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ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Breakthrough ResearchExxonMobil Research and Engineering
GCEP Breakthrough Research WorkshopMonterey CaliforniaNovember 11, 2005
Andy Kaldor
V3

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Breakthrough Research
• Strong Corporate Drive to Develop Breakthrough Technology
• Breakthrough Research in all Sectors
• Process must be driven by ambitious targets connected to business needs / opportunities
Upstream
Breakthrough Program
URC centered
CSR Programs
DownstreamBreakthrough Program
EMRE centeredChemicals
Breakthrough ProgramChemicals centered

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Breakthrough Technology Is Inherently Episodic• There Are Few Breakthroughs to Be Had
Petrochemical Industry Breakthroughs
• Rotary Drilling• Seismic• Deepwater Development• Fluid Catalytic Cracking• Catalytic Reforming• Paraffin Alkylation• Butyl Rubber• Zeigler-Natta Polymerization• Metallocene Catalysts• Sterically-hindered Gas Treating• Synthetic lubricant
• Breakthroughs Explore the Unexplored• Practical, Out-of-the-Box Thinking Is Not a
Routine Activity• Innovation Techniques Exist but Are Still
Much More an Art Than a Science
Many notable examples of targeted breakthroughs
• Transistor• Semiconductor technology• Fiberoptics• NMR imaging• Drug discoveries
• Many examples where basic research and discovery lead to breakthroughs
• The significant difference is the time is takes to recognize the discovery and connect it to practical applications

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
XOM Breakthrough Approach
– Large Economic Potential – Proprietary Advantage– Technical Novelty
• Initial Project Qualifying Criteria:
• Generate Breakthrough Technology That Can: – Generate Step-Out Value– Change the Game– Offset Competitive Threats– Create New Business Opportunity
19 Projects
~ 135 Concepts Evaluated
2 Commercial
BTR Impact Screen
>1300 Ideas
Process Industry experience:3000 300 125 9 2 1Ideas Projects Commercial
ExxonMobil Experience
– Aggressive Goals – Structured Innovation Process – Extensive Root Analysis; Science and Business– Rapid and Improved Yield from Basic Science– Novel Approaches
• Manage Inherently Higher Risk:

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
XOM Breakthrough Research Process
ProjectEvaluation /
Approval
Blue Team
• Testable Hypothesis• Critical Show Stoppers• Phased Execution Plan
Peer Review
PROPOSAL
VolunteeredIdeas
Open Innovation,
ExternalInnovation
IdeaGeneration
Business / Technology Innovation Sessions
HolyGrails
Set By Senior
Business Executives
Proposal Development
Venture Team
Champion
GreenHouse/
Inventory
Research Guidance
OpportunityIdentification

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
BreakthroughTeam
facilitates processsystemsBreakthrough Manager
Budget for BT Programs Stage A through 1
Cross Functional LeaderBusiness Contact
Breakthrough Players
Research Guidancevalue proposition
research strategy/priority
Venture TeamOpportunity Identification
Value PropositionResearch Proposal
Critical PathExecution, staffing
Senior Business & Technology
Management (Blue Team)sponsors and supports
R&D programs
Lead Definition
Pre-Development Development CommercializationIdea
Generation
Gate C Gate 1 Gate 2Gate A Gate B
BT Project TeamExecute Project
Update Value PropositionMeet Gate Goals
Transform as needed
Gate3

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Venture Team Approach to Generate Proposals • Organized Around a Grand Challenge• Leader is Identified, EMRE-Wide Participation on Team• Research Guidance Aimed at Improving Ideas/Define Value Propositions• Objective is to Develop a Proposal for Breakthrough Program• Process:
– Solicit & Assimilate Information and Ideas, Including Business– Organize and Hold Brainstorming Sessions Within/Outside EM
• Consultants, Universities, Venture Co’s, Vendors, etc.– Evaluate Information, Ideas, Develop, or not, Proposal(s)
• Identify Champion(s) for Proposal(s)• Conduct Peer Reviews of Proposals
• Present Proposal to “Blue Team”– BTR Proposal Approved by Blue Team - Champion Forms Team,
Initiates Work

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Work flow to develop proposalsOpportunity Identification
Organize Venture Team• Agree on Focus• Timeline
“Follow the money” or Key Issues• Define the size of the prize, frame problem• What do we know/don’t know• Agree on key elements of problem• Prioritize key elements/size of problem
For each element• What are the real roots of problem• Follow the trail, drill down• Prioritize in terms of value and impact
if solved; difficulty• How many miracles needed?• What problem needs solution ?
For each element• Explore solutions to specific problems,
issues identified• Test if solution works does it actually
solve problem• Recycle • Generate and prioritize potential solutions• Assess potential solutions
Develop Research Proposal(s)• Develop plan, timeline, deliverables,
killer variables, etc• Critical path plan, prioritized• Develop staffing plan, bugdet, equipment
Project Decision• Funding• Go work it!

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Probability of success for technology system based on multiple innovations
known 1 known 2 known 3 unknown 1 unknown 2 unknown 3 unk1x2x3known 1 1.00 0.90 0.50 0.10 0.20 0.30 0.03
known 2 0.90 0.81 0.45 0.09 0.18 0.27 0.027
known 3 0.50 0.45 0.25 0.05 0.10 0.15 0.015
unknown 3 0.30 0.27 0.15 0.03 0.06 0.09 0.009
unknown 2 0.20 0.18 0.25 0.02 0.04 0.06 0.006
unknown 1 0.10 0.09 0.05 0.01 0.02 0.03 0.003
(Known x Known) rule is a good way to recognize complexity of technology development which requires multiple new/novel concepts put
together in new ways. Requires deliberate strategy to manage risk !Early prototyping and model building, commercial test of components of
system, risk assessment are some of the ways to manage risk

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Framing the right problem is critical• “It's not that the right answer can't be found, it's that the right
question isn't being asked.”
• Successful technical creativity is more about finding the critical points-of-attack than ”wild” thinking.
• Working to solve the wrong problem is worse than not working any problem at all
• Complex, multifaceted problems require complex, multifaceted understanding.
• Every problem has simple, easy to understand wrong answers.
A core philosophy is to take the time to define the actual problem, i.e., the root issues associated with a perceived
inadequacy

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Drilling Deep Without Doing Root-canal
Approach• Focus on identifying root issues – "creativity" will largely take care of itself.
• Deconstruct complex problems in sub-units which can be readily understood and innovated on
• But, don't overly deconstruct into so many sub-units that one is "lost in the forest"
• Identify and high-grade a wide range of possibilities prior to focused innovation on any one of them
• Structured layout of issues, elements, and solutions
• Succinct documentation

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Idea Grading• Evaluated ideas based on:
– Order-of-magnitude economic benefit if successful– Feasibility
Observations
• No ideas identified that were both readily doable and would have a huge (i.e. Breakthrough) impact
• Many ideas generated had serious issues with basic physics, chemistry, or engineering
• Idea generation focused on novel and unconventional approaches rather than tweaks to existing methods
Economic Benefit(None) (Low) (High)
(Huge)
Feas
ibili
ty(E
asy)
(1 m
iracl
e)(2
mira
cles
)(3
+ m
iracl
es)
Idea Ranking - January 23, 2003
89
8887
86 85
84
83
82
81
80
79
78 77
76
75
74
73
72
71
70 6968
67
66
65
64
6362
61
60
59
58
57
56
55
54
53
52
51
50
49
48
47
4645
4442 41
40
3938
3736
35
34
33
32
3130
2928
26
25
242322
21
20
19
18
1716
15
14
1312
11
10
9
8
7
6
5
4
3
1
2
43
0
1
2
3
0 1 2 3
y

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Tornado Diagram to Highlight Value Propositions
0.0 20.0 40.0 60.0 80.0 100.0 120.0 140.0 160.0 180.0 200.016-Year A.T. NPV (M$)
Energy+Margin
Approach to Process
Durability
Technical Performance
Breadth Appl
Capex
Roll-Out+2 yr Re-process
Processing Cost
R&D $ to Comm
10% Feedstock5% Feedstock +25% Feedstock
4.1 $/MBtu2.5 $/MBtu
7.3 $/MBtu
65%50% 85% (2yr avg)
100% Cycle50% Cycle 200% (50% Process Cost)
5 yrs10 yrs 3 yrs
150% 50%
11 M$15 M$ 9 M$
8 $/ft12 $/ft 2 $/ft
43%
29% 71%

ExxonMobil Research and EngineeringExxonMobil Research and Engineering“Right-to-Left” Need-driven Science and
Technology Platforms are Enabling Breakthrough
• Mapped Platforms Against Game Changing Business Drivers• Platforms Have to Have Substance for Rapid Delivery of Breakthroughs• Acquire Platforms from Multiple Sources• Dig into Fundamentals of Business Drivers and Technology Needs
A
A
A
$
$
$
$
Business Needs & Opportunities
Technology Platforms Needed
A
1
54
23
Science Platforms Needed

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Example: Energy Reduction Program
New Reaction Pathways
0
20
40
60
80
100
Exergy Process
Limit
Current
BT Prgrm
State of
the Art
Actual
Energy
% C
urre
nt E
nerg
y C
onsu
mpt
ion
Current Best practice Theoretical

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Example A: Opportunity Identification Process Charter: In order to do low pressure deep distillate HDS catalysis we will
identify what specific chemistry steps we want the catalyst to do and what we don’t want it to do. The purpose is to identify the science input weshould seek to help design high throughput experiments
Why low P distillate HDS catalysts have low activity?• Map out chemistry that is known to occur on different catalytic materials
(volcano diagram – generic process steps)– Why-why?
• What are the promoters and inhibitors of the key reactions?– Why-why?
• What specific chemistry do we want to promote with catalytic sites? (Targets for improvement , metrics)
– Why-why? Why-how
• What are analogues to these catalytic sites? (Direct and Functional)
• What science and/or technology approaches could be used to achieve these analogues? Priority?
• What specific solutions should be included in effort? Priority?

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Compositional Modeling Combines Advances InComputing and Analytical Chemistry
• Detailed Molecular Characterization of Refinery Streams CombinedWith Reaction Kinetics
• Process Models Based on 5000+ Molecular Species and MolecularConversion Reactions
• Predicts Detailed Product Compositions, Yields, and Properties
Advanced Analytical Technology
Hydrocarbon Chemistry2H2
2H2
2H2
2H2
2H2
2H2
2H2
2H2
3H2
2H2
2H2
2H2
Modern Delivery Systems
APPLICATIONS:• Crude Selection• Refinery Yield Opt.• B/S Harmonization• Lube Performance• Toxicological Char.• Chemicals Mfr.• Research Guidance

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Generate Molecular Models for Research Guidance • Propose Chemistries and Separation Schemes to Achieve
Desired Products
• Enables research target setting even if means of achieving target are unknown
• Facilitates testing of observed data against proposed mechanisms
7
8
9
10
11
12
300 500 700 900 1100 1300 1500
BP (F)
Solu
bilit
y Pa
ram
eter

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Assessment Process
GATE I
Source/carrierpair analysis.
Identifysource/carrier
pairs withsignificantpotential.
Identify, assessenabling
technologiesand pathwaysof potential
interest
Selectsource/carrier
pairs
Selectspecific
pathways
Pick new source/carrier pair...uselearnings to adjust process
source
CoalSolar
NuclearGas Hydrates
BiomassGeothermal
carrier
Refined LiquidsGas
HydrogenElectricity
EXTERNALPROGRAMS
INTERNALPROGRAMS
CapabilityBuild
LeveragedTechnologyAcquisition
Monitor forBreakthrough
P O S
I T
I O
N I
N G
InternalTechnology
Development
Evaluateenabling
technologies fordevelopment andcommercialization
potential.
Developrecommendations
fordevelopment of
enablingtechnologies
GATE II
PHASE I PHASE II

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Lead Inventory of LG Teams
0
2
4
6
8
10
12
14
16
# of
Lea
ds
Low QualityMedium QualityHigh Quality
Lead Generation Programs Breakthrough Programs

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Fuzzy Front End Model
ENGINE
OpportunityIdentification
OpportunityAnalysis
Idea Generation and
Enrichment Idea
Selection
Concept Definiti
onTo Stage Gate
Engine“Controllable”
Core Front End “Activity”Elements
InfluencingFactors
“Uncontrollable”

ExxonMobil Research and EngineeringExxonMobil Research and EngineeringClosing Comments
• The key element of breakthrough research is a thorough understanding of targets or goals that constitute the breakthrough(s) and the ability to identify the science which has the potential to enable it
• Having a systemic process to evaluate ideas and concepts critical to sharpen and better define targets
• Most breakthroughs come about from a new and different way of posing the questions that guide the research, framing the problem a new, creative way
• Basic research in the absence of a “breakthrough process” has lower probability to find discoveries that lead to major impact, or it may take longer to find appropriate application
• Breakthrough research requires a different approach and management than basic academic or applied industrial research
• Overly focusing the research reduces the probability of success
• Constraining the approaches to achieving the target is counterproductive
• Revisiting the targets on the basis of new knowledge and understanding is critical

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Back-up

ExxonMobil Research and EngineeringExxonMobil Research and Engineering
Recurring Themes on Breakthrough Hurdles• Extensive Experimentation and Modeling Required
– A technical idea is seldom recognizable as “the solution” until extensive scoping work is performed– Any idea with a low acceptance-barrier would almost certainly already been implemented– Thinking exercises inherently limited to identifying promising pathways rather than solutions
– “Genius is 1% inspiration and 99% perspiration” – Thomas Edison
• Risk Aversion– Individual: Why work on high-visibility projects with low chance of success, when important lower
risk projects are options? – Corporate: Why fund high-risk projects with poor tracking metrics, when there are more than
enough incremental efforts to do?
• Disruption– Competes with incremental research programs– Takes resources (e.g. funds and staffing) from established programs– Typically requires some support from naysayers (vocal and private)
• Episodic– Discoveries unevenly distributed in time
• The higher the bar for "Breakthrough", the more unevenly distributed in time the discoveries– "Nonlinear" project progress
• Not Fitting The Mold– Much higher uncertainty than traditional projects
• Timetables and costs cannot be estimated at the outset as accurately as incremental projects• Approval required without endless justification exercises
– Projects often cross business divisions• Cross-disciplinary research by its nature is much well-tread than research focused on single
disciplines– May require new business models to profit from the Breakthrough technology– “Success” of the project and team cannot be measured solely by the project’s ultimate profitability

ExxonMobil Research and EngineeringExxonMobil Research and EngineeringRecurring Themes in Successful Innovation• Clear Articulation by Top Management of Innovation Priorities and Expectations
– Critical audience is all who encourage (or can discourage) research directions– If priorities and expectations are not strongly championed, innovation efforts
readily degrade into repackaging incremental efforts or are dropped in favor of short-term goals
• Fail Fast, Fail Often– Fast
• Streamlined approval process– Don’t require highly detailed economics
• Initial effort is a rapid proof-of-concept• Have gate-system for project continuation
– Often• Best way to get a few great ideas, is to sift through many ideas• Allow “failure” so researchers suggest the novel and difficult rather than the
obvious and straightforward• Project Champions
– Strongly motivated and empowered team leader– Leader with a very strong belief and stake in the project– Commercialization champion likely different than the research champion
• The Right Team– Get the experts
• Cross functional and organizational boundaries as needed– Have only excited team players