zertifikat eu approved - 2b technologies · this certificate is based upon the equipment tested....

13
ATÜVRheinland® Precisely Right. CERTIFICATE of Product Conformity (QAL1 ) Certificate No.: 0000062070 AMsdesignation: Model405nmforNO, N02and NOx Manufacturer: 2B Technologies 2100 Central Avenue Boulder, Colorado 80301 USA Test Laboratory: TÜV Rheinland Energy GmbH This is to certify that the AIVIS has been tested and found to comply with the standards: VDI 4202-1 (2018), EN 14211 (2012), Guide to the demonstration of equivalence of ambient air monitoring methods (2010), EN 15267-1 (2009) and EN 15267-2 (2009) Certification is awarded in respect of the conditions stated in this certificate (this ceriificate contains 13 pages). Publication in the German Federal Gazette (BAnz) of 22 July 2019 Federal Environment Agency Dessau, 05 November 2019 ftJÜJ-,/ Dr. Marcel Langner Head of Section 114.1 Suitability Tested Complying with 2008/50/EC EN 15267 Regular Surveillance www.tuv.com l D 0000062070 Expiry date: 21 July 2024 TÜV Rheinland Energy GmbH Cologne, 04 November 2019 o,, p,ft J+ ppa. Dr. Peterwilbring qal l .de [email protected] Page 1 of 13

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ATÜVRheinland®Precisely Right.

CERTIFICATEof Product Conformity (QAL1 )

Certificate No.: 0000062070

AMsdesignation: Model405nmforNO, N02and NOx

Manufacturer: 2B Technologies2100 Central AvenueBoulder, Colorado 80301USA

Test Laboratory: TÜV Rheinland Energy GmbH

This is to certify that the AIVIS has been tested and found to comply withthe standards:

VDI 4202-1 (2018), EN 14211 (2012),Guide to the demonstration of equivalence of ambient air monitoring methods

(2010), EN 15267-1 (2009) and EN 15267-2 (2009)

Certification is awarded in respect of the conditions stated in this certificate(this ceriificate contains 13 pages).

Publication in the German Federal Gazette(BAnz) of 22 July 2019

Federal Environment AgencyDessau, 05 November 2019

ftJÜJ-,/Dr. Marcel LangnerHead of Section 114.1

Suitability TestedComplying with2008/50/ECEN 15267Regular Surveillance

www.tuv.coml D 0000062070

Expiry date:21 July 2024

TÜV Rheinland Energy GmbHCologne, 04 November 2019

o,, p,ft J+ppa. Dr. Peterwilbring

qal l .de [email protected] Page 1 of 13

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 2 of 13

Test Report: 936/21242468/A dated 19 February 2019

Initial certification: 22 July 2019

Expiry date: 21 July 2024

Publication: BAnz AT 22.07.2019 B8, chapter III number 1.1

Approved application The certified AMS is suitable for continuous ambient air monitoring of nitrogen oxides (sta-tionary operation). The suitability of the AMS for this application was assessed on the basis of a laboratory test and a seven-months field test. The AMS is approved for an ambient temperature range of 0 °C to +30 °C. The notification of suitability of the AMS, performance testing and the uncertainty calculation have been effected on the basis of the regulations applicable at the time of testing. As changes in legal provisions are possible, any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for monitoring the AMS readings relevant to the application. Any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for the intended purpose. Basis of the certification This certification is based on:

Test report no. 936/21242468/A dated 19 February 2019 issued by TÜV Rheinland Energy GmbH

Suitability announced by the German Federal Environment Agency (UBA) as the relevant body

The ongoing surveillance of the product and the manufacturing process

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 3 of 13

Publication in the German Federal Gazette: BAnz AT 22.07.2019 B8, chapter III number 1.1, UBA announcement dated 28 June 2019:

AMS designation:

Model 405 nm for NO, NO2 and NOx

Manufacturer:

2B Technologies, Boulder, USA

Field of application:

For the continuous measurement of nitrogen oxide concentrations from stationary sources in ambient air

Measurement ranges during performance testing:

Component Certification range Unit

Nitrogen monoxide 0–1 200 µg/m³

Nitrogen dioxide 0–500 µg/m³

Software version:

Version 36B

Restriction:

None

Notes:

1. The test report on performance testing is available on the internet at www.qal1.de.

2. As the measuring system does not provide password protection, it has to be mounted in a lockable cabinet.

3. Equivalence to the reference method in accordance with the requirements of the Guide to the Demonstration of Equivalence of Ambient Air Monitoring Methods was demonstrated.

Test Report:

TÜV Rheinland Energy GmbH, Cologne Report no. 936/21242468/A dated 19 February 2019

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 4 of 13

Certified product This certification applies to automated measurement systems conforming to the following de-scription: The Model 405 nm ambient air monitor is a continuous nitrogen oxide analyser. The instru-ment uses direct UV absorption as a measuring principle. It was designed for the continuous measurement of NO, NO2 and NOx in ambient air.

The model 405 NO2/NO/NOx monitor is designed to measure atmospheric nitrogen dioxide (NO2), nitrogen oxide (NO) and NOx (NO + NO2) in a dynamic range from just a few ppb up to 10 ppm for NO2 and 2 ppm for NO based on the detection of visible light at a wave length of 405 nanometres (nm).

The model 405 inside the analyser uses the absolute method to measure NO2 on the basis of Beer-Lambert law. NO2 measurement relies on a conventional absorption method. NO2 is analysed at a UV light wave length of 405 nm. The necessary measurement path length of 2 m is realised by using a measurement cell with a tube design which facilitates low volumes and fast gas replacement.

Nitrogen oxide is measured by measuring UV light intensities with and without adding ozone for oxidising NO to NO2. As described in more detail below, the result is a “semi-direct” measurement of NO in that the NO concentration is output directly and not based on subtrac-tion of NO2 concentration from a total NOx concentration. Instead, the NOx concentration is computed as the sum of the measurements of NO2 and NO.

The pump sucks in sample air through the instrument at a constant flow rate of 1.5 l/min. The NO2 scrubber valve alternately bypasses and sends the sample air through a heated NO2 scrubber to remove all NO2 in the sample. The NO2-scrubbed or unscrubbed air passes through the reactor volume and the DewLineTM Nafion Tubes, through the optical cell and through the cell flow meter. Alternate switching of the NO2 scrubber valve once every 5 sec-onds allows the measurement of a light intensity in the absence (Io) of NO2 and presence (I) of NO2. The Beer-Lambert Law is then used to calculate the concentration of NO2 from I and Io.

Nitrogen oxide is measured by bypassing the NO2 scrubber and measuring the light intensity while adding (I) or not adding (Io) ozone to convert NO to NO2 according to the well-known reaction:

NOx is computed from the measurement of NO and NO2.

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 5 of 13

General remarks This certificate is based upon the equipment tested. The manufacturer is responsible for en-suring that on-going production complies with the requirements of the EN 15267. The manu-facturer is required to maintain an approved quality management system controlling the manufacturing process for the certified product. Both the product and the quality manage-ment system shall be subject to regular surveillance. If a product of the current production does not conform to the certified product, TÜV Rhein-land Energy GmbH must be notified at the address given on page 1. A certification mark with an ID-Number that is specific to the certified product is presented on page 1 of this certificate. This document as well as the certification mark remains property of TÜV Rheinland Energy GmbH. Upon revocation of the publication the certificate loses its validity. After the expiration of the certificate and on request of TÜV Rheinland Energy GmbH this document shall be re-turned and the certificate mark must no longer be used. The relevant version of this certificate and its expiration date are also accessible on the in-ternet at qal1.de.

Document history

Certification of the Model 405 nm measuring system is based on the documents listed below and the regular, continuous surveillance of the manufacturer’s quality management system.

Initial certification according to EN 15267

Certificate no. 0000062070: 05 November 2019 Expiry date of the certificate: 21 July 2024 Test report 936/21242468/A dated 19 February 2019 TÜV Rheinland Energy GmbH, Cologne Publication: BAnz AT 22.07.2019 B8, chapter III number 1.1 UBA announcement dated 28 June 2019

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 6 of 13

Expanded uncertainty, laboratory, NO, system 1

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M405nm

Serial-N

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1073

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Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 7 of 13

Expanded uncertainty, laboratory, NO, system 2

Measuring d

evi

ce:

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Serial-N

o.:

1076

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ponent:

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Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 8 of 13

Combined uncertainty, laboratory and field, NO, system 1

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1073

Measure

d c

om

ponent:

NO

1h-lim

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alu

e:

104.6

nm

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687

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 9 of 13

Combined uncertainty, laboratory and field, NO, system 2

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1076

Measure

d c

om

ponent:

NO

1h-lim

it v

alu

e:

104.6

nm

ol/m

ol

No

.P

erf

orm

an

ce

ch

ara

cte

rist

icR

esu

ltS

qu

are

of

pa

rtia

l u

nce

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inty

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ty s

tandard

devi

ation a

t zero

≤1.0

nm

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ol

0.5

00

ur,

z0.0

90.0

076

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bili

ty s

tandard

devi

ation a

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lh

not

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50

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823

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ity c

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cie

nt

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ple

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1h-lim

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alu

e≤

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1.0

81.1

707

5S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.0

50

ugt

0.1

30.0

158

6S

ensitiv

ity c

oeffi

cie

nt

of surr

oundin

g t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.2

53

ust

0.6

40.4

053

7S

ensitiv

ity c

oeffi

cie

nt

of ele

ctr

ical vo

ltage a

t 1h-lim

it v

alu

e≤

0.3

0 n

mol/m

ol/V

0.0

00

uV

0.0

00.0

000

≤10 n

mol/m

ol (Z

ero

)0.3

30

≤10 n

mol/m

ol (S

pan)

2.8

00

≤5.0

nm

ol/m

ol (Z

ero

)1.0

30

uin

t,pos

≤5.0

nm

ol/m

ol (S

pan)

-0.3

30

≤5.0

nm

ol/m

ol (Z

ero

)1.6

70

≤5.0

nm

ol/m

ol (S

pan)

0.9

70

uin

t,neg

9A

vera

gin

g e

ffect

≤7.0

% o

f m

easure

d v

alu

e3.8

00

uav

2.2

95.2

663

10

Repro

ducib

ility

sta

ndard

devi

ation u

nder

field

conditio

ns

≤5.0

% o

f ave

rage o

ver

3 m

onth

s3.4

10

ur,

f3.5

712.7

225

11

Long t

erm

drift a

t zero

leve

l≤

5.0

nm

ol/m

ol

0.9

40

ud,l,z

0.5

40.2

945

12

Long t

erm

drift a

t span leve

l≤

5.0

% o

f m

ax.

of cert

ification r

ange

0.8

90

ud,l,lh

0.5

40.2

889

18

Diff

ere

nce s

am

ple

/calib

ration p

ort

≤1.0

%0.0

00

uD

sc

0.0

00.0

000

21

Conve

rter

effi

cie

ncy

≥98

99.6

00

uE

C0.4

20.1

751

23

Uncert

ain

ty o

f te

st

gas

≤3.0

%2.0

00

ucg

1.0

51.0

941

Com

bin

ed s

tandard

uncert

ain

tyu

c4.9

039

nm

ol/m

ol

Expanded u

ncert

ain

tyU

9.8

077

nm

ol/m

ol

Rela

tive

expanded u

ncert

ain

tyW

9.3

8%

Maxim

um

allo

wed e

xpanded u

ncert

ain

tyW

req

15

%

0.3

944

8b

Inte

rfere

nt

CO

2 w

ith 5

00 µ

mol/m

ol

1.3

11.7

227

or

8c

Inte

rfere

nt

NH

3 m

it 2

00 n

mol/m

ol

Pe

rfo

rma

nce

cri

teri

on

Pa

rtia

l u

nce

rta

inty

8a

Inte

rfere

nt

H20 w

ith 1

9 m

mol/m

ol

uH

2O

0.6

3

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 10 of 13

Expanded uncertainty, laboratory, NO2, system 1

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1073

Measure

d c

om

ponent:

NO

21h-lim

it v

alu

e:

104.6

nm

ol/m

ol

No

.P

erf

orm

an

ce

ch

ara

cte

rist

icR

esu

ltS

qu

are

of

pa

rtia

l u

nce

rta

inty

1R

epeata

bili

ty s

tandard

devi

ation a

t zero

≤1.0

nm

ol/m

ol

0.3

50

ur,

z0.0

70.0

048

2R

epeata

bili

ty s

tandard

devi

ation a

t 1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol

0.8

80

ur,

lh0.1

70.0

303

3"l

ack o

f fit

" at

1h-lim

it v

alu

e≤

4.0

% o

f m

easure

d v

alu

e2.3

60

ul,lh

1.4

32.0

313

4S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas p

ressure

at

1h-lim

it v

alu

e≤

8.0

nm

ol/m

ol/kP

a0.1

90

ugp

1.9

13.6

572

5S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

00

ugt

0.9

10.8

206

6S

ensitiv

ity c

oeffi

cie

nt

of surr

oundin

g t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

97

ust

1.7

83.1

846

7S

ensitiv

ity c

oeffi

cie

nt

of ele

ctr

ical vo

ltage a

t 1h-lim

it v

alu

e≤

0.3

0 n

mol/m

ol/V

0.0

00

uV

0.0

00.0

000

≤10 n

mol/m

ol (Z

ero

)0.0

70

≤10 n

mol/m

ol (S

pan)

2.2

70

≤5.0

nm

ol/m

ol (Z

ero

)-0

.070

uin

t,p

os

≤5.0

nm

ol/m

ol (S

pan)

-0.5

70

≤5.0

nm

ol/m

ol (Z

ero

)0.9

70

≤5.0

nm

ol/m

ol (S

pan)

0.8

30

uin

t,n

eg

9A

vera

gin

g e

ffect

≤7.0

% o

f m

easure

d v

alu

e3.4

00

uav

2.0

54.2

160

18

Diff

ere

nce s

am

ple

/calib

ration p

ort

≤1.0

%0.0

00

uD

sc

0.0

00.0

000

21

Conve

rter

effi

cie

ncy

≥98

99.8

0u

EC

0.2

10.0

438

23

Uncert

ain

ty o

f te

st

gas

≤3.0

%2.0

00

ucg

1.0

51.0

941

Com

bin

ed s

tandard

uncert

ain

tyu

c4.2

656

nm

ol/m

ol

Expanded u

ncert

ain

tyU

8.5

313

nm

ol/m

ol

Rela

tive

expanded u

ncert

ain

tyW

8.1

6%

Maxim

um

allo

wed e

xpanded u

ncert

ain

tyW

req

15

%

8b

Inte

rfere

nt

CO

2 w

ith 5

00 µ

mol/m

ol

0.4

80.2

299

or

8c

Inte

rfere

nt

NH

3 m

it 2

00 n

mol/m

ol

Pe

rfo

rma

nce

cri

teri

on

Pa

rtia

l u

nce

rta

inty

8a

Inte

rfere

nt

H20 w

ith 1

9 m

mol/m

ol

uH

2O

1.6

92.8

479

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 11 of 13

Expanded uncertainty, laboratory, NO2, system 2

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1076

Measure

d c

om

ponent:

NO

21h-lim

it v

alu

e:

104.6

nm

ol/m

ol

No

.P

erf

orm

an

ce

ch

ara

cte

rist

icR

esu

ltS

qu

are

of

pa

rtia

l u

nce

rta

inty

1R

epeata

bili

ty s

tandard

devi

ation a

t zero

≤1.0

nm

ol/m

ol

0.5

70

ur,

z0.1

20.0

134

2R

epeata

bili

ty s

tandard

devi

ation a

t 1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol

0.7

80

ur,

lh0.1

60.0

248

3"l

ack o

f fit

" at

1h-lim

it v

alu

e≤

4.0

% o

f m

easure

d v

alu

e3.2

90

ul,lh

1.9

93.9

476

4S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas p

ressure

at

1h-lim

it v

alu

e≤

8.0

nm

ol/m

ol/kP

a0.1

70

ugp

1.7

12.9

278

5S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

00

ugt

0.9

10.8

206

6S

ensitiv

ity c

oeffi

cie

nt

of surr

oundin

g t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.2

06

ust

1.8

73.4

822

7S

ensitiv

ity c

oeffi

cie

nt

of ele

ctr

ical vo

ltage a

t 1h-lim

it v

alu

e≤

0.3

0 n

mol/m

ol/V

0.0

20

uV

0.2

80.0

772

≤10 n

mol/m

ol (Z

ero

)0.2

30

≤10 n

mol/m

ol (S

pan)

2.1

30

≤5.0

nm

ol/m

ol (Z

ero

)0.0

70

uin

t,pos

≤5.0

nm

ol/m

ol (S

pan)

0.3

70

≤5.0

nm

ol/m

ol (Z

ero

)0.9

30

≤5.0

nm

ol/m

ol (S

pan)

0.8

00

uin

t,neg

9A

vera

gin

g e

ffect

≤7.0

% o

f m

easure

d v

alu

e1.6

00

uav

0.9

70.9

336

18

Diff

ere

nce s

am

ple

/calib

ration p

ort

≤1.0

%0.0

00

uD

sc

0.0

00.0

000

21

Conve

rter

effi

cie

ncy

≥98

99.6

0u

EC

0.4

20.1

751

23

Uncert

ain

ty o

f te

st

gas

≤3.0

%2.0

00

ucg

1.0

51.0

941

Com

bin

ed s

tandard

uncert

ain

tyu

c4.0

619

nm

ol/m

ol

Expanded u

ncert

ain

tyU

8.1

239

nm

ol/m

ol

Rela

tive

expanded u

ncert

ain

tyW

7.7

7%

Maxim

um

allo

wed e

xpanded u

ncert

ain

tyW

req

15

%

2.5

089

8b

Inte

rfere

nt

CO

2 w

ith 5

00 µ

mol/m

ol

0.6

80.4

558

or

8c

Inte

rfere

nt

NH

3 m

it 2

00 n

mol/m

ol

Pe

rfo

rma

nce

cri

teri

on

Pa

rtia

l u

nce

rta

inty

8a

Inte

rfere

nt

H20 w

ith 1

9 m

mol/m

ol

uH

2O

1.5

8

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 12 of 13

Combined uncertainty, laboratory and field, NO2, system 1

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1073

Measure

d c

om

ponent:

NO

21h-lim

it v

alu

e:

104.6

nm

ol/m

ol

No

.P

erf

orm

an

ce

ch

ara

cte

rist

icR

esu

ltS

qu

are

of

pa

rtia

l u

nce

rta

inty

1R

epeata

bili

ty s

tandard

devi

ation a

t zero

≤1.0

nm

ol/m

ol

0.3

50

ur,

z0.0

70.0

048

2R

epeata

bili

ty s

tandard

devi

ation a

t 1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol

0.8

80

ur,

lh

not

consid

ere

d,

as

√2*u

r,lh

= 0

,24 <

ur,

f-

3"l

ack o

f fit

" at

1h-lim

it v

alu

e≤

4.0

% o

f m

easure

d v

alu

e2.3

60

ul,lh

1.4

32.0

313

4S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas p

ressure

at

1h-lim

it v

alu

e≤

8.0

nm

ol/m

ol/kP

a0.1

90

ugp

1.9

13.6

572

5S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

00

ugt

0.9

10.8

206

6S

ensitiv

ity c

oeffi

cie

nt

of surr

oundin

g t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

97

ust

1.7

83.1

846

7S

ensitiv

ity c

oeffi

cie

nt

of ele

ctr

ical vo

ltage a

t 1h-lim

it v

alu

e≤

0.3

0 n

mol/m

ol/V

0.0

00

uV

0.0

00.0

000

≤10 n

mol/m

ol (Z

ero

)0.0

70

≤10 n

mol/m

ol (S

pan)

2.2

70

≤5.0

nm

ol/m

ol (Z

ero

)-0

.070

uin

t,pos

≤5.0

nm

ol/m

ol (S

pan)

-0.5

70

≤5.0

nm

ol/m

ol (Z

ero

)0.9

70

≤5.0

nm

ol/m

ol (S

pan)

0.8

30

uin

t,neg

9A

vera

gin

g e

ffect

≤7.0

% o

f m

easure

d v

alu

e3.4

00

uav

2.0

54.2

160

10

Repro

ducib

ility

sta

ndard

devi

ation u

nder

field

conditio

ns

≤5.0

% o

f ave

rage o

ver

3 m

onth

s3.4

10

ur,

f3.5

712.7

225

11

Long t

erm

drift a

t zero

leve

l≤

5.0

nm

ol/m

ol

-0.6

10

ud,l,z

-0.3

50.1

240

12

Long t

erm

drift a

t span leve

l≤

5.0

% o

f m

ax.

of cert

ification r

ange

0.6

10

ud,l,lh

0.3

70.1

357

18

Diff

ere

nce s

am

ple

/calib

ration p

ort

≤1.0

%0.0

00

uD

sc

0.0

00.0

000

21

Conve

rter

effi

cie

ncy

≥98

99.8

00

uE

C0.2

10.0

438

23

Uncert

ain

ty o

f te

st

gas

≤3.0

%2.0

00

ucg

1.0

51.0

941

Com

bin

ed s

tandard

uncert

ain

tyu

c5.5

783

nm

ol/m

ol

Expanded u

ncert

ain

tyU

11.1

566

nm

ol/m

ol

Rela

tive

expanded u

ncert

ain

tyW

10.6

7%

Maxim

um

allo

wed e

xpanded u

ncert

ain

tyW

req

15

%

8b

Inte

rfere

nt

CO

2 w

ith 5

00 µ

mol/m

ol

0.4

80.2

299

or

8c

Inte

rfere

nt

NH

3 m

it 2

00 n

mol/m

ol

Pe

rfo

rma

nce

cri

teri

on

Pa

rtia

l u

nce

rta

inty

8a

Inte

rfere

nt

H20 w

ith 1

9 m

mol/m

ol

uH

2O

1.6

92.8

479

Certificate: 0000062070 / 05 November 2019

qal1.de [email protected] Page 13 of 13

Combined uncertainty, laboratory and field, NO2, system 2

Measuring d

evi

ce:

M405nm

Serial-N

o.:

1076

Measure

d c

om

ponent:

NO

21h-lim

it v

alu

e:

104.6

nm

ol/m

ol

No

.P

erf

orm

an

ce

ch

ara

cte

rist

icR

esu

ltS

qu

are

of

pa

rtia

l u

nce

rta

inty

1R

epeata

bili

ty s

tandard

devi

ation a

t zero

≤1.0

nm

ol/m

ol

0.5

70

ur,

z0.1

20.0

134

2R

epeata

bili

ty s

tandard

devi

ation a

t 1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol

0.7

80

ur,

lh

not

consid

ere

d,

as

√2*u

r,lh

= 0

,22 <

ur,

f-

3"l

ack o

f fit

" at

1h-lim

it v

alu

e≤

4.0

% o

f m

easure

d v

alu

e3.2

90

ul,lh

1.9

93.9

476

4S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas p

ressure

at

1h-lim

it v

alu

e≤

8.0

nm

ol/m

ol/kP

a0.1

70

ugp

1.7

12.9

278

5S

ensitiv

ity c

oeffi

cie

nt

of sam

ple

gas t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.1

00

ugt

0.9

10.8

206

6S

ensitiv

ity c

oeffi

cie

nt

of surr

oundin

g t

em

pera

ture

at

1h-lim

it v

alu

e≤

3.0

nm

ol/m

ol/K

0.2

06

ust

1.8

73.4

822

7S

ensitiv

ity c

oeffi

cie

nt

of ele

ctr

ical vo

ltage a

t 1h-lim

it v

alu

e≤

0.3

0 n

mol/m

ol/V

0.0

20

uV

0.2

80.0

772

≤10 n

mol/m

ol (Z

ero

)0.2

30

≤10 n

mol/m

ol (S

pan)

2.1

30

≤5.0

nm

ol/m

ol (Z

ero

)0.0

70

uin

t,p

os

≤5.0

nm

ol/m

ol (S

pan)

0.3

70

≤5.0

nm

ol/m

ol (Z

ero

)0.9

30

≤5.0

nm

ol/m

ol (S

pan)

0.8

00

uin

t,n

eg

9A

vera

gin

g e

ffect

≤7.0

% o

f m

easure

d v

alu

e1.6

00

uav

0.9

70.9

336

10

Repro

ducib

ility

sta

ndard

devi

ation u

nder

field

conditio

ns

≤5.0

% o

f ave

rage o

ver

3 m

onth

s3.4

10

ur,

f3.5

712.7

225

11

Long t

erm

drift a

t zero

leve

l≤

5.0

nm

ol/m

ol

0.5

30

ud

,l,z

0.3

10.0

936

12

Long t

erm

drift a

t span leve

l≤

5.0

% o

f m

ax.

of cert

ification r

ange

1.3

30

ud

,l,lh

0.8

00.6

451

18

Diff

ere

nce s

am

ple

/calib

ration p

ort

≤1.0

%0.0

00

uD

sc

0.0

00.0

000

21

Conve

rter

effi

cie

ncy

≥98

99.6

00

uE

C0.4

20.1

751

23

Uncert

ain

ty o

f te

st

gas

≤3.0

%2.0

00

ucg

1.0

51.0

941

Com

bin

ed s

tandard

uncert

ain

tyu

c5.4

691

nm

ol/m

ol

Expanded u

ncert

ain

tyU

10.9

382

nm

ol/m

ol

Rela

tive

expanded u

ncert

ain

tyW

10.4

6%

Maxim

um

allo

wed e

xpanded u

ncert

ain

tyW

req

15

%

2.5

089

8b

Inte

rfere

nt

CO

2 w

ith 5

00 µ

mol/m

ol

0.6

80.4

558

or

8c

Inte

rfere

nt

NH

3 m

it 2

00 n

mol/m

ol

Pe

rfo

rma

nce

cri

teri

on

Pa

rtia

l u

nce

rta

inty

8a

Inte

rfere

nt

H20 w

ith 1

9 m

mol/m

ol

uH

2O

1.5

8