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2000 Fall meeting

2000FALLNATIONALACSMEETING

Washington,DC(August20-25,2000)

ProgramMeetingChair:WarrenFord

Abstract/PreprintDeadline:April17,2000

ImportantDatesforWashingtonApril18,2000Preprintandabstractsubmissioncloses.ScanningProbeMicroscopyofPolymers:TheNextGenerationVladimirTsukruk,3155GilmanHall,DeptofMaterialsScienceandEngineering,IowaStateUniv,Ames,IA50010,(515)294-6904,fax(515)294-5444,[email protected];NicholasSpencer,LSST,Dept.Materials,ETH-Zentrum,8092Zurich,Switzerland;41-1-632-5850,fax41-1-633-1027,nspencer@surface.mat.ethz.chElectroactivePolymersforCorrosionControl/PreventionPeterZarras,NAWCWPNS,Code4B2200D,ChinaLake,CA93555,(760)939-1396,fax(760)939-1617,[email protected];JohnD.Stenger-Smith,NAWCWPNS,Code4B2200D,ChinaLake,CA93555,(760)939-1661,fax(760)939-1617,[email protected];YenWei,Dept.ofChemistry,DrexelUniv.,Philadelphia,PA19104,(215)895-2650,fax(215)895-1265,weiyen@drexel.edu.MacromolecularSynthesisbySelectiveChemicalModificationMarcA.Hillmyer,Dept.ofChemistry,UofMinnesota,Minneapolis,MN55455,612-625-7834,fax(612)626-7541,[email protected];SteveF.Hahn,CentralR&D,DowChemical,1707Bldg,Midland,MI48674,(517)636-3802,fax(517)638-9547,[email protected],ExxonChemicalCompany,BaytownPolymersCenter,5200BaytownDrive,Baytown,TX77522,(281)834-1533,fax(281)834-2480,[email protected];J.E.McGrath,VirginiaTech;T.L.Hanlon,AlbemarleCorp.4thInternationalBiorelatedPolymersSymposiumA.Kabanov,Dept.ofPharmaceuticalScience,SchoolofPharmacy,UofNebraska,Omaha,NE68198-6021,(402)559-5320,fax(402)697-7385,[email protected];RayOttenbrite,DepartmentofChemistry,VirginiaCommonwealthU,Richmond,VA23284,(804)828-7513,fax(804)367-8599,[email protected]:PreservationfortheNextMilleniumMaryBaker,ChemonicsInternational,EgyptMVE-MaryT.Baker,113320thStreet,NW,Suite600,Washington,DC20036,Phone/fax:202-777-2649x1286mtbaker@zdnetonebox.com.Enviro-compatibleSynthesesandProcesses:TargetingSustainability(cosponsoredbyPMSE)RichardA.Gross,PolytechnicUniversity,PolymerResearchInstitute,SixMetrotechCenter,Brooklyn,N.Y.11201,Fax(718)875-9646,[email protected];H.N.Cheng,HerculesInc.,ResearchCenter,500HerculesRd,Wilmington,DE19808-1599,(302)-995-3505,Fax(302)-995-4135,[email protected];GrahamSwift,215WingedFootDr.,BlueBell,PA19422,(610)239-7345,,[email protected](PMSE,OpticalSocietyofAmerica)RobertTwieg,Dept.ofChemistry,KentStateU,Kent,OH44242,(330)672-2791,fax(330)672-3816,[email protected]

DIVISIONOFPOLYMERCHEMISTRYFinalProgram

2000 Fall meeting W.Ford,ProgramChairOTHERSYMPOSIAOFINTEREST:InterfacialAdhesionandMolecularComposites(seeDivisionofColloid&SurfaceChemistry,Mon,pagexx)PolymerInterfaces:Adsorption,Self-Assembly,andBlendInterfaces(seeDivisionofColloid&SurfaceChemistry,Tue,Wed,Thu,pagexx)Surfactants,Polymers,andColloidsintheAquaticEnvironment(seeDivisionofColloid&SurfaceChemistry,Sun,Mon,pagexx)FunctionalNanostructures(seeDivisionofIndustrial&EngineeringChemistry,Sun,Mon,Tue,pagexx)SOCIALEVENTS:SocialHour,Sun,TueReception,TueBUSINESSMEETING:Sun

SUNDAYMORNING

SectionAJWMarriottGrandSalonI

ScanningProbeMicroscopyofPolymers:TheNextGenerationOverviewsandIntroductionV.V.Tsukruk,N.D.Spencer,OrganizersD.Reneker,N.Spencer,Presiding

8:30—IntroductoryRemarks.8:40—1.Overviewofstate-of-the-artSPMofcrystallinepolymers.M.J.Miles,J.K.Hobbs,T.J.McMaster,A.A.Baker,P.J.James,S.T.Blakely,M-N.Aissaoui9:25—2.Visualizationofnanoscalearchitectureoforderedpolymerswithatomicforcemicroscopy.S.Magonov10:10—Intermission.10:30—3.Nanoindentationofpolymers:Overview.M.R.VanLandingham,J.S.Villarrubia,G.F.Meyers11:15—4.Moleculardynamicsmodelingofscanningprobemicroscopyexperiments.J.A.Harrison

SectionBJWMarriottCapitolSalonE

MacromolecularSynthesisbySelectiveChemicalModificationHydrogenationandOtherSelectiveModificationsM.A.Hillmyer,S.Hahn,OrganizersS.F.Hahn,Presiding

8:00—IntroductoryRemarks.8:30—5.Controlofstructureandpropertiesinpolyphosphazenesbyselectivechemicalreactions.H.R.Allcock9:00—6.Influenceofthetacticityontheesterificationofsyndioandatacticpoly(methacrylicacid)s.P.Gramain,C.Chovino9:30—7.Synthesisofwell-definedmaleicanhydridegraftedPE,PP,EP,ands-PSpolymersviaselectivemodificationsofmetallocene-preparedpolyolefincopolymers.B.Lu,G.Xu,J.Y.Dong,T.C.Chung10:00—Intermission.10:15—8.Catalytichydrogenationofnitrilebutadienerubber.G.Rempel

2000 Fall meeting 10:45—9.Catalyticmodificationofpolymers:Hydrogenationroutestoaminefunctionalmaterials.B.M.Novak,Y.Aoyama11:15—10.Diimidehydrogenationofemulsifiedunsaturatedpolymers:Past,present,andfuture.D.K.Parker11:45—11.Solublepolymerswithcontrolledlevelsofsecondaryandtertiaryaminefunctionalgroups.M.P.McGrath,E.D.Sall,S.J.Tremont

SectionCJWMarriottGrandSalonII

4thInternationalBiorelatedPolymersSymposiumTutorialSession:PolymersinBiorelatedFieldsA.V.Kabanov,R.M.Ottenbrite,OrganizersA.V.Kabanov,T.Ouchi,Presiding

8:00—IntroductoryRemarks.8:05—12.Controllabledesignofblockcopolymervehiclesfordrugdelivery.P.LimSoo,O.Terreau,R.Savic,C.Allen,D.Maysinger,A.Eisenberg8:45—13.Bioinspiredpolymericconjugatesforbiotechnologies.P.Stayton,A.Hoffman,N.Murthy,C.Cheung,C.Lackey,Z.Ding,T.Shimoboji,O.Press9:25—Intermission.9:40—14.Syntheticpolymersasvectorsforgenedelivery.E.H.Schacht,V.Toncheva,L.DeKie,P.Dubruel10:10—15.ThermodynamicinvestigationoftheinteractionofpolycationswithDNA.T.K.Bronich,B.I.Kankia,A.V.Kabanov,L.A.Marky10:40—16.Whathappenstonegativelychargedvesiclesuponinteractingwithpolycationspecies?A.Yaroslavov,V.Kabanov11:10—17.Graftedpolymerlayersandtheirinteractionswithproteins.I.Szleifer

SectionDJWMarriottCapitolSalonF

ElectroactivePolymersforCorrosionControl/PreventionTutorialandOverviewofCorrosionProtectionP.Zarras,J.D.Stenger-Smith,Y.Wei,B.Wessling,OrganizersP.Zarras,J.D.Stenger-Smith,B.C.Benicewicz,Presiding

8:15—IntroductoryRemarks.8:20—18.Tutorialontheuseofelectroactivepolymersascorrosion-inhibitingmaterials.P.Zarras,J.D.Stenger-Smith9:00—19.Corrosion-protectivecoatingsfromelectroactivepolymers.K.G.Thompson,B.C.Benicewicz9:30—20.Synthesisandcharacterizationofpolymerswitholigoanilinesidechains.B.C.Benicewicz,R.Chen10:00—Intermission.10:10—21.Experimentalevidenceforpassivationbytheorganicmetal.B.Wessling,J.Posdorfer10:40—22.Fullysulfonatedpolyaniline(NSPAN)andaluminuminterface:AnESCAstudy.A.J.Epstein,J.A.O.Smallfield,

2000 Fall meeting H.Guan,M.Fahlman11:10—23.Corrosionpreventionofcoldrolledsteelusingwater-dispersiblelignosulfonicacid-dopedpolyaniline.B.C.Berry,A.U.Shaikh,T.Viswanathan11:40—24.Corrosioninhibitionbyanilinetrimersviachargetransfer:ADFTapproach.L.T.SeinJr.,Y.Wei,S.A.JansenOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

SUNDAYAFTERNOON


ScanningProbeMicroscopyofPolymers:TheNextGenerationMicrothermalandChemicalProbingV.V.Tsukruk,N.D.Spencer,OrganizersA.Takahara,A.Karim,Presiding

1:30—25.Lateraldistributionoffunctionalgroupsatpolymersurfacesbychemicalforcemicroscopy:Force-titrationandforce-volumemeasurements.G.J.Vancso,H.Schönherr,M.vanOs,Z.Hruska,J.Kurdi,R.Förch,F.Arefi-Khonsari,W.Knoll2:15—26.Microthermalcharacterizationofpolymers.M.Reading,D.M.Price,D.Grandy,H.M.Pollock,A.Hammiche3:00—Intermission.3:20—27.Characterizationofthesurfacestructural,mechanical,andthermalpropertiesofbenzocyclobutenedielectricpolymersusingscannedprobemicroscopy.G.F.Meyers,M.T.Dineen,E.O.ShafferII,T.M.StokichJr.,J-H.Im3:50—28.Microthermalprobingofpolymers:Dynamiclocalizedthermomechanicalanalysis,localizedIRspectroscopy.H.M.Pollock,A.Hammiche,E.Dupas,D.M.Price,M.Reading,L.Bozec4:20—29.Mappingchemicallyheterogeneouspolymersystemusingchemicalmodificationandatomicforcemicroscopy.D.Raghavan,X.Gu,M.VanLandingham,T.Nguyen


MacromolecularSynthesisbySelectiveChemicalModificationBlockCopolymersM.A.Hillmyer,S.F.Hahn,OrganizersM.A.Hillmyer,Presiding

1:30—30.Thermodynamics,kinetics,andmechanismsoftheformationofmultipleblockcopolymermorphologies.A.Eisenberg2:00—31.Organicallymodifiedceramicprecursorsfornanostructuredblockcopolymer/inorganichybridmaterials.U.B.Wiesner2:30—32.Selectivelyfunctionalizedblockcopolymersformodificationofthermosets.F.S.Bates,R.B.Grubbs,J.M.Dean,M.E.Broz,W.S.Saad3:00—Intermission.3:15—33.Morphologicalbehaviorandself-assemblyofsemicrystallinelinear-dendriticblockcopolymers.M.A.Johnson,P.T.Hammond

2000 Fall meeting 3:45—34.Synthesisandcharacterizationofdiblockcopolymerscontainingsurface-modifyingmoietiesfornonbiofoulingmaterials.S.H.Kang,C.K.Ober,E.J.Kramer4:15—35.Synthesisandcharacterizationofcontrolledarchitectureionic/neutralblockcopolymer.J.Yang,J.Mays4:45—36.Hydrogenationofstyrenicblockcopolymers.K.A.Johnson


4thInternationalBiorelatedPolymersSymposiumBiocompatibleandBiodegradablePolymerMaterialsR.M.Ottenbrite,A.V.Kabanov,OrganizersV.Labhasetwar,I.Szleifer,Presiding

1:30—IntroductoryRemarks.1:35—37.Improvedsynthesisofethyla-hydroxymethylacrylate,auniqueisomericanalogofHEMA.J.M.Antonucci,J.W.Stansbury,B.O.Fowler2:05—38.Degradationbehaviorofporouspoly(a-hydroxyacids)/hydroxyapatitecompositescaffolds.R.Zhang,P.X.Ma2:25—39.Polymer-ceramiccompositesforbonegraftapplications.S.Bose,A.Bandyopadhyay,H.L.Hosick,T.Myers2:45—40.Potentiallymoreblood-compatiblepolymersusingnitricoxidereleasefumedsilicafillers.H.Zhang,M.M.Batchelor,M.E.Meyerhoff3:05—Intermission.3:20—41.Evaluationofclusteringeffectofpartialstructureinheparin.Y.Suda,S.Koshida,A.Arano,T.Morichika,Y.Fukui,S.Kusumoto,M.Sobel3:50—42.StructuralstudiesofbiorelatedpolymersderivedfromnaturalPHAandtheirsyntheticanalogswiththeaidofelectrospraymultistagemassspectrometry.M.Kowalczuk,G.Adamus,W.Sikorska,J.Rydz4:10—43.Newmatricesforcontrolleddrugdelivery.A-C.Albertsson,U.Edlund4:30—44.Water-solubleampholyticpolymersasoralcontrolled-releasecarriers.M.Bari,C-J.Kim4:50—45.Glucose-specificpolymericmolecularimprints.W.Wizeman,P.Kofinas


ElectroactivePolymersforCorrosionControl/PreventionSynthesisandMechanisticStudiesP.Zarras,J.D.Stenger-Smith,Y.Wei,B.Wessling,OrganizersB.C.Benicewicz,K.G.Thompson,Y.Wei,Presiding

1:30—46.Corrosionprotectionwithconductingpolymers:Protectionmechanism,applicationguidelines,anditsvalidityforcommercialproducts.F.A.Lux2:00—47.Polyanilineoxidationstatesandanticorrosion.L.Chigirinskaya,K.Levon2:30—48.Stabilizationandanticorrosionpropertyofphenyl-cappedandanilinetetramerasadditivestocommoncoating.W.Zhang,C.Wang,J.Gao,C.Chen,H.Qui,Y.Yu,L.Chen,Z.Wu

2000 Fall meeting 3:00—49.De-doping/re-dopingstudyoforganicsolublepolyaniline:Impactoncorrosionprotection.A.Dominis,G.Spinks,L.A.P.Kane-Maguire,G.G.Wallace3:30—Intermission.3:40—50.Assessmentofelectronicfactorsnecessaryforcorrosioninhibition:Ananalysisofsubstitutedanilineoligomers.S.A.Jansen,L.T.Sein,Y.Wei,T.Duong4:10—51.Corrosionprotectiononmildsteelusingpolyanilineemeraldinebasebysolvent-freetechnique.X.Wang,Y.Wang,J.Li,J.Lu,X.Jing,F.Wang4:40—52.Polyaniline-metalinterfaces:Implicationsforcorrosionprotectionofsteelandaluminumalloys.M.Fahlman,X.Crispin,H.Guan,S.Li,J.A.O.Smallfield,Y.Wei,A.J.EpsteinOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

SUNDAYEVENING

SectionAGrandHyattIndependenceBallroomA

PosterSessionCharacterizationR.B.Moore,Organizer5:30–7:3053.Core-shellmorphologypredictionviainterfacialenergyestimationanditsapplicationtopolyacrylate-polysiloxanelatexparticles.C.Kan,X.Z.Kong,D.Liu54.Curingbehaviorandthermalpropertiesofcyanateester-curedrigidrodepoxyresin.W-F.Su,C-M.Chuang55.Interactionstudyoffullereneandsingle-wallcarbonnanotubeswithaconductingpolyaniline.C-H.Song,B.C.Berry,T.Viswanathan,W.Zhao56.InvestigationofIRlaser-inducedphotopolymerizationofmultifunctionalacrylatebyreal-timeFTIRspectroscopy.S.ZhangSr.,B.Li,L.Tang,R.Yang,Q.Zhou57.ThermalstabilityofthicktubularHDPEpipewithtemperaturesandheat-transferfluids.S.O.Han,D.W.Lee,S.K.Woo58.WettabilityandproteinadsorptiononepoxidizedHTPB-basedpolyurethanemembrane.J.M.Yang,H.T.Lin59.Novelferromagneticconductinglignosulfonicacid-dopedpolyanilinenanocomposite.B.C.Berry,D.Lindquist,J.P.Smith,T.Viswanathan60.Interactionandplasticizationofdioctylphthalateinlow-densitypolyethylene.Y-T.Shieh,C-M.Liu61.CompressibleRPAanditsapplicationtoaphasesegregatingpolymerblend.J.Cho62.All-opticalpolingofaside-chainpoly(urethane-imide)forsecond-ordernonlinearoptics.X.Yu,Y.Sui,J.Yin,Q.Li,X.Zhong,Y.Chen,Z.Zhu,Z.Wang63.Side-chainpoly(urethane-imide)sforsecond-ordernonlinearoptics.Y.Sui,J.Yin,Z.Hou,N.Zhu,J.Lu,Z.Zhu,Z.Wang64.Centralfunctionalizedasymmetrictriblockcopolymersforsurfacemodificationwithswitchablesurfaceproperties.J.Wang,T.E.Long,T.C.Ward65.Clusteringbehaviorinthreedifferentacrylateionomers.J-S.Kim,J.Kim,Y.H.Nah

2000 Fall meeting 66.Positronannihilationlifetime(PAL)spectroscopyasatooltostudypolyisoprenevulcanizatenetworkstructures.P.E.Mallon,Y.C.Jean,C.M.Huang,H.Chen,R.Zhang,M.H.S.Gradwell67.Compatibilizationofblendsofpoly(butylene-2,6-naphthalenedicarboxylate)andpolycarbonate.B.J.Chisholm,R.Hendrix,P.M.Fong,M.Larsen68.Controlledadsorptionofend-functionalizedpolystyrenetotris(trimethylsiloxy)silylbinarymixedmonolayers.C.M.Stafford,A.Y.Fadeev,T.P.Russell,T.J.McCarthy69.Structuralchangesduringswellingofpoly[2-(N,N-dimethylamino)ethylmethacrylate-l-polyisobutylene(PDMAEMA-l-PIB)amphiphilicco-network.A.Domján,B.Iván,K.Süvegh,A.Vértes70.Effectofhardsegmentsonmorphologyofpolyurethanes.W.Kang,J.O.Stoffer71.EffectofthermaltreatmentonthemorphologyandphysicalpropertiesofNafion/dendrimerblends.E.P.Taylor,R.B.Moore72.Hydrogelpreparedfromcationiccopolymer.Y.Zhong,J.Jachowicz,P.Wolf,R.McMullen73.Influenceoforientationoffunctionalbridgeonthepropertiesofliquid-crystallinepolyacetylenes.F.Salhi,J.W.Y.Lam,J.A.K.Cha,B.Z.Tang74.Developmentoffluorescence-basedfiber-opticsensorsfordeterminingthedegreeofcureinthermosettingresins.S.K.Pollack,C.A.James75.Ion-conductivepolymermultilayersforelectrochromicapplications.D.M.DeLongchamp,P.T.Hammond76.Matrixisolationeffectofwater-solublepoly(p-phenylenevinylene)inalyotropicliquid-crystalnanocomposite.K.Yonezawa,D.L.Gin77.Mean-squareradiusofgyrationofpoly(ethylene-co-propylene)s.Z.ZhouSr.,J.Li,X.Cai,D.Yan78.IntercalationandmechanicalpropertiesoftheSBSblockcopolymerandclayhybridcomposites.J.S.Park,S.Lee,K.Lee,E.Kim,H.Lee79.MorphologiesofPC12cellsculturedonsomepolymericmembranespreparedbyLangmuir-Blodgettandcastingmethods.M.Hara,T.Asakura,C-S.Cho,T.Akaike,A.Higuchi80.Peptide-amphiphileinductionofa-helicalstructures.P.Forns,G.B.Fields81.Fluorescencestudiesofsolvent-polymerinteractionsatpoly(acrylicacid)graftsandtheirderivativesonpolyethylenefilms.G.Tao,M.L.Liu,D.E.Bergbreiter82.MeltcrystallizationofbisphenolApolycarbonateinpolycarbonate/ionomerblends.L.Xu,R.A.Weiss83.Miscibleblendsofaliquid-crystallinepolymerandasulfonatedpolystyreneionomer.H-S.Lee,R.A.Weiss84.Molecularorderingwithinorderedsupermolecularstructure.L.Zhu,S.Z.D.Cheng,Q.Ge,R.P.Quirk,B.Hsiao,F.Yeh85.MonteCarlosimulationofsinglechainofhigh-performancepolymer.S.Zhu,D.Yan86.Randomperfluorocyclobutylcopolymerswithcontrolledopticalproperties.D.W.SmithJr.,A.B.Hoeglund,H.V.Shah,J.Ballato,C.Langhoff,S.F.Macha,P.A.Limbach87.Solid-state13CNMRstudyofpoly(methylacrylate)ionomer.J-S.Kim,A.R.Lim88.StructuralinvestigationonphysicalaginginbisphenolApolycarbonate.J.Lu,Y.Wang,D.Shen89.SynthesisandcharacterizationofhighTgorgano-solubleside-chaincopolyimidescontainingatriazine-basedazochromophore.Y.Sui,J.Yin,X.Guo,Y.Liu,J.Gao,Z.Zhu,D.Huang,Z.Wang

2000 Fall meeting 90.Studiesoninsitucompositesandpropertiesofpoly(etheretherketone)andnovelpoly(aryletherketone)liquidcrystallinecontainingfluorine.G.Wang,C.Chen,Z.Jiang,C.Yu,L.Zhang,W.Zhang,Z.Wu91.Experimentalstudyofreleaseanduptakeinwell-definedimprintedpolymerfilms.K.Das,D.J.Duffy,S.L.Hsu,J.Penelle,V.M.Rotello92.Studyonmolecularmovementandcompatibilityofpolypropylene/polyestersemi-interpenetratingpolymernetworks.F.Li,J.Wang,Y.Li,J.Jin,X.Tang93.Synthesisandstudyofanewpolyorganophosphazenewithpendantcarbazolylgroups.J.Wang,F.Li,Y.Li,X.Tang94.Studyonsurfacephotovoltagepropertiesofa-terthiophenederivatives.C.Wang,C.Cao,Y.A.Cao,Y.H.Shi,Z.M.Guo,T.J.Li95.Natureofaluminumdepositedonaurethane-substitutedpolythiophene.J.E.Whitten,H.Ahn,H.Seung96.Rheologicalcharacterizationofpoly(ethyleneoxide)/claynanocomposites.H.J.Choi,S.G.Kim,Y.H.Hyun,M.S.Jhon97.Self-assemblingmorphologiesofamphiphilicpolyacetylenescontainingaminoacidmoieties.F.Salhi,J.W.Y.Lam,K.K.L.Cheuk,J.A.K.Cha,B.Z.Tang98.SilvernanostructuresonPENandPETfilms.B.Hu,R.M.Ottenbrite,J.A.Siddiqui99.GraftpolyelectrolytelayersonPENandPETfilms.B.Hu,I.Germanenko,R.M.Ottenbrite,J.A.Siddiqui100.Stimuli-responsivereleasefromporoussilica/stimuli-responsivegelhybridparticle.K.Suzuki,T.Yumura,Y.Tanaka,M.Akashi101.Structureandmorphologyofpoly(meta-phenyleneisophthalamide)nanofibersproducedbyelectrospinning.W.Liu,Z.Wu,D.H.Reneker102.Studiesofchainconformationintriblockoligomersandmultiblockcopolymersofethyleneandethyleneoxide.Y.Ding,J.F.Rabolt,K.L.Olson,Y.Chen,G.L.Baker

SectionBGrandHyattIndependenceBallroomA

PosterSessionSynthesisR.B.Moore,Organizer5:30–7:30103.Accuratestructurecontrolofgraftcopolymersviawell-definedpolyfunctionalmacroinitiatorsfornitroxide-mediated"living"free-radicalpolymerization.C.Cheng,N-L.Yang104.Biocompatiblemacroligands:Newsubunitsfortheassemblyofmetal-containingpolymers.P.S.Corbin,J.E.McAlvin,M.P.Webb,S.Shenoy,C.L.Fraser105.Developmentofpolymerizationprocessesbasedonpalladium-mediatedreactions.Z.Wu,D.Wang,P.Wei,J.Xu,X.Bi106.Norbornenepolymerizationwithhalf-titanocene/MAOcatalyst:Dependenceofstructureofthepolymeronpolymerizationconditions.Q.Wu,J.He,Y.Lu,Z.Lu107.Solublepolyimidescontainingnaphthalenestructure.C.S.Wang,T.S.Leu108.Surfacemodificationofpoly(tetrafluoroethylene-co-hexafluoropropylene)(FEP)byadsorptionofpoly(L-lysine)andpoly(acrylicacid).W.Chen,M.E.Evangelista,R.M.Y.Yeung109.Synthesis,characterization,andmicrostructureofpoly(ethyleneterephthalate)copolymerscontaining

2000 Fall meeting nitroterephthalicunits.D.P.R.Kint,A.MartínezdeIlarduya,S.Muñoz-Guerra110.Anioniclivingpolymerizationofn-hexylisocyanate.S-Y.Kim,J-H.Ahn,Y-D.Shin,J-S.Lee111.Triarylphosphineoxide-basedbenzazolepolymersforpotentialspaceapplications.T.D.Dang,N.C.Thiesing,W.A.Feld,N.Venkatasubramanian,C.A.Cerbus,F.E.Arnold112.Useofcarbohydratereagentsforthepolymerizationandoligomerizationofdicyanoalkenesand-arenes.D.J.Sandman,M.A.Rixman,Z.Tsai,D.Wu,I-B.Kim113.Gelformationbetweenthermoplasticpolyurethaneandpoly(ethylene-co-vinylalcohol)duringblendprocessing.D.D.Jiang,R.F.Storey114.Newinitiatingsystemforcontrolledradicalpolymerizationofbutylmethacrylate.W.Wang,D.Yuping,L.Qianshu115.Anionicsynthesisandcharacterizationofpoly(styrene-block-1-buteneoxide)blockcopolymersandtheirapplicationinanionicdispersionpolymerization.Q.Ge,R.P.Quirk116.Anionicpolymerizationof3-nitro-9-ethylcarbazolylmethacrylate.Y-S.Cho,J-S.Lee117.Bergmancyclopolymerizationofbisphenol-A-derivedtetraynes.D.W.SmithJr.,K.P.U.Perera,K.A.Abboud118.Chemicalmodificationofburiedinterfacesusingsupercriticalcarbondioxide.X.Jia,T.J.McCarthy119.Chiralinductioninradicalpolymerizationofmaleimidederivativesusingopticallyactivecobalt(II)complexes.T.Nakano,D.Tamada,J-I.Miyazaki,K.Kakiuchi,Y.Okamoto120.Convenientmethodforthepreparationofpoly(ethyleneoxide)andpoly(ethyleneoxide)blockcopolymers.D.H.Adamson121.Cyclolinearphosphazenesviaacyclicdienemetathesispolymerization.E.C.KellamIII,M.A.Hofmann,H.R.Allcock122.End-groupfunctionalizationofregioregularhead-to-tailpoly(3-alkylthiophene)s.J.Liu,R.D.McCullough123.Free-radicalgraftingofhinderedphenolantioxidantsontolowmolecularweightPE.T.H.Kim,D.R.Oh124.Influenceofbisphenolstructureonthedirectsynthesisofsulfonatedpoly(aryleneether)s.W.Harrison,F.Wang,J.B.Mecham,K.O'Connor,J.E.McGrath125.Linearandstarliquid-crystallinepolymerspreparedusingatomtransferradicalpolymerization.S.M.Ruder,A.Datta,S.D.Allen126.Poly(styrene-divinylbenzene)-boundplatinumcomplexinhydrosilylationofunsaturatedhydrocarbons.C.Kan,X.Z.Kong,D.Liu127.Polycyclotrimerizationofinternaldiynes:Synthesisofhyperbranchedpoly(alkenephenylenes).K.Xu,H.Peng,Y.Huang,Z.Xu,B.Z.Tang128.Polymerizationofpoly(propyleneglycol)methacrylatebyATRP.B.L.Sadicoff,A.E.Acar,L.J.Mathias129.Inclusioncomplexesofa-cyclodextrinand(AB)nblockcopolymers.K.L.Olson,Y.Chen,G.L.Baker130.Newapproachestopolyethylene-functionalizedligandsforatomtransferradicalpolymerization.M.E.Pallack,S.Liou,W.J.Brittain131.Segmentedamine-epoxy-basedthermosettingelastomers.D.W.SmithJr.,T.W.Baughman,E.J.Nelson,S.H.Foulger132.Newmethacrylatederivativesbasedonpyroglutamicacid.T.J.Smith,L.J.Mathias133.Phosphatidylcholine-functionalsurfacesviasequentialgraftingreactions.S.K.Pollack,Y.S.Bullen

2000 Fall meeting 134.Photoconductivepolyimidesbasedonbisphenyl-porphyrin:Synthesisandcharacterization.B.Zhu,Z.Xu,Y.Xu135.SynthesisandcharacterizationofanovelAB2monomerandcorrespondinghyperbranchedpoly(aryleneetherphosphineoxide)s.Q.Lin,T.E.Long136.Photoconductivepolyimidesbasedonbisphenyl-porphyrin:Structureandphotoconductivepropertiesofpolyimideandtheirprecursorfilms.B.Zhu,Z.Xu,Y.Xu137.Synthesisandcharacterizationofpolyimidespreparedfromsulfone,carbonyl,andphosphineoxide-containingdiamines.D.J.Klein,R.G.Bryant138.Photolysisofiodoniumsaltsinthepresenceof1-naphtholand1-methoxynaphthalene.H.Gu,W.Zhang,D.C.Neckers139.Synthesisandcharacterizationofnovelfluorine-containingpolyarylate.B.Liu,Y.Dong,W.Hu,C.Chen,G.Wang,Z.Wu140.Poly(p-phenylene)swithpoly(ethyleneoxide)aspendantgroups.F.H.Asfour,C.Ruud,G.L.Baker141.Synthesisandluminescentpropertiesofanovelrigid-rodalternatingcopolymercontainingoligo(ethyleneoxide)sidechains.H.Cheng,H.Wei,G.Jian,Y.Chang-zheng142.Synthesisandopticalpropertiesofnaphthalene-containingconjugatedpolymers.Z.Peng,Y.Pan143.Synthesisandpolymerizationofphosphorus-containingacrylates.D.Avci,L.J.Mathias144.Polysilsesquioxanesthroughbase-catalyzedredistributionofoligomethylhydridosiloxanes.K.Rahimian,D.P.Lang,D.A.Loy145.Synthesisandpolymerizationofstyryloxycyclophosphazenederivatives.D.Hernández-Rubio,C.W.Allen146.Synthesisandcharacterizationofpolyphosphazeneswithsulfur-bearingsubstituents.H.Ma,Y.Li,S.Liu,J.Wang,X.Tang147.Radicalreactionsof3,4-dimethoxy-1-buteneinthepresenceofaredoxinitiatorsystem.Y.Yoo,L.K.Johnson,A.J.Pasquale,T.E.Long148.Synthesisofblockcopolymercontainingpoly(styrene-alt-N-phenylmaleimide)bystablefree-radicalpolymerization.C-G.Cho,T.E.Chang,K-D.Ahn149.Synthesisofpolyolsofvariousstructureswithnarrowmolecularweightdistributionfordifferentapplications.O.N.Piraner,M.Balasubramanian150.EffectsofincreasingP2O5contentinpolyphosphoricacidbyPOCl3.Y-H.So,M.T.Bishop,R.M.VanEffen,B.L.Kaliszewski151.Ring-openingpolymerizationof1,1-dicyanocyclopropane.L.Kagumba,J.Penelle152.TowardthesynthesisofC-glycosidedendrimers.M.J.Panigot,S-U.Kim,M.W.Arnold,A.Bailey,D.Bailey,J.L.Faulkner,J.Middleton153.Stereospecificpolymerizationofmethylmethacrylatewithbisindenyllanthanidecomplexes.S.Y.Knjazhanski,H.R.López-González,L.Larios-López,G.Cadenas154.StudyonsynthesisandLCbehaviorsofnovelternarypolyurethanes.Y.Lian,D.Liu,Q.Zhou155.Sulfonatedaromaticdiaminesasprecursorsforpolyimidesforproton-exchangemembranes.H.K.Shobha,M.Sankarapandian,T.E.Glass,J.E.McGrath156.Surface-initiatedatomtransferradicalpolymerizationongoldatambienttemperature.J-B.Kim,M.L.Bruening,G.L.

2000 Fall meeting Baker157.Surface-initiatedradicalpolymerizationongoldusingstabilizedinitiatormonolayers.W.Huang,S.Ganesan,M.L.Bruening,G.L.Baker158.Syndiospecificradicalpolymerizationofmethylmethacrylateinthepresenceofsyndiotacticpoly(methylmethacrylate).M.Nodono,T.Makino,K.Nishida159.Synthesisandcharacterizationofcopoly(acrylate)swithsilanefunctionalgroupsinthesidechain.S.Hait,D.E.Nikles160.Synthesisandcharacterizationofnovelbiodegradablepoly(ester-carbonates).R.F.Storey,B.D.Mullen161.Synthesisandcharacterizationofnovelchlorosilylfunctionalpolyisobutylene.I-J.Kim,R.Faust162.Synthesisandcharacterizationofpolymerscontainingdiketopiperazine.D.A.Parrish,L.J.Mathias163.Synthesisandmicrostructuralanalysisofpoly(alkyl1-cyanocyclopropanecarboxylates).L.Kagumba,J.Penelle164.Synthesisofpolymerbrushesonsilicatesubstratesbyreversibleadditionfragmentationchain-transfertechnique.M.Baum,W.J.Brittain165.Synthesisofsolubleandcontrollablecross-linkingpoly(aryletheretherketone)s.Z.Gao,T.Ben,X.Liu,H.Cao,H.Qiu,C.Chen,Z.Wei,Z.Wu,W.Zhang166.Synthesisofstableandluminescenthyperbranchedpoly(alkenephenylenes)viacopolycyclotrimerizationofdiynesandmonoynes.K.Xu,H.Peng,P.P.S.Lee,Y.Dong,B.Z.Tang167.Thiophenepolymerizationinanultrathinhyperbranchedgraftonapolyethylenefilmsubstrate.M.L.Liu,G.Tao,D.E.Bergbreiter

SectionCGrandHyattIndependenceBallroomA

PosterSessionElectroactivePolymersforCorrosionControl/PreventionP.Zarras,J.D.Stenger-Smith,Y.Wei,B.Wessling,OrganizersP.Zarras,Presiding5:30–7:30168.Scanningvibratingelectrodestudyofchromated-epoxycoatingsonsteelandaluminum.J.He,V.J.Gelling,D.E.Tallman,G.P.Bierwagen169.Amine-quinonepolyurethanes.M.Han,R.Sharma,Y.Hu,G.W.Warren,D.E.Nikles170.Newamine-quinonepolyimidesforprotectingironagainstcorrosion.M.Han,H.Bie,D.E.Nikles,G.W.Warren171.Adhesionpropertiesofanalineoligomersandtheirepoxyresin-curedderivativesovercoldrolledsteel.Y.Wei,H.Jamasbi,S.Li,S.A.Jansen,L.T.Sein,S.Cheng172.Conductingpolypyrroleonanepoxysubstrate:Effectofsurfacepretreatment.R.VandenSchoor,M.Krupers,R.VandeLeur,H.DeWit173.Impedancestudiesofpolyanilineepoxycoatings.A.Talo,T.Sammi,M.Tiitu,O.Ikkala,O.Forsén174.Regioregularpolymerizationof3-semifluoroalkylthiophenes.X.M.Hong,J.C.Tyson,X.Wu,D.M.Collard175.Rubber-modifiedwater-solublepolyanilinelatex.C.Kuo,L.Y.Chiang,J.Kumar,L.Samuelson,S.K.Tripathy176.Studyofpoly(3-octylpyrrole)forcorrosioncontrolofaluminum2024-T3.V.J.Gelling,D.E.Tallman,G.P.

2000 Fall meeting Bierwagen,G.G.Wallace177.Synthesisandcharacterizationofpoly(aniline-co-anthranilicacid)s.S.Baek,M.Ree

SectionDJWMarriottGrandSalonII

BusinessMeeting6:30—BusinessMeeting.

MONDAYMORNING


ScanningProbeMicroscopyofPolymers:TheNextGenerationPolymerMorphologyandMicrostructureV.V.Tsukruk,N.D.Spencer,OrganizersM.J.Miles,G.J.Vancso,Presiding

8:30—178.Phase-separatedmicrostructuresin"all-acrylic"thermoplasticelastomers.P.Leclère,A.Rasmont,J-P.Aimé,R.Jérôme,J-L.Brédas,R.Lazzaroni9:00—179.Atomicforcemicroscopystudiesofphaseorderinginpolymerblendsandclay-filledsystems.V.Ferreiro,J.F.Douglas,A.Karim,G.Coulon9:30—180.Evolutionoflamellarstructureduringcrystallizationofabinarysemicrystalline-amorphousblend:Time-resolvedhot-stageSPMstudy.D.A.Ivanov,C.Basire9:50—181.InsituAFMofthecrystallizationofpolyethylene.J.K.Hobbs,M.J.Miles10:10—Intermission.10:30—182.Scanningprobeimagingandnanoindentationstudiesofmodelpressure-sensitiveadhesivesandtheiraging.M.D.Foster,A.Paiva10:50—183.Scanningforcemicroscopyofpolyester:Surfacestructureandadhesiveproperties.G.J.Leggett,B.D.Beake,N.J.Brewer11:10—184.Elastomersfroma,w-dihydroxypolydimethylsiloxaneandtheethoxysiloxanemixture"ES40":Bulkcharacterizationandsurfacefeatures.J.Uilk,S.Bullock,E.Johnston,K.J.Wynne,L.Merwin,S.Myers11:30—185.Patternsinbiopolymersandotherbiologicalsystemsasobservedbyatomicforcemicroscopy.I.V.Yaminsky


MacromolecularSynthesisbySelectiveChemicalModificationM.A.Hillmyer,S.F.Hahn,OrganizersM.A.Hillmyer,Presiding

8:15—186.Hyperbranchedanddendrimer-likearchitecturesbychemicalmodificationofpolymertermini.Y.Gnanou,D.Taton,S.Lecommandoux,M.Saule8:45—187.Hyperbranchedmolecularobjectselaboratedviasuccessivelivingionicpolymerization/chemicalmodificationsteps.A.Deffieux,Z.Muchtar,M.Schappacher

2000 Fall meeting 9:15—188.Preparationofnanoscopicallyresolvedamphiphilicnetworksfromthehybridizationofhyperbranchedfluoropolymersandlinearpoly(ethyleneglycol)s.K.L.Wooley,D.Gan9:45—Intermission.10:00—189.Postpolymerizationion-exchangeandchemicalmodificationofcross-linkedlyotropicliquid-crystalnetworks.J.H.Ding,W-J.Zhou,D.H.Gray,D.L.Gin10:30—190.Functionalizedpolymersforcatalysisandpolymersynthesis.H.Alper11:00—191.ADMETpolymerizationinthepreparationofhydrocarbonpolymerscontainingaminoacid-basedfunctionalities.T.E.Hopkins,J.H.Pawlow,F.J.Gómez,S.M.Solivan,J.A.Davis,K.S.Deters,D.L.Koren,K.B.Wagener11:30—192.Synthesisofnewhydrophilicg-substitutedpoly-e-caprolactones.P.Lecomte,V.D'aloia,M.Mazza,O.Halleux,S.Gautier,C.Detrembleur,R.Jerome


4thInternationalBiorelatedPolymersSymposiumNanoparticlesandBlockCopolymersforDrugDeliveryandGeneTherapyA.V.Kabanov,R.M.Ottenbrite,OrganizersP.Alexandridis,E.H.Schacht,V.Alakhov,Presiding

8:30—IntroductoryRemarks.8:35—193.SP1017:Anonviralcarriersystemforgeneexpressioninskeletalmuscleanddermaltissues.V.Alakhov,P.Lemieux9:05—194.TransfectionofCaco-2cellsbyPLGA-nanoparticles.W-Z.Zhou,V.Labhasetwar9:35—195.Architectureofpolymermicellesfromblockcopolymersoflactideanddepsipeptideasdrugcarriers.T.Ouchi,H.Miyazaki,F.Tasaka,A.Hamada,Y.Ohya10:05—196.Selectiveenergydepletionandsensitizationofmultipledrug-resistantcancercellsbypluronicblockcopolymers.E.V.Batrakova,S.Li,V.Y.Alakhov,A.V.Kabanov10:25—Intermission.10:40—197.Noveldrugdeliverysystems:Nanogelnetworks.S.Vinogradov,E.V.Batrakova,A.V.Kabanov11:00—198.Thermallyresponsiveamphiphilicblockpolypeptidesfordrugencapsulation.Y.Zhou,V.P.Conticello11:20—199.Reactivestabilizationofvesiclesfromcationicsurfactantsself-assembledonanionicblockionomertemplate.T.K.Bronich,M.Ouyang,A.Eisenberg,V.Kabanov,F.C.SzokaJr.,A.V.Kabanov11:40—200.Solvationdynamicsinunimolecularpolymericmicelles.L.Frauchiger,H.Shirota,E.W.CastnerJr.,K.Uhrich


ElectroactivePolymersforCorrosionControl/PreventionSynthesisandTestingP.Zarras,J.D.Stenger-Smith,Y.Wei,B.Wessling,OrganizersS.C.Yang,B.Wessling,K.J.Wynne,Presiding

2000 Fall meeting 8:15—201.Scanningvibratingelectrodestudyofelectronicallyconductingpolymersonaluminumalloy.J.He,V.J.Gelling,D.E.Tallman,G.P.Bierwagen8:45—202.Electroactivepolymersforcorrosioninhibitionofaluminumalloys.S.C.Yang,R.Brown,R.Racicot,Y.Lin,F.McClarnon9:15—203.Corrosionprotectionpropertiesofcoatingsoftheanilineoligomersandtheirepoxyresin-curedderivativesbasedonsaltsprayandcyclictesting.Y.Wei,H.Jamasbi,S.Li,S.A.Jansen,L.T.Sein,S.Cheng9:45—204.Amine-quinonepolymers:Anewclassofcorrosion-resistantcoatings.H.Bie,M.Han,A.B.Helms,G.W.Warren,D.E.Nikles,S.C.Street10:15—Intermission.10:25—205.Uniquemethodofaniline/DBSApolymerizationinaqueousdispersions:Blendingwithpolymersandencapsulationoffillers.M.Narkis,E.Segal,Y.Haba,W.Jia,A.Siegmann10:55—206.Corrosionprotectionofmildsteelwithpolyaniline.T.Schauer,H.W.Greisiger,C.D.Eisenbach11:15—207.Functionalizedconductingpolymerforcoatingsonmetals.W.Li,S.C.Yang11:35—208.Sulfur-quinonepolyurethanesandtheprotectionofironagainstcorrosion.Y.Hu,A.B.Helms,D.E.Nikles,S.C.Street,G.W.Warren,D.YangOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

MONDAYAFTERNOON


ScanningProbeMicroscopyofPolymers:TheNextGenerationThinPolymerFilmsV.V.Tsukruk,N.D.Spencer,OrganizersA.J.Lovinger,M.H.Rafailovich,Presiding

1:30—209.AFMstudiesofconfineddewettingongradientpatternedsurfaces.A.Karim,A.Sehgal,E.J.Amis2:00—210.ScanningforcemicroscopicobservationoftheproteinadsorptionbehaviorontothesurfaceoforganosilanemonolayerspreparedbytheLangmuir-Blodgettmethod.A.Takahara,Y.Hara,K.Kojio,T.Kajiyama2:30—211.Oligo(ethyleneglycol)-terminatedmonolayersunderelectrolytesolutionstudiedwithscanningforcemicroscopy.G.Hähner,C.Dicke,K.Feldman,W.Eck,S.Herrwerth3:00—Intermission.3:20—212.Characterizationofpoly(amidoamine)dendrimerpackingbyatomicforcemicroscopy.J.Li,D.Qin,J.R.BakerJr.,D.A.Tomalia3:40—213.Atomicforcemicroscopyoftethereddiblockcopolymers.W.J.Brittain,B.Zhao,W.Zhou,S.Z.D.Cheng4:00—214.Near-fieldscanningopticalmicroscopystudiesofnanoscalepolymerorderinginthinfilmsofpoly(9,9-dialkylfluorene).J.A.Teetsov,D.A.VandenBout4:20—215.ElectrochemicalAFMonsurface-graftedpoly(ferrocenylsilanes).M.Péter,M.A.Hempenius,R.G.H.Lammertink,M.T.vanOs,G.J.Vancso

SectionB

2000 Fall meeting JWMarriottCapitolSalonE

MacromolecularSynthesisbySelectiveChemicalModificationM.A.Hillmyer,S.F.Hahn,OrganizersJ.W.Mays,Presiding

1:20—216.PyrenylattachmenttopolyethyleneismoreselectivewithMeV-rangeparticlesthanwitheV-rangephotons.G.O.Brown,N.A.Guardala,J.L.Price,R.G.Weiss1:40—217.Novelsynthesisandmodificationofpolymersviaelectrontransfer.Z.Jedlinski,H.Janeczek,I.Bosek2:00—218.Epoxidationofdegradedpoly(vinylchloride).T.Szakács,B.Iván2:20—219.Withdrawn.2:20—220.Synthesisandcatalytichydrogenationofpoly(1,3-cyclohexadiene)star-shapedpolymers.D.T.Williamson,K.P.Brazhnik,J.F.Elman,A.J.Pasquale,T.E.Long2:40—Intermission.3:00—221.Chemicalmodificationofpolyolefins.A.O.Patil3:20—222.Synthesisofbiomedicalgraft-copolymersusingpolysaccharidesasbackbonepolymers.T.Ouchi,T.Hirano,S.Maruhashi,H.Nishizawa,K.Shizuno,Y.Ohya3:40—223.Synthesisofregioselectivelyfunctionalizedpolysaccharideestersavoidingprotectinggroups.R.Dicke,D.O.Klemm4:00—224.Synthesisofnovelbranchedpolylactidesandtheirbiodegradation.F.Tasaka,H.Miyazaki,Y.Ohya,T.Ouchi4:20—225.Nickel-mediatedatomtransferradicalpolymerizationofside-groupsiloxane-containingblockcopolymersforcontrolledwettability.J.P.Youngblood,T.J.McCarthy


4thInternationalBiorelatedPolymersSymposiumBioconjugatedNanocompositeMaterialsandPolymerGelsforPharmaceuticalApplicationsA.V.Kabanov,R.M.Ottenbrite,OrganizersL.E.Bromberg,Y.Nagasaki,Presiding

1:30—IntroductoryRemarks.1:35—226.NovelsynthesisofPEG/polycationblockcopolymerspossessingareactivePEG-endgroupforhigh-performancegenetargeting.Y.Nagasaki,D.Wakebayashi,Y.Akiyama,A.Harada,K.Kataoka2:05—227.Creatingfunctionalgroupsonpolymersurfaceswithw-functionalsurface-activeblockcopolymers.J.Chen,Q.Fu,D.A.Smith,J.T.Koberstein2:25—228.Reconstitutionofthrombomodulinintopolymerizablephospholipidvesicles.J.Feng,E.L.Chaikof2:45—229.Preparationofliposomescontainingdibranchedaminoacidsandcharacterizationoftheirglucose-bindingproperties.H.Seong,W-M.Choi,J-C.Kim,D.H.Thompson,K.Park3:05—230.Bioconjugatesofproteintransductiondomainandshellcross-linkednanoparticles:Nanostructuredmaterialsdesignedforcelldelivery.J.Liu,Q.Zhang,K.L.Wooley3:25—Intermission.

2000 Fall meeting 3:40—231.Modelingofdrugreleasefrompolymermatrixviadiffusionanderosion.S.S.Talukdar,L.Yang,P.Alexandridis4:00—232.Diffusivityof3-D,ionicallycross-linkedalginatehydrogels.C.K.Kuo,P.X.Ma4:20—233.PredictingdegradationbehaviorofPLA-b-PEG-b-PLAhydrogels.A.T.Metters,K.S.Anseth,C.N.Bowman4:40—234.Engineeringdynamicstructureandactivityinartificialproteinhydrogels.S.B.Kennedy,T.P.Russell,D.A.Tirrell5:00—235.Rheologyofpressure-sensitiveadhesivehydrogelsdesignedforskinapplication.S.V.Kotomin,T.A.Borodulina,M.M.Feldstein,V.G.Kulichikhin5:20—ConcludingRemarks.


GeneralSessionNovelPolymerArchitecturesR.B.Moore,OrganizerK.L.Wooley,Presiding

1:30—236.Controlofpolymerstructure:Organizationbynoncovalentinteractions.G.Clavier,F.Ilhan,T.H.Galow,M.Gray,V.Rotello1:50—237.Dendriporeanddendrilockconcepts:Newcontrolled-deliverystrategies.R.Esfand,D.A.Tomalia,A.E.Beezer,J.C.Mitchell,M.Hardy,C.Orford2:10—238.Microgelformationinhighlycross-linkedpolymers:Simulatedandexperimentalresults.J.B.Hutchison,K.S.Anseth2:30—239.Radical-basedpreparationofblockcopolymerscontainingfluorinetags:Toolsfordetailedanalysisofnanostructuredmaterials.M.L.Becker,K.L.Wooley2:50—240.Synthesisandcharacterizationofnovelnanostructuredpolymersenhancedbyhydrogenbondingusingliquid-crystalmonomers.W-J.Zhou,D.Gin3:10—241.Pom-pompolystyrenebyconvergentlivinganionicpolymerization.D.M.Knauss,T.Huang3:30—242.Synthesisoffunctionalstar-shapedpolymersbylivingcationicpolymerization.S.Kanaoka,T.Higashimura3:50—243.Interpolymercomplexesthroughhydrophobicinteractions:C60-end-cappedpoly(ethyleneoxide)/poly(acrylicacid)complexes.X.D.Huang,S.H.Goh4:10—244.Synthesisoflinearandhyperbranchedpoly(silylester)sviacross-dehydrocoupling-basedpolymerization.M.Wang,D.Gan,K.L.WooleyOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

TUESDAYMORNING


2000 Fall meeting

ScanningProbeMicroscopyofPolymers:TheNextGenerationMicrotribologyandApplicationsV.V.Tsukruk,K.J.Wahl,Presiding

8:30—245.Interfacialforcemicroscopy:Applicationtopolymersurfaces.J.E.Houston,R.M.Winter9:00—246.Molecular-levelinterpretationsoffrictionalforcedatacollectedwithatomicforcemicroscopy:Chain-lengtheffectsinself-assembledorganicmonolayers.S.S.Perry,S.Lee,T.R.Lee,M.Graupe,A.Puck,R.Colorado,R.ColoradoJr.,I.Wenzl9:30—247.Nanometer-scalestructural,tribological,andopticalpropertiesofultrathinpoly(diacetylene)films.R.W.Carpick,D.Y.Sasaki,A.R.Burns10:00—Intermission.10:20—248.AFMstudyofpositivechemicallyamplifiedresists.Q.Lin,R.Sooriyakumaran,W-S.Huang10:40—249.Slidingfrictionbetweencelluloseandsilicasurfaces.G.Bogdanovic,F.Tiberg,M.W.Rutland11:00—250.AFManalysisofmass-producednanostructures.D.A.Chernoff,C.S.Cook,D.L.Burkhead11:20—251.IndentationbehaviorofthepolymerthirdbodygeneratedinaPMMA/steelcontact.A.Chateauminois,B.J.Briscoe,D.Parsonage


IndustrialSponsorsAwardE.Sybertz,Organizer,Presiding

9:00—IntroductoryRemarks.G.Whitesides9:25—252.Newgenerationofnonabsorbed,lipid-loweringpolymers.W.H.Mandeville9:50—253.Polymersasnoveldrugdeliverysystems.K.E.Uhrich10:15—254.Currentresearchinpolymericpharmaceuticals.S.R.Holmes-Farley10:40—255.Second-generationPEG-proteinpharmaceuticals.M.J.Roberts,M.D.Bentley,J.M.Harris11:05—256.Self-assemblyofblockcopolypeptides.T.J.Deming11:30—257.Syntheticandbiosyntheticpolymerswithstimuli-responsivemicrodomainsinaqueousmedia.C.L.McCormick,R.S.Armentrout,G.C.Cannon,G.G.Martin


GeneralSessionCompositesandBlendsR.B.Moore,OrganizerK.R.Carter,Presiding

8:30—258.Compositepreparedfromepoxidizedsoybeanoil.P.Lu,J.O.Stoffer,R.A.Babcock,L.R.Dharani8:50—259.Fabricationandpropertiesofnewaramidfiber-cyanateestercomposites.M.Sankarapandian,P.Shih,V.Gabara,G.L.Hendren,A.C.Loos,J.E.McGrath

2000 Fall meeting 9:10—260.Self-encapsulationofpoly-2,7-fluorenesinadendrimermatrix.D.Marsitzky,R.Vestberg,C.J.Hawker,K.R.Carter9:30—261.MolecularweightandtemperaturedependenceoftheinterfacialtensionofPS/PDMSblendsusingimbeddedfiberretractionmethod.G.Biresaw,C.J.Carriere9:50—262.Polymer-mediated"bricks-and-mortar"self-assemblyofnanoparticlesintodiscretestructuredarrays.F.Ilhan,A.K.Boal,V.Rotello10:10—263.Phosphineoxidecontainingpolymer-basedmetalsalt/polymerandsilica/polymerhybridnanocomposites.S.Wang,H.Zhuang,M.Sankarapandian,H.K.Shobha,A.R.Shultz,J.E.McGrath10:30—264.Macromolecularengineeringusingnovelalkoxyamines.Y.Gnanou,S.Robin,O.Guerret,J.L.Couturier10:50—265.Rod/coilblendsviaspecificinteractions:Miscibilityandproperties.D.R.Dean,N.Venkatasubramanian,T.D.Dang,G.E.Price,F.E.Arnold11:10—266.Synthesisofaminopropyltriethoxysilanecatalyzedorgano-silicahybridnanoparticles.R.M.Ottenbrite,J.S.Wall,J.A.Siddiqui


GeneralSessionFunctionalPolymericMaterialsR.B.Moore,OrganizerK.E.Uhrich,Presiding

8:30—267.Azobenzenecontainingphotodynamicpolymersfrompost-azo-couplingreaction.Y.He,H.Yang,X.Wang,Q.Zhou8:50—268.ThermomorphicsystemsforHeckcatalysisandmetalsequestration.J.D.Frels,D.E.Bergbreiter,P.L.Osburn9:10—269.Enzymaticsynthesisofpoly(4-hydroxystilbene):Anewclassofluminescentmaterial.P.Wu,W.Liu,S.Balasubramanian,J.Kumar,L.Samuelson,S.K.Tripathy9:30—270.Photocurablepolymersbasedonmethacrylatesanddimethacrylatescontainingcarbazole.J.E.McGrath,L.Rasmussen,H.Shobha,M.Sankarapandian,K.E.Uhrich9:50—271.Polymerelectrolytesbasedonethyleneoxide-segmentedmicroblockcopolymers.K.A.Swan,M.K.Stowe,Y.Chen,J.Qiao,G.L.Baker10:10—272.Synthesisofnovel,degradablepolyanhydridescontainingpara-aminosalicylicacidasdrugdeliverydevicesfortuberculosistreatment.T.J.Anastasiou,K.E.Uhrich10:30—273.Synthesisandcharacterizationofnovelsiliconemagneticmaterials.J.S.Riffle,M.Rutnakornpituk,M.Vadala,K.S.Wilson,J.K.Hoyt10:50—274.Mechanismofinteractionsbetweenunimolecularpolymermicellesandlipidbilayers.L.N.Albers,K.E.Uhrich11:10—275.Synthesisandcharacterizationofphosphineoxidediolmodifiedepoxyadhesives.M.A.Hickner,A.Banthia,J.E.McGrathOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

TUESDAYAFTERNOON

2000 Fall meeting


ScanningProbeMicroscopyofPolymers:TheNextGenerationMicromechanicalProbingV.V.Tsukruk,N.D.Spencer,OrganizersJ.E.Houston,G.F.Meyers,Presiding

1:30—276.Relationshipbetweentheincreaseofvibratingcantileverdissipationandrelaxationprocessesatthemolecularscale.G.CouturierSr.,J-P.Aimé,J.Salardenne,A.Gourdon,S.Gauthier2:00—277.Slidingtransitions,mechanics,anddissipationinnanoscalecontacts.K.J.Wahl,S.A.S.Asif,R.J.Colton2:30—278.Tappingmodeatomicforcemicroscopystudyofelastomers:Dynamicsoftip-sampleinteraction.G.Bar,L.Delineau,R.Brandsch,M-H.Whangbo3:00—Intermission.3:20—279.Sizeandconfinementeffectsinthinpolymerfilms.R.M.Overney3:50—280.Scalingrelationshipsforindentationmeasurements.Y-T.Cheng,C-M.Cheng4:20—281.Viscoelasticenergydissipationandtime-dependentadhesionhysteresisofpolydimethylsiloxanenetworksonthenanometerscalewithatomicforcemicroscopy.J.P.Pickering,D.Krüger,B.Anczykowski,H.Fuchs,G.J.Vancso4:40—282.NewdirectionsintappingmodeAFMofpolymers:Towardfullcontroloftip-sampleforcesandhighresolution.T.Kowalewski5:00—ConcludingRemarks.


Enviro-CompatibleSynthesesandProcesses:TargetingSustainabilityTutorialLecturesCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,H.N.Cheng,G.Swift,OrganizersH.N.Cheng,Presiding

1:30—283.Biotechnology:Thethirdwave.B.L.Marrs2:15—284.Invitroenzyme-catalyzedpolymersynthesis.R.A.Gross,A.Kumar,B.Kalra3:00—Intermission.3:15—285.CO2technologyplatformforsustainablemanufacturing.J.M.DeSimone4:00—286.Greenchemistryandthepolymerindustry.G.Swift


EmergingFrontiersinPolyolefinsTutorialsT.E.Hanlon,P.Arjunan,Organizers,Presiding

2000 Fall meeting 1:30—IntroductoryRemarks.1:35—287.Overviewofsynthesisandbasicchemicalstructure/physicalpropertyrelationshipsinpolyolefins.J.E.McGrath2:05—288.Advancesinsingle-sitecatalysisforolefinpolymerization.P.Brant2:50—289.Roleactivatorsinsingle-siteolefinpolymerization.T.J.Marks3:35—Intermission.3:45—290.Olefinpolymerizationbynonmetallocenegroup4metalcomplexes.R.R.Schrock4:30—291.Advancedpolyolefincharacterization:Moleculararchitecturetosolid-statemicrostructure.A.H.Tsou,T.Sun,M.L.Lyon,W.Hu,D.W.AbmayrJr.


PolymerMaterialsforthe21stCentury:IndustrialSponsorsProgramM.Jaffe,R.M.Ottenbrite,OrganizersM.Jaffe,Presiding

2:00—IntroductoryRemarks.M.Jaffe2:15—Makingsubstantialthatwhichissuperficial:Thefutureofadhesionandpolymer-basedadditives.A.V.Pocius2:55—Polymerscienceandknowledgeintensityincoatingssystems.D.Engel3:35—NASA:Polymersforthefuture.A-M.McGowan4:15—Newpolyolefinstructuresbycoordinationpolymerizationofethyleneandpropylenemonomers.P.BrantOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

TUESDAYEVENING

SectionAConventionCenterExhibitHallD

JointPMSE/POLYPosterSession4thInternationalBiorelatedPolymersSymposiumA.Kabanov,R.M.Ottenbrite,Organizers6:00–8:00292.Permeationofg-globulinthroughmicroporousmembraneunderexistenceoftraceDNA.K.Hirano,A.Komuro,M.Hara,M.Yokogi,S-I.Manabe,A.Higuchi293.SynthesisofdendriticamphiphilicblockcopolymersbyATRP.S-G.An,C-G.Cho294.Useofpoly(ethyleneoxide)nonionicsurfactantsastemplatesforenzyme-containingmesoporoussol-gelmaterials.J.Xu,H.Dong,Q.Feng,Y.Wei295.Developmentofphasestructureduringtheprocessingofpoly(L-lacticacid)scaffoldsfortissueengineering.S-H.Zhu,P.X.Ma296.Cyclicvoltammetricanalysisofmethylviologeninwaterandsulfonatedpolymermembranes.S.Kaur,D.Michalak,

2000 Fall meeting G.M.Florio297.Selectiveanionsorptionandrecoveryfromwastewaterbypolyelectrolytehydrogels.D.R.Kioussis,P.Kofinas298.Affinityphotocross-linkingfortheefficientidentificationandisolationofheparin-bindingproteins.Y.Suda,K.Mori,M.Nakamura,S.Kusumoto,M.Sobel299.Antimicrobialnylon.J.Lin,C.Winkelmann,S.D.Worley,R.M.Broughton,J.F.Williams,J.Bickert300.Attachmentofproteinstopoly(vinylalcohol)forbiomedicalapplications.C.R.Nuttelman,K.S.Anseth301.Chitosanmacroporousscaffoldsforcellculture.H.Seong,H-J.Baek,I-C.Kwon,S-Y.Jeong,E-H.B.Lee302.Confinementeffectsinpolymersunderanappliedfield.R.Wenczel,C-Y.Shew303.Conformationalbehaviorofanisolatedpolymerchainlabeledwithanelasticball.Y.Chen,C-Y.Shew304.Enhancedproductionofantigen(CEA)andhumanantibodybymammaliancellsculturedonvariouspolymericfilms.S.Adachi,M.Hara,M.Kamei,S.Hashizume,A.Higuchi305.Evaluationofkineticparametersofpolylactide-co-polyethylglycolide.C.Wang,Y.Mao,G.L.Baker306.Experimentalstudiesofphasetransitionsinsolutionsofrandomheteropolymers.M.McCormick,J.A.Reimer307.IFN-bproductionoffibroblastcellsculturedonvariouspolymericmembranes.Y.Takanashi,T.Ohno,M.Hara,T.Asakura,A.Higuchi308.Microfabricationofhydrogelsaspolymerscaffoldsfortissue-engineeringapplications.T.Yu,F.Chiellini,D.Schmaljohann,R.Solaro,C.Ober309.Molecularrecognitionofvesiclescontainingpyrenecompoundsusingfluorescencespectroscopy.H.Kofune,M.Hara,M.Maekawa,T.Nohmi,T.Kinoshita,A.Higuchi310.Physicochemicalaspectsofdrugreleasefrompoloxamerblockcopolymergels.L.Yang,S.S.Talukdar,P.Alexandridis311.Polymermatrixeffectsonthepropertiesofamorphouscalciumphosphate-filledcomposites.D.Skrtic,J.M.Antonucci,D.E.Eanes312.Preparationofvarioussurface-modifiedmembranesandtheiropticalresolutionofaminoacids.H.Yomogita,M.Hara,S.Maniwa,M.Saito,A.Higuchi313.Self-aggregationphenomenainhumanmucin.L.E.Bromberg,D.P.Barr314.Sizeexclusionchromatographyofhighmolecularweightpolymers:Effectsofflowrateandthecreationofauniversalcalibrationcurve.Y.Cheng,R.K.Prud'homme315.Stereoselectivepolymerizationusingaracemiccatalyst.C.P.Radano,G.L.Baker,M.R.SmithIII316.Structurallycontrolledpolymersfromacademiatoindustry:Poly-e-caprolactone-basedblockcopolymers.S.K.Varshney,J.X.Zhang317.SynthesisandcharacterizationofpHandtemperature-sensitivesilk-elastinlikeblockcopolymersforcontrolleddrugdelivery.A.Nagarsekar,J.Crissman,M.Crissman,F.Ferrari,J.Cappello,H.Ghandehari318.Synthesisofaromaticpolyanhydridesforcontrolleddrugdelivery.A.J.Sanders,F.W.Harris319.Synthesisofnovelhydrophilicbiopolymers.E.B.Walsh,M.J.Sheehy,M.W.Grinstaff320.Synthesisofphotocross-linkablebiopolymersforinsituapplications.K.A.Smeds,M.W.Grinstaff

2000 Fall meeting 321.Synthesis,characterization,andevaluationofurethanederivativesofbis-GMA.C.A.Khatri,J.M.Antonucci,J.W.Stansbury,C.R.Schultheisz322.Transportofmacromoleculardrugcarriersacrossmicrovascularbeds.M.El-Sayed,M.Naimark,M.F.Kiani,H.Ghandehari323.UV-inducedradicalgraftingofhydrophilicmonomersfromdithiocarbamatedpolymersurfaces.N.Luo,J.B.Hutchison,N.P.Nartin,C.N.Bowman,K.S.Anseth

SectionBConventionCenterExhibitHallD

JointPMSE/POLYPosterSessionEmergingFrontiersinPolyolefinsP.Arjunan,OrganizerP.Arjunan,T.E.Hanlon,J.E.McGrath,Presiding6:00–8:00324.Applicationsofcobalt(II)porphyrinsincontrolledradicalpolymerizationsofacrylatesinorganicandaqueousmedia.L.Basickes,G.F.Parks,B.B.Wayland325.Elementaryreactionsinthezirconoceneactivationprocessbymethylaluminoxane.A.Deffieux,H.Cramail,J-N.Pédeutour326.Homo-andcopolymerizationofmacromonomersviacoordinationpolymerization.P.J.Lutz,F.Breitling,J-F.Lahitte,F.Peruch,S.PlentzMeneghetti,F.Isel327.Novelaluminum-based,transition-metal-free,catalyticsystemsforhomo-andcopolymerizationofalkenes.J.S.Kim,A.Sen328.Rapidmonomerconsumptionduringinitiationoflivingcationicpolymerizationofolefins:Varyingmonomer/initiatorcombinations.R.F.Storey,Q.A.Thomas329.Studyofinitiationeffectsinthelivingcationicpolymerizationofstyreneusingreal-timeATR-FTIRmonitoring.R.F.Storey,S.J.Jeskey330.Withdrawn.331.Withdrawn.332.Synthesisofsyndiotacticpolyaminostyrenederivativesbyusingcationicmetallocene/boratecatalysts.G.Xu,T.C.Chung333.Synthesisandpropertiesofdouble-bond-terminatedisotacticpolypropylene.P-F.Fu,S.Glover,R.K.King,C-L.Lee,M.R.Pretzer,M.K.Tomalia334.Zirconocene/MAO-catalyzedpolymerizationofetheneand1-hexene:Theinfluenceofmethylsubstitutionpatternonthecyclopentadienylligand.H.Wigum,L.Tangen,J.A.Støvneng,E.Rytter

SectionCConventionCenterExhibitHallD

JointPMSE/POLYPosterSessionEnviro-CompatibleSynthesesandProcesses:TargetingSustainabilityCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,G.Swift,H.N.Cheng,Organizers6:00–8:00

2000 Fall meeting 335.Chemoenzymaticsynthesisofnucleoside-branchedpoly(vinylalcohol).Y.Tokiwa,H.Fan,T.Raku,M.Kitagawa336.EffectofDMSOonselectiveacylationofallopyranosecatalyzedbyprotease.M.Kitagawa,Y.Tokiwa,T.Raku,H.Fan337.Controlofpolyester-chainscissionbylipase-catalysis.M.Bankova,A.Kumar,R.A.Gross,G.Impallomeni,A.Ballistreri338.Exploitinglipase-catalysistoprepareanA2Bhetero-armblockcopolymerfromglycerol.Y.Mei,A.Kumar,R.A.Gross339.Functionalbioresorbablecopolymersfromlipase-catalysis.A.Mahapatro,A.Kumar,R.A.Gross340.HRP-mediatedpolymerizationsofacrylamideandsodiumacrylate.B.Kalra,R.A.Gross341.Lipase-catalysisfacilitatescopolymerizationsthatwereotherwisedifficultorimpossiblebyalternativechemicalapproaches.A.Kumar,K.Garg,W.Gao,R.A.Gross342.Lipase-catalyzedpentadecalactone/caprolactonecopolymerizations.A.Kumar,B.Kalra,A.Dekhterman,R.A.Gross343.Lipase-catalyzedgraftingreactionsonpolysaccharides.Q-M.Gu344.Methylated-b-cyclodextrinmediatedaqueouspolymerizationofhydrophobicmethacrylicmonomers.P.H.MadisonIV,T.E.Long345.Patternablelow-kdielectricsdevelopedusingsupercriticalCO2.G.L.Weibel,H.PryceLewis,K.K.Gleason,C.Ober346.Radicalpolymerizationofmethylmethacrylateinitiatedwithathermaliniferter.S.H.Qin,K.Y.Qiu,G.Swift,W.Lau,D.G.Westmoreland,S.Wu347.Reworkablethermosets:Enablingdisassemblyofmicroelectroniccomponents.J-S.Chen,C.K.Ober,M.D.Poliks348.Sol-gelprocessofmicroencapsulationofreactivechemicals.M.Temchenko,C.Westmark,T.Tiano,R.Kovar,W.Zukas,N.Landrau349.Studyofthermomechanicalpropertiesofpolyesterwithvinylethersidechainsbeforeandafterphotocuring.D.E.Nikles,T.Woo,J-Y.Huh

SectionDConventionCenterExhibitHallD

JointPMSE/POLYPosterSessionMacromolecularSynthesisbySelectiveChemicalModificationM.A.Hillmyer,S.F.Hahn,Organizers6:00–8:00350.Polyetherimide/dicyanatesemi-interpenetratingpolymernetworkshavingmorphologyspectrum.Y.S.Kim,S.C.Kim351.SynthesisandelectricpropertiesofVDF/TrFE/HFPterpolymers.A.Petchsuk,T.C.Chung352.Synthesisofnovelmacrocyclesandpolymersbasedonrestrictedrotation.Y.S.Chong,K.D.Shimizu353.Moleculardesignofpolyimidestowardhighprotonconductingmaterials.Y.Zhang,M.H.Litt,R.F.Savinell,J.S.Wainright,J.Vendramini354.Synthesisofsyndiotacticpolystyrenegraftcopolymerbyatomtransferradicalpolymerization.S.Liu,A.Sen355.Whollyaromaticfive-andsix-memberedringpolyimidescontainingpendantsulfonicacidfunctionalgroups.N.Gunduz,J.E.McGrath356.Readily,continuously,andreversiblytunablehelicalpreferenceofopticallyactivepoly(phenylacetylenes).K.K.L.

2000 Fall meeting Cheuk,F.Salhi,J.W.Y.Lam,B.Z.Tang357.Regiospecifichydrolysisofpoly(enaminonitriles)andmodelcompounds.J.A.Moore,Z.Li358.Entirelyhydrophilicshellcross-linkedKnedel-likenanoparticles.Q.Ma,E.E.Remsen,T.Kowalewski,K.L.Wooley359.Synthesesofpolyethylene-basedgraftcopolymersbyatomtransferradicalpolymerization.S.Liu,A.Sen360.Synthesisofopticallyactivesiloxanederivativescontainingcyclopenteneunits.A.A.Vaidya361.Couplingtheaffinityspectrummethodwithselectivechemicalpostmodificationfortheimprovementofimprintedpolymers.K.D.Shimizu,R.J.UmplebyII362.Dendrimersbasedonmelamine.E.E.Simanek,W.Zhang363.Effectofdegreeofsaponificationonthephysicochemicalpropertiesofhighmolecularweightsyndiotacticpoly(vinylalcohol)solution.W.S.Lyoo,J.H.Choi364.Functionalizationofregioregularhead-to-tailpoly(3-alkylthiophenes)sidechain.L.Zhai,R.McCullough365.Hydrogen-bondingeffectsonmolecularorderingandpolymerizationofmesogenicdisklikediacetylenes.S.J.Lee,J.Y.Chang,M.J.Han366.Imageablepolymersusingfluorocarbinolcontainingpolydienes.Y.C.Bae,J.Dai,G.L.Weibel,C.K.Ober367.Modificationofthethermalcureofaryl-ethynylend-cappedimideoligomers.D.A.Schorzman,M.E.Wright,L.E.Pence368.Newpoly(phenylacetylene)sbearingaminoacidmoieties.F.Salhi,K.K.L.Cheuk,J.W.Y.Lam,B.Z.Tang369.Syndiotacticpolystyrenegraftingbranchedpolyethylenewith[Ni(p-methallyl)(Br)]2/AlCl3catalyst.S.Liu,A.Sen370.SynthesisandthermalpropertiesofnewthermosettingpolysiloxanescontainingSi–HandC–Cmoietiesonthesiliconatom.P.N.Reddy,T.Hayashi,M.Tanaka,M.Itoh371.Mildroutetohighlyfluorinatedmodelpolymers.Y.Ren,M.A.Hillmyer,T.P.Lodge372.Blockcopolymerizationofisobutylenewithpivalolactoneusingsite-transformationtechnique.Y.Kwon,R.Faust373.Synthesisofwell-definedpolymershavinglinearpolyethyleneblocksviaROMPandhydrogenation.S.T.Trzaska,L-B.W.Lee,R.A.Register374.Selectivemethodforhydroxylationandderivatizationofinteriorsitesofpolyolefinicfilms.C.Wang,R.G.Weiss375.Synthesisofliquid-crystallinepoly(oxyethylene)scontaining(6-nonylsulfonyl)hexylsulfonylsidegroupsbychemicalmodificationofpoly(epichlorohydrin).J-C.Lee,Y.G.Kim,H-B.Lee,K.Oh,S-Y.Park,B.L.Farmer

SectionEConventionCenterExhibitHallD

JointPMSE/POLYPosterSessionScanningProbeMicroscopyofPolymers:TheNextGenerationV.V.Tsukruk,N.D.Spencer,Organizers,Presiding6:00–8:00376.InsitubiodegradationstudyofpolyhydroxyalkanotethinfilmsusingAFM.B.H.Augustine,C.J.Rossini,E.R.McCarney,M.Flythe,S.F.Baron,D.E.Dennis377.Highlyregularorganizationofconjugatedpolymerchainsviablockcopolymerself-assembly.P.Leclère,D.Marsitzky,V.Francke,S.Setayesh,K.Müllen,J-L.Brédas,R.Lazzaroni

2000 Fall meeting 378.Effectsofmonolayerdisorderonthefrictionofanchoredalkanechains.J.A.Harrison,S.J.Stuart,P.T.Mikulski,A.B.Tutein379.Langmuirmonolayersfromazobenzene-containingdendrons.A.Sidorenko,C.Houphouet-Boigny,A.Greco,O.Villavicencio,M.Hashemzadeh,D.V.McGrath,V.Tsukruk380.Atomicforcemicroscopystudiesoflow-andhigh-densitypolyethyleneheldintensiledeformation.A.M.Opdahl,G.A.Somorjai381.InsitucrystalizationstudyinPETfilmsbyelevatedtemperatureAFM/UFM.V.N.Bliznyuk,K.Kirov,H.E.Assender,G.A.D.Briggs,Y.Tsukahara382.AutocorrelationfunctionanalysisofthesurfacestructureofamorphousPMMA.V.N.Bliznyuk,V.M.Burlakov,H.E.Assender,G.A.D.Briggs,Y.Tsukahara383.Microthermalanalysisofuntrathinpolymericfilmswithscanningthermalmicroscopy.V.V.Gorbunov,N.Fuchigami,V.V.Tsukruk384.Microthermalanalysiswithscanningthermalmicroscopy.V.V.Gorbunov,N.Fuchigami,V.V.Tsukruk385.Stabilityofmicrodomainmorphologyintetheredblockcopolymermonolayers.I.Luzinov,D.Julthongpiput,V.V.Tsukruk386.Microtribologicalbehavioroftetheredblockcopolymermonolayers.I.Luzinov,D.Julthongpiput,V.Gorbunov,V.V.Tsukruk387.Surfaceorganizationofhyperbranchedpolymermolecules,asstudiedbyatomicforcemicroscopy.P.Viville,A.Deffieux,M.Schappacher,P.Leclère,J-L.Brédas,R.Lazzaroni

WEDNESDAYMORNING


GeneralSessionSynthesisR.B.Moore,OrganizerA.E.Acar,Presiding

8:30—388.Air-induced(reverse)atomtransferradicalpolymerizationofphenethylmethacrylateintheabsenceofanaddedinitiator.A.E.Acar,M.B.Yagci,L.J.Mathias8:50—389.Couplingreactionsofpolystyryllithiumanddibromomethane:Comparisonswithotherdihalomethanes.E.S.Tillman,T.E.Hogen-Esch9:10—390.Determiningstereochemicalrelationshipsinpolylactide:Synthesisandcharacterizationofpolylactidehexads.E.E.Paske,G.L.Baker9:30—391.Effectsofchelatingagentsonthequasilivingcarbocationicpolymerizationofisobutylene.P.WernerGroh,B.Iván,M.Szesztay,F.deJong,T.Graafland9:50—392.Noveldehydroalaninederivatives:HomopolymersandMMAcopolymers.H.YagciAcar,L.J.Mathias10:10—393.Palladium(II)-catalyzedcopolymerizationofnorbornenewithpolarvinylmonomers.A.D.Hennis,A.Sen10:30—394.Perfectlyalternatingpoly(aryleneetherphosphineoxide)-b-poly(dimethylsiloxane)copolymers.W.D.Polk,S.Wang,Y.Kim,M.Sankarapandian,T.E.Glass,J.E.McGrath

2000 Fall meeting 10:50—395.Retardedanionicpolymerization:5-InfluenceofalkylsubstituentsinPSLi/MgR2initiatingsystemsonthecharacteristicsofhigh-temperaturestyrenepolymerization.A.Deffieux,S.Menoret,S.Carlotti,P.Desbois,C.Schade,M.Fontanille11:10—396.Synthesisandcharacterizationofcontrolledmolecularweightsulfonatedaminofunctionalpoly(aryleneethersulfone)spreparedbydirectpolymerization.J.B.Mecham,H.K.Shobha,F.Wang,W.L.Harrison,J.E.McGrath


Enviro-CompatibleSynthesesandProcesses:TargetingSustainabilityDevelopmentofNovelMethodologiesCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,H.N.Cheng,G.Swift,OrganizersA.Steinbüchel,Presiding

8:30—397.Generationofenvironmentallycompatiblepolymerlibrariesviacombinatorialbiocatalysis.J.S.Dordick,D-Y.Kim,X.Wu9:00—398.Synthesisandcationicphotopolymerizationofbiorenewablemonomersandoligomers.J.V.Crivello9:30—399.Continuousapplicationofenzymesandsynzymesinmembranereactors.C.Wandrey,S.Laue10:00—Intermission.10:15—400.Evolvingandscreeningenzymesfornewactivitiesonpolymersubstrates.D.C.Youvan,W.J.Coleman,E.J.Bylina10:45—401.Enzymaticpolymermodification.J.T.KellisJr.11:15—402.Towardthe"greening"ofadipicacid:Genesareonlythebeginning.Y.Hasegawa,T.Tokuyama,P.C.K.Lau


EmergingFrontiersinPolyolefinsCatalysisP.Arjunan,OrganizerT.E.Hanlon,P.Arjunan,Presiding

8:30—IntroductoryRemarks.8:35—403.Next-generationnickelcatalysts.P.B.Mackenzie,L.S.Moody,C.M.Killian,J.A.PonasikJr.,G.G.Lavoie,J.C.Pearson,T.W.Smith,L.A.Tucker,M.R.Moore,A.K.Farthing,G.A.King,M.D.Meadows,C.S.Sass,E.P.Savitski9:05—404.Structure,mechanism,andreactivityinsingle-siteolefinpolymerizationcatalysis.T.J.Marks9:35—405.Usingelectrophile-functionalizedmetalloceneintermediatesinthedesignofolefinpolymerizationcatalysts.P.A.Deck,O.W.Lofthus,X.Cheng10:05—Intermission.10:15—406.Binuclearconstrainedgeometrycatalystsandbinuclearbisboratecocatalystsforolefinpolymerization.L.Li,T.J.Marks,L.M.Liable-Sands,A.L.Rheingold,M.V.Metz10:45—407.VariationofisospecificactivesitesonMgCl2-supportedZieglercatalysts.M.Terano,H.Matsuoka,B.Liu

2000 Fall meeting 11:15—408.1-and2-Substituted(h3-allyl)palladium(II)catalystsfortheadditionpolymerizationofnorbornene.W.Risse,F.Peruch11:45—409.Bis-amidesandaminebis-amidesasligandsforolefinpolymerizationcatalystsbasedonV(IV),Cr(IV),andMn(IV):Adensity-functionaltheorystudy.T.K.Firman,T.ZieglerOrganicThinFilmsforPhotonicApplicationscosponsoredwithDivisionofPolymericMaterials:Science&Engineering(seepagexx)

WEDNESDAYAFTERNOON


GeneralSessionNewMaterialsR.B.Moore,Organizer,Presiding

1:30—410.Aliphaticpolyesterscontainingsymmetricalglutamicaciddiketopiperazines.L.S.SomlaiJr.,D.A.Parrish,L.J.Mathias1:50—411.StudyofcrystallizationkineticsinZenitethermotropicliquid-crystallinepolymer.P.K.Pallathadka,T-S.Chung2:10—412.Synthesisandcharacterizationofpoly(4,4¢-oxydiphthalicanhydride-co-2,2¢-dimethyl-4,4¢-diaminobiphenyl)amicacidanditsimide-kineticstudy.P.S.G.Krishnan,R.H.Vora,T-S.Chung2:30—413.SolidsupportsforCO2applications.S.A.Crétté,J.M.DeSimone,R.G.Carbonell,W.Tumas,J.T.Brady2:50—414.Synthesisofpom-starpolystyrene.D.M.Knauss,T.Huang3:10—415.SynthesisofrandomsolutionSIRsusingdistributedmonomerfeedsystems.G.Xu,M.L.Kerns,S.Christian3:30—416.Synthesisofsulfonatedpoly(phenylenesulfidesulfone)sviadirectpolymerization.F.Wang,J.B.Mecham,W.Harrison,J.E.McGrath3:50—417.Kineticmodelsforhyperbranchedpolymerizationandcopolymerization.D.Yan4:10—418.Photoresponsiveself-assembledmultilayersofthreenewazopolyelectrolytes.X.Tuo,Z.Chen,L.Wu,X.Wang,D.Liu4:30—419.Preparingabrominatedpoly(p-methylstyrene-co-styrene)-block-poly(ethylene-co-butene)-block-poly(p-methylstyrene-co-styrene).R.C-C.Tsiang,C-Y.Tsai


Enviro-CompatibleSynthesesandProcesses:TargetingSustainabilityBiocatalyticRoutestoPolyestersandPolycarbonatesCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,H.N.Cheng,G.Swift,OrganizersJ.S.Dordick,Presiding

1:30—420.InvivoandinvitrometabolicengineeringofPHAbiosynthesispathways.A.Steinbüchel2:00—421.Controllingthepolymermicrostructureofbiodegradablepolyhydroxyalkanoates.A.S.Kelley,F.Srienc

2000 Fall meeting 2:25—422.Enzyme-catalyzeddirectpolyesterification.K.F.Brandstadt,J.C.Saam,A.Sharma2:50—423.GreensyntheticprocessofaliphaticpolycarbonatesfromCO2andtheirbiodegradabilities.M.Ree,Y-T.Hwang,H.Kim3:15—Intermission.3:30—424.Enantio-andregioselectivepolymerizationwithlipasecatalysistopolyesters.S.Kobayashi,H.Uyama4:00—425.Lipase-catalyzedtransesterification:Newsyntheticroutestocopolyesters.A.Kumar,R.A.Gross4:25—426.Functionalpolycarbonatesynthesis:Enzymaticapproach.K.S.Bisht,T.F.Al-Azemi


EmergingFrontiersinPolyolefinsSynthesisP.Arjunan,OrganizerP.Arjunan,T.E.Hanlon,Presiding

1:30—IntroductoryRemarks.1:35—427.C2-Symmetriczirconocenesforhighmolecularweightamorphouspolypropylene.D.Balboni,G.Moscardi,I.E.Nifant'ev,G.Baruzzi,D.Angeli,L.Resconi2:05—428.Kineticsofpropylenepolymerizationusingbis(2-phenylindenyl)zirconiumdichloride/MAO.R.M.Waymouth,S.Lin2:35—429.Long-chainbranchedpolypropyleneviamacromerincorporation.W.Weng,E.J.Markel,A.H.Dekmezian3:05—Intermission.3:15—430.Metallocenepolymerizationwithreactivechain-transferagent:Synthesisoftelechelicpolyolefinandfunctionalpolyolefindiblockcopolymers.G.Xu,J.Y.Dong,T.C.Chung3:45—431.Newchemistryforsurfacemodificationofpolyethylene.D.E.Bergbreiter4:15—432.Synthesisandpropertiesofpolyolefinhybridcopolymerscontainingpolyhedraloligosilsesquioxane.L.Zheng,R.J.Farris,E.B.Coughlin

THURSDAYMORNING


PolymersinMuseums:PreservationfortheNextMillenniumM.T.Baker,Organizer,Presiding

8:55—IntroductoryRemarks.9:00—433.Polymersintimecapsules:Atutorial.M.T.Baker,D.vanderReyden,D.C.Williams10:15—434.Permanenceofplasticizersinpolyvinylchlorideobjectsinthemuseumenvironment.Y.Shashoua10:45—Intermission.11:00—435.SavingAmerica'streasures:ThreatenedartifactsfromtheApolloera.L.A.Young

2000 Fall meeting 11:30—436.Imitationleathercoveringsinearlycarproduction:TheWandererW10/II.I.Carow


Enviro-CompatibleSynthesesandProcesses:TargetingSustainabilityAdvancesinPolysaccharidesCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,H.N.Cheng,G.Swift,OrganizersR.A.Gross,Presiding

8:30—437.Synthesisandmodificationofcarbohydratesthroughbiotechnology.W.Xie,P.G.Wang9:00—438.Enzymaticdegradationofawater-solublepolysaccharide.Y.Cheng,R.K.Prud'homme9:25—439.Graftingrenewablechemicalstofunctionalizechitosan.G.F.Payne,L.Vachoud,T.Chen,J.Govar9:50—440.CharacterizationofpolysaccharidesbysolutionNMRspectroscopy:Bacterialpolysaccharidevaccines.C.A.Bush10:20—Intermission.10:30—441.AssessmentoftheenvironmentalimpactofMater-Bistarch-basedmaterialsinspecificindustrialapplications.C.Bastioli,L.Marini11:00—442.Enzymaticmodificationsofwater-solublepolymers.H.N.Cheng,Q-M.Gu11:25—443.Invitrobiosynthesisofplantb-glucans.J.LaiKeeHim,H.Chanzy,L.Pelosi,J-L.Putaux,V.Bulone


EmergingFrontiersinPolyolefinsSynthesis/CharacterizationP.Arjunan,OrganizerP.Arjunan,T.E.Hanlon,Presiding

8:30—IntroductoryRemarks.8:35—444.Synthesisandcharacterizationofmaleicanhydride-cyclicolefinalternatingcopolymers.A.J.Pasquale,R.Karro,R.D.Allen,T.E.Long9:05—445.Studyoftheuptakeofendo-versusexo-norbornenesininsertionpolymerization.A.D.Hennis,A.Sen9:35—446.Invitroenzyme-catalyzedvinylpolymerization.B.Kalra,R.A.Gross10:05—Intermission.10:15—447.Kineticsofisothermalmeltingofisotacticpolypropyleneswithdifferentdegreesofstereoregularity.R.G.Alamo,W.T.Huang,L.Mandelkern10:45—448.Meltingandcrystallizationbehaviorofpolyethylenecopolymers:Relationshiptotemperaturerisingelutionfractionation.F.M.MirabellaJr.11:15—449.Sequencecontrolofethylene-a-olefincopolymerswithbridgedmetallocenes.R.M.Waymouth,W-H.Fan,M.Leclerc

2000 Fall meeting

THURSDAYAFTERNOON


PolymersinMuseums:PreservationfortheNextMillenniumM.T.Baker,OrganizerY.Shashoua,Presiding

1:30—IntroductoryRemarks.1:35—450.Laserablationofartificiallyageddammarlayersofcontrolledthickness:Spectroscopicstudiesonthedegreeofaging.S.Boyatzis,A.Kaminari,A.Manousaki,V.Zafiropulos2:05—451.InvestigationofLaropalA81:ParaloidB72polymerblendsaspicturevarnishes.J.M.Arslanoglu2:35—452.Canartists'oilpaintsbeacceleratedaged?D.Erhardt,C.S.Tumosa,M.F.Mecklenburg3:05—Intermission.3:20—453.CharacterizationofplantfibersbyIRspectroscopy.P.Garside,P.Wyeth3:50—454.Stayinginshape:Thestabilityofstructuralproteinsinnaturalhistorymuseumstoragefluids.D.W.VonEndt


Enviro-CompatibleSynthesesandProcesses:TargetingSustainabilityBiorelatedReactionsandApplicationsCosponsoredwithDivisionofPolymericMaterials:Science&EngineeringR.A.Gross,H.N.Cheng,G.Swift,OrganizersG.Swift,Presiding

1:30—455.Biochemicalsynthesisofwater-solubleconductingmolecularcomplexofpolyanilineandlignosulfonate.S.K.Tripathy,F.F.Bruno,L.Samuelson,R.Nagarajan,J.Kumar2:00—456.Gelformationbyenzyme-selectivecross-linkingoftyramine-decoratedpoly(aspartamide).B.Kalra,A.Kumar,R.A.Gross2:25—457.Synthesisandpolymerizationofnewmonomersderivedfromitaconicanhydrideandpentaerythritol.M.Ramos,S.J.Huang2:50—458.Globalwarmingreductionbypolymersinautomotivefuels.P.F.Waters3:15—Intermission.3:30—459.Polymer-modulated,diffusion-controlledenzymekineticsonmonolayers.K.Tanaka,H.Yu4:00—460.Controlled/"living"polymerizationof2-(N-morpholino)ethylmethacrylatebyatomtransferradicalpolymerizationinaqueoussolutionat20°C.F.L.G.Malet,N.C.Billingham,S.P.Armes4:25—461.Vinylradicalpolymerizationwithamultifunctionalinifertertechnique.S.H.Qin,K.Y.Qiu


2000 Fall meeting

EmergingFrontiersinPolyolefinsStructure/PropertyRelationshipsP.Arjunan,OrganizerP.Arjunan,T.E.Hanlon,Presiding

1:30—IntroductoryRemarks.1:35—462.Propertiesofisotacticpoly(propylene):Someold,somenew.L.Mandelkern2:05—463.LCBpolymer-chaindimensions:ApplicationoftopologytotheZimm-Stockmayermodel.D.Bonchev,E.J.Markel,A.H.Dekmezian2:35—464.Crystallization,melting,andmorphologyatambientandhighpressuresofhomogeneousethylenecopolymerswithhighcomonomercontents.V.B.F.Mathot,S.V.Eynde,G.Höhne,H.Reynaers3:05—Intermission.3:15—465.InvestigationonthestructuralparametersofpolyethylenesobtainedusingaPdcatalyst.P.J.Lutz,S.PlentzMeneghetti,J.Kress,A.Lapp,M.Duval3:45—466.Cessationofspheruliticgrowthinphase-separatingpolyolefinblends.H.Wang,C.C.Han

2000 fall natl acs meeting - polyacs.org · scanning probe microscopy of polymers: the next...

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