1. - university of hawaii · 2018-08-02 · dumped 55 gallons of sand on top of packer. ran in hole...

• 1. -.... -••· f'' ......

KS-09 WORKOVER HISTORY

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LOCATION: 8957.5' N & 9771.7' E OF THE KALIU BENCHMARK ELEVATION: 618' ABOVE MSL. ALL DEPTHS FROM RXB, 25' ABOVE

G.L.

02/28/93 Depth 4564' Rigged up Halliburton to 3 II side outlet. Pressure tested lines to 2000 psi. Pumped 20 barrels of 10% caustic water and flushed lines with 5 barrels of fresh water. Rigged up and pressure tested FloLog wire line lubricator. Ran temperature log. Temperature at 705' was 354°F. Had small leak at wireline packoff. Ran 3 armed caliper to 600'. Blew wire line out of hole. Blew wellhead gas to atmosphere through ~~~ hole at top of lubricator grease head for approximately 5 minutes before well was shut in. Swab valve did not seal. Wireline pulled out of rope socket leaving caliper tool in hole. Tools in hole:

1' -Rope Socket 7' - 1-11/16 sinker bars - (2)

70 11 - 1% 11 caliper tool

Total length 20.8'

03/01/93 Depth 4564' Had small leak in 3 11 bull plug above swab valve. Bled off pressure. Replaced companion flange and bull plug. Howco pumped 20 barrels of 10% caustic water with 5 ppb H~S scavenger. Flushed lines and wellhead with 5 barrels ot water. Replaced swab valve. Secured well. Waited on wire line fishirig tools.

03/02/93 Depth 4564' Rigged up Howco to 3" swab valve and 3 II wing valve. Pumping water into well through swab valve at ~ barrel per minute. Wellhead pressure at 2100 hours was 1350 psi.

03/03/93 Depth 4564' Pumped water through swab valve into well at ~ barrel per minute. Switched to wing valve. Continued pumping water. Had no H2S below swab valve. Rigged up FloLog and lubricator. Waited on DOH concurrence of wire line work plan. Wellhead injection pressure = 250 psi at 1900 hours. Added 0 2 scavenger to injection water starting at 2000 hours.

03/04/93 Depth 4564 Pumped water with oxygen scavenger through wing valve at 250 psi for 24 hours. Received plan concurrence from DOH at 1130 hours. Picked up fishing tools on wire line.

KS-09 WORKOVER ~ 1

Removed swab valve. Installed lubricator. Tested lubricator to 2500 psi. Weld on 9%" collar leaked. Laid down lubricator and wire line tools. Secured well. Waited on daylight. Had no H2S emissions beyond cellar during operations.

03/05/93 Depth 5464 1

Pumped water through wing valve with oxygen scavenger at ~ barrel per minute and 250 psi. Hydrotested lubricator. Repaired weld. Retested OK. Picked up lubricator and wire line tools. Bled gas from below swab valve through caustic solution. Had low volume, high concentration of ~S seeping through master valve. Removed swab valve and aaapter flange. Installed and tested lubricator above top master valve. Repaired leaks. Retested lubricator to 2000 psi, OK. Opened master valves. Ran in hole with 6" guide, wireline catch, jars and sinker bars checking for fish to 3000 I. Pulled out of hole. Flushed lubricator. Closed master. Removed lubricator. Had no recovery. Laid down tools. Reinstalled adapter flange and swab valve. Rigged and pumped water at ~ barrel per minute and 250 psi through swab valve. Secured well at 2000 hours. Waited on daylight.

03/06/93 Depth 4564 1

Pumped water with oxygen scavenger through swab valve at ~ barrel per minute and 250 psi. Waited on daylight. Switched injection water to wing valve. Picked up 4" bell guide on wire line fishing tools. Removed swab valve and adapter flange. Picked up and installed lubricator. Tested lubricator to 2000 psi, OK. Opened master valves. Ran in hole with tools. Tagged liner top at 3032 I. Set down at 4551 1

• Worked tools. Pulled out of hole. Closed masters. Flushed and removed lubricator. Had no recovery. Checked tools. Reinstalled and retested lubricator, OK. Opened masters. Ran in hole to 4557 1

• Engaged fish. Pulled 1000# 1 S over string weight. Lost all over pull after jars activated. Pulled out of hole. Closed masters. Flushed and removed lubricator and had no recovery. Checked tools. Tools had released from fish. Reinstalled adapter flange and swab valve. Switched injection to swab valve. Injected ~ barrel per minute water at 250 psi. Secured well at 1700 hours. Top of fish 4557 I. Had no ~S emissions during operations.

03/07/93 Depth 4564 1

Pumped water through swab valve at ~ barrel per minute and 250 psi. Shut in well at 1430 hours. Rigged Howco to wing valve. Tested lines to 2200 psi, OK. Shut in wellhead pressure 320 psi at 1510 hours. Howco pumped 10 barrels viscous fluid, then mixed and pumped 82 cubic

KS-0 9 WORK OVER 2

feet Hawaiian cement with 40% SSA-1, 0.65% CFR-3 and 3% CaC12 mixed at 16 pounds per gallon. Displaced with 22 barrels water at ~ barrel per minute. Initial displacement wellhead pressure = 180 psi. Final displacement wellhead pressure = 170 psi. Cement in place at 1620 hours. Monitored wellhead pressure; 1630 hours = 200 psi, 1645 hours - 250 psi, 1800 hours - 440 psi, 2000 hours - 620 psi and 2300 hours - 660 psi.

03/08/93 Depth 4564' Rigged up slick line lubricator and ran sinker bars to 266' ground level (291 KB). Flushed out to bottom master valve with caustic water. Nippled down lubricator. Flushed everything to below bottom master valve. Secured well. Had no H2S beyond cellar.

03/09/93 Depth 4564' Bled pressure from wellhead, had no H2S. Removed top master valve. Nippled up single gate, hydril and work stand. Rigged up cranes. Ran in hole with 8~" bit on 3~" drill pipe to top of cement at 266' ground level (GL). Tripped for bridge plug. Set Pak-N-Pik at 257' GL. Displaced fluid in well with 11 barrels with caustic water. Had no H2S while displacing. Pulled out of hole. Dumped 55 gallons of sand on top of packer. Ran in hole with open ended drill pipe to 235' GL. Howco mixed and pumped 45ft3 Hawaiian cement with 40% SSA-1, 0.65% CFR-3 and 3% CaC12 • Displace with 1 barrel water. Cement in place at 18:45 hours. Estimated cement top at 127' GL. Laid down 3~" drill pipe. Shut in well and monitored pressure. Waited on cement.

03/10/93 Depth 4564' Waited on cement. Wellhead pressure zero. Bled Pressure from below expansion spool packing through H2S abatement equipment. (Had 250 ppm H2S below packing.) Ran wire line to top of cement plug at 123'. Closed in well with 0 psi and waited on cement.

03/11/93 No activity.

03/12/93 No activity.

03/13/93 Depth 4564' Waited on cement. Had zero wellhead pressure for 2 days. Pressure tested plug in 9%" casing. Had slow bleed off from 2500 psi to 2100 psi. Had 50 psi on 9%" by 13~· annulus. Bled pressure off through caustic abatement. Continued to have very low volume bleed of 60 ppm H2S from annulus. Unable to detect any H2S in cellar. Prepared to remove wellhead. Removed master valve. Installed 10" by 3" SSA and 3" swab valve. Hot head

KS-09 WORKOVER 3

installed new casing head on threaded 13o/a" casing stub and tested weld, OK.

03/14/93 Depth 4564' Wellhead pressure zero. Had no H2S in cellar. Had 60 ppm H2S at very low volume in 13o/a" by 95fa" annulus. Removed expansion spool and packing. Had to cut centralizer out of 13o/a" casing bowl. Removed casing head. Cleaned out hard cement in 13o/a" by 95fa" annulus to below pin on 13o/a" casing. Backed out 13o/a" pin. Installed 135fa"-SM SOW casing head with 13o/a", K-55, 681 , SLHC casing stub, into collar at cellar bottom. Made up casing joint with 10, sao ft/lb torque. Secured well. NOTE: 9o/s" casing had expanded 7" above original cut off height.

03/15/93 Depth 4564' Wellhead pressure zero. No ~S. Installed and repacked 13o/a" by 10" - 1500 expansion spool. (Cut 7" off of 95fau casing prior to welding on bit guide.)

03/16/93 Depth 4564' Wellhead pressure zero. Had no H2S. Energized expansion spool packoff with 3500 psi. Installed side outlet valves on casing head and expansion spool. Installed 10"-1500 master valve. Filled 13o/a" by 9%" annulus with nitrogen at 1200 psi. Tested expansion spool valves and master valve to 1200 psi with nitrogen. Had no leaks. Secured well for night with all valves closed on 1200 psi nitrogen pressure.

03/17/93 Depth 4564' Tested master valve, expansion spool packing and side out let valves to 3500 psi with Howco nitrogen unit. Test OK. Bled off Nitrogen pressure. Nippled up kill and bleed lines. Secured well. Suspended operations.

03/23/93 Depth 4564' Moved in and rigged up Cudd 600 hydraulic snubbing unit.

03/24/93 Depth 4564' Held safety meeting. Continued rigging up Cudd hydraulic 600 snubbing unit and associated equipment. Tested blowout prevention equipment and manifold to 2500 psi. Test witnessed and approved by Eric Tanaka, DLNR. Secured well.

03/25/93 Depth 4564' Ran in hole with 8~" drilling assembly. Cleaned out cement from 121' to 210'. Secured well for night.

KS-09 WORKOVER 4

03/26/93 Depth 4564' Held safety meeting. 270' and sand to 288'. tool. Milled up top Retrieved Pac-N-Pic.

Cleaned out cement from 210' to Tripped for Pac-N-Pic retrieving

slips on Pac-N-Pick bridge plug. Secured well for night.

03/27/93 Depth 4564' Held safety meeting. Rigged up and ran multifingered caliper log from 290' to surface. Casing good. Ran in hole with 8~~~ bit. Cleaned out cement from 291' to 322' holding 2000 psi back pressure. Secured well for night.

03/28/93 Depth 4564' Held safety meeting. Pumped viscous sweep. Cleaned out cement from 322' to 478'. Pressured up well to 1600 psi surface pressure. Pressure bled down to 600 psi in 30 minutes indicating plug leakage or movement. Secured well for night.

03/29/93 Depth 4564' Held safety meeting. Cleaned out cement plug from 478' to 571'. Washed well bore at 2 barrels per minute with well shut in from 571' to top of 7 11 liner hanger at 3024'. Well took 2 barrels per minute at 440 psi well head pressure. Secured well for night. Continued pumping into well.

03/30/93 Depth 4564' Held safety meeting. Pumped water at 2 barrels per minute with 440 psi wellhead pressure. Snubbed out of hole. Made up 5~ II overshot. Snubbed into hole. Secured well for night. Continued pumping into well.

03/31/93 Depth 4564' Held safety meeting. Stripped into hole with 5~ II midway overshot to bridge at 4399' . Pumped 5 barrels per minute down tubing and 2 barrels per minute down backside while maintaining constant level in mud tank. Washed out to 4530'. Worked over fish from 4530' to 4543'. Stripped to shoe at 4169'. Secured well for night. Continued pumping into well at 250 psi wellhead pressure.

04/01/93 Depth 4564' Held safety meeting. Pulled out of hole. Recovered 19' of fish, leaving 1~' of in hole. Secured well for night. Pumped ~ BPM water into well continuously.

04/02/93 Depth 4564' Held safety meeting. Snubbed into hole with 6 11 junk mill to 4549'. Washed to 4552' while circulating with back pressure. Had lOppm H2S in water at shaker. Closed in well and pumped down annulus and drill pipe. Worked mill

KS-09 WORKOVER 5

. •' . --.. (~ .

to 4552 1 • Tools began hanging up. Worked free and

pulled to shoe at 4169 1• Secured well for night. Pumped

2 barrels per minute at 250 psi during night.

04/03/93 Depth 4564 1

Held safety meeting. Washed 6" hole from 4552 I to 4555 I •

Stuck pipe and worked free. Pumped sweep to clean hole and worked back to 4555 1

• Stuck pipe and worked free repeatedly while pumping sweeps. Had 35ppm ~S in sulphur water at shaker. Closed in well and pumpea down annulus. Pulled out of hole and secured well for night. Continued pumping 2 BPM.

04/04/93 Depth 4564 1

Held safety meeting. Displaced wellbore to bottom of 7" casing at 4169 1 with nitrogen. Secured well. Rigged down Cudd unit. FINAL REPORT

KS-09 WORKOVER 6

- . -~ - - -...

GROUND SURFACE

CELLAR

17-1/2" IIOLE ----

12-1/4• IIOLE -------J·

2C1' CASING SIIOE

--- 935'

9-5/ll" TIE BACK HANGER TOP 1798"

13-3/5" CASING SIIOE ---- 2005'

9-5/5" cASING SHOE ------ 3224'

8-1/:t' HOLE ------- P.At-------- 1' 291 l-80 BT&C LINER 3024'-3569' + 1' 23f ALLOY NEW VAU X 1' BvnRESS XOVER 3569-3571 + 1' 291 L-BO NEW VN.t LINER

ll" HOLE---------~-

TO 4564' UO TO 44 27' TV0

OPEN HOLE COIAPLEnON

3571'-41&9', CEIAENTEO 3024'-4169'

PUNA GEO'l'HEHMAL VENTUHE

PRODUCTION WELL KS-9 CASING SCHEMATIC

AS COMPLETED 1/22/93

bAK I /tl/13 REV. 2

.... TIJ'I.O!I Fll.E:I'IIII\KS!MSIJU.IITTG FIGURE NO.

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WELL HISTORY KS-9

LOCATION: 8957.5' N & 9771.7' E OF THE KALIU BENCHMARK ELEVATION: 618' MSL. ALL DEPTHS FROM RKB, 25' ABOVE G.L.

11/30/92 Depth 0' Prepared to move and rig up on KS-9.

12/01/92 Depth 0' Finished rig down and move to KS-9.

12/02/92 Depth 0' Moved and rigged up on KS-9.

12/03/92 Depth 101' Rigged up on KS-9.

12/04/92 Depth 101' Rigged up on KS-9. Lined reserve pit. Installed sound proofing.

12/05/92 Depth 101' Completed rigging up on KS-9

12/06/92 Depth 161'

12/07/92

Made up bottom hole assembly. Rig on day rate at 0700 hrs. Cleaned out cement from 97' to 101'. Spudded at 0800 hours. Drilled 26" hole from 101' to 161' with mud motor and foam using 4 air compressors.

Depth 236' Drilled 26" hole from 161' to foam. Tripped to check tools. hole to 236'.

174' with mud motor and Continued drilling 26"

12/08/92 Depth 410' Drilled 26" hole from 236' to 410' with mud motor and foam.

12/09/92 Depth 559' Drilled 26" hole from 410' to 559' with mud motor and foam.

12/10/92 Depth 723'

02/07/93

Drilled 26" hole from 559' to 700' with mud motor and foam. Had no returns from 670'. Strapped out of hole. Made 8 bailer runs to obtain water samples. Fluid level approximately 600'. Ran in hole to 700'. Drilled 26" hole to 723' with mud motor and foam.

WELL HISTORY KS-09 1

12/11/92 Depth 902 1

Drilled 26" hole from 723 1 to 902 1 using mud motor and foam with no returns. Tripped for drilling assembly. Wait on daylight.

12/12/92 Depth 942 1

Ran in hole at 0700 hours to 862 1• Had 3440 PPM CO at

862 1• Cleaned out fill to 902 1

• Drilled 26" hole from 902 I to 922 I with foam without returns. Drilled and reamed through boulders and fractures to 942 1

• Tripped to lay down corkscrewed drill pipe and 26" stabilizer.

12/13/92 Depth 946 1

Cleaned out fill from 939 I to 942 I. Drilled 26" hole from 942 1 to 946 1 with foam and 5 air compressors without returns. Tools were hanging up. Unable to make hole. Tripped for slick drilling assembly. Cleaned out fill from 941 1 to 946 I without returns. Made wiper trip. Had 5 I fill. Pulled out of hole. Rigged up to run 20 11

casing.

12/14/92 Depth 946 1

Ran 26 joints of 20 11, 94#, K-55, BT&C casing with shoe at

935 1 and stab in float collar at 875 1• Ran stab in sub

on 5 11 drill pipe. Stabbed into float collar. Cemented as follows; Howco mixed and pumped 170 bbls of calcium chloride water, 120 cubic feet of Super Flush, and 120 cubic feet of Hawaiian cement mixed at 14.5 ppg followed by 3074 cubic feet of Hawaiian cement premixed 50#/sk Spherelite, 40% silica flour, 4% gel, 1.25% CFR-3, 0.5% Halad 22-A and 3% of calcium chloride mixed at 11.0 ppg plus 250 cubic feet Hawaiian cement premixed 40% silica flour, 0.65% CFR-3 and 3% calcium chloride mixed at 15.5 ppg. Dropped latch-in dart and displaced with 15.5 bbls of water. Bumped plug. Pulled drill pipe. Centered 20 II casing. Waited on cement. Cut 30 II conductor. Did outside job from surface, Howco mixed and pumped 530 cubic feet Hawaiian cement premixed 1:1 perlite, 40% silica flour, 0.65% CFR-3 and 3% calcium chloride while dumping sand and cinders into annulus. Waited on cement.

12/15/92 Depth 946 1

02/07/93

Cemented 30 11 by 20" annulus as follows; from surface Halliburton mixed and pumped 530 cubic feet of Hawaiian cement premixed 1:1 perlite, 40% silica flour, 0.65% CFR-3 and 3% calcium chloride while dumping cinders and sand. Did not fill annulus. Waited on cement. Filled annulus with 486 cubic feet of Redi Mix with 1.5 11 aggregate from surface. Waited on cement.


12/16/92 Depth 946 1

Cut off 20" casing and 30" stub. Welded on 20" flange. Installed 20" riser. Nippled up 20" annular preventer, rotating head and flow line. Ran in hole with slick drilling assembly. Filled hole. Pressured up to 1500 psi with Halliburton. Pressure dropped to 1460 psi in 30 minutes. Test OK, witnessed by Eric Tanaka.

12/17/92 Depth 953 1

Drilled float collar at 835 1• Cleaned out cement to shoe

at 933 1• Tested casing to a 0.7 gradient. Drilled out

shoe. Pressured up to 100 psi. Pressure fell to 0 psi. Pumped into formation at 2~ bpm with 0 psi. Cleaned out cement to 946 1 and drilled 17~" hole from 946 1 to 953 1

with partial returns. Tripped for OEDP. Through OEDP at 936 I Howco mixed and pumped 20 bbls water, 10 bbls calcium chloride water, 1 bbl water, 10 bbls Super Flush and 1 bbl water followed by 250 cubic feet Hawaiian cement premixed 40% silica flour, 3 calcium chloride and 0.65% CFR-3. Displaced with 14.5 bbls of water. Hole filled. Pulled 5 stands. Squeezed with 2~ bbls of water. Final pressure 1500 psi. Tripped for drilling assembly. Waited on cement. Cleaned out cement from 866 1 to 928 1

• Waited on cement. Cleaned out to 928 1

and tested to 0.7 psi/ft gradient. Cleaned out cement to 938 1

• Retested. Established pump in rate of 3 bpm at 130 psi. Tripped for OEDP. Through OEDP at 936 1

, Howco mixed and pumped 250 cubic feet Hawaiian cement premixed 40% Silica Flour, 3% calcium chloride and 0.65% CFR-3. Displaced with 14.5 bbls water. Squeezed 4~ bbls at 1500 psi.

12/18/92 Depth 1205 1

Tripped for slick drilling assembly. Waited on cement. Cleaned out cement to 927 1

• Waited on cement. Cleaned out cement to 953 1

• Tripped for 17~" drilling assembly. Installed diverter line. Drilled 17~" hole from 953 1 to 1205 1 with partial mud loss.

12/19/92 Depth 1624 1

Drilled 17~" hole from 1205 I to 1606 I with partial losses. Made wiper trip. Drilled 17~" hole to 1624 1

•

Had TLC at 1620 1• Tripped for OEDP. Through OEDP at

1610 1, Howco mixed and pumped 150 cubic feet of cement

premixed 40% silica flour and 0.65% CFR-3 displaced with 15 bbls of water. Tripped out.

12/20/92 Depth 1624 1

02/07/93

Waited on cement 4 hours. Unable to fill hole. Tripped in to cement at 1537 1

• Through OEDP at 1509 1 Howco mixed and pumped 150 cubic feet Hawaiian cement with 40% silica


flour and 0.65% CFR-3. Displaced with 15 bbls of water. Tripped out. Waited on cement. Unable to fill hole. Fluid level at 700 I • Tripped into top of cement at 1485 I • Through OEDP at 920 I, Howco mixed and pumped 200 cubic feet Hawaiian cement with 40% silica flour and 0.65% CFR-3. Displaced with 5 bbls water. Tripped out. Waited on cement. Unable to fill hole. Tripped in OEDP to 930 1

• Howco mixed and pumped 200 sacks neat cement with 5 bbls Super Flush ahead and 4 bbls behind. Tripped out. Waited on cement.

12/21/92 Depth 1625 1

Ran in hole to cement at 1485 1• Through OEDP at 930 1

,

Howco pumped 80 barrels of high viscosity pill with 40#/bbl walnut hulls followed by 400 cubic feet neat Hawaiian cement. Displaced with 5 barrels of water. Tripped out. Waited on cement. Fluid level at 570 1

•

Filled hole with 202 barrels of water. Ran in hole with 17~" BHA. Cleaned out cement from 927 I to 1624 I with full returns. Drilled 17~" hole to 1625 1

• Lost circulation. Tripped for OEDP.

12/22/92 Depth 1625 1

Lost 152 bbls fluid in 2 hours. Through OEDP at 1210 1,

Howco pumped 10 bbls of calcium chloride water, 3 bbls of water, 10 bbls of Super Flush, and 3 bbls of water followed by 425 cubic feet of Hawaiian cement premixed 1:1 perlite, 40% silica flour, 0.65% CFR-3 and 0.5% Halad 22-A. Displaced with 10 bbls of water. Tripped out. Waited on cement. Fluid level at 352 1

• Tripped into top of soft cement at 1258 1

• Filled hole and circulated. Through OEDP at 1258 1 Howco mixed and pumped 500 cubic feet of Hawaiian cement with 3% calcium chloride. Displaced with 12 bbls of water. Tripped out. Kept hole full. Fluid level fell 8 1 while waiting on cement. Ran in hole with 17~" drilling assembly. Cleaned out cement from 847 1 to 932 1

•

12/23/92 Depth 1674 1

Cleaned out cement from 932 1 to 1625 1 with losses of 30 to 80 bbls per hour. Drilled 17~" hole from 1625 1 to 1674 1 with 30 to 40 BPH loss. Stuck pipe while taking survey. Worked stuck pipe. Pumped 30 bbls of double strength Super Flush. Worked stuck pipe. Pumped 1625 SCF nitrogen. Worked pipe free with lower hydrostatic head. Pulled out of hole to check drilling assembly and condition mud.

12/24/92 Depth 1955 1

02/07/93

Mixed mud and changed bottom hole assembly. Filled hole with 155 bbls of new mud. Ran in hole to 1366 1

• Reamed


and cleaned out from 1366 1 to 1674 1 with 20 barrels per hour loss. Drilled 17~" hole from 1674 1 to 1955 1 with 10 to 20 barrels per hour loss.

12/25/92 Depth 2050 1

Drilled 17~" hole from 1955 1 to 2050 1 with 20 barrels per hour loss. Circulated 30 bbls Super Flush at 3 bbls/min. Made wiper trip. Reamed out tight spot at 1910 1

• Had no fill. Circulated hole clean with full returns. Pulled out of hole. Rigged up and ran 13%" casing. Ran 1 joint 13%" 68# L-80 New Vam casing, and 52 joints of 13%" 68# K-55 Seal Lock casing. Total length 2005.14 1

• Landed with guide shoe at 2005 1 and screw in float collar at 1960 1

• Ran screw in sub on 5" drill pipe and screwed into float. Circulated and conditioned mud.

12/26/92 Depth 2050 1

Cemented as follows: Howco pumped 40 bbls of Super Flush and 100 cubic feet neat cement plus 954 cubic feet of Hawaiian cement premixed 1:1 perlite, 40% silica flour, 0.65% CFR-3 and 3% gel, plus 1462 cubic feet of Hawaiian cement premixed, 40% silica flour, 50#/Sack spherlite, 0.65% CFR-3 and 4% gel, plus 175 cubic feet of Hawaiian cement premixed 40% silica flour and 0.65% CFR-3. Displaced with 33 bbls water. Had full returns throughout job and good cement returns to surface. Pulled out of hole. Ran 1" in 13o/a" X 20" annulus to 182 1

• Howco mixed and pumped 108 cubic feet Hawaiian cement with 40% silica flour and 0.65% CFR-3. Had good returns to surface. Centered 13o/a" casing. Waited on cement. Rough cut.

12/27/92 Depth 2050 1

Nippled down 20" BOPE. Installed 13o/a"-5M well head. Tested 13%" casing head to 1200 psi. Nippled up BOPE.

12/28/92 Depth 2050 1

Nippled up 135fa" -SM blowout preventers. Set muffler. Installed chokes. Tested 13%" casing to 2000 psi surface pressure. Lost 110 psi over 30 minutes. Test OK. Set plug in casing head and tested BOPE and wellhead valves to 3500 psi. Tested hydril to 2500 psi.

12/29/92 Depth 2050 1

02/07/93

Completed testing BOPE and choke manifold to 3500 psi. Test OK. Witnessed by Eric Tanaka, DLNR. Ran in hole with 12~" BHA. Cleaned out float, cement and shoe. Cleaned out cement from 2005 I to 2016 I • Performed leakoff test. Had breakdown at 450 psi. Established pump in rate. Tripped for OEDP. Tagged cement at 2016 I. Fell through cement. Washed to bottom at 2050 1

•


Established pump in rate of 3 bbls/min at 800 psi. Through OEDP at 2036 1 Howco pumped 10 bbls water ahead followed with 150 cubic feet Hawaiian cement with 40% SSA-1 and 0.65% CFR-3. Displaced with 33 bbls water. Pulled out of hole to 1766 1

• Squeeze away 7 bbls cement at 1900 psi final squeeze pressure. Held for 1 hour. Tripped out of hole.

12/30/92 Depth 2210 1

Waited on cement. Cleaned out cement from 1940 1 to 2050 1

• Ran leak off test to a 0.7 gradient. Had leak off of 1 bbl/hour. Drilled 12~" hole to 2103 1

• Tripped for mud motor. Directionally drilled 12~" hole from 2103 1 to 2210 1

•

12/31/92 Depth 2685 1

Directionally drilled 12~" hole from 2210 1 to 2685 1•

01/01/93 Depth 2837 1

Directionally drilled 12~" hole from 2685 I to 2837 I. Tripped for reaming assembly. Reamed 12~" hole from 2006 1 to 2137 1

•

01/02/93 Depth 2975 1

Reamed 12~" directional hole from 2137 1 to 2837 1•

Tripped for building assembly. Reamed from 2601 1 to 2837 1

• Drilled 12~" hole from 2837 1 to 2975 1•

01/03/93 Depth 3329 1

Drilled 12~" hole with angle building assembly from 2975 I

to 3064 1• Tripped for locked drilling assembly. Drilled

12~" hole from 3064 1 to 3329 1• Had 75 1 to 95 1 per hour

rate of penetration from 3250 1 to 3327 1 and from 3327 1 to 3329 1 torque increased and weight on bit decreased to zero. Checked for flow. Shut in well. Had 329 psi shut in casing pressure. Circulated out kick. Shut in well and mixed barite.

01/04/93 Depth 3329 1

Mixed barite and conditioned mud in pits. Circulated 10.8 ppg mud. Had no flow. Opened rams. Circulated and conditioned mud. Tripped for open ended drill pipe.

01/05/93 Depth 3329 1

02/07/93

Cooled well. Through open ended drill pipe at 3327 1,

Howco mixed and pumped 100 cubic feet Hawaiian cement with 40% SSA-1 and 0.65% CFR-3. Displaced with 59 bbls mud. Tripped for bottom hole assembly. Waited on cement. Cleaned out cement from 3201 1 to 3235 1

•

Circulated and conditioned hole for casing. Picked up liner hanger. Rigged up and ran 37 joints 9%", 47.0#, C-


90, New Vam casing. Ran liner in hole on hanger. Conditioned hole for cement.

01/06/93 Depth 3329' Hung liner on 13o/s" by 95fs" liner hanger with shoe at 3225', float at 3147' and liner top at 1798'. Cemented liner as follows: Howco mixed and pumped 55 cubic feet water, 133 cubic feet Super Flush and 20 cubic feet water followed by 50 cubic feet Hawaiian cement with 40% Silica Flour and 0.65% CFR-3; and 950 cubic feet Hawaiian cement with 50 pounds per sack Spherelite, 40% Silica Flour, 1.25% CFR-3, 0.5% H22A, 0.3% LWL and 4% gel; plus 100 cubic feet Hawaiian cement with 40% silica flour and 0.65% CFR-3. Displaced with 134 bbls mud. Bumped plug. Had good returns during job. Released hanger. Tripped for 12~" bit. Circulated out green cement at 1767'. Waited on cement. Cleaned out cement to top of liner at 1798'. Tripped for 8~" bit.

01/07/93 Depth 3329'

01/08/93

Cleaned out through liner hanger pack off. Cleaned out cement stringers from 2886' to float. Drilled float at 3147'and cement to 3203'. Displaced hole from 1810' to surface with water. Tested liner lap to a 0.9 psi/ft gradient. Test OK. Pulled out of hole. Rigged and ran 46 joints 95/s", 47#, C-90, NV casing. Circulated and latched into top of liner hanger at 1798' with bottom of latch in mandrel at 1805' and float at 1758'. Installed centering ring in well head. Cemented 9%" tieback as follows: with 20 bbls water ahead, Howco mixed and pumped 905 cubic feet Hawaiian cement with 40% SSA-1, 1% CFR-3, 3% calcium chloride and 2% gel. Displaced with 131 bbls water. Had good cement returns to surface. Waited on cement.

Depth 3329' Waited on cement. Nippled down blowout equipment. Cut off 95fs" casing and installed expansion spool. Tested to 3800 psi, test OK. 10" -1500 master valve. Nippled up blowout equipment.

prevention 135/s" X 10" Installed

prevention

01/09/93 Depth 3329'

02/07/93

Ran in hole with bottom hole assembly. Cleaned out cement from 1680' to 1815' and stringers to 1858'. Tested casing to 2000 psi surface pressure for 30 minutes. Tested OK. Tripped for 9%" RTTS packer. Set packer at 500' and tested blinds, expansion spool, master valve and choke manifold to 3500 psi. Tested Hydril to 2000 psi and upper pipe rams to 2500 psi. Released packer and tripped for bottom hole assembly.


01/10/93 Depth 3520 1

Displaced water with 10.0 ppg mud. Ran in hole with open ended drill pipe to obstruction at 2797 1

• Tripped for 8~" drilling assembly. Ran temperature survey at 3203 1

•

Temperature = 347° inside drill pipe. Cleaned out cement, shoe at 3224 1 and cement to 3234 1

• Performed leak off test with 480 psi surface pressure, test OK. Cleaned out cement from 3234 1 to 3329 1

• Drilled 8~" hole from 3329 1 to 3520 1

• Bottom hole temperature was 331°F on survey at 3457 1

• Weighted up mud to 10.5 ppg. Had a 1~" flow. Had no flow while circulating.

01/11/93 Depth 3614 1

Conditioned mud. Raised mud weight from 10.3 to 11.1 ppg. Drilled 8~" hole from 3520 1 to 3614 1

• Tripped for turbo drill. Had no flow while tripping out of hole. Had 105 psi casing pressure build up while out of hole a total of 55 minutes. Took 25 bbl kick at 2587 I •

Circulated bottoms up through full open choke at 50 strokes. Had 2770 ppm C02 and 150 ppm H2S and a 60 bbl total volume increase. Stripped in hole through hydril. Hole packed off at 3576 I. Worked pipe free. Conditioned mud.

01/12/93 Depth 3656 1

Circulated and conditioned mud. Turbo drill failed to operate. Conditioned mud at 11.2 ppg and spotted lignite pill on bottom. Tripped for Mach 3 mud motor with high temperature stators. Directionally drilled 8~" hole from 3614 1 to 3656 1

• Pulled out of hole 5 stands and took 6 barrel kick.

01/13/93 Depth 3900 1

Ran in hole. Circulated and conditioned mud. Tripped for bottom hole assembly. Circulated at shoe. Reamed motor run from 3603 1 to 3656 1

• Drilled 8~" hole from 3656 1 to 3900 1 with full mud returns.

01/14/93 Depth 4181 1

Drilled 8~" hole from 3900 1 to 4181 1• Circulated and

conditioned hole for 7" casing. Short tripped to shoe. Conditioned hole.

01/15/93 Depth 4181 1

02/07/93

Hole started taking mud at 60 barrels per hour after circulating for eight hours. Tripped for open ended drill pipe. Circulated to cool well bore with full returns at 4175 I. Cleaned out 2 I of fill and hole started losing 60 barrels per hour of mud. Through open ended drill pipe Halliburton mixed and pumped 2 barrels of water ahead followed by 40 cubic feet of Hawaiian


cement premixed with 40% SSA-1, 1% CFR-3 and 3% CaC12 • Displaced cement with 70 barrels mud. Tripped for bottom hole assembly and ran in hole to 700 I. Had flow. Circulated 11 ppg mud. Ran in hole. Cleaned out hard cement from 4080 1 to 4170 1

• Pulled out of hole to run pressure-temperature survey.

01/16/93 Depth 4181 1

Ran pressure-temperature survey with traverse from 3000 1

to 4168 1• Maximum temperature 380°F at 3500 1 and bottom

hole temperature 360°F. Ran in hole with 8~" bit to 4170 1

• Conditioned mud. Pulled out of hole. Rigged up and ran 16 joints 7" 29#, L-80 New Vam casing plus 14 joints 7", 29#, L-80 buttress casing.

01/17/93 Depth 4181 1

Ran 7" liner in hole and hung on Midway double slip liner hanger with top of hanger at 3024 1 and shoe at 4169 1

•

Cemented as follows: Howco mixed and pumped 2 bbls H~O, 10 bbls of super flush and 124 cubic feet of Hawai1an cement premixed 40% SSA1 and 1% CFR-3. Displaced cement with 94 bbls mud. Bumped plug. Floats held. Had good mud returns throughout job. Released from liner hanger. Tripped for 8~" drilling assembly. Cleaned out from top of cement at 3000 1 to top of hanger at 3024 1

• Circulated hole clean. Pulled out of hole.

01/18/93 Depth 4181 1

Installed 3~" variable rams. Ran in hole with 6" bit on 4~" drill collars and 3~" and 5" drill pipe to top of cement at 4018 1

• Washed contaminated cement to 4052 1•

Tested lap to 1100 psi. Had 400 psi bleed off in 2 minutes. Tripped for open ended drill pipe. Through open ended drill pipe Howco pumped 90 cubic feet of Hawaiian cement premixed with 40% SSA-1 and 1% CFR-3. Displaced with 28 barrels mud. Pulled 4 stands and squeezed 5 barrels of cement into lap with a final squeeze pressure of 2500 psi. Held pressure for 2 hours. Waited on cement.

01/19/93 Depth 4181 1

02/07/93

Tripped for 8~" bit. Cleaned out cement from 2814 1 to top of liner hanger at 3024 1

• Tested liner lap to 1100 psi, OK. Tripped for 6" bit. Cleaned out cement from 3024 1 to 3126 1 and from 4052 1 to 4162 1

• Pressure tested casing to 1500 psi surface pressure with no pressure drop off. Test witnessed and approved by Eric Tanaka of the DLNR. Tested with 10 ppg mud and a 0. 98 gradient at liner lap and a 0. 85 gradient at 4162 I. Drilled out cement, floats and shoe. Cleaned out cement to 4172 1

•

Performed shoe leak off test with 10 ppg mud to 675 psi


surface pressure and a gradient of 0.68 psi per foot. Shoe tested OK. Cleaned cement to 4182'.

01/20/93 Depth 4330' Tripped for 6 II bottom hole assembly. Drilled 6 II hole from 4182' to 4330' with full returns.

01/21/93 Depth 4564' Drilled 6 11 hole from 4330' to 4533'. Tripped for bit. Drilled 6 11 hole from 4533' to 4545'. Well started taking fluid at 8 barrels per minute. Had drilling break and total lost circulation at 4546'. Drilled ahead to 4564' without returns. Pulled 2 stands and well started to flow. Shut well in. Wellhead pressure increased to 1050 psi. Killed well with 10 ppg mud. Shut well in.

01/22/93 Depth 4564' Kept well dead by pumping mud at intervals as required. Well head pressure varied from vacuum of -9 psi to 70 psi positive pressure. Began pumping water at 0430 hours. Well head pressure slowly increased to 280 psi. Pumped water down backside 8 barrels per minute and 240 to 285 psi well head pressure to cool well while mixing mud, stopped pumping. Shut in well head pressure was 210 psi. Killed well with 9.8 ppg mud at 9 barrels per minute into annulus for 25 minutes. Slowed pump rate down. Pumped 5 barrels per minute mud to keep well dead and pulled out of hole. Closed blind rams. Pumped water at 3.5 barrels per minute into well. Well head pressure increased slowly to 200 psi after pumping one hour. Pumped water into well bore at 8 barrels per minute and 200 to 225 psi. Pressure slowly increasing.

01/23/93 Depth 4564' Continued pumping at 8 barrels per minute. Pumped a total of 5 hole volumes to clear well bore. Shut in well. Cleaned mud pits. Nippled down blowout prevention equipment.

01/24/93 Depth 4564' Laid down drill pipe and tools in mouse hole. Broke and laid down kelly.

01/25/93 Depth 4564'

02/07/93

Nippled down blowout prevention equipment. Tightened all wellhead flanges. Released rig for move to KS-10 at 0700 hours.


LNR T-BK

PGV HELL RECORD

LEASE KAPOHO STATE CKS-9 ) ___ SPUD DATE12/6/92 COMP DATE /-)..5 -"1 3 HELL I K~S_-~9 ____________________ CONTRACTOR PARKER DRLG CO. FIELD KAPOHO PUNA RIG #-"'2-"'3-""1 ________________ _ LOCATION 8957.46 N & 9771.73 E ELEVATION: GROUND~6~1~9 ____________ __

BENCHMARK KAPOHO, PUNA K. B. TO GROUND ___ ~2.:5_'-:--:-----------DIST. HI, COUNTY HI K.B. TO CSG. HEAD ='-3-"'1_,_ . ..,.2_,_0 ________ _

B.H.L. 66.85'S & 659.1B'E OF SURFACE LOCATION TYPE HELL: EXPL. DEV.-=X=X __ _ DEPTH: TD 4564 TVD 4427' ETD 4564' OBSV _____ .STM XX INJ ___ ___

APPROVED PAULSTROUD

SIZE WEIGHT GRADE -lQ.: LINE

20" 941 K-55 13o/e" 681 K-55

96" II 471! C-90 9o/a 471 C-90

___ 7_" 29.01 L-BO

CASING HEAD

HAKE: FOSTER TYPE: ..,..><S-><O.!,!W ________ _ SERIAL I W01672 DESCRIPTION 2 SO OUTLET SIZE 13o/e X 13o/e I • D. ---"'1-"2-':'o/a,___ ____ _ LENGTH --"'1_,_.~4~7 _____ _ PRESS. RATING (PSI) ......=-5 0"-0"-'00<..Jlt.__ __ _

MASTER

HAKE: FOSTER TYPE: 0-SEAL SERIAL 1~60~0"-0~3~7~---

SIZE & I.D. 10-1500 PRESS RATING (PSI) 5000 TEST 3600

HOT HTR DRY HOLE ___ _ COMPANY SUPERVISOR CHUCK WARD

D. WEISGERBER

CASING RECORD

THREAD TOP BOTTOM REMARKS ~ 101' CEMENTED

ftUT'f _o_ __li_5- CEMENTED §!!AL LK _o_ 2005 CEMENTED NEW VAM 1798 3225 CEMEN'fED NEW VAM 1798 1804 CEMENTED 16 NEW VM/3024 4169 CEMENTED 14 BUTTRESS HELL IIEAD ASSEMBLY

EXPANSION SPOOL

FOSTER FLANGED w.o. 2062 2 SIDE OUTLETS 10" 1500X13o/a 5M MIN 10.92 32'a"

5000

VALVES

IIANGER SPOOL XO SPOOL

EXPANSION SPOOL CASING HEAD SWAB

FOSTER 0-SEAL 25777-25779 25782-25780 31/a 5000

5000

BARTON (4) EX'f BONNET 162-006-1 162-008-1 3 1/16 5000

5000

PERFORATIONS

PERFORATED LINER:

PERFORATION DESIGN TEST DATA:

FROM __ 6_" __

TEST DATE lfHP

TO FROM OPEN BOLE 3024

TEMP FLOW RATE

TO 4169

REMARKS! --~N~A~------------------------------------------------

. ·-:::: :···· :::··

.... · ·:.

,----------------GROUIIU SURfACE

26"

17--1/2"

12-1/4"

B-1/2" IIOLE ----

/

/

If' IIOLE ---------

-----------,

2fi' 94f K-55 BI&C CEIJENI£0 0-935'

20" CASI1lG S110E 935'

13-3/8" 68# K-55 SEAL LOCI< CEMHIIED 0-2005'

9- 5/8" HE 8AC1< 11AilGER lOP 1798'

13-3/8" CASING SIIOE 2005'

9··5/e" Hf C-90 !lEW VAM CEMENTED 0- 3224' (TIE!J OACI<)

9-5/8" X 7' 8li11RESS MIDWAY IJOUnl f. SUP UNF.Il 11AtiGfR SET AT 3024'

9·-5/8" CASING SIIOE ----·- 32H'

J" CASING SilO[ 4169'

OPEN 110LE COMPI.EIION

7' 29f L-eo m&c liNER 3024'-3569' -t-7' 231 ALLOY NEW VAM X 7' BUTIRESS XOVER 3569-3571 + 7' 29# L-BO IIEW YAM liNER 3571'-4169', CEMEIHEIJ 3DH'-4169'

---------------PUNA GF.OTIIE:HM/\1. VImTUim

----------------PHOIJUCTION WELL I<S--9

CASING SCHEMATIC AS COMPLETED 1/22/93

TO 4564' MO 10 4127' IVO

bAtt t/2l/U,_ IEV:.;._. -=--2 --1

-- • 01 IEPLOW rllE,rcV\K59AS9ll bWO fiGURE tlO. -------~------------------------- -------------- -- -------------------------------- ----

... · ..

.-:·.

-------~-·----------------------------------------------------------------------• / 1, ~ ... -'

=~===•••• NORTRAK NAVIGATION SURVEY PROGRAM Ver: 2.00PC (03-31-86) ••=•••••=

Date: 1/22/1993 Time: 10:26:45 PAGE: 1 Filename: "KS9SS.SRV" Description: "KS-9 Wellplan Based on Single Shot Surveys

0.000 Tar-et Coordinates: 0.0 N 0.0 E Target TVD: Us 1 Radius of curvature method.

s #

1 2 3 4 5

6 7 8 9

10

11 12 13 14 15

1 1 I

18 19 20

21 22 23 24 25

26 27 28 29 30

31 32 33 34 35

36

MEASURED DRIFT DEPTH ANGLE (feet) (deg)

130.0 258.0 352.0 481.0 590.0

705.0 795.0 918.0

1034.0 1108.0

1167.0 1260.0 1352.0 1445.0 1536.0

1626.0 1740.0 1850.0 1975.0 2080.0

2110.0 2140.0 2171.0 2201.0 2232.0

2264.0 2295.0 2325.0 2358.0 2389.0

2420.0 2450.0 2481.0 2512.0 2540.0

2570.0

1. 50 1. 25 0.75 0.75 0.25

0.00 0.25 0.75 0.75 1.00

0.75 0.75 0.75 0.50 0.50

1.00 1. 25 1. 50 2.00 2.75

2.25 1. 25 0.50 1. 25 2.25

3.25 4.24 5.25 5.75 6.50

6.75 7.75 8.75 9.25 9.75

10.75

DRIFT DIRECTION

(deg)

240.000 245.000 202.000 199.000 265.000

180.000 10.000 33.000 27.000

135.000

141.000 156.000 220.000 268.000 222.000

270.000 255.000 252.000 248.000 272.000

266.000 262.000 205.000 145.000 133.000

140.000 131.000 129.000 116.000 111.000

106.000 106.000 102.000

95.000 90.000

90.000

COURSE LENGTH (feet)

130.0 128.0 94.0

129.0 109.0

115.0 90.0

123.0 116.0 74.0

59.0 93.0 92.0 93.0 91.0

90.0 114.0 110.0 125.0 105.0

30.0 30.0 31.0 30.0 31.0

32.0 31.0 30.0 33.0 31.0

31.0 30.0 31.0 31.0 28.0

30.0

TRUE VERT CAL

DEPTH (feet)

130.0 257.9 351.9 480.9 589.9

704.9 794.9 917.9

1033.9 1107.9

1166.9 1259.9 1351.9 1444.9 1535.9

1625.9 1739.8 1849.8 1974.7 2079.7

2109.6 2139.6 2170.6 2200.6 2231. 6

2263.5 2294.5 2324.4 2357.2 2388.0

2418.8 2448.6 2479.3 2509.9 2537.5

2567.0

VERTCAL SECTION

(feet)

1.5 4.2 5.3 5.9 6.6

6.9 6.8 6.4 5.7 4.7

4.1 3.5 3.6 4.5 5.2

6.3 8.5

11.0 14.6 18.8

20.2 21.1 21.4 21.4 20.8

19.7 18.3 16.4 13.7 10.7

7.3 3.7

-0.6 -5.4

-10.1

-15.4

RECTANGULAR DOGLEG COORDINATES -SEVERITY

(feet) DG/100FT

0.9 s 2.3 s 3.4 s 5.0 s 5.6 s

5.6 s 5.4 s 4.4 s 3. 1 s 2.9 s

3.6 s 4.6 s 5.8 s 6.2 s 6.5 s

7.0 s 7.3 s 8.0 s 9.3 s

10.1 s

10.1 s 10.2 s 10.5 s 10.9 s 11.6 s

12.7 s 14.2 s 15.8 s 17.5 s 18.8 s

19.9 s 21.0 s 22.0 s 22.8 s 23.0 s

23.0 s

1. 5 w 4.2 w 5.3 w 5.9 w 6.6 w

6.9 w 6.8 w 6.4 w 5.7 w 4.7 w

4.1 w 3.5 w 3.6 w 4.5 w 5.2 w

6.3 w 8.5 w

11.0 w 14.6 w 18.8 w

20.2 w 21.1 w 21.4 w 21.4 w 20.8 w 19.7 w 18.3 w 16.4 w 13.7 w 10.7 w

7.3 w 3.7 w 0.6 E 5.4 E

10.1 E

15.4 E

1. 15 0.22 0.92 0.03 0.63

0.22 0.28 0.43 0.07 1. 92

0.45 0.21 0.86 0.60 0.43

0.85 0.34 0.24 0.41 1. 17

1. 88 3.36 3.43 3.63 3.42

3.29 3.70 3.41 4.06 2.97

2.03 3.33 3.72 3.88 3.44

3.33

.,,, ... , . TRUE s MEASURED DRIFT DRIFT COURSE VERTCAL VERTCAL RECTANGULAR DOGLEG # DEPTH ANGLE DIRECTION LENGTH DEPTH SECTION COORDINATES -SEVERITY·

(feet) (deg) (deg) (feet) (feet) (feet) (feet) DG/100FT

3', 2601.0 10.75 94.000 31.0 2597.5 -21.2 23.2 s 21.2 E 2.41 38 2633.0 11.25 94.000 32.0 2628.9 -27.3 23.6 s 27.3 E 1. 56 39 2661.0 12.25 94.000 28.0 2656.3 -32.9 24.0 s 32.9 E 3.57 40 2691.0 13.25 93.000 30.0 2685.6 -39.6 24.4 s 39.6 E 3.41 41 2723.0 14.25 99.000 32.0 2716.7 -47.1 25.2 s 47.1 E 5.44

42 2753.0 13.25 99.000 30.0 2745.8 -54.2 26.3 s 54.2 E 3.33 43 2785.0 12.75 103.000 32.0 2777.0 -61.2 27.7 s 61.2 E 3.22 44 2840.0 14.25 96.000 55.0 2830.5 -73.9 29.8 s 73.9 E 4.03 45 2935.0 16.75 97.000 95.0 2922.0 -99.1 32.7 s 99.1 E 2.65 46 3028.0 19.25 96.000 93.0 3010.4 -127.7 35.9 s 127.7 E 2.71

47 3132.0 21.00 93.000 104.0 3108.1 -163.3 38.7 s 163.3 E 1. 95 48 3216.0 21.50 96.000 84.0 3186.4 -193.7 41.1 s 193.7 E 1. 42 49 3396.0 22.50 97.000 180.0 3353.3 -260.7 48.8 s 260.7 E 0.59 50 3553.0 23.00 95.000 157.0 3498.0 -321.0 55.1 s 321.0 E 0.59 51 3581.0 22.50 94.000 28.0 3523.9 -331.8 55.9 s 331.8 E 2.26

52 3710.0 21.50 98.000 129.0 3643.5 -379.9 61.0 s 379.9 E 1. 40 53 3832.0 20.75 101.000 122.0 3757.3 -423.2 68.3 s 423.2 E 1.08 54 3898.0 22.00 102.000 66.0 3818.7 -446.8 73.1 s 446.8 E 1. 97 55 3992.0 22.50 98.000 94.0 3905.7 -481.9 79.2 s 481.9 E 1. 70 56 4117.0 22.50 95.000 125.0 4021. 2 -529.4 84.6 s 529.4 E 0.92

5"7 4295.0 24.00 95.000 178.0 4184.8 -599.4 90.8 s 599.4 E 0.84 5 ... 4432.0 26.50 95.000 137.0 4308.7 -657.6 95.9 s 657.6 E 1. 82 59 4564.0 26.50 95.000 132.0 4426.8 -716.3 101.0 s 716.3 E 0.00

Final Closure Direction: 98.026 Final Closure Distance: 723.349 feet

,-----------------------

26"

C:l MEN I -- ···------- ----

17-- 1/2" IIOI.E

1 2 - 1/4" HOLE --

to· ------------1

619' ABOVE MSL

ALL DEPTHS MEASURED

----- 2rJ' 94# K-55 Bf&C CEMENlEO 0-935'

20"' CASING SIIOE

---- 935'

13-3/8" CASING SHOE

2005'

· · ------- 9--5/8" 47# C-90 NEW VAM CEMENTED 0-3224' (TIED BACK)

LNR T-BK

PGV WELL RECORD

LEASE KAPOHO STATE (KS-9) SPUD DATE12/6/92 COMP DATE WELL #-=K=S_-~9_______________ CONTRACTOR PARKER DRLG CO. FIELD KAPOHO PUNA RIG # =2~3~1--------~~-------------LOCATION 8957.46 N & 9771.73 E ELEVATION: GROUND-=6=1~9 ____________ __

BENCHMARK KAPOHO, PUNA K. 8. TO GROUND __ =2=5-' ------------=D=I=S~T~·-=H=l~,-=C=O=U=N=T=Y-=H=l __ K.B. TO CSG. HEAD 31.20

B.H.L. 66.85'S & 659.1B 1 E OF SURFACE LOCATION TYPE WELL: EXPL. DEV.~X~X~-DEPTH: TD 4564 TVD 4427 I ETD 4564 I OBSV ___ STM XX INJ __

HOT WTR DRY HOLE ___ _ APPROVED PAUL STROUD COMPANY SUPERVISOR CHUCK WARD

D. WEISGERBER

CASING RECORD

SIZE WEIGHT GRADE THREAD TOP BOTTOM REMARKS ~ LINE ~ 101' CEMENTED __£Q..:_ 94ft K-55 BUTT _o_ 935 CEMENTED 13o/a" 68ft K-55 SEAL LK _o_ 2005 CEMENTED

9%" 471 C-90 NEW VAM 1798 3225 CEMENTED J1L 47ft C-90 NEW VAM 1798 1804 CEMENTED

___ 7_" 29.01 L-80 16 NEW VM/3024 4169 CEMENTED 14 BUTTRESS WELL HEAD ASSEMBLY

CASING HEAD EXPANSION SPOOL HANGER SPOOL XO SPOOL

MAKE: FOSTER FOSTER NLA NLA NLA TYPE: sow FLANGED " " " SERIAL ft W01672 W.D. 2062 " " II

DESCRIPTION 2 SD OUTLET 2 SIDE OUTLETS " " " SIZE 13o/a X 135/a 10"1500X13o/a 5M " " " I.D. 12o/a MIN 10.92 LENGTH 1. 47 32~" II " II

PRESS. RATING (PSI) 50001 5000 " " "

VALVES

LOCATION MAP

WELL KS-9

SCALE

2000'

N

PLAN SHOWING PUNA GEOTHERMAL VENTURE PROJECT

LOCA TIOO OF GEOTHERMAL WELLS KS-1, KS-1A, KS-2, KS-3, KS-4, KS-7, KS-8, KS-9 and KS-~0

BEING PORTION OF L. P. 8177 ON A. P. 4497, L. C. Aw. 8559, Ap. 5 TO C. KAN) KAPOHO, PUNA, HAWAII

TMK : 3RD DIV. 1-4-01 : 2 4 18

.lT.l AUSTIN, TSUTSUMI c!c ASSOCIATES, INC. CIVIL ENGINEERS • SURVEYORS

~ f ~ 820 PI I LAN I STREET, SUITE 102 • HILO, HAWAII 96720

TO: File

Fromo Skip Matlick ~ Subject: KS-9 Groundwater Sample

On December 10. 1992. Well KS-9 was drilled to a KB depth of 699 ft and a sample of the groundwater was successfully bailed from the top of the water table. During drilling. pump pressure and mud returns were monitored to determine the water table depth. Although these parameters were not definitive. it appeared that the water table was encountered at 640 ft KB. Well KS-9 was then drilled to 699 ft and the drill pipe tripped out of the hole. A steel 12.5 gallon bailer was then run into the hole on the sand line. Eight bailer runs were made with the bailer cleaned after each run. Water samples were collected in one-liter plastic bottles previously rinsed with deionized water from runs four through eight. The water temperature was approximately 90°F. These five water samples were allowed to settle and then bottles from runs five through eight were decanted into two 500 ml bottles. These bottles were transported to Brewer Labs with instructions to filter (0.45 um) and analyze for the same parameters as the Well KS-4 groundwater sample.

MAR-08-1993 14:36 FROM BREWER ENVIRONMENTI=L LAB TO 9657254 :p.01

BAE\NER ENVIRONMENTAL INDUSTRIES I INC.

.,.c ............ ,.COI""t'e,..,

CL.IENT: PUNA GEOTHERMAL VENTURE P.O. BOX 30 PAHOA, HAWAII 96778

SAMI'LE LOCATION: PO #5120:3 RELEASE #010

Date/Time Sampled~ 12/10/92 @ 1830 Date/Time Received: 12/ll/92 @ 1532 DATE EXTRACTED: 12/16/92

ANALYSIS

DALAPON

DICAMBA

2,4-0

RtsULT DETECTION mq/L LIMIT mq/L

NO 0.005

NO 0.0002

ND 0.0005

PENTACHLOROPHENOL NO 0.0002

2,4,5-TP (SILVEX) NO 0.0002

OINOSEB NO 0.0025

PICLORAM NO 0.001

OCPA NO 0.0002

NO = NOT DETECTED

BREWER ENVIRONM~L UIIOAATCRIES P.O. BOX 55C MPAI'<O\J. H1 9t-'"8~ ~ (8Q8) 913A-5522 c:t.X •8081 964-s:JCI

LABORATORY ANALYSIS REPORT Environmental laboratories Division

ATTN: BILL TEPLOW

JOB NUMBER: 9093

DATE: JAN. 28, 1993

Matrix; WATER SAMPLE #: KS9-699'

ANAEts!s DATE

12/22/92

12/22/92

12/22/92

12/22/92

12/22/92

12/22/92

12/22/92

12/22/92

METHOD NUMBER

515.1

515.1

51!5.1

515.1

515.1

515.1

5l.S.l

515.1

MRR-08-1993 14:37 FROM BREWER ENVIRONMENTAL LAB TO 9657254 .p. 02

BRE\NER-e•v••a•M•NTAL INDUSTRIES • INC.

.. e R•I'W•Q......._

CLIENT: PUNA GEOTBERMAL VENTURE P.O. BOX 30 PAHOA, HAWAII 96778

SAMPLE LOCATION: PO #51203 RELEASE #010

Date/Time Sampled: 12/10/92 @ 1830 Date/Time Received: 12/~~/92 @ 1~32

asam DEtEC'l'!ON ANALYSIS mq/L LIMIT mq/L

CHLORIDE 470 1

FLUORIDE 0.5 0.1

NITRATE ND 0.01

pH (units} ·· 7.3

SILICA 61 0.01

SULFATE 200 5

TOTAL DISSOLVED 1320 1 SOLIDS

TOTAL SUSPENDED 2697 l SOLZOS

NO =- NOT DETECTED

BReWER INVmONt!EHTAL LA80RATORIES PO !lOX~ ~U.~9e"S1 -Jill! 1!081 ~-532:0' I:AX!!C3t~5~


ATTN: BILL 'l'EPLOW

JOB N1"JMSJ:R: 9093

DATE: JAN. 28, 1993

/

Matrix: WATER SAMPLE #: KS9-699 1

ANXL'ls:ts DATE

12/2S/92

12/28/92

12/21/92

12/14/92

12/23/92

12/28/92

12/16/92

12/15/92

METHOD NUMBER

325.2

340.2

353.3

150.1

370.1

375.4

160.1.

160.2

BRE\NER. RNVIAtiNMIENTAL INDUIITRIRS, INC.

.. c.:"•..-w··~

CLIENT: PUNA GEOTHERMAL VEN'I'URE P.O. BOX 30 PAHOA, HAWAII 96778

SAMPLE LOCATION: PO #51203 RELEASE #010

Date/Time Sampled: 12/~0/94 @ 1830 Date/Time Received: 12/ll/92 @ 1532

USULt bH!C'ftO"N ANALYSIS mq/L LIMIT mq/L

ARSENIC o.os o.os BARIUM 0.13 0.10

CADMIUM NO 0.01

CALCl:TJM 65.9 1.0

CHROMIUM ND 0.01

IRON 12.6 0.01

LEAD NO 0.05

MAGNESIUM 'I 24.7 0.10

MERCURY 0.003 0.002

NICKEL BRL 0.10

POTASSIUM 20.3 4.0

SELEN:I'O'M Bat, O.l

SILVER BRL 0.03

SODIUM 231 0.10

BORON 0.~9 o.os LITHIUM BRL 0.10

VANAD!UM 0.07 0.01

ND = NO'!' DE'rECTED BRL '"'" BELOW REPORT LDII'l'S

8R&WIR ENVIRONMEH'W. LABCRATORIES ::IQ 30C552 l>.t,IIAII«)U. HI ~l """'"''f!:-~:o.G.: .. 4Xt8081~~


A'l"rN 1 BIIJ:, 'rEPLOW

JOB NUMBER: 9093

DATE: JAN. 28, 1993

Matrix: ~s SAMPLE#: KS9-699'

ANAL:Z~I::i ME'rHdb DATE NUMBER

12/18/92 200.7

12/23/92 200.7

12/23/92 200.7

12/23/92 200.7

12/23/92 200.7

12/23/92 200.7

'1.2/23/92 200.7

12/23/92 200.7

12/18/92 245.1

12/23/92 200.7

12/23/92 200.7

12/23/92 200.7

12/23/92 200 •. 7

12/23/92 200.7

1.2/23/92 Z00.7

12/23/92 200.7

12/23/92 200.7

~pproved b~ Mj_Jio -~ mT~ P.c:r~

Summary

PUNA GEOTHERMAL VENTURE WELL KS-9 CLEANOUT FLOW OPERATIONS REPORT

April 20, 1993

The planned cleanout flow of production well KS-9 was completed successfully on April 20, 1993. The test objectives were accomplished and the test was terminated after 3 hours and 39 minutes of steam-dominated flow. Average flow rate for this period was 126,000 lb/hr, and the average wellhead pressure was 1,910 psig. The maximum flow rate was 179, 000 lb/hr at a wellhead pressure of 1,900 psig. The well's potential is much greater, but higher rates were not needed to achieve the cleanout objective, and the rate was purposely constrained to avoid possible problems of excess H2s emissions or liquid carryover from the atmospheric separator. At least within the limited range of the cleanout flow, the well's deliverability conformed to its predicted performance, which indicates it has an excess of capacity for the 25-MW power plant.

Because of problems encountered during the February 8, 1993, flow of KS-9, more elaborate procedures for H2S abatement and personnel safety were implemented for the April 20 operation. The new abatement procedures were fully effective with respect to both personnel safety and environmental permit compliance.

Following the cleanout flow, the temporary piping was removed and the permanent production piping was connected to the wellhead. KS-9 was restarted the next day at about 1300 hrs, supplying steam to the power plant.

Background

The cleanout flow operation on April 20, 1993, constituted the completion of the aborted cleanout flow on February a, 1993. The February 8 operation consisted of a 30-minute flow period followed by a scheduled shutdown to inspect the wellhead and tighten flange bolts. Early in the 30-minute period, there was an excessive release of H2 S resulting from unexpected startup flow conditions in the piping and consequent failure of the chemical abatement to work effectively. PGV elected to postpone resumption the nominal fourhour flow on February 8 pending a review and redesign of the abatement procedures.

During the February 8 cleanout flow, NaOH solution and water were injected into the flowline upstream of the atmospheric separator, in accordance with common H2S abatement practice. This method was effective on Well KS-8 in August 1992 and worked well on KS-9 after the onset of steam-dominated flow. As with any chemical abatement, thorough mixing of the NaOH solution with the flow stream is essential for an effective reaction. The normal production of

PUNA GEOTHERMAL VENTURE WELL KS-9 CLEANOUT FLOW OPERATIONS REPORT April 20, 1993

steam in such a well flow operation provides the necessary turbulence for effective mixing and abatement. However, on February 8, steam flow from KS-9 was unexpectedly preceded by nine minutes of production of condensate and noncondensible gases which probably formed a stratified flow in the pipe without sufficient turbulence for mixing with the NaOH solution. The April 20 cleanout flow employed new procedures to assure effective abatement and to improve monitoring for earlier warning of an abatement failure. These procedures are detailed in the "Revised Cleanout Flow Procedure, Production Well KS-9, April 19, 1993". The principal revision in the startup abatement procedure was to inject NaOH solution upstream and immediately downstream of the throttling valve where flow conditions would be turbulent, even in the absence of steam flow.

Introduction

This and other cleanout flows at Puna are designed primarily for cleanout and sampling purposes and are not intended to be comprehensive well tests. The duration of flow and data acquisition program are not adequate for complete well test or reservoir analyses. A static pressure and temperature survey was run in KS-9 on February 7, but none were run in conjunction with the April 20 cleanout flow. PGV decided against running additional surveys to avoid the risk of any associated problems which could delay the startup and possibly jeopardize the project.

Description of Cleanout Flow Operation

The cleanout flow of production well KS-9 was completed on April 20, 1993, with a 3-hour and 39-minute period of steam-dominated flow. Sixteen days before, the wellbore had been packed with nitrogen, and for the first hour of flow on April 20, only nitrogen with some contamination of noncondensible gases from the resource was produced. Production of geofluids began with a small slug of condensate, followed within five minutes by the onset of steam flow. Average total mass flow rate for the period of steamdominated flow was 126,000 lbjhr, and the average wellhead pressure was 1,910 psig. The maximum flow rate was 179,000 lb/hr at a wellhead pressure of 1,900 psig. The well's potential was much greater, but higher rates were not needed to achieve the cleanout objective, and the rate was purposely constrained to avoid possible problems of excess H2s emissions or liquid carryover from the atmospheric separator.

-2-


Flow rates were calculated from James tube lip pressure readings using an assumed wellhead enthalpy of 1,085 Btujlb, which was the enthalpy of KS-8. The James tube bore (9. 562 inches) is relatively large for the flow rates involved, so lip pressure readings were below the range for optimum flow measurement accuracy. More precise measurements of flow and enthalpy will be obtained with the well on production to the power plant.

Table 1 is a listing of data and calculated flow rates for the cleanout flow. As shown in the table, the first hour after opening the throttle valve involved blowing down nitrogen from the wellbore before the first production of geofluid. The wellbore had been packed with nitrogen on April 4, 1993, after completion of a workover job. The calculated wellbore capacity at static conditions was about 140,000 scf of nitrogen, or about 10,000 pounds of nitrogen. The nitrogen was sampled at the wellhead one day before the cleanout flow and was found to have no detectable level of H~S. However, in recognition of the likelihood of H2S contaminat1on in the nitrogen at depth, NaOH solution was injected into the flowline for abatement during the entire period of nitrogen blowdown. During this time, NaOH solution was injected at three different points on the flowline, providing redundancy and thorough mixing for the abatement reaction.

Figure 1 is a schematic diagram of the cleanout flow facility. As shown in the figure, there are manual throttling valves on the flowline near the wellhead, and the flow is piped to an atmospheric separator (also called a muffler) where steam is vented vertically to the atmosphere and water is drained to a lined pit. There are abatement injection points and fluid sampling points on the flowline, as shown.

The flow operations, sampling and abatement were executed essentially as specified in the Revised Cleanout Flow Procedure, except there was no interruption of the flow to tighten wellhead flange bolts because no leaks developed. Minor leaks are common on a first-time startup of a high-temperature well, and a shutdown had been planned for retightening flange bolts after 30 minutes of flow. However, this was not_ required.

As planned in the Revised Cleanout Flow Procedure, the flowline was monitored for H2 S and liquid pH during the period preceding steam flow for early detection of any abatement failure. H2S concentration in the flowline never exceeded 1 ppm, and liquid pH never went below 12. o units, both of which were indicative of effective abatement. Neither the stationary monitors nor the

-3-


Safety Supervisor with a hand-held GasTec detected any H2s on the well pad.

After the onset of steam-dominated flow, fluid samples were collected from the flowline and from the atmospheric separator for characterization of the produced fluids and emissions to the atmosphere. Results of these analyses will be reported separately.

In compliance with permit requirements, steam from the flowline and muffler (upstream and downstream of abatement injection) were sampled and analyzed for H2S, and emission rates were calculated. As shown on Tecton' s Summary Data Sheet, H2s emissions did not exceed 1.25 lb/hr and the abatement efficiency was better than 99 percent. This abatement efficiency is slightly higher than that achieved on KS-8 and is probably a result of injecting NaOH solution upstream of the James tube rather than downstream. The upstream abatement injection was done for approximately the last 2~ hours of flow to take advantage of the additional turbulence and reaction time through the James tube. This was apparently effective. Abatement upstream of the James tube is not standard industry practice because most geothermal resources produce a brine phase which precipitates silica scale with the addition of caustic. However, the liquid phase in the new Puna production wells is apparently a condensate and is very low in silica and other dissolved solids. Injection of caustic did not cause significant scale deposition in the flowline.

Following the cleanout flow, the temporary piping to the atmospheric separator was removed and the permanent production piping was connected to the wellhead. KS-9 was restarted the next day at about 1300 hrs, supplying steam to the power plant.

-4-

PAGE NUMBER 1:-oF I

DA~ TIME BRINE FLOW KI/HR

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• lr.s·.:z.ol -I I I

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1 OPERATORS INITIALS ABBREVIATIONS:

INJ: :IN.JECTED D: D PAD A: A PAD

I I

I

I

Sr"-AM S'l""<'-AM H2S BEFORE FLOW SOURCE TREATMENT K#/HR PPM #/HR

- Ks-9 - -- .. - -- .. - I -- .. - I -

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- .. - I -I I

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I I I

I

ESRF: EMERGENCY STEAM lU:LEASE FACII.ITY

I

I

TECTON'S SUMMARY DATA SHEET

H2S TOTAL H2S NaOH ABATE WATER COMMENTS I' EMISSIONS EMISSIONS IN.JECTION " MOLE EFFICIENCY IN.JECT PPM #/HR #/HR GPH RATIO \ REMOVAL GAL/HR

- - - IS<i::b 5c% - - .kDDO lo~ .. """'-'' IF - - - I.S:'8t:, So - - bOCO fj',J-.. J;C<.tl !F - - - 10~ b I c::::o - - bDOD fs-tc,p .. .,.,.... i..,.. ... - I - - 330 I 50 - - booo C:-t•""J~-r..;. ;.p ;Jt vrfc ~·D fJ6·'i5 tJ. "1£" .5.50 I 50 I - - (;,COO w,....~, .~

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30'" MUFFLER

INLET~

JAMES TU~~~ ORIFICE ~

UP PRESSURE-~ INDICATOR i

1 Cf SCHEDULE 80

STEAM\ BRINE\ GAS SAMPUNG SEPARATOR

~

Caustic Injec. with Steam Flow

PUNA GEOTHERMAL VENTURE

ATMOSPHERIC SEPARATOR, MUFFLER, AND ABATEMENT SYSTEM, KS-9 CLEANOUT

RESERVE PIT

SEPARATOR\

-r--- SAMPLE PORT FOR H2 S EMISSIONS

ABATC:MENT UNIT CAUSTIC PUMPS

UNIT A

UNIT 8

1a· SCH 80 t 1 (j' 1 500#

THROTILE VALVE

TANK WITH HALUBURTON

CAUSTIC TANK 3000 GAL 50~ CAUSTIC

WATER INJECTION UNE FROM ~~18t.L~oe.~

350 GPM CAPACITY

't' 1 500# BYPASS UNE

t 1Cf 1500#

VALVE

CAUSTIC SOLUTION

- l/l1JW.J IICT 'I'D ~ CAUSTIC SOLUTION PUMPING UNIT

Table 1 KS-9 CLEANOUT FLOW

4/20/93

Aowtine Pressures (psig) Aowtine Wellhead Temp near James Tube Total Mass Pressure Dnstrm of 10" Una@ On 20" Wellhead Up Press Flow Rate

Time (psig) 2" Throt Samp.Ports Une (Deg F)* (psi g) (lblhr)** Comments

10:15 1910 0 0 0 0 Pre-flow readings 10:23 1910 0 0 0 0 Open top master valv 10:33 1890 0 0 0 0 Open 2"throttle valve 10:35 1885 80 0 0 10,000 Increase flow rate 10:45 1840 90 0 0 10,000 Flowing nitrogen 10:48 0 0 10,000 Aowing nitrogen 10:51 1800 85 0 0 104 10,000 Flowing nitrogen 11:05 1715 85 0 0 98 10,000 Aowing nitrogen 11:15 1630 90 0 0 10,000 Flowing nitrogen 11:25 1570 85 0 0 93 10,000 Aowing nitrogen 11:33 1660 65 0 0 111 10,000 Flowing liquid slug 11:38 1700 65 0 0 182 10,000 Onset of steam flow 11:49 1780 90 0 0 365 10,000 Switch Unit 8 to 10" 12:01 1780 90 0 0 10,000 Personnel unmasked 12:07 1880 185 45 0 10,000 Increased flow rate 12:17 1920 o/s 25 0 581 -2.0 114,000 12:22 o/s 0 0.0 132,000 Switch to 10" throttle 12:25 o/s 40 0 2.0 149,000 12:35 1910 o/s 35 0 571 1.0 140,000 12:45 1910 o/s 35 0 585 1.0 140,000 12:55 1915 o/s 33 0 576 0.4 135,000 13:05 1920 o/s 32 0 587 0.2 134,000 13:20 1920 o/s 31 0 586 0.0 132,000 13:35 1920 o/s 31 0 585 0.0 132,000 14:00 1920 o/s 31 0 o/s -0.3 129,000 14:09 1900 o/s 0 o/s 0.0 132,000 Increased flow rate 14:12 1900 o/s 47 0 o/s 5.5 179,000 14:25 1900 o/s 41 0 o/s 3.4 161,000 14:45 1900 o/s 42 0 o/s 3.7 164,000 14:57 1910 o/s 42 0 o/s 3.8 165,000 15:11 1905 o/s 42 0 o/s 3.9 166,000 15:17 1950 o/s 0 o/s 3.9 166,000 Shut in. End cleanout 15:19 1960 o/s 0 0 o/s 0.0 0 Max wellhead PBU

• Temperature was measured by surface probe strapped to flowline and covered with insulation. Readings are probably lower than actual, especially at higher temperatures .

.. Aow rate numbers before 1217 hrs are estimated on the basis the time it took to blow down the nitrogen from the wellbore. Beginning at 1217 hrs, flow rates are calculated from James Tube lip pressure readings using an assumed wellhead enthalpy of 1 085 Btu/lb, adjusted for the injection of caustic solution upstream of the James tube.

i ,,

:1

": .. ---

INALAB, INC. 3615 HARDING AVE. • SUITE 304 • HONOLULU. HAWAII 96816

{808) 735-0422 • FAX: (808) 735-0047

TECHNICAL EXPERTS CONSULnNG IN ENVIRONMENTAL • FORENSIC • OCCUPATIONAL AND LABORATORY SERVICES

INALAB, INC.

Laboratory Report

Puna Geothermal Venture P.O. Box 30

Date: 7 May 1993 Invoice Number: 93335

Your P.O. Number: 60323 Hilo, Hawaii 96778 phone (808) 961-2786 fax (808) 935-5562

Attention: Skip

Detection Sample Concentration of Asbestos Limit Analysis

Description Structures (MFL) (MFL) Date

KS-9 2ASB 0.93 0.46 4/29/93

KS-9 lASB 0.19 0.19 4/30/93

KS-9 lASS none detected 0.23 4/29/93

Note: MFL = Million Fibers per Liter

(1} Sample was not collected by INALAB, Inc. persor~el. (2) Samples will be retained by the laboratory for a maximum of

15 days. Unless otherwise requested in writing, they will then be discarded.

(3) Disposal of all samples found to be hazardous with respect to their physical or chemical properties (as defined by the EPA's 40 CFR part 260 regulations will be the responsibility of the client. A disposal charge of $500.00 will be assessed for all hazardous samples not reclaimed within 10 calendar days of the date of the written report of results.

EPA Accredited AHERA Inspectors/Management Planners • NIST Technical Experts in Bulk Asbestos Identification Ph.D. Chemists, Environmental Scientists, Toxicologists and ABIH Certified Industrial Hygienists

....

PUNA GEOTHERMAL VENTURE KS-9 TEMPERATURE AND PRESSURE PROFILES

PRESSURE (PSIG)

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PRUETT INDUSTRIES! I~C. • 8905 ROSEDALE: 1-iWY. · SAt<ERSriELD~ CA. 93312 C805) 589-2768 TELEX 4992440 PRUETT INT.

SUB-SURFACE PRESSURE: SURV~Y ---------------------------CO. PUNA GC:u"':""l-iE:R~AL VE:i'•T EFi=' DePI!-1 ~ 1 12i01

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DATS: 020693 ELEVATION 1't!AX TEMP PERF TUBING UNITS

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. "1 ..;· ·: . ·.: .~ ...

.r .. ; ': '"; -· ) ,· .. I : _.·. ..

i I· _; :-~·1· ... : ,,. . ~I:· : 1 ·i ·'·:· i

. . ._ .. "·'· .

"i ., .. ,: ·, ; . .. I· . :j. ...• .. :· : •..

....... : r. . .

l·i I; : :·; --::- ""'", ""'·' .. :·, .··. . ' I .··.·' -~ .. ·•

i .c.;;

: 'i .. ..

: .. : .. , . . '

• .

p Q) Q) t.-(/) (!} co ..c:: ~ c.. Q)

Cl

-500

-1000

-1500

-2000

-2500

-3000

-3500

-4000

KS-9 Temperature Survey January 16, 1993

I I I I

I I I I I I I I I I I I I I I -------, ----,-------T-------r-------,-------;-------T-------r-------~-------,-------T-------I I I I I

1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I -------,--- - - l - - - - - - - T - - - - - - - r - - - - - - ""1- - - - - - - ; - - - - - - - T - - - - - - - r - - - - - - -~- - - - - - - l - - - - - - - T - - - - - - -

1 I I I

I I I I I I I I I I I I I I I I I I I I

I I I I I I I I I I I I I I I I I I

I I I I I I I I I I I -------,-------,-- ---T-------r-------,-------,-------T-------r-------r------,-------T-------1 I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

------..,-------~-- ---T-------r------~-------,.-------T-------r------~-------~-------T-------1 I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I ------..,-------,-------T-------r------.., -----1'-------T------- r- ----- -~------- l-------T-------I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

I I I ----- -~-------I-------T------- r----- -~-------1'-------T------- r------ -~-------I---- ::-:?!.,....,Co.IZ:-

1 I I I I I I I I "-L"--~IE-~+E:--?1~ I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

------..,-------~-------T-------r------..,-------,.-------T-------r-----1 I I I I I I I I I I I I I I I I I I I I I I I I I I I

-45oo~~~--~~--~~--~~--~~--~--~~--~~--~~~~--~

100 125 150 175 200 225 250 275 300 325 350 375 400 Temperature (deg. F)

* Temp. Data Points

FLO-LOG INC.

COMPANY __ il_ll.NlLGE.GlllLl\lil\L_ __ _jLLJiTURS

WELL NO. J;'; q

FIELD i'bJlOI!O

COUNTY ---------"-P..~.~U~Nu..l\L-_______ STATE HI.

DATE ______ MAR_Cil__ _ __2_L_~9-9 3

PURPOSE OF SURVEY

Ch~!PER TOP JOO' 0~

9 5/8" CASING

:· '.

', .... :·. _;··

.I i \

:-·

. - --

PUf\lA GEOTHERMAL VENTURE A Hawaii Partnership

June 15. 1993

John c. Lewin, M.D., Director State Department of Health P.O. Box 3378 Honolulu. HI 96801

SUBJ: KS-9 CHEMICAL ANALYSES

Dear Dr. Lewin.

Pursuant to Special Condition No. 20 of Permit To Operate (PTO) No. P-833-1399. Puna Geothermal Venture (PGV) hereby submits the brine and steam condensate chemical analyses for samples taken during the KS-9 cleanout flow on April 20. 1993.

Should you of your staff have any questions. please contact me.

~G--Thomas G. Kizis Environmental Manager

c: s. Morris D. Berube G. Davidson

File: KS-9

. ~=: ··· .. ;::··.-

. . - -~ ... :· ... '·

·~·· -·. -: ... . .·. .. .. .

··: .. . ·-

14-3860 Kapoho Pahoa Road. Pahoa. Hawaii 96778 • (808) 961-2786 • Facsimile (808) 935-5562 Post Office Box 30, Pahoa, Hawaii 96178

·- . . !~;.; .: · .. • -~- .

. · .....

Mr. Tom Kizis

Mesquite Group, Inc. P.O. Box 1283

221 North Harbor Blvd .• SUite K

Fullerton. Califomia 92632

(714) 738-8224 • FAX (714) 525-2852

PUNA GEOTHERMAL VENTURE P. 0. Box 30 Pahoa, HI 96778

Subject: KS-9 Chemical Analyses

Dear Tom:

June 10, 1993

Enclosed are chemical analyses of brine and steam condensate that the Mesquite Group, Inc. collected during the KS-9 cleanout flow on April 20, 1993. Brine samples were collected from the bottom of the flowline and steam condensate samples were collected from the top of the flow line. Both sample types utilized a small separator and were collected from cooling coils submerged in tap water to prevent flashing. The methods used for sampling are listed in Tables 1 and 2. All sample bottles were washed in 10% by volume nitric acid and rinsed in deionized water before sampling. The analytical laboratories and methods are summarized in Tables 3 and 4. Blank samples (Table 5) were also submitted and analyzed. The chemical results are listed on the attached analyses tabulations.

JSM/mjw

Enclosures

Sincerely,

J;;i.p~/ J. S. "Skip" Matlick, III Senior Geologist

Sample

KS-9 1NB

KS-9 2NB

KS-9 1 BEB

KS-9 2BEB

KS-9 1VCB

KS-9 2VCB

KS-9 1 BB

KS-9 2BB

KS-9 1 SB

KS-9 2SB

KS-9 11CAB

KS-9 21CAB

KS-9 10B

KS-9 20B

KS-9 1 HB

KS-9 2HB

KS-9 1AB

Mesquite Group, Inc.

PUNA GEOTHERMAL VENTURE WELL KS-9

Table 1 BRINE SAMPLE METHODS

Sample Analyte Size Container

(ml)

Ammonium 125 amber glass


Benzene 40 VOA

Benzene 40 VOA

Vinyl Chloride 40 VOA


Arsenic, Lead, Boron, Cadmium, Beryllium, Sodium, Calcium, 500 plastic Lithium, Strontium, Silica, Potassium


Sulfide 250 plastic

Sulfide 250 plastic

I CAP* 20 plastic

I CAP* 20 plastic

Silica 10 plastic

Silica 10 plastic

Mercury 100 amber glass


Bromide, Bicarbonate, Carbonate, Sulfate, Chloride, Nitrate, 500 plastic Fluoride, Total Dissolved Solids, Total Suspended Solids, pH

Filtered (0.45 Preservative

micron)

no none

no none

no none

no none

no none

no none

yes 10 ml HN03

yes 10 ml HN03

no 12.5 ml CdCI2

no 12.5 ml CdCI2

yes 4 ml HN03

yes 4 ml HN03

no 2 ml HN03 + 90 ml H20

no 2 ml HN03 + 90 ml H20

no 25 ml K2Cr20 7 + HN03

no 25 ml K2Cr20 7 + HN03

no none

Page 1 of 2

PUNA GEOTHERMAL VENTURE WELL KS-9 Table 1: BRINE SAMPLE METHODS

Sample Filtered Sample Analyte Size Container (0.45 Preservative

(m/J micron)

KS-9 2AB Bromide, Bicarbonate, Carbonate, Sulfate, Chloride, Nitrate, 500 plastic no none Fluoride, Total Dissolved Solids, Total Suspended Solids, pH

KS-9 11B Isotopes 125 plastic no none

KS-9 21B Isotopes 125 plastic no none

KS-9 1ASB Asbestos 1,000 glass no none

KS-9 2ASB Asbestos 1,000 glass no none

KS-9 1RB Radionuclides 1,000 plastic no 10 ml HN03

KS-9 2RB Radionuclides 1,000 plastic no 10 ml HN03

·leAP: Sodium, Potassium, Calcium, Magnesium, Iron, Aluminum, Silica, Boron, Lithium, Strontium, Zinc, Silver, Gold, Barium, Bismuth, Beryllium, Cadmium, Cerium, Cobalt, Chromium, Lanthanum, Manganese, Molybdenum, Nickel, Lead, Tin, Antimony, Tellurium, Thorium, Titanium, Uranium, Vanadium, Tungsten, Zirconium

Mesquite Group, Inc. Page 2 of 2

Sample

KS-9 1AS

KS-9 1 SS

KS-9 1CAS

KS-9 1NS

KS-9 1 BS

KS-9 1 CS

KS-9 1HS

KS-9 1RS

KS-9 1VCS

KS-9 1 BES

KS-9 lASS

KS-9 11S


Table 2 STEAM CONDENSATE SAMPLE METHODS

Sample Analyte Size Container

(m/J

Bromide, Bicarbonate, Carbonate, Sulfate, Chloride, Nitrate, 500 plastic Fluoride, Total Dissolved Solids, Total Suspended Solids, pH

Sulfide 250 plastic

I CAP* 20 plastic



Hydrogen Chloride 250 plastic


Radionuclides 1,000 plastic


Benzene 40 VOA

Asbestos 1,000 glass

Isotopes 125 plastic

Filtered (0.45 Preservative

micron)

no none

no 12.5 ml CdCI2

yes 4 ml HN03

no none

yes 10 ml HN03

no none

no 25 ml K2Cr 201 + HN03

no 10 ml HN03

no none

no none

no none

no none

*ICAP: Sodium, Potassium, Calcium, Magnesium, Iron, Aluminum, Silica, Boron, Lithium, Strontium, Zinc, Silver, Gold, Barium, Bismuth, Beryllium, Cadmium, Cerium, Cobalt, Chromium, Lanthanum, Manganese, Molybdenum, Nickel, Lead, Tin, Antimony, Tellurium, Thorium, Titanium, Uranium, Vanadium, Tungsten, Zirconium


Sample

KS-9 1&2NB

KS-9 1&2BEB

KS-9 1&2VCB

KS-9 1&2BB

KS-9 1&2SB

KS-9 1 &21CAB

KS-9 1&20B

KS-9 1&2HB

KS-9 1&2AB

KS-9 1 &21B

KS-9 1&2ASB

KS-9 1 &2RB


Table 3 BRINE ANALYTICAL METHODS

Analyte lab. EPA Method

Ammonium UURI 600

Benzene BEl 602

Vinyl Chloride BEl 502.2

Arsenic UURI 600 Lead UURI 200.7 Boron UURI 200.7 Cadmium UURI 200.7 Beryllium UURI 200.7 Sodium UURI 200.7 Calcium UURI 200.7 Lithium UURI 200.7 Strontium UURI 200.7 Silica UURI 200.7 Potassium UURI 200.7

Sulfide UURI 600

I CAP •• UURI

Silica UURI 200.7

Mercury UURI

Bromide UURI 600 Bicarbonate/Carbonate UURI 600 Sulfate UURI 600 Chloride UURI 600 Nitrate UURI 600 Fluoride UURI 600 Total Dissolved Solids UURI 600 Total Suspended Solids UURI 600 pH UURI 600

Isotopes SMU

Asbestos Ina lab

Radionuclides TMA

Instrumentation

Electrode

Gas Chromatograph

Gas Chromatograph

Colorimetric I CAP I CAP I CAP I CAP I CAP I CAP I CAP I CAP I CAP I CAP

Titrimetric

I CAP

I CAP

Cold Vapor AA

Titration Titration Turbidimetric Titration Colorimetric Electrode Gravimetric Gravimetric Meter

Mass Spectrographic

TEM

Scintillation

·Lab: UURI - University of Utah Research Institute; BEl - Brewer Environmental Industries; SMU - Southern Methodist University, Institute for the Study of Earth and Man; TMA- TMA-NORCAL; TC- Thermochem

··ICAP: Sodium, Potassium, Calcium, Magnesium, Iron, Aluminum, Silica, Boron, Lithium, Strontium, Zinc, Silver, Gold, Barium, Bismuth, Beryllium, Cadmium, Cerium, Cobalt, Chromium, Lanthanum, Manganese, Molybdenum, Nickel, Lead, Tin, Antimony, Tellurium, Thorium, Titanium, Uranium, Vanadium, Tungsten, Zirconium


Sample

KS-9 1AS

KS-9 1SS

KS-9 1CAS

KS-9 1NS

KS-9 1 BS

KS-9 1 CS

KS-9 1HS

KS-9 1RS

KS-9 1VCS

KS-9 1 BES

KS-9 1ASS

KS-9 11S


Table 4 STEAM CONDENSATE ANALYTICAL METHODS

Analyte lab. EPA Method Instrumentation

Bromide UURI 600 Titration Bicarbonate/Carbonate UURI 600 Titration Sulfate UURI 600 Turbidimetric Chloride UURI 600 Titration Nitrate UURI 600 Colorimetric Fluoride UURI 600 Electrode Total Dissolved Solids UURI 600 Gravimetric Total Suspended Solids UURI 600 Gravimetric pH UURI 600 Meter

Sulfide UURI 600 Titrimetric

I CAP •• UURI I CAP

Ammonium UURI 600 Electrode

Arsenic UURI 600 Colorimetric Lead UURI 200.7 I CAP Boron UURI 200.7 I CAP Cadmium UURI 200.7 I CAP Beryllium UURI 200.7 I CAP Sodium UURI 200.7 I CAP Calcium UURI 200.7 I CAP Lithium UURI 200.7 I CAP Strontium UURI 200.7 I CAP Silica UURI 200.7 I CAP Potassium UURI 200.7 I CAP

Hydrogen Chloride TC Chromatograph

Mercury UURI Cold Vapor AA

Radionuclides TMA Scintillation

Vinyl Chloride BEl 502.2 Gas Chromatograph

Benzene BEll 600 Gas Chromatograph

Asbestos lnalab TEM

Isotopes SMU Mass Spectrographic

·Lab: UURI - University of Utah Research Institute; BEl - Brewer Environmental Industries; SMU - Southern Methodist University, Institute for the Study of Earth and Man; TMA- TMA-NORCAL; TC- Thermochem

··leAP: Sodium, Potassium, Calcium, Magnesium, Iron, Aluminum, Silica, Boron, Lithium, Strontium, Zinc, Silver, Gold, Barium, Bismuth, Beryllium, Cadmium, Cerium, Cobalt, Chromium, Lanthanum, Manganese, Molybdenum, Nickel, Lead, Tin, Antimony, Tellurium, Thorium, Titanium, Uranium, Vanadium, Tungsten, Zirconium


Sample

KS-9 1SBB

KS-9 1QBB

KS-9 11CAB


Table 5 BLANK SAMPLES

Sample Filtered Analyte Size Container (0.45

fm/J micron)

Sulfide 125 plastic no

Silica 60 plastic no

I CAP. 100 plastic no

Preservative

12.5 ml CdCI2

60 ml HN03

2 ml HN03

·ICAP: Sodium, Potassium, Calcium, Magnesium, Iron, Aluminum, Silica, Boron, Lithium, Strontium, Zinc, Silver, Gold, Barium, Bismuth, Beryllium, Cadmium, Cerium, Cobalt, Chromium, Lanthanum, Manganese, Molybdenum, Nickel, Lead, Tin, Antimony, Tellurium, Thorium, Titanium, Uranium, Vanadium, Tungsten, Zirconium

Mssquits Group, Inc. Page 1 of 1

CHEMICAL ANALYSES (NOT FLASH CORRECTED)

SAMPLE TYPE: Brine WELL: KS-9 COLLECTION DATE: April 20, 1993 SAMPLE TIME: 131 5 hrs SAMPLE POINT: Bottom flow line FLOW RATE: 132,000 lbs/hr SAMPLE METHOD: Two-phase liquid flow into separator then into cooling coil

submerged in water.

WHP: 1920 psig Separator Pressure: 38 psig

TDS 220.00 mg/1 pH 6.79 Si02 116.04 mg/1 Fe 0.27 mg/1 Ca 0.57 mg/1 Mg 0.03 mg/1 Na 31.25 mg/1 K 5.60 mg/1 Li 0.092 mg/1 Sr <0.00 mg/1 AI 0.30 mg/1 NH4 0.22 mg/1 Benzene 0.006 mg/1 Vinyl Chloride < 0.001 mg/1 As 0.122 mg/1 Pb < 0.002 mg/1 Cd <0.005 mg/1 HC03 39.00 mg/1 C03 < 1.00 mg/1 S04 4.8 mg/1 Cl 24 mg/1

Analyses*

F 0.34 mg/1 B 5.1 mg/1 Br <0.50 mg/1 S 122 mg/1 N03 <0.01 mg/1 P04 0.89 mg/1 Mo 0.11 mg/1 Mn 0.03 mg/1 Ba 0.12 mg/1 Zn 0.02 mg/1 Be <0.005 mg/1 Hg < 0.0005 mg/1 TTS 9.0 mg/1 Asbestos 0.19 ± 0.19 mfl Gross Alpha 3 ± 2 pCi/L Gross Beta 7 ± 2 pCi/L 226Ra 0 ± 1 pCi/L 228Ra 0 ± 3 pCi/L 180 {SMOW) + 1 .9096o 2H {SMOW) + 3.6%o

* Refer to originals for elements determined to be below detection limits.


CHEMICAL ANAL VSES (NOT FLASH CORRECTED)

SAMPLE TYPE: Brine WELL: KS-9

·CoLLECTION DATE: April 20, 1993 SAMPLE TIME: 151 0 hrs SAMPLE POINT: Bottom flow line FLOW RATE: 166,000 lbs/hr SAMPLE METHOD: Two-phase liquid flow into separator then into cooling coil

submerged in water.


TDS 174 mg/1 pH 6.26 Si02 130.79 mg/1 Fe 0.30 mg/1 Ca 0.51 mg/1 Mg 0.04 mg/1 Na 20.06 mg/1 K 1.89 mg/1 Li 0.03 mg/1 Sr < 0.00 mg/1 AI 0.14 mg/1 NH4 0.17 mg/1 Benzene 0.007 mg/1 Vinyl Chloride <0.001 mg/1 As 0.016 mg/1 Pb < 0.002 mg/1 Cd <0.005 mg/1 HC03 8.00 mg/1 co3 < 1 .00 mg/1 S04 11.00 mg/1 Cl 8 mg/1

Analyses*

F 0.38 mg/1 B 5.98 mg/1 Br <0.50 mg/1 S 141 mg/1 N03 < 0.1 mg/1 P04 0. 51 mg/1 Ba 0.13 mg/1 Be < 0.005 mg/1 Hg <0.0005 mg/1 TTS 9.0 mg/1 Asbestos 0.93 ±0.46 mfl Gross Alpha 3 ± 2 pCi/L Gross Beta 2 ± 1 pCi/L 226Ra 0 ± 1 pCi/L 228Ra 0 ± 3 pCi/L 180 (SMOW) +0.44%o 2H (SMOW) -0.1 %o



CHEMICAL ANALYSES (NOT FLASH CORRECTED)

SAMPLE TYPE: Condensed Steam WELL: KS-9 COLLECTION DATE: April 20, 1993 SAMPLE TIME: 1430 hrs SAMPLE POINT: Bottom flow line FLOW RATE: 161,000 lbs/hr SAMPLE METHOD: Two-phase liquid flow into separator then into cooling coil

submerged in water.


TDS 14.00 mg/1 pH 4.6 Si02 5.28 mg/1 Fe 0.15 mg/1 Ca < 0.02 mg/1 Mg < 0.01 mg/1 Na 0.07 mg/1 K <0.05 mg/1 Li < 0.04 mg/1 Sr <0.00 mg/1 AI <0.05 mg/1 NH4 0.35 mg/1 Benzene 0.036 mg/1 Vinyl Chloride < 0.001 mg/1 As <0.04 mg/1 Pb 0.004 mg/1 Cd <0.005 mg/1 HC03 3.00 mg/1 co3 < 1.00 mg/1 S04 1.00 mg/1 Cl 1.40 mg/1

Analyses*

F 0.07 mg/1 B 0.08 mg/1 Br < 0.05 mg/1 S 403 mg/1 N03 < 0.01 mg/1 P04 <0.15 mg/1 Be <0.005 mg/1 Hg < 0.0005 mg/1 TIS 1.0 mg/1 Asbestos <0.23 mfl Gross Alpha 1 ± 2 pCi/L Gross Beta 1 ± 1 pCi/L 226Ra 0 ± 1 pCi/L 228Ra 0 ± 2 pCi/L 180 (SMOW) + 0.44%o 2H (SMOW) -0.1 %o HCI not detected



PUNA GEOTHERMAL VENTURE WELLKS-9

Appendix

CHEMICAL ANALYSES ORIGINALS


... · .:· .. 0 •• • ...

,;., .: .: ~. ··~ ~ .. BRE\NER ENVIRONMENTAL • INDUBTRI&S, .INC.

• c: •"ewtA .. __

CLIENT: PUNA GEOTH:EF.MAL VENTURE P.O. BOX 30 PAHOA, HAWAII 96778

MA~IX: WATER

QA/QC DATA

s~!K'E COMPOUND

BENZENE

VINYL CHLORIDE

SURROGATE RECOVER~ (BENZENE)

l.BES • 99.S% lBEB -= 94.8% 2BEB = 96.6%

Bs t RZC

97.0

101.2

SURROGATE RECOVERY (VINYL CHLORIDE)

lVCB c 98.9% lVCS =- 100.0% 2VCB • 91.7~ \

MSos % ~c

98.5

99.0

LABORATORY ANALYSIS REPORT Environmental Laboratories DiVision

ATTN: BILL TEPLOW

JOB NUMBER: 0029

OATE: APRIL 29, 1993

1.5

IIAEW•A I!NVIAONMENTAl. LABORATORIES "0 !lOX SS2

\ Approved by. {/)-; ~· '

P4P•ri(QU. HI 96781 ,.,.ONfi teo&l ~·5~:! l'AX (1100) teq.JO!I

-

. . ~ TEL:

~~~-·.:.-· ·;..:...· ..... ..;..._;.,.... ___ ...._ •..... -......

BRE\NER BNVIAONMI!NTAL INDU11TRia&. INC. LABORATORY ANALYSIS REPORT

Environmental Laboratories Division • r: ""ew"" '~~~"',....,

CLIENT: PUNA GEOTHERMAL VENTURE P.O. BOX 30 PAHOA, HAWAII 96779

SAMPLE LOCATION: KS-9

Date/Time Sampled: 04/20/93 @ 1200 Date/Time Received: 04/21/93 @ 1345

SAMPLE IDI

IBES

IBEB

2BEB

SAMPLE ID#

IVCB

IVCS

2VCB

BENZENE RESULT mg/L

0.036

0.006

0.007

VINYL CHLORIDE RESULT mg/L

NO

NO

NO

ATTN: BILL TEPLOW

JOB NUMBER: 0029

DATE: APRIL 29, 1993

Matrix: WATER

DETECTION LIMIT mg/L

ANALYsis METHOD DATE NUMBER

0.005 04/21/93 M 602

0.005 04/21/93 M 602

0.005 04/21/93 M 602

DETECTION ANAL7S!s METlrnD LIMIT mgjL DATE NUMBER

0.001 04/26/93 502.2

0.001 04/26/93 502.2

Q.OOl \

04/26/93 502.2

NO • NOT DETECTED "'~ ~\l~ ~~\,. "~~ ..:_,.~ 'G~o''"'~

tUl"V-' • l:

\ BREW&A ENYIRONMI!NTAL. LA80AATDAIU

····· .. --······ d Approved by' t/); • U '

PO. IIOX"Z P.u'AII<OIJ. HIINI71 I ~Ne tiOIIINiol·5!.22 ,AJ( 11101l""'5.301

THERMOCHEM Tom Kizis Puna Geothermal Venture P.O. Box 30 Pahoa, HI 96778

Lab Number

4832-1

CLIENTSIOESIIPUNAIREPORT/4832.DOC

Report of An~lysi~

Descriptor

KS-91CS

iECEJVEO riAY 1 9 1B9S

4832 (1) May 14, 1993

Chloride ppmw

<0.025

Sodium ppmw

0.012

-------------------------------------------· ---------------------------------------. '. -·. - ,. --..... . ... : . . .'l .•• .1..~.~ 11·.., 1! ... ":,.;..

Thermo Analytical Inc.

TMAINorcal ___ __ 201.£.!!~g_.?t ?.~nue

____ .• P. Q. Qox 4040

Richmond. CA 9-:a04-0040

(570) 235-2633 f:JX Na. ~S70.'2JS·0438

May lS, 1993

Ref: Customer P.O. 60324 TMA/Norcal N3-04-134-8331

Mr. Tom Kizis Project Geologist Puna Geo~hermal Venture P.O. Box l337 Hi.lo, HI 967:21

Dear Mr. Ki:is:

The results of the three water samples we received on 27 April 1993 for analysis have been completed and are shown on Attachmen~ l. The samples were filtered before analysis.

we apprecicte this opportunity to pg of servir.P..

Very truly yours,

c2±1 j(j!_~/(-~ " Dinkar P. Kharkar, Ph.D.

Manager, Nuclear Projec~s

DPK/ss

Enclosures: Attachment 1

- .. .. . .. . -: -;_.~.-j ~:

-..... ,_. .•.... ..... ·;· ..

ATTACHMENT 1

customer ID No.

KS-9-lRS

KS-9-2RB

KS-9-lRS

-~, '.

.. ..... 1'. -.. ' • ~-; ! .... ' : • .;.;:. .. l.

RESOI.TS

TMA/Noreal Group No.

833

l

:z

3

.-~-

. -..... -.... - .. !'. . .. ~ : - : .:. ·=· :· .:.

Analysis

Gross Alpha Oro::~ Deta 226Ra 228Ra

Gross Alpha Gross Beta 226Ra 228Ra

Gross Alpha Gross Beta 2.26Ra 22SRa

.. . :. : . .. -· •· ". ,, .

Result.s pCi/L : 2 a

3 ± 2 7 : 2 0 :!: 1

0 = 3

3 !: 2 2 !: l 0 ± l 0 :t 3

1 !: 2 1 !: l 0 :!: l 0 :!: 2

TMA

·----------------------------------------------------------------------TEL: Jun 02.93 1 :. : 4 7 1··1 o . (I:: 4 F· . 1 t·

I NALAB, INC. 3615 HARDING AVE. • SUITE ~04 • HONOLULU, HAWAII 96816

(808) 735-0422 • FAx: (BOB) 735-0047

TECHNICAL EXPERTS CONSULTING IN ENVIRONMENTAL. • FORENSIC • OCCUPATIONAL AND LABORATORY SERVICES

INALAB, INC.

Laboratory Report

Puna Geothermal Venture P.O. Box 30

Date: 7 May 1993 Invoice Number: 93335

Your P.O. Number: 60323 Hilo, Hawaii 96778 phone (808) 961-2786 fax (808) 935-5562

Attention: Ski?

Detection Sample Concentration of Asbestos Limit Analysis

Description Structures (MFL) (MFL) Date

KS-9 2ASB 0.93 0.46 4/29/93

KS-9 l.h.SB 0.19 0.19 4/30/93

KS-9 lASS none detected 0.23 4/29/93

Note: MFL = Million Fibers per Liter

{1) Sample was not collected by INALAB, Inc. per~onnel. (2) Samples will be retaineo by the laboratory for a maximum of

15 days. Unless otherwise requested in writinq, they will then be discarded.

(3) Disposal of all s~ples found to be hazardouR with respect to their physical or chemical properties (as defined by the EPA's 40 CFR part 260 regulations will be the responsibility of the client. A disposal charge of $500.00 will be assessed for all hazardous samples not reclaimed within 10 calendar days of the date of the written report of results.

EPA Accredlled AHEFfA lmpectors/Mana"ement PIMMfS • NIST Techmc.J Experts In Bu/Jc Aabnfos ldentifiO<Ition Ph.f). Chem/11~, fnvlrormenra/ Scierrtl$t:s. TOJdco/oglsts .,d ABIH Cettlf*!lnacmtiaJ Hygirmists

UNIVERSITY OF UTAH RESEARCH INSTITUTE

Skip Matlick Mesquite Group, Inc. P.O. Box 1283

UURI EARTH SCIENCE LABORATORY

391 CHIPETA WAY, SUITE C SALT LAKE CITY, UTAH 84108-1295

TELEPHONE 801-524-3422

221 North Harbor Blvd., Suite K Fullerton, CA 92632

Sample

KS-9 1 BS

KS-9 2 BB

RLK/cd

REPORT

ppb Se

236

1.0

Ruth L. Kroneman Chemist

~ ECEIVEo J1JN o 7 ~

June 3, 1.993

Sample

KS-9 1 BS

KS-9 1 BB

KS-9 2 BB

KS-9 1 BBB

UNIVERSITY OF UTAH RESEARCH INSTITUTE

Tom Kizis Puna Geothermal Venture P.O. Box 1337 Hilo, HI 96721-1337

Sample

KS-9 1 HSB KS-9 1 HS KS-9 1 HB KS-9 2 HB

Sample

KS-9 1BB KS-9 2BB

UURI EARTH SCIENCE LABORATORY

391 CHIPETA WAY, SUITE C SALT LAKE CITY, UTAH 84108-129S

TELEPHONE 801·524-3422

REPORT

mg/1 Hg method

<0.0005 cold vapor <0.0005 cold vapor <0.0005 cold vapor <0.0005 cold vapor

mg/1 As method

0.120 colorimetric 0.016 colorimetric

mg/1 mg/1 mgjl mg/1 mg/1 mg/1 Pb B Cd Be Na Ca

0.004 0.08 <0.005 <0.005 0.07 <0.02

<0.002 5.00 <0.005 <0.005 31.12 0.58

<0.002 5.86 <0.005 <0.005 20.15 0.52

<0.002 <0.05 <0.005 <0.005 0.49 0.02

May 25, 1993

AA AA AA AA

600 600

mg/1 method Li

<0.04 ICP 200.7

0.09 ICP 200.7

0.03 ICP 200.7

<0.04 ICP 200.7

Sample mg/1 NH4 Method mg/1 s" Method

KS-9 1NS 0.35 gas sensing electrode 600 403 titrimetric 600

KS-9 1NB 0.22 gas sensing electrode 600 122 titrimetric 600

KS-:"'9 2NB 0.17 gas sensing electrode 600 141 titrimetric 600

Samples KS-9, 1SBB, 1SB, 1SS and 2QB contained nitric acid as well as Cadmium chloride. The nitric acid is an interferent for sulfide analysis. Splits labeled 1NS, 1NB and 2NB were analyzed for Sulfide instead •

RLK/cd

enclosures

./ ;-;:/t:."/ /.'~,;i_J2,_ Ruth L. Kroneman Chemist

**************************·~*******************************************

PUNA GEOTHERMAL KS-9 lAB, 1BB

ID #: A:3930391.PG DATE: 05-25-93

**********************************************************************

SPECIES CONCENTRATION ANALYTICAL DETECTION CONCENTRATION (ppm) METHOD LIMITS <MOL/U

Na 31. 12 1 • 04 . 135E-02 K 5.49 1 .05 . 140E-03 Ca • 58 1 • 02 . 145E-04 Mg • 03 1 .01 . 123E-05 Fe . 26 1 . 00 . 466E-05 Al . 29 1 • 05 . 107E-04 Si02 113. 76 1 . 04 . 189E-02 B 5.00 1 . 00 . 463E-03 Li • 09 1 . 00 . 130E-04 Sr • 00 1 .00 .571E-07 Zn . 02 1 • 01 .306E-06 Ag N.D. 1 . 00 ( .371E-07 As • 12 1 • 04 . 160E-05 A•.t N.D. 1 .01 { • 406E-07 Ba 1-::' . ..... 1 . 03 .874E-06 Be N.D. 1 .00 < . 111E-07 Bi N.D. 1 . 20 ( .957E-06 Cd N.D. 1 . 00 < .356E-07 Ce N.D. 1 . 02 < .143E-06 Co N.D. 1 . 00 < . 339E-07 Cr N.D. 1 . 01 ( .192E-0S Cu N.D. 1 .01 ( .787E-07 La N.D. 1 .01 ( • 720E-07 Mn .1213 1 • 02 • 546E-06 Mo • 11 1 .05 .115E-05 Ni N.D. 1 • 01 < .170E-06 Pb N.D. 1 0·=· . '- ( .965E-07 Sn N.D. 1 • 01 ( .843E-07 Sb N.D. 1 . 04 < . 329E-06 Te N.D. 1 • 10 { . 784E-06 Th N.D. 1 . 20 ( .862E-06 Ti N.D. 1 • 01 ( .209E-06 u N.D. 1 .50 ( . 210E-05 v N.D. 1 . 10 ( .196E-05 w N.D. 1 • 01 ( .544E-07 Zr N.D. 1 .01 ( .11ll1E-06 NH4 • 22 5 1-=· . '- • 122E-04 Cs N. A. 10 • 50 ( .376E-05 Rb N. A. 10 . 30 ( • 351E-05

PUNA GEOTHERMAL KS-9 lAB, lBB

ID #: A:3930391.PG DATE: 05-25-93

SPECIES CONCENTRATION (ppm)

ANALYTICAL DETECTION CONCENTRATION

TOTAL ALKALINITY AS HC03 C03 Cl F 504 Br I N03 s P04

39.00 N.D.

24.00 . 34

4.80 N.D. N. A. N.D.

122.00 • 89

TOTAL DISSOLVED SOLIDS

MEASURED CALCULATED 100*MEAS/CALC

pH

220.00 328.45 66.98

6.79

ADDITIONAL ANALYSIS:

u mhos/em ppb

METHOD

.-. .::.

2 .-. .::.

5 11

·::. ..... 2 9 .-. .::.

1

4 6

7

EC Hg As TSS SI02

210 (0.5 120 9.0 16.4 MG/L

ppb ppm 6Jravt..;Af-'fi/tC J tot;

ICP 200.7 (_I 1.;.8)

LIMITS <MOL/L)

1. 00 .639E-03 1. 00 ( .167E-04 1. 00 .677E-03 .05 .179E-04

1. 00 .500E-04 . 50 ( .626E-05 . 10 ( .788E-06 ·ill < .161E-05 . 20 .381E-02 • 15 .934E-05

4.00

**********************************************************************

ANALYTICAL METHODS:

1. INDUCTIVELY COUPLED PLASMA SPECTROMETER .;! o~. 7 2. TITRATION <LABORATORY)~06

3. TITRATION <FIELD) 4. GRAVIMETRIC ~~o 5. SPECIFIC ION ELECTRODE t ~ lJ 6. METHOD OF HEM (1970, USGS Water Supply Paper 1473) 7. pH METER <LABORATORY> & tJ a 8. pH METER <FIELD) 9. COLORIMETRIC t~a

10. ATOMIC ABSORPTION 11. TURBIDIMETRIC ~ IJtJ

N.D. NOT DETECTED N.A. NOT ANALYZED

~~~~~~~&~aa~**********************************************************


ID #: A:3930391.PG DATE: 05-25-93

I Milliequivalents/Liter I

----------------------------------------------------1 CATIONS

----------------------1 Na. K Ca. Mg Fe Al Li Sr' Zn As Ba. Mn Mo NH4

1.35372 .14038 . 028'~4 .00247 . 00931 .03225 . 01297 . 00011 . 00061 .00206 .1210175 .00109 .00229 . 01220

----------------------------------------------------1 SUM OF CATIONS: 1. 60016

I

----------------------------------------------------1 ANIONS

----------------------1 HC03 Cl F

.63921

.67704

. 01790 504 .09994 s 7.61036 P04 .02809 I

I I

1----------------------------------------------------l I I I

SUM OF ANIONS: I 9.07254 I I I

1----------------------------------------------------l I I I I I

CATION-ANION I BALANCE -7.47238 I

BALANCE D IFF. CATION + ANION -70.01

I

****************************************************************

PUNA GEOTHERMAL KS-9 1AB,1BB

TRILINEAR DIAGRAM COORDINATES

ID #: A:3930391.PG DATE: 05-25-93

****************************************************************

Meq I L Pet·cent <Meq I L>

1-------------------- --------------------1--------------------1

I I

CATIONS

Na 1.35372 K .14038 Ca .02894 Mg .00247

TOTAL 1.52551

1-------------------- --------------------

I

ANIONS

HC03 C03 S04 Cl

.63921

. 00000

. 09994

.67704

I

88.73890 9.20213 1. 8'~720 .16177

45.13602 .00000

7.05670 47.80728

I TOTAL 1.41619 100.00000 I I I I

1--------------------------------------------------------------l

***************************************************************


GEOTHERMOMETERS

ID #: A:3930391.PG DATE: 05-25-93

***************************************************************

Ge othet~mo meter Temp (deg C> Reference

Quat't z <no steam 1 oss) 145. Fou"r'n i e)'' (1981)

Quartz (maximum steam loss) 139. Fout'n i er ( 1981)

Chalcedony 119. Fournier ( 1981)

alpha-Cristobalite 94. Fotn~n i er ( 1981)

beta-Cristobalite 45. Fotn~n i et' (1981)

Amorphous Silica 24. Fotn~n i e)'' (1981)

Na/K <Fo•.n'n i er) 271. Fourn i e..-' (1979)

Na/K ( Tt~ue sd e 11) 258. Fout~nier (1981)

Na-K-Ca 215. beta= . 33 Fou..-'n i er and Truesdell (1974>

Na/Li 144. Fo•..1.i llac and Michard < 1981)

PUNA GEOTHERMAL (S-9 1 AS, 188

Co

CATIONS

PERCENT OF TOTAL MILLIEOUIVALENTS PER LITER

UURI ID• A:3930391 .PG DATE: 05- 25- 93

Cl

ANIONS

**********************************************************************

PUNA GEOTHERMAL KS-9 1BBB

ID #: A:3930393.PG DATE: 05-25-93

**********************************************************************

SPECIES CONCENTRATION ANALYTICAL DETECTION CONCENTRATION <ppm> METHOD LII'r1ITS <MOL/U

Na . 49 1 . 04 .213E-04 K N.D. 1 • 05 ( . 128E-05 Ca . 05 1 • 02 .125E-05 Mg N.D. 1 • 01 ( • 535E-0E:-Fe N.D. 1 . 00 ( . 358E-07 Al N.D. 1 . 05 . 185E-05 Si02 4.0€:- 1 . 04 .£-7€:-E-04 B N.D. 1 . 00 ( .370E-0E:-Li N.D. 1 . 00 .432E-0E:. S·r' N.D. 1 . 00 ( . 114E-07 Zn N.D. 1 • 01 ( .7E:-5E-07 Ag N.D. 1 • 00 ( . 371E-07 As N.D. 1 • 04 ( . 534E-0E:. Al..l N.D. 1 .01 ( .406E-07 Ba N.D. 1 • 03 .182E-0E:-Be N.D. 1 • 00 ( . 111E-07 Bi N.D. 1 . 20 < .957E-0E:-Cd N.D. 1 • 00 < . 35€:-E-07 Ce N.D. 1 • 02 ( .143E-0E:. Co N.D. 1 . 00 ( .339E-07 Cr N.D. 1 . 01 ( .192E-0E:-Cl..l N.D. 1 . 01 < .787E-07 La N.D. 1 . 01 ( .720E-07 Mn N.D. 1 • 02 ( .3E:-4E-0E:-Mo N.D. 1 • 05 < .521E-01S Ni N.D. 1 . 01 ( • 170E-0E:-Pb N.D. 1 • 02 ( .9E:.5E-07 Sn N.D. 1 • 01 < .843E-07 Sb N.D. 1 . 04 ( . 329E-0E:-Te N.D. 1 • 10 ( . 784E-0E:-Th N.D. 1 • 20 ( . 8E:-2E-0E:-Ti N.D. 1 • 01 ( • 209E-0E:-u N.D. 1 • 50 ( • 210E-05 v N.D. 1 • 10 < . 19€:-E-05 w N.D. 1 • 01 ( • 544E-07 Zr N.D. 1 • 01 < • 110E-06 NH4 N. A. 5 • 12 ( .E:-E:-SE-05 Cs N. A. 10 • 50 ( .37£-E-05 Rb N. A. 10 . 30 ( .351E-05

PUNA GEOTHERMAL KS-'3 1BBB

ID #: A:3'3303~3.PG

DATE: 05-25-'33

SPECIES CONCENTRATION (ppm>

ANALYTICAL DETECTION CONCENTRATION

TOTAL ALKALINITY HC03 C03 Cl F S04 Br I N03 s P04

AS N. A. N. A. N. A. N. A. N. A. N. A. N. A. N. A. N. A. N.D.


MEASURED CALCULATED

NOT MEAS. 4.60

pH • 00

METHOD

2 ·::. .... 2 5

11 2 2 '3 .-. .::. 1

4 IS

7

LIMITS <MOL/L)

1. 00 { .164E-04 1. 00 .167E-04 1. 00 { .282E-04

• 05 ( .263E-05 1. 00 { .104E-04

. 50 ( .626E-05

. 10 ( .788E-01S • 10 { .161E-05 • 20 ( .624E-05 • 15 { .159E-05

4.00

**********************************************************************

ANALYTICAL METHODS:

1. INDUCTIVELY COUPLED PLASMA SPECTROMETER &0~.7 2. TITRATION <LABORATORY> 3. TITRATION <FIELD> 4. GRAVIMETRIC 5. SPECIFIC ION ELECTRODE 6. METHOD OF HEM <1~70, USGS Water Supply Paper 1473) 7. pH METER <LABORATORY> 8. pH METER <FIELD> '3. COLORIMETRIC

10. ATOMIC ABSORPTION 11. TURBIDIMETRIC


**********************************************************************

PUNA GEOTHERMAL ~S-9 2AB,288

Ca

CATIONS

,.

·~

PERCENT OF TOTAL MlLLlEOUIVALENTS PER LITER

UURI ID• A:3930392.PG DATE: 05-25-93

X

Cl -+

ANIONS

*****************************************************~***************•

PUNA GEOTHERMAL KS-9 lAS, lBS

ID #: A:3930390.PG DATE: 05-25-93

**********************************************************************

SPECIES CONCENTRATION ANALYTICAL DETECTION CONCENTRATION (ppm) METHOD LIMITS <MOL/U

Na . 07 1 . 04 .304E-05 K N.D. 1 . 05 ( . 128E-05 Ca N.D. 1 .02 ( .374E-0S Mg N.D. 1 . 01 ( . 535E-tZt6 Fe . 15 1 • 00 .2S9E-05 Al N.D. 1 • 05 < . 185E-05 Si02 5. 18 1 . 04 .8S2E-04 B N.D. 1 . 00 .370E-06 Li N.D. 1 . ~0 4 "7·=·E-$M S·r• N.D. 1 .1£0 : 1l41::.- 7 Zn N.D. 1 . 01 ( .7S5E-07 Ag N.D. 1 • 00 < .371E-07 As N.D. 1 . 04 ( .534E-06 Au N.D. 1 • 01 < . 406E-07 Ba N.D. 1 • 03 . 182E-0S Be N.D. 1 . 00 ( .111E-07 Bi N.D. 1 . 20 .957E-0S Cd N.D. 1 . 00 . 356E-07 Ce N.D. 1 • 02 . 143E-06 Co N.D. 1 .00 .339E-07 Cr N.D. 1 . 01 . 1'7>2E-0S Cu N.D. 1 . 01 .787E-07 La N.D. 1 .01 { .720E-07 Mn N.D. 1 . 02 { • 3S4E-0S Me N.D. 1 • 05 < .521E-06 Ni N.D. 1 • 01 < . 170E-06 Pb N.D. 1 . 02 < .965E-07 Sn N.D. 1 . 01 { .843E-07 Sb N.D. 1 . 04 { . 329E-0S Te N.D. 1 . 1121 ( .784E-0S Th N.D. 1 . 20 ( .8S2E-06 Ti N.D. 1 • 01 ( .209E-0S u N.D. 1 . 50 { .210E-05 v N.D. 1 • 1 tZI { . 19SE-05 w N.D. 1 . 01 { .544E-07 Zr N.D. 1 • 01 ( . 110E-0S NH4 7•C"

• '"'...J 5 • 12 .194E-04 Cs N. A. 10 • 50 ( .37SE-05 Rb N. A. 10 • 30 ( .351E-05

PUNA GEOTHERMAL KS-9 lAS, 1BS

ID #: A:3930390.PG DATE: 05-25-93

SPECIES CONCENTRATION <ppm)

TOTAL ALKALINITY AS HC03 C03 Cl F S04 Br~

I N03 s P04

3.00 N.D.

1. 40 . 07

1. 00 N.D. N. A. N.D. 403.00

N.D.



pH

14.00 412.70

3.39

4.60


ANALYTICAL METHOD

.-. c.

2 .-. c.

5 11

2 2 g .-. c.

1

4 6

7

DETECTION LIMITS

1. 00 1. 00 1. 00 .05

1. 00 • 50 . 10 • u. jl . 20 . 15

4.00

EC Hg TSS

27 {0. 5 1.0

u mhos/em ppb ppm C,ra v,_,.,.;-t~,c , toe;

CONCENTRATION <MOL/L)

.492E-04 < .157E-04

. 395E-04 • 358E-05 . 104E-04

< • 626E-05 < • 788E-06

.161E-05

.126E-01 < • 159E-05

**********************************************************************

ANALYTICAL METHODS:

1. INDUCTIVELY COUPLED PLASMA SPECTROMETER ~t)tJ . .7 2. TITRATION <LABORATORY> ~bo 3. TITRATION <FIELD> 4. GRAVIMETRIC 6 t> cJ 5. SPECIFIC ION ELECTRODE ~~c 6. METHOD OF HEM <1970, USGS Water Supply Paper 1473> 7. pH METER <LABORATORY> 6 (! a 8. pH METER <FIELD> 9. COLORIMETRIC /, tJ(}

10. ATOMIC ABSORPTION 11. TURBIDIMETRIC t a ~


**********************************************************************

PUNA GEOTHERMAL KS-9 1AS,1BS

I

ID #: A:3930390.PG DATE: 05-25-93

Milliequivalents/Liter

1----------------------------------------------------l I

CATIONS I

1----------------------1 Na Fe NH4

I . 00304 . 00537 • 01940

1----------------------------------------------------l I I I

SUM OF CATIONS: .02782 I

1----------------------------------------------------l I

ANIONS

1----------------------1 I

HC03 Cl F S04 s

. 04917

. 03949

. 00368

. 02082 25. 13CH4

I I

1----------------------------------------------------l I I I

SUM OF ANIONS: I 25.25231 I I I 1----------------------------------------------------l I I

CATION-ANION BALANCE

I

I BALANCE DIFF. I

-25.22449

CATION+ ANION I -99.78 I I I

1----------------------------------------------------l I I I

----------------~-------------------------------------

**********************************************************************


ID #: A:3930392.PG DATE: 05-25-93

**********************************************************************

SPECIES CONCENTRATION ANALYTICAL DETECTION CONCENTRATION <ppm> METHOD LIMITS <MOL/L)

Na 20.45 1 . 04 .8':!0E-03 K 1. 85 1 . 05 . 473E-04 Ca. ... -. • .JC. 1 . 02 . 130E-04 Mg .04 1 • 01 .1S5E-05 Fe . 29 1 . 00 .519E-05 Al . 14 1 . 05 .519E-05 Si02 128.23 1 • 04 • 213E-02 B 2.79 1 .00 .258E-03 Li . 03 1 . 00 .432E-05 Sr N.D. 1 . 00 < • 114E-07 Zn N.D. 1 • 01 < .7S5E-!Z17 Ag N.D. 1 • 00 < .371E-07 As N.D. 1 • 04 ( . 534E-06 A•.1 N.D. 1 .01 . 40SE-07 Ba . 13 1 . 03 .947E-0S Be N.D. 1 . 00 < .111E-07 Bi N.D. 1 . 20 .957E-0S Cd N.D. 1 . 00 ( .35SE-07 Ce N.D. 1 . 02 .143£-06 Co N.D. 1 . 00 ( . 33·:;E-07 Cr N.D. 1 • 01 ( .192E-0S Cu N.D. 1 . 01 { .787E-07 La N.D. 1 . 01 ( .720E-07 Mn N.D. 1 0·::0 . ,_ { • 3S4E-0S Mo N.D. 1 . 05 ( .521E-0S Ni N.D. 1 • 01 ( • 171Z!E-IZIS Pb N.D. 1 0·=· . ,_ ( .9S5E-07 Sn N.D. 1 • 01 ( • 843E-IZI7 Sb N.D. 1 • 04 ( .32':JE-0S Te N.D. 1 . 10 { .784E-0S Th N.D. 1 • 20 { .8S2E-0S Ti N.D. 1 • 01 { .209E-0S u N.D. 1 • 50 { .210E-05 v N.D. 1 • 10 < • 19SE-05 w N.D. 1 • 01 < .544E-07 Zr N.D. 1 .01 < .110E-0S NH4 • 17 5 1·=· . ..... .942E-05 Cs N. A. 10 .50 < • 37SE-05 Rb N. A. 10 . 30 < .351E-05


SPECIES CONCENTRATION <ppm>

ANALYTICAL

TOTAL ALKALINITY AS HC03 C03 Cl F S04 B"r' I N03 s P04

8.00 N.D.

8.00 • 38

11.00 N.D. N. A. N.D.

141.00 . 51



pH

174.00 319.47 54.47

6.26


•-t mhos/em ppb ppb

METHOD

,.., 0::. .-. 0::. .... 0::.

5 11

2 .-. 0::.

9 .-. 0::.

1

4 6

7

EC Hg As TSS SI02

174 <0. 5 16 9.0 17.3

ppm G ~"~ Ill .-Jn c- fv 1 c? . L, t () MG/L ICP 200.7 (1QBB>

ID #: A:3930392.PG DATE: 05-25-93

DETECTION LIMITS

1. 00 1. 00 1. 00

. 05 1. 00

• 50 . 10

. '" • 20 • 15

4.00

CONCENTRATION <MOL/L)

.131E-03 < • 167E-04

• 226E-03 .200E-04 .115E-03

< • 626E-05 < • 788E-06 < . 161E-05

.440E-02

.541E-05

**********************************************************************

ANALYTICAL METHODS:

1. INDUCTIVELY COUPLED PLASMA SPECTROMETER ~~0-7 2. TITRATION <LABORATORY> &06 3. TITRATION <FIELD> 4. GRAVIMETRIC b~C 5. SPECIFIC ION ELECTRODE ~~~ 6. METHOD OF HEM <1970, USGS Water Supply Paper 1473) 7. pH METER <LABORATORY> &4 o 8. pH METER <FIELD> 9. COLORIMETRIC ~~0

10. ATOMIC ABSORPTION 11. TURBIDIMETRIC ~0 ()


w~~~--~~~~~~**********************************************************


I

ID #: A:3930392.PG DATE: 05-25-93

1 Milliequivalents/Liter I

1----------------------------------------------------l I I I

CATIONS I

1----------------------1 I

Na K Ca Mg Fe Al Li Ba NH4

. 88'358 • 04730 . 02595 • 00329 . 01038 . 01557 . 00432 . 00190 • 00942

1----------------------------------------------------l I I I

SUM OF CATIONS: 1.00772 I

1----------------------------------------------------l I I I I ANIONS I

1----------------------1 HC03 Cl F S04 s P04

I I

. 13112

. 22568

. 02000

. 22902 8.79558

. 01627

1----------------------------------------------------l I I I SUM OF ANIONS: 9.41768 I I I I

1----------------------------------------------------l I I I I

I

CATION-ANION BALANCE

I BALANCE DIFF.

-8.40996

I CATION+ ANION -80.67 I I

1----------------------------------------------------l I I

****************************************************************


TRILINEAR DIAGRAM COORDINATES

ID #: A:3930392.PG DATE: 05-25-93

****************************************************************

Meq I L Percent I <Meq j U

I I I I

l--------------------1--------------------l--------------------l I I I

I CATIONS

Na K Ca Mg

TOTAL

• 88958 . 04730 • 1212595 . 121121329

.96612

I I I

92.1217727 4.89635 2.6858121

• 3412158

1--------------------l--------------------l--------------------

ANIONS

HC03 C03 504 Cl

TOTAL

.13112 • 0012100 . 22902 • 22568

. 58582

I I

22.38230 .00000

39.09392 38.52378

100.0001210

--------------------------------------------------------------1

***************************************************************


GEOTHERMOMETERS

ID #: A:3930392.PG DATE: 05-25-93

***************************************************************

Geothermometer

Quartz <no steam loss)

Quartz (maximum steam loss)

Chalcedony

alpha-Cristobalite

beta-Cristobalite

Amorphous Silica

Na/K <Four~nier)

Na/K <Truesdell)

Na-K-Ca

Na-K-Ca with Mg correction

Na/Li

Temp (deg C>

1 c-·-· ~c.

145.

127.

101.

C"·-. ~~-

30.

21Z19.

177.

170. beta= .33

1o2. R= 4.30

98.

Reference

Four~nier <1981)

Fout~n i er ( 1981)

F o •.trn i er~ (1981)

Fourniet~ (1981)

Fout'nier ( 1981)

Four~n i er~ (1979)

Fournier' (1981)

Fournier and TruesdellC1974)

Fournier and Potter (1979)

Fouillac and MichardC1981)

PUNA GEOTHERMAL VENTURE A Hawaii Partnership f; • ·'. ,.

June 23, 1993

Keith W. Ahue. Chairperson Department of Land and Natural Resources P.O. Box 621 Honolulu, HI 96809

SUBJ: KS-9 WELL COMPLETION REPORT

Dear Mr. Ahue.

\""'4> :/' - ,, -;:: ~-

·>:' . ..£.: .....

(~···"

Pursuant to Subchapter 12 (Drilling; Records and Reports of Wells),Section 13-183-85, Puna Geothermal Venture (PGV) here-

\.-,>

by submits the attached well completion report for Well Kapoho State 9 (KS-9).

Included in this report are:

* Well record summary * Well location map * Well schematic * Workover history * Survey plot map * Well history * Navigation survey * Production wellfhead configuration * Chemistry report * Temperature and production report * Chemistry lab reports on produced geofluids and

venting emissions * Groundwater sample analysis * Cleanout flow (test) report

Should you or your staff have any questions. please contact me.

r

~G-~(6aAS Thomas G. Kizis - v ~ \.: Environmental Manager

c: S. Morris G. Davidson Mesquite

File: KS-9

14-3860 Kapoho Pahoa Road, Pahoa, Hawaii 96778 • (808) 961-2786 • Facsimile (808) 935-5562 Post Office Box 30, Pahoa, Hawaii 96778

·~···- .. ~

PAGE NUMBER ~OF (

DATE TIME BRINE FLOW K#/HR

tf- zo Ita: 3S" -.. ,l : ,.._'"' -., ,:z.: IS I -H tz:Es.o -.. ,.., . --~ I

---~- Zt

.. 1.3 : ;;:s"l :Z.l .. I~< i1 I z..~ .. I ,~-:to z..q .. lr_s·.zol -

I

I I

I

I 1 OPERATORS INITIALS ABBREVIATIONS:

INJ: INJECTED D: D PAD A: A PAD

I

STEAM SP-AM H2S BEFORE FLOW SOURCE TREATMENT K#/HR PPM #/F!R

- t\S- '=t - -- .. - -- .. - -- .. - -

11'1 I .. - -II '1 .. ~5-=J to~

lbO .. ~~ ;57

lbO .. c:;'lo I~

- .. - -I

I

ESRF: EMERGENCY STEAM RELEASE FACILITY

.-·

TECTON'S SUMMARY DATA SHEET

H2S TOTAL H2S NaOH ABATE WATER COMMENTS II EMISSIONS EMISSIONS INJECTION \ MOLE EFFICIENCY INJECT PPM #/HR #/HR GPH RATIO \ REMOVAL GAL/HR

- - - IS~b :Sc% - - tDCO lo~,., """:...~' IF - - - IE; '8(:, '50 - - bOCO f},J-... j;c;~ :F - - - fO~b I c:::-o - - bDDO Is-top q~ i'PV'"';t

- - - 3.30 50 - - bOOO c:-t~"-J~w IS; ;.:p .c II "'~ <;·o ~6·'i5 tJ· <15" 350 50 - - (;;.DOO WI~( ~~ 'b·o 0·~ 0· 't5' 3.5CJ so t1·S '1, - t b0CO luJT-*".2. !/!P '8 ·'S I· Z.l r • z..t 330 so l.3 . ( 'l'l . f {;;.CC.O I""G:-r~ t:.(o., 'S·~ 1-z.S"' r.z.r;- .3.3::::> I So JZ.·G:. ,, • f f>DOO I u.ll ..u:-4- rF - - - - - - - - l~.,t-., ... ~I

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1. - university of hawaii · 2018-08-02 · dumped 55 gallons of sand on top of packer. ran in hole...

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