2 countries 10,000 added value to biogas · pentair biogas 3 co2fermentation and purification...

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PENTAIR 1

PRODUCT LINE MANAGEMENT

PRESENTER: NIELS DEN HEIJER

DATE: MAY 8, 2019

BIOGAS UPGRADING

BIOMETHANE & LIQUID CO2

ADDED VALUE TO BIOGAS

PENTAIR

130 locations

United in our belief that the future

of water depends on us

In 34 countries

10,000employees

PENTAIR Biogas 3

CO2 fermentation and purification technologiesfor efficient and safeendproducts.

An extensive product portfolio within qualityand control components.

Innovative solutions – alsofor craft brewers.

Beverage: BreweriesSoft drink bottlersCraft brewersDistilleries

CO2 capture and recoverytechnologies for obtaininga safe endproduct evenfrom a low purity source.

The plants are delivering an end-product that exceedsthe highest demands form ISBT and EIGA.

Industrial Gases: PetrochemicalLarge industrial groupsIndependent gascompanies

Recovery and upgradingplants for ‘zero-methane’ slip solutions.

The upgrading plants areavailable with two differenttechnologies, dependingon need and plant size.

The recovery plants offer a second value stream.

Energy:Biogas plantsFarmers Industrial GasesLandfill

Safe CO2 technology for remineralising the desaltedseawater, in order to supply regions with scarcewater resources.

The plants are efficient and available and an importantingredient in deliveringdrinking water to the people.

Desalination:ContractorsDesalination plantconsortiums

Relocation of an existingCO2 plant, extending the capicity or developing a special technology for scientific purposes.

Process Services:UniversitiesAny existing projectsor company

After Market Service Serious Service is covering all segment,

offering an extensive service programmeglobally.

PENTAIR

STORIES TO SHAREHaffmans story short

Union Engineering’s story short

4

FoundedIn Fredericia, Denmark

First CO2

plant installed; Coca Cola, Iran

Acquired byBritish Oxygen Company BOC )

1933

1948

1972

Foundedin Venlo, Holland

1984

Acquired by Norsk Hydro Danmark

1994

Sales and productionin China established

1995

Sales and productionin Brazilestablished

2013

Acquisitionof Wittemann, USA

ECO2Brew launched

Acquired by Pentair

CO2mpactBrewlaunched

2017

1967

First CO2

Gehaltemeter, Type GMT

1977

Started to produce CO2

recoverysystems

First Biogas upgradingplantsinstalled

2010

Digital CO2/O2

GehaltemeterType c-DGM

20062009

Acquired by Norit togetherwith Südmo

Haffmans, Südmo, NoritProcess Technology and X-Flow acquired by Pentair

2011

Combinedforces allow us to offer greattechnologies, components, units andSeriousServiceglobally!

PENTAIR Biogas5

SEGMENT: ENERGY

LEADING PARTNER IN BIOGAS UPGRADING

PENTAIR

LEADING PARTNER IN CO2 & BIOGAS UPGRADING

20.000+

MEASUREMENT DEVICES

40+

MEMBRANEPLANTS

300+

AMINE PLANTS

1400+

CO2 PLANTS

HAFFMANS & UNION: COMBINING 60 YEARS OF PROCESS TECHNOLOGY6

CO2/O2 in BreweriesBioSENSE

5000 Nm3/h Biogas55000 Nm3/h Industrial

3 Stage & 2 Stage with CO2

> 3000 Nm3/hNo Methane Slip

Market Leader inBreweries & CSD

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3 4

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http://www.google.dk/url?sa=i&rct=j&q=&esrc=s&source=images&cd=&cad=rja&uact=8&ved=0ahUKEwijie_i3MzKAhXDDiwKHU4HC6wQjRwIBw&url=http://cosgb.blogspot.com/2011/12/british-oxygen-company-ltd.html&psig=AFQjCNGOvgzodYbnUNSykcCk2PxFgk-KWg&ust=1454077988855499

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PENTAIR

BIOMETHANE APPLICATIONS

- USE the CH4 as fuel

- Bio-CNG (LNG) for:

- Trucks

- Buses

- Cars

- USE the CH4 for pipeline injection

- Bio-methane for:

- Transportation

- Electricity

- Heat

PENTAIR Beverage SystemsPENTAIR Process TechnologyPENTAIR

CO2 APPLICATIONS

FROM FEEDSTOCK TO GREEN CO2

THE FUTURE: DRY ICE – POWER-TO-GAS – POWER-TO-LIQUID

PENTAIR

SUSTAINABLE GAS SOLUTIONS – ENERGY/BIOGAS

STANDARDMembrane Solution

Without

CO2-Liquefaction<0,5% METHANE LOSS

ADVANCEDMembrane Solution

Without

CO2-Liquefaction0% METHANE LOSS

ADVANCED plusMembrane Solution

Including

CO2-Liquefaction0% METHANE LOSS

PR

OD

UC

TS

BIO-METHANE→GRID INJECTION

BIO-METHANE → CNG

FOODGRADE CO2

LNGFUTURE SOLUTION


BIO-METHANE → CNG

LNG FUTURE SOLUTION


BIO-METHANE→ CNG

LNG FUTURE SOLUTION

PR

OD

UC

TS

PR

OD

UC

TS

CURRENT PENTAIR PORTFOLIO

ELECTRICITY

LOCAL HEAT

PRODUCT

ANAEROBIC DIGESTION

PRE-TREATMENT (COOLING, HEATING, H2S REMOVAL)

WASTE STREAMS ENERGY CROPS LANDFILL

CHPBIOGAS UPGRADING –PRODUCT PORTFOLIO

WASTE WATER MANURE

AMINE Solution

OptionalCO2-Liquefaction

<0,1% METHANE LOSS


BIO-METHANE→ CNG

LNG SOLUTION

PR

OD

UC

TS

CO2 BOLT SOLUTION0% METHANE LOSS

EXISTING UPGRADER(PENTAIR OR NON PENTAIR)

FOODGRADE CO2

PR

OD

UC

TS

0% METHANE LOSS & CO2 ADDITIONAL REVENUEPENTAIR

BIOGAS UPGRADING - MEMBRANE GAS SEPARATION

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PENTAIR

Low Pressure Stage

ScrubberChillerHeater

Activ Carbon(H2S/VOC)

Low PressureConditioning

High Pressure Stage

Compression High PressureConditioning

Membrane Stage 1 & 2

1st Stage 2nd Stage

Biogas AD

TemperatureConditioning

Revenue Stream

QualityControl

Flare

Membrane Stage 3

3rd Stage

BioMethane

Flare / Digester

Methane Recovery

BIOGAS UPGRADING - STANDARD

BIOGAS PART

Membrane SeparationFan Blower

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Vent

PENTAIR

Low Pressure Stage




High Pressure Stage



1st Stage 2nd Stage

Biogas AD


Revenue Stream

QualityControl

Flare

High Pressure Stage


Purification & Liquefaction Stage

RegenerativeActiv Carbon& Drier

CO2 Liquefier Stripper -Reboiler

BioMethane

BIOGAS PART

Membrane Separation

CO2 PART

Cryogenic Separation

Flare / DigesterMethane Recovery Green CO2 to free air /

Local gas consumption

Fan Blower

BIOGAS UPGRADING - ADVANCED

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7 8

9 10

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PENTAIR

Low Pressure Stage




High Pressure Stage



1st Stage 2nd Stage

Biogas AD


Revenue Stream

QualityControl

Flare

High Pressure Stage



RegenerativeActiv. Carbon& Dryer

CO2 Liquefier Stripper -Reboiler+ Pump

BioMethane

Revenue Stream

Liquid CO2

Storage tankFoodgrade

Liquid CO2

BIOGAS PART

Membrane Separation

CO2 PART


Flare / DigesterMethane Recovery

Fan Blower

BIOGAS UPGRADING ADVANCED plus

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Green CO2 to free air /


INTEGRATED PROCESS – NO CH4 SLIP – FOOD-GRADE CO2 – LESS ENERGYPENTAIR

ADDITIONAL REVENUE WITH CO2 -BOLT-ONBiogas AD

Flare

High Pressure Stage



RegenerativeActiv Carbonand Drier

CO2 LiquefierSystem

Reboiler +Stripper + Pump

Revenue Stream

Liquid CO2

Storage tank

EXISTING BIOGAS

UPGRADING PLANT

CO2-Bolt-On

Methane Recovery ~2% of Biogas flow

• CO2 purity acc EIGA Specs

Foodgrade

Liquid CO2

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Green CO2 to free air /


PENTAIR

Low Pressure StageScrubberChillerHeater



First StageAbsorbor

Second StageH2S Polishing Compressor

Biogas AD

Dryer

Revenue StreamQualityControl

Flare

BioMethane

Flare / Digester

Fan Blower

BIOGAS UPGRADING – Amine Solution

BASED ON OVER 60 YEARS OF EXPERT KNOWLEDGE15

Water Scrubber

StripperReboiler

Amine Treatment

Heat for Digester

High Pressure Stage



RegenerativeActiv Carbon& Drier

CO2 Liquefier Stripper -Reboiler

Optional CO2 PART


PENTAIR

REFERENCES BIOGAS UPGRADING AND BOLT-ON CO2

Our installed plants can fuel 133,000 homes or 275,000 cars

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South Africa & Philippines

1 Advance Plus2 CO2 recovery plants

North America3x3220Nm3/hSupported by

US offices

UK & Ireland10x Standard Solution 2x Advanced Solution

6x Advanced Plus Solution1x Bolt-on Solution

Support byIreland office

Scandinavia-1x Standard Solution

-1x Amine SolutionSupport by

DK office

Central Europe4x Standard Solution5x Advanced Solution

5x Advanced Plus SolutionSupport by

NL office

PENTAIR

BIOGAS UPGRADING in Nederland

In 2018 was de productie van Bio-methaan +/- 1,170 GWh (source EBA)

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NL AD – Bio-Methane2018 :

268 bio gas installaties met WKKGeïnstalleerd vermogen 119 MW

Totaal geleverd vermogen 17,0840,720 GWh

34 installaties met bio-methaan productieTotaal geleverd vermogen van 1,170 GWh

6 AD installaties leveren CO2

PENTAIR

NL 2011: 450 Nm3/h BIOGAS TO GRID & GREEN CO2

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6 YEARS OF LIQUID CO2 RECOVERY

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PENTAIR

BIOGAS UPGRADING – COMPACT ENCLOSED SKID

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KALUNDBORG BIOENERGI

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BIGADAN BUILDS BIGGEST BIOGAS PLANT IN DK

5000 Nm3/h heat recovery to AD

PENTAIR

Westdorpe (Aben) 2018

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Start productie Q1 2019

3600 Nm3/h Biogas Jaarlijkse product Bio-methaan : +/- 19 -20 miljoen Nm3 Jaarlijkse productie CO2: +/- 21,000 Ton

PENTAIR

CO2 from Biogas

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Niels den HeijerProduct Line Manager – BiogasHaffmans [email protected]+31 77 3232 396

PENTAIR PENTAIR Process TechnologyPENTAIR

CO2 FROM BIOGAS – QUALITY & EXPERIENCE

FURTHER REFERENCES IN SOUTH AFRICA, USA and PHILIPINES

FOOD SAFETY RISK ASSESSMENT

WITH INDUSTRIAL GAS COMPANY

• Food safety risk assessment completed

• Inline / complete batch analysis before supply

(30 vs. 9 components for industrial CO2)

• 1200+ EIGA samples since 2015

• CO2 complies with food-grade requirements

• Test result: < 2 bacteria / dm3

NL EXPERIENCE

• First plant in operation since 2011

• Mainly bio-waste, vegetable & food waste

• Higher level of impurities -> process control

• CO2 goes via industrial gas companies and

OCAP pipeline mainly to greenhouses

• Demand driven by greenhouses

UK EXPERIENCE

• Energy crops / unprocessed vegetable matter

• High quality -> low risk

• CO2 goes via industrial gas companies to

food & beverage and industrial applications

• Shortage in conventional sources -> imports

• Regional demand & distant industrial sources

PENTAIR 24

SECURITY AND FUTURE PROOFING

CO2 - QUALITY

Food Grade-EIGA DOC 70/08 UK Industrial Grade

-Stricter Values required-Detailed analysis is required-FSRA Mandatory by law

Current Feed stock: Unprocessed vegetable matter + Energy Crops

• FSRA Air Liquide & Pentair has been completed

• Since July 2015 > 400 samples have been analysed

according to the EIGA standard

• Key Indicaters to be installed to avoid non-conforming

product

Air Liquide + Pentair-Haffmans

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PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS

CURRENT NL Bio CO2 to greenhouses (OCAP)

OCAP

• 300.000 ton CO2 jaarlijks via OCAP

• Vraag glastuinbouw +/- 2 miljoen ton

• OCAP ontvangst station in Rotterdam

• +/- 4 AD installaties leveren nu aan OCAP

• Ruimte voor meer!

PENTAIR TECHNICAL & ECONOMIC FEASIBILITY OF SUSTAINABLE CO2 FROM BIOGAS

Nr. Plant Location Process

1. Air Liquide Ince Fertiliser

2. Air Liquide Wissington Bio-ethanol

3. Azelis Billingham Fertiliser

4.NorthBritish

EdinburghDistillery

Fermentation

5. Yara TeessideBio-ethanol

(Mothballed) + Import terminal

6 Yara Purfleet Import Terminal

CURRENT UK CO2 PRODUCTION SITES

2

3

4

5

Air Liquide3rd PartyYara

North British

Yara (Teesside)

Azelis

AL - Ince

AL - Wissington

CO2 Import terminal

CO2 Import terminal

6

Yara (Purfleet)

1

Centralized supply model

• Demand: 500.000 t/a

• Capacity: 450.000 t/a

• Few main production sites

• Import: 100.000 t/r (Shipment every week)

• 9 AD-Plants: 65.000 t/a

PENTAIR

METHANE SLIP, GHG AND RHI IMPACT

27

0

5

10

15

20

25

30

35

Maize (1% CH4 loss) Maize (0% CH4 loss)

GH

G E

mis

sio

ns

(gC

O2

e/M

J o

f b

iom

eth

ane

inje

cte

d)

Scenario

Biogas upgrading - other

Biogas upgrading - methane slip

Biogas Production

Silage - production & transport

Harvesting - diesel

Cultivation - diesel

Pesticides

Soil N2O emissions

Fertiliser Production

Seed

1 %

0 %27.5 – possible future GHG limit?

34.8 – current GHG limit

PENTAIR

Questions?

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Niels den HeijerProduct Line Manager – BiogasHaffmans [email protected]+31 77 3232396

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2 countries 10,000 added value to biogas · pentair biogas 3 co2fermentation and purification...

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