y:eia-projectson-going projectslion tapeslion tapes...
TRANSCRIPT
Page 1 of 108
315th meeting of SEAC-Gujarat, Dated 01.12.2016
Page 1 of 108
Minutes of the 315th meeting of the State Level Expert Appraisal Committee held on
01/12/2016 at Committee Room, Gujarat Pollution Control Board, Gandhinagar.
The 315th meeting of the State Level Expert Appraisal Committee (SEAC) was held on 1st
December, 2016 at Committee Room, Gujarat Pollution Control Board, Gandhinagar. Following
members attended the meeting:
1. Shri T. P. Singh, Chairman, SEAC.
2. Shri V. C. Soni, Vice Chairman, SEAC.
3. Shri R. J. Shah, Member, SEAC.
4. Dr. V. K. Jain, Member, SEAC.
5. Shri Rajesh Shah, Member, SEAC.
The agenda of TOR/Scoping/Category 8 (a) cases and Appraisal cases was taken up. Twelve (12)
cases of TOR/Scoping/Category 8 (a) and thirteen (13) cases of Appraisal was taken up. The
applicants made presentations on the activities to be carried out along with other details furnished in
the Form-1 / Form-1A, EIA report and other reports.
1. High Rise Building Project 2 FP 123
R.S. No.: 54/2+54/3, O.P.No: 27/B1, F.P.No: 123, T.P.S.No: 7, (Anjana), Ta: Choryasi, Dist. Surat
Appraisal case
The project was earlier taken up in meeting of SEAC dated 09/8/16. During the meeting held on
09/08/2016, after detailed discussion on various aspects of the project it was decided to appraise the
project further only after submission of the following:
1. Copy of permission obtained from concerned competent authority for the proposed FSI.
2. Base line status of the existing traffic, impact on it due to the project activities (prior to construction,
during construction and at full site operation), carrying capacity of the existing roads and details of
traffic management in and outside the project during construction and operation phase of the project.
3. Copy of permission obtained from Airports Authority of India for the proposed building height.
4. Location of the proposed STP on the layout plan.
5. Minimum fire water requirement for the proposed project based on the fire study.
6. Type of activities to be carried out in the proposed commercial units. Notarized undertaking stating
that no any kind of manufacturing activity shall be allowed in the commercial units of the proposed
project and they will not sold / allot any commercial unit for storage of chemicals, flammable
substances, explosives, fire crackers or any other material of hazardous characteristics.
7. Perspective view of the building(s) to be constructed along with the materials used such as fibers,
glass, etc. on the facades or external walls and the impacts thereof on the nearby buildings /
residents due to heat island effect and emissions from the air conditioning systems.
8. E waste management plan.
9. Details of mechanical parking to be provided (also including its operation, maintenance, energy
consumption, appointing trained personnel’s etc.) in the basement along with the feasibility of
providing mechanical parking considering the basement height.
10. Details on ventilation, lighting arrangements and CO sensors to be provided in the basements.
Details on provision to be made for natural lighting & ventilation in the proposed commercial units.
11. Detailed plan for loading / unloading of goods, movement plan, space designated for it, parking area
designated for trucks/tempo etc.
Page 62 of 108
315th meeting of SEAC-Gujarat, Dated 01.12.2016
Page 62 of 108
The above mentioned project specific TORs/additional TORs and the model TORs available in the
MoEF’s sector specific EIA Manual for Synthetic Organic Chemical industry shall be considered as
generic TORs for preparation of the EIA report in addition to all the relevant information as per the
generic structure of EIA given in Appendix III in the EIA Notification, 2006. The project shall be
appraised on receipt of the final EIA report.
Validity of ToR:
• The ToRs prescribed for the project will be valid for a period of three years for submission of
EIA & EMP report accordingly, ToR will lapse after 30/11/2019.
• The period of validity could be extended for a maximum period of one year provided an
application is made by the applicant to the Regulatory Authority, at least three months before
the expiry of valid period together with an updated Form-I, based on proper justification and
also recommendation of the SEAC.
12 M/s: Lion Tapes Pvt. Ltd. Plot No:293 GIDC-Chitra Estate Dist: Bhavnagar
Appraisal
Project / Activity No.: 5(f)
Project status: New
Chronology of EC Process:
• This project proposed by M/s: Lion Tapes Pvt. Ltd. (herein after Project Proponent – PP) has
submitted Application vide their letter dated 16/01/2013.
• The project proponent was called for presentation and discussion in the meeting of SEAC held
on 12/03/2013.
• During the meeting, the committee informed the project proponent that as per the report on
"Comprehensive Environmental Assessment of Industrial Clusters", CEPI scores of Chitra -
Bhavnagar was above 70 and hence considered as critically polluted. The proponent was also
informed that the MoEF has imposed temporary restrictions on consideration of developmental
projects in such clusters / areas vide their Office Memorandum dated 13/01/2010 and hence
the proposed project can’t be considered as it is situated in Chitra - Bhavnagar having CEPI
score above 70. At this, the project proponent presented that as per the latest assessment
done recently, CEPI score of Chitra – Bhavnagar is less than 70 and hence their application
should be considered. However, the committee decided not to reconsider the project as new
report on CEPI score is not yet published. It was decided to consider this project only after
verifying that CEPI score of Chitra – Bhavnagar is less than 70.
• The project proponent was again called for presentation and discussion in the meeting of
SEAC held on 24/06/2014.
• During the meeting, the project proponent requested for categorizing the project as B2 and to
exempt them from carrying out detailed EIA study which was not considered by the committee
and the project proponent was asked to include the additional TORs for the EIA study to be
done covering 5 km radial distance from the boundary of the project.
• EIA Report prepared by M/s: Precitech Laboratories Pvt. Ltd., Vapi was submitted by project
Page 63 of 108
315th meeting of SEAC-Gujarat, Dated 01.12.2016
Page 63 of 108
proponent vide dated 09/11/2015.
• PP was called for presentation in the SEAC meeting dated 22/12/2015.
• During the meeting dated 22/12/2015, Committee noted that the site of the proposed project is
located within the Chitra GIDC, where all the industrial units are of Inorganic chemical nature.
On asking about the waste water treatment and disposal, PP informed that they will treat the
entire effluent within premises and send it to disposal pipeline of GIDC Chitra which ultimately
leads to Arabian Sea. Committee was of the view that Organic Chemical industries having high
organic load containing effluent shall not be allowed to discharge in this industrial estate. After
detailed deliberation, Committee asked to change the proposal and go for complete zero liquid
discharge (ZLD). Considering the above facts, it was unanimously decided to consider the
project for appraisal only after submission of revised proposal with complete zero liquid
discharge (ZLD) system.
• PP submitted corrigendum to the EIA report considering Revised proposal with complete zero
liquid discharge (ZLD) system vide their letter no. Nil dated on 27/10/2015.
Project / Activity Details:
This is a proposed unit applied for manufacturing of following Dye & Dye Intermediates.
Sr.No. Name of Products Quantity MT/Month
1. Fast Red B Base 40
2. Fast Bordeaux GP Base 20
3. Fast MNPT (Red G) Base 10
4. Fast Red 3GL Base 5
5. Fast Scarlet R Base 10
6. Fast Yellow GC Base 5
7. Fast Orange GC Base 5
8. Fast Red RC Base 5
Total 100
The proposed production activity falls in the project activity 5(f) as per the Schedule of EIA
Notification, 2006 as amended from time to time.
Capital cost of the project is Rs.3.54 Crores. Total plot area of the proposed project is 4,389.67 sq.
m including green belt area 710 sq. m. Fresh Water requirement of 42.5 KL/day will be met through
GIDC water supply system. Industrial effluent generation will be 29.5 KL/day which will be treated
in the proposed onsite ETP and will be discharged through common pipeline of GIDC. Wood
briquette will be used as fuel in Thermic Fluid heater (2 lac Kcal/hr.) and HSD will be used fuel in
the proposed D.G. Set (31.25 KVA). Bag filter will be provided as APCM to Thermic Fluid heater.
ETP waste, process waste, discarded containers/bags and recovered solvent are the hazardous
waste to be generated from the proposed production.
Observations/Discussions:
Technical presentation made during the meeting by project proponent. The baseline environmental
quality has been assessed for various components of the environment viz. air, noise, water,
biological and socioeconomic aspects. The baseline environmental study has been conducted for
Page 64 of 108
315th meeting of SEAC-Gujarat, Dated 01.12.2016
Page 64 of 108
the study area of 5 km radial distance from project site for the period October 2014 to December
2014. Ambient Air Quality monitoring was carried out for PM10, PM2.5, SO2, NOx, and VOC at Six
locations, including the project site. Values conform to the prescribed standards for Ambient Air
Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3
model. The resultant concentrations are within the NAAQS. While discussing about the treatability
for treatment of waste water to be generated, PP informed that they have proposed segregation of
industrial effluent at source and Zero Liquid Discharge status will be maintained. Upon asking
about the adequacy of the proposed treatment facilities, PP could not reply satisfactorily. In-
process distillation will be carried out to recover spent solvent. Committee asked to submit
adequacy certificate with qualitative analysis of the each waste stream. Sodium acetate solution
(217 MT/Month) and spent Acetic acid (234 MT/Month) will be generated as waste streams from
the manufacturing process. Sodium acetate will be used in Benzyl Acetate manufacturing & spent
Acetic acid will be used in Manganese acetate manufacturing. However actual consumers have not
been identified. After detailed discussion on the matter, It was decided to consider the project only
after submission of the following:
1. A detailed effluent treatability study vis-a-vis the adequacy and efficacy of the treatment
facilities proposed for the waste water to be generated. Give stage wise reduction of main
parameters. Certificate from Schedule I auditor for complete Zero Liquid Discharge.
2. Management of Sodium acetate solution and spent Acetic acid as per the Hazardous and
other Wastes (Management and Transboundary Movement) Rules, 2016.
13 SIA/GJ/IND2/11094/2016 M/s: Anagha Chem Pvt. Ltd. Plot no. D/2/CH-318, Phase-II, Dahej GIDC Estate, Ta.: Vagra, Dist.: Bharuch
Appraisal
Project / Activity No.: 5(f)
Project status: Existing
Chronology of EC Process:
Project / Activity No.: 5(f)
• M/s: Anagha Chem Pvt. Ltd (herein after Project Proponent – PP) has submitted online
proposal vide no. SIA/GJ/IND2/11094/2015 dated 16/04/2016 for EC amendment.
• PP was called for presentation in the SEAC meeting dated 29/06/2016.
• During the meeting dated 29/06/2016, while discussing about the justification for change in fuel
and capacity of the Boiler, PP informed that the Natural gas pipeline is not available in area. PP
could not justify properly about the change in capacity of the Boiler. Total fuel (Bio-Coal)
consumption for the 3 TPH Boiler will be 600 Kg/hr. PP has proposed MDC followed by Bag
filter as APCM. After detailed discussion on the matter, It was decided to consider the project
only after submission of the following: (1) Detailed justification for proposed change in fuel
along with the supporting documents. (2) Technical Justification for change in capacity of the
Boiler from 0.3 TPH to 3 TPH. (3) Give above mentioned justification with regard to earlier EIA
report. (4) Specific details on (i) Type, quantity and quality (CV, Sulphur content, Ash content,
etc,) of coal to be used (iii) Flue gas emission details (iv) Air pollution Control Measures along
with its adequacy to achieve the GPCB Norms. (v) List the sources of fugitive emission from
Page 108 of 108
315th meeting of SEAC-Gujarat, Dated 01.12.2016
Page 108 of 108
ADDITIONAL AGENDA
1. Letter of Shri Bharat S. Dave dtd 14/11/2016 regarding illegitimate allotment of
quarry permits and operation of lease without obtaining Environmental Clearance
regardiing.
The aforementioned letter was received by this office on 16/11/2016 and it was deliberated
in the meeting. After referring to the letter of Shri B.S.Dave dated 14/11/2016, committee
unanimously decided to inform Shri B.S.Dave with a copy to Commissioner, Geology and
mining stating that it is mandatory to obtain Environment Clearance for mining project. It was
also mentioned to inform that for river bed mining proposal, it is required by the concerned
geologist to submit project details along with details of lease whether it is located in dry river
bed and it is not an instream mining. Upon submission of details with validation of concerned
district geologist, river bed mining proposal is recommended to SEIAA for grant of
environment clearance.
Meeting ended with thanks to the Chair and the Members.
--------------------------------
Minutes approved by:
1. Shri T. P. Singh, Chairman, SEAC.
2. Shri V. C. Soni, Vice Chairman, SEAC.
3. Shri R. J. Shah, Member, SEAC.
4. Dr. V. K. Jain. Member, SEAC.
5. Shri Rajesh Shah, Member, SEAC.
HBHAI PATEL EDUCATION SOCIETY'S
a)b)c)
AT. ISROLI, PO. AFWA, TAL. BARDOLI, DIST. SURAT PIN.394620P h one : 92280008 67, 02622-290933, F ax: 02622-29 I 411
E-mai I : [email protected] . Website; wwvv.fetr.ac. i n
Ref. No.: FETR/CHED|ELCD0IT/}J lL Date : o7to3t2ot7
Adequacy Certificate from Environ AuditorThe Environmental Management System Adequacy Certificate
The environmental Audit Scheme was introduced by the Gujarat High court vide lts Orders
dated. 20112196 & l3l3/97 and modified vide order dated.16/9199. We are appointed by the
GPCB Gandhinagar as recognized Auditor for ScheduleJ industries for compliance of the
directions of the Hon. High Court in that matter & have carried out study of quantity/quality ofeffluents (wastewater + solid hazardous waste) of;
lWs. LION-TAPES PVT. LTDLocated at: PLOT NO 293, GIDC CHITRA ESTATE, BHAVNAGAR, GUJARATManufacturing products as under:
Product Details:-
LIST OF PROPOSED PRODUCTS AIID PRODUCTION CAPACITY
LIST OF RAW.MATERIALS AND ITS CONSUMPTION.
FAGULTY OF EilGI}IEEHilG TECHilOLOGY AilD RESEARCH
Sr. No Name of the Products Quantity (MT/IvIonth)
I Fast Red B Base 40.02 FastBordeaux GP Base 20.03 FaStMNPT (Red G) Base 10.04 Fast Red 3GL Base 5.05 Fast Scarlet R Base 10.06 FastYellow GC Base 5.07 Fast Orange GC Base 5.08 Fast Red RC Base 5.0
Total 100.0
S. No. Name of the product Raw material Requirement(Mra{)
1Fast Red B Base & Fast Scarlet RBase
,l^--sG.."x
Ortho Anisidine 38Acetic Anhydride 32Nitric Acid 36Methylene Di-chloride 6
Snhadrrlo-'l Fnvirnr
/iG'#,Ie
frH#.{ Nodar centre For sooken rurd#spd,pfPJ{)F !rGPCB Approved Mumbai.
S. No. Name of the product Raw material Requirement(MT/fvr)
Sulphuric Acid 2Sodium Hydroxide 27
2 Fast Bordeaux GP Base
Para Anisidine l7Acetic Anhydride t6Acetic Acid l6Nitric Acid 26Methylene Di-chloride 2Sodium Hydroxide 7
3 Fast MNPT (Red G) Base
Para Toluidine IAcetic Anhydride 9Acetic Acid 9Nitric Acid I4Methylene Di-chloride 2Sodium Hydroxide 4
4 Fast Red 3GL Base
Para Chloro Aniline 5Acetic Anhydride 4Acetic Acid 4Nihic Acid 6Methylene Di-chloride 1
Sodium Hydroxide 2
5 Fast Yellow GC BaseOrtho Chloro Aniline 5Hydrochloric Acid 5
Sodium Chloride 2
6 Fast Orange GC BaseMeta Chloro Aniline 5
Hydrochloric Acid 5Sodium Chloride )
7 Fast Red RC BaseEgq 3{4 Chloro-Ortho-Anisidine) 5
Hydrochloric Acid 5Sodium Chloride 2
Details of lvlanufacturing Process & Mass Balance : As per Annexure - I
Page2 of26
r'-*\
As per the direction of Hon'ble High Court in Environmental Audit Scheme and based on
literature survey, site visit of the industry, we certify that the Environmental Management
System proposed by this industry for the proposed products is adequate to achieve thequantity/quality of effluents (Wastewater + Solid and hazardous waste) as specified/required by
ConsentsArlotifications of GPCB, Gandhinagar for following quantity of effluents.
d) WATER CONSUMPTTON & EFFLUENT GENERATTON (KL/DAY)
o Water consumption:
Sr.
No.Particular
Water consumption
(KL/Day)
I Domestic 1.5
2 Gardening 4.0
aJ Industrial
Process 0.0*
Boiler 5.4
Washing 4.0
Cooling 6.1
Total Industrial 15.5
4 Total (1+2+3) 21.0
* The fresh water consumption in process unit will be zero because only recycled water(35.4 KL/Day) will be used.
o Effluent generation:
Sr.
No.Particular
Water consumption
(KL/Day)
I Domestic 1.3
2 Gardening 0.0
3 Industrial
Process 33.5
Boiler 1.8
Washing 4.0
Page 3 of26
Cooling 0.7
Total Industrial 40
4 Total (1+2+3) 41.3
Note:
finally mixed with industrial effluent.
MEE system. MEE condensate shall be recycled back to process. Salt from MEE shall be
dispose off into TSDF.
Details of effluent Treatment Plant
Water Balance Diagram
: As Per Annexure - II
: As Per Annexure - III
ADEQUACY OF EFFLUENT TREATMENT PLAIIT
(Nitration Stream)
Flow:16.1 KLlday (Effluent from Nitration Stage).
(Hvdrolvsis Stream)
Flow: 9.3 Kl/day (Effluent from Hydrolysis Stage).
Test Parameters Results of treatabilitv studvInitial After neutralization &,
Carbon TreatmentCondensate Water
Recovered afterEvaporation
pH 4.8 7.8 7.9
SS 650 ms/L 72ms,lL 32 ms,LTDS 20330 ms.lL 30362mslL l48ms.LCOD 13325 ms/L 9054me/L 67 ms/LBOD 3012ms,/L 1770ms/L 24 ms,/L
Test
Parameters'
Results of treatability study
Initial After neutralization &Carbon Treatment
Condensate WaterRecovered after
Evaporation
Page 4 of26
pH 8.s 7.6 7.5
SS 445 mglL 6lmgll aSmglL
TDS 28332mglL 29383 mgtL 168 mg/L
COD 9313 mglL 6476mglL 89mglL
BOD 2232mglL t662mg/L 33mglL
(Washine & othef Stream)
FIow: 14.6 Kl/day @flluent from Washing & others).
CONCLUSION:
Overall Remarks:
Looking to all above points, it is concluded that the proposed Effluent treatment system will be adequate
with respect to waste water treatment & zero liquid discharge system for proposed project.
Test
Parameters'
Results of treatability study (Stream from Washing & others)
Initial After neutralization &Carbon Treatment
Condensate Water
Recovered afterEvaporation
pH 7.1 7.4 7.2
SS 318 mg/L a6mglL 34mglLTDS 7643 mglL 7978mgll- 173 mglL
COD 1265 mglL 876mglL 65 mglLBOD 358m{L 266mgtL 26 mglL
Page 5 of26
e) Hazardous Waste:
Type of waste Source 4ry. Mode of disposaU reuse Category
Ilazardous Waste
Used oil Maintenance l0 Liter/IVlonth Collection, storage and reused aslubricant in plant machinerv
5.1
ETPSludge ETP 2.80MT/lvlonth
Storage, transportation anddisposal to the TSDF
35.3
Evaporation salts MEE 3.20MT/IVIonth
Storage, transportation anddisposal to the TSDF
3s.3
Salts (mainly inform of SodiumNitrate fromnitration andsodium acetatefrom Hvdrolvsis)
MEE 19.0MT/Month
Collection, Storage & sent toactual users or disposal to theTSDF
35.3
Discardedcontainers/ bags
Raw materialstorage
Approximately0.5 MT/\tfonth
Collection, Storage & sale toactual users or authorizedrecycler.
33.3
Spent Carbon ETP 4.0 MT/IVIonth Collection, Storage &disposal tocommon incineration facilifu
Spent Acid (AceticAcid)
Process 17.0MT/IVIonth
Collection, Storage & Reused asRM or sold out to actual users.
D2
Non-Hazardous Waste
Fly Ash Utility 1.5 MT/IVIonth Collection, Storage, & given tofarmer as rnanure
Page 6 of26
]E
FACULTY OF ENGINEERINGTECHNOLOGY AI\DRESEARCH,ISROLI-AFWA,BARI}OLI.
There will be no discharge of the indushial effluent from the manufacturing process and other ancillary
industrial operations.
This certificate is subject to automatic iancellation in case of any change in product profile/capacity,
quantlty & quantity of eflluents (Water + Solid) and effrciency of EMS equipment.
DATE: 0710312017 AUDIT TEAM MEMBERS
1. Dr. Jaydeep lV[.parad, Ph.D. (Chemical)
X;fi,'8:,, fun---2. Mr. Nevil J. Shakwala, M.Tech. (Env.)
*ib"-
Member,Audit Cell
3. Dr. Amish B.Member,Audit Cell
M.! .f,)af,a)*lqr
-tr{Patel, Ph.D. (Chemistry)
J#4. Miss. Krina B. Mistry, M.Sc. (Chemistry)
Member,Audit Cell
, {,.
ffi@
PageT of26
ANNEXURE - I
1) Fast Red B Base & F'ast Scarlet R Base
Ortho anisidine is acetylated with acetic anhydride in the acetylation reactor, after the completion ofthe reaction that mass is to be transferred for recovery of Acetic acid. Then reaction mass is takeninto nitration vessel where it is mixed with MDC, and concentrated Nitric acid is slowly added to it.
After completion of this process the mass is washed with water and further distilled in distillationunit for recovery of MDC. After the recovery of MDC the mass is transferred in to neutch filter andwater is separated from reaction mass. Washing water collected from neutch filter is to be senttowards ETP for treatment purpose.
After that the reaction mass is to be gradually added into the solution of caustic soda flakes andwater at maintained temperature for hydrolysis purpose. After completion of reaction the mass istransferred it to neutch filter and waste water as filtrate is to be sent towards ETP for treatment ,
purpose. Fast Red B Base & Fast Scarlet R Base is separated with dilute Sulphuric acid where FastScarlet R Base dissolved in it & Fast Red B Base collected as a residue after neutralization will getFast Scarlet R Base both are dried, pulverized & packed.
Page 8 of26
].ffiBfiTi fl*! ,: ..
... 1, l
.1..1-
..6 , r,t.
.i
Pasit9,ffi26
Material Balance:
Iilataifrl $r*incc ForRcd E $a:* & Fat$cari*t R $a:r.tAll Valucr in KG!
0rfixoAnisidinBAqett{ Anhyd*de
Areti{ A${X,90%
fi{nNitiis Acd {S&Ya}
t*iathylenp $chiorideFfsshWster
Freeh Water
WstsrT*ETF
M*dlylene Diehh:riule(g*%l Flscot WEBUgsd in 9{@xtEst{h
Evrlp.Loxs {tySC}}TdLi* EIP
*latrrT*ETF
&{}p. l"q6s
lAfatfrts ETF
WslsrTcWathi{rg
t565!+15q{i
132735_>
:rlss----.F
3ffi
2f25--+
2fios
E1
frerh Water
C*u*lic &da Flsl$es*$qrd* Y!,ster ir*m Yua$hi*g
20ss
$0*
E:I
r*
c1
Fregh Wai*r
t{?*r{s696}Fr8sh WsI6r
$r*ah W*tqr
C*usrlc Flfikes
fr66h.Wst8r lay€rlo#TP *&71-*******'*
Hios L{s$ 34
cl
frv*p. Loes 1*0
E4SrFGDBsA#10m
F&sTSEABLEThEASE
t68
Page 10 of26
2) Fast Bordeaux GP Base
Para Anisidine is acetylated with acetic anhydride in the acetylation reactor, after the completion ofthe reaction that mass is transferred for recovery of Acetic acid. Then reaction mass is to be taken
into nitration vessel where it is mixed with MDC and concentrated Nitric acid is slowly added to it.
After completion of this process the mass is washed with water and further distilled in distillationunit for recovery of MDC. After the recovery of MDC the mass is transferred in to neutch filter and
water is separated from reaction mass. Washing water collected from neutch filter is to be sent
towards ETP for treatment purpose.
After that the reaction mass is gradually added into the solution of caustic soda flakes and water at
maintained temperature for hydrolysis purpose. After completion of reaction the mass is transferred
it to neutch filter, waste water as filtrate is to be sent towards ETP for treatrnent purpose and solidpart of the mass is further washed, dried &pulverized to get final product Fast Bordeaux GP Base.
Chemical Reaction:
Bordeaux GP
NHC@H3CH3CO\ MDC ,\+ P--* ll .l +cH3cd \/
H3CO
Acetic Anhydride
102.08
cH3cooH
Fara Anisidine
{23.15
trHCocH3,4-V+
HsCO
165.19
Nitration-----+
+ Heo
t-lNo3
63 210.18 18
l!HCOCH3
-(Il -l + NaoH
\y'No, --------*Hydrolysis 'Noz + CH3C@Na
82.03
Sodium Acehte
ocH3
210.18 39.99
HsCO
't 68. 15
Bordaaux GP
##191-dt, rsroifiF / [ic,: itflvs.CI{'r,.l'xi".i"r1, lp
t-h*-%? Page 11 of26
r3I'!
lll
Material Balance:
tilalerial E.alarec For F.isI Bord@ux GP Bce.(All Vduos in l(G)
P.ila l\hisidins.i-{cetiG:AhhydrideRscorsr Acr1ic Acid (S96)
8{8
Ra9w6r Ac*ic Acid 99,67€3.recyclo4f2 sale.
Evo.Loss (AcetieAcid)
1?2.5
t0
qon.Iftdc.Add (60%)Metrylene Dichlorida
Fresh Waler
12723392
2oih MetMenp DibhloridsRbUsed:in Next:Batch
IJIL tO ETP
WatEr To ETP
Evop- Loes
3256
2737 lE1
1fi)0 ---- E2
'\100
3283 + Cr
2e/JO
'2&
Frt€sh Watbr
Sosium Fidio(ideReqtdoWabr frodr Washin g(Fresh 544 + Recyd.d 2000)
Fresh'Watar
To ETP
Water ToWadring
; Evop. Loss
Fast Bordraur,GP 9!!a{0m
Page12 of26
3) Fast MNPT (Red G) Base
Conversion of Para Toludine to Meta Nitro Para Toludine is carried out in three stages namely
Acetylation, Nitration and Hydrolysis. In Acetylation, Para Toludine is acetylated with Acetic
Anhydride and Acetic Acid to obtain Acetylated Para Toludine. After theAcetylation reaction the
mass is furttrer distilled for recovery of Acetic Acid. The Nitration of Acetylated Para Toluidine and
MDC as a solvent is done'with Concentrated Nitric Acid and Sodium Nitrite as a Catalyst.
MDC is then recovered from Nitro mass and after the recovery of MDC Nitro mass is further
hydrolysed with Caustic Flakes to get Meta Nitro Para Toluidine. Then MNPT is further purified,
centrifuged, dried, blended and pulverized.
Chemical Reaction:
MNPT
NH.A'[)HsG
+CH.CO-\
.o/cH3GO,
Acelic Anhydride
'to2,oB
MDC
-iF.
NHCoC
-'\-[ :-t-'\-VYHac
1 4S.1 A
H3
+ cH3eooH
60.05
Par€ Tol,uidine
'r o7.1 5
NHCOCH3
1All I -r
HaC
149.18
HN()3
63:01
Nitration
--_--.
tHcocH3
[ )^,^--7 rrv2cHs
134.1A
+ Hzo
1A
NHCOCH3
e>*.,CH:
1 94.1 8
+ _____-____>
Hydrolysis
NH.t'
e>'".,HeC
MNPT
152.15
+ CH3COONa
Sodium A.cetate
a2.0339.99
6ffiY/ t"t: lsroli'\'fr /- A^t: lsroli'\ rP(r- / pr: Afwa, \'o I To, Barcoti, I 7
:l\Pin-3e4620/d
Page 13 of26
Material Balance:
t rtrrlel Brlanea For',MNPT,{Rcrl Gl,BCrc.{AIl Vatucs ln KG)
Para'Tolljl.dinoAcsti.c4nhydrideRecover Acitic Acrd
Recover Acetic Acid92.95%' 13188 1 8 recycle 500 sale ,
Ro.Loss (Acetic Acid) 10
Nilric Acid198%lMethylene Eichloride
Fresh Wat€r
Fresh Wgter
Caustic SodaFlalecWater
{Fresh 118'l + Recycledl0oo)
Fresh Water
Mefiylene Dichiorid6Reused in Next Batch
MLIo,EfPwater Io.ETP.
Evopr Loss
h,ater To EfP
WaterToWashing
Evop, Los6,
4364,
1250 ----------r..811000 ----------l E2
100
4218. l C1
2000
637
l$:N.P,T1000
. {,.
Page14 of26
4) Fast Red 3GL Base
Para Chloro Aniline is acetylated with Acetic Anhydride in presence of Acetic acid and after
completion of addition of Acetic Anhydride, mass is fiansferred to distillation reactor to recover
Spent Acetic Acid. After flaking, Aceto product is collected & transferred into nitration vessel withMDCand slow addition of dilute Nitric Acid at required temperature. After completion of nitrationprocess, reaction mass is transfer into distillation vessel for recovery of MDC a.nd then is transferred
into neutch filter. Filtrate is drained out to ETP after washing and reaction mass is transfered into
hydrolysis reactor with caustic soda flake and water. The mass is further filter waste water as filtrateis to be sent towards ETP for treatment purpose and solid mass is further purified by washing and
drying to get Finished Product - Fast Red 3GL Base.
Chemical Reaction:
Fted 3rt.'l-
NH: IIHCoCH3I - CHOCO )
fa> + -""-> 5 fi- -F cH3cooHcH3co Y uo.oscr PlAccticAfihvdride .r6(i.6o
para, chttro Anitine 1A2,AS127.57
trHcocH3a.lCI:
169.60
hrHcocH3
,t'YozYCI
Nitra.tiohH,N()3 '------""">
63-02
ryHCocH3/./\-N02il -t
Gl21:4.6O
-t Hzo
1a
-+- NaoH #Hydr{jYsis
+ cH3GooNa
Seclium ;A{retate
a203:214;60 39:99 Red:3GL
172.s6
#ffiW
Page 15 of26
Material Balance:
Material lialance For Fast Red GL Base.(All Values in KG)
Phra ChlcoiAnilineecetiglnfry*iaeRecover Acitic Acid
Acefic Abid 99cA 12,,
r0
763 recyde 462 sale.
.Loss,(Acetic Aeid)
Nitric Acid (60",6)
MeSrylene Didrloride
Fre$r Urhter Metftylene DichloridoReused in N*t Batch
3256
1585 +E1
'1,000 +E2
100
3283 +Cl
:2000
N1
FreSr llUiiter
Sosiuni HydroxideWater(Fr66h 544 + Recycled 2000)
Fresh Whter
ML to ETP
Water To ETF
Evop.rloss
Water To ETP
To Wa$ing
Ev6p: Loss
F.ast,Red GL,Easemm
Page 16 of26
5) F'ast Yellow GC BaseIn the Reactor water and add Hydrochloric acid (32%) are mixed properly and OrthoChloro Aniline
is added at specific temperature and time. The mass is stirredfor I hour and after that sodium
chloride is added to precipitate of Yellow GC Base from water.
The whole mass is centrifuged for separation of water. Water from centrifuged stage is partially
reused in next batch and rest is diverted to ETP. Wet cake of product is further dried to obtain final
product
Chemical Reaction:
lllHz# $H2.HClCl H2gl
+HCl*CI
ortho chtorp..Anitine. Hydrothloric,Acid ortho Chlom Aniline Hvdrochloride
127.5 36.4 164.03
Material Balance:
fthtetial Bahifce For FaEt YellowG0 Base{All\Ialues in KG}
0rtto'Chloro Aniline 1
Hel32% 1
Nast
Recy.ele V\hter 1
:
f+ 1000 Recycle in next batch
14141It+ 414 To EfP
FastYellowG0 Base,
ud-\'O*LE
Pagel7 of26
r
6) Fast Orange GC BaseIn the Reactor water and add Hydrochloric acid(32%) are mixed properly and Meta Chloro Aniline
is added at specific temperature and time. The mass is stined for t hour and after that sodium
chloride is added to precipitate of Fast Orange GC Base from water.
The whole mass is centrifuged for separation of water. Water from centrifuged stage is partially
reused in next batch and rest is diverted to ETP. Wet cake of product is further dried to obtain final
product.
Chemical Reaction:
Material Balance:
l)JHz
0 + HCIHzo_1.
CI
Meta Chloro Aniline
127.5
l.lydrochloric Acid
36.4
Meta Chloro: Al iline Hydrochloride
164.03
Matef-ial Bal&nae FoI Fast OrangeGG Bess(All VsIuEs in KG)
Meta ehbro.AnilineHoi 32%NaclRecydeWater
1000 Reoyelein,nextbatoh
414 ToEIP
-
Page 18 of26
I ,,7
7) Fast Red RC BaseIn the Reactor water and add Hydrochloric acid (32Y) are mixed properly and Red R (1 Chloro 4
Amino Toluidine) is added at specific temperature and time. The mass is stirred for I hour and after
that sodium chloride is added to precipitation of fast red RC Base from water.
The whole mass is centrifuged for separation of water. Water from centrifuged stage is partially
reused in next batch and rest is diverted to ETP. Wet cake of product is further dried to obtain final
product
Chemical Reaction:
#ocH3 + HCr
HrO--f
CI
Red R Flhkes
123..15
HydrochloriCAcid
36.4
Red RC Base
194.05
Material Balance:
l,Jlaterial'Balanee For Fast Red RO,Base.{Atl Valueg:in' KG)
Red Rr-Jd3a%Nac!Reclcle Water
1000- ReClrclein'n4{,ttatch
414 To tIP
Page19 of26
ANNEXURE - II
Details of Effluent Treatment Plant
Total 4I.3KLD wastewater will be generated from proposed project bifurcated as domestic
wastewater @1.3 KLD & industrial wastewater @ 40.0 KLD. Industrial wastewater includes
wastewater from plant washing @ 4.0 KLD, cooling tower blow-down @ 0.7 I<LD,
wastewater from boiler @1.8 KLD & water arrives from [email protected] KLD.
The domestic wastewater will be disposed off through Septic tank/ soak pit. The industrial
effluent will be segregated in 3 streams as
1) Water from Nitration stage (16.1 KLD)2) Water from Hydrolysis stage (9'3 KLD)3) Water from washing & others - (14.6 KLD)
The entire three stream will be separately collected ln collection tank and given separate
primary treatment as per its characteristics. After primary and tertiary treatment, treated water
from each stream will be separately evaporated in evaporator. Condensate water recovered
from evaporator will be reused in manufacturing process.
Effluent Treatment Scheme for Water from Nitration stage
The entire effluent from the nitration process will be collected in separate collection tank.
Then effluent will be neutralized with NaOH up to pH value 7.5 -8.0. After neutralization,
e{fluent will be filtered in filter press and clear effluent will be given tertiary treatment with
activated carbonand clear effluent will be sent for evaporation. Condensate water from
evaporator will be reused in the process. Based on the effluent quality sodium nitrate salt will
be generated as evaporation salt which will be sold out to actual users or sent to TSDF site.
Sludge from primary treatment will be sent to TSDF site for disposal.
Units of Effluent Treatment Plant (for treatment of Nitration Stage water)
Note: Multiple effedt evaporator will be used as a cemmon facilities for all streams.
400 mm Dia.
1.5 m Height.
Page20 of26
1. Collection TankFLOW: 16.1 KL/DAY (Nitration Stream)
in multi effective evaporation unit to achieve Zero
2. Neutralization Tank
3. Nutsch Filter
4. Carbon Column
Aftbr primary treatment,
discharge.
Req. HRT- 12 Hrs.
Provided HRT - 23.8 Fhs.
It will be adequate
Installing of this tank isto collect effluent whichis coming from the
Installing of this tank isto Neutralize theeffluent.
Req.HRT-2FIrs.Provided HRT - 7.5 Hrs.
Nutschfi lter is typicallyused to dewater settled
sludge from plants.
is being a continuous process and waterill not being stored and sent for other
t Thus it will be adequate for said
Capacity req. - 0.67 m3/hr.Capacrty Provided -2.4 m3ltnIt will be adequate
Activatedcarboncolumnis used inthe treatment of effluentas a frnal polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.
5. HoldingTank
Holding tank is used forcollecting the clarifiedwater from carboncolumn.
Req. HRT-6Provided HRT - 23.8
It will be adequate
it will further feed
Page2l of26
Effluent Treatment Scheme for Water from Hvdrolvsis stage
The entire effluent from the Hydrolysis process will be collected in separate collection tank
Then effluent will be acidified with Acetic acid up to 6 pH and after that the effluent will
neutralized with NaOH up to pH value 7.5 -8.0. After neutralization, effluent will be filtered
in filter press and clear effluent will be given tertiary treatment with activated carbonand
clear effluent will be sent for evaporation. Condensate water from evaporator will be reused
in the process. Based on the effluent quality sodium acetate salt will be generated as
evaporation salt which will be sold out to actual users or sent to TSDF site. Sludge from
primary treatment will be sent to TSDF site for disposal'
Units of Effluent Treatment Plant (for treatment of Hydrolysis Stage water)
Name of the unit Quantity Capacity
Collection Tank I 10m
Neutralization Tank I 5m'
Nutsch Filter I 5.0 m'
Carbon Column 2 400 mm Dia.
1.5 m Height.
Holding Tank I 10m
MEE I 40 Kl/day
Note : Multiple effect evaporator will be common for all streams.
FLOW: 9.3 KL/DAY (Hydrolysis Stream)
2. Neutralization Tank
t. Collection Tank
Req. HRT- 12 Hrs.
Provided HRT- 25.8 Hrs.
It will be adequate
Installing of this tank isto collect effluent whichis coming from the
Req. HRT-2 Hrs.
Provided HRT - 12.9 F{rs.
Installing of this tank isto Neutralize theeffluent.
3. Nutsch Filter
Page22 of26
4. Carbon Column
HoldingTank
After primary treatment, it will further feed in multi effective evaporation unit to achieve Zero
discharge.
Effluent Treatment Scheme for Water from washing and others
The entire effluent from the water and others will be collected in separate collection tank.
Then effluent will acidified with alum up to 6 pH and after that the effluent will neutralized
with NaOH up to pH value 7.5 -8.0. After neutralization, effluent will be filtered in filterpress and clear effluent will be given tertiary treatment with activated carbonand clear
effluent will be sent for evaporation. Condensate water from evaporator will be reused in the
process. Sludge from primary treatment along with evaporation salt will be sent to TSDF site
for disposal.
Units of Eflluent Treatment Plant (for treatment of Washing & others water)
Name of the unit Quantity Capacity
Collection Tank "l 15 m'
Page23
being a continuous process and waternot being stored and sent for other
Thus it will be adequate for said
Nutschfilter is typicallyused to dewater settled
sludge from plants.
2 2.4m3/br Activatedcarboncolumnis used inthe treatment of effluentas a final polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.
Capacrty req. - 0.38 m3flt.Capacrty Provided -2.4 m3lltr.It will be adequate
Req. HRT-6Provided HRT - 23.8
It will be adequate
Holding tank is used forcollecting the clarifiedwater from carboncolumn.
of26
Name of the unit Quantity Capacity
Neutralization Tank I 5m'Filter press 24" x24" I 24x24Carbon Column I 400 mm Dia.
1.5 m Height.
Holding Tank I 15m
MEE I 40KUday
FLOW: 14.61<L{DAY (Washing & others)
1. Collection Tank
Installing of this tank isto collect effluent whichis coming from the
Req. HRT- 12 Hrs.
Provided HRT- 24.6Hrs.It will be adequate
2. Neutralization Tank
3. Filter press
4. Carbon Column
Installing of this tank isto Neutralize theeffluent.
Req. HRT-2 Hrs.Provided HRT- 8.2 Hrs.will be adeouate
24" x24" Req. capacity - l4.6Kl-lday.Provided capacity - 40 KLlday
Activatedcarboncolumnis used inthe treatment of effluentas a final polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.
Capacity req. - 0.60 m3/hr.Capacity Provided -2.4 m3/hr.It will be adequate
Page24 of26
IloldingTank
Note: Condensate recover from the MEE will be further reused in manufacturing process.
ETP Diagram.
MEE DETAILS.
Req. HRT-6Provided HRT- 23.8
Itwill be
Holding tank is used forcollecting the clarified waterfrom carbon column.
For Nitrrtian Stream (t5.1 XtO)
{uld€IlsetEi€use inProrcss SodiunSallsold
out lo s{tual users d sentto TSDF
co{rdefisste fi€ure inProc€ss sodiun Salt sold
out to actrial us€rs or sPnttoTSSF
For W*hing & other Stream (ltt.6 KtDl
condensate ReuseinProcess s.lt to TSDF
€arbon €otru*u
{zl4{X}mmOit.
15 mr$ t*eight
For Hydrolysir Stream {s.l t<to}
{aIbon colurirn
{1}4Bo mm DiB.
1.5mm HeiBht
Page25 of26
lqtt1
ANNEXURE - III
Water Balance Diagram (in KLD)
FrGEh llllater21.s
To reptic Tankt.3
Water Balance Diagram Stream wise (in KLD)
lffater
21"8
f€aJi-;nil]
+*SludEe lo ,l-oB*es & SaH
TSDF
Page26 of26