zertifikat eu approved - 2b technologies · this certificate is based upon the equipment tested....
TRANSCRIPT
ATÜVRheinland®Precisely Right.
CERTIFICATEof Product Conformity (QAL1 )
Certificate No.: 0000062070
AMsdesignation: Model405nmforNO, N02and NOx
Manufacturer: 2B Technologies2100 Central AvenueBoulder, Colorado 80301USA
Test Laboratory: TÜV Rheinland Energy GmbH
This is to certify that the AIVIS has been tested and found to comply withthe standards:
VDI 4202-1 (2018), EN 14211 (2012),Guide to the demonstration of equivalence of ambient air monitoring methods
(2010), EN 15267-1 (2009) and EN 15267-2 (2009)
Certification is awarded in respect of the conditions stated in this certificate(this ceriificate contains 13 pages).
Publication in the German Federal Gazette(BAnz) of 22 July 2019
Federal Environment AgencyDessau, 05 November 2019
ftJÜJ-,/Dr. Marcel LangnerHead of Section 114.1
Suitability TestedComplying with2008/50/ECEN 15267Regular Surveillance
www.tuv.coml D 0000062070
Expiry date:21 July 2024
TÜV Rheinland Energy GmbHCologne, 04 November 2019
o,, p,ft J+ppa. Dr. Peterwilbring
qal l .de [email protected] Page 1 of 13
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 2 of 13
Test Report: 936/21242468/A dated 19 February 2019
Initial certification: 22 July 2019
Expiry date: 21 July 2024
Publication: BAnz AT 22.07.2019 B8, chapter III number 1.1
Approved application The certified AMS is suitable for continuous ambient air monitoring of nitrogen oxides (sta-tionary operation). The suitability of the AMS for this application was assessed on the basis of a laboratory test and a seven-months field test. The AMS is approved for an ambient temperature range of 0 °C to +30 °C. The notification of suitability of the AMS, performance testing and the uncertainty calculation have been effected on the basis of the regulations applicable at the time of testing. As changes in legal provisions are possible, any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for monitoring the AMS readings relevant to the application. Any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for the intended purpose. Basis of the certification This certification is based on:
Test report no. 936/21242468/A dated 19 February 2019 issued by TÜV Rheinland Energy GmbH
Suitability announced by the German Federal Environment Agency (UBA) as the relevant body
The ongoing surveillance of the product and the manufacturing process
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 3 of 13
Publication in the German Federal Gazette: BAnz AT 22.07.2019 B8, chapter III number 1.1, UBA announcement dated 28 June 2019:
AMS designation:
Model 405 nm for NO, NO2 and NOx
Manufacturer:
2B Technologies, Boulder, USA
Field of application:
For the continuous measurement of nitrogen oxide concentrations from stationary sources in ambient air
Measurement ranges during performance testing:
Component Certification range Unit
Nitrogen monoxide 0–1 200 µg/m³
Nitrogen dioxide 0–500 µg/m³
Software version:
Version 36B
Restriction:
None
Notes:
1. The test report on performance testing is available on the internet at www.qal1.de.
2. As the measuring system does not provide password protection, it has to be mounted in a lockable cabinet.
3. Equivalence to the reference method in accordance with the requirements of the Guide to the Demonstration of Equivalence of Ambient Air Monitoring Methods was demonstrated.
Test Report:
TÜV Rheinland Energy GmbH, Cologne Report no. 936/21242468/A dated 19 February 2019
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 4 of 13
Certified product This certification applies to automated measurement systems conforming to the following de-scription: The Model 405 nm ambient air monitor is a continuous nitrogen oxide analyser. The instru-ment uses direct UV absorption as a measuring principle. It was designed for the continuous measurement of NO, NO2 and NOx in ambient air.
The model 405 NO2/NO/NOx monitor is designed to measure atmospheric nitrogen dioxide (NO2), nitrogen oxide (NO) and NOx (NO + NO2) in a dynamic range from just a few ppb up to 10 ppm for NO2 and 2 ppm for NO based on the detection of visible light at a wave length of 405 nanometres (nm).
The model 405 inside the analyser uses the absolute method to measure NO2 on the basis of Beer-Lambert law. NO2 measurement relies on a conventional absorption method. NO2 is analysed at a UV light wave length of 405 nm. The necessary measurement path length of 2 m is realised by using a measurement cell with a tube design which facilitates low volumes and fast gas replacement.
Nitrogen oxide is measured by measuring UV light intensities with and without adding ozone for oxidising NO to NO2. As described in more detail below, the result is a “semi-direct” measurement of NO in that the NO concentration is output directly and not based on subtrac-tion of NO2 concentration from a total NOx concentration. Instead, the NOx concentration is computed as the sum of the measurements of NO2 and NO.
The pump sucks in sample air through the instrument at a constant flow rate of 1.5 l/min. The NO2 scrubber valve alternately bypasses and sends the sample air through a heated NO2 scrubber to remove all NO2 in the sample. The NO2-scrubbed or unscrubbed air passes through the reactor volume and the DewLineTM Nafion Tubes, through the optical cell and through the cell flow meter. Alternate switching of the NO2 scrubber valve once every 5 sec-onds allows the measurement of a light intensity in the absence (Io) of NO2 and presence (I) of NO2. The Beer-Lambert Law is then used to calculate the concentration of NO2 from I and Io.
Nitrogen oxide is measured by bypassing the NO2 scrubber and measuring the light intensity while adding (I) or not adding (Io) ozone to convert NO to NO2 according to the well-known reaction:
NOx is computed from the measurement of NO and NO2.
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 5 of 13
General remarks This certificate is based upon the equipment tested. The manufacturer is responsible for en-suring that on-going production complies with the requirements of the EN 15267. The manu-facturer is required to maintain an approved quality management system controlling the manufacturing process for the certified product. Both the product and the quality manage-ment system shall be subject to regular surveillance. If a product of the current production does not conform to the certified product, TÜV Rhein-land Energy GmbH must be notified at the address given on page 1. A certification mark with an ID-Number that is specific to the certified product is presented on page 1 of this certificate. This document as well as the certification mark remains property of TÜV Rheinland Energy GmbH. Upon revocation of the publication the certificate loses its validity. After the expiration of the certificate and on request of TÜV Rheinland Energy GmbH this document shall be re-turned and the certificate mark must no longer be used. The relevant version of this certificate and its expiration date are also accessible on the in-ternet at qal1.de.
Document history
Certification of the Model 405 nm measuring system is based on the documents listed below and the regular, continuous surveillance of the manufacturer’s quality management system.
Initial certification according to EN 15267
Certificate no. 0000062070: 05 November 2019 Expiry date of the certificate: 21 July 2024 Test report 936/21242468/A dated 19 February 2019 TÜV Rheinland Energy GmbH, Cologne Publication: BAnz AT 22.07.2019 B8, chapter III number 1.1 UBA announcement dated 28 June 2019
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 6 of 13
Expanded uncertainty, laboratory, NO, system 1
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1073
Measure
d c
om
ponent:
NO
1h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.6
70
ur,
z0.1
20.0
140
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
1.0
70
ur,
lh0.0
40.0
015
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e0.6
60
ul,lh
0.4
00.1
589
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.3
40
ugp
0.8
60.7
319
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.0
80
ugt
0.2
00.0
405
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
50
ust
0.6
30.3
957
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
10
uV
0.0
40.0
015
≤10 n
mol/m
ol (Z
ero
)1.8
70
≤10 n
mol/m
ol (S
pan)
2.3
70
≤5.0
nm
ol/m
ol (Z
ero
)1.2
70
uin
t,p
os
≤5.0
nm
ol/m
ol (S
pan)
-0.0
70
≤5.0
nm
ol/m
ol (Z
ero
)1.3
70
≤5.0
nm
ol/m
ol (S
pan)
2.1
30
uin
t,n
eg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e0.5
00
uav
0.3
00.0
912
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.8
0u
EC
0.2
10.0
438
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c2.6
218
nm
ol/m
ol
Expanded u
ncert
ain
tyU
5.2
436
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
5.0
1%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
1.4
52.1
166
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.4
72.1
687
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 7 of 13
Expanded uncertainty, laboratory, NO, system 2
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1076
Measure
d c
om
ponent:
NO
1h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.5
00
ur,
z0.0
90.0
076
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
1.0
30
ur,
lh0.0
40.0
014
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e1.1
50
ul,lh
0.6
90.4
823
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.4
30
ugp
1.0
81.1
707
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.0
50
ugt
0.1
30.0
158
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
53
ust
0.6
40.4
053
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
00
uV
0.0
00.0
000
≤10 n
mol/m
ol (Z
ero
)0.3
30
≤10 n
mol/m
ol (S
pan)
2.8
00
≤5.0
nm
ol/m
ol (Z
ero
)1.0
30
uin
t,p
os
≤5.0
nm
ol/m
ol (S
pan)
-0.3
30
≤5.0
nm
ol/m
ol (Z
ero
)1.6
70
≤5.0
nm
ol/m
ol (S
pan)
0.9
70
uin
t,n
eg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e3.8
00
uav
2.2
95.2
663
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.6
0u
EC
0.4
20.1
751
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c3.2
779
nm
ol/m
ol
Expanded u
ncert
ain
tyU
6.5
558
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
6.2
7%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
0.3
944
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
1.3
11.7
227
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
0.6
3
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 8 of 13
Combined uncertainty, laboratory and field, NO, system 1
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1073
Measure
d c
om
ponent:
NO
1h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.6
70
ur,
z0.1
20.0
140
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
1.0
70
ur,
lh
not
consid
ere
d,
as
√2*u
r,lh
= 0
,05 <
ur,
f-
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e0.6
60
ul,lh
0.4
00.1
589
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.3
40
ugp
0.8
60.7
319
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.0
80
ugt
0.2
00.0
405
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
50
ust
0.6
30.3
957
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
10
uV
0.0
40.0
015
≤10 n
mol/m
ol (Z
ero
)1.8
70
≤10 n
mol/m
ol (S
pan)
2.3
70
≤5.0
nm
ol/m
ol (Z
ero
)1.2
70
uin
t,pos
≤5.0
nm
ol/m
ol (S
pan)
-0.0
70
≤5.0
nm
ol/m
ol (Z
ero
)1.3
70
≤5.0
nm
ol/m
ol (S
pan)
2.1
30
uin
t,neg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e0.5
00
uav
0.3
00.0
912
10
Repro
ducib
ility
sta
ndard
devi
ation u
nder
field
conditio
ns
≤5.0
% o
f ave
rage o
ver
3 m
onth
s3.4
10
ur,
f3.5
712.7
225
11
Long t
erm
drift a
t zero
leve
l≤
5.0
nm
ol/m
ol
0.3
90
ud,l,z
0.2
30.0
507
12
Long t
erm
drift a
t span leve
l≤
5.0
% o
f m
ax.
of cert
ification r
ange
1.2
90
ud,l,lh
0.7
80.6
069
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.8
00
uE
C0.2
10.0
438
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c4.5
001
nm
ol/m
ol
Expanded u
ncert
ain
tyU
9.0
002
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
8.6
0%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
1.4
52.1
166
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.4
72.1
687
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 9 of 13
Combined uncertainty, laboratory and field, NO, system 2
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1076
Measure
d c
om
ponent:
NO
1h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.5
00
ur,
z0.0
90.0
076
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
1.0
30
ur,
lh
not
consid
ere
d,
as
√2*u
r,lh
= 0
,05 <
ur,
f-
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e1.1
50
ul,lh
0.6
90.4
823
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.4
30
ugp
1.0
81.1
707
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.0
50
ugt
0.1
30.0
158
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
53
ust
0.6
40.4
053
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
00
uV
0.0
00.0
000
≤10 n
mol/m
ol (Z
ero
)0.3
30
≤10 n
mol/m
ol (S
pan)
2.8
00
≤5.0
nm
ol/m
ol (Z
ero
)1.0
30
uin
t,pos
≤5.0
nm
ol/m
ol (S
pan)
-0.3
30
≤5.0
nm
ol/m
ol (Z
ero
)1.6
70
≤5.0
nm
ol/m
ol (S
pan)
0.9
70
uin
t,neg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e3.8
00
uav
2.2
95.2
663
10
Repro
ducib
ility
sta
ndard
devi
ation u
nder
field
conditio
ns
≤5.0
% o
f ave
rage o
ver
3 m
onth
s3.4
10
ur,
f3.5
712.7
225
11
Long t
erm
drift a
t zero
leve
l≤
5.0
nm
ol/m
ol
0.9
40
ud,l,z
0.5
40.2
945
12
Long t
erm
drift a
t span leve
l≤
5.0
% o
f m
ax.
of cert
ification r
ange
0.8
90
ud,l,lh
0.5
40.2
889
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.6
00
uE
C0.4
20.1
751
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c4.9
039
nm
ol/m
ol
Expanded u
ncert
ain
tyU
9.8
077
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
9.3
8%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
0.3
944
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
1.3
11.7
227
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
0.6
3
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 10 of 13
Expanded uncertainty, laboratory, NO2, system 1
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1073
Measure
d c
om
ponent:
NO
21h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.3
50
ur,
z0.0
70.0
048
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
0.8
80
ur,
lh0.1
70.0
303
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e2.3
60
ul,lh
1.4
32.0
313
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.1
90
ugp
1.9
13.6
572
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
00
ugt
0.9
10.8
206
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
97
ust
1.7
83.1
846
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
00
uV
0.0
00.0
000
≤10 n
mol/m
ol (Z
ero
)0.0
70
≤10 n
mol/m
ol (S
pan)
2.2
70
≤5.0
nm
ol/m
ol (Z
ero
)-0
.070
uin
t,p
os
≤5.0
nm
ol/m
ol (S
pan)
-0.5
70
≤5.0
nm
ol/m
ol (Z
ero
)0.9
70
≤5.0
nm
ol/m
ol (S
pan)
0.8
30
uin
t,n
eg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e3.4
00
uav
2.0
54.2
160
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.8
0u
EC
0.2
10.0
438
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c4.2
656
nm
ol/m
ol
Expanded u
ncert
ain
tyU
8.5
313
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
8.1
6%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
0.4
80.2
299
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.6
92.8
479
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 11 of 13
Expanded uncertainty, laboratory, NO2, system 2
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1076
Measure
d c
om
ponent:
NO
21h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.5
70
ur,
z0.1
20.0
134
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
0.7
80
ur,
lh0.1
60.0
248
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e3.2
90
ul,lh
1.9
93.9
476
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.1
70
ugp
1.7
12.9
278
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
00
ugt
0.9
10.8
206
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
06
ust
1.8
73.4
822
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
20
uV
0.2
80.0
772
≤10 n
mol/m
ol (Z
ero
)0.2
30
≤10 n
mol/m
ol (S
pan)
2.1
30
≤5.0
nm
ol/m
ol (Z
ero
)0.0
70
uin
t,pos
≤5.0
nm
ol/m
ol (S
pan)
0.3
70
≤5.0
nm
ol/m
ol (Z
ero
)0.9
30
≤5.0
nm
ol/m
ol (S
pan)
0.8
00
uin
t,neg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e1.6
00
uav
0.9
70.9
336
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.6
0u
EC
0.4
20.1
751
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c4.0
619
nm
ol/m
ol
Expanded u
ncert
ain
tyU
8.1
239
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
7.7
7%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
2.5
089
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
0.6
80.4
558
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.5
8
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 12 of 13
Combined uncertainty, laboratory and field, NO2, system 1
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1073
Measure
d c
om
ponent:
NO
21h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.3
50
ur,
z0.0
70.0
048
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
0.8
80
ur,
lh
not
consid
ere
d,
as
√2*u
r,lh
= 0
,24 <
ur,
f-
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e2.3
60
ul,lh
1.4
32.0
313
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.1
90
ugp
1.9
13.6
572
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
00
ugt
0.9
10.8
206
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
97
ust
1.7
83.1
846
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
00
uV
0.0
00.0
000
≤10 n
mol/m
ol (Z
ero
)0.0
70
≤10 n
mol/m
ol (S
pan)
2.2
70
≤5.0
nm
ol/m
ol (Z
ero
)-0
.070
uin
t,pos
≤5.0
nm
ol/m
ol (S
pan)
-0.5
70
≤5.0
nm
ol/m
ol (Z
ero
)0.9
70
≤5.0
nm
ol/m
ol (S
pan)
0.8
30
uin
t,neg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e3.4
00
uav
2.0
54.2
160
10
Repro
ducib
ility
sta
ndard
devi
ation u
nder
field
conditio
ns
≤5.0
% o
f ave
rage o
ver
3 m
onth
s3.4
10
ur,
f3.5
712.7
225
11
Long t
erm
drift a
t zero
leve
l≤
5.0
nm
ol/m
ol
-0.6
10
ud,l,z
-0.3
50.1
240
12
Long t
erm
drift a
t span leve
l≤
5.0
% o
f m
ax.
of cert
ification r
ange
0.6
10
ud,l,lh
0.3
70.1
357
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.8
00
uE
C0.2
10.0
438
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c5.5
783
nm
ol/m
ol
Expanded u
ncert
ain
tyU
11.1
566
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
10.6
7%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
0.4
80.2
299
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.6
92.8
479
Certificate: 0000062070 / 05 November 2019
qal1.de [email protected] Page 13 of 13
Combined uncertainty, laboratory and field, NO2, system 2
Measuring d
evi
ce:
M405nm
Serial-N
o.:
1076
Measure
d c
om
ponent:
NO
21h-lim
it v
alu
e:
104.6
nm
ol/m
ol
No
.P
erf
orm
an
ce
ch
ara
cte
rist
icR
esu
ltS
qu
are
of
pa
rtia
l u
nce
rta
inty
1R
epeata
bili
ty s
tandard
devi
ation a
t zero
≤1.0
nm
ol/m
ol
0.5
70
ur,
z0.1
20.0
134
2R
epeata
bili
ty s
tandard
devi
ation a
t 1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol
0.7
80
ur,
lh
not
consid
ere
d,
as
√2*u
r,lh
= 0
,22 <
ur,
f-
3"l
ack o
f fit
" at
1h-lim
it v
alu
e≤
4.0
% o
f m
easure
d v
alu
e3.2
90
ul,lh
1.9
93.9
476
4S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas p
ressure
at
1h-lim
it v
alu
e≤
8.0
nm
ol/m
ol/kP
a0.1
70
ugp
1.7
12.9
278
5S
ensitiv
ity c
oeffi
cie
nt
of sam
ple
gas t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.1
00
ugt
0.9
10.8
206
6S
ensitiv
ity c
oeffi
cie
nt
of surr
oundin
g t
em
pera
ture
at
1h-lim
it v
alu
e≤
3.0
nm
ol/m
ol/K
0.2
06
ust
1.8
73.4
822
7S
ensitiv
ity c
oeffi
cie
nt
of ele
ctr
ical vo
ltage a
t 1h-lim
it v
alu
e≤
0.3
0 n
mol/m
ol/V
0.0
20
uV
0.2
80.0
772
≤10 n
mol/m
ol (Z
ero
)0.2
30
≤10 n
mol/m
ol (S
pan)
2.1
30
≤5.0
nm
ol/m
ol (Z
ero
)0.0
70
uin
t,p
os
≤5.0
nm
ol/m
ol (S
pan)
0.3
70
≤5.0
nm
ol/m
ol (Z
ero
)0.9
30
≤5.0
nm
ol/m
ol (S
pan)
0.8
00
uin
t,n
eg
9A
vera
gin
g e
ffect
≤7.0
% o
f m
easure
d v
alu
e1.6
00
uav
0.9
70.9
336
10
Repro
ducib
ility
sta
ndard
devi
ation u
nder
field
conditio
ns
≤5.0
% o
f ave
rage o
ver
3 m
onth
s3.4
10
ur,
f3.5
712.7
225
11
Long t
erm
drift a
t zero
leve
l≤
5.0
nm
ol/m
ol
0.5
30
ud
,l,z
0.3
10.0
936
12
Long t
erm
drift a
t span leve
l≤
5.0
% o
f m
ax.
of cert
ification r
ange
1.3
30
ud
,l,lh
0.8
00.6
451
18
Diff
ere
nce s
am
ple
/calib
ration p
ort
≤1.0
%0.0
00
uD
sc
0.0
00.0
000
21
Conve
rter
effi
cie
ncy
≥98
99.6
00
uE
C0.4
20.1
751
23
Uncert
ain
ty o
f te
st
gas
≤3.0
%2.0
00
ucg
1.0
51.0
941
Com
bin
ed s
tandard
uncert
ain
tyu
c5.4
691
nm
ol/m
ol
Expanded u
ncert
ain
tyU
10.9
382
nm
ol/m
ol
Rela
tive
expanded u
ncert
ain
tyW
10.4
6%
Maxim
um
allo
wed e
xpanded u
ncert
ain
tyW
req
15
%
2.5
089
8b
Inte
rfere
nt
CO
2 w
ith 5
00 µ
mol/m
ol
0.6
80.4
558
or
8c
Inte
rfere
nt
NH
3 m
it 2
00 n
mol/m
ol
Pe
rfo
rma
nce
cri
teri
on
Pa
rtia
l u
nce
rta
inty
8a
Inte
rfere
nt
H20 w
ith 1
9 m
mol/m
ol
uH
2O
1.5
8