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  • 8/10/2019 Wasmund Ingles FLOTATION

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    Flotation technology for coarse and fine particle re

    Eric Bain Wasmund

    Global Managing Director

    Eriez Flotation Division

    Vancouver, Canada

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    Presentation

    1. Identifying a universal challenge for froth flo

    2. The case for splitting up the problem into tw

    3. How to treat coarse particles.

    4. How to treat fine particles.

    5. Conclusions.

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    0

    20

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    1 10 100 1000

    Particle Diameter (Microns)

    Recovery(%)

    Copper

    Lead-Zinc

    Coal

    Phosphate

    The result of conventional flotation

    Most concentrators have flotation recoveries of 80-90

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    Flotation: An interactive systemCHEMISTRY Mineral surfac

    CollectorsModifying age

    pH

    ORE

    Particl

    Libera

    Pulp dMACHINE

    HydrodynamicsMixing

    Bubble size

    Air rate

    Wash-water

    Launders

    The Flotation

    Triangle

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    Bubble + Particle Bubble-particle aggregate Recove

    Simplified flotation process

    Kinetics are strongly dependent on size for each step!Challenge: Highly energetic fluid environment is optimacollecting fine particles, and non-optimal for recovering particles

    Conventional machines run under conditions that are a t

    attachment transport to launder

    detachment

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    Conventional flotation

    High amount of mechanical energy

    required ~ kW/m3 Objectives:

    1. Keep the pulp suspended (preventsanding).

    2. Disperse the air.

    3. Create the mixing for particle-bubbleinteractions.

    4. Create low turbulence for frothrecovery

    Pulp phase behaves like a CSTR (short

    circuiting expected).

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    Eriez approach Borrowed from the fertilizer beneficiation industry (ie phosp

    potash).

    Do a size separation first, and then process each stream witappropriate technology.

    Coarse particles treated using Eriez HydroFloat fluidized becell.

    Fine particles treated by Eriez columns.

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    Effects of particle size can be

    reduced by utilizing a split-

    feed flotation approach.

    Efficiency improves,

    especially for coarse

    material, with tighter size

    ranges.

    Other benefits include a

    more efficient use of

    reagents.

    Feed Primary

    Classifier

    Conditioner

    Conditioner

    Reagents

    Finas

    Reagents

    Lets focus on coarse particle flotation and applications

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    Flotation in a fluidized bedFeed

    Freeboard(low turbulence)

    Fluidized bed

    Fluidization manifold

    (not shown)

    Tails

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    Particulate fluidization

    Fluid properties will be modified because of the interactionof other particles in the bed, the hindered settlingregime

    Particle is fluidized when the downward force of gravity (Fg) is

    balanced by the upward drag force from fluidization water (Fd)

    Heavy particles (large size and/or large SG) that have more

    mass relative to their drag will sink relative to the bed

    Lighter particles (small size and/or small SG) will riserelative to the bed

    Bubble particle aggregates will have an effective SG that

    allows them to be lifted out of the bed

    Fluidiza

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    Design features of the HydroFloat

    Flow through the unit is counter-current which maxcontact time.

    Fluidized bed behaves like a plug-flow reactor, shortof particles and bubbles is reduced.

    Fluidized bed allows high and uniform particle concand optimized interaction between bubbles and pa

    Hindered settling regime (ie modified viscosity, denmore residence time.

    Less turbulence than a stirred tank, detachment mi

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    Design considerations of the HydroFloat

    Fine or low density feed particles can be pushed to the pwhich can lower grade. Experience suggests a feed size with top size class/fine size class ~ 5 : 1 depending on m

    Fluidization water will lower the percent solids of the prScreens or cyclones required to de-water

    Mechanical agitation (power) not required.

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    Typical HydroFloat balance for a 4 m dia uFeed: 5000 tonne solids/day

    % solids = 60-75 w/w%

    p80 = 750 mm

    Fluidization water: 5000 m3

    /dayAir: 1000 m3/day

    Tail: 4500 tonne solids/day

    % solids =70-80 w/w%

    p80 = 800 mm

    Concentrate: 500 tonne solid

    % solids = 5-20 w/w%

    p80 = 650 mm

    Water reports to product, underflow has high perce

    De-watering

    cone

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    Evaluation of the HydroFloat on a coarse Spsystem*

    Measured recovery by size class with HydroFloat lab-unbenchmarked against Denver test-cell

    * Optimization of operating parameters for coarse Sphalerite flotation in the HydroFloat fseparator, Minerals Eng., 50-51, pp 99-105 (2013). See also Minerals Eng. 60, pp 51-59 (2

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    HydroFloat commercialization

    Successful applications have been developed for phosphate

    New applications are being developed for copper and gold.

    Opportunity exists to introduce into existing mineral processheet.

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    Simplified conventional concentrator

    Possibility to reduce circulating load.

    Possibility to increase particle size from SAG (increase throughpu

    Possibility to avoid losses of high SG ductile ore like free gold and

    Ball Mill

    SAG

    Mill

    HydroFloat

    To fin

    Feed

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    Test-work done at larger Copper concenSouth America

    Sample taken from mill cyclone underflow to evaluate perform

    inch diameter lab unit.

    To Rougher

    Flotation

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    Test set-up

    Feed = 0.15 t/hr. fluidization water = 1.5 m3/hr.

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    Results

    HydroFloat recoveries of 70-90% on coarse feed

    (ie cyclone underflow).

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    Potential flow-sheet improvement

    HydroFloat could treat part (or all?) of the ball mill cy

    underflow.

    Ball Mill

    SAG

    Mill

    >1000 mm

    HydroFloat

    Feed

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    Effects of particle size can be

    reduced by utilizing a split-

    feed flotation approach.

    Efficiency improves,

    especially for coarse

    material, with tighter size

    ranges.

    Other benefits include a

    more efficient use of

    reagents.

    Feed Primary

    Classifier

    Conditioner

    Conditioner

    Reagents

    Reagents

    Now lets focus on fine particle flotation and applications

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    Fine particle flotation

    Fine particle flotation normally benefits from

    1. Smaller bubbles.

    2. More energetic environment for collisions.

    3. Wash water to reject fine gangue.

    4. Pre-aeration Eriez has multiple technologies to achieve these

    objectives.

    ff f b bbl

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    Rate constant k inversely proportional to bubblesize to third power!

    Effect of bubble size

    Ub

    Db

    2

    2

    3

    b

    p

    cD

    DP

    PD

    Jk

    b

    g

    2

    3

    dac

    PPPP 1

    Small particles have less efficient collisions with large b

    When floating fine particles, high energy collisions and

    are beneficial.

    Eff f h

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    No Wash Water

    Wash Water Addition

    Effect of wash water

    0

    2

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    8

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    12

    14

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    18

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    0 1 2 3

    Number of Dilution Washe

    FrothMineralMatter(%)

    F

    W

    Dilutions

    ofNumber

    M ki ll b bbl th C T b

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    Eriez CavTube

    Contraction/ expansion nozzle Shatters sparged air into ~100

    micron bubbles

    As pressure drops, ~ 1 micron

    bubbles are nucleated from theliquid phase onto ore particles

    No internal parts in the flow

    path. Reduced wear from flow

    impingement.

    Making smaller bubbles- the CavTube

    Inlet

    High P Low P

    Plexiglass mo

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    CavTube bubble size distribution with air a

    *Mining Sci. & Tech, 20 (2010), pp1-19

    0

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    0.01 0.1 1 10 100 1000

    Bubble Diameter (micrometer)

    C

    m

    u

    a

    v

    C

    v

    (

    0

    2

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    6

    8

    10

    P

    a

    o

    D

    t

    y

    (

    Cumulative curve Frother ACumulative curve Frother BPopulation density Frother APopulation density Frother B

    Note: for a typical application with Jg = 0.75 cm/sec, the nucleated bubbles are

    total air volume added to cell

    CavTube sparged column

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    CavTube sparged column

    Standard column with recirculating loop to recycle slurry

    ring of CavTubes

    CavTube can also be used to pre-aerate feed ahe

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    Static Mixer

    Tailings

    Feed

    Wash W

    Sump

    Mixer

    Pressure

    Gage

    Cavitation

    Tube

    Cavitation Feed

    Pretreatment

    Collector

    CavTube can also be used to pre aerate feed, ahe

    flotation cell - lab test*

    * Cavitation pre-treatment of a flotation feedstock for enhanced coal recove

    al Coal Pre 2011

    CavTube used for pre aeration in lab te

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    CavTube used for pre-aeration in lab te

    Pre-aerating the feed with CavTubes increases the flotat

    constant so less residence time is required

    * Cavitation pre-treatment of a flotation feedstock for enhanced coal recovery

    Coal Pre 2011.

    0

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    1 2 3 4 5

    ComponentRecovery(%)

    Flotation Time (min)

    With Cavitation

    Without Cavitation

    With CavTube pre-aeration

    Without CavTube pre-aeration

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    Conclusions

    1. There is a huge opportunity to improve theperformance of concentrators throughout the

    2. Existing flotation technology considers a singapproach. It cannot be optimized for size dis

    typically produced by primary grinding circui3. Eriez approach is to focus on technologies th

    optimization of recovery by size.

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    Gracias