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a.k.a. What to do when things dont work out quite the way you thought they would.

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'Twas the night to make crystals, and all through the hood, Compounds were reacting; As I'd hoped that they would. The hood door I'd closed with the greatest of care, To keep noxious vapors from fouling the air. The reflux condensor was hooked to the tap, And the high vacuum pump had a freshly filled trap. I patiently waited to finish my task, While boiling chips merrily danced in the flask. Then from the pump there arose such a clatter, That I sprang from my chair to see what was the matter. Away to the fume hood! Up with the door! And half my product foamed out on the floor.

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Then what to my watering eyes should appear, But a viscous black oil which had once been so clear. I turned the pump off in a terrible rush, And the oil that sucked back filled the line up with mush. The ether boiled out of the flask with a splash, And hitting the mantle went up with a flash. My nose turned quite ruddy, my eyebrows went bare, The blast had singed off nearly half of my hair. I shut the hood door with a violent wrench, As acid burned holes in the floor and the bench. I flushed it with water, and to my dismay, Found sodium hydride had spilled in to the fray.

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And then the fire got way out of hand, I managed to quench it with buckets of sand. With aqueous base I diluted the crud, Then shoveled up seven big buckets of mud. I extracted the slurry again and again With ether and then with dichloromethane. Chromatographic techniques were applied Several times 'til the product had been purified. I finally viewed with a satisfied smile, One half a gram in a shiny new vial. I mailed the yield report to my boss, Ninety percent (allowing for loss). "Good work," said the boss in the answering mail, "Use same condition on a preparative scale."

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Time Concentration N 2 (g) + 3 H 2 (g) 2 NH 3 (g) H2H2 NH 3 N2N2 Percent Yield 2 L 4 L 2 L = 2/4 x 100 = 50% 6 L

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Example: What is the percent yield of the reaction below if 2.5g of hydrogen gas only produces 18.0 g of water? 2 H 2 + O 2 2 H 2 O Step 1: Calculate the gfm of H 2 and H 2 O and write them under the grams line in your stoichiometry chart. 2.016 g/mol18.015 g/mol Step 2: Calculate how many grams of water would be formed from the 2.5 g of hydrogen. 2.5 g Step 3: Divide what was obtained experimentally (18.0 g H 2 O) by the theoretical yield of water and multiply by 100. 22.4 g Theoretical yield g: gfm: mol:1.24 mol x