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CONTENTS
Preface xvii
Materials Research Society Symposium Proceedings xviii
NANOPHASE MA TERIALS
* Kinetics and Mechanism of Nucleation, Growth andStabilization of Metal Oxide Nanoparticles 3
Rina Tannenbaum, Scott King, K. Hyunh, Melissa Zubris,and Nily Dan
* Photo-formed Metal Nanoparticle Arrays in MonolithicSilica-Biopolymer Aerogels 13
Xipeng Liu, Yu Zhu, Chunhua Yao, and William M. Risen Jr.
* The Use of Mesoporous Systems for Preparation of One-DimensionalOrdered Magnetic Nanowires 25
Andrei A. Eliseev, Kirill S. Napolskii, Dmitry F. Gorozhankin,Alexei V. Lukashin, Yuri D. Tretyakov, Natalia A. Grigorieva,Sergei V. Grigoriev, and A.A. Vorobiev
Formation of Nanosized Metallic Ag Grains by Oxidationof Ag Single Crystals With Hyperthermal Atomic Oxygen 37
Long Li and Judith C. Yang
Molecule Derived Nanomaterials: Chemical Concepts forComposition, Morphology and Particle Size Control 43
Sanjay Mathur
On the Development of the <111> Fiber Texture inNanocrystalline Gold During Growth and Annealing 49
Klaus P. Andreasen, Norbert Schell, Thomas Jensen,Jakob H. Petersen, Martin S. Jensen, Jacques Chevallier,and J. Bottiger
Anomalous Magnetoresistance Behavior of BismuthAntidot Arrays 55
Oded Rabin and Mildred S. Dresselhaus
* Invited Paper
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Spatial Separation Mechanism in Si Quantum DotsDeposited by Chemical Vapor Deposition on SiO2 61
Rosaria A. Puglisi, Giuseppe Nicotra, Salvatore Lombardo,Corrado Spinella, and Cosimo Gerardi
Synthesis and Characterization of Novel VanadiumDioxide Nanorods 69
Wen Chen, Liqiang Mai, Congsheng Jiang, Junfeng Peng,Qing Xu, and Quanyao Zhu
Growth of Single Crystal Tungsten Nanorods by ObliqueAngle Sputter Deposition 75
Tansel Karabacak, Pei-I Wang, Gwo-Ching Wang, andToh-Ming Lu
Self Assembled Gold and Silver Nanoparticulates onSilicon Nanotips as Surface Enhanced Raman ActiveSubstrates 81
S. Chattopadhyay, H.C. Lo, K.H. Chen, C.H. Hsu, L.C. Chen
Magnetic Properties of Nanocrystalline Fe50Co50 Powders 89Shashishekar Basavaraju
Fe3O4 Ultrafine Particles With Narrow Size DistributionFrom Polymer-Metal Complex Gels 97
Cheng Huang, C.Z. Yang, and L. Chen
Genesis and Growth of Nanoparticles During Sol-GelSynthesis 103
Nan Yao, King Lun Yeung, Guoxing Xiong, andShishan Sheng
Sintered Tantalum and Niobium Sub-Micron Powders ofSolid Electrolite Capacitors 109
Y. Pozdeev Freeman, A. Gladkikh, and Yu. Rosenberg
Oxygen Diffusivity and Defect Transport in Pure and YbDoped Nano-Crystalline Ceria 115
Laxmikant Saraf, V. Shutthanandan, S. Thevuthasan,CM. Wang, K.T. Koch, J.A. Andreasen, O. Marina, andY. Zhang
Effects of DC and AC Magnetic Fields on Grain Growth inElectrodeposited Nanocrystalline Nickel 121
T. Matsuzaki, T. Yamada, K. Jyuami, S. Tsurekawa,T. Watanabe, and G. Palumbo
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Synthesis of Ultrafine Oxide Powders by Hydrothermal-Ultrasonic Method 129
Pavel E. Meskin, Yury V. Kolenko, Alexander E. Baranchikov,Vladimir K. Ivanov, Bulat R. Churagulov, andNikolay N. Oleynikov
A Model of New VUV NLO Materials Based on Borate: A NovelNoncentrosymmetric Borophosphate Compound Be3BPO7 135
Zhangzhen He and Hiroshi Moriyama
TEM and DOE Optimization Studies of ElectrospunPolycarbonate Nanofibers 141
Nirupama Kattamuri and Changmo Sung
Preparation of Fe-Pt Nanowires Through AnodicOxidation of Sputtered Aluminum on Glass Surface 147
Satoru Inoue, Song-Zhu Chu, Kenji Wada, andYasushi Kanke
Solution Electrospinning of Nylon/Ferrite Nanofibers 153Autumn Dhanote, Samuel C. Ugbolue, Steven B. Warner,Prabir K. Patra, Phaneshwar Katangur, and Shamal K. Mhetre
Contact Compression of Self-assembled Nano- andMicro-scale Pyramid Structures on Au (100) Surface 159
J. Wang, D. Ward, W.A. Curtin, and K.-S. Kim
Virtual Synthesis of Sub-Nanoscale Materials WithPrescribed Physical Properties 165
Liudmila A. Pozhar, Alan T. Yeates, Frank Szmulowicz,and William C. Mitchel
High-Resolution Analytical Electron Microscopy Investigationof Metastable Tetragonal Phase Stabilization in Undoped,Sol-Gel Derived Zirconia Nanoceramics 171
Vladimir P. Oleshko, James M. Howe, Satyajit Shukla,and Sudipta Seal
NANOCOMPOSITE MATERIALS
* Hierarchically Ordered Multi-Component BlockCopolymer/Particle Nanocomposite Materials 179
M.R. Bockstaller and E.L. Thomas
* Invited Paper
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Nanocomposite Material for Sensing of HalogenatedMethanes: A Model Based on Charge Transfer Interactionfor Selectivity 191
Rajiv Sangoi, L. Fuller, and K.S.V. Santhanam
Nanocomposites With Functionalized Carbon Nanotubes 197Shamal K. Mhetre, Yong K. Kim, Steven B. Warner,Prabir K. Patra, Phaneshwar Katangur, and Autumn Dhanote
UV Curable Polymers With Organically Modified Clay asthe Nanoreinforcements 203
Fawn M. Uhl, Brian R. Hinderliter, Siva Prashanth Davuluri,Stuart G. Croll, Shing-Chung Wong, and Dean C. Webster
Phase Characterization and Morphology Control ofElectrospun Nanofibers of PANI/PMMA Blends 209
K. Desai and C. Sung
Synthesis of Mesoporous Complex Framework ZirconiumPhosphates via Organic-inorganic Nanocomposites:Genesis of Structure, Adsorption and Catalytic Properties 215
Yulia V. Frolova, Vladislav A. Sadykov, S.N. Pavlova,S.A. Veniaminov, R.V. Bunina, E.B. Burgina,V.N. Kolomiichuk, T.V. Larina, N.V. Mezentseva,M.A. Fedotov, A.M. Volodin, E.A. Paukshtis,V.B. Fenelonov, R. Roy, and D. Agrawal
Percolation in Multi-Wall Carbon Nanotube-EpoxyComposites—Influence of Processing Parameters,Nanotube Aspect Ratio and Electric Fields on the BulkConductivity 221
Jan K.W. Sandier, Alan H. Windle, Christian A. Martin,Matthias-Klaus Schwarz, Wolfgang Bauhofer, Karl Schulte,and Milo S.P. Shaffer
Synthesis of Hydroxyapatite-Hyaluronic acid NanoComposite Sol Under Well-Controlled Condition 227
Yuko Ishikawa and Mamoru Senna
Incorporation of Functional Metal Oxide Materials inChemical Microsystems 233
Nan Yao and King Lun Yeung
A Thermodynamic Approach in Tuning Phase Stability inNanocomposite Multilayers 239
G.B. Thompson, R. Banerjee, and H.L. Fraser
vni
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In Situ Synthesis and Magnetic Properties ofPolystyrene/Polypyrrole Nanocomposite MaterialsWith Uniformly Dispersed Iron Nanoparticles 243
H. Srikanth, P. Poddar, J.L. Wilson, K. Mohomed, andJ.P. Harmon
Microstructure of Precipitated Au Nanoclusters in TiO2 249CM. Wang, V. Shutthanandan, Y. Zhang, D.R. Baer,L.E. Thomas, and S. Thevuthasan
Proton Conducting Nano Hybrid Membranes SynthesizedFrom Temperature Tolerant Polydimethylsiloxane(PDMS) Polymers 255
Je-Deok Kim and Itaru Honma
Iron Oxide/Silica Nanocomposites 261Michael Kroll, Markus Pridohl, and Guido Zimmermann
Nanocrystalline Mixed Metal Oxides—Novel OxygenStorage Materials 267
Harry Sarkas, Patrick G. Murray, Aaron Fay, andR.W. Brotzman Jr.
Achieving Electrical Percolation in Polymer-CarbonNanotube Composites 271
Sameer S. Rahatekar, M. Hamm, Milo S.P. Shaffer, andJames A. Elliott
Porous Carbon Nanoturf Using Anodized AluminaTemplating 277
Ramakrishnan Rajagopalan, Krishna Dronavajjala, andHenry C. Foley
Synthesis and Characterization of Novel Organic-InorganicNancomposite Coatings 283
Brian P. Mosher and Taofang Zeng
Flame Retardancy of Laponite- and Montmorillonite-BasedNylon 6 Nanocomposites 289
Gunes Inan, Prabir K. Patra, Yong K. Kim, andSteven B. Warner
Spherulitic Morphology and Thermal Stability of PP/ZnONanocomposites 297
Sandeep Razdan, Prabir Patra, Yong Kim, and Steve Warner
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Nanocomposites of Liquid Crystalline Polyhedral OligomericSilsesquioxane Particles and Liquid Crystalline Polymers 303
Alline P. Somlai, Subramanian Iyer, and David A. Schiraldi
Quaternary-Matrix, Nanocomposite Self-LubricatingPVD Coatings in the System TiAlCNMoS2—Structure andTribological Properties 309
V. Spassov, A. Savan, A.R. Phani, M. Stueber, andH. Haefke
Improved Tribological Properties of DiamondlikeCarbon/Metal Nanocomposites 315
Roger J. Narayan and Dirk Scholvin
Vanadium Oxide Nanofibers and Vanadium Oxide PolyanilineNanocomposite: Preparation, Characterization andElectrochemical Behavior 321
Samuel T. Lutta, Hong Dong, Peter Y. Zavalij, andM. Stanley Whittingham
Carbon-Based Nanocomposite Materials for Cold CathodeSources 327
Alexander V. Karabutov, Viktor G. Ralchenko, andSergey K. Gordeev
NANOPOROUS MA TERIALS
* Macroporous Silica and Alkylene-Bridged PolysilsesquioxaneGels With Templated Nanopores 337
Kazuki Nakanishi
Nanoporous Thermosets via Reactive Encapsulation of aChemically Inert Solvent Versus Free RadicallyPolymerized and Phase Separating Systems 347
Vijay I. Raman and Giuseppe R. Palmese
Controlled Hierarchical Pore Structures in Ethylene-BridgedPolysilsesquioxane Gels 353
Yuki Kobayashi, Kazuki Nakanishi, and Kazuyuki Hirao
HSA-CERCANAM®: A New Material With a ContinuousNanopore Network 359
A. Akash, B. Nair, K. Minnick, M. Wilson, and J. Hartvigsen
*Invited Paper
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Systematic Molecular Control of Interfacial Structure inNanoporous Carbons 365
Kengqing Jian, Gregory P. Crawford, Robert H. Hurt,and Nancy Y.C. Yang
Mechanism of Surfactant Removal From OrderedNanocomposite Silica Thin Films by Deep-UV LightExposure 371
Andrew M. Dattelbaum, Meri L. Amweg, Julia D. Ruiz,Laurel E. Ecke, Andrew P. Shreve, and Atul N. Parikh
Synthesis and Electrochemical Properties of Mesostructured12-Phosphotungstic Acid Thin Films With HierarchicalStructures by Triblock Copolymer Templating 377
Hui-suk Yun, Makoto Kuwabara, Haoshen Zhou, andItaru Honma
Selective Ordered Mesoporous Silica Adsorbents 383Koon Fung Lam, Ka Yee Ho, King Lun Yeung, andGordon McKay
Macroporous Morphology Induced by Phase Separation inSol-Gel Systems Derived from Titania Colloid 391
Junko Konishi, Koji Fujita, Kazuki Nakanishi, andKazuyuki Hirao
Characterization of Porous Silicate Low-& Films byEllipsometric Porosimetry and Variable-Energy PositronAnnihilation Spectroscopy 397
Kenji Ito, Yoshinori Kobayashi, Ryoichi Suzuki,Toshiyuki Ohdaira, Runsheng Yu, Kiminori Sato,Kouichi Hirata, Hisashi Togashi, Miki Egami,Hiroki Arao, Akira Nakashima, and Michio Komatsu
Mesoporous Silica Film Preparation by Novel SupercriticalFluid Extraction of Organic Templates 403
Nobuyuki Kawakami, Takayuki Hirano, Yoshito Fukumoto,and Yoshiyuki Nagase
In Situ Observation of Formation Processes of AnodicPorous Alumina on a Si Substrate Using InfraredAbsorption Spectroscopy 409
Yasuo Kimura, Hirokazu Shiraki, Hisao Ishii,Sachiko Ono, Kingo Itaya, and Michio Niwano
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Synthesis of Porous Ceramics Through DirectionalSolidification and Freeze-Drying 415
Predrag Kisa, Patrick Fisher, Al Olszewski,Ian Nettleship, and Nicholas G. Eror
NANOSTRUCTURED MATERIALS
Assembly of Nano-Domain Buildings Blocks of CopperOxalate With a Cubic Morphology .....423
L.C. Soare, P. Bowen, J. Lemaitre, H. Hofmann,M. Pijolat, and F. Valdivieso
Bramble-Like Mesostructured Nickel Oxide Fiber Clusters 431Jieming Cao, Jun Wang, Jinsong Liu, Shuquan Chang,Baoqing Fang, Xianjia Ma, Xin Chang, Guoyue Xu, andJie Tao
Size Effect Characterization for Nanostructured Materialin Nanoindentation Test 437
Yueguang Wei, Ying Du, Siqi Shu, and Chen Zhu
Mean Inner Potential of Nanostructured Noble MetalCatalysts-Pt/TiO2 Catalyst 443
S. Ichikawa, T. Akita, K. Okazaki, M. Okumura,K. Tanaka, and M. Kohyama
Preparation and Mechanical Properties of NanostructuredTungsten Carbide Alloys Strengthened by CarbonNanotubes 449
G.L. Tan, X.J. Wu, and Z.Q. Li
APPLICA TIONS AND PROPERTIESOF NANOSTRUCTURED MA TERIALS
Oxidative Dehydrogenation of Ethylbenzene to StyreneOver Graphite Nanofibers 455
Xuejun Xu and R. Terry K. Baker
Effect of Mo Doping and Heat Treatment on Microstructureand Electrochemical Performance of Vanadium OxideNanotubes 461
Liqiang Mai, Wen Chen, Congsheng Jiang, Qing Xu,Junfeng Peng, and Quanyao Zhu
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Nanodisperse Many-Particle-Systems: Concept, Structure-Property Relationships and Characterization Strategy 467
Vladimir P. Oleshko
Nanostructured Oxide Films for High-Speed Humidity Sensors 473John J. Steele, Kenneth D. Harris, and Michael J. Brett
Corrosion Protection of Materials by ApplyingNanotechnology Associated Studies 479
Ramazan Asmatulu and Richard O. Claus
Structure Evolution and Corresponding ElectricalProperties in Weakly Bound Co-C60 Mixture 485
Seiji Sakai, Hiroshi Naramoto, and Yonghua Xu
New Advances in Molding and Printing Processes forOrganic/Plastic Electronics Using Chemically Modified Stiff,Photocured Poly (dimethylsiloxane) (PDMS) ElastomersDesigned for Nano-Resolution Soft Lithography 491
Kyung M. Choi and John A. Rogers
CARBON NANOTUBES
Characterizing the Dopant Behavior of FunctionalizedCarbon Nanotubes in Conducting Polymers 503
Mark Hughes, Graeme A. Snook, George Z. Chen,Milo S.P. Shaffer, Derek J. Fray, and Alan H. Windle
Carbon Nanotubes and Nanofibers Grown by MicrowavePlasma Enhanced Chemical Vapor Deposition on a NickelSubstrate 509
K.G. Belay, J. Jackson, and Yan Xin
Growth of Carbon Nanotubes Using Uniformly DistributedCobalt Nanoparticles as Catalyst: Controlled Growth andStructural Characterization 515
Yoon Huh, Jeong Yong Lee, Sang Kyu Choi, andCheol Jin Lee
Low Potential Stable Glucose Detection at CarbonNanotube Modified Gold Electrodes 521
S.G. Wang, Qing Zhang, Ruili Wang, D.J. Yang,S.F. Yoon, and R. Zhang
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Single-Walled Carbon Nanotube Rope for Gas SensorApplication 527
J.W. Lee, Y.M. Choi, KJ. Kong, H.J. Chang, andB.H. Ryu
Thermal and Electrical Transport Measurements ofSingle-Walled Carbon Nanotube Strands 533
Diana-Andra Borca-Tasciuc, Yann LeBon, Claire Nanot,Gang Chen, Theodorian Borca-Tasciuc, Anyuan Cao,Robert Vajtai, and Pulikel M. Ajayan
Controlled Assembly of Carbon Nanotube Fibrils byDielectrophoresis 539
J. Tang, G. Yang, J. Zhang, H.Z. Geng, B. Gao,O. Velev, L.-C. Qin, and O. Zhou
NANOSTRUCTURED THIN FILMSAND COATINGS
Metastable Phase Formation and Stimulated Transitionsin Metallic Nanometer Films 547
Dirk C. Meyer, Alexandr A. Levin, Stefan Braun,Andre Gorbunov, Michael Mertig, Wolfgang Pompe,and Peter Paufler
Atom Probe Tomography Characterization of Thin FilmMultilayers 553
G.B. Thompson, M.K. Miller, R. Banerjee, and H.L. Fraser
Spin-Dependent STM Tunnelling Study of the PatternedMagnetite (111) Surface 559
N. Berdunov, S. Murphy, G. Mariotto, and I.V. Shvets
Preparation and Microstructure Control of Protein ThinFilms Deposited by Pulsed Laser Deposition and viaColloid Chemical Routes 565
Sayuri Nakayama, Ichiro Taketani, Sanshiro Nagare, andMamoru Senna
Structuring of Silicon Wafer Surfaces on the Sub-100 nmScale by Hydrogen Plasma Treatments 571
R. Job, Y. Ma, and A.G. Ulyashin
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Pulsed Laser Deposition Parameter Optimization forGrowth of Alumina (A12O3) Thin Film on Silicon (100) 577
Xinyu Wang, Sergey Yarmolenko, Dhananjay Kumar,Zhigang Xu, and Jagannathan Sankar
LPE Growth of Atomically Flat Ge Layer on a Mesa Pattern 583Takahiro Maruyama, Keiji Matsuda, Norikazu Saikawa,and Shigeya Naritsuka
Nano-Structured Polymer Coatings for Ultraviolet Protection 589Phaneshwar Katangur, Steven B. Warner, Prabir K. Patra,Yong K. Kim, Shamal K. Mhetre, and Autumn Dhanote
Carbon/Nafion® Nanocomposite Thin Films as PotentialMatrix-Free Laser Desorption-Ionization MassSpectroscopy Substrates 595
A. Kaan Kalkan and Stephen J. Fonash
Micromechanics of PS/PB/PS Triblock-Copolymer Filmswith Lamellar Morphology 601
Theodora Tzianetopoulou and Mary C. Boyce
Structure Analysis of Co/Re Superlattice Grown on anA12O3 (110) Substrate 609
Wentao Xu, Timothy Charlton, Lance E. De Long, andDavid Lederman
Photoluminescence of Si/SiO2, RE2O3/Si/SiO2 andRE2O3/Si/Al2O3 (RE = Er, Nd, Tm) Sputtered Thin Films 615
C. Rozo, L.F. Fonseca, O. Resto, and S.Z. Weisz
THEORETICAL AND MODELING STUDIESOF NANOSTRUCTURED MATERIALS
Multiscale Modeling of Carbon Nanotubes 623Marc Hamm, James A. Elliott, Huw J. Smithson, andAlan H. Windle
On Molecular Dynamics Simulation of Metal Clusters andTheir XRD and ELNES Spectra 629
G. D'Agostino and M. Gusso
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Molecular Modeling Computer Simulations of OrganicPolymers: A Novel Computer Simulation Technique toCharacterize Nanostructured Materials 635
Sarah G. Schulz, Hubert Kuhn, and Giinter Schmid
Theoretical Studies of Electronic Structures and OpticalAbsorptions of Encapsulated Guest Alkali Metal Atoms inITQ-4 Zeolite 641
Hong Li and S.D. Mahanti
Exploring Space Groups for Three Dimensional PhotonicBand Gap Structures Via Level Set Equations: The FaceCentered Cubic Lattice 647
Martin Maldovan, Chaitanya K. Ullal, Craig W. Carter,and Edwin L. Thomas
Author Index 653
Subject Index 659
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