9th presentation eng coal2012 conference rev2

8/10/2019 9th Presentation Eng Coal2012 Conference Rev2

1/36

Confidential

Copyright

LurgiGm

bH

2011

2011

Air Liquide Engineering & Construction

for the Mongolian coal industry

ULAANBAATAR, 9TH OF FEBRUARY 2012

14:50-15:10 Rev 2


2/36

2Confidential

Copyright

LurgiGm

bH

2011

AIR LIQUIDE : Our Offer at a Glance

LURGI FBDB Gasification Process

The Next Generation Technologies for Clean Syngas

Improved Rectisol Process & Zero Sulfur

Energy-efficient Ammonia Syngas Syngas Product Technologies

Enhanced Lurgi SNG

Lurgi Methanol Integrated GTL.F1 Liquid Fuels

Next Step AIR LIQUIDE Contribution

Outline


3/36

3Confidential

Copyright

LurgiGm

bH

2011

Lurgi New Gasification Module Mark +

AIR LIQUIDE: Our Offer at a Glance


4/36

4Confidential

Copyright

LurgiGm

bH

2011

Global Portfolio

Hydrogen/SyngasLurgiReformer,MPGGasifier,ATR,

LurgiFBDB,CoGen

Hydrogen

RecoveryMEDALmembranes,ColdBox,PSA

Oxygen/NitrogenASU,Membrane

SulphurRecoveryOxy

Claus,

Tail

Gas

Treating

LTGT,

MAXISULF,AQUISULF,OMNISULF,

SULFREEN,HYDROSULFREEN

PetrochemicalsEPTA,AcrylicAcid,Butadiene,PA,Olefins,

Polymers,Distapex(Aromatics)

CO2Recovery

/Gas

CleaningCompressionandPurificationUnit

Shift,AmineWash,Rectisol,Purisol

ChemicalConversionMethanol,Megamethanol,MTP,Melamine

Biofuels

/

Oleochemicals

Consulting

Feasibility

Studies

Global

Procurement

BasicandDetailEngineering

AuthorityEngineering

Project

Management

Construction/Management

Revamping/Retrofitting

Technical

Services

GasSupply Technologies Engineering

H2Hydrogen

O2OxygenN2Nitrogen

UtilitiesSteam,

power,

demineralized

water&compresseddryair

CO2forwatertreatment

SpecialtyGases


5/36

1Confidential

Copyright

LurgiGm

bH

2011

Manufacturing workshops Engineering centers

Air Liquide Engineering & Construction


6/366Confidential

Copyright

LurgiGm

bH

2011

H2 forRefineries

SMRs

Fertilizers

Chemicals

Power

SNG

CO2

Sulfur

Turbine

Methanation

N2 Wash + H2

Fischer-Tropsch

Methanol

Synthesis

ChemicalSynthesis

DME/MTP

Syngas for DRI

Raw

MaterialSyngas Final Products

Sulfur

Recovery

CO

Cold Box

PSA /

Mem-brane

CO Shif t

(Sulfur)Rectiso

l Stage

1

ProcessesSyngas Purification

Residue

Natural

Gas

Coal

Biomass

AL and Lurg iCapability

ASU

Gasification

FBDB/MPG

Reforming

Technology Portfolio

Clean Conversion Processes

(CO2)

Rectiso

l Stage

1

Synfuels


7/367Confidential

Copyright

LurgiGm

bH

2011

Ai r Liquide

ASU

Integrated Lurgi Coal Gas Island

Lurgi

GLS Process

Lurgi Phenosolvan & CLL

Gas Liquor Recovery and Water Treatment

Liquid Ammonia

Treated Water

Lurgi Rectisol

GasPurification

Lurgi OxyClaus

Sulfur Recovery

Elemental Sulfur

CO2

HP Steam

Syngas

Ai r Liquide

LNW Unit

N2

Lurgi

Methanation

Ammonia Syngas

SNG

(Fuel Gas)

(Rectisol Naphtha)

(Phenols)

(Clear Tar / Oil)

Lurgi MPG

Gasification

Lurgi FBDB

Gasification

Lurgi

CO Shift &Gas Cooling

Coal

Preparation

HP Steam

Ash


8/368Confidential

Copyright

LurgiGm

bH

2011

Lurgi FBDBTM Gasification Island

Typical Footprint

Gas Cooling

Gasification Modules

Gas Liquor Separation

Rectisol

SRU

Phenosolvan

Lurgi CLLTM


9/369Confidential

Copyright

LurgiGm

bH

2011


LURGI Coal Technologies

LURGI FBDBTM Gasification Process


10/3610Confidential

Copyright

LurgiGm

bH

2011

Coal is widely Dispersed in the World and provides countries with a

Strategic Energy Security Component

Gasif ication produces a Valuable Synthesis Gas for the production

of Chemicals, Petrochemical, Fuels and Power

Gasification can meet the Most Stringent Environmental Standards

World Bank Standards (for Financing Needs)

Country Specifications (for Permitting Requirements)

Applied to Gaseous, Water and Solids Emissions

Helps in dealing with the Carbon Dioxide Issue

Lurgis Fixed Bed Dry Bottom Technology is well placed to Meet the

Demands of the Market Place

Rationale for Lurgi Coal Gasif ication


11/3611Confidential

Copyright

LurgiGm

bH

2011

Mark +

Lurgi FBDBTM Benefits of Mk+ - Gasifier

Higher efficiency & reduced cost of eg. SNG

Lower specific coal, steam & oxygen consumptions

Higher specific byproduct values

Number of pieces of equipment greatly reduced

Reduced downstream capex due to higher operating pressure

Reduced capex due to less gas liquor c irculation


12/3612Confidential

Copyright

LurgiGm

bH

2011

Coal

Preparation

Lurgi

FBDBTM Gasification

Unit 03

Gas Cooling

Unit 04

Elemental Sulphur

CO2 Rich Gas

Rectisol Naphtha

Liquid Ammonia

Phenols

Tar / Oil

Ash Handling

Gas Liquor

Separation

Unit 05

Phenosolvan

Unit 06

NH3 Recovery

Unit 07

Gas

Purification

(Rectisol)

Unit 08

Sulphur

Management

Unit 09Recompres.

Unit 03

No Emissions (start-up, normal,

emergency cases)Efficient Waste Heat Recovery

Emissions

Any water effluent compliant to most stringent regulations

Re-use the water in the process as BFW

Waste Water

Treatment

Bolier

Feed

Water

ASU

Syngas

Environment Emissions and Effluents

Coarse non-hazardous

Construction


13/3613Confidential

Copyright

LurgiGm

bH

2011


LURGI Technologies for Clean Syngas -

Improved Rectisol Process


14/3614Confidential

Copyright

LurgiGm

bH

2011

Lurgi Rectisol

The 5 in 1 Solution

Feed Stock

Syn Gas

Gasification

Sulfur

Removal

CO2Removal

Sulfur

RecoveryH2S

CO2

CO2CO2

CompressorCO2

Treatment

Acid Gas

Enrichment

Trace

Removal

COSHydrolysis

Syngas suitable forcatalytic synthesis

processes

CO2 suitable forcompression, synthesis,

or venting

1. Trace contaminant removal

2. Deep Desulfurization

3. Bulk CO2 removal

4. CO2 purificationCO2 Capture Ready

5. Acid Gas Enrichment

Acid gas suitable forsulfur recovery

processes


15/3615C

onfidential

Copyright

LurgiGm

bH

2011

Intensive Redevelopment Since 2009

Operational Expenses Reduced by 30%

Result: New contract every 2 months

Rectisol Improvement Program

Results

-10% OPEX

Capex saving

Capex saving

-10% OPEX

-10% to 20%OPEX

Re-assessment and validation

of thermodynamics

Validation of Equipment

Efficiencies of trays

Application of packings

(where no fouling occurs)

Heat exchanger with small pinch

(where no fouling occurs)

Modfied heat integration


16/3616C

onfidential

Copyright

LurgiGm

bH

2011


Lurgis Sulfur Removal Technology

Zero Emission Concept


17/3617C

onfidential

Copyright

LurgiGm

bH

2011

Sulfur Recovery

97 % Claus with

two catalytical stages

98 % Claus with

three catalytic stages

99,0 99,6%

Claus withtwo cat. stages plus

Sulfreen / Hydrosulfreen

99,9% Claus with

two catalytic stages plus LTGT 100,0% Tailgas recycle

(Emission Free Claus)

Sulfur Recovery Concepts

China:

Acc. GB16297-1996:

99.8%


18/3618C

onfidential

Copyright

LurgiGm

bH

2011

96 % 97% 98% 99% 99,3% 99,5% 99,8% 99,9% 100 %100

Sulphur Recovery

Co

stIndex

2-Rx

Claus

3-Rx

Claus

2Rx + LTGT

Including Regeneration

Emission

Free Design

Lurgi OxyClaus Technology

Emissions Free Total Investment Costs

200


19/3619C

onfidential

Copyright

LurgiGm

bH

2011


Air Liquide Cryogenics Technologies for

Ammonia Syngas


20/3620C

onfidential

Copyright

LurgiGm

bH

2011

Nitrogen Wash Unit


21/36

21Confidential

Copyright

LurgiGm

bH

2011

Typical Cold Box System


22/36

22Confidential

Copyright

LurgiGm

bH

2011

Air Liquide Cold Box References


23/36

23Confidential

Copyright

LurgiGmbH

2011

Lurgis Poly-generation Vision

MARKET DRIVEN

Coal

processing

Steam / power

generation

Utilities

and

amenities

MODULAR ECONOMY OF SCALE

ASU

Oxygen

FBDB

Gasification

FBDB

Gasification

MPG

Gasification

Gas

Work-up(Rectisol plus)

Liquid

Work-up

(GLS plus)

INFRASTRUCTURE

SYNGAS ISLAND

SNG

Methanol

CTL

DRI

FBDB

Gasification

FBDB

Gasification

Power

Ammonia

FBDB

Gasification

FBDB

Gasification

ASU

Oxygen

DME

Acrylic Acid

MTO

MTG

MTPPolypropylene

Etc


24/36

24Confidential

Copyright

LurgiGmbH

2011


LURGI Technologies for SNG Route

Enhanced Methanation Process


25/36

25Confidential

Copyright

LurgiGmbH

2011

Enhanced Methanation Technology -

Gains

Higher Maximum Operating Temperature Allows

Generation of Higher Temperature Steam

Improved OPEX

Reduced Recycle Gas Flow (Smaller Capex)

Choice Between Medium Temperature and High Temperature Processes

Flexibility of Methanation Process to Upstream Gasification, Steam Production Needs

Medium Temperature

Methanation

High Temperature

Methanation

Catalyst G1 85 HT G1 - 85

Maximum Temperature (Deg C) 480 650

Guaranteed Catalyst Life (Years) 3 2

Recycle Compressor (Volume) 100 % 70%

Power Consumption 100 % 40%

Steam Superheating Temp. (Deg C) 460 510


26/36

26Confidential

Copyright

LurgiGmbH

2011

Design of High Temperature and

Low Delta Pressure

Methanation ProcessWith Ensured Link to

Commercial Reference

Performance of HT G1-85 in

Pilot Plant (650C Maximum

Temperature)

Low Pressure Drop Catalyst

Mech. StabilityActivity

G1-85 Operation in

Dakota Gasification

(480C Max Temp.)

Performance of

G1-85 in Pilot Plant

(480C Max. Temp.)

Low Pressure Drop

Catalyst

Mech.

Stability

Activity

Enhanced Methanation Technology -

Validated


27/36

27Confidential

Copyright

LurgiGmbH

2011

Lurgis Methanol Technology


28/36

28Confidential

Copyright

LurgiGmbH

2011

1969 First LP-Methanol Catalyst Test

1970 Cooperation with Sd-Chemie for Catalyst 1970

Operation of 100 Tubes-Reactor Demonstration Unit

1972 First 3 LP-Methanol Plants in Operation

1997 MegaMethanolTM Concept Published

2006 Six contracts awarded for MegaMethanolTM

plants

2011 Six MegaMethanolTM plants in operation

LURGIs Methanol Technology Milestones


29/36

29Confidential

Copyright

LurgiGmbH

2011

Feedstock Natural Gas

31 Plants with a total capacity of 21.40 MMTPY

thereof 17 Plants using Conventional Steam Reforming

13 Plants using Combined Reforming

1 Plant using Autothermal Reforming

Feedstock Natural Gas plus Naphtha4 Plants with a total capacity of 0.60 MMTPY

Feedstock Coal Gas7 Plants with a total capacity of 4.90 MMTPY

Feedstock Heavy Residue7 Plants with a total capacity of 2.00MMTPY

Total : 50 Plants with a total capacity of 29.90 MMTPY

Syngas Options

Possible Feedstocks


30/36

30Confidential

Copyright

LurgiGmbH

2011


AIR LIQUIDE Liquid Fuels Development


31/36

31Confidential

Copyright

LurgiGmbH

2011

GTL.F1 AG

The Company

Operated by Lurgi GmbH partnered by PetroSA

1986 Start of F-T technology development by Statoil 1987/88 First catalyst and reactor patents

2002-08 Construction/ operation Semi-commercial demo

2009/10 Award of first F-T & Upgrading project

The Technologies

Fischer-Tropsch Technology based on

- advanced Slurry Bubble Column Reactor concept

- proprietary Cobalt catalyst

Integrates

- Air Liquide/Lurgis technology portfolio for syngas production & purification

- Proprietary FT technology

- Integrated upgrading technology from third party

FT Demo-Unit Mossel Bay


32/36

32Confidential

Copyright

LurgiGmbH

2011

Ai r Liquide

ASU

CTL: Integration and Options

Lurgi

GLS Process

Lurgi Phenosolvan & CLL

Gas Liquor Recovery and Water Treatment

Lurgi Rectisol

GasPurification

Lurgi OxyClaus

Sulfur Recovery

GTL.F1

Synthesis

GTL.F1

Fuel Workup

Lurgi ATR

Lurgi FBDB

Gasification

Lurgi

CO Shift &

Gas Cooling


33/36

33Confidential

Copyright

LurgiGmbH

2011


AIR LIQUIDE Engineering Capability


34/36

34Confidential

Copyright

LurgiGmbH

2011

Project Execution Expertise

Typical Cost Reduction Potentials

HIGH

LOW

START COMPLETE

Cost Reduction Potentials

Abilityto

Inf

luenceCost

Conceptual Planning

Design

Procurement

Construction

Start-up

Time

Lurgi has considerable experience in value engineering and life cycle costoptimization.

Cost reductions can be realized by early involvement during conceptualengineering, bankable feasibility study and front-end engineering.


35/36

35Confidential

Copyright

LurgiGmbH

2011

Characterization of the Coal

Air Liquide Frankfurt Research & Technology Center (FRTC) ensures Proper Coal

Characterization, key to

The Gasifier Downstream CO Shift, Rectisol, SRU, Synthesis Products

Water Optimisation

Studies

Project Feasibility (Process Configuration: Coal to Product)

Project Economics (CAPEX/OPEX)

Environmental Impact of the Processes

Scheduling

Purchasing Optimization

Licensing and Engineering and Procurement Services

Next Steps


36/36

fidentialCopyright

LurgiGmbH

2011


Thank you for your interest.

For more details please contact us:

CONTACT:

Deepak WADHWA - [email protected]

Vice President E&C Sales, North & Southeast Asia Pacific & India

PRESENTER:

Daniel VAN DER MERWE - [email protected]

Lurgi Solutions Development Manager, Engineering Services Asia

9th presentation eng coal2012 conference rev2

Documents