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Journal Name

Cite this: DOI: 10.1039/c0xx00000x

www.rsc.org/xxxxxx

Dynamic Article Links►

ARTICLE TYPE

This journal is © The Royal Society of Chemistry [year] [journal], [year], [vol], 00–00 |1

Supporting Information

Steric Effect on the Self-assembly Behaviours of Amino Acid DerivativesYulan Fana,‡, Linxiu Chenga,‡, Chunhua Liua, Yunzhi Xiea, Wei Liua, Yongdong Lia, Xun Lia, Yibao Lia,*and Xiaolin Fana,*

5 Received (in XXX, XXX) Xth XXXXXXXXX 20XX, Accepted Xth XXXXXXXXX 20XXDOI: 10.1039/b000000x

1) NMR studies

Fig. S1 (a) 1H NMR spectrum of ANTA; (b) 1H NMR spectrum of PNTA; (c) 13C NMR spectrum of ANTA;

10 (d) 13C NMR spectrum of PNTA.

2) FT-IR spectra of ANTA and PNTA

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2014

CREATED USING THE RSC ARTICLE TEMPLATE (VER. 3.0) - SEE WWW.RSC.ORG/ELECTRONICFILES FOR DETAILS

ARTICLE TYPE www.rsc.org/xxxxxx | XXXXXXXX

2|Journal Name, [year], [vol], 00–00 This journal is © The Royal Society of Chemistry [year]

Fig. S2 ( Top) FT-IR spectra of ANTA;(bottom) FT-IR spectra of PNTA

3) MS spectra of ANTA and PNTA

Journal Name

Cite this: DOI: 10.1039/c0xx00000x

www.rsc.org/xxxxxx

Dynamic Article Links►

ARTICLE TYPE

This journal is © The Royal Society of Chemistry [year] [journal], [year], [vol], 00–00 |1

Fig. S3 (a) MS spectrum of ANTA; (b) MS spectrum of PNTA.

4) HPLC chromatogram of ANTA and PNTA

5

CREATED USING THE RSC ARTICLE TEMPLATE (VER. 3.0) - SEE WWW.RSC.ORG/ELECTRONICFILES FOR DETAILS

ARTICLE TYPE www.rsc.org/xxxxxx | XXXXXXXX

2|Journal Name, [year], [vol], 00–00 This journal is © The Royal Society of Chemistry [year]

Fig. S4 HPLC chromatogram of compounds: (a) for PNTA and (b) for ANTA.

5

5) Addtionnal STM image of PNTA

Journal Name

Cite this: DOI: 10.1039/c0xx00000x

www.rsc.org/xxxxxx

Dynamic Article Links►

ARTICLE TYPE

This journal is © The Royal Society of Chemistry [year] [journal], [year], [vol], 00–00 |1

Fig. S5 (68.70 × 68.70 nm2,Iset= 405.9 nA, Vbias= 360.4 mV) showing PNTA molecule disordered arrangement.

5

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