march 25, 2010: unc report of chemical odor in septic tank · for offsite disposal. once these...
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The University of North Carolina at Chapel HillUNC Department of Environment Health amp Safety EJVRf)Nv1ENI I 120 Estes Drive Ext CB 1650 HFlTH amp S1fETY Cl~ Hill North Carolina7599-1650
March 25 2010
Matthew Fleahman DENR Division ofWater Quality Raleigh Regional Office 1628 Mail Service Center Raleigh NC 27699-1628
Subject Unusual Odor in Septic Tank The University of North Carolina at Chapel Hill (UNC) Bingham Facility (former Research Resource Facility)
Dear Mr Fleahman
I am writing in follow-up to your telephone conversation with Larry Daw on March 17 2010 regarding an unusual odor in the septic tank at the subject facility
On March 1 20 I 0 operators at the Bingham Facility detected an unusual odor emanating from the septic tank of the permitted wastewater treatment system EHS personnel were notified the next day (March 2 2010) and began investigating with the operators to determine the source of the odor The odor was strong in both the septic tank and the nearest wet well and the odor registered at levels up to 30 parts per million on a photoionization detector (PID) On-site methods used to determine the chemical composition of the odor were inconclusive
That same day EHS personnel and the wastewater treatment system operators investigated sewer cleanouts from both Bingham I ( older building) and Bingham 2 and they detected no odor or elevated PID readings Additionally EHS personnel and the facility operators visually inspected Bingham I and 2 and interviewed employees at the facility in an attempt to discover the source of the odor however nothing conclusive was identified
EHS personnel and facility operators also inspected Bingham 3 which is under construction as well as two manholes outside of Bingham 3 EHS personnel and facility operators determined that the manholes and visible piping were dry The construction activities at Bingham 3 have involved installation ofpropylene glycol into the cooling system installation of epoxy flooring and finishing activities
The Bingham Facility is currently operating under a DENR Division of Water Quality (DWQ) Pump and Haul Permit (Permit No WQ0034607) Under the Pump and Haul Permit wastewater from the Bingham Facility is collected within the animal wastewater treatment plant and transported to the Orange Water and Sewer Authority (OWASA) Wastewater Treatment Plant located in Chapel Hill North Carolina Upon becoming aware of the odor from the septic system EHS personnel ceased all pump and haul operations as of March 2 2010 There is adequate storage capacity on-site to collect and retain the wastewater
The University of North Carolina at Chapel HillUNC Department of Environment Health amp Safety lNv IR( )N rvllmiddot0middot1 1120 Estes Drive Ext CB 1650 l-11lTlmiddotI laquo 1f Y 9lgtJel Hill North Carolina_~]599l5c0_____
On March 2 2010 UNCs consultant McKim amp Creed (MampC) collected a water sample from the domestic wastewater system at the septic tank effulent pump station (referred to in the chain-of-custody documents as the post septic tank) EHS personnel requested expedited processing of these results (Attachment 1) which EHS received on the afternoon of March 4 2010 These results showed the presence of toluene and ethylene glycol
Following receipt of these results UNC and MampC determined that additional sampling would be conducted at the equalization basin of the animal wastewater system (referred to in the chain-of-custody documents as the Capetown system) in order to gain additional information regarding the constituents of concern (CoC) and to provide OW ASA with further data about the wastewater to be sent to OWASA This additional sampling was conducted on March 5 2010 UNC also requested expedited processing of these results (Attachment 2) and received them late on Tuesday March 9 2010 The delay in receipt of these results was due to analytical equipment problems at the laboratory
Upon review of the March 5 2010 sampling results UNC and MampC determined that further resampling was necessary because acetone was present in the samples and because UNC and MampC believed that the presence of acetone was a laboratory artifact To confirm that the acetone was a laboratory artifact UNC sent a part of the March 5 2010 sample to SGS North America Inc for analysis (Attachment 3)
On March 11 2010 MampC collected two samples from the equalization basin of the animal wastewater system and a composite sample of the septic tank Each sample was split and one part was sent to EnviroChem for analysis while the second part was sent to SGS for analysis in order to ensure the accuracy of the results UNC requested expedited processing of these results which UNC received on March 15 2010 (Attachment 4)
The main CoC identified in all of the samples included toluene ethylene glycol and propylene glycol which are components of the materials being utilized in the construction site of Building 3 Additionally these chemicals are not commonly used at the Bingham Facility Consequently UNC believes that the construction materials were the likely source of the CoCs The main construction activities have been completed and the floor drains have been covered to reduce the likelihood of a recurrence
On March 16 2010 UNC contacted Damon Forney the Operations Manager at OWASA to supply him with analytical data from the samples collected to date (including an analysis of samples (Attachment 5) taken on February 18-19 2010 which were collected to initiate UNCs evaluation of the wastewater treatment system) and to inquire whether OWASA could continue to accept the wastewater The following day OWASA stated that it could not receive the wastewater because of the concentration of toluene present in the wastewater
UNC has contracted with Clean Harbors to dispose of the wastewater and to determine how to clean out the wastewater system The current plan is to flushclean the wastewater piping from Building 3 remove contaminated water store it on-site in frac tanks and clean the septic tank
The University of North Carolina at Chapel Hill Department of Environment Health amp Safety
l1-VlltONvLNl 1120 Estes Drive Ext CB 1650 lmiddotllbullilll-1 ltmiddot lmiddotFTY
Chapel Hill North Carolina 27_~22bulllc650-----------
and basins in the wastewater system Clean Harbors initiated this process on Monday March 22 2010
Following containerization of the contaminated wastewater the material will be characterized for offsite disposal Once these activities are completed UNC plans to resume normal pump and haul activities
Please contact me if you have any questions or comments
Sincerely
~~~~ Mary Beth Koza Director - Environment Health amp Safety
Attachment 1
6602 Windmill Way Wifmington NC 28405ENVIRONMENTAL CHEMISTS INC OFFCE 910-392-0223 FAX 910-392-4t24
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Analytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT vle-k-bull~ f Cr_J ___f- ( PROJECTNAME Uk__ -J1- REPORTNO o -tt~~
ADDRESS_______________CONTACTNAME K_~ f-tv- f E bull PONO _____________
__________________REPORTTO______________ PHONEIFAX___________
COPYTO______________~E-MAIL
Sampled By fYgt~_ pound~r bull t- SAMPLE TYPE I= Influent E Effluent W =Well ST= Stream SO = Soil SL = Sludge Other - 1 Collection
Sample Identification
Date Time Temp
i)0 LS t_ (J -t_ ~ llflt bull (--t-
CI~bull f(I- )
H ~ +1-
I te~ ~
Ii ~ amp ~ t E 0
C G
C
G C
G C
G
C
G C
G C G C
G C
G C
G
~ ~ 1 ~50 EJS ClS ~ E
- p
G p
G p
G p
G p
G p
G p
G p
G p
G p
G
0 a_w lt( _ il
PRESERVATION
~ Ia IgI8 I5 I2 zCNzocc
i r z I-
_
I-
ffi ANALYSIS REQUESTED
5
Jl-l or to -lo--~~
94=1 )01 s-)
NOTl~E - DECHLORINATION Sam~es for Ammonia ~N Cyanide Phe~I and Bacteria must be dechlorinated (02 ppm or less) In the field at the time of collectlon_ See revese for l~ns
OatefTimeTransfer I Relinquished By I DateTime I Received By
1 _2
Temperature when Received gtmiddotLPlt--- Accepted tL Rejected0 Resample Requested ________
Delivered By ~ Received By -frac14 amp-- Date 312-zlaquon Time l t su Comments z 9 t 0 -s -fr vlt--1 71
3eigt C4 TURNAROUND s ( ~ o rcent I ~A
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
The University of North Carolina at Chapel HillUNC Department of Environment Health amp Safety lNv IR( )N rvllmiddot0middot1 1120 Estes Drive Ext CB 1650 l-11lTlmiddotI laquo 1f Y 9lgtJel Hill North Carolina_~]599l5c0_____
On March 2 2010 UNCs consultant McKim amp Creed (MampC) collected a water sample from the domestic wastewater system at the septic tank effulent pump station (referred to in the chain-of-custody documents as the post septic tank) EHS personnel requested expedited processing of these results (Attachment 1) which EHS received on the afternoon of March 4 2010 These results showed the presence of toluene and ethylene glycol
Following receipt of these results UNC and MampC determined that additional sampling would be conducted at the equalization basin of the animal wastewater system (referred to in the chain-of-custody documents as the Capetown system) in order to gain additional information regarding the constituents of concern (CoC) and to provide OW ASA with further data about the wastewater to be sent to OWASA This additional sampling was conducted on March 5 2010 UNC also requested expedited processing of these results (Attachment 2) and received them late on Tuesday March 9 2010 The delay in receipt of these results was due to analytical equipment problems at the laboratory
Upon review of the March 5 2010 sampling results UNC and MampC determined that further resampling was necessary because acetone was present in the samples and because UNC and MampC believed that the presence of acetone was a laboratory artifact To confirm that the acetone was a laboratory artifact UNC sent a part of the March 5 2010 sample to SGS North America Inc for analysis (Attachment 3)
On March 11 2010 MampC collected two samples from the equalization basin of the animal wastewater system and a composite sample of the septic tank Each sample was split and one part was sent to EnviroChem for analysis while the second part was sent to SGS for analysis in order to ensure the accuracy of the results UNC requested expedited processing of these results which UNC received on March 15 2010 (Attachment 4)
The main CoC identified in all of the samples included toluene ethylene glycol and propylene glycol which are components of the materials being utilized in the construction site of Building 3 Additionally these chemicals are not commonly used at the Bingham Facility Consequently UNC believes that the construction materials were the likely source of the CoCs The main construction activities have been completed and the floor drains have been covered to reduce the likelihood of a recurrence
On March 16 2010 UNC contacted Damon Forney the Operations Manager at OWASA to supply him with analytical data from the samples collected to date (including an analysis of samples (Attachment 5) taken on February 18-19 2010 which were collected to initiate UNCs evaluation of the wastewater treatment system) and to inquire whether OWASA could continue to accept the wastewater The following day OWASA stated that it could not receive the wastewater because of the concentration of toluene present in the wastewater
UNC has contracted with Clean Harbors to dispose of the wastewater and to determine how to clean out the wastewater system The current plan is to flushclean the wastewater piping from Building 3 remove contaminated water store it on-site in frac tanks and clean the septic tank
The University of North Carolina at Chapel Hill Department of Environment Health amp Safety
l1-VlltONvLNl 1120 Estes Drive Ext CB 1650 lmiddotllbullilll-1 ltmiddot lmiddotFTY
Chapel Hill North Carolina 27_~22bulllc650-----------
and basins in the wastewater system Clean Harbors initiated this process on Monday March 22 2010
Following containerization of the contaminated wastewater the material will be characterized for offsite disposal Once these activities are completed UNC plans to resume normal pump and haul activities
Please contact me if you have any questions or comments
Sincerely
~~~~ Mary Beth Koza Director - Environment Health amp Safety
Attachment 1
6602 Windmill Way Wifmington NC 28405ENVIRONMENTAL CHEMISTS INC OFFCE 910-392-0223 FAX 910-392-4t24
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Analytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT vle-k-bull~ f Cr_J ___f- ( PROJECTNAME Uk__ -J1- REPORTNO o -tt~~
ADDRESS_______________CONTACTNAME K_~ f-tv- f E bull PONO _____________
__________________REPORTTO______________ PHONEIFAX___________
COPYTO______________~E-MAIL
Sampled By fYgt~_ pound~r bull t- SAMPLE TYPE I= Influent E Effluent W =Well ST= Stream SO = Soil SL = Sludge Other - 1 Collection
Sample Identification
Date Time Temp
i)0 LS t_ (J -t_ ~ llflt bull (--t-
CI~bull f(I- )
H ~ +1-
I te~ ~
Ii ~ amp ~ t E 0
C G
C
G C
G C
G
C
G C
G C G C
G C
G C
G
~ ~ 1 ~50 EJS ClS ~ E
- p
G p
G p
G p
G p
G p
G p
G p
G p
G p
G
0 a_w lt( _ il
PRESERVATION
~ Ia IgI8 I5 I2 zCNzocc
i r z I-
_
I-
ffi ANALYSIS REQUESTED
5
Jl-l or to -lo--~~
94=1 )01 s-)
NOTl~E - DECHLORINATION Sam~es for Ammonia ~N Cyanide Phe~I and Bacteria must be dechlorinated (02 ppm or less) In the field at the time of collectlon_ See revese for l~ns
OatefTimeTransfer I Relinquished By I DateTime I Received By
1 _2
Temperature when Received gtmiddotLPlt--- Accepted tL Rejected0 Resample Requested ________
Delivered By ~ Received By -frac14 amp-- Date 312-zlaquon Time l t su Comments z 9 t 0 -s -fr vlt--1 71
3eigt C4 TURNAROUND s ( ~ o rcent I ~A
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
The University of North Carolina at Chapel Hill Department of Environment Health amp Safety
l1-VlltONvLNl 1120 Estes Drive Ext CB 1650 lmiddotllbullilll-1 ltmiddot lmiddotFTY
Chapel Hill North Carolina 27_~22bulllc650-----------
and basins in the wastewater system Clean Harbors initiated this process on Monday March 22 2010
Following containerization of the contaminated wastewater the material will be characterized for offsite disposal Once these activities are completed UNC plans to resume normal pump and haul activities
Please contact me if you have any questions or comments
Sincerely
~~~~ Mary Beth Koza Director - Environment Health amp Safety
Attachment 1
6602 Windmill Way Wifmington NC 28405ENVIRONMENTAL CHEMISTS INC OFFCE 910-392-0223 FAX 910-392-4t24
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Analytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT vle-k-bull~ f Cr_J ___f- ( PROJECTNAME Uk__ -J1- REPORTNO o -tt~~
ADDRESS_______________CONTACTNAME K_~ f-tv- f E bull PONO _____________
__________________REPORTTO______________ PHONEIFAX___________
COPYTO______________~E-MAIL
Sampled By fYgt~_ pound~r bull t- SAMPLE TYPE I= Influent E Effluent W =Well ST= Stream SO = Soil SL = Sludge Other - 1 Collection
Sample Identification
Date Time Temp
i)0 LS t_ (J -t_ ~ llflt bull (--t-
CI~bull f(I- )
H ~ +1-
I te~ ~
Ii ~ amp ~ t E 0
C G
C
G C
G C
G
C
G C
G C G C
G C
G C
G
~ ~ 1 ~50 EJS ClS ~ E
- p
G p
G p
G p
G p
G p
G p
G p
G p
G p
G
0 a_w lt( _ il
PRESERVATION
~ Ia IgI8 I5 I2 zCNzocc
i r z I-
_
I-
ffi ANALYSIS REQUESTED
5
Jl-l or to -lo--~~
94=1 )01 s-)
NOTl~E - DECHLORINATION Sam~es for Ammonia ~N Cyanide Phe~I and Bacteria must be dechlorinated (02 ppm or less) In the field at the time of collectlon_ See revese for l~ns
OatefTimeTransfer I Relinquished By I DateTime I Received By
1 _2
Temperature when Received gtmiddotLPlt--- Accepted tL Rejected0 Resample Requested ________
Delivered By ~ Received By -frac14 amp-- Date 312-zlaquon Time l t su Comments z 9 t 0 -s -fr vlt--1 71
3eigt C4 TURNAROUND s ( ~ o rcent I ~A
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Attachment 1
6602 Windmill Way Wifmington NC 28405ENVIRONMENTAL CHEMISTS INC OFFCE 910-392-0223 FAX 910-392-4t24
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Analytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT vle-k-bull~ f Cr_J ___f- ( PROJECTNAME Uk__ -J1- REPORTNO o -tt~~
ADDRESS_______________CONTACTNAME K_~ f-tv- f E bull PONO _____________
__________________REPORTTO______________ PHONEIFAX___________
COPYTO______________~E-MAIL
Sampled By fYgt~_ pound~r bull t- SAMPLE TYPE I= Influent E Effluent W =Well ST= Stream SO = Soil SL = Sludge Other - 1 Collection
Sample Identification
Date Time Temp
i)0 LS t_ (J -t_ ~ llflt bull (--t-
CI~bull f(I- )
H ~ +1-
I te~ ~
Ii ~ amp ~ t E 0
C G
C
G C
G C
G
C
G C
G C G C
G C
G C
G
~ ~ 1 ~50 EJS ClS ~ E
- p
G p
G p
G p
G p
G p
G p
G p
G p
G p
G
0 a_w lt( _ il
PRESERVATION
~ Ia IgI8 I5 I2 zCNzocc
i r z I-
_
I-
ffi ANALYSIS REQUESTED
5
Jl-l or to -lo--~~
94=1 )01 s-)
NOTl~E - DECHLORINATION Sam~es for Ammonia ~N Cyanide Phe~I and Bacteria must be dechlorinated (02 ppm or less) In the field at the time of collectlon_ See revese for l~ns
OatefTimeTransfer I Relinquished By I DateTime I Received By
1 _2
Temperature when Received gtmiddotLPlt--- Accepted tL Rejected0 Resample Requested ________
Delivered By ~ Received By -frac14 amp-- Date 312-zlaquon Time l t su Comments z 9 t 0 -s -fr vlt--1 71
3eigt C4 TURNAROUND s ( ~ o rcent I ~A
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
6602 Windmill Way Wifmington NC 28405ENVIRONMENTAL CHEMISTS INC OFFCE 910-392-0223 FAX 910-392-4t24
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Analytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT vle-k-bull~ f Cr_J ___f- ( PROJECTNAME Uk__ -J1- REPORTNO o -tt~~
ADDRESS_______________CONTACTNAME K_~ f-tv- f E bull PONO _____________
__________________REPORTTO______________ PHONEIFAX___________
COPYTO______________~E-MAIL
Sampled By fYgt~_ pound~r bull t- SAMPLE TYPE I= Influent E Effluent W =Well ST= Stream SO = Soil SL = Sludge Other - 1 Collection
Sample Identification
Date Time Temp
i)0 LS t_ (J -t_ ~ llflt bull (--t-
CI~bull f(I- )
H ~ +1-
I te~ ~
Ii ~ amp ~ t E 0
C G
C
G C
G C
G
C
G C
G C G C
G C
G C
G
~ ~ 1 ~50 EJS ClS ~ E
- p
G p
G p
G p
G p
G p
G p
G p
G p
G p
G
0 a_w lt( _ il
PRESERVATION
~ Ia IgI8 I5 I2 zCNzocc
i r z I-
_
I-
ffi ANALYSIS REQUESTED
5
Jl-l or to -lo--~~
94=1 )01 s-)
NOTl~E - DECHLORINATION Sam~es for Ammonia ~N Cyanide Phe~I and Bacteria must be dechlorinated (02 ppm or less) In the field at the time of collectlon_ See revese for l~ns
OatefTimeTransfer I Relinquished By I DateTime I Received By
1 _2
Temperature when Received gtmiddotLPlt--- Accepted tL Rejected0 Resample Requested ________
Delivered By ~ Received By -frac14 amp-- Date 312-zlaquon Time l t su Comments z 9 t 0 -s -fr vlt--1 71
3eigt C4 TURNAROUND s ( ~ o rcent I ~A
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
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C p Cc -f7 wl
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NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
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C p
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G G
C p
G G C p
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G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 3 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-1978
REPORT OF ANALYSIS
Date Sampled 030210 Project UNC - Bingham
Sampled By Jay Baker ( Envirochern)
WASTEWATERmiddot Paget of4 SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655 Benzene lt2 Bromobenzene lt2 Bromochloromethane lt2 Bromodichloromethane lt2 Bromoform lt2 Bromomethane lt2 n-Butylbenzene lt2 Sec-Butvlbenzene lt2 Tert-Butylbenzene lt2 Carbon Tetrachloride lt2 Chlorobenzene lt2 Chloroethane lt2 2-Chloroethyl vinyl ether lt2 Chloroform lt2 Chloromethane lt2 2-Chlorotoluene lt2 4-Chlorotoluene lt2 Dibromochloromethane lt2 12-Dibromo-3-chloronropane lt2 Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed Report l 0-l 97 8 Page 2 of 4
WASTEWATERmiddot SW 846 METHOD 8260B Domestic Waste (Post Septic)
Analyte microgL 4655
Dibromomethane lt2 I 2-Dibromoethane (EDB) lt2
12-Dichlorobenzene lt2
13-Dicblorobenzene lt2
14-Dichlorobenzene lt2
11-Dichloroetbane lt2
11-Dichloroethene lt2
l 2-Dichloroethane lt2
cis-12-Dichloroethene lt2
T rans-12-Dichloroethene lt2
12-Dichloropropane lt2
l 3-Dichloropropane lt2
22-Dichloropropane lt2
11-Dichloropropene lt2
cis-13-Dichloropropene lt2
trans-13-Dichloropropene lt2
lt2Dichlorodifiuoromethane
Ethylbenzene lt2
lt2Hexachlorobutadiene
lsopropylbenzene lt2
P-Isopropyltoluene lt2
Methylene Chloride lt2
123-Trichlorobenzene lt2
124-Trichlorobenzene lt2
Trichloroethene lt2
Naphthalene lt2
n-Propylbenzene lt2
Styrene lt2
II I 2-Tetrachloroethane lt2
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
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1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report to-t 978 Page 3 of 4
WASTEWATERmiddot METHOD8260 domestic Waste (Post Septic)
4655Analyte microwJ Il 22-Tetrachloroethane lt2
Tetrachloroethene lt2
Toluene 328
l t 1-Trichloroethane lt2
11 2-Trichloroethane lt2
Trichlorofluoromethane lt2
123-Trichloropropane lt2
124-Trimethylbenzene lt2
135-Trimethylbenzene lt2
Vinyl Chloride lt2
M+PXylene lt4
O-Xylene lt2
IPE lt2
MTBE lt2
Acetone lt 10
MEK ltlO
ltJO
2-Hexanone
MIBK
lt2
Ethanol lt2
Vinyl Acetate lt2
Date Analyzed 030310
SW 846 METHOD 8015 Domestic Wate (Post Septic) 4655Analyte mgL
Ethylene Glycol 270
Date Analyred 030310
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
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Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
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z ~ ~ ~
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0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
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NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmh1gton NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsert6wn Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1978 Page 4 of 4
Domestic Waste (Post Septic) 4655 Results ofLibrary Search Compouflds for 625
Match Result Number Compound CAS
Probability microgL
1 Propanaf 123-38-6 7882 8050
2 Acetic Aldehyde 75-07-0 7455 752
3 1-propanol 71-23-8 9391 1152
4
5
6
7
8
9
11
12
Comment
Tentatively Identified Compound (Tlq refers to substances which are not present in the list of target compounds Therefore not all TCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search ofelectron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and qnantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
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T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
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G G
C p
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G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
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O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
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Date Time Temo ltJ - z X X z 0
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NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
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G G C p
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G G C p
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G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Attachment 2
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
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lt n JAJr~~q~h on _0_$~
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G G X C p
G G II C p
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I ANALYSIS REQUESTED
GJ4 [pJsI
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NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
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iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Analytical amp Consulting Chemists
6602 Windmlll Way Wilmington NC 28405 ENVIRONMENTAL CHEMISTS INC OFFICE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3n29
COLLECTION AND CHAIN OF CUSTODY
CLIENT MJltin i- CreeJ PROJECT NAME U(L - (h1Vivuri foe 11i ry REPORT NO 0 - d I10 ADDRESS_____________CONTACTNAME__________f__ PO NO ___________
________________REPORTTO_____________PHONEIFAX__________
COPY TO~----- -middot ___E-MAILmiddot
Sampled By a(V J~etl SAMPLE TYPE I = Influent E = Effluent W = Well ST= Stream SO= Soll SL = Sludge Other
Collection
Sample Identification
Date I Time Temp
~ bull () 1 I3-os-o IDso c1Za-ttJt1_Da~ lo)middot ~
ot 7 amp8 ~
lt n JAJr~~q~h on _0_$~
~-6Sio Ior-lt
T
0001 eqt I
tltJ vJ L bull Ba~ ~ 3-cG-ID I Joio
itE~Jl
11 ~ _ bull PRESERVATION deg c 5ltgt 5-J Qwamp~ 55 aa m w ~ a 8 r 0 E (J Sa C E 5=gt ~ 0 ti) z ~ Xg u- u z z r x c ~
C p
~ ~ 4956
C p
G G C p
G G
C p
G G 49pound1
C p
~ $-C p
G G
C p
~ G frac1295J I)( C p
G G X C p
G G II C p
G G
I ANALYSIS REQUESTED
GJ4 [pJsI
-eslh~ Jl)wl oj~hi
ampJ4 4d5-7
e~ 57ul ~ ~iJ gthi~
ib)_ 1sS 1J5 )lt
CoO To1o 111 1ura J flrltCr ltdeg-
NOTICE__DECHLORINATION SamJ)les for Ammonlt_TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the field at the time of collection See reverse for Instructions
Transfer I Relinquished By I DateTime I Received By OatefTime
1 2 7(ltt~+fTemperature when1Recelved ~-2 deg Accepted __- Resample Requested DellveredBy4C-- OWJY Received~ ~J(XA J2---ltgt Date3-dS-1O Time ZJ3aComments___________________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
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C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
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G G ()-
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-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
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G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (90) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTlFICAfE 94 DLS CEfUIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 9 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2110
REPORT OF ANALYSIS
Date Sampled 030510 Project UNC-Bingham Facility
Sampled By Zach Owen ( Envirochem)
EOUALIZATION BASIN Pae 1 of6
Equalization Basin Equalization Basin EPA Method 624 (Duplicate)
4950 4951
Benzene
Analyte microgL lt40lt40 lt40lt40Bromodichloromethane
Bromoform lt40lt40 Bromometbane lt40 lt40 Carbon Tetrachloride lt40lt40
Chlorobenzene lt40 lt40 Chloroetbane lt40 lt40 2-Chloroethylvinyl ether lt40lt40 Chloroform lt40lt40 Chloromethane lt40lt40 Dibromocblorometbane lt40lt40 12-Dicblorobenzene lt40 lt40 13-Dicblorobenzene lt40 lt40 14-Dicblorobenzene lt40lt40 11-Dicbloroethane lt40lt40 12-Dichloroetbane lt40 lt40 1lcDicbloroethenc lt40 lt40 Trans-12-Dicbloroetbene lt40 lt40 12-Dichlorooropane lt40 lt40 Cis-13-Dicbloroprooene lt40 lt40 Trans-13-Dicbloroorooenc lt40lt40
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
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(C) G C
G C
G IC)
G C
G
C
G
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C
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(G) p
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0 X
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ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
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NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
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Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
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1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab bull (910) 392-4424 (Fax
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 1lt4 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 2 of6
EQUALIZATION BASINmiddot Equalization Basin
Equalization Basin EPA Method 624 (Duplicate)4950
4951
lt40
Analyte microgL
lt40
Methylene Chloride
Ethyl benzene lt40
1122-Tetracbloroethane
lt40
lt40 lt40
lt40lt40Tetrachloroethene 158
111-Trlchloroetbane
148Toluene lt40
112-Trichloroethane
lt40
lt40 lt40
Trlchloroethene lt40
Trichlorot1uoromethane
lt40
lt40
Vinyl Chloride
lt40
lt40 lt40
M+PXylene lt80 lt80
0-Xylene lt40 lt40
MTBE lt40 lt40
Acetone 656 532
030610Date Analyzed
Comments
Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQCERTJFICATE 94 DLS CER11FICATE 37729 -=c_middot------------middotmiddotmiddot-middotmiddot--middot-------middot--=--==-=--middot=-middot==---=middot--middot==middot=====middotmiddotmiddotmiddotmiddot=middotmiddotmiddotc
Customer McKim amp Creed Report 10-2110 Page 3 of6
EOUALIZATION BASIN
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Acenaphthvlene lt50 lt50 Anthracene lt50 lt50 Benzo(a)anthracene lt50 lt50 Benzo(a)pyrene lt50 lt50 Benzo(b)fluoranthene lt50 lt50 Benzo(ghi)perylene lt50 lt50 Benzo(k)fluoranthene lt50 lt50 Bis(2-Chloroethoxy)methane lt50 lt50 Bis(2-Chloroethyl)ether lt50 lt50 Bis(2-Chloroisopropyl)ether lt50 lt50 Bis(2-ethylhexyl)phthalate lt50 lt50 4-bromophenyl phenyl ether lt50 lt50 Butylbenzylpbthalate lt50 lt50 2-Chloronaphthalene lt50 lt50 4-Cbloronhenyl phenyl ether lt50 lt50 Chrysene lt50 lt50 Di-n-Butylphthalate 291 515 Di-n-octylphthalate lt50 lt50 Dibenzo(ah)anthracene lt50 lt50 12-Dichlorobenzene lt50 lt50 13-Dichlorobenzene lt50 lt50 14-Dichlorobenzene lt50 lt50 33-Dichlorobenzidine lt50 lt50 Diethylphthalate lt50 lt50 Dimethylphthalate lt 50 lt 50 24-Dinitrotoluene lt50 lt50 26-Dinitrotoluene lt50 lt50 Fluoranthene lt50 lt50 Fluorene lt50 lt50 Hexacblorobenzene lt50 lt 50 Hexachlorobutadiene lt50 lt50 Hexachlorocyclopentadiene lt50 lt50
Comments
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
ANALYTICAL amp CONSULTING CHEMISTS
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
NCDENR DWQ CERTIFICATE 94 DlS CERTIFICATE 37729
Customer McKim amp Creed
EQUALIZATION BASINmiddot
Report 10-2110 Page 4 of6
EPA Method 625 Analyte microgL
Equalization Basin 4950
Equalization Basin (Duplicate)
4951
Hexachloroethane lt50 lt50 Indeno(l23-cd)pyrene lt50 lt50
lsophorone lt50 lt50 Naphthalene lt50 lt50
Nitrobenzene lt50 lt50 N-Nitrosodi-n-propylamine lt50 lt50 Phenanthrene lt50 lt50 Pyrene
lt50 lt50 124-Trichlorobenzene lt50 lt50
Ackl Extractable middot middot middot _ middotmiddot bull middotmiddot _-c bull
4-Chloro-3-methylphenol lt50 lt50 2-Chlorophenol lt50 lt50 24-Dichlorophenol lt50 lt50 24-Dimethylphenol lt50 lt50 24-Dinitrophenol lt50 lt50 2-Methyl-46-dinitrophenol lt 50 lt 50 2-Nitrophenol lt50 lt50 4-Nitrophenol lt50 lt50 Pentachlorophenol lt50 lt50 Phenol lt50 lt50 246-Trichlorophenol lt50 lt50 4-Methylphenol 353 818
Date Extracted middot 030510 Date Analyzed 030810
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110
4950 Results ofLibrary Search Compounds for 625 Match
Number Compound CAS Probability
l Cholesterol 57-88-5 889
2 Dicyclohexyl Phthalate 84-61-7 913
3 N-Hexadecanoic Acid 57-10-3 845
4 N-Nonylphenol 25154-52-3 815
5 NN-Dimcthyl-lDodccaneaminc 112-18-5 842
6 56-Dihydro-246-Triethyl-4H-13S-Dithiazine
54717-17-8 906
7 Cis-35-Diethyl-124-Trithiolane 38348-26-4 833
8 Trans-35-Diethyl-124-Trithiolane 38348-26-4 839
9 lndolc 120-72-9 944
10 P-Cresol 106-44-5 875
11
12
Comment
Tentatively Identified Compound (TIC) refers to substances which are uot preseut in the list of target compounds Therefore not all TI Cs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Page 5 of6
Result microgL
100
174
61
94
101
99
112
127
57
354
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DIS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2110 Page 6 of6
4951 Results ofLibrary Search Compoundsfor625
Number Compound
I Cholesterol
2 Dicyclohexyl Phthalate
3 N-Hexadecanoic Acid
4 N-Nonylphenol
5 NN-Dimethyl-lDodecaneamine
6 56-Dihydro-246-Triethyl-4H-l35-Dithiazine
7 35-Diethyl-124-Trithiolane
8 lndolzin
9 P-Cresol
11
12
Comment
CAS Match
Probability Result microgL
57-88-5 907 121
84-61-7 887 201
57-10-3 821 72
25154-52-3 845 ll3
ll2-18-5 844 91
54717-17-8 855 272
54644-28-9 846 231
274-40-8 884 67
106-44-5 899 820
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and qnantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Qnantitation provided is an estimate
~~~
Reviewed by-~==bull_---itt-~==__------
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Field Sample Collection and Analysis
Client 1ck(V 1-- reed Report ) - )1tgt
Collected Analyzed By 2th 0NIZA Date 3 middotOS-10
Sample Type Influent (I) Effluent (E) Well (W) Stream (s) Other _______
1 2 3 4 Sample Type Sample Location t 11-0 1 ~ Time Collected Time Analyzed lO~oo oH units 7(1 oH units (duolicate) 7(3 Duplicate pH readings must be withinplusmn 01 units pH and Chlorine must be analyzed within 15 min of collection DO analyzed immediately
DO meL Chlorine (residual) ueL Temperature degC
DO Calibration Time Calibrated
H Calibration
CgtJbull Make Model
Air Calibration Adjusted Comment Calibration
Time Calibrated
0 D
pH 4 Buffer Calibration
pH 10 Buffer pH 7 Buffer Calibration Check
)
Comment
Return Trip Check
1)efilW Model J1ta1
Chlorine Calibration Makemiddot Modelmiddot Time Calibrated
Standard I ( ) mgL
Standard 2 ( ) mgL
Standard 3 ( ) mgL
Mid- Range Standard True Value Reading mgL rngL
Recovery
Annual Standard Curve for Ran on by DI Water Blank
-
Thermometer Make UOf ~ ~YJJQ _ Serial No ___3-s_-t~----
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
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C p Cc -f7 wl
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G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Attachment 3
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
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G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number G 171-349
Client Project E6414
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
Ifthere are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
Environmental Division 5500 Business Dr Wilmington NC 28405 t 910) 350-1903 f (910) 350-l557 wwwussgscom
Member ol lhamp SGS Group Page1of8
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
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Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
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1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project G 171-349 Project Name E6414
SGS North America Inc
March 121 2010
bull Two waste water samples were accepted into the laboratory on March I 011 20 IO at 1415
for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be reported per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although both sample chromatograms display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 8
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
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C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
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Daternme
Time z ltrgt gt T
4
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4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B =Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF =Dilution Factor
Dup =Duplicate
D =Detected but RPD is gt 40 between results in dual column method
E = Estimated concemiddotntration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL= Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL =Reporting Limit Control Limit
RPD = Relative Percent Difference
UJ =Target analytes with recoveries that are I0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg = milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soilds = Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
M13402 I 8084
Page 3 of 8
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID 4950 Client Project ID E6414
Lab Sample ID G171-349-1A Lab Project ID G171-349
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dlchlorobenzene 14-Dichlorobenzene 11-Dlchloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 111-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-de 4-Bromofluorobenzene
Comments
Flags BQL = Below owintitalion Limits
Analyst l
SGS North America Inc
Results for Volatiles
Result UGL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
113 BQL BQL BQL BQL BQL BQL BQL
byGCMS624
Quantitation Limit UGL
400 400 400 400 400 400 400 500 400 400 400 400 400 400 400 400 400 400 400 400 400 100 400 200 400 400 400 400 400 400 400 400 400 800 400
Spike Spike Added Result
10 102 10 994 10 999
Paga 1 of2
Analyzed By CLP Date Collected 352010 950 Date Received 310201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
102 99 100
Reviewed By cmiddot~
GCMSxlamp
Page 4 of 8
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
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Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
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pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
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~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
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(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
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C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
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NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
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Time z ltrgt gt T
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Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
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~
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X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4950 Analyzed By CLP Client Project ID E6414 Date Collected 03-05-2010
Lab Sample ID g171-349-1a Date Received 03-10-2010 Lab Project ID G171-349 Matrix Water
Sample Vol 5 ml Dilution 1 Date Analyzed 03-11-2010
No Comoound Retention
Time CAS Match
Probabllltv Result uaL
0 0 0 4 5 6 7 8 9 10
Dimethyl sulfide Acetaldehyde Propane 1-(methylthio)-Disulfide dimethyl
298 182 590 654
000075-18-3 000075-07-0 003877-15-4 000624-92-0
91 90 97 95
137 101 922 716
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quanlilated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest Internal standard from the totalIon chromatogram TICs are Identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitatlon provided is an estimate
Reviewed by middot fltmiddot
Page 1 Of 1 VOA_TICS_UMSxls
Page 5 of 8
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
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PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID G171-349-2A Lab Project ID G171-349
Compound Benzene Bromodlchloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dlchloroethene 12-Dichloroethane trans-12-dlchloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trichloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags BQL = Below titation Limits
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
108 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 800 BQL 400
Spike Spike Added Result
10 101 10 99 10 102
Page 1 of 2
Analyzed By CLP Date Collected 352010 955 Date Received 3102010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010 4 3112010
Percent Recovered
101 99 102
Reviewed ByTpound
GCMSxa
Page 6 of 8
624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID 4951 Client Project ID E6414
Lab Sample ID g171-349-2a Lab Project ID G171-349
Sample Vol 5 ml Dilution 1
Analyzed By CLP Date Collected 03-05-2010 Date Received 03-10-2010
Matrix Water
Date Analyzed 03-11-2010
Retention Match Result No Compound Time CAS Probabllltv ugL 0 Dimethyl sulfide 297 000075-18-3 91 142 0 Acetaldehyde 181 000075-07-0 90 0 0 Propane 1-(methylthio)- 591 003877-15-4 97 0 4 5 6
7
8 9
10
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by 1j
Page 1 of1 VOA_TICS_UMSxs
Page 7 of 8
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
-----------
G1ft~3Cfr- -ENVIRONMENTAL CHEMISTS INC
6602 Windmill Way Wilmington NC 28405 Phone (910) 392-0223 Fax (910) 392-4424
REQUEST EOR SUBCONTRACTED SEEYICES
Subcontracted To Sc 5 Contact___L______ Purchase Order ( - -
Phone __________ Fax ____________
Lab ID I Sampled I Date Time
Sample Description Analysis Requested Preservation
I L~SD $ lsiiv ltj S-0
1(q SI S5k10 1))
Wftvfrac14 ~L j
Co 2~_ -+ I(_ I - se -kJlt--L (-1-- T
1 bull cl ~ i-lc
7 - h ISpecial Instructions iVJ _ L__ ~ )_--- bull bgtAmf4-S ~
en G) en z 0s sect (D
~ 5 rgt
Send Reports To ______________ echemwiiagt1com or Fax 910-392-4424
Please Mail Original to Environmental Chemists Inc
g J Prepared by ___________For Shipment By __________ Tracking No ________
g_ Relinquished by ~-_ fh Date 3 rclt q Time I-iilt ~ p Q 7L
Received by 1tti~ Date ]jJ6 0 I Time ( lf5 z oc
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Attachment 4
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
) S~nlc frgt
__f~ I
pl- Ct
Collection
Date Time Temo fltos 0
C7gt0
I
J1_ ~lt0 Y 5 lt
UgtO
I 0--I ff
0
c
PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
ll -
bull-- Ogt ~E ()
C ll m~ lt( i1
w z 0 z
PRESERVATION
~ X8 u 0 8 0 Q
X N z lt X X X z
ll w X
0
(C) G
(P (G
tlt ( )lt ( )lt
C p
G G
C p
G G (C)
G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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2-) lt _c_
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C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
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Gf c ltv1t G G G
C p
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G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
__________________
6602 Windmill Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OF=ICE 910-392-0223 FAX 910-3924424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 37729 Anatytical amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT cC-- f c-_-JZ~~1 ADDRESS_______________
Sampled By -~ (-_r- ZL o1 bull r- __ z_
Sample Identification
) Claquo~I-~ tJ
p ff 91 L
2) frc ( C _ ) -
plf Jo
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Collection
Date Time Temo fltos 0
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UgtO
I 0--I ff
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PROJECTNAME u-c- -_(___
CONTACTNAME ficmiddotv r6crk -pound REPORTTO______________
COPY TO ____ -~__ _ _ _ _
REPORTNO o middot ZJ Pj
PONO _____________
PHONEFAX___________
E-MAILmiddot
SAMPLE TYPE 1- lnfluen~ E = Effluent W = Well ST= Stream SO= Soil SL - Sludge Other
bull0 8E ~
1bullo~~ 0 E e 0 ()
bull-CC
bull- 0C 0
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G
(Ip
( G) svV -
C p
G G
C p
G G degfi
C (Pl (G) G
C p
G G
C p
G G
C p
G G
ANALYSIS REQUESTED
60~c) -1 ltI_ 1 ~lt r ~
nsvss ~ lr-1~-I Lz ltfx -amp acc_1c) ftbull Pltlt ( bull 9~ gt eftltJlt z f)~Jvk~_ ~~ =
(fl~-(lt_ - ~ -J(~ ) -
NOTICE - OECHLORINA TlON Samp~ for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) in the- field at the time of collection s~ reverse for instructions
Transfer Relinquished By DateTime Received By
1
2 when Received
~ ~ i
LI- L
J fgt
p _ __
- Accepted
Received By
- ~(-$ -f V C I C
Rejected
=-) _d ~ -t- gt-0
Resample Rred Date gt ~
r
Daternme
Time z ltrgt gt T
4
~
4
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Wfly bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (hix)
710 l3owsPrlmvn Ro)d bull Mlt1nleo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFCAH 94 DLS CERTJFlCAfE 1137729
Customer
McKIM amp CREED - RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number I 0-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER page l 0 f4 EPA 624
Analytc microgL Capetown
5446 Septic 5447
--middot--Benzene lt20 lt20 Bromodichloromethane lt20 lt 20 Bromoform lt20 lt20 Bromomethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzcne lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 12-Dichlorobenzene lt20 lt 20
--middotmiddot-middotmiddot-middot _____ _
13-Dichlorobenwne lt 20 lt20 middot-middotmiddotmiddotmiddotmiddotmiddotmiddotmiddot
14-Dichlorobenwne lt20 lt20 11-Dichloroethane lt20 lt20 l2-Dichloroetha11e lt20 lt20 I 1-Dichloroethene lt20 lt20 Trans-l 2-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDEN[lc OWQ CERTFfCArE 94 DLS CERTlrfCATE 37729
-==============middotcmiddotmiddotmiddotmiddotmiddot=middotmiddotmiddotmiddot=middotmiddotmiddotmiddot-=middotmiddotmiddotmiddot-==
Customer McKim amp Creed Report I0-2303 Page 2 of 4
WASTEWATERmiddot EPA 624
Capetown SepticAnalyte microgL 5446 5447
-middot -12-Dichloropropane lt20 lt20 Cis-13-Dichloropropene lt20 lt20 Trans-13-Dichloropropene lt20 lt20 Ethyl benzene lt2036 Methylene Chloride lt20 lt20 l 122-Tetrachloroethane lt20 lt20 Tetrachloroethene lt20 lt20 Toluene 136 529 11 I-Trichloroethane lt20 lt20 112-Trichloroethane lt20 lt20 Trichloroethene lt20 lt20 Trichlorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20 M_+P Xylene lt4094 O-Xylene lt2016
MTBE lt20 lt20 Acetone lt1037
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown Septic Date
-_ 1nallte lllIL middotmiddot--middotmiddotmiddot-middotmiddotmiddot-middot- 5446 5447 Analywd
Ethylene Glycol 164 194 0312JO
Propylene Glycol lt25 252 0312JO
-
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
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C p u _ SoJJltf( -_)01) lG G C p
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C p Cc -f7 wl
G G C p I
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C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
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pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
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G G C p
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G G C p
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G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of 4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 624
Match ResultNumber Compound CAS Probability 04 microgL
Unknownbull 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio )propane 3877-15-4 9411 320
6
7
8
9
10
JI
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TlCs are identified and quantitated only if the peak height is equal or greater than IOfrac14 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
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Time ltlto
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0
L I C
( pound -
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(C) G C
G C
G IC)
G C
G
C
G
C fG)
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G
C
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G (Pl ( G)
p
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0 X
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ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
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NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
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iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
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1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Wlt1y bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE lll4 DIS CERTIFICAfE ff7729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compountlsfor 624
Match ResuliNumber Compound CAS Probability microgL
Unknown 320
2 1-Propanol 71-23-8 9377 232
3 1-(methylthio)propane 3877-15-4 9348 160
4
5
6
7
8
9
10
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than IO of that of the nearest internal standard Qnantitation provided is an estimate
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
-sosC 0 0 0 u-
(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
G
sbull ~t u
9 ffi 10 10
I sectiz
rN(
ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
ii 0 N X
~
8 z X
X 0
z ~ ~ ~
~ w X
0 ~
ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
N
(JI--(_ - J - )
NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
Resample Rzzted Date gt bull a
~
Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
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I
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lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
___ _ _ _ _ _
Analytical amp Consulting Chemists
6602 Windmill Way WIimington NC 28405ENVIRONMENTAL CHEMISTS INC OF1CE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION 94 NCDHHS DLS CERTIFICATION 3TT29
COLLECTION AND CHAIN OF CUSTODY
CLIENT lcC-_ ~ ea_tf-Zlaquo~lct PROJECTNAME laquo-lt - 4-__ REPORTNO o - L-J PJ ADDRESS_______________CONTACTNAME lZ ~6ltrk pound PONO _____________
__________________REPORTTO______________PHONEFAX___________
COPYTO E-MAIL
Sampled BX_ -1- lt----- Z~~ -~~
Sample Identification
) c flt- -I-_ fJJ I ff 91 L
z) gter-1c(e_) -
pl t Jo
) S~dc 0 -f-f-~k
gt t-1- (Ct
Date 30
)t I
I bull
Collection
Time ltlto
7gt0
f-fO
(0gt0
10
- z__
bull0E obull Temp
0
L I C
( pound -
ff f 0
lt-
SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge 0th-i8 g e 0 e 0 u
(C) G C
G C
G IC)
G C
G
C
G
C fG)
C
G
C
G
C
G
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(P)
(G) p
G p
G (Pl ( G)
p
G p
G ( PJ
G p
G p
G p
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sbull ~t u
9 ffi 10 10
I sectiz
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ifI 1
sltli r
w z 0 z
Y-
PRESERVATION
0 X
(
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ANALYSlS REQUESTED
ampo~lt-l) -laquo- 1 ~~ r gt 755 JS$ ~ 1r1~-4 LZ ltex -4pound aeee) fw 9v t bull fgtOf S-e-U_cJ~ z j)OJvk~ cl~
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NOTICE bull DECHLORINATION Samples for Ammonia TKN Cyanide Phenol and Bacteria must be dechlorinated (02 ppm or less) Jn the field at the time of collection See rnve-rse for insbuciions
Transfer Relinquished By DateTime Received By Daterrime
1
2 when Received
~ ~ -r
p ~
tJ L Accepted --Received By
]-fgt - rtlt-- --rbullvc f C
Rejected
~-0 ~ v [_ ~O
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Time 7- ltFfp7-
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 7729
Customer
McKIM amp CREED- RALEIGH Date of Original Report March 15 2010 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attn Kevin Eberle PE
Report Number 10-2303
REPORT OF ANALYSIS
Date Sampled 031110 Project UNC - Bingham
Sampled By Jay Baker ( Envirochem)
WASTEWATER pale l 0 f4 EPA 624
Analyte microgL Capetown
5446 Septic 5447
Benzene lt20 lt20 Bromodichloromethane lt20 lt20 Bromoform lt20 lt20 Bro mom ethane lt20 lt20 Carbon Tetrachloride lt20 lt20 Chlorobenzene lt20 lt20 Chloroethane lt20 lt20 2-Chloroethylvinyl ether lt20 lt20 Chloroform lt 20 lt20 Chloromethane lt20 lt20 Dibromochloromethane lt20 lt20 l2-Dichlorobenzene lt20 lt20 I 3-Dichlorobenzene lt20 lt20 14-Dichlorobenzene lt20 lt20 l1-Dichloroethane lt20 lt20 12-Dichloroethane lt20 lt20 11-Dichloroetbene lt20 lt20 Trans-12-Dichloroethene lt20 lt20
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NC DEN R DWQ CERTlflCATE 94 DLS CERT FlCATE 37729
middot==================middotmiddotmiddotmiddotmiddot-middotmiddotmiddotmiddot-bullmiddotmiddotmiddot
Customer McKim amp Creed Report 10-2303 Page2 of 4
WASTEWATER EPA 624
Capetown 5446
Septic 5447 Analyte microgL
12-Dichloropropane lt20 lt20
Cis-13-Dichloropropene lt20 lt20
Trans-13-Dichloropropene lt20 lt20
Ethyl benzene 36 lt20 Methylene Chloride lt20 lt20
1122-Tetrachloroethane lt20 lt20
Tetrachloroethene lt20 lt20
Toluene 136 529
111-Trichloroethane lt20 lt20
112-Trichloroethane lt20 lt20
Trichloroethene lt20 lt20
Tricblorofluoromethane lt20 lt20
Vinyl Chloride lt20 lt20
M+PXylene 94 lt40
O-Xylene 16 lt20
MTBE lt20 lt20
Acetone 37 lt JO
Date Analyzed 031210 031210
SW 846 METHOD 8015 Capetown 5446
Septic 5447
Date AnalyzedAnalvte meL
Ethylene Glycol 164 194 031210
Propylene Glycol lt 25 252 031210
Comments Quantitation limit elevated due to sample matrix interference
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
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rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
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Gf c ltv1t G G G
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C p
G G C p
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G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page3 of4
Domestic Waste (Post Septic) 5446 Results ofLibrary Search Compounds for 614
Match Result Number Compound CAS Probability microgL
Unknown 143
2 Unknownbull 128
3 Unknown 345
4 1-Propanol 71-23-8 9447 105
5 1-(methylthio)propane 3877-15-4 94l I 320
6
7
8
9
JO
11
12
Comment bull Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 194 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-2303 Page4 of 4
Domestic Waste (Post Septic) 5447 Results ofLibrary Search Compounds for 624
Number Compound CAS Match
Probability Result microgL
1
2
3
4
Unknown
1-Propanol
1-(methylthio)propane
71-23-8
3877-15-4
9377
9348
320
232
160
5
6
7
8
9
II
12
Comment Compound is reported as unknown if match probability is less than 70
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TlCs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak height of the compound compared to that of the nearest internal standard from the total ion chromatograph TICs are identified and quantitated only if the peak height is equal or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by pound~ ~ __~-=-J--91)lv-f_______=-~~- LEJ
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
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Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
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NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
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ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
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G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
SGS Mr Ray Porter EnviroChem 6602 Windmill Way Wilmington NC 28405
Report Number GI 71-350
Client Project Split Samples
Dear Mr Porter
Enclosed are the results of the analytical services performed under the referenced project The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference Any samples submitted to our laboratory will will be retained for a maximum of thirty (30) days from the date of this report unless other arrangements are requested
If there are any questions about the report or the services performed during this project please call SGS at (910) 350-1903 We will be happy to answer any questions or concerns which you may have
Thank you for using SGS Environmental Services for your analytical services We look forward to working with you again on any additional analytical needs which you may have
Sincerely SGS Environmental Services Inc
9
middotroJt Lori Loe
Environmental Division 5500 Business Or Wilmington NC 28405 t (910) 350middot 1903 f 910) 350-1557 wwwussgscom
Member of the SGS Group Page 1 of 12
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Case Narrative Revision EnviroChem
SGS Project Gl71-350 Project Name I0-2303
SGS North America Inc
March IS 2010
bull Two waste water samples were accepted into the laboratory on March 11 h 20 IO at 1706 for analyses as indicated on the chain of custody The samples were received in good condition with a temperature of 20C
bull All extractions and analyses were completed within holding time limits with the following quality control exceptions
624 Analyses
bull Acetone was requested to be repotted per client communication Acetone is not part of the 624 continuing calibration report but is evaluated under the 8260 QC check
bull Although sample chromatograms for sample Cape Town display a peak eluting at the calibrated retention time for Acetone it is the opinion of the laboratory that this detection cannot accurately be reported as Acetone Due to a co-eluting non-target compound containing an abundance of ion 58 which is the secondary ion for Acetone this factor creates ion ratios that are inconsistent with the mass-spectral pattern of this compound
Page 2 of 12
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
List of Reporting Abbreviations And Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantification Limit (RL or MDL)
DF = Dilution Factor
Dup = Duplicate
D = Detected but RPD isgt 40 between results in dual column method
E = Estimated concentration exceeds calibration range
J = Estimated concentration below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
PQL = Practical Quantitation Limit
RLCL = Reporting Limit I Control Limit
RPD = Relative Percent Difference
UJ = Target analytes with recoveries that are I 0 lt R lt LCL of MEs are allowable and compounds are not detected in the sample
mgkg= milligram per kilogram ppm parts per million
ugkg = micrograms per kilogram ppb parts per billion
mgL = milligram per liter ppm parts per million
ugL = micrograms per liter ppb parts per billion
Rec = Percent Recovery
soi Ids= Percent Solids
Special Notes I) Metals and mercury samples are digested with a hot block see the standard
operating procedure document for details 2) Uncertainty for all reported data is less than or equal to 30 percent
Ml3402 I 8084
Page 3 of 12
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Client Sample ID Capetown
Client Project ID Split Samples
Lab Sample ID G171-350-1B
Lab Project ID G171-350
Analyte
Ethylene Glycol Propylene Glycol
Comments All values corrected for dilution BQL = Below quantitation limit
Results for Glycols by GC 8015 Modified
Analyzed By BWS
Date Collected 3112010 940
Date Received 31112010
Matrix Water
Result RL Dilution Date mgL mgL Factor Analyzed
BQL 200 3122010 BQL 200 31122010
Reviewed By lltJ Page4 of 12
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Results for Glycols by GC 8015 Modified
Client Sample ID Septic Analyzed By BWS
Client Project ID Split Samples Date Collected 3112010 1040
Lab Sample ID G171-350-2B Date Received 3112010
Lab Project ID G171-350 Matrix Water
Analyte Result RL Dilution Date mgll mgll Factor Analyzed
Ethylene Glycol 124 100 5 3122010 Propylene Glycol BQL 100 5 3122010
Comments All values corrected for dilution BQL = Below quantitation limit
Reviewed By JJ2_ Page 5 of 12
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171-350-1A Lab Project ID 8171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 1 4-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethyl benzene Methylene chloride Methyl-tert-buty ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethane 1 1 1-Trlchloroethane 112-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS 624
Result Quantltatlon UGL Limit UGL BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 500 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 100 BQL 400 BQL 200 BQL 400 BQL 400 BQL 400
140 400 BQL 400 BQL 400 BQL 400 BQL 400 BQL 400
111 800 BQL 400
Spike Spike Added Result
10 841 10 992 10 10
Page 1 of 2
Analyzed By DVO Date Collected 311201 O940 Date Received 3112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010 4 3152010
Percent Recovered
84 99 100
GCMS
Page 6 of 12 624
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID Capetown Client Project ID Split Samples
Lab Sample ID G171bull350-1A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
I middot 0Ana yst ___e_____
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantitation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 940 Date Received 31112010
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By _a_middot___
Page 2 of 2 GCMS
Page 7 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Capetown Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID G171-350-1A Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 4 Date Analyzed 03-15-2010
No Compound Retention
Time CAS Match
Probabllltv Result uaL
2
3
4
5 6
7
8
9
10
Dimethyl sulfide
Propane 1-(methylthio)-
1-Propanethiol
299
592
429
000075-18-3
003877-15-4
000107-03-9
91
94
96
418
163
683
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantitation provided is an estimate
Reviewed by L~
Page 1 Of 1 VOA_TCS_LIMSxls
Page 8 of 12
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 11-Dichloroethene 12-Dichloroethane trans-12-dichloroethene 12-Dichloropropane cis-13-Dichloropropene trans-13-Dichloropropene Acetone Ethylbenzene Methylene chloride Methyl-tert-butyl ether (MTBE) 1122-Tetrachloroethane Tetrachloroethene Toluene Trichloroethene 1 1 1-Trlchloroethane 1 12-Trichloroethane Trichlorofluoromethane Vinyl chloride m-p-Xylene o-Xylene
12-Dichloroethane-d4 Toluene-dB 4-Bromofluorobenzene
Comments
Flags
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltatlon UGL Limit UGL BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 313 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 625 BQL 250 BQL 125 BQL 250 BQL 250 BQL 250
522 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 250 BQL 500 BQL 250
Spike Spike Added Result
10 842 10 998 10 972
Page 1 of 2
Analyzed By DVO Date Collected 31112010 1040 Date Received 3112010
Matrix Water Sample Amount 5 ml
DIiution Date Factor Analyzed
25 3152010 25 31152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31512010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 31152010 25 31152010 25 31152010 25 3152010 25 31512010 25 3152010 25 31512010 25 31512010 25 31152010 25 31152010 25 31152010 25 31152010 25 31152010 25 3152010 25 3152010 25 3152010 25 3152010 25 3152010 25 31512010 25 3152010 25 31152010 25 31152010
Percent Recovered
84 100 97
GCMS
Page 9 of 12
624
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Client Sample ID Septic Client Project ID Split Samples
Lab Sample ID G171-350-2A Lab Project ID G171-350
Compound BQL = Below Quantitation Limits
Analyst _ ___D-v--J---
SGS North America Inc
Results for Volatiles byGCMS624
Result Quantltation UGL Limit UGL
Analyzed By DVO Date Collected 3112010 1040 Date Received 311 201 O
Matrix Water Sample Amount 5 ml
Dilution Date Factor Analyzed
Reviewed By -~----
GCMSPage 2 of2
Page 10 of 12 624
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
SGS North America Inc
Results of Library Search for Volatile Compounds byGCMS
Client Sample ID Septic Analyzed By DVO Client Project ID Split Samples Date Collected 03-11-2010
Lab Sample ID g171-350-2a Date Received 03-11-2010 Lab Project ID G171-350 Matrix Water
Sample Vol 5 ml Dilution 25 Date Analyzed 03-15-2010
No Comoound Retention
Time CAS Match
Probability
78
Result uaL 1423
4
5
6
7
8 9
10
1-Propanol 404 000071-23-8
Comment
Tentatively Identified Compound (TIC) refers to substances which are not present in the list of target compounds Therefore not all TICs are identified and quantitated using individual standards TIC listings are prepared utilizing a computerized library search of electron impact mass spectral data and evaluation of the relevant data by a mass spectral data specialist
Quantitation is accomplished by relative peak area of the compound compared to that of the nearest internal standard from the total ion chromatogram TICs are identified and quantitated only if the peak area is equal to or greater than 10 of that of the nearest internal standard Quantltation provided is an estimate
Reviewed by _tli-__
Page 1 Of 1 VOA_TlCS_UMSxls
Page11of12
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
(__ 17- JY-0 ENVIRONMENT AL CHEMISTS INC 6602Wlndmi11Way Wilmington NC 28405 41(iJi OFFlCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFlCA TION 94 NCDHHS DLS CERTIFICATION 3n29Anafytlcal amp Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
CLIENT poundreck- --t 5G-5 PROJECTNAME ff f- 5_lfe_s j REPORTNO 0-27ltgt3 ADDRESS_____________CONTACT NAME 7J PO NO ___________
________________REPORT TO hy J-1-_- PHONEFAX__________
COPYTO_____________~E-MAIL
Sa_mp_ed_Bymiddot s--ampZv SAMPLE TYPE I= Influent E = Effluent W = Well ST= Stream SO= Soil SL= Sludge Other
J
JiI
O 1 Q
Delivered By c -- Received By ~ Date 5I I OI Time 7 Cb CommentsJ TURNAROUND --------
Collection - bull Q 0 PRESERVATIONbull -bull E E _Q 8 8 ~ ~
_w Sample Identification ll - - 1l ml w ii ~ X ANALYSIS REQUESTED ~ ~ 0 - C 0 ie _
~ w E lt z
0 0 X 0 0 11
ltJ _ z 0 X ~ z ~ ~
Date Time Temo ltJ - z X X z 0
) J oV C p t Z-lf Yyct~ ft1 -AE acc+-11 Cjlt+o I ~ G G ~-N-l- X l( micro~k-- 1r_c-bull __
C p vc f lfl - lot)
~ G G -Jo 0 f-gt C p
2-) lt _c_
lo~O G G
iv i-Xyk(- -rS~ ee~T~~ s ~-fltfJ- f- k I bull Z p-o -4_ of-_
C p u _ SoJJltf( -_)01) lG G C p
s_ -7-I- 5f- J G G C p 9--ffc rgt- 5~J) G G
C p Cc -f7 wl
G G C p I
G G C p _ooc G G
C p no Cv-$frJr lteq G G
NOTICE bull OECHLORfNATION Samples for Ammonia TKN Cyanide Phenol and Bacterta must be dechlorinated (02 ppm or less) in the- field at the time ofcollection See teverBe for lmrtructlons
Transfer Relinauished By DateTime Received Bv DateTime
1
2 Temperature w~e~ ~ Accepted _ Rej~ed Resample Requested _
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Attachment 5
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL ampCONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer
McKIM amp CREED - RALEIGH Date of Report March 12 20 I0 1730 Varsity Drive Suite 500 Raleigh NC 27606 Purchase Order Attu Kevin Eberle PE
Report Number l0-1636
REPORT OF ANALYSIS
Date Sampled 021910 Project UNC-Bingham Faclility
Sampled By Eric McHomey ( Envirochem)
SURFACE WATER pael of 3
Influent Effluent Method Date Parameters 3893 3894 Code Analyzed
Biochemical Oxygen Demand BOD as 0 2 mIL
533 5 SM5210B 021910
Carbonaceous Biochemical Oxygen Demand CBOD5 as 0 2 miL
444 3 SM5210B 021910
Chemical Oxygen Demand COD as 0 2 mgL 1080 80 SM5220D 022310
Total Organic Carbon TOC mgL 304 246 SM5310B 022410
Settleable Solids SS mlL lt01 lt01 SM 2540F 021910
Total Suspended Solids TSS mgL 342 5 SM2540D 022310
Turbidity NTU 815 61 SM21308 021910
Total Kjeldahl Nitrogen TKN mgL 196 Pending EPA 3512 030810
Ammonia Nitrogen NH3-N mgL 967 Pending EPA350t 022610
Nitrate + Nitrite Nitrogen NO3+ NO-N mgL 036 970 EPA3532 030110
Total Phosphorus as P mgL 415 282 SM4500P-F 030810
Alkalinity as CaCO3 mgL 895 62 SM 2320B 022510
Color units 200 100 SM2120B 030110
Total Phenol mgL 0313 lt0004 SM 420l 022410 -
Comments
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 Windmill Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Manteo NC 27954 (252) 473-5702
ANALYTICAL amp CONSULTING CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 2 of3
Parameters
Antimony Sb mgL
ArsenicAs mgL
Barium Ba mgL
Beryllium Be mgL
Cadmium Cd mgL
Chromium Cr mgL
Cobalt Co mgL
Copper Cu mgL
Lead Pb mgL
Nickel Ni mgL
Selenium Se mgL
Silver Ag mgL
Thallium TI mgL
Vanadium V mgL
Zinc Zn mgL
Parameter
Temperature degC Eric McHoruey Certificate 94 -
pH units
-
lntluent Effiuent Method Date 3893 3894 Code Analyzed
lt 0010 lt 0010 EPA 2007 022410
lt 0010 lt 0010 EPA 2007 022310
0154 lt 0010 EPA2007 022410
lt0010 lt 0010 EPA2007 022410
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 0010 EPA 2007 022310
lt 0010 lt 00IO EPA 2007 022410
0077 0021 EPA 2007 022310
0039 lt 0010 EPA2007 022310
0016 0014 EPA2007 022310
lt 0010 lt0010 EPA 2007 022310
lt 0010 lt 0010 EPA2007 022310
lt0010 lt 0010 EPA 2007 022510
lt 0010 lt 0010 EPA 2007 022510
0625 0845 EPA2007 022510
middotmiddot---Influent Effiuent Method Date 3893 3894 Code Analyzed
68 64 SM2550B 021910
880 673 SM 4500 ff+
021910B
Comments
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Environmental Chemists Inc 6602 WindmiII Way bull Wilmington NC 28405
(910) 392-0223 (Lab) bull (910) 392-4424 (Fax)
710 Bowsertown Road bull Mante0 NC 27954
(252) 473-5702 ANALYTICAL amp CONSULTING
CHEMISTS NCDENR DWQ CERTIFICATE 94 DLS CERTIFICATE 37729
Customer McKim amp Creed Report 10-1636 Page 3 of3
EPA Method 624 Analyte microgL
Benzene Bromodichloromethane Bromoform Bromomethane Carbon Tetrachloride Chlorobeozene Chloroethane 2-Chloroethylvinyl ether Chloroform Cbloromethane Dibromochloromethane 12-Dichlorobenzene 13-Dichlorobenzene 14-Dichlorobenzene 11-Dichloroethane 12-Dichloroetbane 1 1-Dichloroetbene Trans-12-Dichloroethene 12-Dichloropropane Cis-13-Dichloropropene Trans-13-Dlchloronropene Ethyl benzene Methylene Chloride 1122-Tetrachloroethane Tetrachloroethene Toluene 111-Trichloroethane 112-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl Chloride M+PXylene O-Xvlene MTBE Acetone Date Analysis Started Date Analysis Completed
Influent Effluent 3893 3894
lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt 05 lt20 lt05 lt20 lt05 lt20 lt05 lt 20 lt05 lt20 lt05 lt 20 lt05
186 lt05 lt 20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt20 lt05 lt40 lt 10 lt20 lt05 lt20 lt05
199 030310 030910middot--middot--
258
Comments Reviewed by
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
Analytical amp Consulting Chemists
6602 WJndmll Way Wilmington NC 28405ENVIRONMENTAL CHEMISTS INC OFltCE 910-392-0223 FAX 910-392-4424
NCDENR DWQ CERTIFICATION II 94 NCDHHS DLS CERTIFICATION 37729
COLLECTION AtID CHAIN OF CUSTODY
CLIENT 1dlti ~ Cormicrod- kt(ei~k PROJECTNAME liVC--jL REPORT NO I) - I(J ( ADDRESS____________CONTACTNAME et-~ the_ P PO NO ___________
_______________REPORT TO 4 _ltgt- f 1cf k $b-e-e PHONEFAX_________
COPY TO E-MAIL
middot SAMPLE TYPE I =Influent E =Effluent W =Well ST =Stream SO =Soil SL= Slu~_e Other Sample_ci_Bymiddot
-A~---~~ IL J I
Collection j ~ bull eei PRESERVATION
~ 6bullaamp 5 Sample Identification 1~ ls l i~ it
w g ~
ANALYSIS REQUESTEDi 5~ ii 0 0 8~ z q sDrte Time Temp ltgt z z bull bull
ft)Clfto middot~G11 C p -~8-1s $ e D c wJ CB41)
1 ~ t
I
I h~l---lt- -t I amp amp L G G SS 7S- 1lt N Nt-1r C p ~ a~
1 -rtP 1 I ti
pf-f zf_ fc G G (c ~~-middot ( tb_1t - nlt-1pound C p
lr vmiddotampcL~~) ~~ it--c-i-- I
G G ()-
rfiCgtj 11- -la C p 1 -1r- bull
-i [v iti ff( 1_L-_t
__ 1 l Q
Gf c ltv1t G G G
C p
oil-- amp ~ ~7-
G G
C p
G G C p
G G C p
G G C p
G G C p
G G NOTICE bull OECHLORINATION Samples for Ammonffl TKN Cyanide Phenol and Bacteria must be- dechlorinated (02 ppm or tess) In thamp fretd at the time ofcolfectfon See tElvene for in5tructlons
Transfer Relinauished By DateTime Received By Dat~Time
1 2
- - -
Dellvered By tf- JA-ti+~ -- ~ Received~ltmiddotJj4)l--u2 C-c -e--= Date iJ4frac12 Time~~ f-_ Comments__________T ________________________TURNAROUND _________
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