

different power control strategies for HEVs and presents an approach to optimise the

operation of series hybrid electric vehicles for fuel economy and emissions based on the

forecasting of future load demands.

Unlike some of the reviewed papers, HEV power management implementing engine start-

stop routines is not considered in this Chapter. Here the focus is on the series hybrid

electric vehicle’s performance and driving range extension while maintaining minimal

vehicle fuel consumption and emissions by an optimised and downsized ICE/HPM

component that represents the auxiliary power unit. In this Chapter, several case studies

and simulation results for different driving cycles are investigated.

The vehicle examined is a functional equivalent of a typical London taxi. The propulsion

system evaluated here consists of:

• A ZEBRA battery (Z5-557-ML3C-32) as a stand alone energy source in an all-

electric configuration, and

Page 140: ANALYSIS AND MODELLING OF ENERGY SOURCE …

140

• The ZEBRA battery, which presents the primary energy source, with a secondary

source comprised of an ICE/HPM generator system, fuelled by gasoline and used

mainly as a constant energy input to the vehicle power-train, essentially acting in a

range extending function in a series hybrid configuration format, as illustrated in

Fig. 5.4.

Fig. 5.4 The vehicle power-train in a series hybrid configuration format.

5.4 Series hybrid electric vehicle dynamic model representation The high level vehicle model, which illustrated in chapter 2, is used to investigate the

combination of ZEBRA battery and ICE/HPM as a range extender.

5.4.1 An ICE model In this Chapter, ICE is modelled to operate with a generator to be used as auxiliary energy

source in environmentally healthy operation. For this function, the ICE model is proposed

as efficiency map and implemented in Simulink/ Matlab environment. All parameters in

terms of gas emission and efficiency are predicted.

ICE efficiency map is simulated using data for Toyota Prius 1.5l (43kW) ICE stored in a

look up table of fuel consumption, efficiency, and gases emission. All data are in terms of

torque (Nm) and angular velocity (rad/s). The speed is chosen from the driving cycle’s

library, while the torque is calculated from the speed profile in the torque equation.

To investigate any ICE application using vehicle model, ICE size could be scaled up or

down to the required size. The ICE model is illustrated in Fig. 5.5; the inputs data of in this

case are generated from NEDC speed profile.

Page 141: ANALYSIS AND MODELLING OF ENERGY SOURCE …

141

(a) Simulink model

(b) Implementation of ICE Look up tables.

Fig. 5.5 Simulink ICE model.

The results of ICE efficiency and fuel consumption over NEDC driving cycle are shown in

Fig. 5.6, it is clear that the efficiency is very low and it changed not more 35%, the

efficiency is depends on the demand power, torque, and the linear velocity, which are the

Page 142: ANALYSIS AND MODELLING OF ENERGY SOURCE …

142

input. As a result of low efficiency, high fuel consumption is consumed and high rate of

emission, as shown in Fig. 5.6(b).

0 500 1000 1500 2000 25000.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

Time (s)

Effi

cien

cy (

%)

(a) ICE Efficiency.

0 500 1000 1500 2000 25000

0.5

1

1.5

2

2.5

3

Time (s)

Fu

el u

sed

(g

/s)

(b) ICE Fuel consumption.

Fig. 5.6 Example of ICE model outputs over typical NEDC driving cycle.

Page 143: ANALYSIS AND MODELLING OF ENERGY SOURCE …

143

5.4.2 The optimisation of ICE

To optimise the engine performance in terms of fuel consumption and gas emission, the

engine is operated at a fixed speed of 3000rpm (314 rad/s) chosen, in this case, to minimize

the ICE emissions for a constant output power, as illustrated in Fig. 5.7 showing ICE CO2

emissions for varying engine load torque and speed. The average fuel consumption and

emissions of the ICE hybrid were determined by scaling the fuel consumption and

emissions of the Toyota Prius 43 kW engine to the desired downsized ICE rating based on

the calculated peak power requirements calculated for the proposed driving cycles.

.

.

.. .

T=1 Nm

T=11 Nm

Operating line

0

5

10

15

20

25

30

50 100 150 200 250 300 350 400 450 500

Speed, rad/s

Car

bo

n d

ioxi

de,

mg

/s

Fig. 5.7 Engine emission for different torques.

5.4.3 Power-train Efficiency consideration

The prime mover for the taxi is a brushless permanent magnet (BLPM) machine with an

integrated gear reduction and differential drive to the vehicle back-axle. The BLPM

machine is controlled via a three phase voltage source converter, the DC supply to which is

Page 144: ANALYSIS AND MODELLING OF ENERGY SOURCE …

144

provided by the traction battery and ICE/HPM generator combination. In order to evaluate

the performance of the vehicle model under different modes of operation, the losses of all

components in the power-train are calculated from during the vehicle simulation.

The traction machine operates as a motor during acceleration or as a generator during

regenerative mode. The efficiency is calculated from an efficiency map of the complete

machine power converter embedded as a Look-up table in the traction system model, as

illustrated in Fig. 5.8.

Fig. 5.8 Matlab/Simulink traction machine dynamic model.

5.5 Case studies and simulation results Before starting the analysis on both EV and SHEV power-train, a benchmark data of pure

conventional vehicles for urban, sub-urban and combined driving cycles of different

generations have been obtained. There are many generation of LTI taxi sited in the internet

[156], in which, some of the different generations and some actual data that have been

gathered from different taxi drivers are listed in Table 5.1 and 5.2. The new generation is

made 2006, where the old one is 2001. Moreover, the collected data in Table 5.1 is

compared with numerical test results, via the proposed vehicle power-train simulation

platform, of a scaled up (75 kW) ICE, which supports vehicle dynamic model accuracy.

The vehicle dynamic model simulation results predicts fuel consumption in mile per UK

gallon (m/g) and CO2 emission which shows to be very close to the actual taxi data, as in

Table 5.1.

Page 145: ANALYSIS AND MODELLING OF ENERGY SOURCE …

145

Driving cycle

Old generation (Auto)

New generation (Auto)

New gen. (Manual)

Urban 25.3 25.5 28.0

Sub- urban

35.1 38.2 41.5

Fuel consumption

(m/g)

combined 30.7 32.0 36.2

CO2 Emission (g/km)

Sub- urban

243

233

211

Table 5.1 London taxi LTI TX4 specification of two made

(Auto and Manual) over NEDC.

Driving cycle

Actual data (2005-2009)

Scaled ICE (75 kW Max.)

Urban 23.0 23.5

Sub- urban

27.1 28.0 Fuel consumption

(m/g)

combined 25.0 25.9

CO2 Emission (g/km)

Sub- urban

--

267

Table 5.2 Actual and scaled 75kW Toyota Prius over NEDC.

The reference or base point for these case studies is two typical driving regimes that may

be called on by a taxi in everyday operation:

• Manchester inner city driving characterised by ECE15 driving cycle.

• Motorway driving where an example destination of Manchester to London

(equating to 335 km) is chosen.

The assumption is that the taxi generally operates on inner city routes that could be

facilitated by all-electric operation, but that occasionally an inter-city route is required

demanding a higher energy usage than would normally be experienced. How then will the

power-trains of the future be augmented to satisfy these competing challenges is the

question to be addressed.

For the specified series hybrid vehicle power-train, a production penetration scenario is

needed to asses the adequacy of the calculated ICE/HPM generator size.

Page 146: ANALYSIS AND MODELLING OF ENERGY SOURCE …

146

The vehicle assessment is based on vehicle driving range, battery SOC, specific fuel

consumption and emissions, by the taxi, for the two driving cycles. Note that the

degradation of ICE function with time is ignored in this assessment.

Repetitive cycling of the sub-urban part of the New European Driving Cycle (NEDC) and

US Highway driving cycle (HWFET) were the chosen duty profiles used in the simulation

study, as illustrated for reference in Fig. 5.9 respectively. Table 5.3 summarizes the

specifications of the proposed cycles, highlighting the wide disparity in peak-to-average

power requirements.

4X ECE15

Sub-urban

0

10

20

30

40

0 100 200 300 400 500 600 700 800 900 1000 11001200

Time, s

Sp

eed

, m/s

(a) Sub-urban part of the NEDC

0

10

20

30

0 200 400 600 800

Time, s

Sp

eed

, m/s

(b) US Highway driving cycle (HWFET)

Fig. 5.9 Reference duty profiles for the simulation study.

Page 147: ANALYSIS AND MODELLING OF ENERGY SOURCE …

147

Driving cycle

profile

Re-gen. braking

Cycle Time (s)

Average power (kW)

Peak power (kW)

Yes 17.8 NEDC Sub-urban No

400 18.4

63.2

Yes 20.5 HWFET

No 765

20.8 62.0

Yes 5.81 ECE 15

No 195

6.07 35.1

Table 5.3 Summary of power requirements for proposed vehicle driving profiles.

Fro sub-urban driving cycle, as illustrated in Table 5.3, the peak power required to the

traction motor during this driving cycle is about 63.2 kW.

Using the simulation, the energy consumed during the driving cycle and driven time are

found out. Then a constant power source that could be used to produce all energy

consumed during the driven time can be calculated using equation 5.1.

In this case, the constant power source will be considered as a maximum ICE PM Power,

in case of sub-urban NEDC , applying equation 5.2,

kWPP ICEPMtcons 18(max)tan ==

Thus, the minimum battery power required to provide the total power is calculated using

equation 5.3,

kWPbat 2.45182.63(min) =−=

From this calculation and based on the discussion earlier for ICE and battery combination,

ICE to provide a constant power where the battery system to provide the dynamic power,

and to move out from all electric to hybrid, the limits of battery power is between 64kW

(total of two ZEBRA batteries) and the minimum limit (45.2kW), as shown in Fig. 5.10,

and ICE size limits between zero at all electric vehicle to 18kW.

Fro US highway driving cycle: as illustrated in Table 5.3, the peak power required to the

traction motor during this driving cycle is about 62 kW.

In US highway HFET driving cycle case,

kWPP ICEPMtcons 20(max)tan ==

Page 148: ANALYSIS AND MODELLING OF ENERGY SOURCE …

148

Thus: the minimum battery power required to provide the total power is calculated using

equation 5.3,

kWPbat 422062(min) =−=

likewise, the limits of battery power is between 64kW (total of two ZEBRA batteries) and

the minimum limit (42kW) ,as shown in Fig. 5.10, and ICE size limits between zero at all

electric vehicle to 20kW.

Hence, for the specified series hybrid vehicle power-train, a production penetration

scenario is needed to asses the adequacy of the calculated ICE/HPM generator size. Based

on sub-urban NEDC and HWFET, the maximum allowable ICE/HPM generator output

power in the proposed SHEV power-train configuration are 18, 20 kW respectively.

Therefore, three case studies are considered, in here, each with two operating scenarios.

Case 1 and 3 presents a comparison of a pure EV mode, i.e. ZEBRA battery only, and a

hybrid mode comprising of the ZEBRA battery and a 3kW ICE/HPM generator system.

Case 2 presents a comparison of a hybrid mode with a larger ICE/HPM generator system,

which attains the desired minimum range of driving between some destinations, i.e. a

ZEBRA battery and a 14.55 kW ICE/HPM generator system that is scaled from the 3 kW

unit have been selected. For reference, a pure EV is considered where the ZEBRA battery

system has an increased mass equivalent to the 14.55 kW ICE/HPM generator and 2/3 of

the full fuel tank mass. Fig. 5.10 shows the HR due to 3 and 14.5 kW ICE/HPM

generators.

Fig. 5.10 Hybridization Ratio plot for Case 1 and 2.

64 0 48 16 32 32 16 48 0 64 100 80 60 40 20 0

Bat

tery

pow

er, k

W IC

E/H

PM

Pow

er, kW

% Hybridisation ratio

3 kW ICE/HPM 14.55 kW ICE/HPM Max. allowable ICE/HPM power

Page 149: ANALYSIS AND MODELLING OF ENERGY SOURCE …

149

5.5.1 Simulation results

Vehicle fuel consumption (VFC) is simply calculated as in Equation (5.5). Where, FCR

represents the fuel consumption rate, ICEP the input power of the HPM generator (which is

calculated by the addition of the HPM generator output power and its stator and rotor

losses), t is the instantaneous driving time, ICEη is the ICE efficiency and EC the energy

content of gasoline in consumed fuel rate.

EC

tPFCR

VFC ICE

ICE

(5.5)

Then, vehicle fuel consumption is used to calculate the mass of the fuel tank (kg) using the

litre to gram conversion factor which is 737.22 for gasoline. The mass is based on the

maximum fuel capacity of the vehicle fuel tank which is 15 litres. Simulation results of the

study cases are shown in Tables 5.4 and 5.5. The results illustrates that driving range can

be extended by 18% and 23% for HWFET and NEDC cycles, respectively, in case 1; and

the driving range can be extended by 34% and 52% for HWEFT and NEDC, respectively,

in case 2. However, using the combination of case 1, the vehicle could not reach the

proposed destination, but the energy used was better than the pure battery scenario. In case

2, where equal energy storage mass for both scenarios was taken into account, the new

rating of the ICE/HPM generator system in the proposed taxi power-train reached the

specified destination and passed it by 102 km with less CO2 emission, comparing to the

European Commission proposal for 2012 which is 120g/km [157]. A better utilization of

the battery SOC, i.e. down to 0.1, is achieved by the NEDC cycles of scenario 2 in case 2 if

it were to be compared with 0.149 as in NEDC cycles of scenario 2 in case 1. Moreover,

stored energy in the proposed combination was used efficiently for both driving cycles.

Page 150: ANALYSIS AND MODELLING OF ENERGY SOURCE …

150

Scenario 1 Scenario 2

Case 1 Pure EV mode Hybrid mode ZEBRA + 3kW HPM

Driving cycles HWFET

NEDC

Sub-Urban

HWFET

NEDC

Sub-Urban

Range (km) 103 89.3 121.8 110.3 Fuel use (l) 0 0 1.566 1.721

Fuel use (l/km) 0 0 0.0128 0.0156 SOC 0.1 0.177 0.1 0.149

CO (g/km) 0 0 0.56 0.65 CO2 (g/km) 0 0 25.3 30.14 HC (g/km) 0 0 0.136 0.159 NO (g/km) 0 0 0.265 0.31

Notes: The energy content of gasoline in 1 litre = 32.2 MJ and The gram to litre conversion factor = 737.22.

Table 5.4 Comparison of the simulation results between pure electric and hybrid vehicle modes of Case 1.

Scenario 1 Scenario 2

Case 1 Pure EV mode Hybrid mode ZEBRA + 14.5kW HPM

Driving cycles HWFET

NEDC

Sub-Urban

HWFET

NEDC

Sub-Urban

Range (km) 154.3 124.2 361.9 437.5 Fuel use (l) 0 0 21.7 30.93

Fuel use (l/km) 0 0 0.06 0.0707 SOC 0.1 0.24 0.1 0.1

CO (g/km) 0 0 1.87 2.2 CO2 (g/km) 0 0 86.5 102 HC (g/km) 0 0 0.456 0.537 NO (g/km) 0 0 0.89 1.05

Table 5.5 Comparison of the simulation results between pure electric and hybrid vehicle

modes of Case 2.

Furthermore, Fig.5.11 shows how the total power demand positive peaks decreases (in

generation mode) which means that the ICE/HPM share the demand power and how the

total power demand negative peaks increases (in regeneration mode) which means that the

ICE/HPM charge the battery in case of no demand to the load, this gives a better battery

utilization due to the inclusion of ICE/HPM generator constant power supply. Moreover,

the terminal voltage variation is less due to the proposed ICE/HPM generator size in

SHEV, as result of that the driving range of the proposed combination is extended.

Page 151: ANALYSIS AND MODELLING OF ENERGY SOURCE …

151

0 100 200 300 400 500 600 700 800 900 1000

-10

0

10

20

30

40

50

Time (s)

Po

wer

(kW

)

Total powerICE/HPM powerBattery power

Fig. 5.11 Power demand from each energy source component.

The inner city driving for pure electric and ZEBRA + 3kW ICE/HPM generator results are

illustrated in Table 5.6. The results shows that there is a 100% driving range improvement

in the hybrid case mode, however, since the engine is in operation for the whole period of

the driving cycle, and even at zero speed, the fuel consumption increased by almost a

factor of six if it was to be compared with fuel consumption of the sub-urban driving cycle

cases.

Page 152: ANALYSIS AND MODELLING OF ENERGY SOURCE …

152

Scenario 1 Scenario 2 Case 3 Pure EV mode

ZEBRA only Hybrid mode

Hybridization ratio=95.5 ZEBRA + 3kW HPM

Driving cycles ECE 15 ECE 15

Range (km) 92.01 183.4

Fuel use (l) 0 9.677

Fuel use (l/km) 0 0.0528

Fuel use (m/g) 0 53.5

SOC 0.1 0.1

CO (g/km) 0 2.29

CO2 (g/km) 0 105.45

HC (g/km) 0 0.558

NO (g/km) 0 1.089

Table 5.6 Comparison of the simulation results between pure electric and hybrid vehicle modes

of Case 3(inner city driving ECE 15).

5.5.2 Comparison between hybrid and conventional vehicle

Fig. 5.12 illustrates in a summarized way the comparison between equal masses of four

energy systems considering the all-electric, hybrid (3 and 14.5 kW), and pure conventional

vehicle case over sub-urban NEDC in terms of range, emission, and fuel economy. For

pure conventional vehicle the emission equals 267 g/km, where for hybrid vehicle cases it

equals 26.56 and 102 g/km for 3 and 14.5 kW ICE/HPM generator systems respectively. In

the 14.5 kW ICE/HPM generator case, the fuel economy and range shows a better results

than the pure conventional case due to the optimized down scaled engine. Moreover, in

terms of range improvement, for a similar fuel tank capacity, the 14.5 kW ICE/HPM

hybrid vehicle case the driving range reaches 430 km, where for the 75 kW pure

conventional vehicle the driving range equals 300 km. Hence, a greater driving range have

been achieved by the inclusion of a small engine in the EV with the appearance of a small

amount of emission if it was to be compared with the pure electric case, however this

emission is almost one third the pure conventional vehicle case.

Page 153: ANALYSIS AND MODELLING OF ENERGY SOURCE …

153

0

60

120

180

240

0102030405060708090100

All-electric Hybridsation ratio, % Conventional

Range, km

; C

arbon d

ioxi

de, g/k

m

0

80

160

240

320

400

480

Fuel e

conom

y, m

pg

Fuel economy (mpg) Carbon dioxide emission

Range (km) EU CO2 emission standred, 2012

Fig. 5.12 Comparison between the all electric, hybrid (3 kW, 14.5 kW), and pure conventional vehicle Cases over Sub-Urban NEDC.

5.6 Summary A detailed dynamic model of series hybrid electric vehicle powered by a combination of

battery and ICE/HPM generator systems, has been used to investigate all- and hybrid-

electric vehicle operation via case studies based on a typical urban 2.5 tonne taxi. In the

taxi power-train, a ZEBRA battery presents the main energy source while an ICE based on

a downsized Toyota Prius engine and HPM forms an auxiliary energy source to provide the

desired range extension function. Different scenarios are discussed for the optimal

operation of the vehicle on the road to asses the adequacy of the calculated ICE/HPM

generator size. The assessment is based on vehicle driving range, battery SOC, ICE

specific fuel consumption and emissions for two driving cycles, inner city and

suburban/motorway. The simulation model is used to determine a minimum ICE/HPM

generator rating which, for the cases considered, equated to 14.55 kW. Thus, by

employing the 14.55 kW ICE/HPM generator, as in scenario 2 of case 2, the simulation

results suggest that the proposed combination can fulfilled the requirements of emissions

lower than the 2012 European Commission proposal. In addition, the battery energy is

used more efficiently and an improved battery life is suggested by virtue of the reduced

Page 154: ANALYSIS AND MODELLING OF ENERGY SOURCE …

154

transient battery loadings. Hence, for engine assist hybrid electric vehicles in series

power-train configurations, existing ICE technology and efficiency can reduce CO2

emissions per km while satisfying the desired range extension functions detailed in the

considered case studies.

Page 155: ANALYSIS AND MODELLING OF ENERGY SOURCE …

155

CHAPTER 6

CONCLUSIONS AND RECOMMENDATION FOR

FURTHER WORK

6.1 Conclusions

Comparing with internal combustion engine (ICE) vehicles, Electric vehicles (EV’s)

powered by electro-chemical batteries are more reliable, safe and better quality in terms of

performance and energy conversion efficiency, moreover, they are environmentally free of

emissions. The environmental issues and concerns over sustainable energy use are the key

motivating factors in the development of alternative energy sources and power-trains for

road vehicles. These early advantages quickly subsided with the internal combustion

engine (ICE) which addressed the range issue that was, and still is, problematic with

electric vehicles. The implementation of more than one energy source in an electric vehicle

power-train is to elevate the problems faced by the limited energy density of existing state-

of-art electro-chemical batteries. In this study, some power-train configurations of hybrid-

electric vehicles have been proposed, modelled and then investigated.

The proposed models of energy system components are integrated into a complete vehicle

model that will approximate the behaviour of the system of the interest. The model showed

Page 156: ANALYSIS AND MODELLING OF ENERGY SOURCE …

156

how component choices affect the overall performance of the system beyond the particular

aspect that motivated the selection. The system model suggested a set of combinations by

selecting and sizing and configuring the components, and then optimises the control

scheme to get the performance requirements.

There are many options of energy source combinations for electric vehicles, in this study

ZEBRA battery is chosen to be modelled as energy dense source, supercapacitor is

simulated as a part of the model to present the power dense, ICE and generator set also is

modelled and tested as energy extended for the main energy dense.

The look-up table ZEBRA model is validated by measured data provided by the

DESERVE project, the model showed an excellent agreement with the measured result.

Regardless to other batteries, in ZEBRA battery the cell failed to a short circuit which

makes the string can continue to operate; this feature makes ZEBRA battery is very robust.

In Chapter 3, the multi-battery system has been modelled. The model showed the

interconnection between the ZEBRA batteries and how the batteries share current in

different cases. The MBS is simulated manages the unbalanced system to maintain vehicle

functionality by disconnecting the faulty battery. The real field data of four batteries

system has been used to valid the model. The model showed a good agreement with the

real data. The performance of the multiple battery systems in the case of various unbalance

operating scenarios hence are analysed and investigated.

In Chapter 4, the supercapacitor is simulated as nonlinear voltage dependent capacitance,

the model is validated. The impact of temperature on supercapacitor bank is simulated and

tested in the laboratory. The control strategy was based on that the recovered energy,

which transferred to the supercapacitor proposed and designed. Based on the vehicle

model, the supercapacitor system for 3500 kg van over the ECE15 driving cycle is sized.

As a result, the battery mass is downsized by approximately 17%.

At a fixed mass of battery, the performance of the vehicle is improved by:

• Increasing battery life by decreasing battery current fluctuation, which means

decreasing discharge/ charge current that drawn from the battery.

• The range is extended by about 24%.

• Better energy utilisation.

• Reducing the voltage variation on the battery voltage that makes the inverter design

simpler and less loss.

Page 157: ANALYSIS AND MODELLING OF ENERGY SOURCE …

157

In Chapter 5, a detailed dynamic model of series hybrid electric vehicle powered by a

combination of battery and ICE/HPM generator systems, has been used to investigate all-

and hybrid-electric vehicle operation via case studies based on a typical urban 2.5 tonne

taxi. In the taxi power-train, a ZEBRA battery presents the main energy source while an

ICE based on a downsized Toyota Prius engine and HPM forms an auxiliary energy source

to provide the desired range extension function. Different scenarios are discussed for the

optimal operation of the vehicle on the road to asses the adequacy of the calculated

ICE/HPM generator size. The assessment is based on vehicle driving range, battery SOC,

ICE specific fuel consumption and emissions for two driving cycles, inner city and

suburban/motorway.

The simulation model is used to determine a minimum ICE/HPM generator rating which,

for the cases considered, equated to 14.55 kW. Thus, by employing the 14.55 kW

ICE/HPM generator in the model, the proposed combination fulfilled the requirements of

emissions lower than the 2012 European Commission proposal. In addition, the battery

energy is used more efficiently and an improved battery life is suggested by virtue of the

reduced transient battery loadings. Hence, for engine assist hybrid electric vehicles in

series power-train configurations, existing ICE technology and efficiency can reduce CO2

emissions per km while satisfying the desired range extension functions detailed in the

considered case studies.

6.2 Contribution

In this project, a complete all electric and hybrid electric vehicles has been implemented

and validated over real driving cycles. This work develops a model for a multi-battery

system (MBS) to study unbalanced operation and investigate it’s impact on vehicle

performance in terms of range and energy use.

This analysis also develops a Maxwell supercapacitor model using a variable non-linear

capacitance function determined from test, and implementing a thermal model as part of

the full cell model. The test of three 48V modules connected in series was carried out over

a dynamic regime common for EV applications. The results show good correlation

between calculated and measured supercapacitor input-output energies, as well as

calculated and measured temperatures.

6.3 Publications arising from this thesis study

The following is a list of conference and journal publications that resulted from this study:

Page 158: ANALYSIS AND MODELLING OF ENERGY SOURCE …

158

1 Jarushi, A. M., Schofield, N.: “Modelling and analysis of energy source

combinations for electric vehicles”, World Electric Vehicle Journal, Vol. 3, Paper

5940531, pp. 1-7, 2009, ISSN 2032-6653.

2 Jarushi A., Schofield N.: “Modelling and Analysis of Energy Source

Combinations for Electric Vehicles”, EVS24, Stavanger, Norway, May 13-16,

2009.

3 Jarushi A., Schofield N.: “Multiple Battery Systems for Electric Vehicles”,

EVS24, Stavanger, Norway, May 13-16, 2009.

4 Jarushi, A. M.; Schofield, N.: "Battery and supercapacitor combination for a series

hybrid electric vehicle", 5th IET International Conference on Power Electronics,

Machines and Drives (PEMD 2010), pp.1-6, 19-21 April 2010.

5 Al-Adsani A., Jarushi A., Schofield N.: “Operation of a Hybrid PM Generator in a

Series Hybrid Electric Vehicle”, The 35th Annual Conference of the IEEE

Industrial Electronic Society (IECON 2009), Porto, Portugal, 3-5 Nov. 2009.

6 Al-Adsani A., Jarushi A., Schofield N.: “An ICE/HPM generator range extender

in a series hybrid electric vehicle”, 5th IET International Conference on Power

Electronics, Machines and Drives (PEMD 2010), pp.1-6, 19-21 April 2010.

7 Al-Adsani A., Jarushi A., Schofield N.: “An ICE/HPM generator range extender

in a series hybrid electric vehicle”, submitted to IET Journal, 2010.

6.4 Recommendations for further work

Although the vehicle models with proposed combinations of energy sources have been

successfully implemented and investigated, some recommendations are useful in order to

improve the model performance. The ZEBRA model developed in this work could be

modified by introducing a thermal model and this would result in improving the overall

model resolution. Further work on developing a more advanced model that would

incorporate other battery technologies, like the LiIon battery, and thus facilitate

comparison between a wider range of technologies in terms of energy and efficiency,

would be beneficial, and lead to an improvement in identifying the optimal vehicle energy

source combination.

.

Page 159: ANALYSIS AND MODELLING OF ENERGY SOURCE …

159

REFERENCES

[1] I. Husain.: “Electric and Hybrid Vehicles-Design Fundamentals”, CRC Press, ISBN 0-8493-1466-6, 2003.

[2] C. C. Chan, "The State of the Art Electric and Hybrid Vehicles," Invited Paper for the Proceedings of the IEEE, Vol. 90, pp. 247-275, 2002.

[3] C. C. Chan and K. T. Chau.: “Modern Electric Vehicle Technology”, Oxford University Press, ISBN0-19-850416-0, 2001.

[4] B. Godfrey.: “Managing Energy Demand”, Power for a sustainable future, open university, 2003.

[5] N. Schofield et al.: “Develop high Energy battery and high power Supercaps for all Electric Range Van Evaluation (DESERVE)”, Technology Strategy Board, Low Carbon Vehicles Innovation Platform, Project No. TP/9/LCV/6/I/S0037C, Aug. 2008 - Feb. 2011.

[6] F. Lewis.:“Reducing oil consumption in transport: combining three approaches”, Report No. EET/2004/01, Paris, April 2004.

[7] DERFA Report.: “2005 UK climate change sustainable development indicator and greenhouse gas emissions”, Nobel House, 17 Smith Square, London SW1P 3JR.

[8] W. Lloyd, F. Lewis.: “Climate Change Mitigation and Transport in Developing Nations”, Transport Reviews, Vol. 25, No. 6, pp. 691-717, November 2005.

[9] G. Davies.: “Driving up CO2 Emissions from Road Transport: An Analysis of Current Government Projections”, Transport report, 2006, www.foe.co.uk, last accessed 2 -7-2007.

[10] EU JRC/IES.: “Well-to-Wheels analysis of future automotive fuels and power-trains in the European context”, WELL-to-WHEELS Report, Ver. 1b, January 2004. Report available as an ADOBE on the JRC/IES. ebsite at: http://www.ies.jrc.cec.eu.int , Last accessed 2008.

[11] M. Ehsani, K. M. Rahman, and H. A. Toliyat.: "Propulsion system design of electric and hybrid vehicles," IEEE Transactions on Industrial Electronics, Vol. 44, pp. 19-27, 1997.

Page 160: ANALYSIS AND MODELLING OF ENERGY SOURCE …

160

[12] A. K. Shukla, A.S. Arico, V. Antonucci.: “An appraisal of electric automobile power sources”, Renewable and Sustainable Energy Reviews 5, pp. 137-155, 2001.

[13] E. Karden, P. Shinn, P. Bostock, J. Cunningham, E. Schoultz, D. Kok.: “Requirements for future automotive batteries- a snapshot”, Journal of Power Sources 144, pp. 505-512, 2005.

[14] P. V. Bossche, F. Vergels, J. V. Mierlo, J. Matheys, W. V. Autenboer.: “SUBAT: An assessment of sustainable battery technology”, Journal of Power Sources 162, pp. 913-919, 2005.

[15] P. H. Mellor, N. Schofield, D. Howe.: “Flywheel and Supercapacitor Peak Power buffer technologies”, IEE, London, 2000.

[16] N. Schofield, P. Bentley, D. A. Stone.: “The parallel combination of VRLA and supercapacitor for use as a hybrid vehicle peak buffer”, Journal of Power Source 147, pp. 288-294, 2005.

[17] H.T. Yap, N. Schofield, and C. M. Bingham.: “Hybrid Energy/power sources for electric vehicle traction systems”, IEE PEMD Conference, pp. 1-6, May 2004.

[18] P. A. Paul, C. M. Barrie , S. B. James , J. F. Neville , G. K. James , G. K. Philip.: “Design Principles for a flywheel Energy Store for Road Vehicles”, IEEE transactions on industry application, Vol. 32, No. 6, November/December 1996.

[19] C.C. Chan, K. T. Chu.: “An overview of power electronics in electrical vehicles”, IEEE transactions on Industrial Electronics, Vol. 44, NO. 11, February 1997.

[20] L. T. Lam, R. Louey.: “Development of ultra battery for hybrid electric vehicle applications”, Journal of power sources 158, pp. 1140-1148, May 2006.

[21] K. J. Dyke, A. Jarushi and N. Schofield.: “DESERVE DC-DC Power Converter Design”, Technology Strategy Board, Low Carbon Vehicles Innovation Platform, Project No. TP/9/LCV/6/I/S0037C, Nov. 2009.

[22] A. Emadi, S.S. Williamson, A. Khaligh.: “Power Electronics Intensive Solutions for advanced Electric, Hybrid Electric, and Fuel cell vehicular power systems”, IEEE Trans. Vol. 21, No. 3, May 2006.

[23] M. Ehsani.: “Modern electric, hybrid electric, and fuel cell vehicles: fundamentals, theory, and design”, Power electronics and applications series, ISBN: 9780849331541, 0849331544 (hbk.), Boca Raton, Fla. ; London : CRC

Page 161: ANALYSIS AND MODELLING OF ENERGY SOURCE …

161

Press 2005.

[24] J. M. Miller.: “Propulsion Systems for Hybrid Vehicles”, IEE, ISBN 0-86341-336-6, 2004.

[25] D. Sandeep.: “Electrical Vehicle Battery System”, Book, Butterworth-Heinemann, ISBN 0750699167, 2002.

[26] R. A. Sutula, K. L. Heitner.: “Electric and Hybrid Vehicle Energy Storage R&D program of the US department of energy”, Proceeding of 15th Electrical Vehicle Symposium, Brussels, September 29 –Oct 3 1998.

[27] H. W. Ernest.: “History of the Electric Automobile Hybrid Electric Vehicles”, SAE publication, ISBN 0-7680-0125-0, 1998.

[28] G. Maggette, Ir. Van Mierlo J.: “Electric and Electric Hybrid Vehicle Technology: survey”, Vrije University Brussels.

[29] H. W. Michael.: “The Electric Car, Development and Future of Battery, Hybrid and Fuel Cell Cars”, IEE Power and energy series 38, the institution of electrical engineers, London UK, 1999.

[30] J. V. Mierlo, G. Maggetto.: “Which Energy Source For Road Transport in The Future, A comparison of Battery Hybrid and Fuel Cell Vehicles”, Energy conversion and management 47, pp. 2748-2760, 2006.

[31] A. V. Zyl.: “Review of the zebra battery system development”, Solid State Ionics 86-88, pp. 883-889, 1996.

[32] J. Prakash, L. Redey, D. R. Vissers.: “Morphological consideration of the nickel chloride electrodes for zebra batteries”, Journal of Power Sources 84, pp. 63-69, 1999.

[33] http://www.geenergystorage.com, last accessed November 1st 2010.

[34] C. H. Dustmann.: “Advanced ZEBRA batteries”, Journal of power sources 127, pp. 85-92, 2004.

[35] J. L. Sudworth.: “Zebra batteries”, Journal of Power Sources 51, pp. 105-114, 1994.

[36] R. C. Galloway, S. Haslam.: “The ZEBRA electric vehicle battery: power and energy improvements”, Journal of Power Sources 80, pp. 164-170, 1999.

Page 162: ANALYSIS AND MODELLING OF ENERGY SOURCE …

162

[37] J. L. Sudworth.: “The sodium/nickel chloride (ZEBRA) battery”, Journal of Power Sources 100, pp. 149-163, 2001.

[38] Boham H., Beyermann G., “Zebra batteries enhanced power by doping”, journal of power sources, vol. 84, pp. 270-274, 1999.

[39] N. Schofield, H. T. Yap, C. M. Bingham.: “A H2 PEM Fuel Cell and High Energy Dense Battery Hybrid Energy Source for Urban Electric Vehicle”, pp. 1-6, 2007.

[40] C. H. Dustmann.: “ZEBRA battery meets USABC goals”, Journal of Power Sources 72, pp. 27-31, 1998.

[41] R.C. Galloway, C. H. Dustmann.: “ZEBRA battery- material cost availability and recycling”, EVS 20 , pp. 1-9, Long Beach, CA, November 2003.

[42] E. Karden, S. Ploumen, B. Fricke, T. Miller, K. Snyder.: “Energy storage devices for future hybrid electric vehicles”, Journal of Power Sources 169, pp. 2-11, 2007.

[43] J. Miller, R. Smith.: “Ultracapacitor Assisted Electric Drives for Transportation.”, Maxwell technologies, White Papers. 2004, www.maxwell.com.

[44] Burke A.: “Ultracapacitor; Why, and Where is the technology”, Journal of power sources 91, pp 37-50, 2000.

[45] K.T. Chau, Y.S. Wong.: “Overview of power management in hybrid electric Vehicles”, Energy Conversion and Management, Vol. 43, Issue 15, pp. 1953–1968, 2002.

[46] A.Rufer, P.Barrade.: ” A Supercapacitor-based Energy Storage System for Elevators with Soft Commutated Interface”, Industry Application Conference, Vol. 2, pp. 1413-1418, 2001.

[47] A. Schneuwly,R. Gallay.: “ Properties and applications of supercapacitors from the state-of-the-art to future trends”, pp.1-10, Proceeding PCIM 2000.

[48] www.csiro.com.au website.: “Supercapacitor for load-levelling in hybrid vehicles”, last accessed on 12-5-2008.

[49] Maxwell Technologies, Ultracapacitors, Product Datasheets, “www.maxwell.com”, last accessed on March 2008.

[50] Yukari Kibi, Takashi Ssito, Mitsuyoshi Kurata, Junji Tabuchi, Atsushi Ochi.: “Fabrication of high-power electric double-layer capacitors”, Journal of Power

Page 163: ANALYSIS AND MODELLING OF ENERGY SOURCE …

163

Sources Vol. 60, pp. 219-224, 1996.

[51] J.Gamby, P.L.Taberan, P.Simon ,J.F.Fauvarque, and M.Chesneau.: “Studies and characterizations of various activated carbons used for carbon/carbon supercapacitor”, Journal of Power Sources, Vol. 101 , pp. 109-116 , 2001.

[52] www.en.wikipedia.org:supercapacitors_chart.svg, last accessed 12th July 2009.

[53] Deyang Qu, Hang Shi.: “Studies of activated carbons used in double-layer capacitors”, Journal of Power Sources, Vol. 74, pp.99-107, 1998.

[54] Wendy G.Pell, Brian E. Conway.: ” Analysis of power limitations at porous supercapacitor electrodes under cyclic voltammetery modulation and dc charge”, Journal of Power Source, Vol. 96, pp. 57-67, 2001.

[55] J.V. Mierlo , G. Maggetto.: “Which Energy Source For Road Transport in The Future, A comparison of Battery Hybrid and Fuel Cell Vehicles”, Energy conversion and management 47, pp. 2748-2760, 2006

[56] Kalan B. A., Lovatt H.C., Brothers M. and Buriak V.: “System design and development of hybrid electric vehicles”. In proc. IEEE power Electronic spec. conf. Cairns, Australia, Vol. 2, pp. 768-772, June 2002.

[57] J. Jeong, L.H. KIM, C. CHI, H. CHO.: “A Development of an Energy Storage System for Hybrid Electric Vehicles Using Supercapacitor”, 19th Electric Vehicle Symposium, Busan, Korea, 2002.

[58] H.T. Yap, N. Schofield, and C.M. Bingham.: “Hybrid Energy/power sources for electric vehicle traction systems”, IEE PEMD Conference, pp. 1-6, May 2004.

[59] Mierlo J. V. , Bossche P. V. , Maggetto G.: “Models of Energy Sources for EV and HEV: fuel cells, batteries, ultracapacitor, flywheel and engine- generator”, Power Sources 128, pp. 76- 89, 2004

[60] Welchko B. A., Nagashima J. M.: “The influence of topology selection on the design of EV/HEV propulsion systems”, IEEE Power Electronics, Vol. 1, No. 2, pp. 36-40, January 2003.

[61] D. Mazaika, J. Schulte.: “Batteries vs Ultracapacitors in Hybrid Electric Buses”, 2nd Electric Vehicle Symposium, Monaco, 2005.

[62] Marie-Francoise J. N., Gualous H., Outbib R., Berthon A.: “42V Power Net with Supercapacitor and Battery for Automotive Application”, Journal of power sources 143, pp. 275-283, 2005.

Page 164: ANALYSIS AND MODELLING OF ENERGY SOURCE …

164

[63] Delprat S., Lauber J., Guerra T. M., and Rimaux J., “Control of a parallel hybrid power train optimal control”, IEEE Trans. Vehicles Technology, Vol. 53, pp. 872-881, May 2004.

[64] Leonardo B., Atsutoshi M., Keywan R.: “The Hydrogen Economy in the 21st Century: A sustainable Development Scenario”, Journal of hydrogen energy, March 2002.

[65] L. Xin and S. S. Williamson.: “Comparative Investigation of Series and Parallel Hybrid Electric Vehicle (HEV) Efficiencies Based on Comprehensive Parametric Analysis”, Vehicle Power and Propulsion Conference, VPPC’07, IEEE, pp. 499-505, 2007.

[66] G. Rizzoni, L. Guzzella, and B. M. Baumann.: “Unified modeling of hybrid electric vehicle drive-trains”, IEEE/ASME Transactions on Mechatronics, Vol. 4, pp. 246-257, 1999.

[67] A. Walker, A. McGordon, G. Hannis, A. Picarelli, J. Breddy, S. Carter, A.

Vinsome, P. Jennings, M. Dempsey, and M. Willows.: “A Novel Structure for Comprehensive HEV Powertrain Modelling”, Vehicle Power and Propulsion Conference, VPPC '06, IEEE, 2006.

[68] K. B. Wipke, M. R. Cuddy, and S. D. Burch.: “ADVISOR 2.1: a user-friendly

advanced power-train simulation using a combined backward/forward approach”, IEEE Transactions on Vehicular Technology, Vol. 48, pp. 1751-1761, 1999.

[69] L. Guzzella and A. Amstutz.: “CAE tools for quasi-static modelling and

optimization of hybrid power-trains”, IEEE Transactions on Vehicular Technology, Vol. 48, pp. 1762-1769, 1999.

[70] T. Markel, A. Brooker, T. Hendricks, V. Johnson, K. Kelly, B. Kramer, M.

O'Keefe, S. Sprik, and K. Wipke.: “ADVISOR: a systems analysis tool for advanced vehicle modelling”, Journal of Power Sources, Vol. 110, pp. 255-266, 2002.

[71] S. Onoda, A. Emadi.: “PSIM-based modeling of automotive power systems:

conventional, electric, and hybrid electric vehicles”, IEEE Transactions on Vehicular Technology, Vol. 53 Issue 2, pp. 390 – 400, ISSN: 0018-9545, March 2004.

[72] J. Hellgren.: "Modelling of Hybrid Electric Vehicle in Modelica for Virtual

Prototyping", International Modelica Conference, Oberpfaffenhofen, Germany: Modelica, 2002.

[73] D. Sutanto, H.L. Chan, and C.C. Fok.: “Battery Model for use in Electric

Vehicle and Battery Energy Storage System”, EPE’99, pp.1-10, Lausanne, 1999

[74] Glenn Elert, “Acceleration of a car”, website, last accessed on 1-7-2009.

Page 165: ANALYSIS AND MODELLING OF ENERGY SOURCE …

165

[75] R. I. Sims, J. C Carnes., M. A. Dezieciuch, and F. J. E..: “Computer Modelling of Automotive Lead Acid batteries”, SR-90-154, 25th September 1990.

[76] V. H. Johnson.: “Battery performance models in ADVISOR”, Journal of

Power Sources, Vol. 110, pp. 321-329, 2002.

[77] M. Markel, A. Brooker, T. Hendricks, V. Johnson, K. Kelly, B. Kramer, M. O'Keefe, S. Sprik, and K. Wipke.: “ADVISOR: a systems analysis tool for advanced vehicle modelling”, Journal of Power Sources, Vol. 110, pp. 255-266, 2002.

[78] J. P. Cun, J. N. Fiorina, M. Fraisse, and H. Mabboux.: “The experience of a

UPS company in advanced battery monitoring”, 18th International Telecommunications Energy Conference, INTELEC '96, 1996.

[79] I R. Giglioli and P. Cerolo.: “Charge and discharge fourth order dynamic model

of the lead battery”, 10th international Electric Vehicle Symposium, EVS10, Hong Kong, 1990.

[80] T. M. O'Sullivan, C. M. Bingham, and R. E. Clark.: “Zebra battery

technologies for all electric smart car”, International Symposium on Power Electronics, Electrical Drives, Automation and Motion, SPEEDAM’06, 2006.

[81] M. Y. Ayad, S. Rael, and B. Davat.: “Hybrid power source using

supercapacitors and batteries”, Proceeding of 10th European Conference on Power Electronics and Applications, EPE’03, 2003.

[82] N. Schofield, H. T. Yap.: “Hybrid Energy Sources for Electric Vehicle

Propulsion”, European Ele.-Drive Conference, EET‘07, Brussels, Belgium, May 30 – June 01, 2007.

[83] J. Chiasson and B. Vairamohan.: “Estimating the state of charge of a battery",

Proceedings of American Control Conference, pp. 1-6, 2003.

[84] J. Chiasson and B. Vairamohan.: “Estimating the state of charge of a battery”, IEEE Transactions on Control Systems Technology, Vol. 13, pp. 465-470, 2005.

[85] J. T. Economou.: “Intelligent Energy Source SoC Modelling for a Hybrid Electric Vehicle”, Proceedings of the IEEE International Symposium on Industrial Electronics, ISIE’05, pp. 1-6, 2005.

[86] J. Van Mierlo, P. Van den Bossche, and G. Maggetto.: “Models of energy

sources for EV and HEV: fuel cells, batteries, ultracapacitors, flywheels and engine-generators", Journal of Power Sources, Vol. 128, pp.76-89, 2004.

[87] H. Guo, J. Jiang, and Z. Wang.: “Estimating the State of Charge for Ni-MH

Battery in HEV by RBF Neural Network”, International Workshop on Intelligent Systems and Applications, ISA’09, pp. 1-6, 2009.

Page 166: ANALYSIS AND MODELLING OF ENERGY SOURCE …

166

[88] T. Bhattacharya, V. S. Giri, K. Mathew, and L. Umanand.: “Multiphase Bidirectional Flyback Converter Topology for Hybrid Electric Vehicles”, IEEE Transactions on Industrial Electronics, Vol. 56, pp. 78-84, 2009.

[89] O. Garcia, P. Zumel, A. de Castro, and A. Cobos.: “Automotive DC-DC

bidirectional converter made with many interleaved buck stages”, Power Electronics, IEEE Transactions on, Vol. 21, pp. 578-586, 2006.

[90] K. Hahnsang and K. G. Shin.: “Scheduling of Battery Charge, Discharge, and

Rest”, Real-Time Systems Symposium, RTSS’09, 30th IEEE, 2009.

[91] Mantovani, G., Nicora, F. and Manzoni, R.: “Pure electric buses fleet in Lyon: mission, battery, energy, maintenance”, 3rd European Ele-Drive Transportation Conference, EET’08, pp. 1-9, Geneva, Switzerland, March 11-13, 2008.

[92] M. Chin-Sien, N. Kong Soon, and H. Yao-Ching.: “Parallel Operation of

Battery Power Modules”, Energy Conversion, IEEE Transactions on, Vol. 23, pp. 701-707, 2008.

[93] B. Han-Sik, L. Jeong-Min, M. Hyung-Soo, and C. Gyu-Ha.: “Load sharing

improvement in parallel-operated lead acid batteries”, Industrial Electronics, Proceedings, ISIE’01, IEEE International Symposium on, 2001.

[94] R. Manzole, M. Metzger, G. Crugnola.: “ ZEBRA electric energy storage

system”, THE hi.tech.expo, Milan, 25-28 November 2008.

[95] J. Giancaterino.: “Application considerations for multiple battery disconnects”, 22nd International Telecommunications Energy Conference, INTELEC’00, 2000.

[96] J. N. Marie-Francoise, H. Gualous, R. Outbib, and A. Berthon.:“42 V Power

Net with supercapacitor and battery for automotive applications”, Journal of Power Sources, Vol. 143, pp. 275-283, 2005.

[97] H. Douglas and P. Pillay.: “Sizing ultracapacitors for hybrid electric vehicles,”

presented at Industrial Electronics Society, IECON 2005. 31st Annual Conference of IEEE, pp. 1-6, 6-10 November 2005.

[98] A. F. Burke.: “Prospects for ultracapacitors in electric and hybrid vehicles”,

11th Annual Battery Conference on Applications and Advanced, Ref. No. UCD-ITS-RP-96-03, pp. 1-6, Long Beach, CA, USA, January 1996.

[99] A. Farkas and R. Bonert.: “Ultracapacitors as Sole Energy Storage Devices in

Hybrid Electric Cars?”, Power Electronics in Transportation, pp. 97-101, 1994.

[100] E. J. Cegnar, H. L. Hess, and B. K.Johnson.: “A Purely Ultracapacitor Energy Storage System for Hybrid Electric Vehicles Utilizing a Microcontroller-Based DC-DC Boost Converter”, IEEE Applied Power Electronics Conference and Exposition, APEC ‘04, Vol. 2, pp.1160-1164, 2004.

[101] W. Lhomme, P. Delarue, P. Barrade, A. Bouscayrol, A. Rufer,: "Design and

Control of a supercapacitor storage system for traction applications," Industry

Page 167: ANALYSIS AND MODELLING OF ENERGY SOURCE …

167

Applications Conference, 2005. Fourtieth IAS Annual Meeting. Conference Record of the 2005 , vol.3, no., pp. 2013- 2020 Vol. 3, 2-6 Oct. 2005.

[102] W. Lhomme, Ph. Delarue, Ph. Barrade, A. Bouscayrol.: “Design and Control

of Suprcapacitor Storage System for Traction Applications”, Industry Applications Conference, IAC, Vol. 3, pp. 2013-2020, 2005.

[103] A. Bartsch, B. Braun, B. Schnyder, R. Kotz.: “Glassy carbon supercapacitor:

100,000 cycles demonstrated”, Proceedings of the 38th Power Sources Conference, pp.17-20, 8-11 June 1998.

[104] L. Bertoni, H. Gualous, D. Bouquain, D. Hissel, M. Pera, J. Kauffmann.:

“Hybrid auxiliary power unit (APU) for automotive applications”, Vehicular Technology Conference, VTC’02, IEEE 56th, Vol. 3, pp. 1840-1845, 2002.

[105] Simpson A. G., Walker G. R.: “Lifecycles Costs of Ultracapacitor in Electric

Vehicle Application”, Power Electronics Specialists Conference, IEEE33rd , pp. 1015-1020, Vol. 2, School of information technology and electrical engineering, University of Queensland, 2002.

[106] J. M. Miller, J.N.J. Miller, S. Richard.: “Ultracapacitor Assisted Electric

Drives for Transportation”, Maxwell Technologies white paper on www.maxwell.com. Last accessed on 20-9-2010.

[107] S. Jeon, J. Lee, S. Jeong, T. Lim.: “Hyundai Supercapacitor Fuel Cell Hybrid

Electric Vehicle”, 21st Electric Vehicle Symposium, EVS 21, pp.1-7, Monaco, 2005.

[108] S. Pay and Y. Baghzouz.: “Effectiveness of Battery-Supercapacitor

Combination in electric Vehicles”, IEEE Power Tech Conference Proceedings, pp.1-7, Bologna, Italy, 23-26 June 2003.

[109] S. Se, N. Freeman.: “Fuel Cells and Ultracapacitors in Light Mobility Applications”, 21st Electric Vehicle Symposium, pp. 1-6, Monaco, 2005.

[110] E. Ozatay, B. Zile, J. Anstrom, and S. Brennan.: “Power Distribution Control

Coordinating Ultracapacitors and Batteries for Electric Vehicles”, Proceedings of the American Control Conference, Vol. 5, pp. 4716- 4721, 2004.

[111] R. M. Schupbach and J. C. Balda.: “Comparing DC-DC Converters for Power

Management in Hybrid Electric Vehicles”, IEEE International Electric Machines and Drives Conference, IEMDC’03, Vol. 3, pp. 1369-1374, 2003.

[112] M. H. Todorovic, L. Palma, and P. Enjeti.: “Design of a wide input range DC-DC converter with a robust power control scheme suitable for fuel cell power conversion”, IEEE Applied Power Electronics Conference and Exposition, APEC ’04, Vol. 1, pp. 374-379, 2004.

Page 168: ANALYSIS AND MODELLING OF ENERGY SOURCE …

168

[113] A. Ohkawa.: “Electric Power Control System for a Fuel Cell Vehicle Employing Electric Double-Layer Capacitor”, SAE Technical Paper Series 2004-01-1006, 2004.

[114] B. Vural, A. R. Boynuegri, I. Nakir, O. Erdinc, A. Balikci, M. Uzunoglu, H. Gorgun, and S. Dusmez.: “Fuel cell and ultra-capacitor hybridization: A prototype test bench based analysis of different energy management strategies for vehicular applications”, International Journal of Hydrogen Energy, Vol. 35, pp. 11161-11171, October 2010.

[115] M. B. Camara, H. Gualous, F. Gustin, A. Berthon, and B. Dakyo.: “DC/DC Converter Design for Supercapacitor and Battery Power Management in Hybrid Vehicle Applications-Polynomial Control Strategy”, Industrial Electronics, IEEE Transactions, Vol. 57, Issue 2, pp. 587-597, 2010.

[116] J. Leuchter, P. Bauer, and A. F. Zobaa.: “Power electronics and energy management of hybrid power sources with Supercapacitors”, Power Electronics, Machines and Drives, PEMD 2010, 5th IET International Conference, 2010.

[117] J. W. Dixon, M. Ortuzar, E. Wiechmann.: “Regerative Braking for an Electric

Vehicle Using Ultracapacitors and Buck-Boost Converter”, Catholic University of Chile, Casilla 306, Correo 22, Santiago, Chile.

[118] C. C. Chan, Y. S. Wong.: “Electric Vehicle Charge Forward”, Power and

Energy Magazine IEEE, Vol.2, issue 6, pp. 24-33, 2004.

[119] J. Dixon, M. Ortuzar, E. Arcos, I. Nakashima.: “ZEBRA Plus Ultracapacitors: A good match for energy efficient EVs”, EVS21, pp. 1-6, Monaco, 2005.

[120] J. Dixon, I. Nakashima, E. F. Arcos, and M. Ortuzar.: “Electric Vehicle Using

a Combination of Ultracapacitors and ZEBRA Battery”, Industrial Electronics, IEEE Transactions, Vol. 57, Issue 3, pp. 943-949, 2010.

[121] K.T. Chau, Y.S. Wong.: “Overview of power management in hybrid electric

Vehicles”, Energy Conversion and Management, Vol. 43, Issue 15, pp. 1953–1968, 2002.

[122] A.Rufer, P.Barrade.: ” A Supercapacitor-based Energy Storage System for

Elevators with Soft Commutated Interface”, Industry Application Conference, Vol. 2, pp. 1413-1418, 2001.

[123] A. Schneuwly,R. Gallay.: “ Properties and applications of supercapacitors

from the state-of-the-art to future trends”, pp.1-10, Proceeding PCIM 2000.

[124] www.csiro.com.au website.: “Supercapacitor for load-levelling in hybrid vehicles”, last accessed on 12-5-2008.

[125] Maxwell Technologies, Ultracapacitors, Product Datasheets, US, 2006.

[126] Chunsheng D., Ning P.: “High power density supercapacitor electrodes of

Page 169: ANALYSIS AND MODELLING OF ENERGY SOURCE …

169

carbon nanotube films by electrophretic deposition”, Institute of physics publishing Nanotechnology 17, pp. 5314-5318, 2006.

[127] J.Gamby, P.L.Taberan, P.Simon ,J.F.Fauvarque, and M.Chesneau.: “Studies

and characterizations of various activated carbons used for carbon/carbon supercapacitor”, Journal of Power Sources, Vol. 101 , pp.109-116 , 2001.

[128] Deyang Qu, Hang Shi.: “Studies of activated carbons used in double-layer

capacitors”, Journal of Power Sources, Vol. 74, pp. 99-107, 1998.

[129] Wendy G.Pell, Brian E. Conway.: ” Analysis of power limitations at porous supercapacitor electrodes under cyclic voltammetery modulation and dc charge”, Journal of Power Source, Vol. 96, pp. 57-67, 2001.

[130] ] R. L. Spyker, R. M. Nelms.: ” Classical Equivalent Circuit Parameters for a

double layer capacitor”, IEEE transactions on aerospace and electronic systems, Vol.36, Issue 3. July 2000.

[131] M. Pagano and L. Piegari.: “Hybrid Electrochemical Power Sources for Onboard Applications,” Energy Conversion, IEEE Transactions, Vol. 22, pp. 450-456, 2007.

[132] B. Vural, M. Uzunoglu, O. Erdinc, and O. C. Onar.: “A dynamic ultracapacitor

model for vehicular applications”, International Conference on Clean Electrical Power, 2009.

[133]

F. Rafik, H. Gualous, R. Gallay, A. Crausaz, and A. Berthon.: “Frequency, thermal and voltage supercapacitor characterization and modelling”, Journal of Power Sources, Vol. 165, pp. 928-934, 2007.

[134] H. Gualous, D. Bouquain, A. Berthon, and J. M. Kauffmann.: “Experimental

study of supercapacitor serial resistance and capacitance variations with temperature” Journal of Power Sources, Vol. 123, pp. 86-93, 2003.

[135] J. M. Miller.: “Ultracapacitor Model Designed to simulate electrical and

thermal performance”, Maxwell Technologies Ultracapacitor Equivalent Circuit Model, www.maxwell.com, last accessed on March 2008.

[136] F. Rafik, H. Gualous, R. Gallay, A. Crausaz, and A. Berthon.:

“Supercapacitors characterization for hybrid vehicle applications”, Power Electronics and Motion Control Conference, IPEMC 2006, CES/IEEE 5th International, 2006.

[137] S. Buller, E. Karden, D. Kok, and R. W. De Doncker.: “Modeling the dynamic

behaviour of supercapacitors using impedance spectroscopy”, Industry Applications, IEEE Transactions, Vol. 38, pp. 1622-1626, 2002.

[138] B. A. Boukamp.: “A Nonlinear Least Squares Fit procedure for analysis of

immittance data of electrochemical systems”, Solid State Ionics, Vol. 20, Issue 1, pp. 31-44, 1986.

Page 170: ANALYSIS AND MODELLING OF ENERGY SOURCE …

170

[139] R. M. Nelms, D. R. Cahela, and B. J. Tatarchuk.: “Using a Debye polarization cell to predict double-layer capacitor performance”, Industry Applications, IEEE Transactions, Vol. 37, pp. 4-9, 2001.

[140] L. Zubieta and R. Bonert, “Characterization of double-layer capacitors for

power electronics applications,” Industry Applications, IEEE Transactions, Vol. 36, pp. 199-205, 2000.

[141] www.maxwell.com, last accessed on 12.9.2009

[142] Maxwell Technologies.: “Ultracapacitors Product Guide”, Manual guide,

www.maxwell.com, last accessed on 10.5.2010.

[143] J. M. Miller.: “Electrical and Thermal Performance of the Carbon-carbon Ultracapacitor Under Constant Power Conditions”, Vehicle Power and Propulsion Conference, VPPC 2007, IEEE, 2007.

[144] M. Steiner and J. Scholten.: “Energy Storage on board of DC fed railway

vehicles”, IEEE Power Electronics Specialist Conference, 2004.

[145] K.Dutton, S. Thompson, B. Barraclough.: “The Art of Control Engineering”, Wesley Longman, ISBN 0-0201-17545-2, England, 1997.

[146] F. Rafik, H. Gualous, R. Gallay, M. Karmous, and A. Berthon,.: “Contribution

to sizing of supercapacitors and their applications”, Maxwell Technologies, pp.1-6, CH-1728 Rossens, Switzerland.

[147] Liao G., Weber T., Pfaff D.: ‘Modelling and Analysis of Powertrain

Hybridization on All-Wheel-Drive Sport Utility Vehicle’. Proc. Instn Mech. Engrs, Vol. 218 Part D: J. Automobile Engineering 2004.

[148] E. Karden, S. Ploumen, B. Fricke, T. Miller, K. Snyder.: “Energy storage devices for future hybrid electric vehicles”, Journal of Power Sources 169, pp. 2-11, 2007.

[149] A. Al-Adsani, N. Schofield.: "Hybrid Permanent Magnet Generators for Electric Vehicle Applications", IEEE International Electric Machines and Drives Conference, IEMDC’09 , 3-6 May, Miami, USA, CD, ISBN: 978-1-4244-4252-2. 2009.

[150] A. Al-Adsani , A. Jarushi , N. Schofield.: "Operation of a Hybrid PM Generator in a Series Hybrid Electric Vehicle", The 35th Annual Conference of the IEEE Industrial Electronic Society , IECON 2009, Porto, Portugal 3-5 Nov. 2009.

[151] W. Zhancheng, L. Weimin, X. Yangsheng.: "A novel power control strategy of series hybrid electric vehicle", International Conference on Intelligent Robots and Systems, IROS’07. IEEE/RSJ , Vol. l, pp. 96-102, Oct. 29 -Nov. 2 2007.

Page 171: ANALYSIS AND MODELLING OF ENERGY SOURCE …

171

[152] C. Guijun, H. Bin, X. Liangfei, L. Jianqiu, O. Minggao.: "Systematic Fuel Reduction Strategies of Series Hybrid Transit Bus", IEEE International Conference on Control Applications, CCA’07, pp. 1376-1381, 1-3 Oct. 2007.

[153] M. Amirabadi, S. Farhangi.: "Fuzzy Control of Hybrid Fuel Cell / Battery Power Source in Electric Vehicle", IEEE Conference on Industrial Electronics and Applications, 1ST'06, pp.1-5, 24-26 May 2006.

[154] H. Bufu, S. Xi, X. Yangsheng.: "Parameter Optimization of Power Control Strategy for Series Hybrid Electric Vehicle", CEC IEEE Congress on Evolutionary Computation, pp. 1989-1994, 2006.

[155] D. Jianmin, M. Xu.: “Simulation research on hybrid energy storage of hybrid electric vehicle”, Proceeding of the 2010, International conference on automation and logistics, Hong Kong and Macau, 2010.

[156] www.lti.co.uk/tx4/technical-specification , last accessed 15th of June 2010.

[157] www.VCAfueldata.org.uk , last accessed on 20th of January 2010.