amo environmental decisions auxier & associates, inc. … · amo environmental decisions auxier...

0001

AMO ENVIRONMENTAL DECISIONS

AUXIER & ASSOCIATES, INC.

West Lake Storm Water

ST AND ARD LEVEL IV REPORT OF ANALYSIS

WORK ORDER #18-06097-OR

July 24, 2018

EBERLINE ANALYTICAL/OAK RIDGE LABO RA TORY OAK RIDGE, TN

0002

TABLE OF CONTENTS

SECTION DESCRIPTION PAGE

I Chain of Custody& pH Check 0004

II Sample Acknowledgement 0012

III Case Narrative 0015

IV Analytical Results Summary 0019

V Analytical Standards 0022

VI Quality Control Sample Results Summary 0050

VII Laboratory Technician's Notes 0061

VIII Analytical Data (Isotopic Uranium) 0088

IX Analytical Data (Isotopic Thorium) 0130

X Analytical Data (Radium-226) 0169

XI Analytical Data (Radium-228) 0203

XII Barium-133 Analytical Tracer Data 0219

XIII Analytical Data (Gross Alpha/Beta) 0248

Last Page 0267

0003

STANDARD OPERATING PROCEDURE

Sample Receiving

Eberline Services - Oak Ridge Laboratory

LABORATORY DATA SUPPORT CHECKLIST

MP-001-3

MP-001, Rev. 19 Effective. 2111118

Page 14 of 15

Eberline Services Work Order # __ 1_8_-_0_6_0_9_7 _____ _ The checklist items listed below are to be initialed by appropriate staff upon completion/verification.

Date for Partial Initials Date Initials Checklist Items

Sample Log-In

Data Compilation

First Technical Data Review

Second Technical Data Review

Data Entry/Electronic Deliverable

Case Narrative

Client in Possession of Data El

Invoiced by Laboratory

Technical/Clerical Corrections, Signatures Needed, Problems, Etc Date/Initials

Date package approved by:

Laboratory Manager Date

Copy No Radiochemistry Services

0004

SECTION I

CHAIN OF CUSTODY & pH CHECK

0005

Chain of Custody Record N~

Project Name: West '_c ke Stormwater Project Number:

Send Report To: Paul i~osasco / EMSI Sampler (Print Name):~;;"'

Address: Sampler (Print Name): Jl1dr;,e rJpJ/ly,, Shipment Method: FedEx

Airbill Number: /f 2s ;25])5' 9 Ut Phone: Laboratory Receiving:

Fax:

Eberline Services 601 Scarboro Road Oak Ridge, TN 37830 (865) 481-0683 Phone O (865) 483-4621 Fax

2JEBERLINE ~ SERVICES

PagELf__ot_f_

18-06097 REC'D JUN 2 1 2018

Purchase Order·~·----------

. Sample- Sample .... Sample .. -Number of I Comments, Special Lab Sample ID Field Sarn~:le ID Date Time Matrix Containers Instructions, etc. (to be completed by lab)

l,{ - / - (JfY1 / D,,-...:1-f~II 001 D I S / DOO fA t.Ars ;2. I

Note: Level 4 reoc.'-'-;r..,,_t _._,fo""'r....,s""a!.!..!..!.1=-"-'=1--'--"'""""--'"""'"'"-""-"'=~'-'-=,,....,_ Level 2 report required (combine

__ ;___ __ --+---'---+--'---'----+---=------+---+--'-+---+-..:i----+---+-+----+---+----'--+--

Relinquished by: (Signatur3) Date: Time: Sample Custodian Remarks (Completed By Laboratory): tc~ ,' r& r t?-cv ONQC Level I Turnaround I Sample Receipt ·:- -~ ' ,i¼Tinquished by: (Signature,) Time:

;,!/ /"' f J,l/'HTJJ'1'.'TI O 9 Ii) r 3) ~eceivedaiy: (Signafifre) Date: Time:

Total # Containers Received? ~.,.,

Level I D Routine D COC Seals Present? Leve! !I D 24 Hour D COG Seals Intact? Level Ill D 1 Week D Received Containers Intact? Other D Other ___

Temperature?

0006

EBERLINE

Oak Ridge Laboratory

Internal Chain of Custody

Comments

SAMPLE IS DISSOLVED

Location (circle one)

Received by ~ Rough Prep Prep Separations

Relinquished by Sample Storage Rough Prep Separations

Received by Sample Storage Rough Prep Prep ~ Relinquished by Sample Storage Rough Prep Prep Gmi;ations

Received by Sample Storage Rough Prep Prep Separations

Relinquished by Sample Storage Rough Prep Prep Separations

/"~

Received by fiimple Storag,:,) Rough Prep Prep Separations

~. / .. ____,, Relinquished by Sample Storage Rough Prep Prep Separations







Work Order#

Lab Deadline

Analysis

Sample Matrix i

Sample Fraction

04

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

18-06097 7/11/2018

UUISO - Level 4 Water

i

HP 210 / 270 Storage Detector Activity : Location

30 RRl.4

o--c» _,.,,t:tl '-9--tf (17lV

'¥% ~ '?✓Jb1 ~ o7~vl ,~r 1(10/18 o'·fL/) \(J;) J-/w ,,:---, \'Z}1

Printed: 6/21/2018 12:55 PM

0007

. ~EBER~~'~:;~ · Oak Ridge Laboratory


Comments

SAMPLE IS DISSOLVED

Location (circle one



Received by Sample Storage Rough Prep Prep ~rations "

Relinquished by Sample Storage Rough Prep Prep ~aration;r



Received by s;i~~

"'-·----···•··· Rough Prep Prep Separations








Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

Count Room

Count Room

-~

~ Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

'

18-06097 7/11/2018

ThlSO - Level 4 Water

HP 210 / 270 Storage Detector Activity , Location

30 RRl.4

'

~i? -9-1,k' ,-~~7✓11J1~ ,S]ttv(

~ 'f({Jl>/1~ 6ft5 i ,. .....

\ \:;},~

Printed: 6/21/2018 12:55 PM

0008

EBERLINE ~3EHVl(.::e:_s



Comments

SAMPLE IS DISSOLVED

Location circle one)



Received by Sample Storage Rough Prep ~a~ions




Received by ele~orag;) Rough Prep Prep Separations

--~ Relinquished by Sample Storage Rough Prep Prep Separations







Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

:

I

i

Ra226 ~ Level 4 Water

HP 210 / 270 Storage Detector Activity Location

30 RR1.4

:

ll0 01¼':t

tB 115'5' ·+\ct ,~y 13~

+le y 1'1'V

Printed; 6/21/2018 12:55 PM

0009

( . EBERLINE -~ ,c;EPYICE!::,

·· Oak Ridge Laboratory


Comments

SAMPLE IS DISSOLVED

Location (circle one



Received by Sample Storage Rough Prep Se~s

Relinquished by Sample Storage Rough Prep Prep s_wefrafions ..__



Received by Sample Storage Rough Prep Prep ~ans

Relinquished by Sample Storage Rough Prep Prep S~ns







Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

i

!

18-06097 7/11/2018

Ra228 - Level 4 Water

HP 210 / 270 Storage Detector Activity ; Location

30 RRl.4

Date

D::) tiS'

\;~:;-

\(j) '"tlO\ k~ l'3<s~

'i:J ·:/ )g It 9 {}{)

~rt, 7 {tu ( IB (:J4.:J'f::~

:Jl ') -~' _,,

\(/J 1'11$1:?

·::J-,c-~

Printed: 6/21/2018 12:55 PM

0010

. . ~EBER~~.i~:~ · Oak Ridge Laboratory


Comments

SAMPLE IS DISSOLVED

Location (circle one)





Received by e Rough Prep Prep Separations










Work Order#

Lab Deadline

Analysis

Sample Matrix

Sample Fraction

04

Count Room

Count R~ ~ci~ •~ ( .• l

Ce> ~m --Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

Count Room

18-06097 7/11/2018

GaGbT ThSr - Level 4 Water

: I

I HP 210 / 270 Storage : . Detector Activity i Location

j 30 RRl.4

i I

I

Initials Date

A ...... cteiOJ\! Lf fl :J:4 v. ·1-)0; ;l Uh 1{ {,~ \ ~\ l <--i6<

v ~1,/11/t 9) oq fj ~

I

I

Printed: 6/21/2018 12:55 PM

0011

Printed: 6/21/2018 12:07 PM

~ Sample Receiving Report EBER~~~~,~ (Volumes, pH, & CPM)

FR ClientID # Btls Comments Matrix 01 LCS 0 WA

02 BLANK 0 WA

03 DUP 0 WA

04 OU-1-007 Outfall 007 DIS 2 WA Container Number DH Oria

1 7 2 7

Received by: ___ t ___ ·-_l b __ L,L,_·_·~---,-"'· 1--,.. ____ _

Page 1 of 1

Internal Work Order

Storage RRl.4

RRl.4

RRl.4

RR1.4 DH Final

7 7

..

18-06097 Received By

RSPENCER

Rec Vol Ttl CPM Max

7.52 30 Volume Ill CPM

3.7600 26 3.7600 30

MP-001, Rev 5 Effective: 11 /22/02

0012

SECTION II

SAMPLE ACKNOWLEDGEMENT

0013

Client Name Contract/PO Project Type Date Received Required Turnaround Days .. . ... AMO Environmental Decisions WESTLAKE Environmental 06/21/2018 28 18-06097

Project Name Client WO Sample Disp Lab Deadline Internal Deadline I .• •

WESTLAKE WL STORMWATER w 07/11/2018 07/18/2018 07/19/2018 f- <D a:, 0 0

Internal ID Client ID .0 N N U) U) , ~ Sample Date Matrix Storage ('.) N N

"' "' "' .c :5 ('.) 0:: 0:: f-- ::J

01 LCS 06/21/18 WA RRl.4 X X X X X 5

02 BLANK 06/21/18 WA RRl.4 X X X X X 5

03 DUP 06/21/18 WA RRl.4 X X X X X 5

04 OU-1-007 Outfall 007 DIS 06/20/18 10:00 WA RRl.4 X X X X X 5

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Totals Per Analysis (non QA samples) 1 1 1 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Invoice West Lake Landfill OU-1 Resp Report Data Paul Rosasco. P E

~ AMO Environmental Dec1s1ons Eng. Management Support. Inc

Oak Ridge Laboratory PO Box 410 7220 W Jefferson Ave. Suite 406

601 Scarboro Rd. Oanboro. PA 18916 Lakewood. CO 80235 EBER~INE Oak Ridge, TN 37830 ~ERV ICES

Voice 215-230-8282 Voice 303-940-3426

Sample Log In Report Voice: (865) 481-0683 Fax 215-230-8283 Fax

Fax: (865) 483-4621 Contact Marsha Joseph

Voice 865-675-3669

Fax 865-675-3677

Printed 6/2112018 12 55 PM

0014

STANDARD OPERATING PROCEDURE

Sample Receiving

Eberline Services - Oak Ridge Laboratory

SAMPLE RECEIPT CHECKLIST MP-001-2

WORKORDER#_1_8_-_Q_6_O_9_7 __

MP-001, Rev. 19 Effective. 2/11/18

Page 13 of 15

SAMPLE MATRIX/MATRICES: (CIRCLE ONE OR BOTH)

~ NON-AQUEOUS

(CIRCLE EITHER YES, NO, ORN/A)

WERE SAMPLES·

Received in good condition? cry·") N

If aqueous, properly preserved (~) N N/A

WERE CHAIN OF CUSTODY SEALS:

Present on outside of package? C /''J", y) N

Unbroken on outside of package? C y:) ~----- N

Present on samples? ( TI N

( V '0 Unbroken on samples?

y \ N -/ -·

Was chain of custody present upon sample receipt? ( y ') N ~

IF THE RESPONSE TO ANY OF THE ABOVE IS NO, A DISCREPANT SAMPLE RECEIPT REPORT

(DSR) HAS BEEN ISSUED.

REMARKS: _____________________________ _

SIGNATURE: --~£__·~· ·~(_C_>c...v~"'~· (::_::...> ✓-'~------· --- DATE: __ lQ--=--+-'-(;;u..-<-+-l ...... l_[_' _· --

Copy No. ___ _ Radiochemistry Services

0015

SECTION III

CASE NARRATIVE

0016

BERLINE

EBS-OR-44023

July 23, 2018

Paul Rosasco

SERVICES

Engineering Management Suppmt, Inc. 7220 W. Jefferson Ave., Suite 406 Lakewood, CO 8023 5

SAMPLE RECEIPT

CASE NARRATIVE Work Order# 18-06097-OR

EBERLINE ANALYTICAL CORPORATION

601 SCARBOFlO F~OAD

OAK RIDGE. TEf'-lNESSEE 37850

PHONE (865) 481-0663

FAX (865) !~83-·L,621

This work order contains one water sample received 06/21/2018. Sample was analyzed as dissolved for Isotopic Uranium, Isotopic Thorium, Radium-226/228 and Gross Alpha/Beta.

CLIENT ID

OU- 1-007 Outfall 007 DIS

ANALYTICAL METHODS

LAB ID

18-06097-04

Isotopic Uranium was analyzed using EPA Method 908.0 Modified. Isotopic Thorium was analyzed using EPA Method 907.0 Modified. Radium-226 was analyzed using EPA Method 903.0 Modified. Radium-

228 was analyzed using EPA Method 904.0. Gross Alpha/Beta was performed using EPA Method 900.0

Modified.

ANALYTICAL RESULTS

Combined Standard Unce1tainty is repo1ted at I-sigma value.

Minimum Detectable Activity (MDA) values for data represented in this repmt are sample-specific.

MDA measurements are dete1mined based on factors and conditions including instrument settings, aliquot size and matrix type.

SPECIAL CIRCUMSTANCES

Samples were filtered through 0.45 µm media to dissociate the suspended fraction from the dissolved

fraction. After filtration, samples were preserved with nitric acid to a pH of <2.0. Results for this work order are all from the dissolved fraction.

Page 1 of 3

0017

ANALYTICAL RES UL TS CONTINUED

ISOTOPIC URANIUM

Sample was prepared by removing a representative aliquot followed by mixed acid digestions as

appropriate. Uranium was selectively extracted by ion exchange. Uranium was eluted, micro-precipitated

and mounted on micro-porous filter media. Sample activities were then determined by alpha spectroscopy

using energy specific regions of interest for Uranium-234, Uranium-235 and Uranium-238. Chemical recovery was determined by the use of a Uranium-232 tracer. Activity of the Uranium-232 tracer was

determined by alpha spectroscopy using an energy specific region of interest.

Sample demonstrated acceptable results for all Uranium analyses. Total Uranium results were calculated

by mass conversion of Isotopic Uranium activity. Chemical recovery was acceptable for all samples. The Uranium-234, Uranium-235 and Uranium-238 method blank demonstrated acceptable results. Results for

the Uranium-234, Uranium-235 and Uranium-238 duplicate demonstrated a high relative percent difference; however, normalized difference is within acceptable limits for the analytical technique.

Results for the Uranium-234 and Uranium-238 laboratory control sample demonstrated an acceptable

percent recovery.

ISOTOPIC THORIUM

Sample was prepared by removing representative aliquots followed by mixed acid digestions as appropriate. Thorium was selectively extracted by ion exchange. Thorium was eluted, micro-precipitated and mounted on micro-porous filter media. Sample activities were then determined by alpha spectroscopy using energy specific regions of interest for Thorium-230 and Thorium-232. Chemical recovery was

determined by the use of a Thorium-229 tracer. Activity of the Thorium-229 tracer was determined by

alpha spectroscopy using an energy specific region of interest.

Sample demonstrated acceptable results for all Thorium-230 and Thorium-232 analyses. Chemical

recovery was acceptable for all samples. The Thorium-230 and Thorium-232 method blank demonstrated

acceptable results. Results for the Thorium-232 duplicate demonstrated a high relative percent difference;

however, normalized difference is within acceptable limits for the analytical technique. Results for

Thorium-230 duplicate demonstrated an acceptable relative percent difference and normalized difference. Results for the Thorium-230 and Thorium-232 laboratory control sample demonstrated an acceptable

percent recovery.

RADIUM-226

Sample was prepared by removing a representative aliquot followed by mixed acid digestions as

appropriate. This was followed by precipitations of Radium/Barium Sulfate. Precipitates were dissolved in alkaline EDTA. Radium was selectively precipitated and then mounted on micro-porous filter media. Sample was counted by alpha spectroscopy using an energy specific region of interest for Radium-226. Inherent self-absorption from elemental Barium was corrected for in the final result. Chemical recovery was calculated by the use of a Barium-133 tracer, which was determined by HPGe gamma spectroscopy.

Sample demonstrated acceptable results for all Radium-226 analyses. Chemical recovery was acceptable

for all samples. The Radium-226 method blank demonstrated an acceptable result. Results for the

Radium-226 duplicate demonstrated a high relative percent difference; however, normalized difference is

within acceptable limits for the analytical technique. Results for the Radium-226 laboratory control

sample demonstrated an acceptable percent recovery.

Page 2 of 3

0018

c--------

ANALYTICAL RESULTS CONTINUED

RADIUM-228

Following alpha spectroscopy analysis of Radium-226, Barium/Radium Sulfate precipitates were

redissolved and allowed for sufficient ingrowth of the Actinium-228 daughter. After ingrowth, Actinium-

228 was selectively precipitated. Precipitates were filtered and beta emissions for Actinium-228 were then

counted on a gas prop011ional counter. Chemical recovery was determined by the use of a Barium-133

tracer, the activity of which was determined by HPGe gamma spectroscopy and an elemental Yttrium

carrier by gravimetric measurements. The product of these two recoveries was used to calculate chemical

yield.

Sample demonstrated acceptable results for all Radium-228 analyses. Chemical recovery was acceptable

for all samples. The Radium-228 method blank demonstrated an acceptable result. Results for the

Radium-228 duplicate demonstrated a high relative percent difference; however, normalized difference is

within acceptable limits for the analytical technique. Results for the Radium-228 laboratory control

sample demonstrated an acceptable percent recovery.

GROSS ALPHA & BETA

Sample was prepared by evaporation of a representative volumetric aliquot acidified with HNO3.

Reduced sample was then transferred to a steel planchet for final evaporation to dryness and flaming.

Sample was then counted on a gas proportional counter. Results were corrected as required for inherent

self-absorption based on residual mass present.

Sample demonstrated acceptable results for all Gross Alpha and Beta analyses. Due to the high Total

Dissolved Solids content within the sample, method detection limits are slightly high. The Gross Alpha

and Beta method blank demonstrated acceptable results. Results for the Gross Alpha and Beta duplicate

demonstrated a high relative percent difference; however, normalized difference is within acceptable

limits for the analytical technique. Results for the Gross Alpha and Beta laboratory control sample

demonstrated an acceptable percent recovery.

CERTIFICATION OF ACCURACY

I ce11ify that this data repo11 is in compliance with the terms and conditions of the Purchase Order, both

technically and for completeness, for other than the conditions detailed above. Release of the data

contained in this hard copy data package has been authorized by the cognizant project manager or his/her

M.R.McD~ll I Laboratory Manager 1

i Date: 7/23/2018

l'bcrlinc /\nalylical wunts and encourages your feedback regarding our performance providing radiounalylical services. Pkasc

visi1 http://eberlincanalytical.com/ to provide us wilh feedback on our services.

Page 3 of3

0019

SECTION IV

ANALYTICAL RESULTS SUMMARY

0020

Printed: 7/23/2018 9:07 AM

Eberline Analytical Final Report of Analysis

Lab ID

18-06097-01

18-06097-01

18-06097-02

18-06097-03

18-06097-04

18-06097-01

Sample Type

LCS

LCS

MBL

LCS

18-06097-01 LCS

18-06097-02 MBL

18-06097 -03

18-06097-04

18·06097-01

18-06097 •01

18-06097-02

18-06097 •03

18-06097 -04

LCS

LCS

MBL

LCS

KNOWN

SPIKE

BLANK

Client ID

OU-1-007 Outfall 007 DIS


KNOWN

SPIKE

BLANK



KNOWN

SPIKE

BLANK

OU·1-007 Outfall 007 DIS


18-06097-01

18-06097-01

18-06097-02

········----···-·•--s-••··-KNOWN

SPIKE

18-06097-03

18-06097-04

18-06097-01

18-06097-01

18-06097-02

18-06097-03

18-06097-04

18-06097-01

18-06097-01

18-06097-02

18-06097-03

18-06097-04

LCS

MBL

LCS

LCS

MBL

DUP

DO

LCS

LCS

MBL

DUP

DO

BLANK ................. -•-············



KNOWN

SPIKE

BLANK



KNOWN

SPIKE

BLANK



Report To:

Paul Rosasco, P.E.

Eng: ManagE!n:1~11! ~l_lP.PC>_!t,_ Inc ... 7220 W. Jefferson AvE!., ... ~llite .. 406 Lakewood, CO 80235

Sample Date

06/21 /18 00:00

06/21/1800 00

06/21/18 00:00

06/20/18 10:00

06/20/18 10:00

06/21/18 00:00

06/21/18 00:00

06/21/18 00:00

06/20/18 10:00

06/20/18 10:00

06/21118 00:00

06/20/18 10:00

06/20/18 10:00

06/21/18 00:00

06/21/18 00:00

Receipt Analysis Batch Date Date ID

6/21/2018 7/11/2018 18-06097

6/21/2018 7/11/2018 18-06097

6/21/2018 7/11/2018 18-06097

6/21/2018 7/11/2018 18-06097

6/21/2018 7/11/2018 . 18-06097

Analyte

Gross Alpha

Gross Alpha

6/21/2018 7/11/2018 18-06097 Gross Beta

6/21/2018 7/11/2018 18-06097 Gross Beta

6/21/2018 7/11/2018 18-06097 Gross Beta ,~,~~•~•-- ~•----v~~m,_

6/21/2018 7/11/2018 18-06097 Gross Beta - __ ,,-,, ,.__,,.,_ ,,,,,,, ___ ...,,.,._~_,~,m 6/21/2018

6/21/2018 7/9/2018

6/21/2018 7/9/2018 18-06097 Radium-226

6/21/2018 7/9/2018 18-06097 Radium-226 ······-··-·----········· .--1 ....

6/21/2018 7/10/2018 18-06097 Radium-228 •• o~~~w ~-•~mmw, """

6/21/2018 7/10/2018 . 18-06097 .Radium-228 +-· 06/21/18 00:00 6/21/2018 7/10/2018 18-06097 Radium-228

06/20/18 10:00 6/21/2018 7/10/2018 · 18-06097 Radium-228

06/20/18 10:00 6/21/2018 7/10/2018 18-06097 Radium-228

06/21/18 00:00

06/21 /18 00:00

06/21/18 00:00

06/20/18 10:00

06/20/18 10:00

06/21/18 00:00

06/21/18 00:00

06/21/18 00:00

06/20/18 10:00

06/20/18 10:00

6/21/2018 7/10/2018 18-06097 Thorium-230

6/21/2018 7/10/2018 18-06097 Thorium-230

6/21/2018 7/10/2018 18-06097 Thorium-230

6/21/2018 7/10/2018 18-06097 Thorium-230

6/21/2018 7/10/2018 18-06097 Thorium-230

6/21/2018 7/10/2018 18-06097 Thorium-232

6/21/2018 7/10/2018 18-06097 Thorium-232

6/21/2018 7/10/2018 18-06097 Thorium-232

6/21/2018 7/10/2018 18-06097 Thorium-232

6/21/2018 7/10/2018 18-06097 Thorium-232

SDG:

P_rojec_t: Analysis Category·

Sample Matrix:

Method

EPA 900.0 Modified

EPA 900.0 Modified

Work Order Details·

18-06097 WESTLAKE ENVIRONMENTAL WA

Result cu CSU

2.71 E+02

2.97E+02

1.16E+01

3.77E+00 3.26E+01

MDA

2.39E-01

Page 1 of 2

CV

9.99E-01

Report Units

pCifl

EPA 900.0 Modified 2.77E+02 8.32E+00 --~-s-••··-··-•--'"•····---s-----··········--· ----·········

2.62E+02 2.95E+00 3.63E+01 5.04E-01 1.15E+00 pCi/1

-1.28E-01 2.72E-01 2.73E-01 5.96E-01 1.52E+00 pCi/1 ···············-···········•··························s··-······· EPA 900.0 Modified 2.91 E+00 5.26E+00 5.27E+00 1.08E+01 2.40E+01

EPA 900.0 Modified 1.14E+01 5.14E+00 5.37E+00 9.83E+00 2.29E+01 pCifl

EPA 904.0

EPA 904.0

EPA 904.0

EPA 907.0 Modified

EPA 907.0 Modified

1.37E+00 2.53E+00 2.87E-01 -,~--~- __ , ____ ~-~ ''-----·--·~-

1.05E-01 1.06E-01 3.70E-01 3.46E-02 pCi/1

4.69E-01

7.52E-01

3.09E-01 3.78E-01 4.17E-02

2.14E-01 4.06E·01 3.85E-02

2.09E+00 8.66E-01 8.83E-02

pCi/1

pCi/1

~----,,~---------

pCi/1

pCi/1

pCi/1 4.48E-01 4.27E-01 4.39E-01 8.63E-01 9.19E-02 ······-··-·····-·•············------·--·

8.70E-01 4.99E-01 5.37E-01 9.81 E-01

4.12E-01 4.12E-01 8.71E-01

1.45E-01

1.31E+00 1.55E+00 1.53E-01 '------------ -~---- ,_,,, _____ ,,, ____ ,,,,,,,,,_, __ , ___ _ 6.63E-02 6.66E-02 1.04E-01 9.47E-02 pCifl ·-· --------~~-- ""' "" ,,,, ___ , __ 8.88E-02 9.07E-02 5.26E-02

.. ___ ,,,,_,__ ----~-·-1.73E-01

4.87E+00

1.90E-02

1.08E-01 1.1 0E-01 9.65E-02 9.16E-02 pCi/1

1.75E-01

1.18E+00 1..28E+00 1.44E-01 ---,,~---·-·---- ---

5.37E-02 5.38E-02 8.76E-02

4.38E-02

5.21 E-02

4.38E-02 7.09E-02

5.21E-02 1.07E-01

pCifl

2.00E-02 pCi/1

1.72E-02

9.85E-03

2.64E-02

pCi/1

pCi/1

pCi/1

CU=Counting Uncertainty;CSU=Combined Standard Uncertainty (1-sigma);MDA=Minimal Detected Activity;LCS=Laboratory Control Sample; MBL=Blank; DUP=Duplicate; TRG=Normal Sample; DO=Duplicate Original; CV=Critical Value

( EBERLINE ~ -


601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621

0021

Printed: 7/23/2018 9:07 AM Page 2 of 2

Report To· Work Order Details:

Eberline Analytical Paul Rosasco, P.E. SDG: 18-06097 ~11JI.:llll-a,_11~g~!l!ent Support, Inc. P,:oLect: WESTLAKE

Final Report of Analysis 7220 W. Jefferso11_Ave,_~llite 406 Anatys_is_~ategory. ENVIRONMENTAL . .. ,_,

Lakewood, CO 80235 Sample Matrix: WA Lab Sample Client Sample Receipt Analysis Batch Report

ID Type ID Date Date Date ID Analyte Method Result cu CSU MDA CV

Units

18-06097-02 MBL BLANK 06/21/18 00:00 6/21/2018 7/10/2018 18-06097 Total Uranium EPA 908.0 Modified 1.90E-01 1.90E-01 3.00E-01 1.54E-02 ug/I ,,_, __

18-06097-03 DUP OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 4.65E-01 4.70E-01 4.46E-01 2.05E-02 ug/I

18-06097-04 DO OU-1-007 Outfall 007 DIS 06/20/18 10:00 2.75E-01 2.94E-01 "--~"'-,,~--, "-' ,,, ________ ,,,. -"'"' '""'"·----

18-06097-01 pCin

""•"'~,,-,,~,,

18-06097-01 LCS SPIKE 06/21/18 00:00 6/21/2018 9.05E-01 7.77E-02 1.47E-02 pCin .--~---- ''" ---~,~--

18-06097-02 MBL BLANK 06/21 /18 00:00 6/21/2018 7/10/2018 7.36E-02 8.90E-02 2.13E-02 pCin

18-06097-03 DUP OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 7/10/2018 1.52E-01 1.32E-01 2.95E-02 p """'"'-·-·-·-·-~-•--· .. e"-''"' ---------,-~•-•<- '""'"-"'-----·--·- .. ---~-~-

18-06097-04 DO OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 7/10/2018 18-06097 1.18E-01 1.19E-01 1.17E-01

18-06097-01 LCS SPIKE 06/21 /18 00:00 6/21/2018 7/10/2018 18-06097 Uranium-235 1.77E-01 1.80E-01 6.68E-02

18-06097-02 MBL BLANK 4.63E-02 1.01E-01 1.49E-02 pCin ,,,,,,,, __ ,,,,, "--·--,,,,

18-06097-03 DUP OU-1-007 Outfall 007 DIS 1.21E-01 1.21E-01 1.56E-01 2.31E-02 --~--------··--~ ··~"'""'" __ ,,,,,,,,,,,,._

18-06097-04 DO OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 7/10/2018 18-06097 Uranium-235 4.02E-02 4.03E-02 8.44E-02 4.92E-03

18-06097-01 LCS KNOWN 06/21/18 00:00 6/21/2018 7/10/2018 18-06097

18-06097-01 LCS SPIKE 06/21/18 00:00 6/21/2018 7/10/2018 18-06097 9.18E-01 -----~--·---- .,,,_,,,,,_ __ "'""•-----~•-•_,,,,,,,,,,_

18-06097-02 MBL BLANK 06/21/18 00:00 6/21/2018 7/10/2018 18-06097 Uranium-238 EPA 908.0 Modified 6.22E-02 6.33E-02 6.35E-02 8.52E-02 1.83E-02 pCin

--·-------- ,,,,, .. --·-------

18-06097-03 DUP OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 1.55E-01 1.56E-01 1.26E-01 -•-•-•-~=•~-vn-•-~•-""'"-,,,,,=• --•-""'"" ---·-·-

__ ,,_, ________

18-06097-04 DO OU-1-007 Outfall 007 DIS 06/20/18 10:00 6/21/2018 9.17E-02 9.21E-02 8.57E-02 1.20E-02 pCi/I

CU:Counting Uncertainty;CSU:Combined Standard Uncertainty (1-sigma);MDA:Minimal Detected Activity;LCS:Laboratory Control Sample; MBL:Blank; DUP:Duplicate; TRG:Normal Sample; DO:Duplicate Original; CV:Critical Value

( . EBERLINE M> ANALYTICAL


601 SCARBORO ROAD OAK RIDGE, TN 37830 865/481-0683 FAX 865/483-4621

0022

SECTION V

ANALYTICAL STANDARD

0023

..__, ·-·

QA/QC REVIEWED CERTIFICATE OF CALIBRATION L,L-8

Date '7 q(lnitials J![_ ALPHA STANDARD SOLUTION Radionuclide: U-238NAT

Half Life:

Customer:

P.O.No.:

TMA EBERLINE

OR2778

Catalog No.:

(4.468 ± 0.005) x 10~9 years

7338 Reference Date: January 1 1995 12:00 PST.

Source No.: 479-50 Contained Radioactivity: (Total U) 8.016 µ.Ci

Contained Radioactivity: (fotal U) 297 kBq

Description of Solution a. Mass of solution:

b. Chemical form:

65. 2896 g in a 50 ml flame sealed ampoule

Uranyl Nitrate in H20

c. Carrier content: None

d. Density: Approximately I.3202

Radioimpurities

Radioactive Daughters

Refer to attached technical data sheet

Refer to attached technical data sheet

Radionuclide Concentration

(Total U) 0.1228 Method of Calibration

Activity calculations are based upon known specific activity and mass.

Uncertainty of Measurement a. Systematic uncertainty in instrument calibration:

b. Random uncertainty in assay:

c. Random uncertainty in weighing(s):

d. Total uncertainty at the 99 % confidence level:

NIST Traceability

±3.0%

±0,0%

±2,0%

±3,6%

•

g/ml @20°c.

µCi/g.

This calibration is implicitly traceable to the National Institute of Standards and Technology.

Leak Test(s)

See reverse side for Leak Test(s) applied to this source.

Notes

1. Nuclear data were taken from "Table of Radioactive Isotopes•, edited by Virginia S. Shirley, 1986.

2. IPL participates in an NIST measurement assurance program to l!otablish and maintain implicit traceability for a number of nuclidcs,

based on the blind assay (and later NIST certification) of Standard Reference Materials (As in NRC Regulatory Guide 4. 15).

E=(t(vAu,.A_2 YCONfROL

·· ... ·.·1·· · .. ~. \.•· .. ·:··· .. ·'.···•·:· .. \; ... ·.··.··.··• .. · .. t7J?'. . .

. · .. ·. · .. ·.

: . '-.:.: .. ·-·:.

ISOTOPE PRODUCTS LABORATORIES

3017 N, SAN FERNANDO BLVD.

~ Oet,€r,,1hz{k I f?:2f Date Signed

l ·s. 0 T O P I,

·rROD.UCT.S

l,ABCJRATORIES·:

BURBANK, CALIFORNIA 91504

8]8•843•7000 FAX 818•843•6168

0024

Rev.a; 11101103

QUALITY CONTROL PROGRAM MP-009

Title: Radioactive Refere11ce Sta11dards Solutions & Records

EBERLINE SERVICES* OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICATION

MP 009

CURRENT DATE 7/6/2018 0:00 SOLUTION REFERENCE #....,IP...,L ..... 4_7__,9...,-5,,,,.0,.,...: -----.------, SOLUTION #1-----,U..,....S._--,.,-1

Princi al Radionuclide 234, s, 238u

Radionuclide

Half Life, Years 1 · 4.468E+09j

------1 Certified Activity 8;0}61::+00 µCi Certified Concentration...__ ___ __,µCi per gram

Ampoule /Solution Gross Empty Ampoule

Solution Net Total Activity in Ampoule

Chemical Composition of Standard Solution I Uranyl nitrate in diluteHNO3. · ·

Half Life, Days l 1,632E+12I

Reference Date!,_ __ 1_/1'--/_19_9_5_0_:0__.o!

97.6400 Weight, Grams 32;$020 Weight, Grams 65.1380 Weight, Grams

8.0160 µCi

Dilution Instructions: Dilution Solvent Used l1MHN03,

Dilute to a volume of! ·· · 1000~00 ·. jmilliliters

Certified Total Activity of! 8.016DjµCi Which Equals 1.780E+07ldpm at the date listed above

This activity concentration is based on the original And after dilution the activity of this solution isl 1. 77955E+04ldpm/m~eforence date listed above. Ail activities am corrected

to the date and time of analysis by the laboratory dai.a processing software.

Expiration Date: I June 26, 2019

Date; 7/6/2018 0:00 --------Date: J i&-J,,c: ----'-1,.......,.,-.~--

0025

Rev.8; 11101/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES ~ OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY Dil.UTJON RECERTIFICATION

MP-009 Solution Reference# JPL479,50

Princi al Radionuclide 234. i35. 238u

Radionuclide of Interest 234• 235

· 238u

Half Life, Years I 4.468E+oel

Parent Solution Cone. 1.7796E+04 dpm/ml

Date 7/6/2018 0:00 Solution # . U-8a

Half Life, Days I 1.632E+12I

Reference Datel._ _ _;....;· 1 .... 11"'°'·11;..,.;e....;.9.;;..5-"'o;a.;;.OO_.!

Chemical Com osition of Standard Solution Uranly Nitrate in 1M HNO3 ·

Dilution Instructions: Dilution Solvent Used

SECONDARY VOLUMETRIC DILUTION

Vol. Parent Solution: Total Activity: Final Volume:

NOTES:

4.0000 ml 7.1182E+04 dpm

1000.00 ml Final Activity Concentration: I 7. 1182E+01 jdpm/ml

This activity concentration is based on the original reference date listed above. All activities are corrected to the date and tirne of analysis by the laboratory data processing software. ------------------------, Isotopic Distribution as:

U-238 Atom%= 48.239 U-235 Atom % = 2.25 U-234 Atom % ,, 49.501 All values +/- 3.6%

U-238 == 71.182 dpm/ml X 0.48249 = 34.345 dpm/ml U-235 = 71.182 dpm/ml X 0.0225 = 1.602 dpm/ml U-238 = 71.182 dpm/ml X 0.49501 = 35.236 dpm/ml

Isotopic ratios from manufacturer's data sheet ....--....._

9 Expiration Date:f June 26, 2011

Date: 7/6/2018 0:00 _____ ;..._.:..:.;;,_

Date: __ ~--1(-'-'-'+-/__,?.....___

0026

RECORD COPY

Tracer Solution for Environ1nental Analysis & Disequilibrium Studies

Description

Product Description & Measurement Certificate

Principal radionuclide: Daughter Nuclide:

uranium 232 (U-232) Th-228

Product code: UDPl 0050 Batch Number: 92/232/67

Measurement Reference date: 01 March 2000

Accuracy

Radionuclidic Purity

Isotopic Purity

Chemical Composition

Physical Data

Remarks

Approved Signatory

Radioactive concentration U-232 which is equivalent to

6.739E+o3 becquerels per gram of solution 1.821E-01 microcuries per gram of solution

Volume of solution Total activity ofU-232

which is equivalent to

5.035 millilitres 3.61E+o4 becquerels 9. 76E-O 1 microcuries

Method of measurement (see reverse of this certificate) Random uncertainty is:± 0.7% Systematic uncertainty:± 0.5% Overall uncertainty in the radioactive concentration quoted above: ± 1.7% Overall uncertainty is defined on the reverse of this certificate.

Any radioactive impurities measured are listed below, expressed as percentages of the activity of the principle radionuclide at the referenc•e date.

Th-228 and daughter activity removed 2 Feb 2000 U-232 daughters activity will increase with time. By alpha 88% U-232, 12% daughters on l/3/00

""he isotopic composition, exprP,Ssed as atom per cent at the reference date .

i'Jot measured

Calculated weight ofU-232, 4.42E-08 grams, as 2M HNO3 solution in a flame sealed glass vial. This Tracer solution has been produced 'carrier free'.

Recommended halflifo of uranium 232: 6.980E+Ol years Principle energies of alpha emissions (MeV): 5.263 31.7%, 5.320 68.0% Branching ratio for alpha emission: 100% Calculated specific activity of uranium 232: 8.167E+o5 Bq per microgram U-232.

For safety information and notes to ensure correct usage by all persons handling this radior1ctive Tracer solution please read the instructions accompanying the package.

AEA Technology operates a quality management system which has been independently audited and approved to ISO 9001.

Project Ref. AE23 l 5

Roger Wiltshi.re

Prepared and characterised .in the UK, for world wide distribution by Isotrak, AEA Technology, QSA.

Trkcert.wps I 0/03/00 AEA Techn,;logy is the trading name of AEA Technology pJc

0027

1(EBER~~"~~ Rev.a; 11/01/03


Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICATION

MP009

.----------,CURRENTDATEt--I __ 10~/7~/~20_1_7_0_:0---10I SOLUTION REFERENCE# AENAmersham 92/232/67 I SOLUTION #I U-10 I

Principal Radionuclide 232u I

Half Life, Years

I· 7.200E+01 I Half Life, Days I 2.630E+04I

Radionuclide 232U Reference Date ._I ___ 3/_1_/2_0_00_0:_0_,0 I

Certified Activity 9. 760E-01 µCi Certified Concentration · µCi per gram ....__ ___ ....

Ampoule /Solution Gross~Weight, Grams Empty Ampoule Weight, Grams

Solution Net Weight, Grams Total Activity in Ampoule 0.9760 µCi

Chemical Composition of Standard Solution


Dilute to a volume ofl 1000.00 !milliliters

Certified Total Activity ofl 0.9760lµCi Which Eauals I 2.167E+06ldpm at the date listed above

And after'dilution the activity of this· solution isl 2.167E+03ldp'm/ml This activity concentration is based on the original reference date listed above. All activities are corrected to tl1e date and time of analysis by the laboratory data processing software.

Expiration Date:! October 4, 2018 I

Date: 10/7/2017 0:00

Date:

--------/0 /✓0/,·7

I I

0028

Rev.8; 11/01/03

QUALITY CONTROL PROGRAM . MP-009

Title; Radioactive Reference Standards Solutions & Records

EBERUNE SERVICES - OAK RIDGE LABORATORY · RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION RECERTIFICATION

MP-009 Date f--__ 1_0/_7_/2_0_17_0:_00---1

Solution Reference # AEA/Amersham 92/232/67 Solution# U-10a

Principal Radionuclide 3 .u

Radionuclide of Interest 23 U

Half Life, Years

I 7.200E+01 j

Parent Solution Cone. 2.167E+03 dprn/rnl


Half Life, Days

I 2.630E+041

Reference Date~' ___ 3/_1_/2_0_00_0_:_oo~I



NOTES:


10.0000 ml 2.1670E+04 dpm

1000.00 ml Final Activity Concentration: I 2.1670E+01 jdpm/ml

This activity concentration is based on the original reference date listed above. All activities are · corrected to the date and time of analysis by the laboratory data processing software. ·

Expiration Date:! October 4, 2018

0029

CERTIFICATE OF CALIBRATION ALPHA STANDARD SOLUTION

Radionuclide: Th-232

Half Life: . (1.405 ± 0.006) x 10" 10 years Customer:

P.O.No.:

TMA EBERLINE

VH1632

14-B

Catalog No.: 7232

435-104-2

Reference Date: November 1 1993 12:00 PST.

Source No.: Contained Radioactivity: (Th-232) 0.0933 µCi.

Contained Radioactivity: (Th-232) 3.45 kBg.


b. Chemical form:

c. Carrier content:

11.9712 g (in a 10 ml flame sealed ampoule)

Th(N03)4 in water

None added

d. Density: Approx. 1.21 g/ml @20°C.

Radioimpurities None detected (other than daughters).

Radioactive Daughters Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Po-212, Tl-208


(Th-232) 0.00779

Method of Calibration Activity calculations are based upon known specific activity and mass.




d. Total uncertainty at the 99 % confidence level:

NIST Traceability

±3,0%

±0,0%

±2,0%

±3,6%


Leak Test(s)

See reverse side for Leak Test(s) applied to this source.

Notes

1. Nuclear data were taken from "Table of Radioactive Isotopes", edited by Virginia S. Shirley, 1986.

µCi/g.

2. IPL participates in an NIST measurement assurance program lo establish and maintain implicit traceability for a number of nuclides,

ba.ed on the blind assay (and later NIST certification) of Standard Reference Materials (As in NRC Regulatory Guide 4. 15).


1800 North Keystone Street

Burbank, California 91504

818 843 - 7000

QUALITY CONTROL

;Vw. ~.1 l 1 'l > Date Signed

0030

Rev.8; 1/10/03

QUALITY CONTROL PROGRAM MP--009


EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERT/F/CA TION

MP 009

CURRENT DATE 8/16/2017 0:00 SOLUTION REFERENCE #""IP"'""L-4.,..,3....,5....,.:.1,._.04,...:....,.2-· -----. SOLUTION #1-----.=T--h-8...,....;.'--'-'---,-1

Princi al Radionuclide 23 Th, 228Th

Half Life, Years l 1AOSE+tol

Half Life, Days l 5.132E+12!

Reference Date! L.. __ 1 ___ .1_/.1_/1_9_93_· _o:_oo .... l

Ampoule /Solution Gross 18.8415 Weight, Grams Empty Ampoule. ~ ..... 6.9296 Weight, Grams

Solution Net 11.9119 Weight, Grams Total Activity in Ampoule 0.0933 µCi


Dilution Instructions: Dilution Solvent Used . j1% NitricAcid

Dilute to a volume ofl. -1000.00 . I milliliters

Certified Total Activity ofl 0.0933lµCi Which Eauals 2.071 E+05ldpm at the date listed above

And after dilution the activity of this solution isl 2.071 E+02ldpm/ml This activity concentration is based on the original . . reference date listed above. All activities are corrected

to the date and time of analysis by the laboratory data processing software.

Expiration Date: l August 11, 2018

R/1Rl?n17 n-n0

Date: --=gj+-f_,wµ ..... C_,__J--

0031

Rev.8; 1/10/03 Title: Radioactive Reference Standards· Solutions & Records

EBERLINE SERVICES-OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS


MP-009 Solution Reference# IPL 435:::104-2

Princi al Radionuclide 2w&232Th

Radionuclide of Interest · 228 &

232Th

Half Life, Years I 1.4b5E+1ol

Parent Solution Cone. 2.07E+02 · dpm/ml


Date 8/16/2017 0:00 Solution # • ·· · Th,8b


Reference Date._l __ 1.;..;1.;../1;.;../1.;...;9...;.9.;.3.;;..0:;.;;.o.;.iol

Dilution Instructions: Dilution Solvent Used l 1 % Nitric Acid


NOTES:


· 500,0000 ml 1.0355E+05 dpm

1000.00 ml Final Activity Concentration:! 1.0355E+02jdpm/ml

This activity concentration is based on the original reference date listed above. All activities are corrected to the date and time of analysis by the laboratory data processing software.

Expiration Date:l August 11, 2018 f

Date: 8/16/2017 0:00

I

0032

RTIFICA TE OF CALIBRA Tl<>ti.t~ 99

\

LPHA ST AND ARD SOLUTION" \Jc' \ ~~t\\t\~,

Radionuclide

Half Life:

Th-230 Customer:

P.O.No.:

~~tit~ \,'?A TMA EBE~~ ~ \t,t \

Catalog No.:

(7 .54 ± 0.03) x 10"4 years

7230 TI4944 \)t\l

Reference Date: November 1 1991 12;00 PST.

Source No.: Contained Radioactivity: 1.036 µCi.


b, Chemical form:

c. Carrier content:

d. Density:

Radioimpurities

Radioactive Daughters


Method of Calibration

5.0042

Th(NO3)4 in O.lN HNO3

None added 1.0016

See attached technical data sheet

See attached technical data sheet

0.207

Weighed aliquots of the solution were assayed using a liquid scintillation counter.




d. Total uncertainty at the 99% confidence level:

NIST Traceability

±2.0%

±0,5%

±0,2%

±2,7%

grams.

gram/ml @ 20°c.

µCi/gram.

This calibration is implicitly traceable to the National Institute of Standards and Technology. Notes

1. Nuclear data were taken from "Table of Isotopes", Seventh Edition, edited by Virginia S. Shirley. 2. IPL participates in an NIST measurement assurance program to establish and maintain implicit

traceability for a number of nuclides, based on the blind assay(and later NIST certification) of Standard Reference Materials. (As in NRC Regulatory Guide 4.15)

ISOTOPE PRODUCTS LABORATORIES 1800 No. Keystone Street., Burbank, California 91504 818 843 - 7000

0033

Rev.14; 10/10/2012


Tille: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS

PRIMARY DILUTION RECERTIF/CA TION MP 009

CURRENT DATE 2/10/2018 0:00 SOLUTION REFERENCE #,...IP-L-38-8---11_6 ____ _____, SOLUTION #1---T-h---1---1

Princi al Radionuclide 230Th

Half Life, Years

I 7.540E+04l

Radionuclide 230Thorium Certified Activity 1.036E+00 µCi

Certified Concentration ...__ ___ __,µCi per gram




Half Life, Days

I 2.754E+07I

Reference Date._! __ 1_1_/1_/1_9_9_1 _0_:o__,ol

9.2660 Weight, Grams 4.6218 Weight, Grams 4.6442 Weight, Grams 1.0360 µCi


Dilute to a volume of I 1000.00 !milliliters

Certified Total Activity ofi 1.0360jµCi Which Eauals 2.300E+06ldpm at the date listed above

. • • • • . • .----------, This activity concentration is based on the original

And after d1lut1on the act1v1ty of this solution isl 2.300E+03jdpmITTtl-ence date listed above. All activities are corrected to the date and time of analysis by the laboratory data processing software.

Expiration Date: I January 10, 2019

Date: 2/10/2018 0:00 -----,----Date: '3 q;

---'-'--+="'-I-'-=;......-

0034

Rev.14; 10/10/2012



EBERLINE SERVICES - OAK RIDGE LABORATORY

RADIOACTIVE REFERENCE STANDARD SOLUTIONS SECONDARY DILUTION RECERTIFICATION

MP-009 Date! 2/10/2018 0:001

Solution Reference# IPL 388-116 I Solution #I Th-1 b I

Principal Radionuclide ,.,uTh j

Half Life, Years

I 7.540E+04I

Half Life, Days

I 2.754E+o7\

Radionuclide of Interest ,.,uThorium Reference Date!..._ __ 1_1_/1_/1_9_9_1 _0_:o~ol



Dilution Instructions:


NOTES:

Dilution Solvent Used 10.1N HN03


10.0000 ml 2.2999E+04 dpm

1000.00 ml Final Activity Concentration: I 2.2999E+01 ldpm/ml

This activity concentration is based on the original

reference date listed above. All activities are

corrected to the date and time of analysis by the

laboratory data processing software.

Expiration Date: l January 10, 2019 !

Date: 2/10/2018 0:00

Date:

-------

2, ,3/1 c;:( I

0035

-~ Isotope Products Laboratories

24937 Avenue Tibbitts Valencia, California 91355

An Eckert & Ziegler Company Tel 661•309•1010 Fax 661•257•8303

CERTIFICATE OF CALIBRATION ALPHA STANDARD SOLUTION

Radionuclide: Half-life: Catalog No.:

Th-229 7340 ± 160 years 7229

Customer: P.O.No.: Reference Date:

EBERLINE SERVICES 00009633 15-Jan-02 12:00 PST

Source No.: 867-54 Contained Radioactivity: (Th-229 only)

1.013 µCi 37.48

Physical Description: A. Mass of solution:

B. Chemical form:

5.0147 gin 5 ml flame-sealed ampoule Th(NO3)4 in 0.1 M HNO3

C. Carrier content: 10µg Th/ml D. Density: 1.0016 g/mL @ 20°c.

Radioimpurities:

None detected (daughters in equilibrium)

Radionuclide Concentration: 0.2020 µCi/g, 7.474 kBq/g

Method of Calibration:

This source was prepared from a weighed aliquot of solution whose activity in µCi/g was determined using gamma ray spectrometry. Peak energy used for integration: 193 .5 keV Branching ratio used: 0.0441 gammas per decay

Uncertainty of Measurement: A. Type A (random) uncertainty: B. Type B (systematic) uncertainty: C. Uncertainty in aliquot weighing: D. Total uncertainty at the 99% confidence level:

Notes: - See reverse side for leak test(s) performed on this source.

± 0.7 % ± 3.0 % ± 0.0 % ± 3.1 %

7Ji-, 8

kBq

- IPL participates in a NIST measurement assurance program to establish and maintain implicit traceability for a number of nuclides, based on the blind assay (and later NIST certification) of Standard Reference Materials (As in NRC Regulatory Guide 4.15).

- Nuclear data was taken from IAEA Technical Report Series No. 261. - This solution has a working life of 5 years.

QualityTuntrol Date Signed IPL Ref. No.: 867-54

------------------ ISO 9001 CERTIFIED ------------------Medical Imaging Laboratory Industrial Gauging Laboratory

24937 Avenue Tibbitts Valencia, California 91355 1800 North Keystone Street Burbank, California 91504

0036

,: IS: BE .. i,,1,~o!'< I QUALITY CONTROL PROGRAM

MP-008

Rev.a; 1110/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES -OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICA T/ON

MP 009

CURRENT DATE 8/16/2017 0:00 SOLUTION REFERENCE #,...IP_L.,....8-67-.• ...,54...,··:-· --.,-,-_.,...-, SOLUTION #1-•· ---:-. ·T-h-.,.1-8-· --

Half Life, Years I i340E+03l

Half Life, Days ! 2.681E+06j

Radionuclide m-rh Certified Activity 1.013E+0O µCi

Reference Date ... l __ 1_/_15_/2_0.,...02_0:_oo .... J

Certified Concentration._ ___ _,µCi per gram



8.7752 Weight, Grams .. -.. ~,7591 Weight, Grams

5.0161 Weight, Grams 1.0130 µCi

Chemical Com osition of Standard Solution


Dilute to a volume of! .· 1000~00. !milliliters

Certified Total Activity ofl 1.0130jµCi Which Equals 2.249E+06jdpm at the date listed above

This activity concentration is based on the original And after dilution the activity of this solution isl 2.249E+D3jdprn/ml reference date listed above. Alf activities are corrected to the date and time of analysis by the laboratory data processing software,

Expiration Date: I August 11, 2018

VP.rifiArl P.. AnnrnvArl Av " ----::,:,-r'!"-------+--½---- n~tA· R/1RI?n11 n-nn

Date:

0037

, f;:;J:3g'.R,L,JNg I QUALITY COMPNnTo9ROL PROGRAM ~ S~RVICC:$ "'\I

Rev. 7; 9/29/99 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS


MP-009 Solution Reference # IPL ae7,:,54

Princi al Radionuclide · 229rh ·

Radionuclide of Interest 229rh

Half Life, Years ! 7.340E+03!


Date 8/16/2017 0:00 Solution# Th~18a ..

Half Life, Days l 2.aa1 E+oaj

Reference Date ... ! __ 1_/1_5_/2_0_02_0:_oo ..... l




NOTES:

Dilution Solvent Used


· · · 10:0000 ml 2.2490E+04 dprn

1000:00 ml Final Activity Concentration: I 2.2490E+01 !dpm/ml


Expiration Date: I August 11, 2018

Date: __ a_11_6,_12_0 ... 17_0_:.;..oo_

D;,.te:_~-f c./F----,'(3.___· ·.

0038

jl}attonal 1Jnstttute of ~tanbatbs & ~tcbnologp

C!terttf tcate' · 0\

't ,/)., ,~

~· C / · • 1 (1 Standard Reference Material 4251C Barium-133 Radioactivity Standard V ·1-

This Standard Reference Mate.rial (SRM) consists of radioactive barium-133 c~loride, non-radioactive barium

chloride, and hydrochloric acid dissolved in 5 mL of distilled water. The solution is contained in a flame

sealed NIST borosilicate-glass ampoule. The SRM is intended for the calibration of ionization chambers and

solid-state gamma-ray_spectrometry.systems.

Radiological Hazard

The SRM ampoule contains barium-133 with ·a total activity of approximately 2.5 MBq. Barium-133 decays

by electron capture and during tlle decay process X-rays and galllI?a rays with energies from 4 to 400 ke V are

emitted. Most of these photons escape from the SRM ampoule and can represent a radiation hazard.

Approximate unshielded dose rates at several distances (as of the reference time) are given in note [a]*.

Appropriate shielding and/or distance should be used to minimize personnel exposure .. The SRM should be

used only by persons qualified to handle radioactive material. ·

Chemical Hazard

The SRM ampoule c_ontains hydr~chloric acid (HCl) with a concentration of 1 mole per liter of water. The

solution is corrosive and represents a health hazard if it comes in contact with eyes or skin, If the ampoule

is to be opened to transfer the solution, the recommended procedure is given on page 2. The ampoule should

be opened only by persons qualified to handle both radioactive material and strong acid solution.

Storage and Handling

The SRM should be stored and used at a temperature between 5 and 65 °C. The solution in an unopened

ampoule should remain stable and homogeneous until at least June 2004.

The ampoule ( or any subsequent container) should always be clearly marked as containing radioactive

material. If the ampoule is transported it should be packed, marked, labeled, and shipped in accordance with

the applicable national, international, and carrier regulations. The solution in the ampoule is a dangerous

good (hazardous material) both because of the radioactivity and because of the strong acid.

Preparation

This Standard Reference Material was prepared in the Physics Laboratory, Ionizing Radiation Division,

Radioactivity Group, J.M.R. Hutchinson, Group Leader. The overall technical direction and physical

measurements leading to certification were provided by L.L. Lucas of the Radioactivity Group and D.B. Golas,

Nuclear Energy Institute Research Associate.

The support aspects involved in the preparation, certification, and issuance of this SRM were coordinated

through the Standar~ Reference Materials Program by N.M. Trahey.

Gaithersburg, Maryland 20899 October 1994

SRM 4251C, page 1 of 6

Thomas E. Gills, Chief Standard Reference Materials Program

*Notes and references are on pages 5 and 6.

0039

(EBER!;-;~~!', I QUALITY CONTROL PROGRAM

QCP-009

Rev.8; 11/10/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PH/MARY DILVTION RE'CERTIFICA TION

QCP 009-1

CURRENT DATE 5/5/2018 0:00 SOLUTION REFERENCE #.-N-IS_T_S_R_M_4_2_5_1 C---...... SOLUTION #1----B-a--6-----1

Princi al Radionuclide 133Barium

Half Life, Years

I 1.048E+01 I Radionuclide lJ;jBarium

Certified Activity µCi 1---,---,,-----,--i

Certified Concentration 1.318E+01 µCl per gram



Chemical Composition of Standard Solution j1 33BaCl2 in 1 M HCI


Reference Date~l ___ 9/_1_/1_9_93_0_:o_,ol

9.3081 Weight, Grams 4.2582 Weight, Grams 5.0499 Weight, Grams

66.5577 µCi

Dilution Instructions: Dilution Solvent Used !1M HCI

Dilute to a volume of! 1000.00 I milliliters

Certified Total Activity ofl 66.5577lµCi Which Equals 1.478E+08ldpm at the date listed above

And after dilution the activity of this solution isl 1.478E+05ldpm/ml This ,1ctivity concontrntion is based on the orininal reference date listed above. Al! activiik•s am con-ect,,d to the date and time of analysis by the laboratory tfatrn procnssinfJ softvvaro.,

Expiration Date: I April 26, 2019

0040

Rev.fl; 11/10/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDAF?Y IJILUTION RECEFITIFICATION

QCP-009-1-A Date I 5/5/18 I Solution #li-----B-a--6-a---i, Solution Reference# NIST SRM4251C

Principal Radionuclide 133sa I

Radionuclide of Interest 1338a

Half Life, Years

I 1.048E+01 I



I Half Life, Days

I 3.828E+03I

Reference Date._! ___ 9_/_1/_1_99_3_0_:_oo_,I

Dilution Instructions: Dilution Solvent Used l1M HCI


NOTES:


25.0000 ml 3.6950E+06 dpm

1000.00 ml Final Activity Concentration: j 3.6950E+03!dpm/ml

This activity concfN,tratlon is based on the ori1:1inal rofornnce date listed above. Al! activitius are corrected to the date an<l l:irne of analysis by the laboratory data procei,sing software.

Expiration Date:! April 26, 2019 I

Date: ___ 5_/5_/_18 __ _

Date: ·Ji\\({ ---+'\ '+\ __ _

0041

CERTIFICATE OF CALIBRATI :r+sAtQC REVIEWED

Radionuclide:

Half Life:

ALPHA STANDARD SOLUTIO ore g, g

Customer:

P'.O.No.:

TMA EBERLINE

VH1888

Catalog No.:

Source No.:

Ra-226

1600 ± 7 years

7226

453-26

Reference Date: February 1 1994

Contained Radioactivity: (Ra-226) 1.001

Contained Radioactivity: (Ra-226) 37.0

12:00 PST.

µCi.

kBq.


b. Chemical form:

c. Carrier content:

5.1864 g (in a 5 ml Flame Sealed Ampoule)

Ra(NO3)2 in 1 N HNO3

None added

d. Density: L0318 g/ml @20°C.

Radioimpurities None detected(other than daughters)

Radioactive Daughters Rn-222, Po-218, At-218, Pb-214, Bi-214, Po-214, Tl-210, Pb-210, Bi-210, Po-210 and Tl-206.


(Ra-226) 0.1929

Method of Calibration

Weighed aliquots of the solution were assayed using gamma spectrometry:

Energy peak(s) integrated under: 186 keV.

Branching ratio(s) used: 0.0351 gamma rays per decay.




d. Total uncertainty at the 99 % confidence level;

NIST Traceability

±3.4% ±3.1% ±0.2%

±4.6%

µ.Ci/g,


Leak Test(s)

See reverse side for Leak Test(s) applied to this source,

Notes

1. Nuclear data wen: uiken from "Table of Radioactive Isotopes", editeo by Virginia S. Shirley, 1986.

2. IPL participates in an NIST measurement assurance program to establish and mainuiin implicit traceability for a number of nuclides,

based on the blind assaf (and later NIST certification) iifStimdard Reference Materials {As in NRC Reguliltoi:y Guide 4.15).


1800 North Keystone Street

Burbank, California 91504

818 843 - 7000

QUALITY CONTROL

/iA,. '! /99 If Date Signed

0042

;: E El ER!;-;,~!::!,!', I

' QUALITY CONTROL PROGRAM

MP009

Rev.a; 11/01/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES· OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS PRIMARY DILUTION RECERTIFICATION

MP009

CURRENT DATEI 9/20/2017 0:001 SOLUTION REFERENCE# IPL453~26 I SOLUTION#! . :Ra~s. I

Principal Radionuclide Half Life, Years Half Life, Da~s 226Radium I I·· .. 1.600E+03I I s.844E+osl

Radionuclide ~0 Radium Reference Date! • 21111994 o:ool

Certified Activity . .1.001E+O0 µCi Certified Concentration µCi per gram

Ampoule /Solution Gross~Weight, Grams Empty Ampoule · Weight, Grams

Solution Net Weight, Grams Total Activity In Ampoule 1.0010 µCi

Chemical Composition of Standard Solution l~Ra(NO3)z in 1 MHNOa • I

Dilution Instructions: Dilution Solvent Used I1M HN03 . I Dilute to a volume ofl · .1000.00 · !milliliters

Certified Total Activity of! 1.0010jµCi Which Equals I 2.222E+06ldpm at the date listed above

And after dilution the activity of this solution isl 2.222E+03ldpm/ml This activity concentration is based on the original reference date listed above. All activities are corrected to the date and time of analysis by the laboratory data processing software,

Expiration Date: I September 20, 2018 I

~ ( VerCied & Approved By ~- Date: 9/2012017

~~ I \ _/

QC Approval \. ~~ \. ~ Date: 9/20/2017 - I J -

0043

Rev.a; 11/01103 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES-OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS


MP009 Date 9/20/2017 0:00 Solution Reference# IPL~453'-2e Solution # .. Ra:..sb

Princi al Radionuclide Half Life, Years 226Radium I · 1.600E+•3j

Half Life, Days I 5.B44E+osl

Radionuclide of Interest· .. 226Radium Reference Date ... I __ 2/_1_/1_9_94_ .. _o:_o_,o I Parent Solution Cone. 2.22E+03. dpm/ml




NOTES:


20.0000 ml 4.4440E+04 dpm

.· 1000.00 ml Final Activity Concentration: I 4.4440E+01 jdpm/ml


Expiration Date:! __ 2_0._s_e_p-_1_a _ _.

Date: 9/20/2017 0:00 -------Date: 9/20/2017 0:00

-----..;.;,.,,~____,.;.;.....;;...

0044

1380 Seaboard Industrial Blvd. Atlanta, Georgia 30318 • U.S.A.

CERTIFICATE OF CALIBRATION Standard Radionuclide

72325-207 1~ . 2/2-, i5 \ lt

Ra-228 5 mL Liquid in Flame Sealed Vial

Phone (404) 352-8677 Fax ( 404) 352-2837

This standard radionuclide source was prepared

gravimetrically from a calibrated master solution. The

master solution was calibrated using a germanium gamma

spectrometer system.

Radionuclide purity and calibration were checked using a

germanium gamma spectrometer system. The nuclear decay rate

and assay date for this source are given below.

ANALYTICS maintains traceability to the National Institute

of Standards and Technology through Measurements Assurance

Programs as described in USNRC Reg. Guide 4.15, Revision 1.

ISOTOPE:

ACTIVITY (dps):

HALF-LIFE:

CALIBRATION DATE:

RELATIIVE EXPANDED UNCERTAINTY (k=2):

Ra-228

4.022 E3

5.75 years

February 10, 2006 12:00 EST

4.0%

Impurities: y-impurities <0.1%

5.10721 grams 0.lM HCl solution with 50 µg/g Ba carrier.

PO NUMBER 00003181, Item 1

SOURCE PREPARED BY: M. Taskaeva, Radiochemist

QA APPROVED:

0045

~EBER""~~!', I


Rev.a; 1/10/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES - OAK RIDGE LABORATORY RADIOACTIVE REFERENCE SOLUTIONS

INITIAL DILUTION MP 009

CURRENT DATE! 2/28/2017 0:00! ~----------. --------1 SOLUTION REFERENCE# Analytics 7235-207 SOLUTION #I Ra-12 I Principal Radionuclide

22sRa I Half Life, Years

I 5. 750E+ool

Radionuclide 228Ra Certified Activity 1.087E-01 µCi

Certified Concentration,__ ___ __,µCi per gram





Reference Date ... l __ 2_/1_0_/2_0_06_0_:_oo .... l

9.0741 Weight, Grams 3.9858 Weight, Grams 5.0883 Weight, Grams 0.1087 µCi

Dilution Instructions: Dilution Solvent Used I0.5 M HCI

Dilute to a volume ofj 991.00 \Kg

Certified Total Activity ofl 0.1087lµCi Which Equals I 2.413E+05\dpm at the date listed above

And after dilution the activity of this solution isl 2.435E+02ldpm/ml This activity concentration is based 011 the ori9inal rnfernnce dalH listed abovn, A!! 11ctiv!ties arn conedt,d to Hw date and timn of am1lysis by the h1boratory d<1ta processing softwarn ..

Expiration Date:! February 12, 2019 I

Date: 2/12/18

Date:

I I

0046

QA/QC REVIEWED ANALYTICS

CERTIFICATE OF CALIBRATION Standard Radionuclide Source

52094-416

Am-241 10 mL Liquid in Flame Sealed Vial

1380 Seaboard Industrial Blvd. Atlanta, Georgia 30318 · U.S.A.

Phone (404) 352-8677 Fax (404) 352-2837

This standard radionuclide source was prepared gravimetrically from a calibrated master liquid radionuclide solution source. The master source was calibrated by liquid scintillation counting.

ANALYTICS maintains traceability to the National Institute of Standards and Technology through Measurements Assurance Programs as described in USNRC Reg. Guide 4.15, Revision 1.

ISOTOPE:

ACTIVITY (dps):

HALF-LIFE:

CALIBRATION DATE:

TOTAL ERROR:

Am-241

1.975 E+05

432.2 years

March 19, 1996 12:00 EST

3.0%

SYSTEMATIC ERROR: 2.37%

RANDOM ERROR: 0.63%

10.01177 grams of solution lM HCl.

PO NUMBER OR3830, Item 1

SOURCE PREPARED BY: Beverly,

QA APPROVED: M-~

0047

~ 1;;: a _-=:J:;;!. t.,,.tN .e: I QUALITY c~~-00T9ROL PROGRAM

~ SE:RVICES.

Rev.8; 1/10/03 Title: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES" OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION (RE-CERT/FICA TION)

Solution Reference # Anal !cs 52094-416

Half Life, Years I 4.322E+o2j

Date 7/29/2017 0:00 Solution# A/B-7 al ha

Half Life, Days I 1.579E+05 I

Radionuclide of Interest 241Am Reference Date!,_ __ 3_/_19_/1_9_9_6_0_:o_,ol


Chemlcal Composition of Standard Solution



NOTES:

Dilution Solvent Used j1 M HNO3


60.0000 ml 7.1100E+05 dpm

1000.00 ml Final Activity Concentration:! _ 7.11 OOE+02ldpm/ml


Expiration Date:! July 29, 2018

0048

l,,.,,o,~ '!t:.. ·\

\~) ~ational 3Jnstitute of ~tanbarbs & mccbnolog!'

ctertif icatt Standard Reference Material 4234A Strontium-90 Radioactivity Standard

This Standard Reference Material (SRM) consists of radioactive strontium-90 chloride, non-radioactive

strontium chloride, non-radioactive yttrium chloride, and hydrochloric acid dissolved in 5 mL of distilled water.

The solution is contained in a flame-sealed NIST borosilicate-glass ampoule. The SRM is intended for the

calibration of beta-particle counting instruments and for the monitoring of radiochemical procedures.

Radiological Hazard

The SRM ampoule contains strontium-90 with a total activity of approximately 13 MBq. Strontium-90 decays

by beta-particle emission to yttrium-90, which also decays by beta-particle emission. None of the beta particles

escape froni the SRM ampoule. The beta particles emitted from strontium-90 and yttrium-90 produce

bremsstrahlung photons with energies up to 2 MeV. Most of these photons escape from the SRM ampoule

and can represent a radiation hazard. Approximate unshielded dose rates at several distances (as of the

reference time) are given in note [a]*. Appropriate shielding and/or distance should be used to minimize

personnel exposure. The SRM should be used only by persons qualified to handle radioactive material.

Chemical Hazard

The SRM ampoule contains hydrochloric acid (HCl) with a concentration of 1 mole per liter of water. The

solution is corrosive and represents a health hazard if it comes in contact with eyes or skin. If the ampoule

is to be opened to transfer the solution, the recommended procedure is given on page 2. The ampoule should

be opened only by persons qualified to handle both radioactive material and strong acid solution.

Storage and Handling

The SRM should be stored and used at a temperature between 5 and 65 °C. The solution in an unopened

ampoule should remain stable and homogeneous until at least March 2005.

The ampoule (or any subsequent container) should always be clearly marked as containing radioactive

material. If the ampoule is transported it should be packed, marked, labeled, and shipped in accordance with

the applicable national, international, and carrier regulations. The solution in the ampoule is a dangerous

good (hazardous material) both because of the radioactivity and because of the strong acid.

Preparation

This Standard Reference Material was prepared in the Physics Laboratory, Ionizing Radiation Division,

Radioactivity Group, J.M.R. Hutchinson, Group Leader. The overall technical direction and physical

measurements leading to certification were provided by L.L. Lucas of the Radioactivity Group and D.B. Golas,

Nuclear Energy Institute Research Associate.

The support aspects involved in the preparation, certification, and issuance of this SRM were coordinated

through tbe Standard Reference Materials Program by N.M. Trahey.

Gaithersburg, Maryland 20899 May 1995 (Text only revised November 1997)

SRM 4234A. page l of 6

Thomas E. Gills, Chief Standard Reference Materials Program

"'Notes and references are on pages 5 and 6.

0049

~ f;; _ _e_f;::RJ.,.._J_hl E I QUALITY c~c~!:oL PROGRAM ~ SER'VICl:::S ~

Rev. 7; 9/29/99 TiHe: Radioactive Reference Standards Solutions & Records

EBERLINE SERVICES· OAK RIDGE LABORATORY RADIOACTIVE REFERENCE STANDARD SOLUTIONS

SECONDARY DILUTION (RE-CERT/FICA TIONJ

QCP-009-1-A Date 7/29/2017 0:00 Solution Reference # NIST 4234A Solution # · A/B-7 beta

Princi al Radionuclide 90Strontium ·

Half Life, Years I · 2.878E+01 !

Half Life, Days I 1.051E+04!

Radionuclide of Interest' 80Sr ·· 1 Parent Solution Cone._· · 1,52E+06 .· dpm/ml

Reference Date! ·. · 3/13i19950:oo!

The beta activity of solution reflects the original oostronijum concentration and an equal concentration of OOVttrium.

Chemical Composition of Standard Solution l90SrCl2 in .1 M HCI · I



NOTES:

Dilution Solvent Used


·· 0'.5000 ml 7.5764E+05 dpm

· 1000;00 ml Final Activity Concentration: I 7 .5764E+02 ! dpm/ml


Expiration Date:I July 29, 2018

Date: 07/29/17 _____ ;__,;..;... __ Date: __ ~..,../ 1-+{.._11--

I

0050

SECTION VI

QUALITY CONTROL SAMPLE RES UL TS SUMMARY

0051

Eberline Analytical Analysis Control Chart

• 18-06097

Analyte

U-234

U-238

Analyte

Analyte

U-234

U-238

U-235

Version

Nonnalized Difference

Analysis

UUISO

LCS Measured

86.16%

90.66%

MS Actual %Rec

I I

CSU Measured

14.34%

14.27%

Expected MS Result

I

i

i

I

Duplicate Results

Nonnalized Original I Difference

RPD Result

0.70 30.91 1.88E-01 I

1.69 78.13 1.22E-01

1.63 152.02 1.68E-02

Printed: 7/10/2018 12:23 PM Page 1 of 2

Run Activity Units Aliquot Units __ ___, ____________ Client Name

1 pCi

Laboratory Control Sample

LCS Expected

100.00%

100.00%

Expected MS Uncert

Original CSU

1.19E-01

9.21E-02

4.03E-02

I

Uncert.

I Expected

Known

3.60% 7.32E+00 I

3.60% 7.09E+00 [

Matrix Spike

Actual MS Result

Duplicate Result

2.57E-01

2.79E-01

1.23E-01

Actual MS CSU

Duplicate CSU

1.52E-01

1.56E-01

1.21 E-01

Known Error

2.64E-01

2.SSE-01

Sample Result

LCS Relative

Bias

0.86

0.91

AMO Environmental Decisions

Result CSU

6.31E+00 9.0SE-01 I

1 6.43E+00 I 9.18E-01

Sample CSU

Sample Aliquot

Standard ID

U-8a

U-Sa

Standard ID

Standard

ACT(dpm)

3.20E+01

3.10E+01

Standard ACT(dpm)

QC Summary

LCS¾R I

MS¾R I

MSND

OK I

OK ! i

OK I

I

I

Standard Error

3.60E+00

3.60E+00

Standard Error%

I

Standard Added (g}

15.08E-01

I

[ 5.08E-01

Standard Added (g)

RepRPD I Rep ND

NA I OK

NA OK

NA OK

0052


• 0

18-06097

130.00

120.00

110.00

100.00

90.00

80.00

I~-·- Analysis Run

UUISO 1

LCS % Recovery

T - - - _I I I • t I , . --------- l

Activity Unit_s Aliquot Units

pCi

40.00

35.00

30.00

25.00

20.00

15.00

10.00

i


Client Name


Replicate Sample RPD

,--------------

i 70.00 +----------"--------~----------------~

U-234 U-238 5.00

- Lower Error 68.22 72.79

- Upper Error 104.11 108.53

• %R 86.16 90.66

- -LCL 75 75

--Mean 100 100

1- -UCL 125 125

0.00 +-------------~-----------~---------

- LowerError

- UpperError

• RPO

- -CL

U-234 U-238 U-235 ~ 40.32 102.33

I 239.84

21.51 53.94 64.20

30.91 78.13 152.02

35 35 I 35

Normalized Difference

3.50 No Matrix Spike

3.00

2.50

2.00

1.50

1.00

0.50

0.00 LCS ND MSND

-u-2341 0.00

~U-2381 000

0.00

1.69

0.00

0.00

000

0.00

-UCL I 3 3 3

Version

0053


WO

18-06097

Analyte

TH-228

TH-230

TH-232

Analyte

Analyte

TH-228

TH-230

TH-232

Version

Analy,s_is

ThlSO

LCS CSU Measured Measured

119.46% 22.52%

122.48% 23.47%

118.34% 22.29%

Nonna/ized MS Actual Expected Difference %Rec MS Result

Duplicate Results

I Nonna/ized RPD Original

Difference Result

1.35 186.84 5.66E-02

0.33 14.85 1.73E-01

0.29 42.23 1.90E-02

Run Activity Units~ ,:'l_iguot Units

1 pCi I


LCS Uncert. Known

Known Result

Expected Expected Error

100.00% 3.60% 4.87E+00 1

1.75E-01 5.82E+00 ..

'

100.00% 2.70% 5.38E+00 i 1.45E-01 6.59E+00

100.00% 3.60% 4.87E+00 ! 1.75E-01 5.76E+00 I

Matrix Spike

Expected Actual Actual Sample Sample

MS Uncert MS Result MS CSU Result CSU

Original Duplicate Duplicate LCS Relative I LCS¾R CSU Result CSU Bias

7.47E-02 1.92E-03 2.69E-02 1.19 OK

1.10E-01 1.49E-01 9.07E-02 1.22 OK

5.21E-02 2.92E-02 4.38E-02 1.18 OK


Client Name


CSU Standard Standard Standard Standard

ID ACT(dpm) Error Added (g) I

1.31E+00 Th-Sb I 1.04E+02 3.60E+00 1.04E-01

1.55E+00 Th-1b 2.35E+01 2.70E+00 5.0BE-01

1.28E+00 Th-Sb 1.04E+02 i 3.60E+00 1.04E-01

I

I Sample Standard

I Standard

I Standard Standard

Aliquot ID ACT(dpm) Error% Added (g)

QC Summary

I I MS¾R I MSND I RepRPD I Rep ND

NA I OK

NA OK

i I NA OK

0054


WO

18-06097 Analysis Run

ThlSO 1

LCS % Recovery i..::,v.uv

r------r------t-120.00

110.00

100.00

- l l 90.00

80.00

--------------- LCL

70.00 TH-228 I TH-230 TH-232

- Lower Error 93.34 I 96.30 92.45

- Upper Error 145.58 I 148.65 144.22

• o/oR 119.46 I 122.48 118.34

- -LCL 75 ' 75 75

--Mean 100 I 100 100

[--UCL 125 125 125


3.50 1 --------------------------

3.00 +--------------------------------2.50 -1--------------------------------

2.00 +---------------------------------

1.50 -j----------------------------------

1.00 -1--------------

0.50 +--------------

0.00 LCS ND MS ND

-TH-2281 0.00 1.35 0.00

=rH-230I 0.00 0.33 0.00

- UCL 3 3 3

Version

ActiVi!Y Units

pCi

-+U.UU

35.00

30.00

25.00

20.00

15.00

10.00

I 5.00

I 0.00 .

I - Lower Error

I I

- Upper Error_

• RPD

- -CL

Ali_guot Units


Client Name



~--------------1

T I

TH-228 I TH-230 I TH-232

349.09 19.49 I 84.27

24.58 ! 10.22 I 0.20

186.84 I 14.85 i 42.23

35 ! 35 I 35

No Matrix Spike

I I I I I

0055


• 18-06097

Analyte

RA-226

Analyte

Analyte

RA-226

Version

Nonnalized Difference

Analysis

Ra226

LCS Measured

100.62%

MS Actual %Rec

I

CSU Measured

25.16%

Expected MS Result

Duplicate Results

Nonnalized Original

Difference RPD

Result

1.45 115.42 1.02E-01

i

Run Activity Units Aliquot "LJnits

1 pCi


LCS Expected

100.00%

Expected MS Uncert

Original CSU

2.14E-01

Uncert. Known

Expected

4.60% I 1.00E+01 I

Matrix Spike

Actual MS Result

Duplicate Result

3.81 E-01

Actual MS CSU

Duplicate CSU

3.09E-01

I

Known Error

4.60E-01

Sample Result

I !

LCS Relative I Bias

1.01 I

Result

1.01 E+01

Sample CSU

LCS¾R

OK

I

I

I


Client Name


CSU

2.53E+00 I

Sample Aliquot

Standard ID

Ra-Sb

Standard ID

Standard

ACT(dpm)

I 4.40E+01

Standard ACT(dpm)

QC Summary

I I

MS¾R MSND

i

I I I

Standard Error

4.60E+00

Standard Error%

RepRPD

NA

I

I

Standard Added (g)

5.0SE-01

Standard Added(g)

Rep ND

OK

0056


WO Analysis Run Activity Units

18-06097 Ra226 1

LCS % Recovery 13000

1 120 00 t

110.00

100.00 •

90.00 I

8000 t I

l 70.00 :

RA-226

Lower Error I 70.86

- Upper Error, 130.38

• %R 100.62

- -LCL 75

--Mean 100

- -UCL 125


3.50 ,-----------------------------------

3.00 r---------------------------------2.50 +-------------------------------

2.00 +---------------------------------

1.50 t----------------===----------------

1.00 +--------------

0.50 +--------------

0.00 LCS ND

-RA-226 0.00

- UCL 3

Version

MSND

1.45 0.00

3 3

pCi

--•

40001

35 00

30 00

25 00

20 00

15 00

10 00

5 00

ooo I

Lower Error\

Upper Error I RPD I

- -CL I

Aliguot Units


Client Name


Replicate Sample RPO

RA-226

178.00

52.85

115.42

35

No Matrix Spike

0057


WO

18-06097

Analyte

RA-228

Analyte

Analyte

RA-228

Version

Analysis Run Activity Units Aliquot Units

Ra228 1 pCi



LCS Measured

93.82%

MS Actual %Rec

CSU LCS Measured Expected

24.26% I 100.00%

Expected Expected MS Result MS Uncert

Duplicate Results

Normalized RPD

Original Original

Difference Result CSU

2.29 166.75 7.89E-02 4.12E-01

i

Uncert. Known

Expected

5.10% I 9.20E+00

Matrix Spike

Actual MS Result

Duplicate Result

8.70E-01

Actual MS CSU

Duplicate CSU

5.37E-01

I

Known Error

4.69E-01

Sample Result

LCS Relative I Bias

0.94

Result

8.63E+00

Sample CSU

LCS¾R

OK


Client Nam_e ----------1


CSU I I

2.09E+00 I

Sample Aliquot

Standard

ID

Ra-12

Standard ID

Standard ACT(dpm)

I 5.46E+01

Standard ACT(dpm)

QC Summary

MS¾R MSND i

Standard Error

5.10E+00

Standard Error%

RepRPD

NA I

Standard Added (g)

3.75E-01

Standard Added(g)

Rep ND

OK

0058


• A..a~ysis Run

18-06097

130.00

120,00

110.00

100.00

90.00

80.00

70.00 1 I - Lower Error I : - ,_,e.o, I -I • %K

I - -LCL

,--Mean I I- -UCL

Ra228 1

LCS % Recovery

RA-228

64.46

123.18

93.82

75

100

125


3.50 ---------------------------------

3.00 +-----------------~---------------2.50 +--------------------------------

2.00 +--------------

1.50 1 ------------

1.00 +--------------

0.50 ,------------:

0.00 , LCS ND MSND

-RA-228I o.oo 2.29 0.00

- UCL 3 3 3

Version

A_ctivit,'_LJnits Aliquot Units

pCi

40 00

35.00

30.00

25.00

20 DO

15.00

10.00

5.00


Client Name



000 +---------------------------------------I RA-228

[--=-_L,ow_er Errori

i l - Upper Error

• RPD --CL

I 250.09 ----i 83.41

I 166.75

35

No Matrix Spike

0059


WO

18-06097

Analyte

GROSS ALPHA_TH

GROSS BETA_SR

Analyte

Analyte

GROSS ALPHA_TH

GROSS BETA_SR

Version

Analysis Run Activity_ Units Aliquot Units

GaGbT ThSr

NonnaJized Difference

LCS Measured

109.59%

94.38%

MS Actual %Rec

CSU Measured

11.00%

13.86%

Expected MS Result

Duplicate Results

i

1 pCi


LCS Expected

100.00%

100.00%

Expected MS Uncert

Uncert. Known

Known

Expected Error

4.30% 2.71E+02 1.16E+01

3.00% 2.77E+02 8.32E+00

Matrix Spike

Actual I Actual Sample MS Result [ MS CSU Result

I I Normalized Original

I Original Duplicate Duplicate LCS Relative I

RPD Difference Result CSU Result CSU Bias :

i I

2.48E+00 I 3.12E+00 , 7.82E+00 I 1.96 103.70 4.33E+00 1.10

2.21 118.66 i 1.14E+01 I 5.37E+00 I 2.91E+00 I 5.27E+00 I 0.94 I

Result

2.97E+02

2.62E+02

Sample CSU

LCS¾R

OK

OK I


Client Name,___ ___________ -t


CSU

3.26E+01

3.63E+01

Sample Aliquot

Standard ID

A/B-07

A/B-07

Standard ID

Standard ACT (dpm)

5.93E+02

6.08E+02

Standard ACT(dpm)

QC Summary

I

I

MS¾R I MSND I

I

I I

I I

I I

I

Standard Error

4.30E+00

3.00E+00

Standard Error%

RepRPD

NA

NA

I

I

I

Standard Added (g)

1.01E+00

1.01E+00

Standard Added (g)

Rep ND

OK

OK

0060


• 18-06097

130.00

120.00

110.00

100.00

90.00

'

Analysis

GaGbT ThSr

LCS % Recovery

• i

•

Run Activity _!,!_nits Aliquot Units

1 pCi

:::: I 30.00

25.00

20.00 +

15.00

10.00


Client Name



=-1' ----------~ ?o.oo +.------G-R_O_S_S_A_L_P_H_A_T_H·-----~------G-R_O_S_S_B_E_T_A_S_R-----~

- 5.00

- Lower Errorj 94.30 i 77.52 ' - Upper Error I 124.89 I 111.24 000 ~. -------------------------------~

GROSS ALPHA TH GROSS BETA SR ~

• ¾R I 109.59 I 94.38 - Lower Error 141.15 162.78

- -LCL I 75 I 75

--Mean I 100 I 100 - Upper Error

I • RPO

66.25 74.55

103.70 118.66

- -UCL I 125 I 125 [--CL 35 35

Normalized Difference 3.50

3.00 No Matrix Spike

2.50

2.00

1.50

1.00

0.50

0 00 LCSND I REP ND ! MSND

- GROSS ALPHA TH 0.00 I 1.96 I 0.00

= GROSS BETA SR 0.00 l 2.21 I 0.00

= 0.00 i 0.00 I 0.00

- UCL 3 I 3 I 3

Version

0061

SECTION VII

LABORATORY TECHNICIAN'S NOTES &RUN LOGS

0062

ISOUNOTES

0063

Printed: 7/6/2018 9:39 AM

~EEIERb~~!;i Work Order Analysis Notes

# Date Dept User

1 07/06/18 09:39 PREP JHARVEY


601 Scarboro Rd. Oak Ridae, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-06097 UUISO

1

ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED

SAMPLES TO SEPARATIONS

0064

Printed: 7/9/2018 3:57 PM

4: ~ E El I::: R ~-},J16 ~ Work Order Analysis Notes

# Date Dept User

07 /06/18 09: 39 PREP JHARVEY

2 07 /09/18 15:57 CHEM JDEMELAS

Page 1 of 1

Oak Ridge Laboratory Internal Worl< Order 18-06097 601 Scarboro Rd. -~-· Oak Ridge, TN 37830 Analysis Code UUISO Voice: 865.481.0683 ·-•·"·-~-----·- --· ·-----· www.eberlineservices.com Run Number 1

Notes

AUQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


----·-

Added concentrated HCI to sample beakers and heated to dryness; Added 20 ml 8N HCL to samples and

transferred to new, labeled C-Tubes, rinsing with 8N HCI to bring volume to ~35 ml; Preconditioned resin

columns with 35 ml 8N HCI; Centrifuged samples and loaded onto columns; Rinsed C-Tubes with 20 ml 8N

HCI, centrifuged as needed and loaded onto columns; Rinsed columns with 35 ml 8N HCI - 0.1 N NH4I, 35 ml

of 6.5N HCI - 0.04N HF, and 10 ml of 6.5N HCI; Eluted Uranium with 50 ml of 0.5N HCI into clean, labeled 100

ml beakers; Dried-down samples on hotplate; Dissolved samples in ~10 ml of concentrated HCI; Transferred to

new, labeled C-Tubes with DI H2O. Set samples asideJQc.Jsl!J3J:precipitation and filtering. -------~---·~ . ······--·· .,

0065

Printed: 7/10/2018 4:37 AM

~EBER~~!;':lc!;;; Work Order Analysis Notes

# Date Dept User

1 07/06/18 09:39 PREP JHARVEY

2 07 /09/18 15:57 CHEM JDEMELAS

3 07/10/18 04:37 CHEM TSMITH


601 Scarboro Rd. Oak Ridge, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-06097 Analysis Code UUISO

---··-····-··----+---------·-··················--11

Run Number 1

Notes



Added concentrated HCI to sample beakers and heated to dryness; Added 20 ml 8N HCL to samples and

transferred to new, labeled C-Tubes, rinsing with 8N HCI to bring volume to ~35 ml; Preconditioned resin

columns with 35 ml 8N HCI; Centrifuged samples and loaded onto columns; Rinsed C-Tubes with 20 ml 8N

HCI, centrifuged as needed and loaded onto columns; Rinsed columns with 35 ml 8N HCI - 0.1 N NH4I, 35 ml

of 6.5N HCI - 0.04N HF, and 10 ml of 6.5N HCI; Eluted Uranium with 50 ml of 0.5N HCI into clean, labeled 100

ml beakers; Dried-down samples on hotplate; Dissolved samples in ~1 O ml of concentrated HCI; Transferred to

new, labeled C-Tubes with DI H2O. Set samples aside for later precipitation and filtering.

Followed steps 12.1.7 to 12.4.5 in AP-005. ( Precipitated and filtered samples for Uranium)

0066

Eberline Analytical Oak Ridge Laboratory

•=A•-.---~•~''-"'~,~----•••M•o<,•••~ >

. . -~ ~ EBERLINE ~--------------------- -------------- --------SERv1c-Es

Reagents Used in an Analysis

Reagent Reagent

ID Name ""-•"•--w==

017344P Anion Exchange Resin - ---· -· ·--·-·-···"·· ·~···-···-·····,---·······~--·---

019999D02 Hydrochloric Acid ,.

020076S Hydrochloric Acid ,___ ~--·-·-·----~

020137S Hydrochloric Acid , ··--···-··-·-· ·~---~-··'"·

020155S HCI - NH4I ···-•~- --•~N,

020123S HCI - HF """~-·

019999P Hydrochloric Acid -M•- ..

020099S Carbon substrate - ····~····----·--•>••·

020095P Hydrofluoric Acid

019640S Neodymium Carrier ,. ........ -········"········~---·-···- ... -~···

019771P Reagent Alcohol

I 019956P Titanous Chloride 0 M• ••- -•• ••••• •-••••-~• ~ ••-'""-"•W••• •-• ••• ···-····· ··- ·~-····-···


-··

Internal Work Order ~~--~,-

18-06097 Analysis Code Run

UUISO 1 --

Reagent Analyst Date

Concentration ID Recorded

Reagent Grade JDEMELAS 7/9/2018 ··-···--·---

O.SN JDEMELAS 7/9/2018 .. ·-

6.SN JDEMELAS 7/9/2018

SN JDEMELAS 7/9/2018

SN - O.lM JDEMELAS 7/9/2018

6.SN - 0.04N JDEMELAS 7/9/2018

Reagent Grade JDEMELAS 7/9/2018

Solution TSMITH 7/10/2018 ~---··-~-

Reagent Grade TSMITH 7/10/2018

1 mg/ml TSMITH 7/10/2018 -

Reagent Grade TSMITH 7/10/2018

Reagent Grade TSMITH 7/10/2018 -·-----·-· ~•••m

0067

-~ 109

_ ____,,\ c-G_e1~iu11e ~n u~1:±utie-'-A:na1¥>-t> TedJ-~.

~~~~~ '----1---~~~-__. =-+---"--'---"--'--v-+--U_Um ~ -.

1----------------t------

-j-------t-------------~------+--~ ------11-~--~1---·--->;

0068

ISO TH NOTES

0069

Printed: 7/6/2018 9:39 AM

~EBERLINE ~ SERVICES

Work Order Analysis Notes

# Date Dept I User !

1 07/06/18 09:39 PREP

I JHARVEY


601 Scarboro Rd. Oak Ridae, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-06097 >---------+-----·------·-~'·---·-

Analysis Code Th ISO 1--------+---------------··~--

Run Number 1

Notes



0070


~ Oak Ridge Laboratory Internal Work Order 18-06097 601 Scarboro Rd. ~------·--- ··~---·-·-.. ~"¥---····-· -~--··"~-·-·· -~-----·-EBER~~~c~ Oak Ridge, TN 37830 Analysis Code ThlSO

Work Order Analysis Notes Voice: 865.481.0683 ·•-"··-·

www.eberlineservices.com Run Number 1

# Date Dept User Notes

1 07/06/18 09:39 PREP JHARVEY ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED


2 07/09/18 15:58 CHEM JDEMELAS Added concentrated HNO3 to sample beakers and heated to dryness; Added 20 ml 8N HNO3 to samples and

transferred to new, labeled C-Tubes, adding 8N HNO3 to bring volume to ~35 ml; Preconditioned resin

columns with 50 ml 8N HNO3; Centrifuged samples as needed, and passed through columns; Rinsed C-Tubes

with 20 ml 8N HNO3; Centrifuged rinsates and loaded onto columns; Rinsed columns with 40 ml 8N HNO3;

Eluted Thorium with 50 ml of 8N HCI into clean, labeled 100-ml beakers; Dried-down samples on hotplate;

Dissolved samples in ~1 O ml of concentrated HCI; Transferred to new, labeled C-Tubes with deiononized

water brinoinn vnl11me to ~15ml. SAi ,s,amnles recioitation and filterina.

0071


~ Oak Ridge Laboratory Internal Work Order 18-06097 601 Scarboro Rd. EBER~~tt~ Oak Ridge, TN 37830 Analysis Code ThlSO Voice: 865.481.0683

Work Order Analysis Notes ------- ~~····· ·-··•~~-- --·~------- ··•-.-.,-----· www.eberlineservices.com Run Number 1


1 07/06/18 09:39 PREP JHARVEY ALIQUOTED AND ADDED SPIKES AND TRACERS- DRIED SAMPLES DOWN AND SUBMITTED

SAMPLES TO SEPARATIONS -·

2 07/09/18 15:58 CHEM JDEMELAS Added concentrated HNO3 to sample beakers and heated to dryness; Added 20 ml 8N HNO3 to samples and

transferred to new, labeled C-Tubes, adding 8N HNO3 to bring volume to ~35 ml; Preconditioned resin

columns with 50 ml 8N HNO3; Centrifuged samples as needed, and passed through columns; Rinsed C-Tubes

with 20 ml 8N HNO3; Centrifuged rinsates and loaded onto columns; Rinsed columns with 40 ml 8N HNO3;

Eluted Thorium with 50 ml of 8N HCI into clean, labeled 100-ml beakers; Dried-down samples on hotplate;

Dissolved samples in ~1 0 ml of concentrated HCI; Transferred to new, labeled C-Tubes with deiononized

___ ,_ water, brin~g volume to ~15ml. Set sameles aside for later erecieitation and filterino. ···-·3-·

07/10/18 04:39 CHEM TSMITH Followed steps 12.2.5 to 12.4.5 in AP-005. ( Precipitated and filtered samples for Thorium)

0072

...


'~"~-·---=--•--·-~----,-·

. . ·~ ..

Q_ EBERLINE ~ ----- --------------------------------------- SERv-icEs

Reagents Used in an Analysis .....

Reagent Reagent ID Name .

017344P Anion Exchange Resin Y•~••••-••-• ··• ---- ··--··---,

020137S Hydrochloric Acid r·······

019999P Hydrochloric Acid f· • ee••~s,••••-••-" •

020000P Nitric Acid , ..• .. .... ~-~"'-' . .. ··-·- ···~·-·. --~--,--~--·-·· ---·-····· ------~···--··~.,---.

020146S Nitric Acid f· --· --······---···--------···-·--

020099S Carbon substrate --·····-·~·--·-·

019812S Cerrium Carrier

020095P Hydrofluoric Acid "-·--•-_, .. ,_,,, .. ~~ ------~----·-···--·- ..

019771P Reagent Alcohol ··•··•······ ··••·······•••


Internal Work Order --

18-06097 ---~,_,

Analysis Code Run ..

ThISO 1

Reagent Analyst Date


Reagent Grade JDEMELAS 7/9/2018 •<••·-

SN JDEMELAS 7/9/2018

Reagent Grade JDEMELAS 7/9/2018

Reagent Grade JDEMELAS 7/9/2018 -~-·····

SN JDEMELAS 7/9/2018 ·---~-- ---- ---- " .... ----~---···-·---···- ,_ ___

Solution TSMITH 7/10/2018

0.lmg/ml TSMITH 7/10/2018

Reagent Grade TSMITH 7/10/2018 ----

Reagent Grade TSMITH 7/10/2018 ~------

0073

-. _ __,,,":"----.____,,_ ___________ ,

0074

RA-226 NOTES

0075

Printed: 7/6/2018 10:00 AM

<(EBER~~~c!;'i Work Order Analysis Notes

# Date Dept User

1 07/06/18 10:00 PREP JHARVEY

Oak Ridge Laboratory 601 Scarboro Rd. Oak RidCle, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-06097 Analysis Code Ra226

1---------+------------- ... Run Number 1

Notes

ALIQUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB

CARRIERS AND AMMONIUM SULFATE- DECANTED SAMPLES AND CENTRIFUGED- SUBMITTED RADIUM PREr'IP TO C:,t=PIIPIITIONS

0076

Printed: 7/9/2018 1:49 PM

~EBER !;;,~!;;IC!;;; Work Order Analysis Notes

# Date Dept User

1 07/06/18 10:00 PREP JHARVEY

2 07/09/18 13:49 CHEM JBAILEY



Internal Work Order

Analysis Code

Run Number

Notes

Page 1 of 1

18-06097 Ra226

1

AUQUOTED AND ADDED SPIKES AND TRACERS- PH'D SAMPLES- PRECIPITATED WITH BA AND PB

CARRIERS AND AMMONIUM SULFATE- DECANTED SAMPLES AND CENTRIFUGED- SUBMITTED

RADIUM PRECIP TO SEPARATIONS ADDED EDTA TO SAMPLES AND LET SIT. ADDED AMMONIUM SULFATE AND ACETIC ACID TO

SAMPLES. FILTERED ONTO TARED FILTER PAPERS, LET DRY UNDER HEAT LAMP, REWEIGHED,

AND SUBMITTED TO COUNT.

0077

·-


}!Jl;:BERLINE ~ SERVICES


Reagent Reagent ID Name

019782P Ammonium Hydroxide

019733D05 Ammonium Sulfate

019792D04 Barium Carrier

019767D01 Lead Carrier

019846P Nitric Acid

019210P Acetic Acid

019733D02 Ammonium Sulfate

0199465 EDTA

Reagent


Internal Work Order


Ra226 1 Analyst Date


Reagent Grade JHARVEY 7/6/2018

200 mg/ml JHARVEY 7/6/2018




Reagent Grade JBAILEY 7/9/2018

200 mg/ml ]BAILEY 7/9/2018

0.25M JBAILEY 7/9/2018

0078

~. 109

-" . 1+~ · · ~J]1_e__C_oufl:l:±1Una lyS,5 . Teel;_. _ ___ u::!:Q ,r l.llim j:&_ __

p.-{ \ k,/ Vv tJ \ ·-.µ; .

----------+---------1----1------+----~--

l

j -------+-----

_,/ '-------l'--------1--------+-----+-------li---------t----·.1

~------~------l-------t-----4-----1-------1----

0079

RA-228 NOTES

0080

Printed: 7/6/2018 10:00 AM

4: EBER ~·R~C!'; Work Order Analysis Notes

# Date Dept User

1 07/06/18 10:00 PREP JHARVEY

Oak Ridge Laboratory 601 Scarboro Rd. Oak Ridqe, TN 37830 Voice: 865.481.0683 www.eberlineservices.com

Page 1 of 1

Internal Work Order 18-06097 Analysis Code Ra228

---.~----Run Number 1

Notes



RADIUM PRECIP TO SEPARATIONS

0081

Printed: 7/10/2018 2:37 PM

,:E:BER!ret~c~ Work Order Analysis Notes

I # Date Dept User

1 07/06/18 10:00 PREP JHARVEY

2 07/10/18 14:37 CHEM JBAILEY



Page 1 of 1

Internal Work Order 18-06097 1---·-------+--------·------··-----11

Analysis Code Ra228 -··""•·~---·~·-------·t----------·-·-·'"·············--·······

Run Number 1

Notes



RADIUM PRECIP TO SEPARATIONS ADDED FILTER PAPERS FROM COUNT ROOM TO LABELED C-TUBES, FILLED WITH EDTA SOLUTION

AND LET SIT OVERNIGHT. REMOVED FILTER FROM EDTA-ADDED 2MLS YTTRIUM 9MG/ML CARRIER

ADDED 18N NAOH TO SAMPLES AND RECORDED T1. HOT BATHED FOR 15 MIN, CENTRIFUGED AND

DISCARDED SUPERNANT. ADDED 6N HNO3, DI WATER, AND 10N NAOH. HOT BATHED FOR 15 MIN,

CENTRIFUGED AND DISCARDED SUPERNANT. ADDED 1N HNO3, DI WATER, AND AMMONIUM

OXALATE. FILTERED ONTO TARED FILTER PAPERS. LET DRY UNDER HEAT LAMP, REWEIGHED AND

SUBMITTED TO COUNT.

0082


-~ . . Q EBERLINE ~ ·· ········· -·································•···· s·ERv1·c-Es

Reagents Used in an Analysis ---~~ -"~~-·"~

Reagent Reagent ID Name

019782P Ammonium Hydroxide -·

019733D05 Ammonium Sulfate "W•----•

019792D04 Barium Carrier

019767D01 Lead Carrier ---

019846P Nitric Acid , .... 018297D01 Ammonium Oxalate

- -------018971D06 Nitric Acid

019673D02 Nitric Acid

018699D10 Sodium Hydroxide -·---·~-.,

019344D01 Sodium Hydroxide -·--·-·

019519S Yttrium Carrier

-·-·~


Internal Work Order


Ra228 1 Reagent Analyst Date





166 mg/ml JHARVEY 7/6/2018 ,,.-·,--~·-- ---

Reagent Grade JHARVEY 7/6/2018 -• 'A•-•

5% JBAILEY 7/10/2018

lN ]BAILEY 7/10/2018

6N JBAILEY 7/10/2018 -~--.. -~

l0M JBAILEY 7/10/2018

18M JBAILEY 7/10/2018

9 mg/ml JBAILEY 7/10/2018 ··-

0083

/ ; -A90c, Lr-:}-1 \lO - ' ------- 55 1··

---f'1l~•'I- i~t'~~~Cti<l _c~0 Le ~~Me~~~~ ·T~h,:: · -~i~JoL,~ lioL,c"ct i,,A li· '-1,} .. A.Mo_+-----'-'~ d I,_.., ~_i_ \0-: I ---+-·---m---------1--- .----J-----~----1-- ,:i 1 .. t

',

-~;---~-~-=---=--=--=--=--=--=---· . ___ , __ _,__ ___ ----',________ :: t ---L--·-T ~ 1---------t----,,s; t r , ---J---.. -·- __ _._, .. ,-~,.-, ,1 r ~-i --r---- --:-- f L I --1 -·--------------+--------1---------t------l-----> I

. I --------,~--.. ~I --------;-------+-----t---------+-----4-------.; i

--~---__ .,_ ______ l--------+-----------4---------

-·-~-.. ----.. -·!---------+----~

I -----l--~--·•--------+---------.+- ' --~t-·-·---.. ··J--

:: --·-~·-----··-·--··~ -----·-·------+------->--------->----

' ----t-----·---·1'-------·---·-----··------·-·-~ --------···-··-----'I------·---·----·-~-

- .. ___ ---.. ------1------------------------J------------>---------<----..___

____ __,t--------

. ____ t---------------t------+-----+--------·---~- --------·•- .. -----~·1-------"'

-~~------------------+------------+----------" _______ }·-----------------------4------------1

0084

GROSS A/B NOTES

0085


4: Oak Ridge Laboratory Internal Work Order 18-06097 601 Scarboro Rd. nwm • •, ~'""•••~•m•m ,,, • •

J::::.l::IER.~t~c~ Oak Ridge, TN 37830 Analysis Code GaGbT ThSr Voice: 865.481.0683

Work Order Analysis Notes =--~

www.eberlineservices.com Run Number 1


1 07/10/18 11:49 PREP JPACHELLA Samples were aliquoted, nitrated and dried. Samples were transferred to tared planchetes, flamed, re-

weighed, and submitted to count room .

(_ " ..,,"J -~ .,.---· ·.-~·· C;;'G

0086


. e: e I;; R ~l~c ~


Reagent ID

019074D01

019673P ······················-··------

Nitric Acid

Nitric Acid

Reagent Name

3N


Internal Work Order

18-06097 Analysis Code

GaGbT_ThSr Reagent

Concentration Analyst

ID

JPACHELLA

Run

1 Date

Recorded

7/10/2018

Reagent Grade JPACHELLA 7/10/2018

0087

/

6+-:> ~ Y7 ID f" o£jZZ ~()--,'.

l, ~~--1 ~--J,.-I-":

0088

SECTION VIII

ANALYTICAL DAT A (ISOTOPIC URANIUM)

0089


Analysis Sheet

Work Order 18-06097 Analysis Code l UUISO I

Run 1 Date Received 6/21/2018

Lab Deadline 7/11/2018

Client I AMO Environmental Decisions

Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA

Method EPA 908.0 Modified

Instrument Type Alpha Spectroscopy

Radiometric Tracer U-232

Radiometric Sol# U-10a

Tracer Act (dpm/g) 18.16

Carrier

Carrier Cone (mg/ml)

Internal Sample I Fraction Desc

i

01 LCS

02 MBL

03 DUP

04 DO

~

18-06097 UUISO Run 1

Client ID

LCS

BLANK



* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. " Indicates estimated SAF value.

** Actual mass exceeded the calibration curve range. Results should be qualified as appropriate.

I

I Login CPM

I 30

!

30

i


I

Sample Sample Date Aliquot

06/21/18 00:00 1.0000E+00

06/21 /18 00:00 1.0000E+00

06/20/18 10:00 1.0000E+00

06/20/18 10:00 1.0000E+00

0090

Eberline Analytical Oak Ridge Laboratory Analysis Sheet

Internal Sample Tracer Fraction Desc Aliquot (g)

01 LCS 1.1051

02 MBL 1.1017

03 DUP 1.0974

04 DO 1.1022

Tracer Total Radiometric Radiometric ACT(dpm) Tracer (pCi) %Rec

20.1 0.00

20.0 0.00

19.9 0.00

20.0 0.00

I


Grav Carrier I Grav Filter Added(ml) Tare (g) I

Grav Filter Final (g)

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.

•• Actual mass exceeded the calibration curve range. Results should be qualified as appropriate.

' Grav Filter Grav

Net(g) %Rec

i

i

I


I Mean SAF SAF %Rec 1* 2*

0091


Internal I Sample Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

Rough Prep I

Date I

Rough Prep ! Prep

By I

Date

I

07 /06/18 07:29

07 /06/18 07:29

07/06/18 07:29

07/06/18 07:29


Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

Sep to Date/Time

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. h Indicates estimated SAF value.


Sep tO By

Printed: 711012018 4:40 AM Page 3 of 3

Sep t1 Sep t1

Date/Time By

0092


Preliminary Data Report & Analytical Calculations

Work Order: 18-06097-UUISO-1 Printed: 7/10/2018 12:23 PM

Page 1 of 3

~ i::: ::, ~ a:

Cl) 0 b 0 u en -~ -U)

~ ::, ca i::: ::, <(

... -e 0

t: ~ ii <>

i ca C: <( ., .E ;:: ., t3 -~

II) C:

.2

.!!? (.) Q)

Cl ns ....

II C: Q)

E C: 0 ... ·s;: C: w 0 ~ <(

Lab Fraction --01 -----·

02 ------·

I· ~: I

1-~~.

Nuclide Sample

Desc

Client Identification

Activity Units

Results Error Estimate l MDA LCS

Known LCS ¾R

U-234

U-234

LCS

MBL

LCS

BLANK . .. ... . ~:: .. ;::;1 :~:~ .:::~:1 732E•:J:16

U-234 DUP OU-1-007 Outfall 007 DIS pCi/1 2.57E-01 I 1.50E-01 I 1.32E-01

-·--·--------····--1----··--··· ------+··--··-- ·· · I-···-···

U-234 DO OU-1-007 Outfall 007 DIS pCi/1 1.88E-01 I 1.1 SE-01 I 1.17E-01

----l ---------•---··-- - ----- ------·----t--··--~--

--··-····-·l---·---·---1---- ·

LCS Flag

OK

I

RPD Flag

NA

MDA Flag

OK

OK

OK

OK

Blank Flag

OK

--------·-+---··--···-+·--· -+-·--····---··--· +----- ------1-------1----1--· --+-----1--------j -----------l

- ---+---- -----j- I·-···- - ---- ···-·····----··----- ···l··-···---·----·-I··--···-···

·-----··--···t------ t---------·-1-·------j

····-----·-···--·--·-f-··-·-·-1·-·--

---··--···-l·------1----·-· ----i-------- -• ... --•·- 1------·····--·-·+··-·-··--·---· ···I-- ---+-- i -----1 ----+------+------!

1·---·-··-·····-1 ····--··---- ··--··--------+-----1---· ---···---·

0093

Eberline Analytical


( 11 .. ~o• r:I 01 02

i::

& I 03

Nuclide

U-234

U-234

U-234 ~

04 QI 0 "0 0 en 0 ,!!! -

U-234

i ::, (IJ

::, i:: <(

'-

~ 0 ~

~ ai


Work Order: 18-06097-UUISO-1

, Sample I Sample

I Sample Radiometric Grav Mean

SAF

Desc Date Aliquot % Rec %Rec %Rec

LC$ I 06/21/18 00:00 I 1.00E+00: 117.30 0.00 0.00

MBL I ::::::: :::: I ::::::1 116.21 o.oof o.oo

------···-·------- --------- ·---·---·-

i DUP 84.64 0.00 0.00

... -----+

DO I 06/20/18 10:00 1.ooE+oo[ 11~:3}J o.ool o.oo .. ----··- -----------·----·--------+--- --------~-

-+---------1 --- ----------------------- +------------ ----1--- --·--+-· -··. --~-·- e------ -----!-"'""

----+------- - --(-------------------+------- --------+----- -- ---- +

-+---------1---------------------- ------+-- ----------+- --- --


SeptO

I Sept1

Date/Time Date/Time

1 .. - ---i----- ----- --1 -------------- ----------------- ----"-------- --------f-- ---- - f-------------1------------+---------+----------+---------

C: <( ., .!: .:: 1------j----------------- ------+------------1------ ------------

., .Q

~~ U) C: 0 -------------- -.,._

-- ------r------ -- ---------------1- ------------------1--- ----------------t-------------1--- ----------+----------,

U)

·c::; Q)

1----------1---------------------- - --+-------!-- -------------- ------- ----------- --+---------j--- -------------- ---------1-----

Cl iii

--- -+----- -------1---- ------ ---i--------1----------- --- ---------- 1---- -----f-----------------------"-

-~I C: Q)

E C: 0 ... ·s;: C: w 0 ~ ~

0094

Eberline Analytical


~ Lab i

Nuclide Fraction I

01 I U-234

§ a:

.g 0 0 .r!,!

1 <ii C: C(

~

0 u, -::::, ::::,

02

03 ---- . -----

04 ---

------ - ---- --·-·-

----·-- ·------·---

--·----

U-234 ------------·--

U-234 --- -----

U-234

-------· ·-- -------- ----

------ ·------- -----····-------· -·--

----

Sample Desc

LCS ---··-~----

MBL --·------

DUP

DO

------

·---------

--·--~-

---~-·---~ ----- --~·----

---



Counting

i Halflife Count I 8kg

Detect Carrier Counts

Date/Time (days) Time i CPM

07/10/18 08:08 A_Spec Alpha_047i 170 ! 4.86 E+02 5.00 E-03 I

------·----··· -------·· -·------. -------------------- -------·-···---- .r-

170-16.64 E+00 07/10/18 08:08 A_Spec Alpha_048i 8.00 E-03

·------------ -- --- --- ----·--- -- " ---- _L l 1-----------~---I

110[1.28 E+01 07/10/18 08:08 A_Spec Alpha_049 7.00 E-03

-- ·---~-- ·-·-------- ·- ·-------- 1

07/10/18 08:08 A_Spec Alpha_050 17011.15 E+01 9.00 E-03

" - -- ----------·------··--

I ---·---····-·"·- - ------·--------- -··- ···-- ---·------------- -···- --·- -1-----

i

---- ---- -1--·---- --------·------ I --- -1 ----·-----·-----

!

·--··----·-----·. - -- ------------·---- --- --I - ---+

~---------- ··--------···-----·--···- -· ----··--·---------------··· ·---·-··-·· -------- - ' -- -!------I

·--------···------- -----··-- ------------ ------·-·---- ··- --·---------~------·--- ----

-----------·- -·····- ---- ·--·---- --···-----·------·- - - --·-----·----·-·-·· --·--·---- - --- --------

---------- ----- .. ------ ·----·--------··- ··-··-----·· t--- ····-·-. - - ---·- -------- - - - --- --- ·--···------- .. ----1·····-· --·-····--

-------- -- - ---------··--------- ----·~ ---··- --!-···- ... ---·------------·-· ··------·- --··---- ·-

1/) C: 0 ~-------- -····

-·--·-------- ----·---·- - --· ---·----··---·~·--···-- -···-··-----·------·----·-

:1!? 0 ·-·----·----··--- -··----- _____ ,. .. ____________ ---·----~· ----··-···--···---- .. ----,·------··· ---------··--· ··- -- ---·-··---···-· --- ·-·--···----·-----I .. --

Q)

Q

ni ----~-~--·--·- -------- ·--- -- ·----···------ ------··-··~ ------ ---·-·· ·--- ···-·- - - . . -- - ·- -- ·-- --- ----------·-· ·----· ----- ·-----·-----·--·-- ·---- _______ _,_ ---------

-i1 C: Q)

0 E C:

- -··---·------· ··----- -- ·--·-- --··-··----· -- ---··-·----·-·- -··-·------ - --· --- --------·------- ·-----·· --- -

0 ---------- t------ ---------· -----·····----··-- ------- ·----··- ------------- -··-·--···--- --·-- ---·--···--·-- -··--------- ···-· --··

I..

"> C: ·- ----~------------·- -· ·----···-·- -- - -- -·--··--····- --- ···-- ---·----·--------- -----·-·--- -·-----·-····

w 0 :ii!

---·----· ------------ --·-----·--· -·------- -----~-·----~-----··-··· ---··------·····-- ---·------------ -----~-·

<(

I

I


Eff

17.4 -·-----

17.6

15.6

13.7

0095


~ -. Lab Nuclide

Fraction

01 U-238

----- ---··--

02 U-238

_ Sample

Desc

LCS -

MBL



Client I Activity . I I LCS Results Error Est,rnate\ MDA

I Identification I Units Known

LCS pCi/1 6.43E+00 7.95E-01 6.18E-02 7.09E+00!

------------·------------ ---- - --··-------~-·

BLANK pCi/1 6.22E-02 6.33E-02 8.52E-02

~ &, ~ ------ --------··-~·-----···· - -··· --- - ·------------- . --------·------------------- ------ -------- ---------·---··--

03 U-238 DUP OU-1-007 Outfall 007 DIS pCi/I 2.79E-01 1.55E-01 1.26E-01

-· -----··-·--·---------- --- -- -------------·-·--·---· --------·----- ----·-·- ---····----·- ------------- - ···--·------

a, 0 'ti 0 0 U) -!!! -

04 U-238 DO OU-1-007 Outfall 007 DIS pCi/1 1.22E-01 9.17E-02 8.57E-02

------- --------- -------- -----·· ··-- ----·--- ····----- -·--·--····--- ---·-·-··-·------

--------· - ---------------- ----- --------- -, __

~ :::, ca C: :::, <(

···----------··-- . ·------------- ---- -···---------···· ·--- -··-----·-··--··-···- I····

-· ----··-----··--·-----------·- - . ---------- -······--·--- ------------· ·- ··-1-----·-------- -- ---- -------------- ---- -----

... ., 'E 0 --- --------------- -----------··- ------------· --------- -·-··---- ·---·· --------------··· ------ -----------~

t: ~ -------·-- -----·-------------- ·-----·--···--

... ________ ., ___________ ------!---------------

oi -~ ~ .. --- !----------- --- -------------

______ I _________ ··----·- -----· ------ ·----····-·--- -- ----- ---------------- -----------

C: <{ ., .s .:: --------·-------- --------------·- ------·--- ----- -- ---·----··-·--···~--~-------· -·-------- _,_ .... -···-- ---------------- -····---·----------·- -----···-

., ~ --~ ------·· t----- ---- -- ----------·-··----- ----------------- ·------- --·-··----- ··--·---- -- - --·· -----·-------- ···- ---·---··----

1/) C:

.2 ------····-···--·-- 1--·· -·- -··--·-----·--- ---~--------. -··---- ·------------------- ------ ·-·--- ----··------ ------- -··-· ----------· ----------·----

1/)


LCS I LCS

I RPO MDA Blank

i %R Flag Flag Flag Flag

90.66 OK OK -------

OK OK ---

NA OK ----------- ----------

OK

·-------

-------

------

-----

·c:; ------------ ------·-------·--·--- ---- •-~--•••-• •••--••-a-••-•-~--••••---•••••--••• •••• -------------. - -- ---- ------- --- ------------------ --------------- -

--------·-·--Cl)

C ca - ----·--- --- ---·-------- ··------------···-···- ---·------· ------- ----- ··-----·······--- ·------ ---- -·--- --· ------·-----

I

i1 C: Cl)

E C:

-------·--J.-..-..-------- --- ----------~------ ··--- -·-·- -------······-- - -·--·----·-·------- ---------·· ------ --·-----·-

0 -----··-- ---- -------- ---·---------- -------- --·-----···--···· --------- ----------- ---·· --· ,--··---- ---·--- ------ ------------- ----------------- --·-

... ·s; C: ----- ·-----------·- '••·- -·· ----------------- ---------·--·---···-~ ·------

w 0 :ii::

--- ------ --·-----·-· -- -- ------ -----------·----·- -- ---·-------

<(

0096

Eberline Analytical


Preliminary Data Report & Analytical Calculations Printed: 7/10/2018 12:23 PM Page 2 of 3

~ Lab

Fraction ,I

01 ---·-·----

02

03 - ... -·--

Cl> 0 b 0

Cl) 0

-~ -04

~ ::> Ill

::> C: c:(

~ 0 t: ~ iii " ~ ca C: <( Q)

=e Q) .Q

~~ "' C 0 ·; ·c:; Q)

C cu -~I C Q)

E C 0 .... > C w 0 :i! <(


Nuclide Sample Sample Sample

Desc Date Aliquot

U-238 LCS 06/21/18 00:00 1.00E+00

---------···--- """ ----·-- -·------··--· -------------. --

U-238 MBL 06/21/18 00:00 1.00E+00

U-238 --1 ~,; I 06/20118 '"" --· ---··· ·-- ,. -·--------·-------·-·---··-- -

U-238 DO 06/20/18 10:00

Radiometric

I Grav

%Rec %Rec

117.30 ______________ o.oo [_ ·-·--·

116.21 o.ooi

+ 84.64[ 0.00 ------- -- ---- .... - - l

118.31 0.001 --- - . - r

i '

Mean % Rec

SAF

o.ooj

SeptO Date/Time

o.oo[ . . -+ -----f---·---------------· r----- ..

o.ool

Sept1 Date/Time

... ·····1·· ===r~ --···--··--0.001 I

i ---·- ·-··---···

-~ i --

····'····--·····--····r··------------+-------- -·--···

·1 -·· - ---1--- I

i Ti ---+------1 .

-0 - - - f -~-t-_ -- -_, -r~1--+---l---·--·-1-------+--t -1----+--~ _ -j- - '

I

0097

Eberline Analytical




Page 3 of 3

~ -C: :l

"'""" a:

<I> 0 'tl 0 0 en ,!!? -~ Ill

:::, C: :::, c:(

,._ <D

'E 0 .,c ,._ ~ .. u

i .. c:: <t ., ~ ., ill -~

ti) C: .2 ti)

(.) Q)

C iu ......

~I C: Q)

E C: 0 ... "> C: w 0 :i: <(

Lab I Fraction

o-i7 02 I

03 -

04

Nuclide

U-238

U-238

U-238

U-238

II Sample

Desc

LCS

MBL

DUP

DO +-------

, ____ _, --- ---------------------!-----------

Counting

Date/Time

07/10/18 08:08

07/10/18 08:08

I Halflife

(days)

------1-------- --------------+-

07/10/18 08:08

Detect [-ca:e,-1

A_Spec I Alpha_047I

A_Spec Alpha_048

-+-

A_Spec I Alpha_049

Count

Time Counts

170/4.98 E+02

170/4.81 E+00

17011.40 E+01

i Bkg

I CPM

r 2.00 E-03

7.00 E-03 ~----

6.00 E-03

--- ------------1------------------- -- 1---------------- ---1-----------------1---------+-------+- -------

07/10/18 08:08 A_Spec I Alpha_050 170/7.49 E+00 3.00 E-03

------------1--------

---+------------·-- --1--------·----. I·-·---- .. ·------~----

I-----' ------------------1----------1---------- --------1--------------1------ --,-------------+------t----------1-----

1-----i------- -----4 ----- --+---------1~-·----~- -·-r

!

Eff

17.4 ---·----

17.6 -----··---~

15.6

13.7

1-----+-------------------i-------~---·····----

1-------1-------- ------------ --------1-- ---1-- ---- -------------1---------------1----------- -I----------------,------- ------J---------1

------------1---------- ---------------+---------- ------ ------1-------------------1---+--- ----1 ------+------I

------, ----------1--- --------1---------------------- - , __ _

----+ ··-------!-- ----------- ·-----··----·------+---- --------.-- 1-------·-·-·-··--·--- -·--!-

r-rr=+---- I I

_ I==-= a-~ a- -------+---- -l-----1 ·-------"'1 ~ --- . ·-------~---- ---· /--

-1- ----------1------

11-----'---- --e---l ------------------------------1------------------I--------------------- --+--

1-----+-- -------+--- !------------------------ ------I ------+------l-------4-----1-------1

-------/----------------- --1 --- --------- -- -----1------------ - - 1-----------1------ ----+-----~,-----

1------,-----------+---1---~------+---------------------1---- ---- ---- ----1----- ----+----

0098

Eberline Analytical


~ La~ I Nuclide

Fraction [

I 01 U-235

&I

Q> "O 0 u .!!,!

i "' r::: <:(

-~

-11~0_2 +

03

~,,~1 ::, => I 1------·-1--

___ .J_

II) C:

.Q II)

·o Cl)

C

s C: Cl)

E C: 0 ... "> C: w

l-·-·-·-··-1---

U-235 - -··

U-235

U-235

Sample Desc

LCS ·-· ·- -· ·-··--

MBL

DUP

DO ----- ---·--·



Client Activity Results Error Estimate MDA I

Identification Units ii

LCS pCi/1 4.78E-01 1.77E-01 6.68E-02]

--·---···-· ---·-- - ·----- ···- --·---- ··- ----· --····----··. -··+· BLANK i pCi/I 1.57E-02 4.63E-02 1.01 E-01 i

·--·---- I ··----·-----·--- --·--······--·- _J r ····- ····--·· ···--1.21 E-01 1.56E-01 !

OU-1-007 Outfall 007 DIS I pCi/1 1.23E-01 ··~·~ f OU-1-007 Outfall 007 DIS pCi/I 1.68E-02 4.02E-02 8.44E-02

--------·--·--- - - ----~---- -----········ --

-- - ------ ------- --------------·---

LCS LCS

Known %R

I

I

I

I_


I LCS RPD MDA

I Blank

Flag Flag Flag Flag

I I

OK

I I I OK I OK

I I NA i OK

I I OK

J I

-·---!----------- ---------+ ·---- ··~- ---j-------j------+-----+-----+-----+-------j

·--1···-· ·-· .. ···--1 ···--··-

·1-··-·--·· · -·-i·----·--·· ---··· .-----

1---··-··· ------------· . f---·-··-···-···--··+-·-·-·--·-·-·····--1-··--··--·--+-·---·····-j-------j------+-----+------+-------f-------l

0 :E <(

1------+--·---------------+--·-1---- -------- i---- ··-t---

0099

Eberline Analytical




Page 2 of 3

( Lab ] Nuclide I Sample I Sample

Fraction I Desc Date

01 U-235 I LCS I 06/21/18 00:00

Sample I

Radiometric

Aliquot % Rec

1.00E+00I 117.30

Grav

% Rec

Mean % Rec

0.001 0.00

SAF Sep to

DatefTime Sept1

Date/Time

c:: ::, ct:

GI ,:, 0 u .!!!

i Ill c:: q:

.... -~ u

--·----·--

02 I U-235 I MBL I 06/21/18 00:00 I

~

03 I U-235 I DUP I 06/20/18 10:00

~·---

04 I U-235

QII-en -::,

1.00E+00I 116.21

1.00E+00I 84.64

118.31

0.00/

I 0.001

I ·1

0.001

0.00

o.oo/ ... ---~· ··----·---~i

0.00

---------------- ... [--- -- ------

--------------1--------------1----------+-------------I

::, I I----- --1---- - --- ------+---------1------------ ---- -+------------------ -----+------ -- ··--~--------I

i

1/) C .2 1/)

·c3 Q)

C co .... C Q)

E C e '> C w 0 :E 4:

1--------- ---·----l-··--·-------------t----1--------------+-------------1

--- _______ ,_______ ---+---- -----+-------- -1---------------+

________ , _______ _

------ -------1--------------- ---1------------------------+-----. ------------+--------------------+--

. ------+-- -----------------------+-----------,

----+-------- .. -------------1---

l----1------------ -+------+------------------1----- -------- ---1------ ----------------1- --------------

0100

Eberline Analytical




~ Lab I Nuclide

Fraction

01 I U-235

--

02 I U-235 C:

"""'" :::i a: . L_?! __ J ___ U-235

U-235

Sample Desc

LCS

MBL

DUP

Counting

Date/Time

07/10/18 08:08

07/10/18 08:08 -·-------~---··-- ---------l- --·-

07/10/18 08:08

Halflife (days)

-----!-------- +---------

DO 07/10/18 08:08

~I O 11 04

-I -- -

-~ en · ------·--- -1 - -----------1 -----··--·---

(..)

"' ~ Ill C: q;

t: fi

-::> ::>

1/) C 0

.!!? 0 Q)

Cl

Jg C Q)

E C 0 ... ·s; C w 0 :E <(

t----------1··--······ -----··-+-----··-··I-· ·- ···-·-·····--·----··

IL ___ - -

~------- ------1--------- -··------ 1-----·-···. ·---·--·-··-·-··-J-·---·-··

1--------+------·----··-------·------1-··--· ____ , .... --

·+-

Detect Carrier

A_Spec Alpha_047

A_Spec Alpha_048

Count Time

Counts

17012.98 E+01

17019.80 E-01

Bkg CPM

• 1.00 E-03

Eff

17.4

·-·--·-,------, i6.00 E-03 17.6

A_Spec I Alpha_049 170[4.98 E+00 !6.00 E-03 15.6

A_Spec I Alpha_oso 170/ 8.30 E-01 i 1.00 E-03 13.7

- ·-·-· ------+-·· ·----·-·-1-------·-·· ----- - :- . ·--- ·-. ----

. -- ··-·--·-+·-·-··-·-·-+·•·---····---.---·· i-··- - ·--·

. --1· - --·-!- ---+----------!-----. ----+-----,

-~------ ----~1------·-·----f------------·-·------+...........- ____ _,_ _____ _,

""•+--

··I

·+···--·-

0101


~ . "

Lab Fraction

Nuclide

01 Total U

i:: ::, Q:

{; 0 (.)

,!(?

~ 'iij i::

"'(

!I

T-

=> => ..J II-

(fj C: 0

-~ (.) (I)

0 ~ -C: (I)

E C: 0 ... > C: w 0 :ii!: <(

02 Total U

03 Total U

04 Total U

Sample Desc

LCS

MBL

DUP

DO



Client Activity I LCS LCS

Identification Units Results Error Estimate MDA

Known %R

LCS ug/I 1.94E+01 2.37E+00 2.1 SE-01 2.11 E+01 91.71

BLANK ug/I 1.92E-01 1.90E-01 3.00E-01 ------·-- ~---------- -----

OU-1-007 Outfall 007 DIS ug/I 8.87E-01 4.65E-01 4.46E-01

OU-1-007 Outfall 007 DIS ug/1 3.71 E-01 2.73E-01 2.94E-01

-------··

---~----------

----··----- ---·-----·-- ---~-----·--

. -- --- ------ -------- -·----- -------- ------------ --

--------- ··-------- . ··-----·--------- --·--------. -------- -~----~--

------~--------- - ... -------·· ···- ·---- ---·-----··--~ -----·-··-------- ----···---------

--·------ ·----·--- --·----·-··--- ------ -··--·····

------

-·---~·--··-·-·-·--·-·-··· ------ ··---- ------~·-------· ·------·-~----

--·---- --·----······-----· --------·

--~-- ·---.. -----·---·-···· - --·---···--·---. --·-· ------·--·-

-·-----·-- -- ·----- ···--------·-·· ----·-··--·-···-- -·--·----~·---·-- -----~----

-·-··· ----·-·-·--· ---··--·· ----------

----··----- ---·--------·····-- ---···-·--------- -·--·-·---··---~ ---------------

··---~---------- -··-·- -------· ------ ------ --·····------··- -·-··----------- ---·------------ -----


LCS I RPD MDA Blank

Flag Flag Flag Flag

OK OK ----

OK INV -- ····-----·---

NA OK -·----·-

OK

--~----- ----·---------

----~-- ··-------

I ! i

-----

·····---·---

---- -------------

----·---- ---·-·-------

-·----·-·-

·--------

--------- ··----·-~--- ---------------- -·-----

--·----·- -----·---··---- - -·--· --- -----

-····-------- --- - ···--·----·--- ----------

-··----·-- - ··-··-----·. -·- - ------··-·-

-·--·------- --·····---- ---- -------

. ··-----·-·--- ----------

-----------

0102




(

Lab Fraction

01

Nuclide I Sample Sample

I Sample

I Radiometric

I Oesc Date Aliquot % Rec

Total U LCS 06/21/18 00:00 1.00E+00 117.30 --·---·---- ···--·-·- -------- ------

c: 02 Total U MBL 06/21 /18 00:00 1.00E+00 116.21

& """" 03 --~-------- -------------- - -··----- -·-------

Total U DUP 06/20/18 10:00 1.00E+00 84.64

··-·-···----·-----···------- ···-- -- . __ ., _____ - ... ··--------

.g ::) 04 Total U DO I 06/20/18 10:00 1.00E+00 118.31 ---- --·-----~ -----

8 => -~ ..J j t-q; t-

,._

-e 0 ~

~

'" .,__ ___ _____, _____________ -1--------1---·------------------- ----1 ---- · ---------1-- ----1--

! ., C: "( Q)

~ Q)

i'il -~

rn C 0

.!!l (.) Q)

Cl

1: I ~ ,!!:? Q)

u E C 0 ... ·s: C w 0 :E <(

--- --t-------------1------1------------- ----------····-·--1

l--------·----1--------- ---------1--------

1-----+-------- --1----1-----------·---····

+-------1---- -·-------- --+---

Grav

% Rec

0.00 ...... -- ---·-·-·

0.00

0.00 ----------

0.00

I·---

Mean

''lo Rec

0.00

0.00

SAF

-- I ______ ---·

0.00

Sep to Date/Time

7 I

--i--

····-·-·-··--1------------- --- ··--···-···

---

I

. ------\---· ----·····- -- --1-------·------···-- -·-------·--- - I

.. - -1- -----···· ·-·---- 1- ----------

Sep 11 Date/Time

- -·-

-·-····----~

---·-- - ------------

----~---

---1------------- --1 -1--------- --------1------------

---1--

i-----·-- --- ·---------------------------1 ·· ------- ----

0103


~ .

'

Lab Nuclide

Sample

Fraction Desc

01 Total U LCS

C: ::i a::

{: 0 (.)

,!!l

~ "' C:

'<I;

t 'E 0

~ ~

l "' c:: <,:

"' ~ ., 6l

1: .!!,? u

""""

::::> ::::> ..J II-

VI C: 0 VI (,) Q)

Cl

ctl ..... C: Q)

E C: 0 ... > C: w 0 ~ <(

-----·---

02 ~-

03 -~--------- -

04 ------------····

-------

------------

-· ----~------- ~----- -

Total U MBL ·-~~·

Total U DUP --·--- ·--~

Total U DO ·--

- ·---·-···-·-

. ---·

---.. -·-~--------------

-·

--------·--------·--~ ----

+--·--------···--

----···---·--

--·-··-----··---·--- --···------·

·····------·---- ·-·--··-··---



Counting Halflife Count Counts

Bkg Eff

Date/Time (days) Detect Carrier

Time CPM

07/10118 08:08 A_Spec Alpha_047 170 4.98 E+02 2.00 E-03 17.4

-- ···-·-,.-- ---·· --------- - I-···-· _,, ______ ·--------- ---- ---------· ----- ---·-·-···--- ··------I·. -- ·-·------- -- ------

07/10/18 08:08 A_Spec Alpha_048 170 4.81 E+00 7.00 E-03 17.6

-··-------- - ... ----------- -- - ·---------- ----·--·- ·----···------- - ·----~--------···- --- ----------···----

07110118 08:08 A_Spec Alpha_049 170 1.40 E+01 6.00 E-03 15.6

•·--· ~- ····---- -- ---·------ -- ------------ --·-· ------- -- ---------··----- -------· --------·--- -----·----

07/10118 08:08 A_Spec Alpha_050 170 7.49 E+00 3.00 E-03 13.7

---·--------·------- ·-···-···----- -------···- ------·---- - ..... .. _, .... , . -,·-·-

----- --··------ -- --------··-------- -----···------- . --· , ...... __ ...... -

---------···· ... -----·····-·-1--- '' .... __ , ....... ---- ---- -··· ,-~

--·-----·--- -----------·---- ---·------------ ·-·--· .. ····-· - . ·····-I·------------·-·-----

-------·---~----··-· --- ----- --··-··- - ---·-·-----·----- -·-·-···---- -- . -----· -------··---- ... ,.-... --- -·-

--------------- -------·1-· ·-·····"" ""•--

, ... ···-•-· .. --···

. ·-----·· ------ --·-- - --·-··-- -·--- -· --·-- ••-.--· , .... ,~_ .... _ ....... -

---·-··----- .... ,,,,. --- -- .... .. ··-·----

,_., __ . -------·····--·- -- ·---· --··-··-··--- ....... .... ______ ,,

- ·---------- ---~-----·-·· ... - I··- --·--···-·----- .... ----- . ------- ··---'---· __ _, ---- --·-- -·-···--

- ... ···---- --·------------ --··

- -- ---· --····--- ------·- -------- -------

--··----- ,, ..... - .......... ----- , .. - ·-- ,., .... ... _ .... ..... ,.__,

..... ---------- ---···· ---·-------

_,.,_, ... . -------- ---- --···-· ---- --------- ---····---- -·--·· ----- . --- ------·- ---··-········-----·-- -· - -·

..... "'"""""" . --- -- ·--· ......... ------- ---···· .... --.-· .. ··- ·--'-·

0104

~/cp

Count Room Report Client: AMO Environmental Decisio

18-06097-UUISO-1 (pCi/1) in WA

Tracer ID: U-1 0a

Printed: 7/1012018 4:40 AM Page 1 of 1

Internal Sample Client Sample Sample I Tracer Tracer Radiometric Ii Radiometric ! SAF SAF

Fraction Desc ID Date Aliquot I

Aliquot (g) ACT (dpm) Tracer (pCi) % Rec 1* 2*

01 LCS LCS 06/21/18 00:00 1.0000 1.1051 20.0686 0.00

02 MBL BLANK 06/21/18 00:00 1.0000 1.1017 20.0069 0.00

03 DUP OU-1-007 Outfall 007 DIS 06/20/18 10:00 1.0000 1.0974 19.9288 0.00

04 DO OU-1-007 Outfall 007 DIS 06/20/18 10:00 1.0000 1.1022 ' 20.0160 0.00 [

i

0105


Spike and Tracer Worksheet

Analysis Code Date Technician

UUISO 7/6/2018 7:25 JHARVEY

LCS MS LCSD l MSD 1 LCS MS

lsoto e I So/ # , Activity I Solution 1

1

ApP_r~x Volume Volume

p i dpm/g I Date Addition Used (g) Used (g) Volume I Volume l Known

I Error Added Error

Used(g) Used(g) pCi Estimate pCi Estimate

U-234 / U-8a / 32.0oo/ 7/6/2018/ 0.550 0.5080 7.32/ 0.264 0.00 0.000

U-238 I U-8a I 31.oool 7/6/20181 0.550 0.5080 7 09] 0.255 0.00 0.000

Tracers Balance Printer Tapes

fraction I Isotope So/# Activity Solution Volume Approx Tracer dpmlg Date Used(g) Addition

01 U-232 U-10a 18.160 7/6/2018 1.1051 1.1000

02 U-232 U-10a I 18.160 7/6/2018 1.1017 1.1000

03 U-232 U-10a 18.160 7/6/2018 1.0974 1.1000

04 U-232 U-10a 18.160 7/6/2018 1.1022 1.1000

I

Version 2.0 08/99

Page 1 of 1 Printed: 7/6/2018 7:29 AM

Witness Initials

LCSD -MSD Known i Error Added Error

pCi I Estimate pCi Estimate

0.00 1 0.000 0.00 0.000

0 OOi 0.000 0.00 0.000

LCS

Matrix Spike

0106

Lab



Fraction Client ID

01 LCS

02 BLANK

03 OU-1-007 Outfall 007 DIS


Comments

Sample

Type

LCS

MBL

DUP

DO

Aliquot Worksheet

Analysis Code Rpt Units Lab Deadline

UUISO liters 7/11/2018

Muffle Data Dilution Data Aliquot Data

Ratio Post/Pre No of Dils Oil Factor Ratio Aliquot Net Equiv

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

1.0000E+OO 1.0000E+OO

Techaiciaac ~al\lC,ff atec '.::/-; a

Technician

JHARVEY

MS Aliquot Data

Aliquot Net Equiv


H-3 Solids Only Water Aclcleu H3-D1st-

(ml) Aliq

i

0107

Sample Description: Spectrum File: Batch Identification:

SPIKE \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167

1806097A-UU Sample Identification: Sample Geometry: Procedure Description:

Detector Name: Chamber Serial Number: Detector Serial Number: Env. Background: Reagent Blank:

Sample Size: Sample Date/Time: Acquisition Date/Time: Acquisition Live Time: Acquisition Real Time:

Tracer Certificate: Tracer Quantity: Effective Efficiency:

01 Shelf 2 U iso

Alpha_047 10006125A 91086 System Bkgd 219035

<not performed>

l.000E+000 7/10/2018 7/10/2018

+/- 0.000E+000 liter 5:51:27 AM 8:08:05 AM

170.0 minutes 170.0 minutes

U232 UU-l0A 1.105 mL 0.2046 +/- 0.0091

Counting Efficiency: 0.1744 +/- 0.0030 on 6/6/2018 1.1730 +/- 0.0558

2:37:41 PM

Chem. Recovery Factor:

Control Certificate Name: NatU U-8A Chem. Recov. of Control: U-238 0.797558 +/- 0.055693

Peak Match Tolerance: 0.150 MeV

Nuclide

U-232 T U-234 U-235 U-238

Energy (MeV)

5.277 4.734 4.379 4.159

PEAK AREA REPORT

Net Pk Area

697.98 486.15

29.83 497.66

Pk Area Error%

7.43 8.90

36.01 8.79

Ambient Backgnd

1. 02 0.85 0.17 0.34

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

8.4 37.0 3.7

36.9

T Tracer Peak used for Effective Efficiency

Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.995 0.995 1.000 0.995

NUCLIDE ANALYSIS RESULTS

Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*

Activity (pCi/liter)

9.06E+000 +/- 7.87E-001 6.31E+000 +!- 7.85E-001 4.78E-001 +/- l.77E-001 6.43E+000 +/- 7.95E-001

1-t-t 1/o/fg

MDA (pCi/liter

8.18E-002 +!- 7.l0E-003 7.77E-002 +/- 6.75E-003 6.68E-002 +/- 5.81E-003 6.18E-002 +!- 5.37E-003

0108

60

55

50

45

40

35 V} .j-J C ::::s 8 30

25

20

15

10

5

0 I

3500 4000

I if

l.orii M.' I ~1.,1 =?.I ]J,1

- [,

11 I

ROI Type: 1

4500

0000216758.CNF

5000 Energy(kev)

I 11

1,1\,1 i'! 11

i lrJ

iii I I

5500

Live Time :10200.000 sec Real Time :10200.400 sec start: 1:3453.S(kev) stop : 1024:6472.?(kev) Acq. start :Tue Jul 10 08:08:05 2018

6000

ROI Type: 3

0109

Channel Data Report 7/10/2018 11:07:54 AM Page 1

******************************************************* ***** s p E C T R A L D A T A R E P O R T ***** *******************************************************

Sample Title: 01

Elapsed Live time: 10200 Elapsed Real Time: 10200

Channell------l-------l-------l-------1-------1-------1-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 1 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 1

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 1 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 1 0 0 0 0 1 1

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 1 0 0

153: 0 1 1 0 0 0 0 1

161: 1 0 0 0 1 0 1 1

169: 1 0 0 1 0 0 0 0

177: 1 0 1 1 2 0 1 1

185: 2 1 2 2 2 1 0 1

193: 1 1 1 0 1 1 1 0

201: 1 1 0 2 2 1 4 2

209: 5 3 3 2 2 3 2 2

217: 2 3 1 7 7 2 4 6

225: 7 5 7 6 6 13 4 4

233: 10 9 5 16 12 7 8 12

241: 13 14 12 12 20 13 14 14

249: 16 11 13 10 10 10 18 11

257: 11 13 11 10 7 7 7 4

265: 2 1 0 0 0 0 1 0

273: 0 0 0 0 0 1 0 0

281: 0 1 1 1 0 0 0 2

289: 0 0 0 1 0 0 0 0

297: 2 0 1 0 0 0 0 3

305: 1 0 0 0 1 0 1 1

313: 1 2 0 1 0 1 1 0

321: 1 0 3 1 0 0 0 0

329: 1 1 0 1 1 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 1 0 1 0 0

353: 0 0 0 0 0 2 0 1

361: 1 0 0 0 0 1 0 0

0110


369: 0 1 0 2 0 0 0 2

Sample Title: 01

Channell------l-------l-------1-------1-------1-------I-------I-------I 377: 1 0 3 2 1 2 0 3

385: 0 0 3 2 1 1 1 0

393: 3 0 1 2 0 2 1 1

401: 0 0 1 4 4 4 0 1

409: 3 4 3 3 4 2 5 7

417: 3 5 7 10 5 5 11 11

425: 5 10 9 9 14 11 9 6

433: 12 10 15 8 9 15 12 14

441: 13 12 18 14 11 14 12 13

449: 20 6 12 16 14 10 3 8

457: 4 2 0 1 0 1 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 1 0 0 0

481: 0 0 0 0 0 0 1 0

489: 0 0 0 0 0 0 0 1

497: 0 0 0 0 0 1 0 0

505: 0 0 0 0 0 0 1 1

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 1 0 0

529: 1 0 0 1 0 0 0 0

537: 0 0 0 4 1 0 0 1

545: 0 1 0 0 0 0 1 0

553: 2 0 1 1 0 0 1 2

561: 1 3 0 0 1 1 2 1

569: 1 0 2 0 1 1 4 2

577: 3 2 2 5 1 1 2 2

585: 2 2 3 5 2 4 8 5

593: 2 2 5 11 3 3 3 6

601: 7 4 4 8 10 10 10 16

609: 12 14 6 25 16 20 10 17

617: 14 14 13 15 16 12 18 26

625: 13 18 20 20 17 20 26 22

633: 24 19 23 9 20 7 11 5

641: 10 5 2 0 0 1 0 0

649: 0 0 1 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0111


801: 0 0 0 0 0 0 0 0

Sample Title: 01

Channell------l-------1-------1-------1-------I-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 1 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0112


BLANK \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167 1806097A-UU

Sample Identification: Sample Geometry: Procedure Description:




02 Shelf 2 U iso

Alpha_048 10006125B 83111 System Bkgd 219036

<not performed>

l.000E+000 +!- 0.000E+000 7/10/2018 5:51:27 AM

7/10/2018 8:08:07 AM


0.0091

liter

Counting Efficiency: Chem. Recovery Factor:

U232 UU-l0A 1.102 mL 0.2045 +/-0.1760 +/-1.1621 +/-

0.0030 on 6/6/2018 0.0554

2:37:42 PM

Peak Match Tolerance:

Nuclide

U-232 T U-234 U-235 U-238

Energy (MeV)

5.295 4.777 4.368 4.143

0.150 MeV

PEAK AREA REPORT

Net Pk Area

695.62 6.64 0.98 4.81

Pk Area Error%

7.45 84.69

294.85 101.48

Ambient Backgnd

2.38 1. 36 1. 02 1.19

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

39.1 3.0 3.0 3.0


Nuclide

U-232 U-234 U-235 U-238

Id Conf.

1.000 0.998 0.998 0.988


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*

Activity (pCi/liter )

9.03E+000 +/- 7.86E-001 8.62E-002 +!- 7.34E-002 l.57E-002 +/- 4.63E-002 6.22E-002 +!- 6.33E-002

l1Gr 1/10/rt

MDA (pCi/liter

1. 06E-001 +!- 9.26E-003 8.90E-002 +/- 7.75E-003 l.0lE-001 +/- 8.78E-003 8.52E-002 +!- 7.41E-003

0113

60

55

50

45

40

35 Vl +-' C: :::::s

8 30

25

20

15

10

5

0 I

3500 4000

!.Ml

4500

ROI Type: 1

0000216759.CNF

I

I_,\ 1:'. I:

5000 Energy(kev)

i h

! 'I

5500

Live Time :10200.000 sec Real Ti me : 10200. 400 sec Start: 1:3443.9(kev) Stop : 1024:6472.3(kev) Acq. Start :Tue Jul 10 08:08:07 2018

6000

ROI Type: 3

0114


******************************************************* ***** s p E C T R A L DAT A R E p 0 R T ***** *******************************************************

Sample Title: 02


Channell------l-------l-------l-------1-------1-------1-------I-------I 1 : 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 1 0

201: 0 0 0 1 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 1

249: 0 0 0 1 0 1 0 0

257: 0 0 0 0 0 0 0 0

265: 0 1 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 1 0 0

313: 0 0 0 1 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0115


369: 0 0 0 0 0 0 0 0

Sample Title: 02

Channel\------\-------\-------\-------\-------\-------\-------\-------1 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 1 0 1 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 1 0 0

449: 0 1 0 0 0 0 0 0

457: 0 0 0 0 0 2 0 1

465: 0 0 0 0 0 0 1 0

473: 0 0 0 0 0 0 0 0

481: 1 0 0 0 0 0 0 0

489: 0 1 0 0 1 0 0 0

497: 0 1 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 1 0 0 0 0 0 0

521: 0 1 0 1 0 0 1 0

529: 0 0 0 0 1 0 0 0

537: 1 0 0 0 0 0 0 0

545: 0 0 0 0 1 0 1 0

553: 0 1 0 0 1 0 0 1

561: 0 0 1 0 2 3 0 0

569: 0 0 0 2 0 1 3 1

577: 1 0 2 2 1 2 1 0

585: 2 3 1 1 2 2 2 3

593: 1 3 6 3 2 3 3 1

601: 7 4 4 6 6 2 5 6

609: 6 7 9 14 12 12 8 10

617: 6 13 16 11 12 15 13 19

625: 16 14 9 18 11 16 16 18

633: 22 25 23 30 28 27 27 21

641: 24 30 15 14 14 3 5 1

649: 1 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 2 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 1 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0116


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------1-------1-------1-------I-------I-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 1 1 0 1 0 0 1 0

977: 1 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0117

Sample Description: Spectrum File: Batch Identification: Sample Identification: Sample Geometry: Procedure Description:



Tracer Certificate: Tracer Quantity: Effective Efficiency: Counting Efficiency: Chem. Recovery Factor:


Nuclide

U-232 U-234 U-235 U-238

T

Energy (MeV)

5.265 4.722 4.405 4.133

OU-1-007 OUTFALL 007 DIS DUP \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167 1806097A-UU 03 Shelf 2 U iso


<not performed>

1.000E+000 6/20/2018 7/10/2018

+/- 0.000E+000 liter 5:51:27 AM 8:08:01 AM


U232 UU-l0A 1.097 mL 0.1325 +/- 0.0070 0.1565 +/- 0.0028 on 2/16/2018 12:37:01 PM 0.8464 +/- 0.0471

0.150 MeV

PEAK AREA REPORT

Net Pk Area

448.77 12.81

4.98 13.98

Pk Area Error%

9.29 57.66 97.79 54.61

Ambient Backgnd

3.23 1.19 1. 02 1. 02

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

38.9 3.0 3.0 3.0


Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.990 0.989 0.997 0.981


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*


9.00E+000 +/- 9.30E-001 2.57E-001 +!- 1.50E-001 l.23E-001 +!- 1.21E-001 2.79E-001 +/- 1.55E-001

/rG

1fo/rs

MDA (pCi/liter

l.83E-001 +!- l.89E-002 l.32E-001 +!- 1.36E-002 1.56E-001 +/- l.61E-002 l.26E-001 +!- 1.30E-002

0118

60

55

50

45

40

35 V)

-I-' C: ~

8 30

25

20

15

10

5

0000216760.CNF

!I ! )I

'' ~

1l ii

7

0 q I I! !I 1! !I'"' •, ,,, . ' I i' ~I l I ' . ! i I I .' ' •. · ·•·"· I· · 1 1 '' ! ! 1 l 500 .. I 1 1

: 1 1 F 1 1 I I I I I 111111 1 I/: I

4000 4500 5000 Energy(kev)

5500

ROI Type: 1

Live Time :10200.000 sec Real Time :10200.300 sec start: 1:3474.l(kev) Stop : 1024: 6513, l(keV) Acq. Start :Tue Jul 10 08:08:01 2018

I I 1 I 1! I ! ! 1 l 6000 6500

ROI Type: 3

0119



Sample Title: 03


Channel\------l-------l-------1-------1-------1-------I-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 1

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 1

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 1 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 1

177: 0 0 0 0 1 0 0 0

185: 0 0 0 0 0 1 0 1

193: 0 0 0 0 0 0 0 1

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 1 1 0 0 0 0

225: 0 0 0 0 1 1 1 1

233: 0 1 0 0 0 1 1 0

241: 0 1 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 1 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 1 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 1 0 1 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 1 0 0 0 0 0 0

329: 0 0 1 0 0 0 1 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 1 0

361: 0 0 0 0 0 0 0 0

0120


369: 0 1 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------1-------1-------1-------I-------I-------I 377: 0 0 0 0 0 0 0 0

385: 1 0 0 0 0 0 0 0

393: 0 0 0 0 1 0 0 0

401: 0 0 0 0 1 0 0 0

409: 0 0 0 0 1 0 1 0

417: 0 0 0 0 0 0 1 1

425: 1 0 0 0 1 0 2 0

433: 0 1 0 0 0 0 0 0

441: 1 1 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 1 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 1 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 0 0

529: 1 0 0 0 0 0 0 0

537: 0 0 1 1 0 0 2 1

545: 0 0 1 0 0 2 0 0

553: 1 0 3 0 0 0 1 0

561: 2 1 0 0 1 4 3 2

569: 1 3 4 2 3 4 1 3

577: 2 4 1 1 5 4 4 3

585: 4 4 4 3 4 6 4 9

593: 8 3 7 10 11 13 8 11

601: 11 11 12 5 11 4 13 13

609: 14 15 13 13 14 18 14 14

617: 11 14 17 5 12 12 8 4

625: 4 0 2 0 1 2 1 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0121


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------1-------1-------1-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 1 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 1 0

945: 0 0 0 0 0 0 0 0

953: 1 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0122




Tracer Certificate: Tracer Quantity: Effective Efficiency: Counting Efficiency: Chem. Recovery Factor:


Nuclide

U-232 T U-234 U-235 U-238

Energy (MeV)

5.281 4.742 4.385 4.137

OU-1-007 OUTFALL 007 DIS \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167 1806097A-UU 04 Shelf 2 U iso


<not performed>

l.000E+000 6/20/2018 7/10/2018

+/- 0.000E+000 liter 5:51:27 AM 8:08:03 AM


U232 UU-l0A 1.102 mL 0.1620 +/- 0.0078 0.1369 +/- 0.0025 on 2/16/2018 12:37:00 PM 1.1831 +/- 0.0612

0.150 MeV

PEAK AREA REPORT

Net Pk Area

551.15 11.47

0.83 7.49

Pk Area Error%

8.36 62.23

239.53 74.41

Ambient Backgnd

0.85 1.53 0.17 0.51

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

29.2 4.4 3.0 3.0


Nuclide

U-232 U-234 U-235 U-238

Id Conf.

0.997 0.997 1.000 0.984


Energy (keV)

5302.50* 4761.50* 4385.50* 4184.40*


9.04E+000 +/- 8.58E-001 l.88E-001 +/- 1.18E-001 l.68E-002 +/- 4.02E-002 l.22E-001 +/- 9.17E-002

N, 7/rofrg

MDA (pCi/liter

9.82E-002 +/- 9.33E-003 l.17E-001 +/- l. llE-002 8.44E-002 +/- 8.0lE-003 8.57E-002 +/- 8. 13E- 003

0123

60

55

50

45

40

35 V) ...., C ::::i;

8 30

25

20

15

10

5

0 I

3500

'1

,\ :\/ i1}fj~

4000

ROI Type: 1

= ~ ' ::,

4500

0000216761.CNF

5000 Energy(kev)

~ = ' ::,

5500

Live Time :10200.000 sec Real Time :10200.300 sec Start: 1: 344 7. 7 (kev) Stop : 1024:6482 .6(kev) Acq. Start :Tue Jul 10 08:08:03 2018

6000

ROI Type: 3

0124


******************************************************* ***** s p E C T R A L D A T A R E p 0 R T ***** *******************************************************

Sample Title: 04


Channell------l-------1-------1-------1-------I-------I-------I-------I 1: 0 0 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 1 0 0 0 0 0 0 0 49: 0 0 0 0 0 0 0 0

57: 1 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0 73: 0 0 0 0 0 0 0 0 81: 0 0 0 0 0 0 0 0 89: 0 0 0 0 0 0 0 0 97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0 113: 0 0 0 0 0 0 0 0 121: 0 0 0 0 0 0 0 0 129: 0 0 0 0 0 0 0 0 137: 0 0 0 0 0 0 0 0 145: 0 0 0 0 0 0 0 0 153: 0 0 0 0 0 0 0 0 161: 0 0 0 0 0 0 0 0 169: 0 0 0 0 0 0 0 0 177: 0 0 0 0 0 0 1 0 185: 0 0 0 0 0 0 0 0 193: 0 1 0 0 0 0 0 1 201: 0 0 0 0 0 0 0 0 209: 0 0 0 0 0 0 0 0 217: 0 1 0 0 0 0 0 0 225: 0 0 0 0 0 0 0 0 233: 0 0 0 0 0 0 0 0 241: 0 0 0 1 0 0 0 1 249: 0 0 1 0 0 0 1 0 257: 1 0 0 0 0 0 0 0 265: 0 0 0 0 0 0 0 0 273: 0 0 0 0 0 0 0 0 281: 0 0 0 0 0 0 0 0 289: 0 0 0 0 0 0 0 0 297: 0 0 0 0 0 0 0 0 305: 0 0 0 0 0 0 0 0 313: 0 0 0 0 1 0 0 0 321: 0 0 0 0 0 0 0 0 329: 0 0 0 0 0 0 0 0 337: 0 0 0 0 0 0 0 0 345: 0 0 0 0 0 0 0 0 353: 0 0 0 0 0 0 0 0 361: 0 1 0 0 0 0 0 1

0125


369: 0 0 1 0 1 0 0 1

Sample Title: 04

Channell------l-------l-------l-------l-------1-------1-------1-------\ 377: 0 0 0 0 0 0 0 0

385: 1 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 1 0

409: 0 0 0 0 0 0 0 1

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 1 2 0 0

433: 0 0 0 0 0 0 1 0

441: 1 0 0 1 2 0 0 0

449: 0 1 1 0 0 0 0 0

457: 0 1 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 1 0 0 0 0 0

481: 0 0 0 1 0 0 0 0

489: 0 0 1 0 0 0 2 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 1 0

513: 0 0 0 0 0 0 1 0

521: 0 0 0 0 0 0 0 1

529: 0 0 0 0 0 1 0 0

537: 0 0 0 1 1 0 0 0

545: 0 0 0 0 0 0 0 1

553: 0 0 1 0 0 0 1 0

561: 1 0 0 2 0 0 2 1

569: 0 2 1 0 0 1 1 0

577: 2 1 2 4 2 4 0 1

585: 1 2 2 2 2 1 3 3

593: 2 1 6 2 3 5 4 1

601: 4 7 12 6 1 9 12 12

609: 10 7 15 11 8 10 11 15

617: 12 9 15 10 14 10 13 12

625: 12 19 21 17 26 22 19 19

633: 18 17 13 13 10 13 7 1 641: 1 0 1 0 0 0 0 0 649: 0 0 0 0 0 0 0 0 657: 0 0 0 0 0 0 0 0 665: 0 0 0 0 0 1 0 0

673: 0 1 0 0 0 0 0 0 681: 0 0 0 0 0 0 0 0 689: 0 0 0 0 0 0 0 0 697: 0 0 0 0 0 0 0 0 705: 1 0 0 0 0 0 0 0 713: 0 0 0 0 0 0 0 0 721: 0 0 0 0 0 0 0 0 729: 0 0 0 0 0 0 0 0 737: 0 0 0 0 0 0 0 0 745: 0 0 0 0 0 0 0 0 753: 0 0 0 0 0 0 0 0 761: 0 0 0 0 0 0 0 0 769: 0 0 0 0 0 0 0 0 777: 0 0 0 0 0 0 0 0 785: 0 0 0 0 0 0 0 0 793: 0 0 0 0 0 0 0 0

0126


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------j-------1-------1-------1-------j-------l-------l-------l 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 1 0 0 897: 0 0 0 0 0 0 0 0 905: 0 0 0 0 0 0 0 0 913: 0 0 0 0 0 0 0 0 921: 0 0 0 0 0 0 0 0 929: 0 0 0 0 0 0 0 0 937: 0 0 0 0 0 0 0 0 945: 0 0 0 0 0 0 0 0 953: 0 0 0 0 0 0 0 0 961: 0 0 0 0 0 0 0 0 969: 0 0 0 0 0 0 0 0 977: 0 0 0 0 0 0 0 0 985: 0 0 0 0 0 0 0 1 993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0 1009: 0 0 0 0 0 0 0 0 1017: 0 0 0 0 0 0 0 0

0127

Page 1 of 2 7/10/2018 5:36:53 AM

/'") I\ Cl II\ Al\ 11 I\ DV or::::onoT ~It VVIIIIIVlrH \ I I \l-1 \../I\ I

Review Of QA Results - Pulser Check

Date : 7/10/2018 Time : 5:36:53 AM

CHAMBER DEVICE PARAMETER FLAG DATE

Alpha 001 2lf ALL Not Done


Alpha 003 2lf ALL Passed 7/10/2018 5:16:04 AM














Alpha 033 Alpha Analystl 00DC Peak Energy Action 7/10/2018 5:16:10 AM

Alpha 034 Alpha AnalystlO0DC ALL Not Done

Alpha 035 Alpha Analystl00DC ALL Passed 7/10/2018 5:16:11 AM


Alpha 037 Alpha Analystl00DC ALL Not Done

Alpha 038 Alpha Analystl 00DC ALL Not Done

Alpha 039 Alpha Analystl 00DC PeakFWHM Action 7/10/2018 5:16:14 AM


Alpha 041 Alpha Analyst I 00DC ALL Passed 7/10/2018 5:16:17 AM


Alpha 043 Alpha AnalystlO0DC ALL Not Done




Alpha 047 Alpha Analystl 00DC ALL Passed 7/10/2018 5:16:25 AM


Alpha 049 Alpha AnalystlO0DC ALL Passed 7/10/2018 5:16:28 AM




Alpha 053 Alpha Analystl00DC PeakFWHM Action 7/10/2018 5:16:35 AM






0128

Page 2 ot 2 Kev1ew ot UA Kesutts - t'ulser 1..;necK 7/10/2018 5:36:53 AM


Alpha 059 Alpha Analyst 1 00DC ALL Passed 7/10/2018 5:16:44 AM

Alpha 060 Alpha Analvstl00DC ALL Passed 7/10/2018 5:16:47 AM

APPROVED BY:

APPROVAL DATE: "])I_O/t8

0129

Library Listing Report 6/12/12 12:17:04 PM Page 1

*************************************************************************

***** L I B R A R Y L I S T I N G R E P O R T *****

*************************************************************************

Nuclide Library Title: Uranium

Nuclide Library Description: U-232,-234,-235,-238

Nuclide Half-Life Energy Energy Yield Yield

Name (Seconds) (keV ) Uncert. (keV ( % ) Uncert. (Abs.+-)

U-232 2.174E+009 5302.500* 0.000 99.8000 0.0000

U-234 7.731E+Ol2 4761.500* 0.000 99.8000 0.0000

U-235 2.221E+016 4385.500* 0.000 80.9000 0.0000

U-238 1.410E+Ol7 4184.400* 0.000 100.2300 0.0000

* :=, key line

TOTALS: 4 Nuclides 4 Energy Lines

0130

SECTION IX

ANALYTICAL DATA (ISOTOPIC THORIUM)

0131


Work Order 18-06097

Analysis Code [~·Th ISO.. 7 Run 1

Date Received 6/21/2018



Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA



Radiometric Tracer Th-229

Radiometric Sol# Th-18a

Tracer Act (dpmlg) 22.46

Carrier

Carrier Cone (mglml)


01 LCS

02 MBL

03 DUP

04 DO

18-06097 ThlSO Run 1

Client ID

LCS

BLANK



• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.


Login CPM

30

30



06/21/18 00:00 1.0000E+00

06/21/18 00:00 1.0000E+00

06/20/18 10:00 1.0000E+00

06/20/18 10:00 1.0000E+00 I

!

0132


Internal Sample Tracer

Fraction Desc Aliquot (g)

01 LCS 0.4656

02 MBL 0.2332

03 DUP 0.2319

04 DO 0.2310

Tracer Total Radiometric I Radiometric ACT(dpm) Tracer(pCi) %Rec

10.5 0.00

5.2 0.00

5.2 0.00

5.2 0.00


Grav Carrier I Grav Filter

Added(ml) Tare (g) Grav Filter Final (g)

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.


I I

I

Grav Filter Grav I

Net (g) ¾Rec I

I


Mean SAF SAF ¾Rec 1* 2*

0133


Internal Sample Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Rough Prep Prep

Date By Date

07 /06/18 07:25

07/06/18 07:25

07 /06/18 07:25

07/06/18 07:25


Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

Sep to Date/Time

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.


Sep to By

I


Sep t1 Sep t1 Date/Time By

0134



Work Order: 18-06097-ThlSO-1 Printed: 7/10/2018 12:14 PM

Page 1 of 3

~ ®

C: ::, a::

~ 8 -!!! (I)

~ 111 C: <t

~I

"C""'"

0 u, -.c I-

II) C: 0 ·-.!!! (.) Q)

C ns -C: Q)

E C: 0 .... ·s; C: w 0 ::!!: <(

Lab Fraction

01

I 02

Nuclide

TH-228

TH-228

I. Sample

Desc

LCS

MBL

Client

Identification

LCS

Activity Units

Results ) Error Estimate MDA I LCS LCS

Known %R

pCi/1 s.s2E+ool 1.19E+oo 1.BBE-01 4.B7E+ool 119.46

i ---~ .. ·----+---• .. l ·- ~-------- -··---~··------ ··1-··- -r··--

BLANK pCi/1 4.84E-02I. 6.01 E-02 9.12E-02 ;

LCS Flag

OK

RPD Flag

I

MDA I Flag

OK

OK

Blank Flag

OK

03 TH-228 DUP OU-1-007 Outfall 007 DIS pCi/1 1.92E-03 I 2.69E-02 I 7 .69E-02 NA OK

I I ----1-- ------------+-- ------ .... , .... ••·----+---....... • +·--......... --... ; ..... .

04 TH-228 DO OU-1-007 Outfall 007 DIS pCi/1 5.66E-02I 7.45E-02I 1.19E-01 OK

-----+··-··-·-----+---- , ... ----+-----~-- --+----------t-----;--------

_ ..... ---+·······-····--····-.... __ --+--- ···I

I-·-···· -I··-· ... ••-----+------ I····· -- -- -. - - ----··------l - ·····1··········--·········+-----·+-.. -·--·· .. I······· .. ······-c .. ·····-·--+-----+-----+------1

··-···· ....... --+------ I ·-· , .. ·······-----·-··· .. +···· ... · ······-+··.. . .. ····+··-----+------,--·---+--......... , ··-·····--+------1•----+------,

,-----+--- .. -----+---.. I·· .. •·· ·•· .. ·-+···· ···· ....... ·······1--.... _._ ·-···I

····+·· t-------1·--·· .. ·-··· -+------1- -----,-1----+----+----l-----1

1·-·-····· --+·-···· ...... ------+-- .... ,

1-------j-·--··· -----· - -----4 ·--- -1--·-- .:_ ... : . -- ·--······:- ·- ·- .. + ... ___ •--- t ....... ·········I······--··· ---- ·····+· ....... ·········· ·····-·· .. ···-·····- ... ••·I········· ····· .. +··· .. ······· ... --1---..

_., ___ ,._ .. ----+-- ------+- ···· .. ·I·· ........................ -----·--r-----· .... + .. ······· · ··-l·····--··-····+---.. +·-----1----.... -t------1f---------1----f---------1

+--········· .

r------+-----·- - ------1 ·-----·I·--------

1-.. ··-·····+- .. •· -----1----+-----··•• .. •·····--·· .. ····--··· ----,.---·· ...... + ...

-···-------f----- I·.. ······-1··

: ~~ i I I I I I : I

0135

Eberline Analytical




Page 2 of 3

~ Lab Nuclide

Sample Sample

Fraction i Desc Date -----,

01 [ TH-228 LCS 06/21/18 00:00

Sample Radiometric

Aliquot % Rec

1.ooE+oo! 65.13 I

Grav % Rec

0.00

Mean

% Rec

o.ooi

SAF SeptO

Date/Time

Sep t1 Date/Time

&!

a, "ti 0 0 .!!! ~ ca C: q;

C: ~ 0

T"" I I

0 en -~ t-- I 1---···-··+·

1/) C: 0 1/)

·o Q)

C

Jg C: Q)

E C: 0 ... ·s: C: w 0 :ii: <(

-·---- -·-- -------- ·--/

TH-228 MBL 06/21/18 00:00

··-- --------~-·~

TH-228 I DUP I 06/20/18 10:00 -- --------- -------·---· ·---· ·-

TH-228 DO 06/20/18 10:00

-- -·-- --- -+-- -------1-----·

·-----1---

1.00E+00 107.62 0.00

······-·-·····-···I··-·······--···-·---

1.ooE+oo! 114.43 0.00

.. / .

1.ooE+ooi 92.94 0.00

f·-···

0.00i i

-T o.oo,

I o.ool

I

I l

------·-·----~-·-----f~···--····- ------------ - --1-----···--

···--·-1---1----------+-- ·· -·-·-1- ··· -··-··-····--·····--+··-· ~~--t=----t--------+-------1

--·-·----+-·--· 1------- ----+---·····-- ----·-·----··-------1---·----------------~------t-------------1

----+----1-···--··-·······-·-·--···--·--··- 1-·-··-----·-·f--···-- -·-·····-·-I·····--·-·-·-······· I·····--·-····-

-··--··-···· ·······-+-··-···--· .. --f-··· . -· -··-+···--·-·

- -+--··--·I-···-···

+-·-··-·!----- -·----+--

0136


~ Lab Nuclide I Sample I

Fraction Desc

01 TH-228 LCS I

02 TH-228 MBL I C: :::, -c-0:: 03 I TH-228 I DUP I

--~-

0 I I _ 04 _J__ TH-228 ___ _L_ DO _j

Cl> "0 0

(.)

~ I 1-------·-~---•...J----.-.!!!

~ .c Ill C: ... I 1---------l--- ------ ------------,---ci:


Work Order: 18-06097-ThlSO-1

Counting

I Halflife

Date/Time (days) Detect Carrier Count I Counts I

Bkg

Time CPM

07 /10/18 08:04 ' '

110)2.27 E+02 I 1.00 E-02 A_Spec / Alpha_003'

07/10/18 08:04

07/10/18 08:04

i I I------

I ' A_Spec !Alpha:-0_04! 170 I 3.64 E+00 18.00 E-03

A_Spec IA1pha_o10I 110.02j1.5o E-01 15.00 E-03

-I '------.--

07/10/18 08:04 A_Spec Alpha_o11f 170.02j3.79 E+oo_J1.30 E-02

.. --- . --,-. -- --------- .

I


Eff

15.9

18.5

18.4

19.5

-------1--------------)----------------.+-------t-----

---1---------

---------1--

---+---- -~------j------1

1/) C: 0 I 1---------- -1------

1/)

·o Q)

C (ti -~I C: Q)

E C:

- ... ---1 ----- ---------------

. . . . .. I · --------------- ---------------

!

0 ... ·s: C: w 0 ::!!: <(

0137




Page 1 of 3

~ Lab

Fraction

01

Nuclide ! Sample Client Activity

\ Desc Identification Units

TH-230 LCS LCS pCi/I

Results I Error Estimate

6.59E+00/ 1.31E+00

MDA LCS

Known LCS %R

1.53E-01 / 5.38E+00I 122.48

LCS Flag

OK

RPO Flag

MDA Blank

Flag Flag

OK

C: ::i T""' 0::

Cl)

"l::J 0 0 (..) en .!!!

~ -ca .c C: I-"(

-.... ., ~ 0 t: ~ .; .g ~ "' C: <( ., :§ .... ., il:l --~

II)

C: 0 II)

·c:; Cl> C

--- -~---- ---·--·---- ----·-

02 TH-230 MBL BLANK

03 TH-230 I DUP I OU-1-007 Outfall 007 DIS

-

04 TH-230 DO OU-1-007 Outfall 007 DIS

---- ""--·-···- --·------- ----···

--·----·-·----- . -··---------· ---·- --------·-

--·---- ·-·---- ------·-------···-···------···-·--·-----·----

--------- - -----

1------1--·-·-----·- ---·--··--+---·-···--1·--··-·-·---

pCi/I

pCi/I

pCi/I

----+---------- -

5.27E-021 6.63E-02 1.04E-01,

i

OK I OK -1----

l 1.49E-01 I 8.SSE-02

1.73E-01 I 1.0SE-01

5.26E-02j

----··i --9.65E-02/ ___ ._···t----+---+------+

NA OK -OK

_!

I

i-+----t-17-- --------1 - -I

·-r-·---·-1 I

-1------·····---~~~~·~-~ l ~=L ~ I I I I I

-·---·r----;----------------- ··----+--

----~-----~----------·····-•-- . -+·· ------1- -----+--

----+----1---·---·----·-·-·--------------·--·-----·----.i.-- ·-1--··-·-··--------+--·---- ·--+--·-·-·- ·-

co I L--··- - ·--,.----1------;---- •',----·--- -----·-----) - ----J------···-----··-· --/---··---

-~I C: Cl> E C: 0 I.,

> C: w ------1--·-· -----+-------! --------- -····--··-~·---+----- -+----------·+---------•-------+------+-----+-----+-----+-----I

0 :ii: <t

0138

Eberline Analytical




Page 2 of 3

,: Lab Fraction

Nuclide

01 TH-230

Sample Desc

LCS

Sample Date

06/21/18 00:00

Sample Aliquot

1.00E+00

Radiometric Grav Mean SAF

SeptO Sept1

%Rec % Rec % Rec Date!Tirne Date/Time

65.13 0.00: 0.00

C: ::, a::

Cl> ,::i 0 0 .!/.! ~ a, C: q;

~ 1:! 0 ~ ~

l .. C: "I: Cl> .s .:: ., ~

j

---~-----------------J--------1----·- -·---- . --------·· ----·-

02 TH-230 MBL 06/21/18 00:00 1.00E+00I 107.621 o.ool 0.00

~

--- -----~-1----·-

03 TH-230 DUP 06/20/18 10:00 1.00E+00I 114.43I 0.001 0.00 I

-·----·---- I ·--·--· )-

04 I TH-230 DO 06/20/18 10:00 1.00E+00I 92.94I 0.001 0.00

0 en -..c I- I I ·-- ·· - !-··

11'1 C: 0

.!!? (.) Q)

C

Jg C: Q)

E C: 0 ... '> C: w 0 :E <(

------·· -1----------.---···-~--t-- -------+-------·-------l-------------1

--+-----· ·--·· ····-··-·--·· ···t·-······-----····-- · ····-·· ·· f··---···-······- ······-·I·---····

······-····- ..... J..•-·-······- ····---·--------1··--·-··-·1-·--·-······· ·-··· ·--·· -··--·--1--·-···-·····--····+···

----·

•··---···-···--1-·- --/.------····---·l~------·-------1------ . +--·········· ·-·--···· ···-+----·----+----------+--·-------------1

·-f---

1----··•-•i-••-···-·--------t----1-···-···-···--·--·- ---+------ , ____ ····---···· ---······1 ··-········-·····------·-1·····---···-··-····· f--------+--------------1-----------1

1-----,-.-------------l---+---~~-·-·--···· . ----1--- ··-+-

0139

Eberline Analytical


Preliminary Data Report & Analytical Calculations Printed: 7/10/2018 12:14 PM

Page 3 of 3 Work Order: 18-06097-ThlSO-1

~ 11 "' Fraction

~H1 c: I 02 ::, ~

a:: I • • 03 -

Nuclide : Sample I ~SC

TH-230 LCS I

TH-230 i MBL I TH-230

r-ou;-J.

04 TH-230 DO

Counting DatefTime

07/10/18 08:04

07/10/18 08:04

07/10/18 08:04 -------··--·-------

07/10/18 08:04

Halflife (days)

--~--

Detect

A_Spec

A_Spec

A_Spec

A_Spec

~' 0 I - - . -- , ___ ·---------- ···--t-···---···----· . I-···

u U) ,!!! ~ -ii .c:

I-

1--··-·--•-··---- ····--1-·······- -···l-····-·-····- ··-----+-- ···--··-····· +-

l-----+----------------+---------1----

1-----J··-···-· ----· +-··-· +······-· - --~----- -->-------- --)---

,, _____ ,.. _______ ··f-··--1-···---·-··--·-···· --r---------j·········-··

1----+------ 1---····-1··--·····-······-·· · ----+---- ···+

l--·--·1------- f·--···--1-··-···-·- -··- ·--···---t---- ·····-····I·····-···-

Carrier Count I Counts 8kg

Time CPM Eff

Alpha_003 170 2.57 E+02 5.00 E-03 15.9

----

Alpha_004 170 3.96 E+00 1.20 E-02 18.5

---··· --·+ . Alpha_010 170.02 1.18 E+01 i1.oo E-03 18.4

I -·

Alpha_011 170.02 1.18 E+01 !1.00 E-03 19.5

+·--·-··-·--l .. ··--····+----···-·--·······~-······-· -----1

- ______ ..J ______ _,

·-·· +·--··-·--1 --1---- ··-'- ·······--··---1 -------1

···-l-·····-·····---·I· ---+----· -·, I

1--····-·+·--··· ------j ···-··· ·1---····-· .. ···-1·····-····--· +··-- -·-1-·--··--t------+------1

1/) C 0 1----······-····--· +---- ··-·-+·-·······-···-·-·I-·-··· ········--·····-1·-······-·+-·-··-·---+------+------1

.!!? 0 a,

----•l--•··--1--·· · -·-····-·····-·--··1-·--·--·------·· ···· I··· ····1·· ····---·-f-····-···-···'------C--- ---t-----1

C ca IL .. +-····--1··-·-···---··--· · -·· ---1----···---·····-I····-·· · ······--·····1-----j

.... ~I C

a, E C

1------<-·--------1--··--·11------ ----·-!---·--·----· ···I-···--·· ..

0 ... > C w 0 ~

1----•-l-••· ----+ -····-·· -----<----- +----·--

<(

0140

Eberline Analytical




Page 1 of 3

;: Lab Fraction

01

Nuclide I Sample Client I Activity

Desc Identification I Units

TH-232 ~LCS LCS pCi/1

Results I Error Estimate, MDA LCS

Known

LCS

%R

5.76E+00[ 1.18E+001 1.44E-01[ 4.87E+00I 118.34 I

LCS Flag

OK

RPO Flag

MDA Flag

OK

Blank Flag

c:: :::i ll::

a, ,:, 0 0 .!!,!

i 111 c:: ct

... ~

---·-

02 T"'"

I I 03

----- -------------·---·-·- - ----- ----~---

TH-232 MBL BLANK pCi/I -- --·-·-------- -··---·----

TH-232 I DUP I OU-1-007 Outfall 007 DIS pCi/I -·--

3.73E-021 --;_;;;.02\ 8.76E~; l

2.s2E-02l_4_.3_sE_-o~J __ 1~oiE:o~--- i------+----~---

04 0

TH-232 I DO I OU-1-007 Outfall 007 DIS pCi/I 1.90E-02 s.21 E-02! 1.07E-01 I --+--·-----·-------,- -- ------·--------·1 ----- ---+----t----J,

I

u, -.I:. 1-- I 1----- ---·

- -,---·-·-----··---····+-----1----- ----+------ - -----!-·---·---- -1---

···-- -- -------t---------- ----·---\-----~---- ···----j---·- I

··----·/---

-----

1------ ----+------ ----+--- 1---- -----··--·-------·----- ···----• -··----···---

(/) C: 0 I 1--- ---+-- --

.~ (.) Cl)

C

.5 C:

-----

------------ -·----··--- ----·-····-- -------·

-----·- ---- ----+·--- -·---·-··-·---1 ·····--···-- --------1-----~-·---------+----

-----+-----

-OK OK

-·7---

NA I OK

OK

Cl)

E ---·- --1------···-···-·---·-r----~----- --·----r--------1------t--------,f------1-----1------1

C: 0 ... '> C: w 0 ~ <(

----·--1 ----------·------+--- -!---------- ·--------,------

0141

C: ::3 a:

.g 0 u


~ ~ ~

Lab Fraction

01

02

03

04

Nuclide

TH-232 ·---

TH-232

TH-232

TH-232

I Sample

! Desc

LCS

MBL ------

DUP

-----·- -··· ---·--

DO

0 en -------~---··-----~- --------- ..


Work Order: 18-06097-ThlSO-1

Sample Sample Radiometric Grav I Mean I SAF Date Aliquot % Rec % Rec I % Rec I

06/21/18 00:00 1.00E+00 65.13 0.00 0.00

------ --f-.-.-------·- -

06/21/18 00:00 1.00E+00 107.62 0.00

--1--=-----~-------·

06/20/18 10:00 1.00E+00 114.43[ 0.00 0.00

-- ------------~- ----~------·----- ----~ - --I

06/20/18 10:00 1.00E+00 92.941 0.00 0.00

-··----·----~--- --------·----- --

,!!! ----- - -- -- ·---- - --- --·· -------------- ~-----~-- !---·---------·- . . --- --·------- ---------·------·- --~----

~ "' C: c:t

~

~

-.c I-

1/) C 0

.!!? c., Q)

C

J9 C Q)

E C 0 ... > C w 0 :E <(

~------·--

-~------·--

---------- - ----------

···--·--

-----·---

------·--·

··-~-- -·-·---

-·-·--····- ---------·--

---·-··---------·-- -·-··-·-··-

---- ---------

--'----··----····-

--·-

·-~-------·-·

·----•-.------~--- ---·-

------

. -- ·-·-- -· ---·----··-··

--·--~------

-··----··-

---- ---· --·--------·---

·----··--- ·-- ------- -----

--·--------

--····-- -··---- ·------··-- ··--·-····--

----·-------- ----------------

·-·---- ----·----- -·

.. -·-···--···---··---------

-------

------- ·-----~-~--··--~---------

··----·----- !-·------------ ----- --

- -- - ----· -·- -- ---· ··------·-·---·---

·------···-··-------

.... ----···---------- . --·--------------------

-----···

i ·--------•-,-- - --,--- ·-----·-·------··· - ----- -·----- ------------ ·-------~---

--···------···~ --·-----··--·-··- - -- ······-- ------- --·-- ----··--- ···------·----···-- ---···-----·-

---·-·--------- ----------------- ----- ·- ----- ------·-···--- --··---------

------------··~·····------- --------··-·-----··--···-·- 1---,---------·-----·•-I---

---------· ------------- --·-·-- ----.----

·----- I---·-··--------

~---~-- ·---- ·------·-- .. -·- - -·-· ··----------~----~--

-------···----·-- -···--·~-·---- ------~---

: I

I i


Sep tO Sep 11 Date/Time Date/Time

-~

I ! - -------------

-·-----·-··--~---·-

--------

------ I

--------

0142




Page 3 of 3

( Lab i Nuclide I Sample I Counting

Fraction I Desc Dateffime

01 I TH-232 I LCS I 07/10/18 08:04

Halflife (days)

Detect Carrier

A_Spec I Alpha_003

Count Time

Counts 8kg CPM

170)2.25 E+02 [4.00 E-03

-+-- ---- - -! -i

Eff

15.9

C: :::i ll::

G> 1:l 0 0 .!/? ~ Ill C: C(

~

~

~

0 en -.c I-

U) C 0

.!!1 0 Cl)

C

Jg C Cl)

E C 0 ... ·s; C w 0 :E <(

·----\-.

02 I TH-232 I MBL I 07/10/18 08:04 A_Spec Alpha_004 170\ 2.81 E+00 [7.00 E-03 18.5

-----1--··--·-----·---·---r·-·--~-----··-r-----·-·-11----···- --",-----1------'

03 TH-232 I DUP I 07/10/18 08:04

-

04 TH-232 ! DO I 07/10/18 08:04

170.02 [ 2.32 E+00 \ 4.00 E-03

·----+----+I ;

110.02/1.3~ E+oo koo E-02

A_Spec

A_Spec

Alpha_010

Alpha_011

18.4

19.5

--···-----····

1----- i

--f-

----+-----1 i .. I

---+--· .. ---.. , ... _ .... +---·----+---

. --··· r-------·- -----· --·-·-+·-----·-- _ __, ___ ___, ·--·-··--·--------+------1--------1

1----,---- .. --·--+-.. --1--· .. -

1--.. --- -------.. ---1 --+------+-.. - · .... -•,

---.. ----... -1 .. -·

-~---------+-··· --------+

... --.. ------l--·------1----------+ ... - ... ---·----.... - - .. I .. - .. ---. - ........ -1------------+ .. -- ·------+ ...... __ ........ -+

------,---~.--------------~--~-------- --··· ..... -,------+-- ·-+-----

0143

>.\ '17


Internal Sample Client I

Fraction Desc ID

01 LCS LCS

02 MBL BLANK

03 DUP OU-1-007 Outfall 007 DIS

04 DO OU-1-007 Outfall 007 DIS

I

18-06097-ThlSO-1 (pCi/1) in WA Tracer ID: Th-18a

Sample I Sample Tracer

Date Aliquot Aliquot (g)

06/21/18 00:00 1.0000 0.4656

06/21/18 00:00 1.0000 0.2332

06/20/18 10:00 1.0000 0.2319

06/20/18 10:00 1.0000 0.2310

Tracer ACT(dpm)

10.4574

5.2377

5.2085

5.1883

I Radiometric Tracer (pCi)

I


I Radiometric SAF SAF . %Rec 1* 2* I

0.00 I

I

0.00

0.00

0.00

0144

Eberline Analytical


Isotope So/# Activity dpm/g

Th-228 Th-8b 103.560

Th-230 Th-1b 23.520

Th-232 Th-8b 103.560

fraction I Isotope Sol#

01 Th-229 Th-18a

02 Th-229 Th-18a

03 Th-229 Th-18a

04 Th-229 Th-18a

Version 2.0 08/99

Solution I Approx Date I Addition

7/6/2018/ 0.100

11612018 I 0.500

7/6/20181 0.100

Tracers Activity I Solution dpmlg / Date

22.4601 7/6/2018

22.460 7/6/2018

22.460 7/6/2018

22.460 7/6/2018

i I I


Analysis Code Date

ThlSO 7/6/2018 7:19

LCS MS LCSD MSD LCS

Volume Volume Volume Volume Known I

Technician

JHARVEY

MS Error Added I Error

Page 1 of 1

Printed: 7/6/2018 7:25 AM

Witness Initials

--

Leso· -----

""""lVISD Known I Error Added Error

Used(g) Used(g) Used(g) Used(g) I

pCi i Estimate pCi I Estimate pCi ; Estimate pCi I Estimate I

0.1044 4.81I 0.175 o.ool 0.000 o oo/ 0.000 0.00 I

0.000

0.5078 o.ool I

5.38] 0.145 0.000 0 001 0.000 0.00 0.000

0.1044 4.81I 0.175 I

0.00! I

0.000 o.oo[ 0.000 0.00 0.000 - - -

Balance Printer Tapes

Volume Approx Tracer LCS Used(g) Addition

0.4656 0.2200

0.2332 0.2200

0.2319 0.2200

0.2310 0.2200

Matrix Spike

I

0145

Lab



Fraction Client ID

01 LCS

02 BLANK



Comments

Sample

Type

LCS

MBL

DUP

DO

Aliquot Worksheet


ThlSO liters 7/11/2018


Ratio Post/Pre No of Dils Oil Factor Ratio Aliquot Net Equiv

i 1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

Teohoiciao ~~~Date ~£12

Technician

JHARVEY

MS Aliquot Data

Aliquot Net Equiv


H-3 Solids Only WaterAaaea N:ruIsr

(ml) Aliq

0146


SPIKE \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167

1806097A-TH Sample Identification: Sample Geometry: Procedure Description:




01 Shelf 2 Th iso

Alpha_003

3 System Bkgd 219019

<not performed>

1.000E+000 +!- 0.000E+000 7/10/2018 5:43:45 7/10/2018 8:04:56


Th229 S TH-18A 0.466 rnL 0.1036 +/- 0.0083

AM AM

liter


3:44:29 PM

Chern. Recovery Factor:

Control Certificate Name: NatTh Th-8 Chern. Recov. of Control: TH-232 1.183360 +/- 0.128602


Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.830 5.384 4.874 4.626 3.955

0.175 MeV

PEAK AREA REPORT

Net Pk Area

6 .13 227.30 184 .13 257.15 225.32

Pk Area Error%

92.21 13. 06 14.53 12.25 13. 08

Ambient Backgnd

1. 87 1. 70 1. 87 0.85 0.68

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

3.0 9.2 6.2 4.4 4.6


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.998 0.999 1.000 0.989 0.991


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


1.61E-001 +/- 1.50E-001 5.82E+000 +/- 1.19E+000 4.73E+000 +!- 7.45E-001 6.59E+000 +!- l.31E+000 5.76E+000 +/- 1.18E+000

~ 1/rrfrs

MDA (pCi/liter

1. 99E-001 +!- 3.13E-002 1.88E-001 +/- 2. 96E- 002 1.95E-001 +/- 3.07E-002 1.53E-001 +!- 2.42E-002 1.44E-001 +!- 2.27E-002

0147

Vl .µ C ~

60

55

50

45

40

35

0000216763.CNF

Live Time :10200.000 sec Real Time :10200.000 sec Start: 1:3496.6(kev) Stop : 1024:6544.G(kev) Acq. start :Tue Jul 10 08:04:56 2018

8 30

25

20

15

10

5

0 ITT" w I Mm 1m1 1111 1 1 1 , " . M 1 11 'I ! 1M! ! M!IW]OHM!r-l!jf', , , ·· .. "·. ' 1

: j 11 / 111' j I 1 , ii'. , ·•··1,wl''' ,1 • l 3 500 \! "' ·· ,Jii: i!, , 1 rnimmw:1 rn 1 1 ·. 1~ 1 1111 AMijflli.' , 1, . . . 1 I II ,MH!1! ! Mlj)lill Ml I I ~

4000

ROI Type: 1

4500 5000 Energy(kev)

5500 6000 6500

ROI Type: 3

0148


******************************************************* ***** s p E C T R A L DAT A R E P O R T ***** *******************************************************

Sample Title: 01

Elapsed Live time: 10200

Elapsed Real Time: 10200

Channel\------l-------1-------1-------1-------I-------I-------I-------I

1 : 10200 10200 0 0 0 1 0 0

9 : 0 0 0 0 0 0 0 0

17: 1 0 0 0 0 0 1 0

25: 0 0 0 1 0 0 0 0

33: 0 0 1 0 0 0 0 0

41: 0 0 1 0 0 1 0 0

49: 1 0 0 0 1 0 1 1

57: 0 0 0 0 0 0 0 0

65: 0 0 0 1 0 0 0 0

73: 2 0 2 2 1 2 0 0

81: 0 1 1 1 1 0 0 2

89: 1 2 0 3 2 1 1 1

97: 2 3 3 2 1 0 0 3

105: 0 0 2 2 1 1 1 1

113: 3 4 2 0 2 4 3 2

121: 1 3 3 2 1 6 2 2

129: 4 2 5 4 8 3 2 5

137: 4 3 1 5 3 8 6 5

145: 5 5 4 4 7 4 5 3

153: 3 5 4 5 5 8 2 1

161: 3 5 7 7 9 2 11 5

169: 3 6 8 3 6 3 7 2

177: 1 0 1 0 0 0 0 0

185: 0 0 1 0 0 1 0 0

193: 0 0 0 0 0 1 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 1 0

217: 1 0 0 0 0 0 0 0

225: 0 0 0 1 0 0 0 0

233: 0 0 0 0 0 0 1 0

241: 1 0 0 0 0 1 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 1 0 0 0 0

265: 0 0 0 0 0 0 1 0

273: 0 0 1 1 0 0 1 0

281: 0 0 0 1 1 0 1 1

289: 0 1 2 1 1 0 1 0

297: 0 0 1 1 1 0 1 0

305: 0 0 1 0 0 0 0 1

313: 0 2 0 0 1 0 0 2

321: 1 1 1 2 0 0 1 0

329: 3 2 3 3 1 0 2 1

337: 1 0 1 2 2 1 2 2

345: 1 2 1 0 1 3 2 3

353: 2 0 3 4 1 4 2 2

361: 5 1 5 4 3 6 2 5

0149


369: 2 8 5 6 4 5 7 3

Sample Title: 01

Channell------l-------l-------1-------1-------1-------I-------I-------I 377: 4 11 3 4 5 5 6 7

385: 5 3 4 8 5 3 6 2

393: 8 8 3 8 4 6 6 9

401: 7 4 2 0 1 1 0 0

409: 3 1 2 0 0 1 3 2

417: 0 0 2 2 3 0 2 1

425: 1 0 0 1 0 1 0 3

433: 4 3 4 1 4 3 1 6

441: 3 4 7 1 4 3 0 5

449: 3 4 5 1 3 0 1 2

457: 4 3 2 1 0 1 2 5

465: 1 2 3 0 3 1 0 0

473: 1 2 3 3 0 0 0 1

481: 1 1 3 2 1 2 1 1

489: 3 2 0 0 1 1 1 1

497: 0 0 0 2 2 2 0 1

505: 1 1 0 1 0 1 2 0

513: 1 1 2 1 2 0 2 2

521: 0 0 1 0 0 2 1 2

529: 0 0 0 0 0 1 1 0

537: 1 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 1 1 0 1 1 1 2

561: 4 1 0 3 0 0 0 2

569: 1 0 3 1 2 1 0 4

577: 0 2 2 0 2 2 2 0

585: 1 0 1 1 1 2 1 4

593: 0 2 3 2 1 3 2 3

601: 0 6 1 6 4 2 0 1

609: 6 2 5 4 4 2 5 6

617: 5 7 6 3 8 5 7 4

625: 4 0 2 4 9 5 2 5

633: 11 7 6 3 4 4 9 4

641: 7 7 10 9 10 10 10 3

649: 4 8 2 3 1 1 3 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 1 0 0 0 1

673: 0 0 0 0 0 0 0 0

681: 1 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 2 0 0 0

705: 2 0 0 0 0 0 1 1

713: 0 0 1 0 0 1 1 0

721: 0 0 2 0 0 1 0 2

729: 2 1 1 1 2 1 0 0

737: 0 0 2 1 0 0 1 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 1 0

769: 0 0 0 1 0 0 0 0

777: 0 1 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 1 0 0 0 0 0 0 0

0150


801: 0 0 0 0 0 0 0 0

Sample Title: 01

Channell------l-------l-------l-------l-------1-------1-------1-------\ 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 1

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 1 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 1 0 0 0 0

881: 0 0 0 0 0 0 1 0

889: 0 0 1 0 1 0 0 0

897: 1 0 0 0 1 0 0 1

905: 0 0 0 0 0 1 0 0

913: 0 0 0 1 0 0 0 0

921: 0 0 1 0 1 0 0 0

929: 1 2 1 0 2 1 1 0

937: 0 2 2 0 2 0 0 3

945: 0 1 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 1

961: 0 0 2 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 1 0 0

0151


BLANK \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167





02 Shelf 2 Th iso

Alpha_004


<not performed>

l.000E+000 7/10/2018 7/10/2018

170.0

+/- 0.000E+000 liter 5:43:45 AM 8:04:57 AM

minutes 170.0 minutes

Th229 S TH-18A 0.233 mL 0.1994 +/- 0.0162


3:44:30 PM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.806 5.295 4.880 4.673 3.991

0.175 MeV

PEAK AREA REPORT

Net Pk Area

3.15 3.64

177.49 3. 96 2.81

Pk Area Error%

126.67 123.16

14.74 124.69 142.99

Ambient Backgnd

0.85 1. 36 0.51 2.04 1.19

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

2.9 2.9 9.3 2.9 2.9


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.990 0.944 1.000 1.000 1.000


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


4.29E-002 +/- 5.48E-002 4.84E-002 +/- 6.0lE-002 2.37E+000 +/- 3.78E-001 5.27E-002 +/- 6.63E-002 3.73E-002 +/- 5.37E-002

~ 1/ro/r5

MDA (pCi/liter

8.16E-002 +!- l.30E-002 9.12E-002 +!- l.45E-002 7.0lE-002 +!- l.12E-002 1. 04E- 001 +/- l.65E-002 8.76E-002 +/- l.40E-002

0152

Vl +-' C ~

60

55

50

45

40

35

8 30

25

20

15

10

5

0000216738.CNF

,;,~ 11 :i: i< I-

Live Time :10200.000 sec Real Time :10200.000 sec start: 1: 3488. l(kev) stop : 1024:6492.S(kev) Acq. Start :Tue Jul 10 08:04:57 2018

11 I I " I I ! ·' I 1· I 'I"' I '!"'' 'ii ''I ,,,, ' ! \ ' I I ' I ! ! l

0 ,· ,I I I• ''I•' ;1, I· ,,; I •\'I I ,'.I '. ' ' I ' I I, I I 11

3500 4000 4500 5000 5500 6000 6500 Energy(kev)

ROI Type: 1 ROI Type: 3

0153



Sample Title: 02


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 10200 10200 0 0 0 0 0 0

9: 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 1 0 0 0

153: 0 0 0 0 0 0 0 0

161: 1 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 1 1 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 1 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0154


369: 0 0 0 0 0 0 0 0

Sample Title: 02

Channelj------l-------l-------l-------l-------1-------1-------1-------\ 377: 0 1 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 1 0 0 0 0 0 0

401: 0 0 1 0 0 0 0 0

409: 0 0 0 1 0 0 0 0

417: 0 0 1 1 0 0 0 1

425: 1 0 0 0 0 1 0 1

433: 0 0 0 0 0 1 1 2

441: 2 2 1 1 2 1 4 0

449: 3 4 1 4 3 1 2 3

457: 2 2 3 3 6 1 7 8

465: 6 3 4 1 2 1 5 1

473: 4 0 5 3 2 2 1 0

481: 1 0 1 1 0 2 3 2

489: 1 4 1 3 3 4 0 2

497: 2 2 2 1 2 1 0 2

505: 2 1 2 0 1 0 1 1

513: 0 0 1 1 2 0 0 1

521: 2 0 0 2 0 0 0 1

529: 2 0 2 0 0 0 0 0

537: 0 0 0 0 1 0 1 0

545: 0 0 0 0 0 0 0 0

553: 1 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 1 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 1 0 0 0 0 0

609: 0 0 0 0 1 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 1 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 1 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 1 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 1 0 0 0 0

793: 0 1 0 0 0 0 0 0

0155


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------l-------l-------1-------1-------1-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 1 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 1 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 1 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0156


OU-1-007 OUTFALL 007 DIS DUP \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167





03 Shelf 2 Th iso

Alpha_0l0


<not performed>

l.000E+000 6/20/2018 7/10/2018

170.0

+/- 0.000E+000 liter 5:43:45 AM 8:04:53 AM


Th229 S TH-18A 0.232 mL 0.2106 +/- 0.0168


3:44:30 PM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.934 5.438 4.882 4.656 3.965

0.175 MeV

PEAK AREA REPORT

Net Pk Area

0.32 0.15

186.49 11. 83

2.32

Pk Area Error%

647.08 1398. 6

14.38 57.46

149.13

Ambient Backgnd

0.68 0.85 0.51 0.17 0.68

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

2.9 2.9 5.1 2.9 2.9


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.964 0.992 1.000 0.999 0.995


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


4 .13E- 003 +!- 2.68E-002 1. 92E-003 +/- 2.69E-002 2.36E+000 +/- 3.68E-001 1. 49E-001 +!- 8.88E-002 2.92E-002 +!- 4.38E-002

M 1/1oft

MDA (pCi/liter

7.29E-002 +!- l.14E-002 7.69E-002 +/- l.20E-002 6.63E-002 +/- l.04E-002 5.26E-002 +!- 8.21E-003 7.09E-002 +!- 1.llE-002

0157

V)

-1-' C ~

45

35

8 30

25

20

15

10

5

0000216739.CNF

0 11 ' , II

4000

ROI Type: 1


5500

Live Time :10201.000 sec Real Time :10201.000 sec start: 1:3509.l(kev) Stop : 1024: 6494. 5 (keV) Acq. Start :Tue Jul 10 08:04:53 2018

6000

ROI Type: 3

6500

0158


*******************************************************

***** s p E C T R A L DAT A R E p 0 R T *****

*******************************************************

Sample Title: 03


Channell------l-------l-------1-------1-------1-------I-------I-------I 1: 10201 10201 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 1 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 1 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 1 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 1

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 1 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 1 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 1 0 0 0

345: 0 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0159


369: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------l-------l-------1-------1-------1-------\

377: 0 0 0 1 0 0 0 0

385: 0 1 1 0 0 0 1 0

393: 0 0 1 0 1 0 0 0

401: 0 1 0 0 0 0 0 1

409: 0 0 1 0 0 2 0 0

417: 0 0 1 1 0 1 0 0

425: 0 1 0 0 1 1 0 0

433: 2 3 3 0 0 2 1 1

441: 2 2 3 1 1 5 2 6

449: 3 0 5 5 3 3 4 0

457: 5 5 3 1 3 2 2 3

465: 5 1 0 4 3 2 1 2

473: 2 2 1 3 4 2 6 1

481: 0 1 4 3 2 1 2 4

489: 0 2 3 0 3 1 4 1

497: 1 0 0 1 0 0 0 0

505: 0 1 2 1 2 3 1 0

513: 1 2 2 0 2 0 0 0

521: 1 0 0 1 0 0 1 1

529: 0 1 1 0 1 0 0 0

537: 0 0 1 2 1 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 1 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 1 0 0

665: 0 0 0 0 0 0 0 1

673: 0 0 0 0 0 0 1 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 1 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 1 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0160


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channel\------l-------l-------l-------l-------1-------1-------1-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 1

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 1 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 1 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 1 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0161


OU-1-007 OUTFALL 007 DIS \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002167





04 Shelf 2 Th iso

Alpha_0ll


<not performed>

l.000E+000 6/20/2018 7/10/2018

170.0

+/- 0.000E+000 liter 5:43:45 AM 8:04:55 AM


0.0155

Counting Efficiency:

Th229 S TH-18A 0.231 mL 0.1812 +/-0.1950 +/-0.9294 +/-

0.0034 on 2/16/2018 0.0809

3:44:30 PM



Nuclide

TH-227 TH-228 TH-229 T TH-230 TH-232

Energy (MeV)

5.869 5.285 4.883 4.616 3.930

0.175 MeV

PEAK AREA REPORT

Net Pk Area

2.47 3.79

159.81 11.81

1. 30

Pk Area Error%

163.79 130.59

15.57 60.30

273.47

Ambient Backgnd

1. 53 2.21 1.19 1.19 1.70

Reagent Backgnd

0.00E+000 0.00E+000 0.00E+000 0.00E+000 0.00E+000

FWHM (keV)

2.6 2.6 5.5 2.6 2.6


Nuclide

TH-227 TH-228 TH-229 TH-230 TH-232

Id Conf.

0.998 0.933 0.999 0.984 0.977


Energy (keV)

5850.00* 5400.00* 4872.00* 4672.00* 3997.00*


3.71E-002 +/- 6.llE-002 5.66E-002 +!- 7.45E-002 2.35E+000 +!- 3.92E-001 l.73E-001 +/- l.08E-001 l.90E-002 +/- 5.21E-002

1ro1(t,

MDA (pCi/liter

l.07E-001 +!- 1. 78E-002 l.19E-001 +!- 1. 99E-002 9.68E-002 +!- 1. 62E-002 9.65E-002 +!- 1.61E-002 l.07E-001 +/- l.80E-002

0162

V)

+-' C: :::::i

60

55

50

45

40

35

8 30

25

20

15

10

5

0000216740.CNF

I I

0 ,I ,, '"

4000

ROI Type: 1

' 4500 5000

Energy(kev) 5500

Live Time :10201.000 sec Real Time :10201.000 sec Start: 1:3638.?(kev) Stop : 1024:6325.9(keV) Acq. Start :Tue Jul 10 08:04:55 2018

6000

ROI Type: 3

0163



Sample Title: 04


Channell------l-------1-------1-------1-------I-------I-------I-------I 1: 10201 10201 0 0 0 0 0 0

9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 1 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 1 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 1

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 1 0 0

233: 0 0 0 0 0 0 0 0

241: 0 0 0 0 0 0 0 0

249: 0 0 1 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 0

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 1 0

313: 0 0 0 0 0 0 0 1

321: 0 0 0 0 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 0

345: 0 0 1 0 1 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 1 0 0

0164


369: 0 0 1 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------1-------1-------1-------I-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 1 0 1

393: 0 0 0 0 0 0 1 1

401: 0 3 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 1

417: 0 0 0 0 1 0 0 0

425: 0 1 0 0 0 0 2 0

433: 1 1 0 1 2 1 1 1

441: 1 3 0 0 3 4 4 2

449: 1 1 1 0 2 1 0 8

457: 7 2 4 7 4 2 1 1

465: 1 6 1 3 2 1 5 1

473: 1 1 3 3 1 3 2 0

481: 3 2 3 0 1 0 2 2

489: 0 1 1 0 0 0 2 1

497: 1 0 0 1 1 0 0 1

505: 0 1 3 1 1 2 0 1

513: 1 0 0 0 2 2 0 0

521: 2 1 1 0 1 0 1 1

529: 1 1 1 1 2 0 1 1

537: 1 0 1 1 0 1 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 1 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 1 0 0 0 0

585: 0 0 0 1 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 1 0 0 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 1 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 0 0 0 0 0

673: 0 0 0 1 1 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 1 0 0 0 0 0 0 0

785: 0 0 0 1 0 0 0 1

793: 0 0 0 0 0 0 0 0

0165


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channel\------\-------\-------\-------\-------\-------\-------\-------1 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 1 0 0 0 0 0 0

913: 0 0 1 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 1 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 1

1001: 0 0 1 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0166

Page 1 of 2 7/10/2018 5:36:53 AM

ex-Al r'\ l\ Cl II\ 111\ 111\ DV DCDnDT ~n \JVIVIIVlr\l \ I I \'-I ~,\I


Date : 7/10/2018 Time : 5:36:53 AM


















Alpha 033 Alpha Analystl00DC Peak Energy Action 7/10/2018 5:16:10 AM





Alpha 038 Alpha Analyst 1 00DC ALL Not Done










Alpha 048 Alpha Analyst 1 00DC ALL Passed 7/10/2018 5:16:27 AM






Alpha 054 Alpha Analyst! 00DC ALL Not Done


Alpha 056 Alpha AnalystlO0DC ALL Passed 7/10/2018 5:16:37 AM



0167

Page 2 of 2 Kev1ew OT UA KeSUltS - t-'UISer GnecK

7/10/2018 5:36:53 AM




APPROVED BY:

APPROVAL DATE: ·+/lo/t8

0168

Library Listing Report 6/12/12 12:16:29 PM Page 1

*************************************************************************


*************************************************************************

Nuclide Library Title: Thorium

Nuclide Library Description: Th-227,-228,-229,-230,-232


Name (Seconds) (keV ) Uncert. (keV ( % ) Uncert. (Abs.+-)

TH-227 6.873E+008 5850.000* 0.000 97.5000 0.0000

TH-228 6.034E+007 5400.000* 0.000 99.9400 0.0000

TH-229 2.487E+Oll 4872.000* 0.000 99.5200 0.0000

TH-230 2.379E+012 4672.000* 0.000 99.8200 0.0000

TH-232 4.434E+017 3997.000* 0.000 100.0000 0.0000

* = key line


0169

SECTION X

ANALYTICAL DATA (RADIUM-226)

0170

Eberline Services Oak Ridge Laboratory Analysis Sheet

Work Order

Analysis Code

Run

Date Received

Lab Deadline

18-06097

Ra226 I 1

6/21/2018

7/11/2018


Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA



Radiometric Tracer Ba-133

Radiometric Sol# Ba-6a


Carrier



01 LCS

02 MBL

03 DUP

04 DO

!

18-06097 Ra226 Run 1

Client ID

LCS

BLANK





Login CPM

30

30


Sample i Sample

Date I

Aliquot

06/21/18 00:00 1.0000E+00

06/21/18 00:00 1.0000E+00

06/20/18 10:00 1.0000E+00

06/20/18 10:00 1.0000E+00

i

I I

0171


Internal Sample Tracer Fraction Desc Aliquot (g)

01 LCS 2.2121

02 MBL 2.2067

03 DUP 2.2113

04 DO 2.2115

Tracer Total ACT(dpm)

1063.3

1060.7

1062.9

1063.0

Radiometric Radiometric Tracer (pCi) %Rec

655.0 136.75

658.0 137.72

584.0 121.98

621.0 129.69

18-06097 Ra226 Run 1

Grav Carrier Grav Filter Added(ml) Tare (g)

0.0208

0.0210

0.0212

0.0215


0.0308

0.0315

0.0288

0.0292



Grav Filter Grav

I Net(g) %Rec

0.0100

0.0105

0.0076

0.0077

Printed: 71912018 2:36 PM Page 2 of 3

Mean SAF SAF

%Rec 1* 2*

110.00 3.00" 1.00

110.00 3.00" 1.00

110.00 2.66 1.00

110.00 2.69 1.00

0172



01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Date

Rough Prep Prep By Date

07/06/18 07:18

07/06/18 07:18

07/06/18 07:18

07/06/18 07:18

18-06097 Ra226 Run 1

Prep By

JHARVEY

JHARVEY

JHARVEY

JHARVEY

Sep to Date/Time

07 /09/18 12:48

07/09/18 12:48

07/09/18 12:48

07 /09/18 12:48



Sep to

I By

JBAILEY

JBAILEY

JBAILEY

JBAILEY



0173

Eberline Analytical


~ ®

C: ::i a::

i 0 0 ,!!! ~ 'iij C: ct

-~

~

(D N N ca a::

ti) C: .2 .!!? (.) Q)

C cu -C: Q)

E C: 0 ... ·s; C: w 0 :ii: <(

Lab Nuclide Fraction

01 RA-226

-----

02 RA-226

03 RA-226

--------·

04 RA-226

~--·--------·

--

-·----

-·--··--·

Sample Desc

LCS

MBL -----·-

DUP r·---·

DO


Work Order: 18-06097-Ra226-1

Client Activity

I Results I Error Estimate MDA Identification Units i

I

LCS pCi/I 1.01E+01 j 1.37E+00 2.87E-01 !

--·· "---•-··---- - -----·-· .. T

BLANK pCi/I -6.23E-02 1 1.0SE-01 3.70E-01

----- " -·-· - ---·---·---··-----· --

OU-1-007 Outfall 007 DIS pCi/I 3.81E-01 2.99E-01 3.78E-01

----· - -------

OU-1-007 Outfall 007 DIS pCi/I 1.02E-01 2.13E-01 4.0SE-01

··--------- - --------··-·--

---------· --·- . ---- -- -------

------- ----------------- ---·------ ------····-~---- ---~--- -

---·-------.. r

' -·--·-··----···

·-----· ----

--------~-

·-·--···---~-

---~·-· --

-----

-

LCS LCS

Known %R

1.00E+01 100.62 ,

'

i I


LCS RPD MDA

I Blank

Flag Flag Flag Flag

OK OK

OK OK

NA OK

OK

0174

C:

&!

~ 0 0 .!!,!

~ iii C: ct

II

Eberline Analytical


~

(0 N N ca a::

1/) C: .Q .!!! (.) Cl)

C C'a ...... C: Cl)

E C: 0 ... > C: w 0 :E <(

Lab Fraction

01 -------~-

02

03

04

----

----

---··

Nuclide

RA-226 ------

RA-226

RA-226

RA-226 --·----···---·· - -------~-

---------·-·-

---------

---------··----

r----------------··

---------~-

--------·------------

---~-----

·-

Sample Desc

LCS

MBL

DUP

DO -------

-----

---·-----


Work Order: 18-06097-Ra226-1

Sample I Sample Radiometric Grav

I Mean

Date I Aliquot %Rec % Rec %Rec

06/21/18 00:00 1.ooE+ooi 100.00 0.00 110.001

- ---- ---

06/21/18 00:00 1.ooE+ooi 100.00 0.00 i

110.001 i

"---7---···---· i.

06/20/18 10:00 1.ooE+ooi 100.00 0.00 110.00!

·+ L-

06/20/18 10:00 1.00E+00! 100.00 0.00 110.00

··r-·· i I ····1 I

--=-=l--------- ~----

··- ---- --------

-----·-- ·-· -------~--·-------.

-···-- ···--·- ·---···---~--

I .

---··---·-

-----·--------

-------- ·-----

---·--

SAF I i I

I I

Printed: 7/10/2018 7: 19 AM Page 2 of 3

Sep to I

Sep t1

Date/Time Date/Time

7/9/2018 12:48 ·------ -···----

7/9/2018 12:48 ··---------- -

7/9/2018 12:48 ----- -------

7/9/2018 12:48

----·--·--

-------

0175


~ ~

§ a:: """"

GI (0 "O 0 N 0 .!!! N £ ns cu a:: c:: ct

... ~ 0 -l: ~ oi u

i .. C: <( ., .s 1:: ., fil -~

fl) C 0 'iii ·c:; Q)

C ta -!I C Q)

E C 0 ... ·s; C w 0 :E <(

Lab

I Nuclide Fraction

01 RA-226

02 RA-226

03 RA-226

04 RA-226

--


Work Order: 18-06097-Ra226-1

Sample Counting Halflife Detect i Carrier Count

Desc Date/Time (days) I Time Counts

LCS 07/09/18 14:44 A_Spec [Alpha_047 170 2.21 E+02 i

~--.. ·--- "·----- -

MBL 07/09/18 14:44 A_Spec Alpha_048 170 -1.38 E+00

-------- .. ----

DUP 07/09/18 14:44 A_Spec Alpha_049 170 8.45 E+00

----·-~---- _.. ________

DO 07/09/18 14:44 A_Spec Alpha_oso 170 1.96 E+00

__ ,. __ ' ...

- ··---------- --~- --·-·--· --------------

------·----·-

--------

---···------· -·--

·-----·-·- -----

---~-- -----------

-~----- . -----------~--··--

·--~----·

·--- -··--··---·---

------

·-------

Bkg CPM

6.00 E-03

1.40 E-02

1.50 E-02

1.20 E-02


Eff

17.4

17.6

15.6

13.7

0176


Internal Sample I

Client Fraction Desc ID

01 LCS LCS

02 MBL BLANK



18-06097-Ra226-1 (pCi/I) in WA Tracer ID: Ba-6a

Sample Sample

I Tracer

Date Aliquot Aliquot (g)

06/21/18 00:00 1.0000 2.2121

06/21/18 00:00 1.0000 2.2067

06/20/18 10:00 1.0000 2.2113

06/20/18 10:00 1.0000 2.2115

Tracer Radiometric ACT(dpm) Tracer (pCi)

1063.2901 655.0000 I

1060.6945 658.0000

1062.9056 584.0000

1063.0017 621.0000


Radiometric SAF SAF ¾Rec 1· 2·

136.75 3.00A 1.00

137.72 3.00A 1.00

121.98 2.66 1.00

129.69 2.69 1.00

I

0177

Eberline Analytical


LCS & Matrix Spikes

Isotope So/#

Ra-226 Ra-Sb

fraction I Isotope

01 Ba-133

02 Ba-133

03 Ba-133

04 Ba-133

Version 2.0 08/99

Activity dpm/g

43.970

So/#

Ba-6a

Ba-6a

Ba-6a

Ba-6a

Solution Date

7/6/2018

Tracers Activity dpmlg

480.670

480.670

480.670

480.670

Approx Addition

0.500

Solution Date

7/6/2018

7/6/2018

7/6/2018

7/6/2018


Analysis Code

Ra226 LCS

Volume Used (g)

0.5054

Volume Used (g)

2.2121

2.2067

2.2113

2.2115

MS Volume Used(g)

Approx Addition

2.1100

2.1100

2.1100

2.1100

Date

7/6/2018 7:01

LCSD Volume Used(g)

MSD Volume Used (g)

Technician

JHARVEY

LCS MS Known

pCi

10.01

Tracer

Error Estimate

0.460

Added pCi

0.00

Error Estimate

0.000


Page 1 of 1

Printed: 7/6/2018 7:18 AM

Witness Initials

MSD Known i Error Added Error

pCi Estimate pCi Estimate

o.ool 0.000 0.00 0.000

LCS

Matrix Spike

0178

Lab



Fraction Client ID

01 LCS

02 BLANK



Comments

Sample

Type

LCS

MBL

DUP

DO

Aliquot Worksheet


Ra226 liters 7/11/2018


Ratio Post/Pre Noof Dils Dil Factor Ratio Aliquot Net Equiv

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

Technician d-~e~oare '-4-, m

Technician

JHARVEY

MS Aliquot Data

Aliquot Net Equiv


H-3 Solids Only wa tefA<Rlecr-1 3u1st-

(ml) , Aliq

0179

Eberline Analytical - Oak Ridge Version 1.1 10/2015

Work Order

TRetec AMO Environmental Decisions

Fraction Client ID

01 LCS

02 BLANK

03 DUP


/""\.

Technician: t;,'1,-f'l o/ '(jl I \

Sample

Type

LCS MBL

DUP DO

Gravimetric Worksheet

Analysis Code

Ra226

Carrier Data

Gravimetric Carrier

Filter Data Carrier Added Filter Tare Filter Final

(ml) (g) (g)

0.0208 0.0308

0.0210 0.0315 0.0212 0.0288 0.0215 0.0292

..,....1 (\

,1 'JI 1v Date: _1_/ __ I _/.J..LL_


Filter Net (g)

0.0100 0.0105

0.0076

0.0077

Printed: 7/9/2018 1 :45 PM Page 1 of 1

Technician

JBAILEY

Gravimetric %

Recovery

0180



Sample Size: Generic Mult. Factor: Sample Date/Time: Acquisition Date/Time: Acquisition Live Time: Acquisition Real Time:

Chem. Recovery Factor: Counting Efficiency: Effective Efficiency:

SPIKE \\OR-ALPHAl\Canberra\Apex.Alpha\Root\Data\00002166 1806097A-RA 01 Shelf 2 Ra


<not performed>

l.000E+000 +/- 0.000E+000 liter 3.000E+000 7/9/2018 7/9/2018

Generic Div. Factor: 2:09:31 PM 2:44:04 PM


1.0000 +/- 0.0000 0.1744 +/- 0.0030 on 6/6/2018 0.1744 +/- 0.0030

l.000E+000

2:37:41 PM

Control Certificate Name: Ra226 Ra-Sb Chem. Recov. of Control: RA-226 0.335357 +/- 0.025425 Peak Match Tolerance: 0.350 MeV

Nuclide

RA-224 RA-226

Nuclide

RA-224 RA-226

Energy (MeV)

Id Conf.

5.471 4.585

PEAK AREA REPORT

Net Pk Area

5.47 220.98

Pk Area Error%

96. 55 13. 22

Ambient Backgnd

1. 53 1. 02


Energy (keV)


0.942 0.949

5685.50* 4785.00*

2.62E-001 +/- 2.53E-001 l.0lE+00l +/- l.37E+000

Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

MDA

3.0 4.4

(pCi/liter

3.41E-001 +/- l.lSE-002 2.87E-001 +/- 9.72E-003

0181

60

55

50

45

40

35 Vl .j-J s::: ::::s

8 30

25

20

15

10

5

0 I

3500

ROI Type: 1

I

4000 4500

0000216682.CNF

5000 Energy(kev)

Live Time 10200.000 sec Rea 1 Time 10200 .100 sec start: 1 3453.S(kev) stop : 1024 6472. 7(kev) Acq. start Mon Jul 09 14:44:04 2018

5500 6000

0182

Channel Data Report 7/9/2018 5:38:47 PM Page 1


Sample Title: 01


Channell------l-------l-------l-------l-------1-------1-------1-------I 1: 2 0 2 1 1 1 1 0

9: 0 3 0 1 1 0 0 2

17: 1 2 0 1 1 1 1 0

25: 0 0 1 0 2 2 0 0

33: 0 1 1 1 1 2 3 1

41: 4 1 0 1 2 0 1 1

49: 1 2 1 1 1 0 1 0

57: 0 2 2 1 1 1 2 0

65: 0 0 4 1 1 1 3 1

73: 1 0 4 0 2 2 2 0

81: 2 1 2 2 1 0 1 0

89: 1 2 2 0 2 0 3 0

97: 1 2 2 2 3 1 1 2

105: 1 1 2 1 1 1 1 0

113: 1 0 1 1 1 2 2 3

121: 0 2 2 1 2 3 1 4

129: 1 2 1 1 2 2 2 2

137: 3 0 2 1 3 2 2 4

145: 0 0 0 4 1 0 1 0

153: 1 2 1 3 1 1 2 1

161: 0 2 0 2 0 2 1 1

169: 1 0 3 3 1 2 0 2

177: 0 0 0 0 2 2 0 1

185: 2 2 0 1 0 1 1 0

193: 2 1 5 0 1 2 2 1

201: 2 1 1 0 4 2 1 3

209: 1 2 2 2 2 2 1 0

217: 0 1 3 2 1 0 1 0

225: 3 1 2 1 1 1 3 1

233: 3 3 4 1 2 0 2 1

241: 0 2 1 0 2 1 1 4

249: 0 4 1 3 4 0 3 2

257: 3 3 2 0 4 1 0 2

265: 3 2 2 3 1 1 3 2

273: 3 0 5 0 1 1 0 1

281: 0 0 1 3 1 2 1 2

289: 4 3 1 0 4 0 1 0

297: 0 3 2 1 1 1 0 1

305: 1 0 1 2 2 2 2 1

313: 0 2 1 2 3 2 2 1

321: 2 2 4 2 2 0 0 1

329: 0 1 2 2 0 3 2 3

337: 4 0 0 1 2 2 1 2

345: 0 2 3 0 0 3 0 1

353: 3 3 1 0 1 3 2 3

361: 1 1 4 2 3 2 1 0

0183


369: 0 2 4 2 1 0 1 1

Sample Title: 01

Channell------l-------l-------l-------l-------1-------1-------1-------\ 377: 0 1 3 2 1 3 0 0

385: 2 3 0 1 0 1 0 1

393: 0 1 1 1 4 0 0 1

401: 0 2 2 1 1 0 0 3

409: 3 2 6 2 1 3 1 5

417: 1 1 2 3 0 1 2 0

425: 1 3 3 2 1 1 1 1

433: 3 1 4 2 1 2 4 0

441: 3 2 3 1 1 1 0 3

449: 0 0 1 0 1 2 1 0

457: 1 0 1 0 1 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 1 0 0 0 0 0 0

489: 0 0 0 1 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 1 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 0 1

529: 0 0 1 0 0 0 0 0

537: 0 1 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 1 0 0 0 0 0

569: 0 0 0 0 0 1 1 0

577: 1 0 0 0 0 0 0 0

585: 1 0 0 0 0 0 0 2

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 1 0 0 0

617: 0 0 0 0 0 0 0 0

625: 0 0 0 0 0 0 0 1

633: 0 0 0 1 0 0 0 0

641: 1 0 0 0 0 0 0 0

649: 0 1 0 0 0 0 0 0

657: 0 1 0 1 0 0 1 0

665: 0 0 0 1 0 0 0 0

673: 0 0 0 0 0 0 0 1

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 1 0

729: 0 0 0 0 0 0 0 1

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 1 1 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 1 0 1

785: 0 0 0 0 0 0 0 1

793: 0 0 0 0 0 0 1 0

0184


801: 0 0 0 0 0 0 0 0

Sample Title: 01

Channell------l-------1-------1-------1-------I-------I-------I-------I 809: 0 0 1 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 1 0 1

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 1 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 1 0 0

0185






Nuclide

RA-224 RA-226

Energy (MeV)

5.531 4.779

BLANK \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002166

1806097A-RA 02 Shelf 2 Ra


<not performed>

1.000E+000 +/- 0.000E+000 liter 3.000E+000 7/9/2018 7/9/2018

Generic Div. Factor: 2:09:31 PM 2:44:05 PM


1.0000 +/- 0.0000

1.000E+000

0.1760 +/- 0.0030 on 6/6/2018 0.1760 +/- 0.0030

2:37:42 PM

0.350 MeV

PEAK AREA REPORT

Net Pk Area

-2.89 -1.38

Pk Area Error%-

82.82 168.33

Ambient Backgnd

2.89 2.38


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

0.0 3.0

Nuclide Id

Conf. Energy (keV)


MDA (pCi/liter

RA-224 RA-226

0. 969 1.000

5685.50* -1.37E-001 +/- 1.14E-001 4785.00* -6.23E-002 +/- 1.05E-001

4.16E-001 +/- 1.41E-002 3.70E-001 +/- 1.25E-002

0186

60

55

50

45

40

35 V)

+-' C:

8 30

25

20

15

10

5

0 I I

3500 4000 4500

ROI Type: 1

0000216683.CNF

<D

~

5000 Energy(kev)

5500

Live Time :10200.000 sec Real Time :10200.100 sec start: l:3443.9(kev) Stop : 1024: 6472 .3(keV) Acq. start :Mon Jul 09 14:44:05 2018

6000

0187


******************************************************* ***** s p E C T RA L DAT A R E P O R T ***** *******************************************************

Sample Title: 02


Channell------l-------l-------l-------l-------l-------1-------1-------1 1 : 0 0 0 0 0 0 0 0

9: 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 0 0 0 233: 0 0 0 0 0 0 0 0 241: 0 0 0 0 0 0 0 0 249: 0 0 0 0 0 0 0 0 257: 0 0 0 0 0 0 0 0 265: 0 0 0 0 0 0 0 0 273: 0 0 0 0 0 0 0 0 281: 0 0 0 0 0 0 0 0 289: 0 0 0 0 0 0 0 0 297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 0 0 0

313: 0 0 0 0 0 0 0 0 321: 0 0 0 0 0 0 0 0 329: 0 0 0 0 0 0 0 0 337: 0 0 0 0 0 0 0 0 345: 0 0 0 0 0 0 0 0 353: 0 0 0 0 0 0 0 0 361: 0 0 0 0 0 0 0 0

0188


369: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------l-------1-------1-------1-------I-------I-------I 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 1 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0 569: 0 0 0 0 0 0 0 0 577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0 601: 0 0 0 0 0 0 0 0 609: 0 0 0 0 0 0 0 0 617: 0 0 0 0 0 0 0 0 625: 0 0 0 0 0 0 0 0 633: 0 0 0 0 0 0 0 0 641: 0 0 0 0 0 0 0 0 649: 0 0 0 0 0 0 0 0 657: 0 0 0 0 0 0 0 0 665: 0 0 0 0 0 0 0 0 673: 0 0 0 0 0 0 0 0 681: 0 0 0 0 0 0 0 0 689: 0 0 0 0 0 0 0 0 697: 0 0 0 0 0 0 0 0 705: 0 0 0 0 0 0 0 0 713: 0 0 0 0 0 0 0 0 721: 0 0 0 0 0 0 0 0 729: 0 0 0 0 0 0 0 0 737: 0 0 0 0 0 0 0 0 745: 0 0 0 0 0 0 0 0 753: 0 0 0 0 0 0 0 0 761: 0 0 0 0 0 0 0 0 769: 0 0 0 0 0 0 0 0 777: 0 0 0 0 0 0 0 0 785: 0 0 0 0 0 0 0 0 793: 0 0 0 0 0 0 0 0

0189


801: 0 0 0 0 0 0 0 0

Sample Title: 02

Channell------l-------1-------1-------1-------I-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 0 0 0

953: 0 0 0 0 0 0 0 0

961: 0 0 1 0 0 0 0 0

969: 1 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0190






Nuclide

RA-224 RA-226

Energy (MeV)

5.580 4.575

OU-1-007 OUTFALL 007 DIS DUP \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002166 1806097A-RA 03 Shelf 2 Ra


<not performed>

1.000E+000 2.660E+000 6/20/2018 7/9/2018

170.0

+/- 0.000E+000 liter Generic Div. Factor:

2: 09: 31 PM 2:44:00 PM


1.0000 +/- 0.0000

1.000E+000

0.1565 +/- 0.0028 on 2/16/2018 12:37:01 PM 0.1565 +/- 0.0028

0.350 MeV

PEAK AREA REPORT

Net Pk Area

-5.29 8.45

Pk Area Error%

53.30 78.43

Ambient Backgnd

6.29 2.55


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0

Nuclide Id

Conf. Energy (keV)


MDA (pCi/liter

RA-224 RA-226

0.986 0.944

5685.50* -2.52E-001 +/- 1.35E-001 4785.00* 3.81E-001 +/- 2.99E-001

5.54E-001 +/- 1.95E-002 3.78E-001 +/- l.33E-002

0191

55

50

45

40

35 V'I -I-' C:

8 30

25

20

15

10

5

0 3500

ROI Type: 1

4000

0000216684.CNF

i1 .'l :\I i_ Ii ,\'


5500

""' ~ ~ ;l;

Live Time :10200.000 sec Real Time :10200.100 sec Start: 1: 3474. l(kev) Stop : 1024: 6513. l(kev) Acq. Start :Mon Jul 09 14:44:00 2018

6000 6500

0192



Sample Title: 03


Channell------l-------l-------l-------l-------1-------1-------1-------I 1 : 0 0 0 0 0 0 0 0

9: 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0

25: 0 0 0 0 0 0 0 0

33: 0 0 0 0 0 0 0 0

41: 0 0 0 0 0 0 0 0

49: 0 0 0 0 0 0 0 0

57: 0 0 0 0 0 0 0 0

65: 0 0 0 0 0 0 0 0

73: 0 0 0 0 0 0 0 0

81: 0 0 0 0 0 0 0 0

89: 0 0 0 0 0 0 0 0

97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0

113: 0 0 0 0 0 0 0 0

121: 0 0 0 0 0 0 0 0

129: 0 0 0 0 0 0 0 0

137: 0 0 0 0 0 0 0 0

145: 0 0 0 0 0 0 0 0

153: 0 0 0 0 0 0 0 0

161: 0 0 0 0 0 0 0 0

169: 0 0 0 0 0 0 0 0

177: 0 0 0 0 0 0 0 0

185: 0 0 0 0 0 0 0 0

193: 0 0 0 0 0 0 0 0

201: 0 0 0 0 0 0 0 0

209: 0 0 0 0 0 0 0 0

217: 0 0 0 0 0 0 0 0

225: 0 0 0 0 0 1 0 0

233: 0 0 0 0 0 0 0 0 241: 0 0 0 0 0 0 0 0

249: 0 0 0 0 0 0 0 0

257: 0 0 0 0 0 0 0 0

265: 0 0 0 0 0 0 0 0

273: 0 0 0 0 0 0 0 0

281: 0 0 0 0 0 0 0 1

289: 0 0 0 0 0 0 0 0

297: 0 0 0 0 0 0 0 0

305: 0 0 0 0 0 1 0 0

313: 0 0 0 0 0 0 0 0

321: 0 1 0 1 0 0 0 0

329: 0 0 0 0 0 0 0 0

337: 0 0 0 0 0 0 0 1

345: 1 0 0 0 0 0 0 0

353: 0 0 0 0 0 0 0 0

361: 0 0 0 0 0 0 0 0

0193


369: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------l-------1-------1-------1-------I-------I 377: 1 1 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 1 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 1

417: 0 0 0 0 0 0 0 0

425: 0 0 0 0 0 0 0 0

433: 0 0 0 0 0 0 1 0

441: 1 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 1 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0 521: 0 0 0 0 0 0 0 0 529: 0 0 0 0 0 0 0 0 537: 0 0 0 0 0 0 0 0 545: 0 0 0 0 0 0 0 0 553: 0 0 0 0 0 0 0 0 561: 0 0 0 0 0 0 0 0 569: 0 0 0 0 0 0 0 0 577: 0 0 0 0 0 0 0 0 585: 0 0 0 0 0 0 0 0 593: 1 0 1 0 0 0 0 0 601: 0 0 0 0 0 0 0 0 609: 0 0 0 0 0 0 0 0 617: 0 0 0 0 0 0 0 0 625: 0 0 0 0 0 0 0 0 633: 0 1 0 0 0 0 0 0 641: 0 0 0 0 0 0 0 0 649: 0 0 0 0 0 0 0 0 657: 0 0 0 0 0 0 0 0 665: 0 0 0 0 0 0 0 0 673: 0 0 0 0 0 0 0 0 681: 0 0 0 0 0 0 0 0 689: 0 0 0 0 0 0 0 0 697: 0 0 0 0 0 0 0 0 705: 0 0 0 0 0 1 0 0 713: 0 0 0 0 0 0 0 0 721: 0 0 0 0 0 0 0 0 729: 0 0 0 0 0 0 0 0 737: 0 0 0 0 0 0 0 0 745: 0 0 0 0 0 0 0 0 753: 0 0 0 0 0 0 0 0 761: 0 0 0 0 0 0 0 1

769: 0 0 0 0 0 0 0 0 777: 0 0 0 0 0 0 0 0 785: 0 0 0 0 0 0 0 0 793: 0 0 0 0 0 0 0 0

0194


801: 0 0 0 0 0 0 0 0

Sample Title: 03

Channell------l-------l-------l-------l-------1-------1-------1-------\ 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0

865: 0 0 0 0 0 0 0 0

873: 0 0 0 0 0 0 0 0

881: 0 0 0 0 0 0 0 0

889: 0 0 0 0 0 0 0 0

897: 0 0 0 0 0 0 0 0

905: 0 0 0 0 0 0 0 0

913: 0 0 0 0 0 0 0 0

921: 0 0 0 0 0 0 0 0

929: 0 0 0 0 0 0 0 0

937: 0 0 0 0 0 0 0 0

945: 0 0 0 0 0 1 0 0

953: 1 0 0 0 0 1 0 0

961: 0 0 0 0 0 0 0 0

969: 0 0 0 0 0 0 0 0

977: 0 0 0 0 0 0 0 0

985: 0 0 0 0 0 0 0 0

993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0

1009: 0 0 0 0 0 0 0 0

1017: 0 0 0 0 0 0 0 0

0195






Nuclide

RA-224 RA-226

Energy (MeV)

5.426 4.624

OU-1-007 OUTFALL 007 DIS \\OR-ALPHAl\Canberra\ApexAlpha\Root\Data\00002166 1806097A-RA 04 Shelf 2 Ra


<not performed>

l.000E+000 +/- 0.000E+000 liter 2.690E+000 6/20/2018 7/9/2018

Generic Div. Factor: 2: 09: 31 PM 2:44:02 PM


1.0000 +/- 0.0000

l.000E+000

0.1369 +/- 0.0025 on 2/16/2018 12:37:00 PM 0.1369 +/- 0.0025

0.350 MeV

PEAK AREA REPORT

Net Pk Area

-1. 21 1. 96

Pk Area Error%

189.99 208.49

Ambient Backgnd

2.21 2.04


Reagent Backgnd

0.00E+000 0.00E+000

FWHM (keV)

3.0 3.0

Nuclide Id

Conf. Energy (keV)


MDA (pCi/liter

RA-224 RA-226

0.916 0. 967

5685.50* -6.67E-002 +/- l.27E-001 4785.00* l.02E-001 +/- 2.13E-001

4.41E-001 +/- l.57E-002 4.06E-001 +/- l.44E-002

0196

60

55

50

45

40

35 V) .j-J C ::::l

8 30

25

20

15

10

5

0 I

3500

ROI Type: 1

I

4000 4500

0000216685.CNF

5000 Energy(kev)

.._,.

' ~

5500

Live Time :10200.000 sec Rea 1 Ti me : 10200 .100 sec start: 1: 3447. 7(kev) stop : 1024:6482.G(kev) Acq. start :Mon Jul 09 14:44:02 2018

6000

0197



Sample Title: 04


Channell------l-------1-------1-------1-------I-------I-------I-------I 1: 0 0 0 1 0 0 0 0 9 : 0 0 0 0 0 0 0 0

17: 0 0 0 0 0 0 0 0 25: 0 0 0 0 0 0 0 0 33: 0 0 0 0 0 0 0 0 41: 0 0 0 0 0 0 0 0 49: 0 0 0 0 0 0 0 0 57: 0 0 0 0 0 0 0 0 65: 0 0 0 0 0 0 0 0 73: 0 0 0 0 0 0 0 0 81: 0 0 0 0 0 0 0 0 89: 0 0 0 0 0 0 0 0 97: 0 0 0 0 0 0 0 0

105: 0 0 0 0 0 0 0 0 113: 0 0 0 0 1 0 1 0 121: 0 0 0 0 0 0 0 0 129: 0 0 0 0 0 0 0 0 137: 0 0 0 0 0 0 0 0 145: 0 0 0 0 0 0 0 0 153: 0 0 0 0 0 0 0 0 161: 0 0 0 0 0 1 0 0 169: 0 0 0 0 0 0 0 0 177: 0 0 0 0 0 0 0 0 185: 0 0 0 0 0 0 0 0 193: 0 0 0 0 1 0 0 0 201: 0 1 0 0 0 0 0 0 209: 0 0 0 0 0 0 0 0 217: 0 0 0 0 0 0 0 0 225: 0 0 0 0 0 0 0 0 233: 0 0 0 0 0 0 0 0 241: 0 0 0 0 0 0 0 0 249: 0 0 0 0 0 0 0 0 257: 0 0 0 0 0 0 0 0 265: 0 0 0 0 0 0 0 0 273: 0 0 0 0 0 0 0 0 281: 0 0 0 0 0 0 0 0 289: 0 0 0 0 0 0 0 0 297: 0 0 0 0 0 0 0 0 305: 0 0 0 0 0 0 0 0 313: 0 0 0 0 0 0 0 0 321: 0 0 0 0 0 0 0 0 329: 0 0 0 0 0 0 0 0 337: 0 0 0 0 0 0 0 0 345: 0 0 0 0 0 0 0 0 353: 0 0 1 0 0 0 0 0 361: 0 0 0 0 0 0 0 0

0198


369: 0 0 1 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------l-------l-------1-------1-------1-------\ 377: 0 0 0 0 0 0 0 0

385: 0 0 0 0 0 0 0 0

393: 0 0 0 0 0 0 0 0

401: 0 0 0 0 0 0 0 0

409: 0 0 0 0 0 0 0 0

417: 0 0 0 0 0 0 0 0

425: 0 0 0 1 0 0 0 0

433: 0 0 0 1 0 0 0 0

441: 0 0 0 0 0 0 0 0

449: 0 0 0 0 0 0 0 0

457: 0 0 0 0 0 0 0 0

465: 0 0 0 0 0 0 0 0

473: 0 0 0 0 0 0 0 0

481: 0 0 0 0 0 0 0 0

489: 0 0 0 0 0 0 0 0

497: 0 0 0 0 0 0 0 0

505: 0 0 0 0 0 0 0 0

513: 0 0 0 0 0 0 0 0

521: 0 0 0 0 0 0 0 0

529: 0 0 0 0 0 0 0 0

537: 0 0 0 0 0 0 0 0

545: 0 0 0 0 0 0 0 0

553: 0 0 0 0 0 0 0 0

561: 0 0 0 0 0 0 0 0

569: 0 0 0 0 0 0 0 0

577: 0 0 0 0 0 0 0 0

585: 0 0 0 0 0 0 0 0

593: 0 0 0 0 0 0 0 0

601: 0 0 0 0 0 0 0 0

609: 0 0 0 0 0 0 0 0

617: 0 0 1 0 0 0 0 0

625: 0 0 0 1 0 0 0 0

633: 0 0 0 0 0 0 0 0

641: 0 0 0 0 0 0 0 0

649: 0 0 0 0 0 0 0 0

657: 0 0 0 0 0 0 0 0

665: 0 0 0 1 0 0 0 0

673: 0 0 0 0 0 0 0 0

681: 0 0 0 0 0 0 0 0

689: 0 0 0 0 0 0 0 0

697: 0 0 0 0 0 0 0 0

705: 0 0 0 0 0 0 0 0

713: 0 0 0 0 0 0 0 0

721: 0 0 0 0 0 0 0 0

729: 0 0 0 0 0 0 0 0

737: 0 0 0 0 0 0 0 0

745: 0 0 0 0 0 0 0 0

753: 0 0 0 0 0 0 0 0

761: 0 0 0 0 0 0 0 0

769: 0 0 0 0 0 0 0 0

777: 0 0 0 0 0 0 0 0

785: 0 0 0 0 0 0 0 0

793: 0 0 0 0 0 0 0 0

0199


801: 0 0 0 0 0 0 0 0

Sample Title: 04

Channell------l-------l-------1-------1-------1-------I-------I-------I 809: 0 0 0 0 0 0 0 0

817: 0 0 0 0 0 0 0 0

825: 0 0 0 0 0 0 0 0

833: 0 0 0 0 0 0 0 0

841: 0 0 0 0 0 0 0 0

849: 0 0 0 0 0 0 0 0

857: 0 0 0 0 0 0 0 0 865: 0 0 0 0 1 0 0 0 873: 0 0 0 0 0 0 0 0 881: 0 0 0 0 0 0 0 0 889: 0 0 0 0 0 0 0 0 897: 0 0 0 0 0 0 0 0 905: 0 0 0 0 0 0 0 0 913: 0 0 0 0 0 0 0 0 921: 0 0 0 0 0 0 0 0 929: 0 0 0 0 0 0 0 0 937: 0 0 0 0 0 0 0 0 945: 0 0 0 0 0 0 0 0 953: 0 0 0 0 0 0 0 0 961: 0 0 0 0 0 0 1 0 969: 0 0 0 0 0 0 0 0 977: 0 0 0 0 0 0 0 0 985: 0 0 0 0 0 0 0 0 993: 0 0 0 0 0 0 0 0

1001: 0 0 0 0 0 0 0 0 1009: 0 0 0 0 0 0 0 0 1017: 0 0 0 0 0 0 0 0

0200

i--age I m L.

7/9/2018 5:33:38 AM

I I nA ,~I II\Al\!1ARV Rt=PnRT """""',;;,,. --~"1,lt,,U>I.I llil ll, II II ll-111 -II 'Iii II


Date : 7/9/2018 Time : 5:33:38 AM

CHAMBER DEVICE PARAMETER FLAG DATE Alpha 001 21f ALL Not Done Alpha 002 21f ALL Not Done Alpha 003 21f ALL Passed 7/9/2018 5:20:39 AM Alpha 004 21f ALL Passed 7/9/2018 5:20:39 AM Alpha 005 2lf ALL Not Done Alpha 006 21f ALL Not Done Alpha 007 21f ALL Not Done Alpha 008 21f ALL Not Done Alpha 009 21f ALL Not Done Alpha 010 21f ALL Passed 7/9/2018 5 :20:40 AM Alpha 011 2lf ALL Passed 7/9/2018 5:20:41 AM Alpha 012 21f ALL Passed 7/9/2018 5:20:42 AM Alpha 013 2lf ALL Not Done Alpha 014 2lf ALL Passed 7/9/2018 5:20:43 AM Alpha 015 2lf ALL Not Done Alpha 016 21f ALL Not Done Alpha 033 Alpha Analyst! 00DC Peak Energy Action 7/9/2018 5:20:44 AM Alpha 034 Alpha Analyst! 00DC ALL Not Done Alpha 035 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:20:46 AM Alpha 036 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:20:47 AM Alpha 037 Alpha Analyst 1 00DC ALL Not Done Alpha 038 Alpha Analyst 100 DC ALL Not Done Alpha 039 Alpha Analystl00DC PeakFWHM Action 7/9/2018 5:20:49 AM Alpha 040 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:20:50 AM Alpha 041 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:20:52 AM Alpha 042 Alpha Analystl00DC ALL Passed 7/9/2018 5:20:53 AM Alpha 043 Alpha Analystl00DC ALL Not Done Alpha 044 Alpha Analystl00DC ALL Passed 7/9/2018 5:20:55 AM Alpha 045 Alpha Analyst 100 DC ALL Passed 7/9/2018 5:20:56 AM Alpha 046 Alpha Analystl00DC ALL Passed 7/9/2018 5:20:58 AM Alpha 047 Alpha Analyst 100 DC ALL Passed 7/9/2018 5:21:00 AM Alpha 048 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:21:01 AM Alpha 049 Alpha Analystl00DC ALL Passed 7/9/2018 5:21:03 AM Alpha 050 Alpha Analystl00DC ALL Passed 7/9/2018 5:21:05 AM Alpha 051 Alpha Analyst! 00DC ALL Not Done Alpha 052 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:21:07 AM Alpha 053 Alpha Analyst! 00DC PeakFWHM Action 7/9/2018 5:21:09 AM Alpha 054 Alpha Analyst 1 00DC ALL Not Done Alpha 055 Alpha Analyst 1 00DC ALL Not Done Alpha 056 Alpha Analystl00DC ALL Passed 7/9/2018 5:21:10 AM Alpha 057 Alpha Analyst! 00DC ALL Passed 7/9/2018 5:21:13 AM Alpha 058 Alpha Analyst 1 00DC ALL Passed 7/9/2018 5:21:15 AM

0201

1-'age L OT L Kev1ew ot UA Kesults - 1-'u1ser l;necK

7/9/2018 5:33:38 AM

CHAMBER DEVICE PARAMETER FLAG DATE Alpha 059 Alpha Analystl 00DC ALL Passed 7/9/2018 5:21:17 AM


APPROVED BY:

APPROVAL DATE: ·119 I \b

0202

Library Listing Report 6/12/12 12:16:17 PM Page l

*************************************************************************


*************************************************************************

Nuclide Library Title: Radium

Nuclide Library Description: Ra-226, Po-218, Rn-222


Name (Seconds) (keV ) Uncert. (keV (%) Uncert. (Abs.+-)

PO-218 5.049E+010 6003.000* 0.000 99.9800 0.0000

RN-222 5.049E+010 5490.000* 0.000 99.9200 0.0000

RA-226 5.049E+0l0 4785.000* 0.000 100.0000 0.0000

* = key line


0203

SECTION XI

ANALYTICAL DAT A (RADIUM-228)

0204


Work Order 18-06097

Analysis Code I Ra228 I Run 1

Date Received I 6/21/2018

Lab Deadline I 7/11/2018


Project I WESTLAKE

Report Level I 4

Activity Units I pCi

Aliquot Units

Matrix WA

Method EPA 904.0

Instrument Type Alpha/Beta GPC

Radiometric Tracer Ba-133

Radiometric Sol# Ba-Ga


Carrier Yttrium

Carrier Cone (mg/ml) 31.1


01 LCS

02 MBL

03 DUP

04 DO

18-06097 Ra228 Run 1

Client ID

LCS

BLANK





I Login I CPM

30

30



06/21 /18 00:00 1.0000E+00

06/21/18 00:00 1.0000E+00

06/20/18 10:00 1.0000E+00

06/20/18 10:00 1.0000E+00

0205



Fraction Desc Aliquot (g)

01 LCS 2.2121

02 MBL 2.2067

03 DUP 2.2113

04 DO 2.2115


1062.5

1059.9

1062.1

1062.2

Radiometric Radiometric

Tracer(pCi) %Rec

655.0 136.85

658.0 137.82

584.0 122.06

621.0 129.79

18-06097 Ra228 Run 1

Grav Carrier Grav Filter

Added(ml) Tare (g)

2.000 0.0859

2.000 0.0862

2.100 0.0860

2.000 0.0862

I Grav Filter

Final (g)

0.1480

0.1470

0.1509

0.1467

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.


Grav Filter I Grav Net(g) %Rec

0.0621 99.84

0.0608 97.75

0.0649 99.37

0.0605 97.27


Mean SAF SAF %Rec 1* 2*

109.82 1.00 1.00

107.52 1.00 1.00

109.31 1.00 1.00

106.99 1.00 1.00

0206



01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Date

Rough Prep Prep I By Date

07/10/18 12:40

07/10/18 12:40

07 /10/18 12:40 I

I 01110118 12:40 i

18-06097 Ra228 Run 1

Prep By

JBAILEY

JBAILEY

JBAILEY

JBAILEY

Sep to Date/Time

07/09/18 12:48

07/09/18 12:48

07/09/18 12:48

07/09/18 12:48

• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. " Indicates estimated SAF value.


Sep to By

JBAILEY

JBAILEY

JBAILEY

JBAILEY

I



07/10/18 12:59 JBAILEY

07/10/18 12:59 JBAILEY

07/10/18 12:59 JBAILEY

07/10/18 12:59 JBAILEY

0207

Eberline Analytical



Work Order: 18-06097-Ra228-1 Printed: 7/11/2018 7:35 AM

Page 1 of 3

~ Lab

Fraction

01

T

Nuclide I Sample I Client Activity Results I Error Estimate i MDA

LCS

I LCS LCS

I RPO MDA

I Blank

Desc Identification Units Known %R Flag Flag Flag Flag

RA-228 LCS LCS pCi/1 8.63E+00 7.52E-01 I 8.66E-01 9.20E+ool 93.82 OK OK I

c:: ::i a::

GI "0 0 u .!!!

i <a c:: q:

'l:

~

~---··

02 or- -·------·

03 ------------

04 00 N N I 1---- --1 -

C'G 0::

1/) C: .2 1/) ·c:; Q)

0 ca -C: Q)

E C: e ·s;:

11 ----

--------1-----

--··---~-- ----·- --------·-----·

RA-228 MBL BLANK

-------· ____ ,. ___ --~-----

RA-228 DUP OU-1-007 Outfall 007 DIS

--------- --·-------··

RA-228 DO OU-1-007 Outfall 007 DIS

··----- --~---- ---------------

- ----+------1- ------·

.. --- -------+-------1--------------------

- --------- -4--------1--------- --------------------

I --- --- - ----- -1 -- -- ---7 pCi/1 4.48E-01 __ 4.2~~-01 ~ 8.63E-01 OK OK

pCi/1 8.70E-01 4.99E-01 9.81 E-01 ! NA OK

-----·---- -··--···-- - ····-- -···+ -· ··-·-------···----I

pCi/1 7 .89E-02 4.12E-01 8. 71 E-01 ( I

OK

- - --·- - -----· ---

.. -- +--------1 - -- . ___ J _ ----~- -- ___ i

I I

- -:--------- -------- +--

--1-------

-+-----------+--~--+---+----- -1--i---------,

I

I I

--------- ... ·--·-····---!-· --- - -

- ----····--r----··--

------------e---------1---------- ------------ ---- -+------------ -- --+---- ··-------------1--------+------+--------t------+------+------+------r-------l

C: w ----- -1----- ----------- ----+

I I

0 ::i: <(

0208



Work Order: 18-06097-Ra228-1 Printed: 7/11/2018 7:35 AM

Page 2 of 3

~ ~

C: ::, a::

{: 0 u .!2 ~ iii C: c:(

1:

5

T"'"

00 N N ca 0::

1/) C: .Q .!!? u Q)

C

s C: Q)

E C: 0 ... ·;; C: w 0 :E <(

Lab I r I Sample I Sample I Sample I Radiometric Grav ·1 Mean ·1 S F [ Sep to [ Sep 11

Fraction Nuc ide Desc Date Aliquot % Rec % Rec % Rec ! A / DatefTime · DatefTime

I I I 01 I RA-228 I LCS I 06/21/18 00:00 1.00E+00 136.851 99.841 109.82 1.00/ 7/9/2018 12:48/ 7/10/2018 12:59

i f ' I

02 I RA-228 MBL I 06121118 00:00 1.ooE+oo . ~;;_~;I 97.151 . . 101.52! 1.001 11912018 12:48[ 111012018 12:59

___ 03 ______ RA-228 DUP 06/20/18_1~:~~-t-~~OE~~Or--~ :9.3~1···· 109.31[ 1.00[ 7/9/201812:48[ 7/10/201812:59

04 RA-228 DO 06/20/18 10:00 1.00E+00 129.791 97.27 106.99[ 1.00[ 7/9/2018 12:481 7/10/2018 12:59

--- ------·-----·"·------ ··-- -- ___ ., ·- -----· ·---·----- --------· ---~ -- -

I ·-1-··-------·1·- --·- ----1 I

.... -------1 .. --------· .. -r __ ....... _____ ... 1 ............. ___ --t· ·------1.. _..,__ ______ _J I

.. -1--- ..... ___ l·-- .... ··--·-t··-- ·--····---··----- .... f·· --i--- ···----··---+-·- ... _......, · ----- -·--f-l

_I ,_ I

----1-.... -• ----- .. ,+--·------....

--+--......... _,____ ............ ·"·i--"----+- ---+---

-~--------------l·-·--·--- ·--·--.. --f-··--.. --,-· ... ... -·-··--·-·--·-··"-J-...

-----+-- ··-+· ...... 1. · ........ ,_ __ .......... · +--..--- ··---·"-1-----· ---; -------- t-------------1

··-- ............. f-· .. ··· .. •-.. •-·--i--f----· .. ---.-t·-----------1-----------I

----t--· ----1--

. - ---• .. --• .. ---+--- ---1--.. •-"

1-----·--t·--···"·-·----·--+----1·-.. --,---·--· .. --.... - •-.. ·--·!--·"

0209

Eberline Analytical


( I I Lab Fraction

01

Nuclide

RA-228

----

02 i:::

RA-228

~ ::i

a: 11 03 --- -. ·----- -·---- ~---·

RA-228

__ 04 RA-228 Q) 00 "0 0 N u .!!1 N i ca Ill 0:: i::: q;

Preliminary Data Report & Analytical Calculations Printed: 7/11/2018 7:35 AM Page 3 of 3

Work Order: 18-06097-Ra228-1

: Sample I Counting Halflife

' Desc OatefTime (days) Detect

LCS 07/10/18 15:01 LB4110A

------·-·-- ·-----------····------

MBL 07/10/18 15:01 LB4110A

i -·· -------- ---------·- --------··-· ----

I DUP 07/10/18 15:01 LB4110A

DO I 07/10/18 15:01 LB4110A

--·--·f---····---·-1-- ------------------------1-----··.

·-----·---. ··--------

. -+-·------- ---1---------- --- --

Carrier Count I Time 1

Counts Bkg CPM

Eff

j

I :: -I . :::i C3 120

C4 120

1---- ----

---)------

856/ 1.21 0.4667

199 i 1 _333333333 0.4578

-+ 30~1 -

1.9 0.4699

17711.416666667[ 0.4692 I -T·-··

i -----··-------1----------1

-~-·"·--- ·-·--·----)--·-- ----,------

+---------r------i--------~--------+---

1-------- --1----- -----···- -----····-----1----------

t: ~ u

II)

C: 0 II)

(.) Q)

C ni -C: Q)

E C: 0 I-

> C: w 0 ~ <{

- ·---+-··---·-·---, --·----------- -------------1----- -- - -· -1-----------~1-----·- -- 1--- ---------!--

---------/--- ·----+---·-·-- +---------- -- 1--·····-- ·-··-·/---

---+-----·-· -· ---+--- --------+-------!

------- ;-------·--1----------- ----------i-------------- .. -+-· --------- ··-+----- ----4---------1----

_. ___________ _

0210


Internal Sample Client

Fraction Desc ID

01 LCS LCS

02 MBL BLANK



18-06097-Ra228-1 (pCi/I) in WA Tracer ID: Ba-Ga

Sample Sample Tracer

Date Aliquot Aliquot(g)

06/21/18 00:00 1.0000 2.2121

06/21/18 00:00 1.0000 2.2067

06/20/18 10:00 1.0000 2.2113

06/20/18 10:00 1.0000 2.2115

Tracer Radiometric ACT(dpm) Tracer (pCi)

1062.5159 655.0000

1059.9221 658.0000

1062.1316 584.0000

1062.2277 621.0000


Radiometric SAF SAF %Rec 1• 2•

136.85 1.00 1.00

137.82 1.00 1.00

122.06 1.00 1.00

129.79 1.00 1.00

0211


LCS & Matrix Spikes

Isotope Sol# Activity Solution dpmlg Date

Ra-228 Ra-12 54.550 7/10/2018

Tracers

fraction Isotope Sol# Activity dpmlg

01 Ba-133 Ba-6a 480.320

02 Ba-133 Ba-6a 480.320

03 Ba-133 Ba-6a 480.320

04 Ba-133 Ba-Sa 480.320

Version 2.0 08/99

Approx Addition

0.370

Solution Date

7/10/2018

7/10/2018

7/10/2018

7/10/2018


Analysis Code Date Technician

Ra228 7/10/2018 12:40 JBAILEY

LCS MS LCSD MSD LCS MS Volume Volume Volume Volume Known Error Added Error

Used(g) Used(g) Used{g) Used(g) pCi Estimate pCi Estimate

0.3745 9.20 0.469 0.00 0.000


Volume Approx Tracer Used (g) Addition

2.2121 2.1100

2.2067 2.1100

2.2113 2.1100

2.2115 2.1100

Page 1 of 1 Printed: 7/10/2018 12:40 PM

Technician Initials Witness Initials

16 LCSD MSD

Known Error Added Error

pCi Estimate pCi Estimate

0.00 0.000 0.00 0.000

LCS

Matrix Spike

0212

Lab

Eberline Analytical



Fraction Client ID

01 LCS

02 BLANK



Comments

Sample

Type LCS

MBL

DUP

DO

Aliquot Worksheet

Analysis Code Rµt Units Lab Deadline

Ra228 liters 7/11/2018


Ratio Post/Pre Noof Dils Oil Factor Ratio Aliquot Net Equiv

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

Technician: =d~ o-Wtj Dare ':I&: a

Technician

JHARVEY

MS Aliquot Data

Aliquot Net Equiv


H-3 Solids Only vvater ruiaoo-~A:ruIst-

(ml) Aliq

0213

Eberline Analytical - Oak Ridge Version 1.1 10/2015 Gravimetric Worksheet

Work Order -

1s-oso91 I 1

Work Order Analysis

Code

Gravimetric Carrier

Ra228 Yttrium

TRetec AMO Environmental Decisions Sample Carrier Data Filter Data

Carrier Added Filter Tare Filter Final

Fraction Client ID Type (ml) (g) (g)

01 LCS LCS 2.0000 0.0859 0.1480

02 BLANK MBL 2.0000 0.0862 0.1470

03 DUP DUP 2.1000 0.0860 0.1509

04 OU-1-007 Outfall 007 DIS DO 2.0000 0.0862 0.1467

/\ I -~' . . '

Technician: , .I ~/1/'

(~ 0

'-'°' l ~ 1

Date: _:z__J _)_£_! -1tL_

Carrier Cone

(mg/ml)

31.1000

Filter Net (g)

0.0621 0.0608 0.0649 0.0605

Printed: 7/10/20182:31 PM Page 1 of 1

Technician

JBAILEY

Gravimetric %

Recovery

99.84 97.75 99.37 97.27

0214

Detector ID Sample ID Alpha Beta Count Time Voltage TOD ~ \'.'-i C1 1806097-01 20 856 120 1410 7/10/2018 3:01:24 PM

\~~ 4

C2 1806097-02 10 199 120 1410 7/10/2018 3:01:25 PM

C3 1806097-03 13 307 120 1410 7/10/2018 3:01 :25 PM

C4 1806097-04 12 177 120 1410 7/10/2018 3:01:25 PM

0215

Eberline Analytical Oak Ridge Labo·atory

Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

! LB4110A - B3

LB4110A - B4

LB4110A - Cl

• LB4110A - C2

• LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

• LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

LB4110A - G4

Alpha/Beta Calibration Date

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

Alpha 11/2/2017

GPC Detector Report (ALL Backgrounds)

Count Date Bkg CPM

7/10/2018 1.33E-01

7/10/2018 5.00E-02

7/10/2018 1.83E-01

7/10/2018 5.00E-02

7/10/2018 1.17E-01

7/10/2018 5.00E-02

7/10/2018 1.67E-02

7/10/2018 6.67E-02

7/10/2018 1.S0E-01

7/10/2018 3.33E-02

7/10/2018 3.33E-02

7/10/2018 5.00E-02

7/10/2018 5.00E-02

7/10/2018 2.00E-01

7/10/2018 2.33E-01

7/10/2018 1.00E-01

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

7/10/2018 6.67E-02

7/10/2018 0.00E+00

7/10/2018 1.00E-01

7/10/2018 3.33E-02

7/10/2018 1.33E-01

7/10/2018 1.S0E-01

7/10/2018 8.33E-02

7/10/2018 3.33E-02

I

PFW LCL

p -4.47E-02

p I -5.83E-02

p -3.30E-02

p -2.93E-02

p -3.93E-02

p -1.32E-02

p -6.0lE-02

p -3.72E-02

p -2.54E-02

p -3.87E-02

p -5.53E-02

p -3.35E-02

p -3.17E-02

p -l.97E-02

p -4.46E-02

p -2.32E-02

p -4.29E-02

p -3.09E-02

p -8.81E-02

p -4.SSE-02

p -3.0lE-02

p -3.30E-02

p -4.14E-02

p -2.38E-02

p -4.87E-02

p -4.75E-02

p -4.94E-02

p -3.17E-02

Mean

8.87E-02

9.57E-02

9.88E-02

8.48E-02

1.l0E-01

1.13E-01

8.0lE-02

7.99E-02

8.68E-02

6.04E-02

6.92E-02

7.86E-02

1.34E-01

1.20E-01

1.04E-01

1.44E-01

1.lOE-01

6.37E-02

9.llE-02

7.04E-02

6.71E-02

4.64E-02

5.42E-02

6.91E-02

5.68E-02

7.47E-02

8.17E-02

7.70E-02

(Q \ Printed: 7/10/2018 6:44 AM --71 "0(63

Page 1 of 1 -r-

UCL

2.22E-01

2.S0E-01

2.30E-01

1.99E-01

2.59E-01

2.40E-01

2.20E-01

l.97E-01

1.99E-01

1.59E-01

1.94E-01

1.91E-01

3.00E-01

2.59E-01

2.52E-01

3.12E-01

2.62E-01

1.58E-01

2.70E-01

1.86E-01

1.64E-01

1.26E-01

1.S0E-01

1.62E-01

1.62E-01

1.97E-01

2.13E-01

1.86E-01

0216

Eberline Analytiec I Oak Ridge Labore tory

Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - 01

_B4110A - 02

_B4110A - 03

_B4110A - 04

LB4110A - El

LB4110A - E2

_B4110A - E3

_B4110A - E4

_B4110A - Fl

_B4110A - F2

_B4110A - F3

_B4110A - F4

!_B4110A - Gl

LB4110A - G2

LB4110A - G3

LB4110A - G4


Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017


Count Date Bkg CPM

7/10/2018 1.S0E+00

7/10/2018 1.48E+00

7/10/2018 1.30E+00

7/10/2018 1.33E+00

7/10/2018 1.48E+00

7/10/2018 1.65E+00

7/10/2018 1.07E+00

7/10/2018 1.45E+00

7/10/2018 1.20E+00 .

7/10/2018 1.33E+00

7/10/2018 1.90E+00 .,

7/10/2018 1.42E+00,

7/10/2018 1.45E+00

7/10/2018 1.72E+00

7/10/2018 1.48E+00

7/10/2018 1.72E+00

3/23/2018 3.33E-02

3/23/2018 1.67E-02

3/23/2018 6.67E-02

3/23/2018 0.00E+00

7/10/2018 1.43E+00

7/10/2018 7.S0E-01

7/10/2018 6.13E+00

7/10/2018 1.12E+00

7/10/2018 1.80E+00

7/10/2018 2.38E+00

7/10/2018 1.77E+00

7/10/2018 1.88E+00

PFW LCL

p 9.02E-01

p 9.79E-01

p 1.04E+00

p 9.48E-01

p 1.08E+00

p 6.16E-01

p 9.0lE-01

p 7.lSE-01

p 8.28E-01

p 7.00E-01

p 9.35E-01

p 7.89E-01

p 8.40E-01

p -4.53E-01

p 8.14E-01

p I 9.28E-01

p 7.66E-01

p 5.45E-01

p 4.98E-01

p 5.67E-01

p 9.21E-01

p 4.87E-01

F -2.lSE-01

p i

6.77E-01

p 8.44E-01

f 1.27E+00

p 9.16E-01

p 6.SSE-01

Mean

1.36E+00

1.S0E+00

1.53E+00

1.40E+00

1.56E+00

1.SlE+00

1.37E+00

1.39E+00

1.25E+00

1.21E+00

1.83E+00

1.22E+00

1.32E+00

1.66E+00

1.27E+00

1.43E+00

1.32E+00

9.58E-01

1.20E+00

1.04E+00

1.39E+00

8.71E-01

1.31E+00

1.16E+00

1.31E+00

1.75E+00

1.43E+00

1.37E+00


UCL

1.82E+00

2.02E+00

2.0lE+00

1.85E+00

2.03E+00

2.41E+00

1.84E+00

2.07E+00

1.67E+00

1.73E+00

2.72E+00

1.65E+00

1.80E+00

3.77E+00

1.73E+00

1.93E+00

1.88E+00

1.37E+00

1.91E+00

1.S0E+00

1.87E+00

1.25E+00

2.84E+00 ,

1.65E+00

1.78E+00

2.23E+00

1.94E+00

2.09E+00

\LQ '1-\\d\ ~

0217

Eberline Analytical Oak Ridge Latoratory

Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - B1

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB411 )A - Gl

LB411)A - G2

LB411JA - G3

LB4110A - G4

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

GPC Detector Report (ALL Efficiencies)

Count Date Eff

7/10/2018 0.2304

7/10/2018 0.2108

7/10/2018 0.2159

7/10/2018 0.2055

7/10/2018 0.2185

7/10/2018 0.1988

7/10/2018 0.2398

7/10/2018 0.2138

7/10/2018 0.2086

7/10/2018 0.2150

7/10/2018 0.2403

7/10/2018 0.2116

7/10/2018 0.2178

7/10/2018 0.2475

7/10/2018 0.2497

7/10/2018 0.1912

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

7/10/2018 0.2180

7/10/2018 0.1825

7/10/2018 0.2406

7/10/2018 0.2091

7/10/2018 0.1993

7/10/2018 0.2018

7/10/2018 0.2216

7/10/2018 0.1980

PFW LCL

p 0.2156

p 0.2006

F 0.1853

F 0.2114

p 0.2028

p 0.1824

I p 0.2169

p 0.2061

I p 0.1961

p -0.1433

p 0.2299

p 0.1993

! p 0.2109

p 0.2355

p 0.2378 . p 0.1824

F 0.1687 I F 0.1518

F 0.1547

F 0.1747

p 0.1478

p 0.1776

p 0.2311

p 0.2020

p 0.1904

p 0.1941

p 0.2154

p 0.1915

,<? Printed: 7/10/2018 6:44 AM ~y§

Page 1 of 1.'1-,\\o{\

Mean UCL

0.2257 0.2357 !

0.2111 0.2215

0.1999 0.2144

0.2267 0.2421

0.2227 0.2425 I

0.2009 0.2194

0.2344 0.2519

0.2215 0.2370

0.2077 0.2194

0.2268 0.5968 I 0.2425 0.2551 I 0.2149 0.2305

0.2219 0.2329

0.2517 0.2679

0.2500 0.2623

0.1955 0.2086 I

0.2258 0.2830

0.2051 0.2584

0.2075 0.2603

0.2355 0.2963

0.2130 0.2782

0.1846 0.1915

0.2382 0.2453

0.2110 0.2200

0.1991 0.2078

0.2025 0.2109

0.2249 0.2345

0.1997 0.2079

0218

Eberline Analy:ical Oak Ridge Laboratory

Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB411JA - C2

LB411JA - C3

LB411JA - C4

LB411JA - D1

LB411JA - D2

LB411JA - D3

LB4110A - D4

LB411JA-El

LB411JA - E2

LB411 )A - E3

LB411 1)A - E4

LB411 )A - Fl

LB411 1)A - F2

LB4110A - F3

LB4111)A - F4

LB4110A - Gl

LB4110A - G2

LB4110A - G3

LB4110A - G4


Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017


Count Date Eff

7/10/2018 0.5450

7/10/2018 0.4636

7/10/2018 0.5365

7/10/2018 0.4867

7/10/2018 0.5324

7/10/2018 0.4951

7/10/2018 0.5872

7/10/2018 0.5289

7/10/2018 0.4767

7/10/2018 0.5179

7/10/2018 0.5931

7/10/2018 0.5184

7/10/2018 0.6478

7/10/2018 0.6343

7/10/2018 0.6415

7/10/2018 0.4983

3/23/2018 0.0436

3/23/2018 0.0428

3/23/2018 0.0551

3/23/2018 0.0569

7/10/2018 0.5352

7/10/2018 0.4595

7/10/2018 0.6095"

7/10/2018 0.5234

7/10/2018 0.4589

7/10/2018 0.4885

7/10/2018 0.5459

7/10/2018 0.4826

PFW

p

p

F

F

p

p

p

p

p

p

p

p

p

p

p

p

F

F

F

f

p

p

p

p

p

p

p

p

Printed: 7/10/2018 6:44 AM t---?@. Page 1 of 11,--\\o(\D

LCL Mean UCL

0.5123 0.5366 0.5608

0.4285 0.4632 0.4980

0.4423 0.4784 0.5144

0.5060 0.5417 0.5774

0.4983 0.5385 0.5786

0.4604 0.4995 0.5385

0.5433 0.5817 0.6201

0.5062 0.5442 0.5822

0.4451 0.4808 0.5165

0.4954 0.5192 0.5431

0.5690 0.5995 0.6300

0.4857 0.5257 0.5658

0.6207 0.6409 0.6610

0.6032 0.6440 0.6848

0.6135 0.6418 0.6701

0.4763 0.5026 0.5289

0.4162 0.5409 0.6655

0.3730 0.4913 0.6097

0.3852 0.4994 0.6137

0.4534 0.5890 0.7247

0.3672 0.5284 0.6896

0.4417 0.4610 0.4802

0.5949 0.6144 0.6339

0.5177 0.5344 0.5510

0.4393 0.4583 0.4773

0.4753 0.4874 0.4996

0.5234 0.5438 0.5642

0.4687 0.4870 0.5053

0219

SECTION XII

BARIUM-133 ANALYTICAL TRACER DATA

0220

7/9/2018 2:14:35PM

~pex-Gamma Analysis Report for 1806097-01

SPIKE

GAMMA SPECTRUM ANALYSIS

Sample Identification

Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure

Operator Detector Name

Geometry Live Time Real Time

Dead Time

Peak Locate Threshold

Peak Locate Range (in channels)

Peak Area Range (in channels)

Identification Energy Tolerance

Energy Calibration Used Done On

Efficiency Calibration Used Done On

Efficiency Calibration Description

Sample Number

: 1806097-01 : SPIKE : RA RECOVERY

: 1.000E+00 units

: Countroom

: 7/9/2018 1:56:33PM

: 7/9/2018 1 :59:23PM

: BAFIL

: Administrator

: GE3 : BAFIL : 900.0 seconds

: 902.2 seconds

: 0.25 %

: 2.50 : 1 - 4096 : 9 - 4096 : 1.000 keV

: 2/17/2018 : 11/9/2014

: 68074

PEAK ANALYSIS REPORT

Peak Analysis Performed on 7/9/2018 2:14:28PM

Peak

No.

Peak Analysis From Channel

Peak Analysis To Channel 4096

Energy (keV)

ROI start

ROI end

Peak Centroid

Net Peak Area

Net Area Uncertainty

Page 1 of6

Continuum Counts

FWHM (keV)

0221

7/9/2018 2:14:35PM Page 2 of6

Analysis Report for 1806097-01

M m M m M

M m

M m

M m

M

m M m M

SPIKE

Peak Energy ROI

No. (keV) start

1 20.23 15 -2 31. 26 15 -3 52.13 44 -4 62.28 44 -5 81.13 75 -6 112.71 104 -7 141.18 132 -8 159.32 154 -9 276.48 267 -

10 285.82 267 -11 303.55 294 -12 333.77 328 -13 337.94 328 -14 355.96 349 -15 366.92 362 -16 386.36 374 -17 391.80 374 -18 416.55 407 -19 436.82 432 -20 455.90 451 -21 468.01 4 60 -22 511.07 504 -

M = First peak in a multiplet region

m = Other peak in a multiplet region

F = Fitted singlet

Errors quoted at 2.000sigma

ROI Peak Net Peak Net Area Continuum

end Centroid Area Uncertainty Counts

40 20.67 2.88E+02 53.00 3.84E+02

40 31.70 7.85E+03 138.07 5.46E+02

69 52.55 4.24E+0l 73.03 6.24E+02

69 62.70 7.44E+02 79 .11 8.74E+02

97 81.53 1.52E+03 75.13 1.89E+02

119 113.09 3.77E+02 72. 35 5 .11E+02

152 141.54 1.00E+02 71.15 5.18E+02

166 159.67 5.18E+0l 45.78 2. 96E+02

288 276.76 1.77E+02 49.99 1.83E+02

288 286.09 2.43E+0l 16.45 4.09E+0l

311 303.81 1.80E+02 55.68 2.18E+02

342 334.01 1.21E+02 33.17 6.69E+0l

342 338.17 3.llE+0l 27.40 4.67E+0l

362 356.19 6.70E+02 58.09 7.72E+0l

374 367.14 2.24E+0l 24.17 5.72E+0l

395 386.56 6.18E+02 55.24 9.78E+0l

395 392.00 1.89E+0l 28.00 2.69E+0l

428 416.73 1.10E+02 36.03 6.60E+0l

442 437.00 l.25E+02 25.03 1.78E+0l

459 456.06 9.00E+00 10.99 1.20E+0l

475 468.17 5.12E+0l 16.85 7.69E+00

516 511.20 2.32E+0l 12.09 5.65E+00

BACKGROUND SUBTRACT REPORT

Peak Analysis Performed on

Env. Background File

Peak Energy

No. (keV)

1 20.23 2 31.26 3 52.13 4 62.28 5 81.13 6 112. 71 7 141.18

: 7/9/2018 2:14:28PM

: \\OR-GAMMA 1\ApexRoot\Countroom\Data\0000066391.CNF

Original Orig. Area Ambient Backgr. Subtracted

Area Uncertainty Background Uncert. Area

2.88E+02 53.00 7.20E+0l 4.82E-01 2.16E+02

7.85E+03 138.07 7.85E+03

4.24E+0l 73.03 4.24E+0l

7.44E+02 79.11 7.44E+02

1.52E+03 75.13 1.52E+03

3.77E+02 72.35 2.15E+0l 5.28E-01 3.56E+02

1.00E+02 71.15 1.00E+02

FWHM (keV)

4.25 6.57 8.86 6.27 2.37 2.17 4. 96 2.95 8.38 3.73 1. 65 5.23 4.84 1. 87 1. 39 5.30 5.27 4.30 1. 99 1. 47 1. 75 1. 60

Subtracted Uncert.

5.30E+0l 1.38E+02 7.30E+0l 7.91E+0l 7. 51E+0l 7.23E+0l 7. llE+0l

0222

7/9/2018 2:14:35PM Page 3 of 6


SPIKE

Peak Energy Original Orig. Area Ambient Backgr. Subtracted Subtracted

No. (keV) Area Uncertainty Background Uncert. Area Uncert.

8 159.32 5.18E+0l 45.78 5.18E+0l 4.58E+0l

M 9 276.48 1.77E+02 49.99 1.77E+02 5.00E+0l

m 10 285.82 2.43E+0l 16.45 2.43E+0l 1.65E+0l

11 303.55 1.80E+02 55.68 1.80E+02 5.57E+0l

M 12 333.77 1.21E+02 33.17 1.21E+02 3.32E+0l

m 13 337.94 3.llE+0l 27.40 3.llE+0l 2.74E+0l

14 355. 96 6.70E+02 58.09 6.70E+02 5.81E+0l

15 366.92 2.24E+0l 24.17 2.24E+0l 2.42E+01

M 16 386.36 6.18E+02 55.24 6.18E+02 5.52E+01

m 17 391.80 1.89E+0l 28.00 1.89E+0l 2.80E+0l

18 416.55 l.10E+02 36.03 1.10E+02 3.60E+0l

19 436.82 l.25E+02 25.03 1.25E+02 2.50E+0l

20 455.90 9.00E+00 10.99 9.00E+00 1.l0E+0l

21 468.01 5.12E+0l 16.85 5.12E+0l 1.69E+0l

22 511.07 2.32E+0l 12.09 1.39E+0l 1.31E+00 9.23E+00 1.22E+0l



F = Fitted singlet Errors quoted at 2.000sigma

NUCLIDE IDENTIFICATION REPORT

Nuclide Library Used : \\OR-GAMMA1\ApexRoot\Countroom\Library\WSRC.NLB

IDENTIFIED NUCLIDES

Nuclide Id Energy Yield(%) Activity Activity

Name Confidence (keV) (pCi/units) Uncertainty

SN-113 0. 96 255.12 1. 93 391.69 * 61.90 1.44E+0l 2.14E+0l

BA-133 0.97 30.80 * 97.60 6.73E+00 l.18E-01

302.84 * 17.80 7.84E+02 3.69E+02

356.01 * 60.00 6.55E+02 8.76E+0l

0223


SPIKE

* = Energy line found in the spectrum.

- = Manually added nuclide.

? = Manually edited nuclide.

@ = Energy line not used for Weighted Mean Activity

Energy Tolerance : 1.000 keV

Nuclide confidence index threshold = 0.30


7/9/2018 2:14:35PM

INTERFERENCE CORRECTED REPORT

? = X =

Nuclide Name

SN-113 BA-133

Nuclide Id

Confidence

0. 964 0.973

nuclide is part of an undetermined solution

nuclide rejected by the interference analysis

Wt mean Activity

(pCi/units)

1.44E+Ol 6.73E+OO

@ = nuclide contains energy lines not used in Weighted Mean Activity


Wt mean Activity

Uncertainty

2.14E+Ol 1.18E-01

Page 4 of 6

Comments

0224


M

M

m M

M

m M

m

M

SPIKE

Peak Locate Performed on

Peak Locate From Channel

Peak Locate To Channel

Peak No. Energy (keV)

1 20.23

3 52 .13

4 62.28

5 81.13

6 112. 71

7 141.18

8 159.32

9 276.48

10 285.82

12 333.77

13 337.94

15 366.92

16 386.36

18 416.55

19 436.82

20 455.90

21 468.01

22 511.07



F = Fitted singlet


7/9/2018 2:14:35PM

UNIDENTIFIED PEAKS

: 7/9/2018 2:14:28PM

: 1 : 4096

Peak Size (CPS)

2.40231E-01

4. 71317E-02

8.26408E-01

1.68641E+00

3.95497E-01

1. lllllE-01

5.75278E-02

1. 96732E-01

2. 69646E-02

1.34854E-0l

3.45494E-02

2.48911E-02

6.86279E-0l

l.22222E-01

1.39026E-01

1.00000E-02

5.68384E-02 ,

1.02514E-02

Peak CPS(%) Uncertainty

12.26

86.08

5.32 2.48

10.16

35.57

44.21

14.12

33.90

13. 66

44.06

53.95

4.47

16.38

10.00

61.05

16.47

65.92

NUCLIDE MDA REPORT

Peak Type

Sum

Sum


Page 5 of6

Tolerance Nuclide

0225

7/9/2018 2:14:35PM Page 6 of 6


SPIKE

Nuclide Energy Yield(%) Line MDA Nuclide MDA Activity Dec. Level

Name (keV) (pCi/units) (pCilunits) (pCi/units) (pCilunits)

FE-55 5.89 24.50 4.06E-09 4.06E-09 -9.89E-11 1.95E-09

CO-57 122.06 85.51 8.08E+0l 8.08E+01 -l.17E+02 3.95E+0l

136.48 10.60 6.19E+02 2.llE+0l 3.00E+02

NI-59 6.92 29.80 3.18E-08 3.18E-08 -7.38E-10 1.53E-08

MO-93 16.59 52.90 7.53E-04 7.53E-04 -1.llE-05 3.68E-04

18.60 10.00 1.53E-02 2.34E-03 7.49E-03

NB-93M 16.57 9.43 4.18E-03 4.18E-03 -6.16E-05 2.04E-03

CD-109 88.03 3. 72 1.16E+03 1.16E+03 7.43E+03 5.70E+02

+ SN-113 255.12 1. 93 2.60E+03 5.26E+0l -2.25E+03 1.24E+03

391.69 * 61.90 5.26E+0l 1.44E+0l 2.53E+0l

SN-119M 23.87 16.10 1.74E-01 1.74E-01 -l.61E-02 8.63E-02

25.10 22.70 1.98E-01 2.47E+00 9.82E-02

I-125 35.49 6.49 9.54E+00 9.54E+00 -2.82E+00 4. 72E+00

I-129 29.78 57.00 3.08E-01 3.08E-01 3.84E+00 1.53E-01

33.60 13.20 3.19E+00 -9.41E-01 1.58E+00

39.58 7.52 1.70E+0l -5.08E+00 8.43E+00

+ BA-133 30.80 * 97.60 1.28E-01 1.28E-01 6.73E+00 6.31E-02

302.84 * 17.80 3.61E+02 7.84E+02 1.75E+02

356.01 * 60.00 4.49E+0l 6.55E+02 2.llE+0l

CE-139 165.85 80.35 9.19E+0l 9.19E+0l -2.26E+00 4.44E+0l

CE-144 133.54 10.80 5.72E+02 5. 72E+02 7.30E+0l 2.77E+02

HG-203 279.19 77.30 7.62E+0l 7.62E+0l 7.66E+0l 3.66E+0l

PB-210 46.50 4.25 3.79E+0l 3.79E+01 -2.45E+0l 1.86E+0l

PA-231 9.28 42.00 1.16E-06 l.16E-06 -2.24E-08 5.62E-07

10 .11 20.20 7.52E-06 -1.31E-07 3.66E-06

283.67 1. 60 3.59E+03 -1.12E+0l 1.73E+03

302.67 2.30 2. 72E+03 6.36E+03 1.32E+03

TH-231 25.64 14.70 3.65E-01 3.65E-01 4.54E+00 1.81E-01

84.21 6.40 5.78E+02 3.63E+03 2.85E+02

PA-234M 9.89 89.00 1.18E-06 l.18E-06 -2.28E-08 5.73E-07

21.72 64.90 1.84E-02 -3.63E-05 9.13E-03

37.93 23.75 4.09E+00 -1.21E+00 2.03E+00

131.42 20.40 2.83E+02 -1.71E+02 1.37E+02

TH-234 63.29 3.80 2.34E+02 2.34E+02 -5.10E+02 1.15E+02

NP-237 29.37 14.00 1.13E+00 1.13E+00 1.41E+0l 5.59E-01

86.50 12.60 3.22E+02 2.04E+03 1.59E+02

U-237 97.08 16.30 1.78E+02 1.31E+02 -1.28E+0l 8.63E+0l

101.07 26.30 1.31E+02 -8.92E+00 6.39E+0l

114.00 12.30 4.99E+02 -2.79E+02 2.44E+02

208.01 22.00 3.48E+02 -1.53E+02 1.68E+02

AM-241 59.54 35.90 1.86E+0l 1.86E+0l 8.0lE+0l 9. llE+00

AM-243 74.67 66.00 3.72E+0l 3.72E+0l -6.05E+0l 1.84E+0l

+ = Nuclide identified during the nuclide identification

* = Energy line found in the spectrum

> = MDA value not calculated

@ = Half-life too short to be able to perform the decay correction

0226

105

104

= = ..... ' <(

~ lQ3__J rd u V)

O'l 0

,--I

V)

+-' C :::s 0 u

102

101

100

= = ..... ' ~

500 1000

-ROI Type: 1

1500

0000068074.CNF

2000 channel

2500

Live Time :900.000 sec Real Time :902.240 sec Start: 1: O.S(kev) stop : 4096:4097.3(kev) Acq. start :Mon Jul 09 13:59:23 2018

3000

-ROI Type: 2

3500 4000

0227

7/9/2018 2:31:02PM

pex-Gamma Analysis Report for 1806097-02

BLANK



Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure Operator Detector Name

Geometry Live Time Real Time

Dead Time








Sample Number

: 1806097-02 : BLANK : RA RECOVERY

: 1.000E+00 units

: Countroom

: 7/9/2018 1 :56:42PM

: 7/9/2018 2:15:51PM

: BAFIL : Administrator

: GE3 : BAFIL : 900.0 seconds

: 902.3 seconds

: 0.26 %

: 2.50

: 1 - 4096 : 9 - 4096 : 1.000 keV

: 2/17/2018

: 11/9/2014

: 68077

PEAK ANAL YS/S REPORT

Peak Analysis Performed on 7/9/2018 2:30:56PM

Peak No.


Peak Analysis To Channel

Energy (keV)

ROI start

ROI end

: 1 : 4096

Peak Centroid

Net Peak Area


Page I of6

Continuum Counts

FWHM (keV)

0228

7/9/2018 2:31:02PM Page 2 of6


M m M m m m

M m

M m

M m

m

m

M

m

BLANK

Peak Energy ROI

No. (keV) start

1 20.19 15 -2 31. 2 9 15 -3 54.08 4 6 -4 61.86 46 -5 66.36 4 6 -6 81.15 46 -7 112.67 102 -8 276.57 271 -9 286.38 271 -

10 304.68 297 -11 334.76 328 -12 356.20 34 7 -13 386.49 378 -14 417.01 406 -15 436.98 433 -16 445.31 443 -17 468.54 4 62 -18 509.57 503 -19 567.65 562 -




ROI Peak Net Peak Net Area Continuum

end Centroid Area Uncertainty Counts

40 20.63 2.07E+02 54.22 4.SSE+02

40 31.73 7.74E+03 138.58 6. 21E+02

88 54.50 2.04E+02 65.86 4.74E+02

88 62.27 3.97E+02 50.32 2.12E+02

88 66.77 2.18E+02 47.24 2.1SE+02

88 81. 55 1.46E+03 75.55 2.26E+02

120 113. OS 3.23E+02 83.38 6.85E+02

290 276.84 6.66E+Ol 37.52 l.36E+02

290 286.64 1.96E+Ol 25.16 6.17E+Ol

322 304.94 2.01E+02 70. 27 2.08E+02

345 335.00 1.60E+02 44.01 l.21E+02

367 356.42 6.7SE+02 66.37 1.35E+02

396 386.69 4.86E+02 57.84 l.14E+02

428 417.20 1.0SE+02 38.75 7.87E+Ol

443 437.16 l.37E+02 26.70 2.20E+Ol

449 445.48 6.23E+OO 8.99 9.SSE+OO

474 468.69 4.27E+Ol 15.04 6.54E+OO

514 509.70 1.99E+Ol 11. 31 6.26E+OO

573 567.75 1.20E+Ol 6.93 O.OOE+OO




Peak Energy

No. (keV)

1 20.19 2 31.29 3 54.08 4 61.86 5 66.36 6 81.15 7 112. 67 8 276.57 9 286.38

10 304.68

: 7/9/2018 2:30:56PM

: \\OR-GAMMA 1\ApexRoot\Countroom\Data\0000066391.CNF



2.07E+02 54.22 7.20E+Ol 4.82E-01 1.3SE+02

7.74E+03 138.58 7.74E+03

2.04E+02 65.86 2.04E+02

3.97E+02 50.32 3.97E+02

2.18E+02 47.24 2.18E+02

1.46E+03 75.55 1.46E+03

3.23E+02 83.38 2.lSE+Ol S.28E-01 3.01E+02

6.66E+Ol 37.52 6.66E+Ol

1. 96E+Ol 25.16 1.96E+Ol

2.01E+02 70.27 2.01E+02

FWHM (keV)

4. 27 6.57 8.70 2.43 2.41 2.37 2 .11 4.69 4.44 2.02 1. 49 1. 95 4.10 4.38 2.48 2 .11 2 .13 2.51 6,74

Subtracted Uncert.

S.42E+Ol l.39E+02 6.59E+Ol 5.03E+Ol 4. 72E+01 7.SSE+Ol 8.34E+Ol 3.75E+Ol 2.52E+Ol 7.03E+Ol

0229

7/9/2018 2:31:02PM Page 3 of6


BLANK

Peak Energy Original

No. (keV) Area

11 334.76 1.60E+02 12 356.20 6.75E+02 13 386.49 4.86E+02 14 417.01 l.05E+02 15 436.98 1.37E+02 16 445.31 6.23E+00 17 468.54 4.27E+0l 18 509.57 1.99E+0l 19 567.65 1.20E+0l




Orig. Area Uncertainty

44.01 66.37 57.84 38.75 26.70

8.99 15.04 11. 31

6.93

Ambient Background

Backgr. Subtracted Uncert. Area

1.60E+02 6.75E+02 4.86E+02 1.05E+02 1.37E+02 6.23E+00 4.27E+0l 1.99E+0l 1.20E+0l



IDENTIFIED NUCLIDES

Nuclide Id Energy

Name Confidence (keV)

BA-133 0. 96 30.80 302.84 356.01

• = Energy line found in the spectrum.



*

*





Yield(%)

97.60 17.80 60.00

Activity

(pCi/units)

6.68E+00

6.58E+02

Activity

Uncertainty

1. 20E-01

9.31E+01

Subtracted Uncert.

4.40E+0l 6.64E+01 5.78E+0l 3.88E+0l 2.67E+0l 8.99E+00 1.50E+0l 1.13E+0l 6.93E+00

0230

7/9/2018 2:31:02PM


BLANK


? = X = @ =

Nuclide Name

BA-133

Nuclide Id

Confidence

0.968



Wt mean Activity

(pCi/units)

6.68E+OO

nuclide contains energy lines not used in Weighted Mean Activity


Wt mean Activity

Uncertainty

1.20E-01

Page 4 of 6

Comments

0231


M

M

m

m

m

M

m

BLANK





1 20.19

3 54.08

4 61.86

5 66.36

6 81.15

7 112. 67

8 276.57

9 286.38

10 304.68

11 334.76

13 386.49

14 417.01

15 436.98

16 445.31

17 468.54

18 509.57

19 567.65




7/9/2018 2:31 :02PM

UNIDENTIFIED PEAKS

: 7/9/2018 2:30:56PM

: 1 : 4096

Peak Size (CPS)

1.50472E-01

2.27214E-01

4.41649E-01

2.41795E-01

1. 6212 lE+00

3.34525E-01

7.40426E-02

2.17270E-02

2.23308E-01

1.78195E-01

5.40040E-01

1.16296E-01

1.52222E-01

6.91919E-03

4.74758E-02

2.20773E-02

1.33333E-02


20.02

16.10 6.33

10.85 2.59

13. 85

28.15 64.35

17.48

13. 72 5.95

18.51 9.75

72 .15 17.60

28.47

28.87

NUCLIDE MDA REPORT

Peak Type

Sum


Page 5 of6

Tolerance Nuclide

0232

7/9/2018 2:31:02PM Page 6 of6


BLANK


Name (keV) (pCi/units) (pCilunits) (pCi/units) (pCi/units)

FE-55 5.89 24.50 4.00E-09 4.00E-09 -8. 98E-11 1.93E-09

CO-57 122.06 85.51 7.92E+0l 7.92E+0l -5.28E+0l 3.87E+0l

136.48 10.60 5. 96E+02 2.74E+02 2.89E+02

NI-59 6.92 29.80 3.13E-08 3.13E-08 -6.70E-10 1.51E-08

MO-93 16.59 52.90 7.42E-04 7.42E-04 -1.0lE-05 3.62E-04

18.60 10.00 1.48E-02 1.58E-03 7.28E-03

NB-93M 16.57 9.43 4.llE-03 4. llE-03 -5.59E-05 2.0lE-03

CD-109 88.03 3. 72 l.16E+03 l.16E+03 -2.62E+03 5.69E+02

SN-113 255.12 1. 93 2.89E+03 8.03E+0l 8.20E+02 1.38E+03

391.69 61.90 8.03E+0l -5.45E+00 3.91E+0l

SN-119M 23.87 16.10 1.73E-01 1.73E-01 -9.93E-03 8.56E-02

25.10 22.70 1.96E-01 2.43E+00 9.72E-02

I-125 35.49 6.49 9.44E+00 9.44E+00 -6.93E+00 4.68E+00

I-129 29.78 57.00 3.05E-01 3.05E-01 3.70E+00 1.51E-01

33.60 13.20 3.16E+00 -2.31E+00 1.57E+00

39.58 7.52 l.69E+0l -1.25E+0l 8.37E+00

+ BA-133 30.80 * 97.60 1.38E-01 1.38E-01 6.68E+00 6.78E-02

302.84 17.80 3.58E+02 -1.36E+0l 1.73E+02

356.01 * 60.00 6.88E+0l 6.58E+02 3.31E+0l

CE-139 165.85 80.35 9.46E+0l 9.46E+0l 1.57E+0l 4.58E+0l

CE-144 133.54 10.80 5.44E+02 5.44E+02 -5.34E+0l 2.64E+02

HG-203 279.19 77. 30 7.80E+0l 7.80E+0l 1.31E+02 3.75E+0l

PB-210 46.50 4.25 3.83E+0l 3.83E+0l -6.02E+0l 1.88E+0l

PA-231 9.28 42.00 1.15E-06 1.15E-06 -2.03E-08 5.58E-07

10 .11 20.20 7.36E-06 -l.19E-07 3.58E-06

283.67 1. 60 3.64E+03 -3.78E+0l 1.75E+03

302.67 2.30 2.77E+03 -1.05E+02 1.34E+03

TH-231 25.64 14.70 3.61E-01 3.61E-01 4.47E+00 1.79E-01

84.21 6.40 5.73E+02 -8.95E+02 2.82E+02

PA-234M 9.89 89.00 1.17E-06 1.17E-06 -2.07E-08 5.68E-07

21.72 64.90 1.81E-02 -2.68E-04 8.97E-03

37.93 23.75 4.05E+00 -2.98E+00 2.00E+00

131.42 20.40 2.75E+02 -5.26E+02 1.33E+02

TH-234 63.29 3.80 2.38E+02 2.38E+02 -4.75E+02 1.17E+02

NP-237 29. 37 14.00 1.12E+00 1.12E+00 1.35E+0l 5.53E-01

86.50 12.60 3.20E+02 -6.51E+02 1.58E+02

U-237 97.08 16.30 1.78E+02 1.32E+02 -1.06E+03 8.66E+0l

101.07 26.30 1.32E+02 2.56E+0l 6.40E+0l

114.00 12.30 4.94E+02 -7.81E+0l 2.42E+02

208.01 22.00 3.50E+02 5.70E-01 1.69E+02

AM-241 59.54 35.90 1.90E+0l 1.90E+0l 8.04E+0l 9.33E+00

AM-243 74.67 66.00 3.77E+0l 3.77E+0l 1.39E+02 1.86E+01





0233

lQS

lQ4

= = 7 <(

~ lQLLl ro u Vl

O'l 0 .-

1 Vl +-' C: :::l 0 u

102

101

100

...... ' ;;!;

500 1000

-ROI Type: 1

1500

0000068077 .CNF

2000 channel

2500

Live Time :900.000 sec Real Time :902.330 sec Start: 1: 0.S(keV) Stop : 4096:4097.3(kev) Acq. Start :Mon Jul 09 14:15:51 2018

3000

-ROI Type: 2

3500 4000

0234

7/9/2018 2:15:16PM


OU-1-007 OUTFALL 007 DIS

GAMMA SPECTRUM ANAL YS/S


Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure

Operator Detector Name

Geometry Live Time

Real Time

Dead Time








Sample Number

: 1806097-03 : OU-1-007 OUTFALL 007 DIS

: RA RECOVERY

: 1.000E+00 units

: Countroom

: 7/9/2018 1:57:01PM

: 7/9/2018 1:59:31PM

: BAFIL : Administrator

: GE4 : BAFIL

: 900.0 seconds

: 936.7 seconds

: 3.91 %

: 2.50 : 1 - 4096 : 15 - 4096

: 1.000 keV

: 2/24/2018

: 11/9/2014

: 68075

PEAK ANALYSIS REPORT

Peak Analysis Performed on : 7/9/2018 2:15:10PM

Peak No.



Energy (keV)

ROI start

ROI end

: 1 : 4096

Peak Centroid

Net Peak Area


Page 1 of6

Continuum Counts

FWHM (keV)

0235

7/9/2018 2:15:16PM Page 2 of6


M m

M m M

m m

M

m m

M

m


Peak Energy ROI

No. (keV) start

1 30.94 24 -2 35.28 24 -3 52.66 4 7 -4 61.64 57 -5 66.64 64 -6 81.17 75 -7 112. 57 106 -8 122.80 120 -9 142.29 138 -

10 149.40 14 6 -11 276.45 272 -12 302.95 297 -13 306.95 297 -14 330.70 329 -15 333.81 329 -16 337.70 32 9 -17 356.12 34 9 -18 384.41 380 -19 387.04 380 -20 390.66 380 -21 430.04 427 -22 436.85 432 -23 468.36 4 64 -24 509.54 504 -




ROI end

39 39 56 64 69 86

118 124 145 151 279 311 311 341 341 341 360 397 397 397 432 439 472 512

Peak Net Peak Net Area Continuum

Centroid Area Uncertainty Counts

30.00 2.06E+03 98.61 2.17E+02

34.34 4.92E+02 72.99 1.62E+02

51.74 5.05E+0l 48.04 3.03E+02

60.73 1.04E+02 58.92 5.11E+02

65.73 7.59E+0l 41. 40 2.64E+02

80.27 8.78E+02 77.69 3.08E+02

111.69 2.19E+02 65.06 3.91E+02

121.93 1.92E+0l 21.08 7.76E+0l

141.44 3.33E+0l 28.77 1.15E+02

148.56 l.85E+0l 23.94 1.01E+02

275.70 5.88E+0l 24.41 6.04E+0l

302.23 1.18E+02 27.20 4.94E+0l

306.23 1.95E+0l 21.52 3.70E+0l

330.00 1.25E+0l 8.43 9.89E+00

333.11 5.88E+0l 23.07 4.06E+0l

337.00 2.48E+0l 20.37 5.47E+0l

355.44 3. 72E+02 46.52 8.53E+0l

383.75 7.92E+0l 27. 47 5.06E+0l

386.39 9.20E+0l 28.97 3.l0E+0l

390.01 2.51E+0l 32.75 3.80E+0l

429.42 6.60E+00 7.62 6.80E+00

436.24 6.00E+0l 16.97 8.00E+00

467.78 1.64E+0l 10.98 7.20E+00

508.99 1.0lE+0l 9.82 7.86E+00



Env. Background File : \\0 R-GAMMA 1 \ApexRoot\Countroom\Data\0000066684 .CNF

Peak Energy Original Orig. Area Ambient Backgr. Subtracted

No. (keV) Area Uncertainty Background Uncert. Area

1 30.94 2.06E+03 98.61 2.06E+03

2 35.28 4.92E+02 72.99 4.92E+02

3 52.66 5.05E+0l 48.04 5.05E+0l

4 61.64 1.04E+02 58.92 1.04E+02

5 66.64 7.59E+0l 41.40 7.59E+0l

FWHM (keV)

2.29 2.40 1. 96 1. 7 2 1. 97 2.34 2.20 2.62 2. 96 1. 62 1. 50 2.53 2.28 2.32 2.55 2.32 2.09 2.98 1. 98 3.79 1. 76 2.08 5.01 1. 62

Subtracted Uncert.

9.86E+0l 7.30E+0l 4.80E+0l 5.89E+0l 4.14E+0l

0236

7/9/2018 2:15:16PM Page 3 of 6





6 81.17 8.78E+02 77.69 8.78E+02 7.77E+0l

7 112.57 2.19E+02 65.06 2.19E+02 6.51E+0l

8 122.80 1.92E+0l 21.08 1.92E+0l 2. llE+0l

9 142.29 3.33E+0l 28.77 3.33E+0l 2.88E+0l

10 149.40 1.85E+0l 23.94 0.00E+00 0.00E+00 1.85E+0l 2.39E+0l

11 276.45 5.88E+0l 24.41 5.88E+0l 2.44E+0l

M 12 302.95 1.18E+02 27.20 1.18E+02 2. 72E+0l

m 13 306.95 1.95E+0l 21.52 1.95E+0l 2.15E+0l

M 14 330.70 1.25E+0l 8.43 1.25E+0l 8.43E+00

m 15 333.81 5.88E+0l 23.07 5.88E+0l 2.31E+0l

m 16 337.70 2.48E+0l 20.37 2.48E+0l 2.04E+0l

17 356.12 3. 72E+02 46.52 3.72E+02 4.65E+0l

M 18 384.41 7.92E+0l 27.47 7.92E+0l 2.75E+0l

m 19 387.04 9.20E+0l 28.97 9.20E+0l 2.90E+0l

m 20 390.66 2.51E+0l 32.75 2.51E+0l 3.28E+0l

21 430.04 6.60E+00 7. 62 6.60E+00 7.62E+00

22 436.85 6.00E+0l 16.97 6.00E+0l 1.70E+0l

23 468.36 1.64E+0l 10.98 1.64E+0l 1.l0E+0l

24 509.54 1.0lE+0l 9.82 1.0lE+0l 9.82E+00




NUCLIDE /DENTJFICAT/ON REPORT


IDENTIFIED NUCLIDES



CO-57 0.75 122.06 * 85.51 9.39E+00 1.04E+0l

136.48 10.60

I-125 0.99 35.49 * 6.49 4.39E+02 6.61E+0l

BA-133 0.99 30.80 * 97.60 9.30E+0l 4.80E+00

302.84 * 17.80 5.83E+02 2.24E+02

356.01 * 60.00 5.84E+02 l.06E+02

PA-231 0.99 9.28 42.00 10 .11 20.20

283.67 1.60 302.67 * 2.30 4.52E+03 1.74E+03

0237










7/9/2018 2:15:16PM


? = X =

Nuclide Name

CO-57 I-125 BA-133 PA-231

Nuclide Id

Confidence

0.758 0.993 0.997 0.997



Wt mean Activity

(pCi/units)

9.39E+00 4.39E+02 9.41E+0l 3.79E+03



Wt mean Activity

Uncertainty

l.04E+0l 6.61E+0l 4.79E+00 l.74E+03

Page 4 of6

Comments

0238

7/9/2018 2:15:16PM


m M

m m M

m m






3 52.66

4 61.64

5 66.64

6 81.17

7 112. 57

9 142.29

10 149.40

11 276.45

13 306.95

14 330.70

15 333.81

16 337.70

18 384.41

19 387.04

20 390.66

21 430.04

22 436.85

23 468.36

24 509.54



F = Fitted singlet


UNIDENTIFIED PEAKS

: 7/9/2018 2:15:10PM

: 1 : 4096

Peak Size (CPS)

5.60616E-02

1.15995E-01

8.42842E-02

9.75564E-01

2.42841E-01

3.70086E-02

2.05395E-02

6.53308E-02

2 .1 7021E-02

1.39126E-02

6. 53501E-02

2.75285E-02

8.79544E-02

1.02252E-01

2. 79411E-02

7.33333E-03

6.66667E-02

1.82222E-02

1. 11905E-02

Peak CPS(%)

Uncertainty

47.61 28.22 27.29

4.42 14.88 43.20 64.75 20.76 55.08 33.65 19.61 41.11 17.35 15.74 65.12 57.70 14.14 33.47 48.77

NUCLIDE MDA REPORT


Peak Type

Sum Sum

Sum

Sum

Sum

Sum

Page 5 of6

Tolerance Nuclide

0239

7/9/2018 2:15:16PM Page 6 of6



Nuclide Energy Yield(%) Line MDA NuclideMDA Activity Dec. Level

Name (keV) (pCi/units) (pCi/units) (pCilunits) (pCilunits)

FE-55 5.89 24.50 5.43E-03 5.43E-03 0.00E+00 0.00E+00

+ CO-57 122.06 * 85.51 1.67E+0l 1.67E+0l 9.39E+00 7.71E+00

136.48 10.60 1.99E+02 6.87E+0l 9.34E+0l

NI-59 6.92 29.80 7.53E-03 7.53E-03 0.00E+00 0.00E+00

MO-93 16.59 52.90 1.04E+00 1.04E+00 2.81E-0l 4.92E-01

18.60 10.00 9.70E+00 2.15E+0l 4.66E+00

NB-93M 16.57 9.43 5.79E+00 5.79E+00 1.57E+00 2.75E+00

CD-109 88.03 3. 72 3.24E+02 3.24E+02 -1. 22E+02 1.52E+02

SN-113 255.12 1. 93 1. 2 9E+03 7.17E+0l 4.26E+02 5.92E+02

391.69 61.90 7.17E+0l 1.56E+0l 3.37E+0l

SN-ll 9M 23.87 16.10 1.02E+0l 7.78E+00 7.69E+00 4.91E+00

25.10 22.70 7.78E+00 2.00E-01 3.72E+00

+ I-125 35.49 * 6.49 9.79E+0l 9.79E+0l 4.39E+02 4.77E+0l

I-129 29.78 57.00 1.56E+0l 1.56E+0l 1.18E+02 7. 72E+00

33.60 13.20 8.42E+0l 5.89E+02 4.16E+0l

39.58 7.52 5.42E+0l -1.02E+0l 2.58E+0l

+ BA-133 30.80 * 97.60 5.02E+00 5.02E+00 9.30E+0l 2.45E+00

302.84 * 17.80 2.39E+02 5.83E+02 1.13E+02

356.01 * 60.00 7.13E+0l 5.84E+02 3.35E+0l

CE-139 165.85 80.35 3.29E+0l 3.29E+0l -4.05E+00 1.55E+0l

CE-144 133.54 10.80 1.95E+02 1.95E+02 l.17E+02 9.17E+0l

HG-203 279.19 77. 30 4.79E+0l 4.79E+0l -1.09E+00 2.25E+0l

PB-210 46.50 4.25 1.08E+02 1.08E+02 -7.61E+00 5.l0E+0l

+ PA-231 9.28 42.00 1.32E-02 1.32E-02 0.00E+00 0.00E+00

10 .11 20.20 3.53E-02 0.00E+00 0.00E+00

283.67 1. 60 1.60E+03 6.07E+02 7.29E+02

302.67 * 2.30 1.85E+03 4.52E+03 8.72E+02

TH-231 25.64 14.70 1.49E+0l 1.49E+0l -2.56E+00 7.19E+00

84.21 6.40 5.34E+02 2.45E+03 2.61E+02

PA-234M 9.89 89.00 7.52E-03 7.52E-03 0.00E+00 0.00E+00

21. 72 64.90 2.24E+00 3.39E+00 1.08E+00

37.93 23. 7 5 2.94E+0l 8.80E+0l l.43E+0l

131.42 20.40 9.80E+0l 4.48E+00 4.60E+0l

TH-234 63.29 3.80 4.18E+02 4.18E+02 8.18E+02 2.03E+02

NP-237 29.37 14.00 6.05E+0l 6.05E+0l 4.93E+02 2.99E+0l

86.50 12.60 9.92E+0l 8.52E+00 4.67E+0l

U-237 97.08 16.30 9.06E+0l 6.36E+0l -4.62E+0l 4. 27E+0l

101.07 26.30 6.36E+0l 2.14E+0l 3.0lE+0l

114.00 12.30 2.63E+02 6.13E+02 1.28E+02

208.01 22.00 1.24E+02 -1.56E+0l 5.76E+0l

AM-241 59.54 35.90 3.60E+0l 3.60E+0l 6.49E+0l 1.74E+0l

AM-243 74.67 66.00 1.63E+0l 1.63E+0l -3.26E-01 7.72E+00





0240

105

104

~ 103 ro u V)

O"> 0 ,

I V)

+-' C: :::s 0 u

102

0000068075.CNF Live Time :900.000 sec Real Time :936.660 sec Start: 1: 2. O(kev) Stop : 4096:4091.G(kev) Acq. Start :Mon Jul 09 13:59:31 2018

100 U® Pl I \@ 1 ) a I H Ml I I Ip t II m 1 111 rnunnv !YU DO Ill IW ~IJ I I IHI II JI) Ill II It\ l I I \I I I I

500 1000

-ROI Type: 1

1500 2000 channel

2500 3000

-ROI Type: 2

3500 4000

0241

7/9/2018 2:31:41PM





Sample Description

Sample Type

Sample Size

Facility

Sample Taken On

Acquisition Started

Procedure

Operator

Detector Name

Geometry

Live Time

Real Time

Dead Time








Sample Number

: 1806097-04

: OU-1-007 OUTFALL 007 DIS

: RA RECOVERY

: 1.000E+00 units

: Countroom

: 7/9/2018 1:57:16PM

: 7/9/2018 2: 15:58PM

: BAFIL

: Administrator

: GE4

: BAFIL

: 900.0 seconds

: 934.1 seconds

: 3.65 %

: 2.50

: 1 - 4096

: 15 - 4096

: 1.000 keV

: 2/24/2018

: 11/9/2014

: 68078

PEAK ANAL YS/S REPORT


Peak

No.



Energy (keV)

ROI start

ROI end

: 1 : 4096

Peak Centroid

Net Peak Area


Page 1 of6

Continuum Counts

FWHM (keV)

0242

7/9/2018 2:31:41PM Page 2 of6


M m

M m

M m m M m

M

m

M

m


Peak Energy ROI

No. (keV) start

1 30.95 24 -2 35.14 24 -3 52.20 4 7 -4 61.77 56 -5 66.08 56 -6 81. 24 7 5 -7 112. 2 9 10 6 -8 159.62 155 -9 225.48 219 -

10 276.77 272 -11 303.37 2 97 -12 335.09 328 -13 356.05 34 9 -14 376.09 372 -15 384.47 380 -16 387.22 380 -17 391.75 380 -18 414.96 40 9 -19 418.12 409 -20 437.16 432 -21 467.82 4 65 -22 471.82 4 65 -23 511.83 505 -24 583.78 579 -25 759.44 7 55 -26 1238.97 1235 -




ROI end

39 39 55 74 74 86

117 163 228 281 309 340 360 378 396 396 396 424 424 442 478 478 517 587 762

1242

Peak Net Peak Net Area Continuum Centroid Area Uncertainty Counts

30.01 2.20E+03 103.43 2.47E+02

34.21 5.10E+02 76.01 2.01E+02

51. 27 5.43E+0l 42.06 2.39E+02

60.86 2.30E+02 46.47 2.08E+02

65.17 1.16E+02 42.51 2.19E+02

80.34 9.42E+02 77.10 2.60E+02

111.42 2.34E+02 59.40 3.24E+02

158.78 4.l0E+0l 35.74 1. 72E+02

224.69 3.21E+0l 32.22 1.30E+02

276.02 7.0lE+0l 25.02 4.79E+0l

302.64 1.45E+02 34.54 7.47E+0l

334.39 9.07E+0l 29.33 5.86E+0l

355.37 3.96E+02 43.91 4.64E+0l

375.42 1.27E+0l 10.43 1.06E+0l

383.82 1.31E+02 31.30 1.l0E+0l

386.57 1.15E+02 28.46 4.16E+00

391.10 3.98E+0l 29.46 3.28E+00

414.33 2.26E+0l 18.37 3.03E+0l

417.50 2.06E+0l 16.29 1.98E+0l

436.55 7.50E+0l 17.32 0.00E+00

467.24 1.97E+0l 6.93 6.55E-0l

471.24 9.22E+00 10.77 4.76E+00

511.29 3.l0E+0l 13. 35 6.00E+00

583.30 2.00E+0l 8.94 0.00E+00

759.13 8.00E+00 5.66 0.00E+00

1239.14 7.00E+00 5.29 0.00E+00




Peak Energy

No. (keV)

1 30.95 2 35.14 3 52.20

: 7/9/2018 2:31:34PM

: \\OR-GAMMA 1 \ApexRoot\Countroom\Data\0000066684. CNF



2.20E+03 103.43 2.20E+03

5.10E+02 76.01 5.10E+02

5.43E+0l 42.06 5.43E+0l

FWHM (keV)

2.26 2.20 2.20 2.18 2.39 2.21 2.42 4.85 4.77 2.19 2.52 2.31 2.28 4.58 3.24 1. 98 4.58 2.86 2.34 3.06 2.63 2. 63 2.33 2.70 1.16 1. 92

Subtracted Uncert.

1.03E+02 7.60E+0l 4.21E+0l

0243

7/9/2018 2:31 :41PM Page 3 of6





M 4 61.77 2.30E+02 46.47 2.30E+02 4.65E+0l

m 5 66.08 1.16E+02 42.51 1.16E+02 4.25E+0l

6 81. 24 9.42E+02 77.10 9.42E+02 7.71E+0l

7 112.29 2.34E+02 59.40 2.34E+02 5.94E+0l

8 159.62 4.l0E+0l 35.74 4.l0E+0l 3.57E+01

9 225.48 3.21E+0l 32.22 3.21E+0l 3.22E+0l

10 276.77 7.0lE+0l 25.02 7.0lE+0l 2.50E+0l

11 303.37 1.45E+02 34.54 1.45E+02 3.45E+0l

12 335.09 9.07E+0l 29.33 9.07E+0l 2.93E+0l

13 356.05 3. 96E+02 43.91 3. 96E+02 4.39E+0l

14 376.09 l.27E+0l 10.43 l.27E+0l 1.04E+0l

M 15 384.47 1.31E+02 31.30 l.31E+02 3.13E+0l

m 16 387.22 1.15E+02 28.46 l.15E+02 2.85E+0l

m 17 391.75 3.98E+0l 29.46 3.98E+0l 2.95E+0l

M 18 414.96 2.26E+0l 18.37 2.26E+0l 1.84E+0l

m 19 418.12 2.06E+0l 16.29 2.06E+0l 1.63E+0l

20 437.16 7.50E+0l 17.32 7.50E+0l 1.73E+0l

M 21 467.82 1.97E+0l 6.93 1.97E+0l 6.93E+00

m 22 471.82 9.22E+00 10.77 9.22E+00 1.08E+0l

23 511.83 3.l0E+0l 13. 35 1.27E+0l 1. 4 lE+00 1.83E+0l 1.34E+0l

24 583.78 2.00E+0l 8.94 3.74E+00 l.22E+00 1.63E+0l 9.03E+00

25 759.44 8.00E+00 5.66 8.00E+00 5.66E+00

26 1238.97 7.00E+00 5.29 7.00E+00 5.29E+00






IDENTIFIED NUCLIDES



SN-113 0.94 255.12 1. 93 391.69 * 61.90 6.26E+0l 4.71E+0l

I-125 0.98 35.49 * 6.49 4.52E+02 6.83E+0l

BA-133 0.99 30.80 * 97.60 9.96E+0l 5.05E+00

302.84 * 17.80 7. 13E+02 2.77E+02

356.01 * 60.00 6.21E+02 1.06E+02

0244



Nuclide Id Energy

Name Confidence (keV)

PA-231 0.99 9.28 10 .11

283.67 302.67




*





7/9/2018 2:31:41PM Page 4 of 6

Yield(%) Activity Activity

(pCi/units) Uncertainty

42.00 20.20 1. 60 2.30 5.52E+03 2.15E+03


Nuclide Name

SN-113 I-125 BA-133 PA-231

Nuclide Id

Confidence

0.946 0.981 0.993 0.995

? = nuclide is part of an undetermined solution

X = nuclide rejected by the interference analysis

Wt mean Activity

(pCi/units)

6.26E+0l 4.52E+02 1.01E+02 4.74E+03



Wt mean Comments Activity

Uncertainty

4.71E+0l 6.83E+0l 5.04E+00 2.15E+03

0245

7/9/2018 2:31:41PM


M

m

M

m M

m

M

m






3 52.20

4 61.77

5 66.08

6 81.24

7 112.29

8 159.62

9 225.48

10 276.77

12 335.09

14 376.09

15 384.47

16 387.22

18 414.96

19 418.12

20 437.16

21 467.82

22 471.82

23 511.83

24 583.78

25 759.44

26 1238.97




UNIDENTIFIED PEAKS

: 7/9/2018 2:31 :34PM

: 1 : 4096

Peak Size (CPS)

6. 03161E-02

2.55640E-01

1.29421E-01

1.04675E+00

2.60000E-01

4.55818E-02

3. 564 72E-02

7.78605E-02

1.00759E-01

1.41049E-02

1.46046E-01

1.27384E-01

2.51648E-02

2.28952E-02

8.33333E-02

2.19202E-02

1.02399E-02

2.03082E-02

1.80656E-02

8.88889E-03

7.77778E-03


38.74 10.10 18.25

4.09

12.69 43.56 50.21 17.85 16.17 41.07

11.91

12.41 40.56 39.54

11. 55 17.56

58.43 36.73 27.76

35.36 37.80

NUCLIDE MDA REPORT


Peak Type

Sum Sum

Sum

Sum

Page 5 of6

Tolerance Nuclide

0246

7/9/2018 2:31:41PM Page 6 of6




Name (keV) (pCi/units) (pCi/units) (pCi/units) (pCi/units)

FE-55 5.89 24.50 5.43E-03 5.43E-03 0.00E+00 0.00E+00

CO-57 122.06 85.51 2.18E+0l 2.18E+0l -7.87E+00 1.02E+0l

136.48 10.60 1.87E+02 -1.23E+02 8.75E+0l

NI-59 6.92 29.80 7.53E-03 7.53E-03 0.00E+00 0.00E+00

MO-93 16.59 52.90 9.54E-01 9.54E-01 8.62E-02 4.51E-01

18.60 10.00 9.32E+00 2.00E+0l 4.48E+00

NB-93M 16.57 9.43 5.33E+00 5.33E+00 4.82E-01 2.52E+00

CD-109 88.03 3.72 3.60E+02 3.60E+02 -1.06E+02 1.70E+02

+ SN-113 255.12 1. 93 1.21E+03 3.61E+0l -4.85E+02 5.51E+02

391.69 * 61.90 3.61E+0l 6.26E+0l 1.59E+0l

SN-119M 23.87 16.10 1.08E+0l 8.41E+00 6.04E+00 5.18E+00

25.10 22.70 8.41E+00 -2.44E+00 4.04E+00

+ I-125 35.49 * 6.49 1.04E+02 1.04E+02 4.52E+02 5.09E+0l

I-129 29.78 57.00 1.64E+0l 1.64E+0l 1.29E+02 8.13E+00

33.60 13.20 8.85E+0l 6.74E+02 4.37E+0l

39.58 7.52 5.78E+0l 5.27E+00 2.76E+0l

+ BA-133 30.80 * 97.60 5.37E+00 5.37E+00 9. 96E+0l 2.62E+00

302.84 * 17.80 2.14E+02 7.13E+02 l.00E+02

356.01 * 60.00 7.16E+0l 6.21E+02 3.37E+0l

CE-139 165.85 80.35 2.83E+0l 2.83E+0l -1.33E+00 1.32E+0l

CE-144 133.54 10.80 1. 96E+02 1. 96E+02 6.34E+0l 9.22E+0l

HG-203 279.19 77.30 4.73E+0l 4.73E+0l 5.36E+0l 2.22E+0l

PB-210 46.50 4.25 l.21E+02 1.21E+02 1.92E+0l 5.72E+0l

+ PA-231 9.28 42.00 1.32E-02 1.32E-02 0.00E+00 0.00E+00

10 .11 20.20 3.53E-02 0.00E+00 0.00E+00

283.67 1. 60 1.24E+03 9.33E+0l 5.51E+02

302.67 * 2.30 1.66E+03 5.52E+03 7.77E+02

TH-231 25.64 14.70 1.62E+0l 1.62E+0l -4.0lE+00 7.83E+00

84.21 6.40 5.43E+02 2.56E+03 2.66E+02

PA-234M 9.89 89.00 7.52E-03 7.52E-03 0.00E+00 0.00E+00

21. 72 64.90 2.24E+00 2.92E+00 1.08E+00

37.93 23.75 3.08E+0l 9.05E+0l 1.50E+0l

131.42 20.40 1.03E+02 2.49E+0l 4.85E+0l

TH-234 63.29 3.80 4.20E+02 4.20E+02 8.54E+02 2.04E+02

NP-237 29.37 14.00 6.38E+0l 6.38E+0l 5.57E+02 3.15E+0l

86.50 12.60 l.06E+02 8.04E+00 5.03E+0l

U-237 97.08 16.30 8.88E+0l 5.99E+0l -4.58E+0l 4.18E+0l

101.07 26.30 5.99E+0l -1.12E+00 2.82E+0l

114.00 12.30 2.62E+02 5.95E+02 1. 27E+02

208.01 22.00 1. 27E+02 -4.73E+0l 5.95E+0l

AM-241 59.54 35.90 3.61E+0l 3.61E+0l 6.79E+0l 1.75E+0l

AM-243 74.67 66.00 1.83E+0l 1.83E+0l -1.21E+02 8.69E+00

+ = Nuclide identified during the nuclide identification • = Energy line found in the spectrum

> = MDA value not calculated @ = Half-life too short to be able to perform the decay correction

0247

lQS

104

= =

~ 103 .I ro u V}

0-, 0

r--1

V}

+-' s::::: :=s 0 u

102

101

= = 7 ~ _, = -,c

= = _, ' ~

100 ll"PI IN I I I •-,

500 1000

-ROI Type: 1

1500

0000068078.CNF

2000 channel

2500

Live Time :900.000 sec Real Time :934.050 sec Start: 1: 2.0(kev) Stop : 4096:4091.6(kev) Acq. Start :Mon Jul 09 14:15:58 2018

3000

-ROI Type: 2

3500 4000

0248

SECTION XIII

ANALYTICAL DATA (GROSS ALPHA/BETA)

0249

Eberline Services


Analysis Sheet

Work Order 18-06097

Analysis Code [ . GaGbT_ThSr

Run 1 Date Received 6/21/2018



Project WESTLAKE

Report Level 4

Activity Units pCi

Aliquot Units

Matrix WA


Instrument Type Alpha/Beta GPC

Radiometric Tracer

Radiometric Sol#

Tracer Act (dpm/g)

Carrier


Internal Sample

Fraction Desc

01 LCS

02 MBL

03 DUP

04 DO

18-06097 GaGbT_ThSr

Run 1

Client ID

LCS

BLANK



• SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. h Indicates estimated SAF value.


I I Login CPM

30

30

Printed: 7/10/20181:15 PM

Page 1 of 3

I Sample

I Sample

Date Aliquot

06/21 /18 00:00 1.0000E+00

06/21/18 00:00 1.0000E+00

06/20/18 10:00 7.0000E-02

06/20/18 10:00 7.0000E-02

I

0250

Eberline Services Oak Ridge Laboratory

Analysis Sheet


Fraction Desc A/iquot(g)

01 LCS

02 MBL

03 DUP

04 DO

I I I

I I


I

I I !

I

I

I

Radiometric Radiometric

Tracer (pCi) %Rec

0.00

0.00

0.00

0.00

18-06097 GaGbT_ThSr

Run 1

Grav Carrier Grav Filter

Added(ml) Tare(g)

7.7589

7.7589

7.7668

7.7539

I


7.7590

7.7590

7.8039

7.7879

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. "Indicates estimated SAF value.


Grav Filter Grav Net(g) %Rec

0.0001

0.0001

0.0371

0.0340

I i !

I

I

i I I

I

i I

I I I

I

Printed: 7/1012018 1:15 PM Page 2 of 3

Mean SAF SAF

%Rec 1* 2*

1.00 1.00

1.00 1.00

1.00 1.00

1.00 1.00

I

0251


Analysis Sheet


01 LCS

02 MBL

03 DUP

04 DO

Rough Prep Rough Prep

Date By Prep Date

07/10/1811 :47

07/10/1811 :47

07/10/18 11 :47

07/10/1811:47

I

I

'

l

I :

18-06097 GaGbT_ThSr

Run 1

I Prep By

I

JPACHELLA

JPACHELLA

JPACHELLA

JPACHELLA

i

Sep tO Date/Time

* SAF1 is used for Gross Alpha and all other radionuclides. SAF2 is used for Gross Beta only. A Indicates estimated SAF value.


I Sep tO

I By i

I

I

!

I

'

I I

Printed: 7/10/20181:15 PM Page 3 of 3

Sept1 Sep t1

Date/Time By

I

i

I i

0252

Eberline Analytical



Work Order: 18-06097-GaGbT-1 Printed: 7/11/2018 9:51 AM

Page 1 of 3

~ . ., Lab

Fraction

01

02

Nuclide i Sample i Oesc

GROSS ALPHA LCS

Client Identification

LCS

Activity Units

pCi/1

Results [_Error Estimate I MDA I

2.97E+02 I 3. 77E+00 2.39E-01 [

LCS LCS I

LCS

I RPD

Known ¾R Flag Flag MDA Blank

Flag Flag

2.71E+02 109.59 I OK OK

C: ::3 ct

~ 0 (.)

.!!! ~ ca C: ,:(

i t: ~

l "' C: <C Cl)

.E: .:: Cl)

nl

t: .!!! u

oir-

1-.c C) ca

C)

ti) C .Q .!!? 0 Q)

C

s C Q)

E C 0 ... ·s: C w 0 :ii: <(

GROSS ALPHA MBL BLANK pCi/1

1---+------··+·. ------l-·---·-

03 GROSS ALPHA I DUP OU-1-007 Outfall 007 DIS pCi/1

·--1--·· ____________ __, ___ ----

04 GROSS ALPHA DO I OU-1-007 Outfall 007 DIS pCi/1

I --1-----------+- - ·- ---1--·-------·· ------------+---

------+-------------! -------1---------

1------+------------+-~-·----I~-- ------------ -------+·----··-··

--···----

--- ·----r---- +----------'---·--·--

1.29E-02 1.36E-01 3.14E-01 I OK OK ----

7.82E+00 4.24E+00 7.21E+00 NA INV ··-----1----·---~- ~--

2.48E+00I 3.10E+00 6.27E+00 INV

.. --·-+---

---1

I------+---------+---·--+-- -------------··--1---·-·--- -- --, ---- · -----··-----,-·--------------1-----·-·-----+---- --·----- '-----------+---+-----------1-----+------J

- --------···--+--·---- ··--------!-·------------;-------+--- i

1------+------------+-----I- ·--·· +------- ·--- -·-----l·---- ---·---- --·· --·--7------+------+------+------+------1

1-----+--------------, --+---- -------- 1---- --- - +----

1-------------------------,--.--•··--·· ----------+-------------t-----------1

-----------l-------t-··- . i J

1-----+--------- --l----t----------------t------- ·-----1-·--

I o---------+-------r--------1- --- -------1--------------1----+-------+-------+----+

1--------+--------+--------t--------------j-------+-----+-----r-----r----+-------+----1----------+----------1---

0253

Eberline Analytical


~ Lab Nuclide I Sample

Fraction Desc

01 GROSS ALPHA LCS ------

02 GROSS ALPHA MBL

--··-

03 I GROSS ALPHA DUP

--- -·--- ----------;.....-----

I-04 GROSS ALPHA DO

--·- --- --------- -----~

..0 (!) --·~------

a:s (!) .•. --- -----··-----~- ~---

----- - ·-- - -·--- ---- -----··--------·-- ---··-.... .g ._ 0 -·-- c-···-

~

~ .; -~ ~ .. ----------·----------~ C: <{ .. :§ .... .. ijj -~ ------------ -- ----------··· ----------

(/)

C: .2 (/)

·o --------··· --·----·-- ------------~-- --···---

Cl) C

.5 -----··--··--- ------------------------·-· -----

~I C: Cl)

E C:

·--·--------------- ----

0 ---·- ------- i---------... ·s;: C: w

---------------f--·

0 ::!!: <(


Work Order: 18-06097-GaGbT-1

Sample Sample Radiometric Grav Mean I SAF

Date Aliquot %Rec %Rec % Rec I

06/21/18 00:00 1.00E+00 0.00 0.00 o.oo' 1.00

- ---"-·---------··---- -------- ------ --·--------··---- -----.-·-- -----~--

06/21/18 00:00 1.00E+00 0.00 o.oo: 0.00 1.00

-----·- . -- --·•--,----- - --

06/20/18 10:00 i 7.00E-02 0.00 o.ooi 0.00 1.59 -- -- -----

06/20/18 10:00 I

7.00E-02 0.00 0.00 0.00 1.51

---------~----------- --·· -- ···-- --- -----·---

I --------

·•--I·-

·--- ----.--- . ----·--· ----------- ,-----·- --··----- -- ----- - ·----·---- -·

-------- --------------·· ···-- ····-·-··-·-··-····------·- !--------

--····-----------------------·--·-- ------·-----· --- - - . ----- ----·-·-·· f----------

-----------··---- ----------·---

·------- -·~------- -· ---- ··-- .. --------

·----------·--· --···---··-----------·--

--·---- -- --·-- - - - ---···-- ------·---···------- -- ... -····---·--·--

------ -·------------ -·------------·--··-- --·----·--·---

------ --- ---- ------------ ---•-.------·-----------. ---···--···- ____ ,, _____ , _______ --------

-·------·---- -- -------- --------------------------- ---- ----- -·-··---· ···--- - --·-----------·

---------------- --- --------------~- ,_ ________

----··-··--··-- ------ -------------+--~---·---·----

- ------------··- --·------

----------

I

I

SeptO


Sep 11

DatefTime Date/Time

. -----------

---··---------

i ----··--·

! ·-

i I

I !

0254


~ ' Ji

j Sample Lab Nuclide Fraction Desc

01 GROSS ALPHA I LCS I

c:: :J It

.g 0 (.)

.!!! ~ iij c:: q;

....

~ t: ~ j ~ .. C: "( Q)

.!:: 'i:: ., i'd

i: ,!!! u

~

....

.c (!) cu (!)

(/) C: 0

.!!? 0 Q)

C

~ C: Q)

E C: 0 ... ·s; C: w 0 :E <(

02

03

04

------

I ··~··--~·-···T··

GROSS ALPHA I MBL ·-- -

i

GROSS ALPHA I DUP I

-1 ·-

GROSS ALPHA +o~ --------

·------·-

··------

----·---·-

···--------- -------·

-------

--- -·-

--------

-



I

I Counting I Halflile Carrier Count

I Detect Counts

Date/Time (days) i Time

07/11/18 07:32 LB4110A D1 120 23786 __ ,, ________

·---· -- ·---

07/11/18 07:32 LB4110A D2 120 15

--·- --··- --·----. ·-·- -·-· ---------------

07/11/18 07:32 LB4110A D3 120 44

---------- ·--------··--·-----·- ------·· --- ··----------i----··

07/11/18 07:32 LB4110A D4 120 21

----···------- --··- -----------------· - ----

- .. --------------·----- --·--·--- ·---~-------- -

--------·- ___ ., -~

-·---- --·- ----·- - ----·-------- ··---- -· -- ----------------

·---

-----·- ···----------

-~-·-------- ------·-·------ . --·-·---------- -

-----· ----·----_____ ,, __

------·· ·----·-----· ----···-· --·--·-·----. --- --·---·-------

-------------- ----~---- . ·-----------

----------·------------- ---------·--- -----

------- --------- -·---------

-----~--·-- -· ~---------- ·--- f------·

·---··----· -·-

---···--------- ------ -~-----------··-·

··>---·-···

I Bkg

I CPM

0.066666667 1

0.1166666671


Elf

0.3007 ··-···---~--

0.2912 ______ J_ I

0.1333333331 0.3054

0.1 0.2944

i I

I

I

I i

I

0255

Eberline Analytical


( Lab Nuclide

Fraction

01 GROSS BETA

§ a::

{: 0 0 ,!! ~ cii c:: <t

1: .!!! 0

""'"

1-jl (!) ca (!)

1/) C 0 1/)

·c:; Q)

a .! C Q)

E C 0 ... ·s: C w 0 :E <(

I

02 GROSS BETA -- ·-- ----··--·--·----

03 GROSS BETA

04 GROSS BETA

--- ,, -- ·----------

··--·------

----------

--·

I Sample Desc

LCS

MBL ----~

DUP

DO



Client Activity LCS Results Error Estimate MDA

Identification '

Units Known

LCS pCi/I 2.62E+02 2.95E+00 I 5.04E-01 i 2.77E+02

------··-··---·-· -

BLANK pCi/I -1.28E-01 2.72E-01 5.96E-01 \

--~- ------- .. -------------i ·,~···

OU-1-007 Outfall 007 DIS pCi/1 2.91E+00 5.26E+00 1.08E+01 I .. -- --· -------

~983E~01• OU-1-007 Outfall 007 DIS pCi/I 1.14E+01 5.14E+00

i---- --~-------

---------------·------------ - ---·· , ____ ··---·-----~

·- ------ -- ---------- --------- ------- ------------ -·---

----~--··----·--- ----- -·----

.. -~-----

I --·---·-

--···

------ ···-~·-·

------ --·----·------·--. -···-·---··

·- -~--·-----

-- --- "·-~·----·--

-----··---

LCS I %R I

94.38


LCS I RPD MDA Blank

I Flag Flag Flag Flag

OK OK

OK OK

NA INV --'----------

INV

0256

Eberline Analytical


Preliminary Data Report & Analytical Calculations Printed: 7/11/2018 9:52 AM Page 2 of 3


~ ---,-

Lab

I Nuclide I Sample Sample Sample Radiometric Grav

I Mean

I SAF I Sep to I Sep 11

Fraction Desc Date Aliquot % Rec % Rec % Rec Date/Time I Datemme

01 I GROSS BETA I LCS 06/21/18 00:00 1.00E+00 0.00 o.oo\ ____ 0.00 1.00 -------- ----····-- -· ---· - ----

~

---

.g I-0 .c 0

02 t GROSS BETA MBL 06~111800~0 -1 1.00••1 - o.oo 0.00 0.00 1.00

1-- -- ---- - -- -- -- -- ·--------·------ ---·--. -- ----

03 GROSS BETA DUP 0612011810:00 __ J 1.ooE-02 _______ o.oo 0.00 0.00 1.08

-·-·----- ~----------- - ----[--------------- ------· -------

04 GROSS BETA DO 06/20/18 10:00 I 7.00E-02 0.00 o.oo[ 0.00 1.07

,!!! (!) _; Ill cu i::: q: (!)

-- ---------1---

- ---l------··--t

.... a,

t! 0 t: ~

i f--------1---- I

I i

.; -~ ~ ., C: <I;

1--------1---- --- -- ----------+--------!------ - ---------------------+ - ----1---·- - -----+- -----+--+-- 7 --------ti __ _

a, .s .::: a,

nl -~ ------l-----------------------1---------1--------------- ___ ___, _________ --------1---- ----------

1/) C: 0

.!? 0 Q)

•------------,----- -----------------+- ----1-----

Q

J9

~I C: Q)

E C: 0 ---,------!----- -----1--- ----1------- -------------+

... -----+- ----------+-----+-----------+---------------1

·s: C: w 0 :E <(

0257

Eberline Analytical


( Lab Nuclide

Sample

Fraction Desc

01 GROSS BETA I LCS

C: ::s a:

.g 0 0 ,!!! ~ "iii C: q:

-~

"'"""

1-.c (!) ns (!)

II) C: 0 II)

·o Q)

C

.f:! C: Q)

E C: 0 ... ·s; C: w 0 ~ <(

----------- -----···· - ..

02 GROSS BETA MBL

·------··- - ·-···

03 GROSS BETA DUP ----~------

04 GROSS BETA DO _L............ __________ -··---- :-----·---~

--------- -~---~- ----- .. - -- -

··---- 4-------··---

----

--4••·---

- ---·----·- ··--- ·-------

-·-·--·----·- ·-------- _____ ., ___

·--------- -------·-··-

--------·------·--·-- -----··----

·--··· ------·---

--·----- -·- --

-·---- ------------------ -- ---- -----·-

-------- ------···

---------

··---



Counting I Halflife Detect I Carrier Count

Counts 8kg

Date/Time l (days) I Time CPM

07/11/18 07:32 LB4110A D1 12oi 41871 1.1

--~· -· ---!-07/11/18 07:32 LB4110A D2 1201 161 1.483333333

' -------·-- ------ ---·-·------·-------- ---------------

07/11/18 07:32 LB4110A D3 1201 2191 1.55

------·---·-----· - ------·--- - /--- ---------·--- ----·-· ---------·----- -------------

07/11/18 07:32 LB4110A D4 120 297 i 1.666666667

--------~-----------~------- ----· ... , ... ---··------· --------- ---···

-·---------·----- - --- ·-·-----·-!-------- ----- -----·-

-~----- ··--·------ ·------·-- ------ ·------·---. -----··-- -·--- -----

I --------- ·--···--·----- ----· -·-----·------- -------- ----·----- -----·

---------·~·-·-··- ·---- . -··-------·

---------- -·------------- ·- - ·-·----·-·· ----·---- -···-···--·- ------~- --------·-- --'·-·

--·---····-···----· ---·---- --····-·-----·-----·--- ··----------

----~---- ----· . ., ___________

------ ----------- --·-·-----· ··----·---- - ·----·---- ····--·-----··-- -- -

----·-·--·-------·--- --·--·-·------- ·------·---------··· -----···--·-

---·-·- -----····-- - ----------·---·-·---·- ··-·-··-------------- - -------------···-

--------. ·······-·- -- --···------- ·-------·-----

-- -__________ _. ___ -----··'"-----

-·---- ----- --·------ ---------

---- ···------------------- ---· ·-f------ --·----'----

-------- --- --~---·---- ··-

I

Printed: 7 /11/2018 9 52 AM Page 3 of 3

Eff A to B, Cor

0.5104 297.844565

0.4979 1.341666667

0.4343 1.732086667

0.4889 2.475

0258


Internal Sample Client

Fraction Desc ID

01 LCS LCS

02 MBL BLANK


04 DO OU-1-007 Outfall 007 DIS '

I !

I i

I i ! I I :

I I I i I

I I I

I

I I

18-06097-GaGbT _ ThSr-1 (pCi/I) in WA Tracer ID:

Sample Sample Tracer Tracer

Date Aliquot Aliquot (g) ACT(dpm)

06/21/18 00:00 1.0000

06/21/18 00:00 1.0000

06/20/18 10:00 0.0700

06/20/18 10:00 0.0700

'

'

I

I

I

I

I

Radiometric Tracer (pCi)

Printed: 7/10/2018 1 :15 PM Page 1 of 1

Radiometric SAF SAF %Rec 1* 2*

0.00 1.00 1.00

0.00 1.00 1.00

0.00 1.00 1.00

0.00 1.00 1.00

I

I

0259


Internal Work Order Run I 18-06097 1

LCS & Matrix Spikes I Isotope Sol# '

, ............ J Solution Approx

dpmlg Date Addition

Am-241 NB-07 i 593.400 7/10120181 0.800

SrY-90 NB-07 607.930 711012018i 0.900 --- ·--

Tracers

fraction ! Isotope Sol# Activity Solution dpmlg Date

--r---

Version 2.0 08/99


Analysis Code

GaGbT ThSr LCS MS

Volume Volume Used (g) Used(g)

1.0133

1.0133

Volume Approx Used(g) Addition

Date

7/10/2018 11:47

LCSD Volume Used(g)

MSO Volume Used(g)

Technician

JPACHELLA

LCS MS

Known pCi

270.85

277.48

Tracer

Error Estimate

11.647

8.325

Added pCi

0.00

0.00·

Error Estimate

0.000

0.000 --+------- -----·-----


o.oo:

0.00

Page 1 of 1 Printed: 71101201811:47 AM

Error Estimate

0.000

0.000

LCS

Witness Initials

MSO Added

pCi

o.oo'

0.00,

Error Estimate

0.000

0.000

Matrix Spike

0260

Lab



Fraction Client ID

01 LCS

02 BLANK



Comments

Sample

Type

LCS MBL

DUP DO

Aliquot Worksheet

Analysis Code I Rpt Units lab Deadline

GaGbT _ ThSr I liters 7/11/2018


Ratio Post/Pre No of Dils Dil Factor Ratio Aliquot Net Equiv

1.0000E+00 1.0000E+00

1.0000E+00 1.0000E+00

7.0000E-02 7.0000E-02

7.0000E-02 7.0000E-02

I

'

Technician: /vie ......, r 'c Date: __ 11_:::_1~

Technician

MHIGHTOWER

MS Aliquot Data


H-3 Solids Only Water Added H3 Dist

Aliquot Net Equiv (ml) Aliq

0261

Eberline Services - Oak Ridge Version 1.0 9/1999 Gravimetric Worksheet

Work Order •

1s-oso91 I 1

Work Order Analysis

Code Gravimetric

Carrier

GaGbT ThSr

TRetec AMO Environmental Decisions Sample Carrier Data Filter Data Carrier Added Filter Tare Filter Final

Fraction Client ID Type (ml) (g) (g)

01 LCS LCS 7.7589 7.7590

02 BLANK MBL 7.7589 7.7590

03 DUP DUP 7.7668 7.8039

04 OU-1-007 Outfall 007 DIS DO 7.7539 7.7879

Technician: craJU Date:~ /(7',/ ~

Carrier Cone {mg/ml)

Filter Net (g)

0.0001 0.0001 0.0371 0.0340

Printed: 7/10/2018 11 :44 AM Page 1 of 1

Technician

JPACHELLA

Gravimetric %

·Recovery

0262

Eberline Services - Oak Ridge Version 1.0 9/1999 TDS / TSS Worksheet

Work Order I Run I

1s-oso91 I 1

Analysis Code

GaGbT_ThSr

TRetec AMO Environmental Decisions Filter Data Aliquot Filter Tare Filter Final

Fraction Client ID ml (g) (g)

04 OU-1-007 Outfall 007 DIS 5.0000 7.7913 7.7978

Technician: /t Date: _2_;~ ( tl

Filter Net (g)

0.0065

Technician


MHIGHTOWER

TDS/TSS Maximum Aliq

(mg/L) (ml)

1300.0000 76.92

0263

Detector ID Sample ID Alpha Beta Count Time Voltage TOD

D1 1806097-01 23786 41871 120 1410 7/11/2018 7:32:07 AM -~p D2 1806097-02 15 161 120 1410 7/11/2018 7:32:07 AM I I' c~ D3 1806097-03 44 219 120 1410 7/11/2018 7:32:08 AM :}I\ io D4 1806097-04 21 297 120 1410 7/11/2018 7:32:08 AM

0264

Eberline Analyticc I Oak Ridge Laborctory

[ Detector

~ LB4110A - Al LB4110A - A2

LB4110A - A3

f LB4110A - A4 LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

_B4110A - Cl

_B4110A - C2

_B4110A - C3

_B4110A - C4 ,_ _B4110A - D1

_B4110A - D2

_B4110A - D3

i_B4110A - D4

_B4110A - El

_B4110A - E2

_B4110A - E3

'_B4110A - E4

_B4110A - Fl

'_B4110A - F2

1-B4110A - F3

LB4110A - F4 -LB4110A - Gl

LB4110A - G2 -LB4110A - G3 -LB4110A - G4

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017


Count Date Bkg CPM i i

7/11/2018 1.17E-01

7/11/2018 1.33E-01

7/11/2018 1.17E-01

7/11/2018 2.S0E-01

7/11/2018 1.00E-01

7/11/2018 1.17E-01

7/11/2018 1.33E-01

7/11/2018 1.17E-01

7/11/2018 6.67E-02 I 7/11/2018 1.00E-01 I 7/11/2018 6.67E-02

7/11/2018 l.67E-02

7/11/2018 6.67E-02 ·

7/11/2018 l.17E-01.

7/11/2018 l.33E-01 ,

7/11/2018 1.00E-01 "

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

3/23/2018 0.00E+00

7/11/2018 3.33E-02

7/11/2018 3.33E-02

7/11/2018 1.67E-02

7/11/2018 5.00E-02

7/11/2018 1.67E-02

7/11/2018 1.17E-01

7/11/2018 6.67E-02

7/11/2018 6.67E-02

PFW LCL Mean

p -4.43E-02 8.89E-02

p -5.78E-02 9.59E-02 p , -3.26E-02 9.89E-02

p -3.23E-02 8.56E-02

p -3.90E-02 1.lOE-01

p -1.29E-02 1.13E-01

p -5.98E-02 8.03E-02

p -3.69E-02 8.0lE-02

p -2.53E-02 8.67E-02

p -3.85E-02 6.06E-02

p -5.S0E-02 6.92E-02

p -3.41E-02 7.82E-02

p -3.21E-02 1.34E-01

p -1.94E-02 1.20E-01

p -4.41E-02 1.04E-01

p i -2.32E-02 1.44E-01

p -4.29E-02 1.lOE-01

p -3.09E-02 6.37E-02

p -8.81E-02 9.llE-02

p ! -4.SSE-02 7.04E-02

p -3.04E-02 6.67E-02

p -3.27E-02 4.63E-02

p -4.19E-02 5.37E-02

p -2.36E-02 6.89E-02

p -4.89E-02 5.66E-02

p -4.72E-02 7.49E-02

p -4.92E-02 8.16E-02

p -3.lSE-02 7.69E-02


UCL

2.22E-01

2.S0E-01

2.30E-01

2.04E-01 ' I 2.59E-01

2.40E-01

2.20E-01

1.97E-01

1.99E-01

1.60E-01

1.93E-01

1.91E-01

2.99E-01

2.59E-01

2.52E-01

3.12E-01

2.62E-01

1.58E-01 I

2.70E-01

1.86E-01

1.64E-01

1.25E-01 I 1.49E-01

1.61E-01

1.62E-01

1.97E-01

2.12E-01

1.85E-01 I

G? ·:-+/t l ft9J

0265

Eberline Analytiec,I Oak Ridge Laborntory

r Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

i LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

:_B4110A - D2

_B4110A - D3

_B4110A - D4

LB4110A - El -LB4110A - E2

~

,_B4110A - E3 -_B4110A - E4

LB4110A - Fl -_B4110A - F2 ~

_B4110A - F3

_B4110A - F4

LB4110A - Gl

I_B4110A - G2

LB4110A - G3

LB4110A - G4

Alpha/Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Beta

Calibration Date

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017


Count Date Bkg CPM

7/11/2018 1.22E+00

7/11/2018 1.37E+00

7/11/2018 1.45E+00

7/11/2018 1.68E+00

7/11/2018 1.22E+00

7/11/2018 1.37E+00

7/11/2018 1.33E+00

7/11/2018 1.63E+00

7/11/2018 1.02E+00

7/11/2018 1.30E+00

7/11/2018 2.lSE+00

7/11/2018 1.28E+00

7/11/2018 1.lOE+00

7/11/2018 1.48E+00

7/11/2018 1.SSE+00 ·

7/11/2018 1.67E+00 ,,

3/23/2018 3.33E-02

3/23/2018 1.67E-02

3/23/2018 6.67E-02

3/23/2018 0.00E+00

7/11/2018 1.23E+00

7/11/2018 1.02E+00

7/11/2018 8.S0E-01

7/11/2018 1.53E+00

7/11/2018 1.75E+00

7/11/2018 2.42E+00

7/11/2018 1.88E+00

7/11/2018 1.33E+00

PFW LCL

p 9.0lE-01

p 9.79E-01

p 1.04E+00

p 9.47E-01

p 1.07E+00

p I 6.17E-01

p 9.02E-01

p I 7.17E-01

p 8.26E-01

p 7.02E-01

F 9.37E-01

p 7.90E-01

p 8.38E-01

p -4.49E-01

p 8.13E-01

p 9.28E-01

p 7.66E-01

i p 5.45E-01

p 4.98E-01

p 5.67E-01

p 9.19E-01

p 4.89E-01

p -2.20E-01

p 6.73E-01

p 8.41E-01

F 1.26E+00

p 9.12E-01

p 6.56E-01

Mean

1.36E+00

1.S0E+00

1.53E+00

1.40E+00

1.SSE+00

1.SlE+00

1.37E+00

1.39E+00

1.25E+00

1.21E+00

1.83E+00

1.22E+00

1.32E+00

1.66E+00

1.27E+00

1.43E+00

1.32E+00

9.58E-01

1.20E+00

1.04E+00

1.39E+00

8. 73E-01

1.30E+00

1.17E+00

1.31E+00

1.75E+00

1.43E+00

1.37E+00


UCL

1.82E+00

2.02E+00

2.0lE+00

1.85E+00

2.04E+00

2.41E+00

1.84E+00

2.07E+00

1.67E+00

1.73E+00

2.72E+00

1.65E+00

1.80E+00

3.76E+00

1.73E+00

1.93E+00

1.88E+00

1.37E+00

1.91E+00

1.S0E+00

1.86E+00

1.26E+00

2.83E+00

1.66E+00

1.79E+00

2.25E+00

1.95E+00

2.09E+00

f;? -:i--r,, nf3

0266

Eberline Analyt cal Oak Ridge Laboratory

Detector

LB4110A - Al

LB4110A - A2

LB4110A - A3

LB4110A - A4

LB4110A - Bl

LB4110A - B2

LB4110A - B3

LB4110A - B4

LB4110A - Cl

LB4110A - C2

LB4110A - C3

LB4110A - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A - F3

LB4110A - F4

LB411CA - Gl

LB411CA - G2

LB411CA - G3

LB411CA - G4

Alpha/Beta

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Alpha

Calibration Date

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017

11/2/2017


Count Date Eff

7/11/2018 0.2275

7/11/2018 0.2161

7/11/2018 0.2016

7/11/2018 0.2221

7/11/2018 0.2202

7/11/2018 0.1946

7/11/2018 0.2337

7/11/2018 0.2164

7/11/2018 0.2047

7/11/2018 0.2180

7/11/2018 0.2411

7/11/2018 0.2130

7/11/2018 0.2250

7/11/2018 0.2523

7/11/2018 0.2477

7/11/2018 0.1939

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

3/23/2018 0.0000

7/11/2018 0.2178

7/11/2018 0.1823

7/11/2018 0.2377

7/11/2018 0.2057

7/11/2018 0.1998

7/11/2018 0.2059

7/11/2018 0.2279

7/11/2018 0.1952

PFW LCL

p 0.2156

p 0.2006

p 0.1853

p 0.2114

p 0.2028

p 0.1824

p 0.2169

p 0.2060

p 0.1961

p -0.1424

p 0.2299

p 0.1993

p 0.2109

p 0.2355

p 0.2378

p 0.1824

F 0.1687

F 0.1518

F 0.1547

F 0.1747

p 0.1483

p 0.1776

p 0.2312

p 0.2019

p 0.1904

p 0.1941

p 0.2154

p 0.1914

Printed:

Mean

0.2257

0.2111

0.1999

0.2267

0.2226

0.2009

0.2344

0.2215

0.2077

0.2267

0.2425

0.2149

0.2219

0.2517

0.2500

0.1955

0.2258

0.2051

0.2075

0.2355

0.2131

0.1845

0.2382

0.2109

0.1991

0.2025

0.2250

0.1997

7/11/2018 7:16 AM ~Y/ rL Page 1 of 1 •1,-/() jc:7

UCL

0.2357

0.2216

0.2144

0.2421

0.2425

0.2193

0.2518

0.2369

0.2193

0.5958

0.2551

0.2304

0.2329

0.2679

0.2622

0.2086

0.2830

0.2584

0.2603

0.2963

0.2779

0.1915

0.2452

0.2200

0.2078

0.2109 I

0.2345

0.2079

0267


Detector

LB4110A - Al

LB411(,A - A2

LB411CA - A3

LB411CA - A4

LB411CA - Bl

LB411CA - B2

LB411CA - B3

LB411CA - B4

LB411CA - Cl

LB411CA - C2

LB411CA - C3

LB411CA - C4

LB4110A - D1

LB4110A - D2

LB4110A - D3

LB4110A. - D4

LB4110A - El

LB4110A - E2

LB4110A - E3

LB4110A - E4

LB4110A - Fl

LB4110A - F2

LB4110A. - F3

LB4110A. - F4

LB4110A - Gl

LB4110A - G2

LB4110/\ - G3

LB4110i'\ - G4


Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017

Beta 11/2/2017


Count Date Eff

7/11/2018 0.5488

7/11/2018 0.4709

7/11/2018 0.4783

7/11/2018 0.5486

7/11/2018 0.5288

7/11/2018 0.4978

7/11/2018 0.5971

7/11/2018 0.5322

7/11/2018 0.4772

7/11/2018 0.5198

7/11/2018 0.6054

7/11/2018 0.5120

7/11/2018 0.6424

7/11/2018 0.6435

7/11/2018 0.6387

7/11/2018 0.5044

3/23/2018 0.0436

3/23/2018 0.0428

3/23/2018 0.0551

3/23/2018 0.0569

7/11/2018 0.5376

7/11/2018 0.4733

7/11/2018 0.6204

7/11/2018 0.5353

7/11/2018 0.4446

7/11/2018 0.4920

7/11/2018 0.5425

7/11/2018 0.4838

PFW

p

p

p

p

p

p

p

p

p

p

p

p

p

p

p

p

F

F

F

F p

p

p

p

p

p

p

p

Printed: 7/11/2018 7:16 AM l? Page 1 of 1-::j- /\ \ /\ ~

LCL Mean UCL

0.5123 0.5366 0.5609

0.4286 0.4633 0.4980

0.4424 0.4784 0.5143

0.5061 0.5417 0.5774

0.4983 0.5384 0.5785

0.4605 0.4994 0.5384

0.5434 0.5818 0.6202

0.5062 0.5441 0.5821

0.4452 0.4808 0.5164

0.4955 0.5192 0.5430

0.5691 0.5995 0.6300

0.4857 0.5257 0.5657

0.6208 0.6409 0.6610

0.6033 0.6440 0.6847

0.6135 0.6418 0.6700

0.4764 0.5026 0.5288

0.4162 0.5409 0.6655

0.3730 0.4913 0.6097

0.3852 0.4994 0.6137

0.4534 0.5890 0.7247

0.3683 0.5285 0.6886

0.4416 0.4611 0.4806

0.5950 0.6145 0.6339

0.5178 0.5344 0.5509

0.4391 0.4582 0.4773

0.4753 0.4875 0.4996

0.5234 0.5438 0.5642

0.4688 0.4870 0.5053

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