contentsassets.cambridge.org/97811074/09347/toc/9781107409347... · 2014. 6. 12. · ramakrishnan...

CONTENTS

Preface xvii

Materials Research Society Symposium Proceedings xviii

NANOPHASE MA TERIALS

* Kinetics and Mechanism of Nucleation, Growth andStabilization of Metal Oxide Nanoparticles 3

Rina Tannenbaum, Scott King, K. Hyunh, Melissa Zubris,and Nily Dan

* Photo-formed Metal Nanoparticle Arrays in MonolithicSilica-Biopolymer Aerogels 13

Xipeng Liu, Yu Zhu, Chunhua Yao, and William M. Risen Jr.

* The Use of Mesoporous Systems for Preparation of One-DimensionalOrdered Magnetic Nanowires 25

Andrei A. Eliseev, Kirill S. Napolskii, Dmitry F. Gorozhankin,Alexei V. Lukashin, Yuri D. Tretyakov, Natalia A. Grigorieva,Sergei V. Grigoriev, and A.A. Vorobiev

Formation of Nanosized Metallic Ag Grains by Oxidationof Ag Single Crystals With Hyperthermal Atomic Oxygen 37

Long Li and Judith C. Yang

Molecule Derived Nanomaterials: Chemical Concepts forComposition, Morphology and Particle Size Control 43

Sanjay Mathur

On the Development of the <111> Fiber Texture inNanocrystalline Gold During Growth and Annealing 49

Klaus P. Andreasen, Norbert Schell, Thomas Jensen,Jakob H. Petersen, Martin S. Jensen, Jacques Chevallier,and J. Bottiger

Anomalous Magnetoresistance Behavior of BismuthAntidot Arrays 55

Oded Rabin and Mildred S. Dresselhaus

* Invited Paper

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Spatial Separation Mechanism in Si Quantum DotsDeposited by Chemical Vapor Deposition on SiO2 61

Rosaria A. Puglisi, Giuseppe Nicotra, Salvatore Lombardo,Corrado Spinella, and Cosimo Gerardi

Synthesis and Characterization of Novel VanadiumDioxide Nanorods 69

Wen Chen, Liqiang Mai, Congsheng Jiang, Junfeng Peng,Qing Xu, and Quanyao Zhu

Growth of Single Crystal Tungsten Nanorods by ObliqueAngle Sputter Deposition 75

Tansel Karabacak, Pei-I Wang, Gwo-Ching Wang, andToh-Ming Lu

Self Assembled Gold and Silver Nanoparticulates onSilicon Nanotips as Surface Enhanced Raman ActiveSubstrates 81

S. Chattopadhyay, H.C. Lo, K.H. Chen, C.H. Hsu, L.C. Chen

Magnetic Properties of Nanocrystalline Fe50Co50 Powders 89Shashishekar Basavaraju

Fe3O4 Ultrafine Particles With Narrow Size DistributionFrom Polymer-Metal Complex Gels 97

Cheng Huang, C.Z. Yang, and L. Chen

Genesis and Growth of Nanoparticles During Sol-GelSynthesis 103

Nan Yao, King Lun Yeung, Guoxing Xiong, andShishan Sheng

Sintered Tantalum and Niobium Sub-Micron Powders ofSolid Electrolite Capacitors 109

Y. Pozdeev Freeman, A. Gladkikh, and Yu. Rosenberg

Oxygen Diffusivity and Defect Transport in Pure and YbDoped Nano-Crystalline Ceria 115

Laxmikant Saraf, V. Shutthanandan, S. Thevuthasan,CM. Wang, K.T. Koch, J.A. Andreasen, O. Marina, andY. Zhang

Effects of DC and AC Magnetic Fields on Grain Growth inElectrodeposited Nanocrystalline Nickel 121

T. Matsuzaki, T. Yamada, K. Jyuami, S. Tsurekawa,T. Watanabe, and G. Palumbo

VI






Synthesis of Ultrafine Oxide Powders by Hydrothermal-Ultrasonic Method 129

Pavel E. Meskin, Yury V. Kolenko, Alexander E. Baranchikov,Vladimir K. Ivanov, Bulat R. Churagulov, andNikolay N. Oleynikov

A Model of New VUV NLO Materials Based on Borate: A NovelNoncentrosymmetric Borophosphate Compound Be3BPO7 135

Zhangzhen He and Hiroshi Moriyama

TEM and DOE Optimization Studies of ElectrospunPolycarbonate Nanofibers 141

Nirupama Kattamuri and Changmo Sung

Preparation of Fe-Pt Nanowires Through AnodicOxidation of Sputtered Aluminum on Glass Surface 147

Satoru Inoue, Song-Zhu Chu, Kenji Wada, andYasushi Kanke

Solution Electrospinning of Nylon/Ferrite Nanofibers 153Autumn Dhanote, Samuel C. Ugbolue, Steven B. Warner,Prabir K. Patra, Phaneshwar Katangur, and Shamal K. Mhetre

Contact Compression of Self-assembled Nano- andMicro-scale Pyramid Structures on Au (100) Surface 159

J. Wang, D. Ward, W.A. Curtin, and K.-S. Kim

Virtual Synthesis of Sub-Nanoscale Materials WithPrescribed Physical Properties 165

Liudmila A. Pozhar, Alan T. Yeates, Frank Szmulowicz,and William C. Mitchel

High-Resolution Analytical Electron Microscopy Investigationof Metastable Tetragonal Phase Stabilization in Undoped,Sol-Gel Derived Zirconia Nanoceramics 171

Vladimir P. Oleshko, James M. Howe, Satyajit Shukla,and Sudipta Seal

NANOCOMPOSITE MATERIALS

* Hierarchically Ordered Multi-Component BlockCopolymer/Particle Nanocomposite Materials 179

M.R. Bockstaller and E.L. Thomas

* Invited Paper

vn






Nanocomposite Material for Sensing of HalogenatedMethanes: A Model Based on Charge Transfer Interactionfor Selectivity 191

Rajiv Sangoi, L. Fuller, and K.S.V. Santhanam

Nanocomposites With Functionalized Carbon Nanotubes 197Shamal K. Mhetre, Yong K. Kim, Steven B. Warner,Prabir K. Patra, Phaneshwar Katangur, and Autumn Dhanote

UV Curable Polymers With Organically Modified Clay asthe Nanoreinforcements 203

Fawn M. Uhl, Brian R. Hinderliter, Siva Prashanth Davuluri,Stuart G. Croll, Shing-Chung Wong, and Dean C. Webster

Phase Characterization and Morphology Control ofElectrospun Nanofibers of PANI/PMMA Blends 209

K. Desai and C. Sung

Synthesis of Mesoporous Complex Framework ZirconiumPhosphates via Organic-inorganic Nanocomposites:Genesis of Structure, Adsorption and Catalytic Properties 215

Yulia V. Frolova, Vladislav A. Sadykov, S.N. Pavlova,S.A. Veniaminov, R.V. Bunina, E.B. Burgina,V.N. Kolomiichuk, T.V. Larina, N.V. Mezentseva,M.A. Fedotov, A.M. Volodin, E.A. Paukshtis,V.B. Fenelonov, R. Roy, and D. Agrawal

Percolation in Multi-Wall Carbon Nanotube-EpoxyComposites—Influence of Processing Parameters,Nanotube Aspect Ratio and Electric Fields on the BulkConductivity 221

Jan K.W. Sandier, Alan H. Windle, Christian A. Martin,Matthias-Klaus Schwarz, Wolfgang Bauhofer, Karl Schulte,and Milo S.P. Shaffer

Synthesis of Hydroxyapatite-Hyaluronic acid NanoComposite Sol Under Well-Controlled Condition 227

Yuko Ishikawa and Mamoru Senna

Incorporation of Functional Metal Oxide Materials inChemical Microsystems 233

Nan Yao and King Lun Yeung

A Thermodynamic Approach in Tuning Phase Stability inNanocomposite Multilayers 239

G.B. Thompson, R. Banerjee, and H.L. Fraser

vni






In Situ Synthesis and Magnetic Properties ofPolystyrene/Polypyrrole Nanocomposite MaterialsWith Uniformly Dispersed Iron Nanoparticles 243

H. Srikanth, P. Poddar, J.L. Wilson, K. Mohomed, andJ.P. Harmon

Microstructure of Precipitated Au Nanoclusters in TiO2 249CM. Wang, V. Shutthanandan, Y. Zhang, D.R. Baer,L.E. Thomas, and S. Thevuthasan

Proton Conducting Nano Hybrid Membranes SynthesizedFrom Temperature Tolerant Polydimethylsiloxane(PDMS) Polymers 255

Je-Deok Kim and Itaru Honma

Iron Oxide/Silica Nanocomposites 261Michael Kroll, Markus Pridohl, and Guido Zimmermann

Nanocrystalline Mixed Metal Oxides—Novel OxygenStorage Materials 267

Harry Sarkas, Patrick G. Murray, Aaron Fay, andR.W. Brotzman Jr.

Achieving Electrical Percolation in Polymer-CarbonNanotube Composites 271

Sameer S. Rahatekar, M. Hamm, Milo S.P. Shaffer, andJames A. Elliott

Porous Carbon Nanoturf Using Anodized AluminaTemplating 277

Ramakrishnan Rajagopalan, Krishna Dronavajjala, andHenry C. Foley

Synthesis and Characterization of Novel Organic-InorganicNancomposite Coatings 283

Brian P. Mosher and Taofang Zeng

Flame Retardancy of Laponite- and Montmorillonite-BasedNylon 6 Nanocomposites 289

Gunes Inan, Prabir K. Patra, Yong K. Kim, andSteven B. Warner

Spherulitic Morphology and Thermal Stability of PP/ZnONanocomposites 297

Sandeep Razdan, Prabir Patra, Yong Kim, and Steve Warner

IX






Nanocomposites of Liquid Crystalline Polyhedral OligomericSilsesquioxane Particles and Liquid Crystalline Polymers 303

Alline P. Somlai, Subramanian Iyer, and David A. Schiraldi

Quaternary-Matrix, Nanocomposite Self-LubricatingPVD Coatings in the System TiAlCNMoS2—Structure andTribological Properties 309

V. Spassov, A. Savan, A.R. Phani, M. Stueber, andH. Haefke

Improved Tribological Properties of DiamondlikeCarbon/Metal Nanocomposites 315

Roger J. Narayan and Dirk Scholvin

Vanadium Oxide Nanofibers and Vanadium Oxide PolyanilineNanocomposite: Preparation, Characterization andElectrochemical Behavior 321

Samuel T. Lutta, Hong Dong, Peter Y. Zavalij, andM. Stanley Whittingham

Carbon-Based Nanocomposite Materials for Cold CathodeSources 327

Alexander V. Karabutov, Viktor G. Ralchenko, andSergey K. Gordeev

NANOPOROUS MA TERIALS

* Macroporous Silica and Alkylene-Bridged PolysilsesquioxaneGels With Templated Nanopores 337

Kazuki Nakanishi

Nanoporous Thermosets via Reactive Encapsulation of aChemically Inert Solvent Versus Free RadicallyPolymerized and Phase Separating Systems 347

Vijay I. Raman and Giuseppe R. Palmese

Controlled Hierarchical Pore Structures in Ethylene-BridgedPolysilsesquioxane Gels 353

Yuki Kobayashi, Kazuki Nakanishi, and Kazuyuki Hirao

HSA-CERCANAM®: A New Material With a ContinuousNanopore Network 359

A. Akash, B. Nair, K. Minnick, M. Wilson, and J. Hartvigsen

*Invited Paper

x






Systematic Molecular Control of Interfacial Structure inNanoporous Carbons 365

Kengqing Jian, Gregory P. Crawford, Robert H. Hurt,and Nancy Y.C. Yang

Mechanism of Surfactant Removal From OrderedNanocomposite Silica Thin Films by Deep-UV LightExposure 371

Andrew M. Dattelbaum, Meri L. Amweg, Julia D. Ruiz,Laurel E. Ecke, Andrew P. Shreve, and Atul N. Parikh

Synthesis and Electrochemical Properties of Mesostructured12-Phosphotungstic Acid Thin Films With HierarchicalStructures by Triblock Copolymer Templating 377

Hui-suk Yun, Makoto Kuwabara, Haoshen Zhou, andItaru Honma

Selective Ordered Mesoporous Silica Adsorbents 383Koon Fung Lam, Ka Yee Ho, King Lun Yeung, andGordon McKay

Macroporous Morphology Induced by Phase Separation inSol-Gel Systems Derived from Titania Colloid 391

Junko Konishi, Koji Fujita, Kazuki Nakanishi, andKazuyuki Hirao

Characterization of Porous Silicate Low-& Films byEllipsometric Porosimetry and Variable-Energy PositronAnnihilation Spectroscopy 397

Kenji Ito, Yoshinori Kobayashi, Ryoichi Suzuki,Toshiyuki Ohdaira, Runsheng Yu, Kiminori Sato,Kouichi Hirata, Hisashi Togashi, Miki Egami,Hiroki Arao, Akira Nakashima, and Michio Komatsu

Mesoporous Silica Film Preparation by Novel SupercriticalFluid Extraction of Organic Templates 403

Nobuyuki Kawakami, Takayuki Hirano, Yoshito Fukumoto,and Yoshiyuki Nagase

In Situ Observation of Formation Processes of AnodicPorous Alumina on a Si Substrate Using InfraredAbsorption Spectroscopy 409

Yasuo Kimura, Hirokazu Shiraki, Hisao Ishii,Sachiko Ono, Kingo Itaya, and Michio Niwano

XI






Synthesis of Porous Ceramics Through DirectionalSolidification and Freeze-Drying 415

Predrag Kisa, Patrick Fisher, Al Olszewski,Ian Nettleship, and Nicholas G. Eror

NANOSTRUCTURED MATERIALS

Assembly of Nano-Domain Buildings Blocks of CopperOxalate With a Cubic Morphology .....423

L.C. Soare, P. Bowen, J. Lemaitre, H. Hofmann,M. Pijolat, and F. Valdivieso

Bramble-Like Mesostructured Nickel Oxide Fiber Clusters 431Jieming Cao, Jun Wang, Jinsong Liu, Shuquan Chang,Baoqing Fang, Xianjia Ma, Xin Chang, Guoyue Xu, andJie Tao

Size Effect Characterization for Nanostructured Materialin Nanoindentation Test 437

Yueguang Wei, Ying Du, Siqi Shu, and Chen Zhu

Mean Inner Potential of Nanostructured Noble MetalCatalysts-Pt/TiO2 Catalyst 443

S. Ichikawa, T. Akita, K. Okazaki, M. Okumura,K. Tanaka, and M. Kohyama

Preparation and Mechanical Properties of NanostructuredTungsten Carbide Alloys Strengthened by CarbonNanotubes 449

G.L. Tan, X.J. Wu, and Z.Q. Li

APPLICA TIONS AND PROPERTIESOF NANOSTRUCTURED MA TERIALS

Oxidative Dehydrogenation of Ethylbenzene to StyreneOver Graphite Nanofibers 455

Xuejun Xu and R. Terry K. Baker

Effect of Mo Doping and Heat Treatment on Microstructureand Electrochemical Performance of Vanadium OxideNanotubes 461

Liqiang Mai, Wen Chen, Congsheng Jiang, Qing Xu,Junfeng Peng, and Quanyao Zhu

xu






Nanodisperse Many-Particle-Systems: Concept, Structure-Property Relationships and Characterization Strategy 467

Vladimir P. Oleshko

Nanostructured Oxide Films for High-Speed Humidity Sensors 473John J. Steele, Kenneth D. Harris, and Michael J. Brett

Corrosion Protection of Materials by ApplyingNanotechnology Associated Studies 479

Ramazan Asmatulu and Richard O. Claus

Structure Evolution and Corresponding ElectricalProperties in Weakly Bound Co-C60 Mixture 485

Seiji Sakai, Hiroshi Naramoto, and Yonghua Xu

New Advances in Molding and Printing Processes forOrganic/Plastic Electronics Using Chemically Modified Stiff,Photocured Poly (dimethylsiloxane) (PDMS) ElastomersDesigned for Nano-Resolution Soft Lithography 491

Kyung M. Choi and John A. Rogers

CARBON NANOTUBES

Characterizing the Dopant Behavior of FunctionalizedCarbon Nanotubes in Conducting Polymers 503

Mark Hughes, Graeme A. Snook, George Z. Chen,Milo S.P. Shaffer, Derek J. Fray, and Alan H. Windle

Carbon Nanotubes and Nanofibers Grown by MicrowavePlasma Enhanced Chemical Vapor Deposition on a NickelSubstrate 509

K.G. Belay, J. Jackson, and Yan Xin

Growth of Carbon Nanotubes Using Uniformly DistributedCobalt Nanoparticles as Catalyst: Controlled Growth andStructural Characterization 515

Yoon Huh, Jeong Yong Lee, Sang Kyu Choi, andCheol Jin Lee

Low Potential Stable Glucose Detection at CarbonNanotube Modified Gold Electrodes 521

S.G. Wang, Qing Zhang, Ruili Wang, D.J. Yang,S.F. Yoon, and R. Zhang






Single-Walled Carbon Nanotube Rope for Gas SensorApplication 527

J.W. Lee, Y.M. Choi, KJ. Kong, H.J. Chang, andB.H. Ryu

Thermal and Electrical Transport Measurements ofSingle-Walled Carbon Nanotube Strands 533

Diana-Andra Borca-Tasciuc, Yann LeBon, Claire Nanot,Gang Chen, Theodorian Borca-Tasciuc, Anyuan Cao,Robert Vajtai, and Pulikel M. Ajayan

Controlled Assembly of Carbon Nanotube Fibrils byDielectrophoresis 539

J. Tang, G. Yang, J. Zhang, H.Z. Geng, B. Gao,O. Velev, L.-C. Qin, and O. Zhou

NANOSTRUCTURED THIN FILMSAND COATINGS

Metastable Phase Formation and Stimulated Transitionsin Metallic Nanometer Films 547

Dirk C. Meyer, Alexandr A. Levin, Stefan Braun,Andre Gorbunov, Michael Mertig, Wolfgang Pompe,and Peter Paufler

Atom Probe Tomography Characterization of Thin FilmMultilayers 553

G.B. Thompson, M.K. Miller, R. Banerjee, and H.L. Fraser

Spin-Dependent STM Tunnelling Study of the PatternedMagnetite (111) Surface 559

N. Berdunov, S. Murphy, G. Mariotto, and I.V. Shvets

Preparation and Microstructure Control of Protein ThinFilms Deposited by Pulsed Laser Deposition and viaColloid Chemical Routes 565

Sayuri Nakayama, Ichiro Taketani, Sanshiro Nagare, andMamoru Senna

Structuring of Silicon Wafer Surfaces on the Sub-100 nmScale by Hydrogen Plasma Treatments 571

R. Job, Y. Ma, and A.G. Ulyashin

xiv






Pulsed Laser Deposition Parameter Optimization forGrowth of Alumina (A12O3) Thin Film on Silicon (100) 577

Xinyu Wang, Sergey Yarmolenko, Dhananjay Kumar,Zhigang Xu, and Jagannathan Sankar

LPE Growth of Atomically Flat Ge Layer on a Mesa Pattern 583Takahiro Maruyama, Keiji Matsuda, Norikazu Saikawa,and Shigeya Naritsuka

Nano-Structured Polymer Coatings for Ultraviolet Protection 589Phaneshwar Katangur, Steven B. Warner, Prabir K. Patra,Yong K. Kim, Shamal K. Mhetre, and Autumn Dhanote

Carbon/Nafion® Nanocomposite Thin Films as PotentialMatrix-Free Laser Desorption-Ionization MassSpectroscopy Substrates 595

A. Kaan Kalkan and Stephen J. Fonash

Micromechanics of PS/PB/PS Triblock-Copolymer Filmswith Lamellar Morphology 601

Theodora Tzianetopoulou and Mary C. Boyce

Structure Analysis of Co/Re Superlattice Grown on anA12O3 (110) Substrate 609

Wentao Xu, Timothy Charlton, Lance E. De Long, andDavid Lederman

Photoluminescence of Si/SiO2, RE2O3/Si/SiO2 andRE2O3/Si/Al2O3 (RE = Er, Nd, Tm) Sputtered Thin Films 615

C. Rozo, L.F. Fonseca, O. Resto, and S.Z. Weisz

THEORETICAL AND MODELING STUDIESOF NANOSTRUCTURED MATERIALS

Multiscale Modeling of Carbon Nanotubes 623Marc Hamm, James A. Elliott, Huw J. Smithson, andAlan H. Windle

On Molecular Dynamics Simulation of Metal Clusters andTheir XRD and ELNES Spectra 629

G. D'Agostino and M. Gusso

xv






Molecular Modeling Computer Simulations of OrganicPolymers: A Novel Computer Simulation Technique toCharacterize Nanostructured Materials 635

Sarah G. Schulz, Hubert Kuhn, and Giinter Schmid

Theoretical Studies of Electronic Structures and OpticalAbsorptions of Encapsulated Guest Alkali Metal Atoms inITQ-4 Zeolite 641

Hong Li and S.D. Mahanti

Exploring Space Groups for Three Dimensional PhotonicBand Gap Structures Via Level Set Equations: The FaceCentered Cubic Lattice 647

Martin Maldovan, Chaitanya K. Ullal, Craig W. Carter,and Edwin L. Thomas

Author Index 653

Subject Index 659

xvi






contentsassets.cambridge.org/97811074/09347/toc/9781107409347... · 2014. 6. 12. · ramakrishnan...

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