yang, silicon materials used for solar cells

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Erice, Sept.18, 2007 Deren Yang Silicon Materials Used for Solar Cells Deren Yang State Key Laboratory of Silicon Materials Zhejiang University, China

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Page 1: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Silicon Materials Used for Sola

r CellsSilicon Materials Used for Sola

r Cells

Deren Yang

State Key Laboratory of Silicon MaterialsZhejiang University, China

Page 2: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

State key lab of silicon

PV and Silicon industry

Research of silicon

Outline Outline

Page 3: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

ShanghaiShanghai

HangzhouHangzhou

BeijingBeijingHangzhouHangzhou

State key lab of silicon State key lab of silicon

Page 4: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Human-being: 7000 year

City: 2000 years

Capital city: 800 years

3,000,000 population

West Lake

Hangzhou Hangzhou Capital of Zhejiang ProvinceCapital of Zhejiang Province

Page 5: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Zhejiang University

Built in 1897 (one of oldest)

One of top 5 university

Five campus

22 colleges, 60 departments

Nearly 40,000 students

Page 6: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Cz silicon used for IC,

specially nitrogen-doped CZ silicon Silicon used for solar cells Nanowire silicon Silicon based opto-electronic materials

19541954

State key lab of Silicon Materials

Zhejiang University

Page 7: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Page 8: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

0100200300400500600700800900

1000

Sola

r Ce

lls(

MW)

1998 2000 2002 2004 2006

Year

In 2001, 4 MW solar cells and about 1% share of world.

~32% share of the world

In 2008, ~2580 MW solar cells, ~4000 MW capability

PV and Si in China PV and Si in China

Page 9: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

0

500

1000

1500

2000

2500

3000

3500

4000

Ton

t(

1996 1998 2000 2002 2004 2006 2008

Year

Polycrystalline silicon Polycrystalline silicon

In 2002, 75 tons In 2008, ~4500 tons

Page 10: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Polycrystalline SiPolycrystalline Si

Line

In building

Planning

Capbility: ~ 100,000 t

Page 11: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

0

1000

2000

3000

4000

5000

6000

Sili

con

t(

1996 1998 2000 2002 2004 2006

Year

Yield of Silicon for PVYield of Silicon for PV

CZ-Si: ~12,000 t

mc-Si:~ 12,000 t

2008, ~24,000

Page 12: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Crystal growth (CZ and multicrystalle-Si)

Defect and impurity (dislocation, grain boundary,oxygen, c

arbon, metals…)

Defect and impurity engineering (nitrogen-doping, german

ium doping)

materials issues during solar cell process (gettering,passiva

tion…)

Up-grade metallurgical silicon

….

Silicon Research Silicon Research

Page 13: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Solar Energy Material and Solar Cells, Vol.62, 37

Oxygen and carbon in mc-Si

Solar Energy Materials and Solar Cells, Vol.72, 133

Solid State Phenomena, Vol. 82, 2002, P.707-712 Solar Energy Materials and Solar Cells, Vol.72, 541

Page 14: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Aluminum in mc-Si

Eur. Phys. J. Appl. Phys.27, .119-122

Page 15: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

New complex in mc-Si

Physica B 344, 1-4

Page 16: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Metal precipitation in mc-Si

Applied physics Letters, Vol.83,No.15, .3048-3050 Physica B 344.407-412 Semicond . Sci.Technol.19 ,299-305

Page 17: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Texturization in mc-Si

Renevable Energy 29 ,2101-2107 Solar Energy Materials&Solar Cells 77, 255-263 Semicond. Sci.Technol.19, 485-48

Page 18: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Grain boundary in mc-Si

J. Phys.: Condens. Matter 16 , S211-S216.

J. Appl. Phys. 96 , 5490-5495.

J. Appl. Phys. 97 , 033701.

Page 19: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

PV and silicon industry is developing very fast in

China.

Czochralski, multicrystalline and up-grade metallu

rgical silicon have been investigated.

Growth, defect and impuries during crsyal growth

and solar cell process has been focused.

SummarySummary

Page 20: Yang, Silicon Materials Used for Solar Cells

Erice, Sept.18, 2007 Deren Yang

Thank you!