4.1 atomic structure - high demand - ms€¦ · page 1 of 22 4.1 atomic structure - high demand –...

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4.1 Atomic structure - High demand – Mark schemes

Q1. (a) both have 6 electrons

1

both have 6 protons 1

carbon-12 contains 6 neutrons but carbon-14 contains 8 neutrons allow carbon-14 has 2 more neutrons

1

(b) 1

(20 × 2 × 2 × 2 =) 160 an answer of 160 scores 2 marks

1

(c) carbon-14 is in (some) carbon dioxide (in air) 1

carbon-14 / carbon dioxide taken in (by plants) in photosynthesis 1

becomes part of glucose / starch / carbohydrate 1

plant eaten by humans / herbivores / passed up food chain allow carbon compounds passed up food chain

1

starch is digested or glucose diffuses into cells or glucose stored as glycogen in cells

1 [10]

Q2. (a) electromagnetic radiation from the nucleus

‘electromagnetic radiation’ is insufficient 1

(b) (Gamma is the most penetrating) so a large proportion of the emitted radiation will leave the body

1

more easily detected outside the body 1

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(c) (average) time it takes for the number of nuclei of the isotope in a sample to halve

or

(average) time it takes for the count rate from a sample containing the isotope to fall to half its initial level

1

(d) initially there is a high level of hazard. 1

level of hazard drops to a low level quickly 1

answer must imply short period of time

(activity initially high) due to short half-life

or

(drops to safe level quickly) due to short half-life 1

(e) it is exposed to ionising radiation 1

(f) does not become radioactive 1

[9]

Q3. (i) (fast moving) electrons (from the nucleus)

(allow negatively charged particles) for 1 mark

1

(ii) protactinium has one neutron fewer protactinium has one proton more (credit has different numbers of neutrons / protons with one mark)

for 1 mark each 2

[3]

Q4. (a) indication (in writing or on graph) of finding point where radiation

is halved (e.g. to 24 [from an initial 48]) and relating to the time difference between the two points

gains 1 mark

but 4.2-4.8* (*i.e. in this range, including extremes)

gains 2 marks

units billions of years for 1 mark

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3

(b) ¾ or 75% [allow ecf from (a)]

for 1 mark 1

(c) (i) idea that the intermediate nuclides are relatively short-lived for 1 mark

1

(ii) idea that ¼ has decayed or ¾ remains gains 1 mark

but read graph for radiation level of 36 (stated or shown on graph itself)

gains 2 marks

but 1.6-1.8* (billion years) (* i.e. in this range, including extremes)

gains 3 marks 3

[8]

Q5. (a)

[Accept He2+ for α]

each for 1 mark 4

(b)

[Accept β for e]

each for 1 mark 4

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(c) (i) beta/ β alpha/ α alpha/ α beta/ β beta/ β but alpha/ α alpha/ α beta/ β [i.e. consistent for 1; consistent and correct for 2]

gains 2 marks 2

(ii) ideas that • many thorium atoms because they take so long to decay* • (many lead atoms because) the thorium has been decaying for so long/for billions of years or (because) the rock is so/very/billions of years of years old • many lead atoms because this is the stable end product [of the decay series] • few atoms of other isotopes because they decay so quickly*

[*N.B. credit answers in terms of half-life] any three for 1 mark each

3 [13]

Q6. neutron becomes proton / neutron emits electron / neutron emits beta particle

gains proton neutral [1]

Q7. (a) (i) two protons

1

2 neutrons if neither point gained allow 1 mark for helium nucleus

1

(ii) electron 1

(b) neutron splits (to form proton and electron) 1

[4]

Q8. (i) 7 or 8

1

correct data extracted from graph e.g. takes 8 days to drop from 50 to 25 allow appropriate annotation of graph

1

(ii) long enough to destroy cancer cells do not accept dangerous unqualified

1

but short enough to minimise damage to surrounding tissues

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1 [4]

Q9. (a) (i) two protons

1

2 neutrons if neither point gained allow 1 mark for helium nucleus

1

(ii) electron 1

(b) neutron splits (to form proton and electron) 1

[4]

Q10. (a) radium

accept Ra 1

(b) different numbers of protons accept one has 91 protons, one has 92 or Pa has 91 protons, U has 92 do not credit they have different atomic numbers reject different numbers of protons and neutrons

1

(c) alpha 1

(d) neutron changes into proton accept electron lost / beta radiation accept singular or plural answers

1 [4]

Q11. (a) (i) beta and gamma (any order)

for one mark 1

(ii) gamma for one mark

1

(b) (i) particles / atoms / molecules become charged / gain / lose electrons for one mark

1

(ii) e.g. to kill cancer cells (allow any use of alpha, beta or gamma or X- radiation) for one mark

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1

(c) (i) time taken for no. of atoms / no. of nuclei / mass of U238 / activity to halve – not radioactivity or time taken for count rate to halve

for one mark 1

(ii) atoms with unstable nuclei which emit radiation (not definition of isotope but isotope which is radioactive gets 1 mark)

for 1 mark each 2

(d) (i) 1 / 4 accept 25% or 0.25 for one mark

1

(ii) 2 × half life or 2 × 4500 million years (independent of (i)) gains 1 mark but

9000 million years ecf only if answer to (i) is etc. gains 2 marks

2 [10]

Q12. (a) nucleus positive charge / protons in nucleus electrons / negative charges

orbit nucleus each for 1 mark

3

(b) (i) positive dough repels positive alpha particles or 2 positive charges repel forces small

each for 1 mark 2

(ii) large force needed + ves in plum pudding spread out – may appear in (i)

positive charge must be concentrated / in nucleus (ignore references to electrons)

for 1 mark each 3

(c) 1, 0 X,–l (X = negligible / very small/(1/1840) (1/2000),but not nothing)

each row for 1 mark 2

(d) (i) 4 for 1 mark

1

(ii) B and C have the same number of protons / atomic number

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but different number of neutrons / mass number each for 1 mark

3 [14]

Q13. (a) 1.

-1 2

for 1 mark each

(b) (i) 19p, 20n, 19e

all correct for 2 marks 2 correct for 1 mark

2

(ii) K40 has an extra neutron/different number of neutrons/ it has more neutrons/21 neutrons

for 1 mark NOT fewer neutrons

1

(iii) radioactive/unstable nucleus/ nucleus disintegrates/ emits radiation/it has too many neutrons

for 1 mark 1

(iv) calcium/Ca for 1 mark

1

(v) 1 (e) in outer shell/same number of electrons/outer electron same distance from the nucleus

for 1 mark 1

(c) (i) Geiger-Muller tube (photographic) film for 1 mark

1

(ii) cancer, leukaemia, radiation sickness etc. for 1 mark

1 [10]

Q14. (a) decrease

for 1 mark 1

(b) (i) none would go through paper for 1 mark

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1

(ii) all would go through paper for 1 mark

1

(iii) only some absorbed/amount absorbed depends on thickness of paper

for 1 mark each 2

(c) 1 → 1/2 → 1/4 → 1/8 for 1 mark

3 half lives/3 × 433 for 1 mark

1299 years gains 3 marks

3 [8]

Q15. (a) (i) a helium nucleus

accept He accept 2 protons + 2 neutrons do not accept He do not accept helium atom

1

(ii) nucleus only answer, no alternative

1

(b) (i) each axis given a linear scale time axis must go up to 12 days y-axis must go up to 40 000

1

curve concave to axis drawn 1

curve shows correct half-life of four days do not accept a straight line must show one half-life check first two plotted points correct to half square a curve drawn dot-to-dot scores a maximum of 1mark

1

(ii) 38 750 no tolerance allow 1 mark for 5 half-lives allow 1 mark for showing that 1 250 are undecayed

3

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(c) (i) more radon enters shaft (through cracks in the rock face) accept radon emitted from surroundings

1

(ii) (alpha) radiation will damage cell structure or ionise cells accept kill cells

1

causing cancerous growth an answer in terms of the daughter product polonium being a solid or lodging in the throat and also emitting alpha gains full credit

1 [11]

Q16. (a) electron

accept e 1

(b) 5400 – 7000

horizontal line drawn corresponding to their halving 1

or

a cross in the correct position on the line 1

(c) count rate converted to 14.5/min for 1g mass accept 14.5 clearly marked on graph

1

decay time taken as 750 years ± 100 years accept 750 years clearly marked on graph

1

refer their answer to 837 years (or approximately 800 or a value 837 - 937 years)

no the shirt was made after he died (if numbers justify)

or

yes it could have been his shirt (if numbers justify) allow an alternative answer working backwards from 837 years

1 [6]

Q17. (a) (i) element with equal number of protons, different number neutrons

or same atomic/proton number different mass/nuclear number

1

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(ii) time taken for activity or count rate or number of nuclei to decrease to half accept parents atoms or radioactive isotope do not accept time taken for radioactivity/substance/ material to halve

1

(iii) 12 (s) 1

(b) (i) 22800 (years) allow 1 mark for iterative steps 80-40-20-10-5 or statement of 4 half-lives

2

(ii) decay (of carbon 14) over 150 years is insignificant accept very little decay accept change is too small

1

(c) either argument gains full credit accept any 3 valid points from for and/or against arguments

FOR

– massive dilution of waste – reduces concentration (within a given volume) to insignificant levels – distant from habitation

AGAINST

– pollution (of the sea/beach) – mutation or harm caused to living things (animals/plants) – effect on food chain – long period of time necessary

3 [9]

Q18.

(i) accept 0.25 or 25%

1

(ii) 2600 if answer to (c)(i) is ½ then accept 1300

1 [2]

Q19. (i) nucleus / neutron

do not accept shells or orbits 1

(ii) neutron changes to a proton or number of neutrons goes down 1

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and the number of protons goes up by 1 do not accept becomes positive

1 [2]

Q20. (a) (i) gamma hardly ionises the air

accept does not ionise accept gamma radiation is not charged do not accept answers in terms of danger of gamma or other properties

1

(ii) half-life (too) short accept need frequent replacement ‘it’ refers to curium-242

1

(iii) (two) fewer neutrons accept different numbers of neutrons if a number is specified it must be correct do not accept more neutrons unless curium-244 is specified

1

(b) (i) gamma accept correct symbol

1

(ii) both absorbed by the metal / steel / weld only scores if (b)(i) is correct accept cannot pass through the metal / steel / weld

1

(c) (i) put source into water at one point on bank accept the idea of testing different parts of the river bank at different times

1

see if radiation is detected in polluted area accept idea of tracing

1

(ii) 2.7 (days) allow 1 mark for showing correct use of the graph

2 [9]

Q21. (a) 146

1

(b) atomic number 1

(c) (i) alpha

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1

(ii) number of protons changes accept atomic number changes accept loses or gains protons do not accept protons with any other particle e.g. number of protons and neutrons changes incorrect do not accept any reference to mass number

1 [4]

Q22. (a) (i) (atoms / elements with) the same number of protons but different numbers

of neutrons accept (atoms / elements with) different mass number but same atomic number

1

(ii) substances that give out radiation accept alpha, beta or gamma for radiation accept an unstable nucleus that decays radioactive decay takes place is insufficient

1

(b) 85 years ± 2 years allow 1 mark for showing correct method on the graph

2

(c) (i) a helium nucleus accept 2 neutrons and 2 protons accept 2 4He do not accept helium atom

1

(ii) the rate of decay (of plutonium) decreases accept fewer (plutonium) nuclei (to decay) accept radioactivity decreases

1

less heat produced do not accept energy for heat

1

(d) (i) (outside the body)

alpha (particles) cannot penetrate into the body

(inside the body) 1

(heat produced from decay) damages / kills cells / tissues accept causes cancer for damages / kills cells / tissues accept highly toxic

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1

(ii) any one from:

• worried same could happen again

• an accident may cause radiation to be spread around the Earth / atmosphere

• idea of soil contamination resulting from accident / release of radioactive material

• idea of negative effect on health resulting from accident / release of radioactive material accept any sensible suggestion

1 [10]

Q23. (a) (i) alpha (particle)

1

(ii) (unstable) nucleus accept (unstable) nuclei do not accept middle do not accept helium nucleus

1

(iii) same number of protons accept same number of electrons accept same atomic / proton number accept they both have 92 protons same number of neutrons negates answer

1

(b) (i) 4500 million years do not accept 4500 years

1

(ii) curve starting at 100 000 with a correct general shape 1

passing through (4500, 50 000) and (9000, 25 000) allow 1 mark for points plotted or line passing through (4500, 50 000) and (9000, 25 000)

1 [6]

Q24. (a) (i) number of protons are the same

accept atomic number / number of electrons for number of protons

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1

number of neutrons are different accept mass numbers are different – only if the first mark is awarded

1

(ii) an electron from the nucleus both parts needed

1

(b) decays at the same rate as it is made accept decays as fast as it is made accept absorbed / used by plants (in CO2) at same rate as it is being made

1

(c) (i) 3500 no tolerance

1

(ii) adjusted age correctly obtained from the graph accept values between 3700–3800 inclusive accept their (c)(i) used correctly to obtain an adjusted age from the graph

1

adjusted age +50 second mark can only be scored if first mark awarded if no working shown an answer between 3750–3850 inclusive scores both marks note: any line or mark made on the graph counts as working out

1 [7]

Q25. (a) beta

1

alpha: would not pass through (the aluminium / foil) 1

gamma: no change in count rate when thickness changes must be a connection between detection / count rate / passing through and change in thickness

1

(b) foil thickness increases then decreases (then back to normal / correct thickness) a description of count rate changes is insufficient

1

gap between rollers decreases, then increases (then back to correct size) or pressure from rollers increases then decreases

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accept tightness for pressure answers may link change in thickness and gap width for full credit ie: foil thickness increases so gap between rollers decreases (1) foil thickness decreases so gap between rollers increases (1)

1

(c) 56 (years) accept any value between 55-57 inclusive allow 1 mark for correct calculation of mass remaining as 1.5 (micrograms) allow 1 mark for a mass of 4.5 micrograms plus correct use of graph with an answer of 12 maximum of 1 compensation mark can be awarded

2 [7]

Q26. (a) (i) (total) number of protons plus neutrons

accept number of nucleons accept amount for number do not accept number of particles in the nucleus

1

(ii) number of neutrons decreases by one 1

number of protons increases by one accept for both marks a neutron changes into a proton

1

(b) (i) 1

correct order only 1

(ii) the number of protons determines the element accept atomic number for number of protons

1

alpha and beta decay produce different changes to the number of protons there must be a comparison between alpha and beta which is more than a description of alpha and beta decay alone

or alpha and beta decay produce different atomic numbers

ignore correct reference to mass number 1

[7]

Q27. (a) has an equal amount of positive charge

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accept pudding/it is positive 1

(b) (experimental) results could not be explained using ‘plum pudding’ model or (experimental) results did not support plum pudding model

accept (experimental) results disproved plum pudding model 1

(c) (i) A – most of atom is empty spaceormost of atom concentrated at the centre 1

B – nucleus is positive (so repels alpha particles) accept nucleus has the same charge as alpha

1

C – nucleus is very small accept nucleus is positive if not scored for B

or nucleus is a concentrated mass

accept nucleus has a very concentrated charge 1

(ii) (if predictions correct, this) supports the new model answers should be in terms of the nuclear model accept supports his/new/nuclear theory accept proves for supports accept shows predictions/ Rutherford was correct

1 [6]

Q28. (a) B E G

all 3 required and no other any order

1

same number of / 88 protons (and different numbers of neutrons) same number of electrons is insufficient

1

(b) (i) 222 1

86 1

(ii) 4800 allow 1 mark for obtaining 3 half-lives

2

(c) ethical 1

deceived / lied to (about safety of working conditions)

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accept (women) not warned of the dangers given no protection is insufficient

or value own / scientists' lives more than women or did not treat women humanely

1

(d) accept any sensible suggestion eg too many interests in continued use of radium

evidence may cause public unrest do not accept not enough evidence

doctors not want to be blamed for illnesses (caused by radium) accept doctors not wanting to be sued (for harm caused by using radium)

doctors thought (possible) benefits outweighed (possible) risks do not accept did not know radium could be harmful believe radium could treat illnesses is insufficient

1 [9]

Q29. (a) 78

1

(b) atomic 1

(c) (i) 131 correct order only

1

54 1

(ii) 32 (days) allow 1 mark for showing 4 half-lives provided no subsequent step

2

(iii) limits amount of iodine-131 / radioactive iodine that can be absorbed accept increases level of non-radioactive iodine in thyroid do not accept cancels out iodine-131

1

so reducing risk of cancer (of the thyroid) accept stops risk of cancer (of the thyroid)

1 [8]

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Q30. (a) (i) splitting of a(n atomic) nucleus

do not accept splitting an atom 1

(ii) Neutron 1

(b) (i) nuclei have the same charge or nuclei are positive

accept protons have the same charge 1

(ii) (main sequence) star accept Sun or any correctly named star accept red (super) giant

1

(c) (i) any two from: • easy to obtain / extract • available in (very) large amounts • releases more energy (per kg)

do not accept figures only • produces little / no radioactive waste.

naturally occurring is insufficient seawater is renewable is insufficient less cost is insufficient

2

(ii) any one from: • makes another source of energy available • increases supply of electricity • able to meet global demand • less environmental damage • reduces amount of other fuels used.

accept any sensible suggestion accept a specific example accept a specific example

1

(d) 12 allow 1 mark for obtaining 3 half-lives

2 [9]

Q31. (a) (i) (atoms with the) same number of protons

allow same atomic number or same proton number

1

(atoms with) different number of neutrons allow different mass number

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1

(ii) 82 1

(iii) 124 1

(b) (i)

1 mark for each correct box 3

(ii) (a) neutron 1

(iii) 4.0 × 10-4 (s) or 0.0004

3.00 × 108 × 0.1 = 12 000 / t gains 1 mark

2

(iv) particles need to travel a large distance 1

equipment would have to be very long 1

with circular paths long distances can be accommodated in a smaller space

1

(c) (i) the average time for the number of nuclei to halve 1

the time for count rate to halve 1

(ii)

1 mark if top boxes total = 265 and bottom boxes total = 108 1 mark for 4 and 2 for alpha

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2

(d) (i) 3 plotted points ± ½ small square

1

best line through points 1

(ii) 190−205 (pm) or correct from student’s line

1 [20]

Q32. (a) half-life read from graph = 2 hours

1

time to fall to 1.56 is six half lives = 6 × 2 = 12 (hours) 1

(b) one mark for each correct element in the equation

3

(c) ionising radiation turns atoms into ions 1

which can break up molecules 1

this can change DNA 1

causing mutations to genes 1

which can cause cancer 1

[10]

Q33. (a) 10 000

1

(b) Increase

absorb electromagnetic radiation 1

Decrease

emit electromagnetic radiation 1

(c) atomic number is the number of protons

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1

mass number is the number of protons and neutrons 1

(d) Level 2 (3–4 marks): A clear comparison, with logical structure.

Level 1 (1–2 marks): Fragmented points, with no logical structure.

0 marks: No relevant content

Indicative content

Beta decay • Atomic number increases by one • When a neutron decays into a proton

Alpha decay • Atomic number decreases by two • When an alpha particle is emitted

Comparison

Both change number of protons (hence new element / transmutation) Beta decay increases atomic number and alpha decay decreases (explicit)

NB No credit is given for different number of protons = new element. 4

[9]

Q34. (a) protons, electrons

both required, either order 1

neutrons 1

electron, nucleus both required, this order

1

(b) 2.7 (days) allow 1 mark for showing correct use of the graph

2

(c) put source into water at one point on bank accept the idea of testing different parts of the river bank at different times

1

see if radiation is detected in polluted area accept idea of tracing

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or

put source into water at three points on bank (1) see if radiation is detected downstream of factory or farmland or sewage treatment works (1)

1 [7]

Q35. any two pairs from:

to gain credit it must be clear which model is being described do not accept simple descriptions of the diagram without comparison

• nuclear model mass is concentrated at the centre / nucleus (1) accept the nuclear model has a nucleus / the plum pudding model does not have a nucleus for 1 mark

plum pudding model mass is evenly distributed (1)

• nuclear model positive charge occupies only a small part of the atom (1)

plum pudding model positive charge spread throughout the atom (1)

• nuclear model electrons orbit some distance from the centre (1) accept electrons in shells / orbits provided a valid comparison is made with the plum pudding model

plum pudding electrons embedded in the (mass) of positive (charge) (1) do not accept electrons at edge of plum pudding

• nuclear model the atom mainly empty space (1)

plum pudding model is a ‘solid’ mass (1) [4]

4.1 atomic structure - high demand - ms€¦ · page 1 of 22 4.1 atomic structure - high demand –...

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