additional information urmila chemopharma private limited list … · ash content % 35 sulphur...

Additional Information Urmila Chemopharma Private Limited

Prepared By Rightsource Industrial Solutions Pvt. Ltd.

LIST OF ANNEXURES

S. No. Content Annexure 1 List of Proposed Products Annexure-I 2 Site Plan Annexure-II 3 Manufacturing Process Description Annexure-III 4 Water Consumption Details Annexure-IV 5 Solid & Hazardous waste generation & Disposal method Annexure – V 6 Stack Emission details Annexure-VI 7 Process Emission details Annexure-VII 8 List of Raw Materials Annexure-VIII 9 Waste water Details Annexure-IX

10 Consolidated Statement – Pollution Details Annexure-X



Annexure-I

LIST OF PRODUCTS & QUANTITIES

S. No Name of the Product Quantity in Kg/Month

Quantity in Kg/Day

1 3,5Dimethyl–Nitro pyridine – N-Oxide 5000.00 166.66

2 3-Carbamoylmethyl-5-Methyl-hexanoic acid 5000.00 166.66

Total 10000.00 333.32



Annexure-II



Annexure-III

3, 5 Dimethyl 4-Nitro pyridine N-Oxide

Route of Synthesis:

Stage-1:

N

CH3H3CN

CH3H3C

3,5 LutidineO

3,5 di methyl pyridine n-Oxide

C7H9N107.15

123.15

C7H9NO

+ H2O2

34.03

Hydrogen peroxide

+ H2O

18.02

Acetic acid

Stage-2:

N

CH3H3C

O3,5 Dimethyl pyridine n-Oxide

123.15C7H9NO

+

+

HNO3 H2SO4+

Nitric Acid Sulfuric acid

63.01 98.08

N

CH3H3C

O

NO2

(NH4)2SO4 +

3,5 Dimethyl-4-nitro pyridine n-Oxide

168.15

C7H8N2O3

Ammonium Sulphate

132.14

+ 2NH3

34.06

Ammonia

18.02

H2O



Flow Chart:

Stage-1

Stage-2

3,5 Lutidine Hydrogen peroxide (50%)Acetic acid

Acetic acid Recovery

Stage-1Nitric acid (72%)Sulphuric acid Ammonia

Effluent water

3, 5 Dimethyl 4-Nitro pyridine N-Oxide

Material Balance:

Material balance of 3, 5 Dimethyl 4-Nitro pyridine N-Oxide Stage-1

Batch Size: 500.0.0 Kg Name of the input Quantity

in Kg Name of the out put Quantity

In Kg 3,5 Lutidine 394.00 Stage-1 407.00 Hydrogen peroxide (50%) 300.00 Acetic acid Recovery 285.00 Acetic acid 300.00 Acetic acid loss 6.00 Generated water 211.26,

Hydrogen peroxide-50 261.26

Organic residue process residue-25.74 Distillation residue -9 (Acetic acid)

34.74

Total 994.00 Total 994.00



Material balance of 3, 5 Dimethyl 4-Nitro pyridine N-Oxide Stage-2

Batch Size: 500.0.0 Kg Name of the input Quantity


In Kg Stage-1 407.00 3, 5 Dimethyl 4-Nitro pyridine N-

Oxide 500.00

Nitric acid (72%) 788.00 By product

(Ammonium sulphate-2000) 2000.00

Sulphuric acid 1550.00

Effluent water (Water-1531, Nitric acid water -577.20,Ammonium Sulphate -88, Generated water -59.54

2255.74

Ammonia 550.00 Organic residue 39.26 Water 1500.00

Total 4795.00 Total 4795.00

3-CARBAMOYLMETHYL-5-METHYLHEXANOIC ACID

Route of Synthesis:

Stage-1:

Isovaleradehyde

+

NC

H2N OCN

NH2

O

C11H16N4O2

236.27

2,4-Dicyano-3-isobutyl-pentanedioic acid

diamideC5H10O

86.13C3H4N2O

2 X 84.08=168.16

Piperdine & water + H2O

18.02

H3C

CH3

H

O O

NH2

N

2-Cyano-acetamide



Stage-2

NC

H2N O CNNH2

O

C11H16N4O2

236.27

2,4-Dicyano-3-isobutyl-pentanedioic acid

diamide

HO O

OH

O

+

3-Isobutyl-pentanedioic acid

C9H16O4

188.22

+ 2 (NH4)2SO42 H2SO4

196.16

6H2O

+ 2CO2

88.02

108.09

+ Toluene

2 X132.14=264.28

Stage-3

Step-A

HO O

OH

O

3-Isobutyl-pentanedioic acid

C9H16O4

188.22

NH

OO

4-Isobutyl-piperidine-2,6-dione

+

C9H15NO2

169.22

+

H2O

18.02

Urea

NH2

O

H2N

CH4N2O

60.06

NH3

17.03+ CO2

44.01

+



Step-B

NH

OO

4-Isobutyl-piperidine-2,6-dione

OHO

O

NH2

C9H15NO2

169.22

3-Carbamoylmethyl-5-methyl-hexanoic acid

C9H17NO3

187.24

NaOH+ + HCl

40.00 36.46NaCl+58.44

Water

Flow Chart:

Stage-1

Stage-2

Isovaleraldehyde CyanocetamidePiperdine

Stage-1 product with water

Stage-1product with water, Sulphuric acid Toluene

Toluene Recovery

Stage-3

Stage-2Urea Activated carbon EDTA Hydrose Sodium hydroxide Hydrochloric acid (40%)Water

Effluent water

3-carbamoylmethyl-5-methylhexanoic acid



Material Balance

Material balance of 3-carbamoylmethyl-5-methylhexanoic acid Stage-1

Batch Size: 624 Kg Name of the input Quantity


In Kg Isovaleraldehyde 354.00 Stage-1product with water 2757.91 Cyanocetamide 69.11 Piperdine 14.80 Water 2320.00 Total 2757.91 Total 2757.91


Batch Size: 624.0 Kg Name of the input Quantity


In Kg Stage-1product with water 2757.91 Stage-2 696.00 Sulphuric acid 1750.00 Toluene recovery 960.00 Toluene 1000.00 Toluene loss 20.00 By product

(Ammonium sulphate-1080 Spent Sulphuric acid(40%)-2360)

3440.00

Process Emission Carbon dioxide -361.76

361.76

Organic residue Process residue -10.15 Distillation residue -20

30.15

Total 5507.91 Total 5507.91




Batch Size: 624.00 Kg Name of the input Quantity


In Kg Stage-2 696.00 3-carbamoylmethyl-5

methylhexanoic acid 624.00

Urea 222.00

Effluent water (Water-1000, EDTA-1, Hydrose-1, Sodium chloride-216.15, Water form hydrochloric acid -288.10, Generated water-66.60)

1572.85

Activated carbon 10.00 Process emission (Ammonia-62.91, Carbon dioxide-162.72)

225.63

EDTA 1.00 Spent carbon 10.00 Hydrose 1.00 Process residue

(organic residue) 77.52

Sodium hydroxide 150.00 Hydrochloric acid (33%) 430.00 Water 1000.00 Total 2510 2510



Annexure-IV

WATER CONSUMPTION DETAILS

S. No Purpose Water input KLD 1 Process 1.61 2 Washings 3.00 3 Boiler make up 12.00 4 Cooling towers make up 11.00 5 Scrubbing system 3.00 6 Domestic 3.00 7 Gardening 2.00

Total 35.61



Annexure-V

HAZARDOUS &SOLID WASTE GENERATION DETAILS & DISPOSAL METHOD

S. No Name of the Hazardous Waste

Quantity Kg/Day Disposal Method

1 Organic Solid Waste 50.89 Sent to Cement Industries

2 Spent Carbon 3.33 3 Solvent distillation residue 9.67 4 ETP Sludge 20.00 Sent to TSDF

5 Inorganic solid waste 0.00 6

Used Oils 500.00 Ltrs /Annum

SPCB Authorized Agencies for Reprocessing/Recycling

7 Detoxified Containers

300.00 No s/month

After Detoxification sent back to suppliers/sent to outside Parties

8 Used Lead Acid Batteries 2.00 Nos /Annum

Sent back to suppliers on buyback basis

9 Fly ash from boiler 1400.00 Sent to Brick Manufacturers



Annexure-VI

STACK EMISSION FOR BOILER

Particulars Units 2.0 TPH Coal fired Boiler

Type of Fuel -- Indian Coal Coal Consumption TPD 5.0 Ash Content % 35 Sulphur Content % 0.4 Nitrogen Content % 1.0 No. of Stacks No. 1 Height of stack m 30 Diameter of Stack m 0.5 Temperature of Flue Gas oC 125 Velocity of Flue Gas m/s 15 Particulate Matter at outlet of Bag filter (Based on 115 mg/Nm3 at outlet)

gm/sec 0.20

Sulphur dioxide emission gm/sec 0.46 Oxides of Nitrogen emission gm/sec 1.89

STACK EMISSION DETAILS FOR DG SET

Capacity In KVA

Emission of SPM in mg/Nm3

Emission Of SO2 in mg/Nm3

Emission of NOx

in mg/Nm3

Stack dia. in m

Flue Gas Temp. in

OC

Stack Height in m

Flue gas Velocity in m/sec.

125 KVA 33 55 68 0.15 110 10 9.25



Annexure-VII

PROCESS EMISSION DETAILS

S. No Name of the Gas Quantity in Kg/Day Mitigation Method

1 Carbon dioxide 174.83 Dispersed into the atmosphere

2 Ammonia 20.97 Scrubbed by using Chilled water media



Annexure-VIII

1. 3,5Dimethyl–Nitro pyridine – N-Oxide

LIST OF RAW MATERIALS

S. No.

Raw Material Consumption/ Batch in Kgs

Consumption/ Day in Kgs

1 3,5 Lutidine 394.00 131.33 2 Hydrogen peroxide (50%) 300.00 100.00 3 Acetic acid 300.00 100.00 4 Nitric acid (72%) 788.00 262.67 5 Sulphuric acid 1550.00 516.67 6 Ammonia 550.00 183.33

2. 3-Carbamoylmethyl-5-Methyl-hexanoic acid

LIST OF RAW MATERIALS

S. No. Raw Material Consumption/ Batch in Kgs

Consumption/ Day in Kgs

1 Isovaleraldehyde 354.00 118.00 2 Cyanocetamide 69.11 23.04 3 Piperdine 14.80 4.93 4 Sulphuric acid 1750.00 583.33 5 Toluene 1000.00 333.33 6 Urea 222.00 74.00 7 Activated carbon 10.00 3.33 8 EDTA 1.00 0.33 9 Hydrose 1.00 0.33

10 Sodium hydroxide 150.00 50.00 11 Hydrochloric acid (33%) 430.00 143.33



Annexure-IX

WASTE WATER DETAILS

S. No Purpose Effluent

Details KLD 1 Process 1.36 2 Washings 3.00

3 Boiler Blow down 2.00

4 Cooling towers Blow down 1.00

5 Scrubbing system 3.00 6 Domestic 2.50

Total 12.86

HTDS & LTDS Effluent DETAILS, Disposal Method

S. No Purpose HTDS KLD

LTDS KLD Disposal method

1 Process 1.28 0.09

After pre Treatment sent to Green field CETP Pvt Ltd,

Chincholi, MIDC

2 Washings 0.00 3.00 3 Boiler Blow down 0.00 2.00

4 Cooling towers blow down 0.00 1.00

5 Scrubbing system 3.00 0.00 6 Domestic 0.00 2.50

Total 4.28 8.59 12.86



Annexure-X

S. No Product Name

Production capacity

Kg/ Month

Kg Per Day EFFLUENT WATER SOLID WASTE EMISSIONS

Water Input

Water In effluent

Inorganics In

Effluent

Organics In

Effluent TDS COD HTDS LTDS Total

Effluent Organic Inorganic Spent Carbon

Distillation Residue

Process emissions

Fugitive loss

1 3,5Dimethyl–Nitro pyridine – N-Oxide

5000.00 500.00 793.00 46.00 0.00 46.00 0.00 751.91 87.09 839.00 21.67 0.00 0.00 3.00 0.00 2.00

2 3-Carbamoylmethyl-5-Methyl-hexanoic acid

5000.00 1106.67 355.87 168.08 0.33 168.08 0.38 524.28 0.00 524.28 29.22 0.00 3.33 6.67 195.80 6.67

Total 10000.00 1606.67 1148.87 214.08 0.33 214.08 0.38 1276.20 87.09 1363.28 50.89 0.00 3.33 9.67 195.80 8.67

Production/Month Water Input TDS Total Effluent Organic Inorganic

Spent Carbon



LIST OF ENCLOSURES

S. No. Content Enclosures 1 Land Documents Enclosure-1