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J. Gmehling U. Onken W. Arlt VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION Aromatic Hydrocarbons Chemistry Data Series Vol. I, Part 7 Published by DECHEMA Deutsche Gesellschaſt fur Chemisches Apparatewesen, Chemische Technik und Biotechnologie e.V. Executive Editor: Gerhard Kreysa

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Page 1: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

J. Gmehling

U. Onken

W. Arlt

VAPOR-LIQUID EQUILIBRIUM

DATA COLLECTION

Aromatic Hydrocarbons

Chemistry Data Series

Vol. I, Part 7

Published by DECHEMA

Deutsche Gesellschaft fur Chemisches Apparatewesen,

Chemische Technik und Biotechnologie e.V.

Executive Editor: Gerhard Kreysa

Page 2: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

Vapor-Liquid Equilibrium Data Collection

7

Aromatic Hydrocarbons

Tables and diagrams of data for binary and

multicomponent mixtures up to moderate pressures. Constants of correlation equations for computer use.

J. Gmehling, U. Onken, W. Arlt

Technische Chemie Universitat Oldenburg Universitat Dortmund

lnstitut fOr Verfahrenstechnik Technische Universitat Berlin

Page 3: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

Die Deutsche Bibliothek-CIP-Einheitsaufnahme

Chemistry data series I publ. by DECHEMA, Deutsche Gesellschaft fi.ir Chemisches Apparatewesen, Chemische Technik und Biotechnologie e.V. Executive ed.: Gerhard Kreysa. -Frankfurt am Main : DECHEMA.

Teilw. hrsg. von DECHEMA, Deutschen Gesellschaft fi.ir Chemisches Apparatewe­sen. - Teilw. hrsg. von Dieter Behrens und Reiner Eckermann. - Teilw. hrsg. von Reiner Eckermann und Gerhard Kreysa

Vol 1. Vapor liquid equilibrium data collection. Pt. 7. Aromatic hydrocarbons.-2. ed. with minor changes and corr. -1997

Vapor liquid equilibrium data collection I publ. by DECHEMA, Deutsche Gesellschaft fOr Chemisches Apparatewesen, Chemische Technik und Biotechnologie e.V. -Frank­furt am Main : DECHEMA.

Chemistry data series ; Vol. 1) Teilw. hrsg. von DECHEMA, Deutsche Gesellschaft fi.ir Chemisches Apparatewesen

Pt. 7. Aromatic hydrocarbons : tables and diagrams of data for binary and multicompo­nent mixtures up to moderate pressures ; constants of correlation equations for compu­ter use I J. Gmehling; U. Onken; W. Arlt.-2. ed. with minor changes and corr. -1997 ISBN 3-926959-88-6 NE: Gmehling, JOrgen

© DECHEMA Deutsche Gesellschaft fOr Chemisches Apparatewesen, Chemische Technik und Biotechnologie e. V. Postfach 15 01 04, D-60061 Frankfurt am Main, Germany, 1997

Dieses Werk ist urheberrechtlich geschOtzt. Alle Rechte, auch die der Obersetzung, des Nach­drucks und der Vervielfaltigung des Buches oder Teilen daraus sind vorbehalten.

Kein Teil des Werkes dart ohne schriftliche Genehmigung der DECHEMA in irgendeiner Form (Fotokopie, Mikrofilm oder einem anderen Verfahren), auch nicht fi.ir Zwecke der Unterrichts­gestaltung, reproduziert oder unter Verwendung elektronischer Systeme verarbeitet, vervielfal­tigt oder verbreitet werden.

Die Herausgeber Obernehmen fi.ir die Richtigkeit und Vollstandigkeit der publizierten Oaten keinerlei Gewahrleistung.

This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, including those of translation, reprinting, reproduction by photocopying machine or similar means.

No part of this work may be reproduced, processed or distributed in any form, not even for teaching purposes -by photocopying, microfilm or other processes, or implement in electronic information storage and retrieval systems -without the written permission of the publishers.

The publishers accept no liability for the accuracy and completeness of the published data.

This volume of the Chemistry Data Series was printed using acid-free paper.

Printed by SchOn & Wetzel GmbH, D-60599 Frankfurt am Main, Germany

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7

Aromatic Hydrocarbons

Benzene

Toluene

Sty re ne

Ethyl benzene

m-Xylene

o-Xylene

p-Xylene

Isopropyl benzene

Systems with:

Propyl benzene

1 ,2,3-Trimethylbenzene

1 ,2,4-Trimethylbenzene

1 ,3,5-Trimethylbenzene

Butyl benzene

p-Cymene

1-Methylnaphthalene

Anthracene

Page 5: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

VI

SUBJECTS OF VOLUME I

The table lists the parts of Volume I already published or in preparation.

Subtitle Vol. I, Part

Aqueous Systems 1 (1980) Supplement 1 1a (1981) Supplement 2 1b (1988)

Organic Hydroxy Compounds Alcohols 2a (1977) Alcohols and Phenols 2b (1978) Supplement 1 2c (1982) Supplement 2 2d (1982) Supplement 3 2e (1988) Supplement 4 2f (1990)

Aldehydes, Ketones, Ethers 3/4 (1979) Supplement 1, Aldehydes 3a (1993) Supplement 1, Ketones 3b (1993) Supplement 1, Ethers 4a (1994)

Carboxylic Acids, Anhydrides, Esters 5 (1982) Supplement 1 Sa (in prep.)

Aliphatic Hydrocarbons C4-C6 6a (1980) Aliphatic Hydrocarbons C7-C18 6b (1980)

Supplement 1 6c (1984) Supplement 2 6d (in prep.)

Aromatic Hydrocarbons 7 (1980) Supplement 1 7a (in prep.)

Halogen, Nitrogen, Sulfur and other Compounds 8 (1984)

Supplement 1 8a (in prep.)

Page 6: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

VII

AUTHORS' PREFACE

With part 7 of our Vapor-Liquid Equilibrium Data Collection appearing now, only parts 5 and 8 are still to be completed. Besides, preparation of supple­ments to parts 1 and 2 has been started. On the whole, we can state to-day, that the amount of work necessary to transform our computerized Dortmund Data Bank (DDB) of vapor-liquid equilibrium data into this printed edition was underestimated by us at the start. So much the more are we indebted to the great number of people who have helped us in various ways. At this point we wish to thank in particular the head of the computer center of the University of Dortmund, Dipi.-Phys. G. Schwichtenberg, and his staff, especially Mr. T. Blaszyk, for their constant co-operation. Likewise we should like to express our gratitude to Dr. R. Eckermann and Chem.-lng. (grad.) C. Hammer (both DECHEMA, Frankfurt/M.) for their efforts in editing the data collection.

Finally, we should like to mention with thanks all members of our team who were engaged in the preparation of part 7 of our VLE Data Collection; these are: Mrs. U. Arlt, Mrs. A. Brunk, Dipl.-lng. P. Grenzheuser, Mrs. G. Hennig, Dipl.-lng. B. Kolbe, Mrs. L. Kunzner, Dr. G. No((on, Mrs. G. Obermann.

As to the contents of the data sheets, an alteration concerning pure compo­nent vapor pressures is to be mentioned here. From this part 7 onwards, in­cluding part 5, the vapor pressures of the pure components from the original VLE data publications are used for data evaluation and parameter fitting, wherever such data are reported in the original VLE data set. For this purpose the first Antoine constant (A) is fitted to these pure component vapor pres­sures, with the two other Antoine constants B and C being taken from our data files for pure compounds, as explained in the General Remarks and Explanations (part 1, p. XXXIX). In case of the Antoine constant A being fitted in this way, it is given at the bottom of the respective data sheet.

Dortmund, August 1980

Ulfert Onken Jurgen Gmeling Wolfgang Arlt

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VIII

PREFACE OF EDITORS

Subjects of this series are the physical and thermodynamic property data of chemical compounds and mixtures essentially for the fluid state covering PVT data, heat capacity, enthalpy, and entropy data, phase equilibrium data, transport and interfacial tension data.

The main purpose is to provide chemists and engineers with data for process design and development. For computer based calculations in process design appropriate correlation methods and accurate data must be used. These are only in some cases available in the open literature. For that reason the most urgent requirement regarding the publication of data is to offer classified and critically evaluated data, thus giving an impression which of them are reliable or not. This will be the goal of the series.

DECHEMA gives the opportunity to authors especially from universities to publish not only their theoretical results, but also their measured or compiled data, most often a large amount, that would otherwise never have been published.

The work of Dr. Gmehling, Prof. Onken and Dipi.-Chem. Arlt on vapor-liquid equilibria which was partly supported by the Federal Ministry of Research and Technology and DECHEMA has been very fruitful; in particular, it led to an extension of the UNIFAC method. The authors have produced what is probably the largest collection of vapor-liquid equilibrium data that is today available with evaluation programs and experimental data.

We present the evaluation of this material in several parts of the first volume of the series. We hope that this gives particularly the users an instrument that will allow them to solve their problems considerably more easily and quickly than before.

Frankfurt!Main, August 1980 Dieter Behrens Reiner Eckermann

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CONTENTS

Vol. I, Part 7

IX

Subjects of Volumes I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VI

Authors' Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII

Preface of Editors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VIII

Contents Volume I, Part 7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX

Contents Volume I, Part 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI

Contents Volume I, Part 2a . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XII

Contents Volume I, Part 2b . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII

Contents Volume I, Parts 3+4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV

Contents Volume I, Part 6a . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XVII

Contents Volume I, Part 6b . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIX

Guide to Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXI

List of Symbols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXXI

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXXIII

Data Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Binary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Benzene ............................................... . Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329 Styrene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445 Ethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 458

m-Xylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 478 o-Xylene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 486 p-Xylene .......... : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 494 lsopropylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 510 Propylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 511 1 ,2,3-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 512 1 ,2,4-Trim ethyl benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 520 1 ,3,5-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 524 Butyl benzene ................................... ,. . . . . . . . . 527 p-Cymene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 528 1-Methylnaphthalene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 530 Anthracene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 536

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X

Ternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 537

Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 537

Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 540

1,2,3-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 541

Quaternary Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 543

Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 543

Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 544

Appendix A: Pure Component Parameters . . . . . . . . . . . . . . . . . . . . . . . . 547

Formula Index of Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 553

Alphabetical Index of Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 559

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553

Formula Index of Systems

R= RECOMMENDED VALUES

2N:J C()-..tPOti!:NT '"3H 0 COM POIH:.NT PAGf 4TH CO"�P�WF.: �T

��=======================================================================================================

SENHNE

PHOSGENE

C CL!.- TETRACHLOPOMLTH\NE

C2H3N

r.H �R3 TP I BR OMOMETH .4 'lE

CH CL r� O!FLUOROCHLORONETHANE

CH CL3 CHLOROFOR�

CH _)I METHYL IODIDE

N ITROME THA NE

CH 4S METHANETHIOL

CS? CARBON DISULFIDl

1,1,�-TRICHLOR0-1,2,2-TRJFLUOROETHANf:

C ��L4 TETR�CHLOROETHYLENE

PHCL3 TRICHlOROETHYLENE

C �H CL5 PENTACHlOROETHANE

C2H2CL4 1,1,2,2-HlRACHLOROETHAH

C�H3CL3 1,1,1-TRICHluROETHANE

ACE TON !TR I lE

1,2-D!BROMOETHANE

C'H4Cl2 1,2-DICHlOROETHANE

C�H5BP ETHYl BRO�IDE.

ETHYl IODIDE

C�!-15NO N-M�THYLFOR�AttiDE

C 2H SN02 N ITRO£THANE

C?H�ClS D!nETHYlSULFJXIDE

ETHYLENEOIA�!NE

, , 1 I 1 ,3 ,3 ,3-HEX AFLLIOR 0-2 -P�OPANOL

c:�t-�7Nn N.N-DIMETHYLFOR�AMIDE

C3H7NO� 1-N !TROPROPAtl E

nH7N07. 2-111 TROPROPANE

t;31f']A03 �ETHYL BOR ATl

THIOPHENE

C�H�02S SULFOLANE

C fH302S 1, 4-TH I OX ANE -S -vX ID£

ACETONITRILE

2- 58 5� •

531-538

59- 61

62- 63

64- 83

84

85- 88 8� R

89

102-111 111 p

112

113-1H 118 R

119

H1

12�-133 15� R

134-137

138-158 158 R

159

1 6•

161-162

163

11e-11�

177

178-1 o4 H4R

185

18�

187

18�-1 �0

190-191

Page 11: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

554

Formula Index of Systems

=�:=== =�===================================================================================�=============

2Nn CO'tPOk[NT

C:)tt6

C ��19NO METHYl �THYl KETQX!M

C 4H 11N B\JTY l �MINE

TERT-BUTYLAMINE

C 4H11 N DIETHYLAMINE

C 5H 5N PYRIDINE

DIETHYlFOR�AHlOE

('...,F6 HEXAFLUOROBE�ZENC

C6H4 CL 2 P-DICHLOROBENZEN�

&ROf'OHNZENE

CHLOROBENZENl

CoH5f flliOROBENZENC

Ct;H)N02 NITROBENZENE

ANILINE

CAH11Cl CHLOROCYCLOHLXA�E

CSH11NO

C-:>H13N CYCLOHEXYLAMl'lE

C�H15N Th IETHY LAM INE

BEtZONITR!lE

C7Ho TOlllEkf:

N-fliETHYLC YCLUtr[):. Yl AM I �E

STYRENE

C }H 10 ET H YLB ENZENE

P-XYlENE

C �H 11 N N,N-DI�ETHYlrti�ILINE

TETRAfTHYL SiLANE

c:Ht2404S 14 OCTo\�fTIHLCYCUHlT��t-.�ILO>.!\�E

l�flPI\OPYlBE .. Zl!i(

PROf'YLSENZENf.

C1 !H 111i BIPHENYL

C 1 iH1ft

"31<[1 CU ... POUEtH 4TH COI'Pf'fiUIT

CdHH

OH10 C9 H1 L

ETfiYLSENZENE

Al�hA-MlTHYLSTYRENE

ISOPROPYLBENZENE

PAGE

199-l�1 ,�,

<05-2t7

208-2>1

222-<'2� >25 p

226-2'7 237 p

B8

239-24?

243-251 ? 51 R

252

253-254

255-26� 2o�

26 7-lH

271

275-277 277 •

278

279-501 301

>39

305

543

H7-H9

3 1 0 -.1 1 1

31l

3H-lH 31� p

517-321

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nT �011PONF.rH

C-:'113

Z�D C0�1PONENT

TOlUENE

CCL4 TETRACHlOROMETHANE

CHCL3 CHlOROFORM

cs: CARBON DISUlFIOE

C !HC l3 TRICHlOROETHYLENE

C�HJN ACETON ITR !LE

C2�3NO METHYL ISOCYANATE

C�H�Cl? 1,2-DICHLOROETHANE

C2H5N02 NI TROETHANE

CZH60S DIHETHYlSUlfOXIDE

C2H<lN2 ETHYLENEDIAMINE

C3H5N PROPION ITR ILE

C3H7NO N, N-OIM ET HYlfORfiA!UDE

C4H4S THIOPHENE

C4H7N 8UTYRONITR!LE

C4H802S SUlfOlANE

C4H11 N DIETHYLAMINE

C5H5N PYHDINE

CSF6 HEXAflUOROBE�ZENE

CoH5BR BROHOBENlENE

C6H5Cl CHLOROBENZENE

CI,H5F FLUOROBENZENE

C6H 5NO� NITROBENZENE

C6H7N AN !LINE

C6H7N 2-HETHYlPYR!DlNE

CoH7N 3-HETHYlPYRIOINE

C6H11NO 6-CAPRO lACTAH

C7H5N BENZONITRllE

C7tl7F 0- FLUOR OTO lUl NL

555

Formula Index of Systems

3RD COHPOUENT 4TH COMPnN[f;T

1,2-DIBROHOETH A NE

PAGE

329-351

351

54t

352-3-53

354-361

362-371

372-375

376

377-384

384

385

386

387

388-389

39t-394

395-396

397

398-399

4 ..

411-4t7

488-414 41 4

415

416-417

418-421 421

422

423-431 431

432

433

434

435

436-439

C 7H?.20�S 13 1,1, 1 ,3 ,5 ,5, 5-HPT AflETHY LT RI S ILOXANE 441-442

C�H10 £THYLBENZENE

C3HH P-XYLENE

STYRENE

C �HCl5 PENTACHLOROETIIA� E

C9HU C9H12

ALPHA-HETHYLSTYRENE ISOPROPYLBENZENE

443

544

444

445

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556

Formula Index of Systems

1ST rQ!lPOt. ENT �N J C0'1POI�ENT

STYRrNE

�CRYLON ITR I U

C3H 1 � ETIIYLBE NZ ENE

C 9H10 A LPH� -METHYL STYR EN L

COil12 P�OPYLBENHN£

C3H1� E THYLBENZENE

CCL4

CH3N ACETONITRILE

1,2-DICHLOROETHjN£

C3�3N ACRYLONITRILE

c ..H 1 111 DIETHYLAMINE

C6H5CL CHtOROBENZENE

C6H5NOc NITROBENZENE

ANILINE

C9H 1 � ISOPROPYLBENZENE

C10Ht4 BUTYL BENZENE

C8H1� M-XYLENE

C Cl4 TETRA CH L O ROM E TH �NE

C.3H7NO N, N-DIMETHYLFORf!AM !DE

C5H5N PYRIDINE

C6H7N ANILINE

P-XYLENE

0-X YL EN E

C CL4 TETRACHLOROMETHAN£

C ?H CL 5 PENTACHLOROETHANE

C ?.H4CL? 1,2-0ICHLOROETHANE

C2H8N2 ETHYL EN EO !AMI NE

C3H7NO 11, N-D IHETH Yl FORMAM I VE

3RD CO MPONENT HH COMPMIENT

PAGE

446

447-45 �

456

457

458-464

465

466

467

468

469

471-475 475

476

477

481

482

483

48b-4d8

489

490

491-492

493 =======================================�================================================= ================

C3f1•

CC L ?Q

C CL4

C�H4CL?.

- .

P-XYL EN E

PHOSGENE

TETRACHLOROMETH.NE

ACETONITRILE

1,�-DICHLOPOETHANE

N,N-D IMETHYLFOR�AMIDE

HEXAFLUOROBENZ[NE

494-495

499

5U

5t1

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P -XYLENE

C S>i 5C L CHLOROBENHNE

ANILINE

I SOPR OP Yl B ENZ EN E

C CL4 TETRACHLOROHETHANE

C9H1� PROPYLBENZENE

C·SH5N02 NITROBENZENE

C9H1 � 1, 2,3 -TR IMETH YLBENZENE

C9H12 1,2,4-TRIMETHYLBENZENE

C9H12 1,3,5-TRIHETHYLBENZENE

1,2,4-TRIHFTHYLBENZENE

1,3,5-TRI�ETHYLSENZENE

1,3,5-TRIMETHYLBENZENE

C<\H1�N TRIETHYLAMINE

CHt114 BUTYL8ENZENE

CSH5NO� N !TROBENZENE

P -CYME N E

C6H 7N ANILINE

1-METHYLNAPHTHALENE

C11H10 2-HETHYLNAPHTHALENE

ANTHRACENE

C1 •H10 PHENANTHRENE

557

Formula Index of Systems

3RO COHPPNENT 4TH COHP�NENT

C9H12 1,3,5-TRIHETHYLBENZENE

HGE

518

5U

511

512-515

541-542

516-519

52a-52�

524-526

527

528-529

5H-535

536

Page 15: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part
Page 16: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

1ST f.OIIPONFNT 2ND COt<'PON EN T

ANTIHI:A C F N E C1 4 H1 0

PHEt<IANTHREN E C14H10

BENZFNE CbH6

AC f TONI TR I LE C2H3N

ANlli�E C6H7N

BENZCN ITR llf C7H S N

BIPHENYL C12H10

BRO�OEI ENZENE C6H 5 B R

BUT YLAf!l lN E C4H11N

lERT-BUHLA�INE C4H11 N

6-CAPROLACTA� C6H11NO

CAR90N Dl SUlfIDE CS2

CHL O ROBENZENE C6H5CL

CHLOROCYCLOHEXANE C 6 H 11 CL

CHLORCFOR� CHCL3

CYCLOHEXYLAMINE C6H13N

1, 2 -DIBRO�OETHANE C2H4BR2

P-DICHLOROBENZENE C6 H4C L2

1,2-DICHLOROETHANE C2H4CL2

DIETHYLAMINE C4H11N

CSH11NO

DJFLVOROCHLORO�ETHANE CHCLF2

C8H 11 N

N ,N -Dl�ETHYlfCRMA�lOE C3H7NO

DI�ElHYLSULfCXIOE C2H6 0 S

ETHYlBENHNE C8H10

ETHYL BROMIDE C2H5 BR

ETHYLENEDIA�INE C2H8N2

fTHYL IODIDE C2HSI

FLUORCBENZENE C6H5F

HEXAFLUOROBENZENE C6F6

1,1,1,�13,3-HEXAFLUOH0-2-PROPANCL C3H2F60

I SOP ROPY l6E NZE NE C9H12

�ETH ANETH I OL CH4S

559

Alphabetical Index of Systems

HO COMPON ENT 4TH COJII!PONENT

IS OP ROP YLB EN ZEN E ALFHA-•ETHYLSTYRENE

CYH12

C9H10

PAGE

536

122-133

133 R

255-266 266 •

278

324-326

239-24 2

199-201

201 R

202-204

271

90-101

243-251 251

267-270

64- 83

272-274

134-137

138-158 158 R

205-207

222-225 22 5 •

62- 63

312

178-184

184 •

164-169

306

159

170-176

160

2 52

226-237 237 R

177

32?

89

Page 17: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

560

Alphabetical Index of Systems

1ST COrtP('INFNT

BfNZE"lf

2ND COMPONFNT

C 6 H6

... ETHYl �OF(P.TE OH %03

�--�T�YLCYCLO�EXYLA�l�E C7H15N

MEl�Yt ETHYl KETOXI� C4H9NO

�-�ETHYLFOR�A�IDE C2H5NO

�ETHYL IODIDE CH3 I

NITROBENZENE C6H5N02

NITROETHANE C2H5N02

NJTROHTHANE CH3N02

1-NITRCPROPANE C3H7N02

2-NIHOPROPANE C3H7N02

CYCLOTETRASILOXANE C8H2404SI4

PENTACHLOROETHANE

PHOSGENE

PROPYLB ENZ ENE

PYRIDINE

STYREH

SULFOLANE

'-TERPHENYL.

1,1,2,2-TETRACHLOROETHANE

TETRACHLOROETHYLENE

TETRACHLORO•ETHANE

TETRAETHYL SILANE

THIOPHENE

1,4-THIOXANE-S-OXIDE

TOLUENE

TRIBROM�ETHANE

1,1,1-TRICHLOROETHANE

TRICHlOROETHYlENE

1,1,2-TRICHLOR0-1,2,2-TRIFLUOROETHA�E

T RI E THYLA>INE

�-XYlENE

P-XYLENE

C2HCL5

CCl20

C9H12

C5H5N

C8 H8

C4H8 02S

C18H14

C2H2CL4

C2CL4

CCL4

C8H20SI

C4H4S

C4H802S

C7H8

CHBR3

C2H3CL3

C2HCL3

C2CL3F3

C6H15N

C8H10

C8H10

3RD COMPONENT 4 TH COM PONE.NT

ACETONITRllf

ETHYLBENlENE

C2H3N

C�H1 0

PAG f

187

302-304

304 •

194-198 198 R

161•162

84

253-254

163

85- 88 88 R

185

186

317-321

119

323

208-2?1

305

190-191

327-328

120

112

2- 58 58 R

537-538

313-316 316 R

188-189

192-193

279-301 301 R

539

59- 61

121

113-118 118 •

102-111 111 R

275-277 277 R

307-309

310-311

Page 18: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

1 ST CMFONENT 2ND CCIIIIPONENl

BUTYLP.E�HNf

NITROPENZENE

P-C Y,.. fNE

�Nil!NE

ET �YlPENZENE

ACETONITRIlE

ACRYlONITRilE

ANILI�E

BUT Yl BEN Z ENE

CHlOROBENZENE

1,2-DICHLOROETHANE

DlfTHYL�MINE

ISOPROPYlBENZENE

NITROBENZENE

TETRACHlORO"ETHANE

I SOP POPYlBH Z EN E

TETRACHlORO"ETHANE

1-�ETHYlNAPHTHALENE

2-METHYLNAPHTHAL[NE

PROP Y lB E NZ ENE

NITROBENZENE

S TYRFNE

ACRYLONITRILE

£THYLBENZ ENE

AlPHA-�ETHYlSTYRENE

PENTACHLOROETHANE

PROPllBENZEN£

A CETONITR ll£·

ANiliNE

B E NZ ONITRJl[

BRO"'OBENlENE

BUTYRONITRILE

C 10H14

C6H5N02

C10H14

C6H7N

C 8 H1 0

C2H3N

C3H3N

C6H7N

C10H14

C6H5Cl

C2H4CL2

C4 H11 N

C9H12

C6H5N02

CCl4

C9H12

CCl4

C11 HI 0

C11 H10

C9H12

C6H5N02

C8H8

C3H3N

C8H10

C9H 10

C2 H Cl5

C9H12

C7H8

C2H3N

C6H7N

C7H5N

C6H5BR

C4H7N

561

Alphabetical Index of Systems

3RD COMPONENT

4TH COMPONENT

PAGE

527

528-529

465

467

471-475

475 R

477

469

466

468

476

470

458-464

510

530-535

511

446

447 -45 5

. 456

445

457

372-375

423-431

431 R

435

415

397

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562

Alphabetical Index of Systems

1ST COMPONENT 2ND COMPONENT

TOLUENE

CARBON DISUlfiOf

CH LOROBENZ£NE

CHLORCFORfl"

1,2-DICHLOROET�AN�

OHTHYLA�INE

N,�-DI�ETHYLFOR�A�JDF

DIMFTHYLSUlfOXIDE

E THYleENZ ENE

FLUOROBENZENE

C-FLUCRCTOLUENE

1,1,1,3,5,S,5-�EPTA�ETHYL­TRISILOXANE

HEXAFLUOROBENZENE

�ETHH ISOCYANAT E

2-METHYLPYRIDINE

NITROBENZENE

NITROfTHANl

PROPION ITR ILE

PYRIDINE

SULFOLANE

TETRACHLOROMETHANE

THIOPHENE

TRICHLOROETHYLENE

P-XYLENE

1,2,3-TRJ�fTHYLBENZENE

1,2,4-TRl�ETHYLB�NZENf

1,3,5-TRI�ETHYLBENlENE

1,2,4-TRl�ElHYLeE�lE�E

1,3,5-TRl"ETHYL6EN2£NE

C7H�

C6H11NO

C S2

C6H5CL

CHCL3

C2H4Cl2

C4H11N

C3H7NO

C2H60S

C8H10

C2H8N2

C6H5 F

C7H7f

C7H2202SI3

C6f6

C2H3NO

C6H7N

C6H7N

C6H5N02

C2H5N02

C3H5N

C5H5N

CCL4

C4H4S

C2HCL3

C8H10

C9H12

C9H12

C9H12

C9H12

C9H12

3RD COMPONENT 4TO COMPONENT

ISOPROPYLBENZENE ALPHA-M�THYlSTYRENF

1,2-DIBROMOETHANE

1,3,5-lRI,ETHllBENZENE

C9H12 C9H10

C2H4BR2

C9H12

PAGE

434

354-361

416-417

352-353

377-384 384 R

400

390-394

386

44 3

544

387

418-421 421 R

436-439

440-442

408-414 414 •

376

432

433

422

385

388-389

401-407

398-399

329-351 351 R

540

395-396

362-371

444

512-515

541-542

516-519

520-523

Page 20: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTIONdechema.de/dechema_media/CDS01Pt07.pdf · Alcohols 2a (1977) Alcohols and Phenols 2b ... Aldehydes, Ketones, Ethers 3/4 (1979) ... With part

1ST CO,..PONUI/1 2ND C01'1PONENT

1,3,�-TRI�F.lHYLP.F.NlfN£

THHlHYlAJt.INE

M.-XYtFJo.E

ANILINE

�,N-Dl�fTHYLFOR�AriDf

PYRIDINE

TETRACHlORO�ElHANE

P-)(YlENE

O-XYlfhf

1,2-DICHLOROETHANE

N,N-DI�ETHYLFOR�A�IDE

ETHYlENEDIAMINE

PENTACHlO�OETHAhE

TETRA CHLOROMETHANE

P-XYLE�E

ACETCNITR llf

ANILINE

CHLOROBENZENE

1,2-D J CHL OR OETHANE

N,N-DIMETHYLFOR�A�IOE

HEXAflUOROBENZENE

PHOSGENE

TETRACHLOROMETHANf

C9H12

C6H15N

C8H1 0

C6H7N

C3H 7NO

C5H5N

CCl4

C8H1 0

C8H10

C2H4CL2

C3H7NO

C2H8N2

C2HCL5

CCL4

C8H10

C2H3h

C6H7N

C 6H5Cl

C2H4CL2

C3H7No

C6f6

Ctl20

CCL4

563

Alphabetical Index of Systems

3RD COMPONENT 4TH COMPONENT

PAGE

524-526

483

481

482

478-480

484-48 5

490

493

491-492

489

486-488

499

509

508

500

501

502-507

so 7 •

494-495

496-498