which is the stronger acid?
DESCRIPTION
Which is the stronger acid?. HNO 2 HNO 3. Which is the stronger base?. NO 2 - NO 3 -. Acid-Base Reactions. strong acid + strong base strong acid + weak base weak acid + strong base weak acid + weak base. Extent of Weak Acid-Weak Base Reactions. Extent of Weak Acid-Weak Base Reactions. - PowerPoint PPT PresentationTRANSCRIPT
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Which is the stronger acid?
1. HNO2
2. HNO3
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Which is the stronger base?
1. NO2-
2. NO3-
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Acid-Base Reactionsstrong acid + strong base
strong acid + weak base
weak acid + strong base
weak acid + weak base
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Extent of Weak Acid-Weak Base Reactions
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Extent of Weak Acid-Weak Base Reactions
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pKa and Acid Strength pKa = -log Ka
Ka pKa
Trends:
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Buffers
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How Buffers Minimize pH Changes
NH4+/NH3 buffer
If an acid is added:
If a base is added:
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What controls pH of a buffer?
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What controls pH of a buffer?
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Buffer pH
a[base]pH = pK + log[acid]
Two cases:
1. When the acid and base of interest are in bulk and control the pH
2. When other acids and bases are in bulk and the acid/base state of the species of interest is controlled by the pH (ex: indicators)
a[base]pH = pK + log[acid] a
[base]pH = pK + log[acid]
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1a. Buffer pH
a[base]pH = pK + log[acid]
What is the pH of a solution with [H2CO3] = 0.25 M and [HCO3-] = 0.25 M?
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1b. Buffer pH
a[base]pH = pK + log[acid]
What is the pH of a solution with [H2CO3] = 0.25 M and [HCO3-] = 0.11 M?
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Review
Buffer components
pH of a buffer solution-- Question: if dilute a buffer, does the pH change?
Preparing a buffer by “direct addition”
Now: Preparing a buffer by an acid-base reaction
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Preparing Buffer SolutionsMake a buffer of pH = 3.6
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Preparing Buffer Solutions by ReactionMake a buffer of pH = 5.00 using sodium acetate and 1.0 M HCl
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Preparing Buffer Solutions by ReactionMake a buffer of pH = 5.00 using sodium acetate and 1.0 M HCl
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Alpha Plots
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Alpha Plots
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pH Titration CurvesStrong Acid – Strong Base
Strong Base – Strong Acid
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pH Titration CurvesWeak Acid – Strong Base: Finding Ka
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pH Titration CurvesWeak Acid – Strong Base: Finding Ka
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pH Titration CurvesStrong Acid – Weak Base: Finding Kb
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Polyprotic Acids
H2CO3 HCO3- CO3
2- Ka1 = 4.2 x 10-7
Ka2 = 4.8 x 10-11
What is the pH of a 0.10 M solution of H2CO3?
What is [CO32-] in this solution?
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Polyprotic Acids
H2CO3 HCO3- CO3
2- Ka1 = 4.2 x 10-7
Ka2 = 4.8 x 10-11
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Polyprotic pH Titration Curves
0 5 10 15 20 25 30 35 40 450
2
4
6
8
10
12
14
mL of base
pH
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AminoAcids
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When pH Controls Acid-Base State: Amino Acids Situations where an acid-base species is a minor component in a solution where other things control the pH. Henderson-Hasselbalch and Alpha plots.
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When pH Controls Acid-Base State: Amino Acids Situations where an acid-base species is a minor component in a solution where other things control the pH.
pH = 0.00 pH = 2.34
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pH = 0.00 pH = 2.34 pH = 7.00
pH = 9.60 pH = 13.00
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Alpha Plots