elementary introduction to subdoppler laser spectroscopy...

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united nationseducational, scientific

and culturalorganization

theiinternational centre for theoretical physics

international atomicenergy agency

SMR 1302- 16

WINTER SCHOOL ON LASER SPECTROSCOPY AND APPLICATIONS

19 February - 2 March 2001

Elementary Introductionto

Subdoppler Laser Spectroscopy

Part I and II

M. INGUSCIOL.E.N.S. - Lab. Europeo di Spettroscopie Non Lineari

Largo Enrico Fermi, 2 - Firenze, Italy

These are preliminary lecture notes, intended only for distribution to participants.

strada costiera, I I - 34014 trieste italy - tel.+39 04022401 I I fax +39 040224163 - scLinfo@ictp.trieste.it - www.ictp.trieste.it

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Physical structure and energy band diagram ofnear-infrared DFB lasers. "

IXE.COOPER,LASER

FT$ - £6]

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8150 8200 5250 8300 8350 8400 8450 8500

WAVE NUMBERS / cm ~ 1

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Detection of HCl on the first and second overtones

at 1.7 jum and 1.2 jam using semiconductor diode lasers

C. Corsi1, S. Czhudzynsky2, F. D'Amato3, M. De Rosa4, K. Ernst2

LENS-INFM1 Dip. di Neuroscienze, Univ. Firenze; 2 Dip. di Fisica, Univ. Warsaw;

3 ENEA, Frascati; 4 SIT, Firenze

Ig

1000 c

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23-SEP-1997 11'-24 +39 55 224072 94* S.0S '-SEP-1997 11:24 +39 55 224072 94*:

Why using diode lasers for monitoring gases?

fast response time (ms)

selectivity

• non-intrusiveness

6MVlR0Mrte/JTAL

sensitivity

—^

low energy consumption

^ AT PPM L6V6L

low costIN SITU "

small-size

remote sensing—b

Abdications

-Control of combustion processes

O2, CO, HC1

-Detection of hazardous gases

CO, H2S, CH4i

-Monitoring of exhaust gases

CO, CO2

-Monitoring of e^mission gases in power plants

NH3

Medical Applications

-Non invasive diagnostic of human breath

12CO2,13CO2, NH3, C2H6

Geophysical Applications

-Monitoring of volcanic gases

H2S, H2O, CO2

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