zive electrochemical workstations · designing the solution for electrochemistry ... (*1) the...

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ZIV ZIVE Electrochemical Workstations Electrochemical Workstations ZIVE SP1 ZIVE SP1 ZIVE SP1 ZIVE SP1 Designing the Solution for Electrochemistry Potentiostat/Galvanostat І Battery Cycler І Fuel Cell Test Station +82-2-578-6516 І [email protected] www.wonatech.com І www.zivelab.com І www.fctest.com

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Page 1: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

ZIVZIVEE Electrochemical WorkstationsElectrochemical Workstations

ZIVE SP1ZIVE SP1ZIVE SP1ZIVE SP1

Designing the Solution for ElectrochemistryPotentiostat/Galvanostat І Battery Cycler І Fuel Cell Test Station+82-2-578-6516 І [email protected] І www.zivelab.com І www.fctest.com

Page 2: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

FeaturesZIVE SP1ZIVE SP1

Page 3: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

FeaturesZIVE SP1ZIVE SP1

• Economical high quality potentiostat/galvanostat/impedance analyzer• Compact size with full functions & Smart LCD display• Wide current range(1A to 1nA) for various applications• Wide current range(1A to 1nA) for various applications• Supports fourteen(14) kind of EIS techniques• Current interrupt IR measurement/IR compensation• Pulse charge/discharge test available• Bipolar pulse capability• High speed data sampling time

- 50usec/sample in burst mode- 1msec/sample in normal mode1msec/sample in normal mode- 2usec/sample in fast sweep mode

• Internal 350,000 data point storage• Multichannel configuration available• Software packages

- Energy software package (BATe)- EIS software package (EISe)- Electrochemical analysis software package(EASe)y p g ( )- Corrosion software package (CORe)

• Free software package

Page 4: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

AppearanceFront ViewFront View

Page 5: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

AppearanceLCD Display – DC ModeLCD Display DC Mode

Page 6: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

AppearanceLCD Display – EIS ModeLCD Display EIS Mode

Page 7: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

AppearanceRear ViewRear View

Page 8: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

System Configuration

• System setup with multiple ZIVE SP1s• Connecting by USB hub

• System setup with one or more ZIVE product family• Connecting by USB hub

Page 9: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

When communication fails…

• When communication error occurs between ZIVE SP1 and PC the data will• When communication error occurs between ZIVE SP1 and PC, the data will be stored on the device memory.

• The data will be transferred to the PC after PC is restored.

Page 10: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Strong Point (Hardware)

• Wide current range• Wide current range: Max. 1 Amp: Suitable for various application

• 3 measurement/control voltage range &/ g g10 measurement/control current range

• Independent operation by DSP with FPGA

• Built-in FRA : Impedance measurements available: No other device is needed.

• Compact size and light weight• Compact size and light weight: Small footprint: Suitable for field application

• Big memory capacityg y p y: 350,000 data point can be stored.

• One auxiliary voltage measurement available

Page 11: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Available Techniques

• Potentiostatic• Galvanostatic• Double step potentiostatic• Double step galvanostatic• OCP measurement• Potential sweep• Current sweep• Cyclic voltammetry• Fast potential sweep• Potentiostatic Ru measurement • Galvanostatic Ru measurement

Page 12: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Available Techniques

• Potentiostat EIS• Galvanostatic EIS• Pseudo galvanostatic EIS• OCP* EIS• Potentiodynamic PEIS• Galvanodynamic GEIS• Poteniodynamic HFR• Galvanodynamic HFR • Potentiostatic HFR monitor• Galvanostatic HFR monitor• Multisine potentiostatic EIS • Multisine galvanostatic EIS• Intermittent potentiostatic EIS • Intermittent galvanostatic EIS

(*1) The system measures open circuit potential before each frequency change and applies AC sinewave on this potential.

Page 13: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Available Techniques

a) Battery test technique- CC/CV test for cycle life test of lithium battery - CC/CC tet for cycle life test of NiCd or NiMH battery - Discharging test- EVS(electrochemical voltage spectroscopy)- Variable scan rate CV- Potentiostatic IV curve- Galvanostatic IV curve- Steady state CV- PITT(Potentiostatic intermittent titration technique) test- GITT(Galvanostatic intermittent titration technique) test- Pulse mode is available for GSM & CDMA profile.

Pulse shape profile can be measured by user's demand.b) Control mode

- Charge : CC, CC-CV, pulse, sine wave- Discharge : CC, CP, CR, pulse, sine wave

c) Cut-off condition- Time, voltage, current, power, auxV etc.- Various battery charge/discharge test is available including

pulse discharge for GSM, CDMA application

Page 14: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Available Techniques

• Tafel(Tafel experiment)• Rp(Polarization resistance)• RpEc trend• PDYN(Potentiodynamic)• CYPOL(Cyclic polarization resistance)• GDYN(GalvanoDynamic)• Reactivation• Galvanic corrosion• Potentiostatic ECN• Galvanostatic ECN• ZRA mode ECN

Page 15: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Available Techniques

a) Step techniques- CA(Chronoamperometry)- CC(Chronocoulometry)- CP(Chronopotentiometry)

b) Sweep techniques- LSV(Linear sweep voltammetry)- SDV(Sampled DC voltammetry)- Fast CV- Fast LSV

c) Pulsed techniques- DPV(Differential pulse voltammetry)- SWV(Square wave voltammetry)- DPA(Diff.pulse amperometry)- NPV(Normal pulse voltammetry)- RNPV(Reverse normal pulse voltammetry)- DNPV(Differential normal pulse voltammetry)

Page 16: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Applicable FieldMarket For the ProductMarket For the Product

Other Application- Coating evaluation- Heavy metal detection- Semiconductor- EDLC- Membrane- Bioelectrochemistry- Material testing etc.g

Page 17: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

System

Cell cable 1 meter shielded type(standard)working, reference, counter, working sense, auxiliary V

ControlDAC

DSP with FPGA2x16bit DAC(50MHz) for bias & scan

Data acquisitionADC

2x16 bit ADCs(500kHZ) for voltage, current1x16bit ADCs(250kHz) for auxiliary readingADC 1x16bit ADCs(250kHz) for auxiliary reading

Calibration Automatic

Filter selection 4ea (5Hz, 1kHz, 500kHz, 5MHz)

Scan rate 0~200V/sec in common mode0~5000V/sec in fast mode

Max. channel no. 8 channels via USB connection

Internal data memory 350,000 points

Page 18: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

Power Amplifier(CE)

Power 12Watt (12V@1A)

Compliance voltage ±12VCompliance voltage ±12V

Max. current ±1A

Control speed selection 4eap

Bandwidth 2MHz

Slew rate 10V/usec

Page 19: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

Potentiostat Mode (Voltage Control)

Voltage Control

Control voltage range ±10V, ±1V, ±100mV

Voltage resolution 16 bit per each range

Voltage accuracy ±1mV, ±0.05% of setting(gain x1)

Max scan range ±10V vs ref EMax. scan range ±10V vs. ref. E

Current Measurement

Current range 10 ranges (auto/manual setting)100nA~1A1nA & 10nA with gain

Current resolution 16 bit30uA, 3uA, 300nA, 30nA, 3nA, 300pA,30uA, 3uA, 300nA, 30nA, 3nA, 300pA, 30pA, 3pA (300fA, 30fA with gain)

Current accuracy ±10pA ±0.1% f.s. (gain x1)>100nA f.s.

Page 20: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

Galvanostat Mode (Current Control)

Current Control

Control current range max. ±1A± full scale depending on selected range± full scale depending on selected range

Current resolution 16 bit30uA, 3uA, 300nA, 30nA, 3nA, 300pA, 30pA, 3pA (300fA 30fA ith i )(300fA, 30fA with gain)

Current accuracy ±10pA ±0.1% f.s. (gain x1)>100nA f.s.

Voltage Measurement

Voltage range 10V, 1V, 100mV

Voltage resolution 16 bit0.3mV, 30uV, 3uV0.3mV, 30uV, 3uV

Voltage accuracy ±1mV ±0.05% of reading(gain x1)

Page 21: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

EIS(Internal FRA) for System( ) y

Frequency range 10uHz ~ 1MHz

Frequency accuracy 0.01%

Frequency resolution 5000/decade

Amplitude 0.1mV ~ 5V rms (potentiostatic)f ( l )0.1 ~ 70% f.s. (Galvanostatic)

Mode Static EIS:Potentiostatic, Galvanostatic,Pseudogalvanostatic OCPPseudogalvanostatic, OCP

Dynamic EIS:Potentiodynamic, Galvanodynamic

Fixed Frequency Impedance:Potentiostatic GalvanostaticPotentiostatic, Galvanostatic,Potentiodynamic, Galvanodynamic

Multisine EIS:Potentiostatic, Galvanostatic

Intermittent PEIS/GEISIntermittent PEIS/GEIS

Page 22: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

ElectrometerElectrometer

Max. input voltage ±10V

Input impedance 2x1013 Ω ιι 4.5pF

Bandwidth >22MHz

CMRR >114dB

Interface for System

Auxiliary port

Auxiliary voltage input 1 analog input: ±10V

Zero resistance ammeter 100nA ~ 1AZero resistance ammeter 100nA ~ 1A

External booster interface Via booster I/F cable

Sync terminal For channel synchronizing

Page 23: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

SoftwareSoftware

Max. step per experiment 1000

Shutdown safety limits voltage, current, power, AuxV, etc.

Max. sampling rate 20kHz(50usec) in burst mode500kHz(2usec) in fast sweep mode

Max. sampling time unlimitedp g

Sampling condition Time, dV/dt, dI/dt, etc.

Main Systemy

PC communication USB 2.0 high speed

Line voltage 100~240VAC, 50/60Hz, 1Amp

Power adapter 24V, 2.5Amp

Size / Weight 160x330x81mm(WxDxH) / 2.05kg

Max. output power 15Watt

Page 24: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

Smart LCD Display

DC mode Control value, E value, I valueE range, I range

EIS mode Frequency, Magnitude, PhaseE range, I range

Operation status Mode: PST, GST, ZRA, EIS, CC, CV, CP, CRStatus: Cell on Run ErrorStatus: Cell on, Run, Error

Page 25: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

SpecificationZIVE SP1ZIVE SP1

PC RequirementPC Requirement

Operating system Windows XP SP3/7/8/10(32bit/64bit OS)

PC ifi ti P ti 4 RAM 1GB hi hPC specification Pentium4, RAM 1GB or higher

Display 1600x900 high color or higher

USB High speed 2.0g p

General

Dummy cell One external dummy cell included

Impedance data analysis software ZMANTM software

DC data analysis software IVMANTM software

Page 26: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Ordering Guide

Zi SP1Zive SP1- Comes with following items as standard

a) Cell cable with alligator clips, 1eab) Dummy cell, 1ea) AC/DC d t +24V 2 5A 1

Standard Systemc) AC/DC adapter, +24V 2.5A, 1ead) Power cord, 1eae) USB cable, 1eaf) Install CD, 1ea

Software Package- EIS software package (EISe)- Energy software package (BATe)gy p g ( )- Corrosion software package (CORe)- Electrochemical analysis software package (EASe)

Optional Booster I/F Cable, 1.5m

Optional Items

Page 27: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Quick Start Guide

① Insert installation CD and click ‘Smart Manager’ ② The Smart Manager installation program will run① Insert installation CD and click Smart Manager button to install Smart Manager program.

② The Smart Manager installation program will run.- Follow the prompts through the rest of the

installation process.- If Microsoft visual C++2010 was not installed on

your PC, it will be installed. Or if VC++2010 wasy ,installed on your PC already, click cancel button.

Page 28: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Quick Start Guide

③ Click LabView RTE2013 button which is needed ④ Install data analysis software packages③ Click LabView RTE2013 button, which is neededfor data analysis packages.

④ Install data analysis software packages.- Click ZMAN button to install EIS data analysis

software package- Click IVMAN button to install DC data analysis

software packagesoftware package- Click SIM4U button to install cyclic voltammetry

digital simulation software package

Page 29: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Quick Start Guide

⑤ Plug in the ZIVE instrument’s power cord ⑥ Microsoft Windows will detect ZIVE instrument⑤ Plug in the ZIVE instrument s power cord.- Plug in the USB cable.- Plug in the cell cable.- Switch on the ZIVE instrument.

⑥ Microsoft Windows will detect ZIVE instrument.

l h ’Plug in the potentiostat’s power cord. Plug in the USB cable.

Run Device Manager on control panel.Double click on

Switch on the ZIVE SP1Plug in the cell cable.

Page 30: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Contact Information

+82-2-578-6516

[email protected]

+82-2-578-6516+82 2 578 6516

[email protected]

Page 31: ZIVE Electrochemical Workstations · Designing the Solution for Electrochemistry ... (*1) The system measures open circuit potential before each frequency change and applies AC sine

Thank o !Thank you !