vacuum pipe cleaner - media.bluestonepim.com · lifting the upper and lower lids. ... eye injuries...
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Wilhelmsen Ships Service AS
VACUUM PIPE CLEANER
Catalogue number: 740498
Version No: 11.33
Safety Data Sheet (Conforms to Regulation (EC) No 2015/830)
Issue Date: 05/05/2016
Print Date: 10/05/2016
Initial Date: 18/04/2016
S.REACH.NOR.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
1.1.Product Identifier
Product name VACUUM PIPE CLEANER
Synonyms 740498
Other means ofidentification
740498
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product CategoryChemical
PC35 Washing and cleaning products (including solventbased products)
Relevant identifieduses
Acid cleaner - Product declaration number offshore: 304539
Uses advised against Not Applicable
1.3. Details of the supplier of the safety data sheet
Registered companyname
Wilhelmsen Ships Service AS Wilhelmsen Ships Service AS*For quotations or productinformation contact your localCustomer Services
Address Strandveien 20 Lysaker 1366 NorwayWillem Barentszstraat 50 Rotterdam3165AB Netherlands
For other suppliers and/or contactdetails please visit our website -https://wssdirectory.wilhelmsen.com/#/networkdirec Norway
Telephone +47 67 58 40 00 +31 10 4877 777 Not Available
Fax Not Available +31 10 4877888 Not Available
Websitehttps://www.wilhelmsen.com/services/maritime/compan
https://www.wilhelmsen.com/services/maritime/compa
https://wssdirectory.wilhelmsen.com/#/networkdirec
Email [email protected] [email protected] Not Available
1.4. Emergency telephone number
Association /Organisation
Giftinformasjonssentralen - 24 timerInternational NCEC (24hr)/Dutchnat. poison centre
Not Available
Emergency telephonenumbers
+47 22591300 + 44 1865 407333 Not Available
Other emergencytelephone numbers
Not Available + 31 30 274 88 88 Not Available
SECTION 2 HAZARDS IDENTIFICATION
2.1.Classification of the substance or mixture
Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods fortransport purposes.
Classificationaccording to
Skin Corrosion/Irritation Category 2, Eye Irritation Category 2
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regulation (EC) No
1272/2008 [CLP] [1]
Legend:1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I ; 3. Classification drawn from ECDirective 1272/2008 - Annex VI
2.2. Label elements
CLP label elements
SIGNAL WORD WARNING
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
Supplementary statement(s)Not Applicable
CLP classification (additional)Not Applicable
Precautionary statement(s) Prevention
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
Precautionary statement(s) StorageNot Applicable
Precautionary statement(s) DisposalNot Applicable
REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
3.1.SubstancesSee 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1.CAS No2.EC No3.Index No4.REACH No
%[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP]
1.5329-14-62.226-218-83.016-026-00-04.01-2119488633-28-XXXX,01-2119846728-23-XXXX
5-10Eye Irritation Category 2, Skin Corrosion/Irritation Category 2, Chronic Aquatic Hazard
Category 3; H319, H315, H412 [3]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I ; 3. Classification drawn from EC
sulfamicacid
Catalogue number: 740498
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Directive 1272/2008 - Annex VI 4. Classification drawn from C&L
SECTION 4 FIRST AID MEASURES
4.1. Description of first aid measures
General
If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
Eye Contact
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.
Inhalation
If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.
Ingestion
For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
4.2 Most important symptoms and effects, both acute and delayedSee Section 11
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4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid onproteins in specific tissues.
INGESTION:Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. Charcoal has no place in acid management. Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes.
DO NOT use neutralising agents or any other additives. Several litres of saline are required. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificialtears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology]
SECTION 5 FIREFIGHTING MEASURES
5.1. Extinguishing mediaThere is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.
5.2. Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
5.3. Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area.
DO NOT approach containers suspected to be hot.
Fire/Explosion Hazard
Non combustible. Not considered to be a significant fire risk. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit corrosive, poisonous fumes.
May emit poisonous fumes. May emit corrosive fumes.
SECTION 6 ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency proceduresSee section 8
6.2. Environmental precautionsSee section 12
6.3. Methods and material for containment and cleaning up
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up.
Major Spills
Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard.
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Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.
6.4. Reference to other sectionsPersonal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
7.1. Precautions for safe handling
Safe handling
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
Fire and explosionprotection
See section 5
Other information
7.2. Conditions for safe storage, including any incompatibilities
Suitable container
Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.
Storageincompatibility
Sulfamic acid:reacts violently with chlorine, nitric acid, fuming nitric acid, strong bases, chlorine, hypochlorous acid, strong oxidisingagents, sulfides, cyanides or when heated with nitrates, nitrites is strongly acidic in aqueous solution hydrolyses to ammonium bisulfate at elevated temperatures is incompatible with alkylene oxides, aliphatic amines, alkanolamines, amides, ammonia, epichlorohydrin, organicanhydrides, isocyanates, metal nitrates/ nitrites, oxidisers, vinyl acetate, common metals and their alloys, water
Contact with metals may result in the evolution of hydrogen (H2) which can form explosive mixtures in air.
Avoid strong bases.
+ X + O + + +
X — Must not be stored together
0 — May be stored together with specific preventions
+ — May be stored together
7.3. Specific end use(s)See section 1.2
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Control parameters
DERIVED NO EFFECT LEVEL (DNEL)
Not Available
PREDICTED NO EFFECT LEVEL (PNEC)
Not Available
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Not Available Not Available Not Available Not Available Not Available Not Available Not Available
EMERGENCY LIMITS
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Ingredient Material name TEEL-1 TEEL-2 TEEL-3
sulfamic acid Sulfamic acid 9.5 mg/m3 100 mg/m3 630 mg/m3
Ingredient Original IDLH Revised IDLH
sulfamic acid Not Available Not Available
8.2. Exposure controls
8.2.1. Appropriateengineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an aircontaminant if designed properly.
8.2.2. Personalprotection
Eye and faceprotection
Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there isa danger of splashing, or if the material may be under pressure.Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properlyfitted.Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; theseafford face protection.Alternatively a gas mask may replace splash goggles and face shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.
Skin protection See Hand protection below
Hands/feet protectionElbow length PVC gloves When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Body protection See Other protection below
Other protection
Overalls. P.V.C. apron. Barrier cream. Skin cleansing cream.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the
computer-generated selection: VACUUM PIPE CLEANER
Material CPI
BUTYL A
NEOPRENE A
VITON A
NATURAL RUBBER C
PVA C
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of theglove, a final selection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequentbasis, factors such as "feel" or convenience (e.g. disposability), maydictate a choice of gloves which might otherwise be unsuitable followinglong-term or frequent use. A qualified practitioner should be consulted.
Respiratory protectionParticulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 ornational equivalent)
Where the concentration of gas/particulates in the breathing zone,approaches or exceeds the "Exposure Standard" (or ES), respiratoryprotection is required.Degree of protection varies with both face-piece and Class of filter; thenature of protection varies with Type of filter.
Required MinimumProtection Factor
Half-FaceRespirator
Full-FaceRespirator
Powered AirRespirator
up to 10 x ES -AUS P2 --PAPR-AUS /Class 1 P2
up to 50 x ES --AUS / Class 1P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acidgas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN),E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3),Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Lowboiling point organic compounds(below 65 degC)
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8.2.3. Environmental exposure controlsSee section 12
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Not Available
Physical state LiquidRelative density
(Water = 1)1.2
Odour Not AvailablePartition coefficient
n-octanol / waterNot Available
Odour threshold Not AvailableAuto-ignition
temperature (°C)Not Available
pH (as supplied) Not ApplicableDecomposition
temperatureNot Available
Melting point /freezing point (°C)
>250 Viscosity (cSt) Not Available
Initial boiling pointand boiling range (°C)
Not AvailableMolecular weight
(g/mol)Not Available
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit(%)
Not AvailableSurface Tension
(dyn/cm or mN/m)Not Available
Lower Explosive Limit(%)
Not AvailableVolatile Component
(%vol)Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water(g/L)
Miscible pH as a solution (20%) 1.1
Vapour density (Air =1)
Not Available VOC g/L Not Available
9.2. Other informationNot Available
SECTION 10 STABILITY AND REACTIVITY
10.1.Reactivity See section 7.2
10.2.Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.
10.3. Possibility ofhazardous reactions
See section 7.2
10.4. Conditions toavoid
See section 7.2
10.5. Incompatiblematerials
See section 7.2
10.6. Hazardousdecomposition
productsSee section 5.3
SECTION 11 TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhaled
The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lungdamage.Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage. Theremay be dizziness, headache, nausea and weakness.
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Not normally a hazard due to non-volatile nature of product
The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This isbecause of the lack of corroborating animal or human evidence.
Ingestion
Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus. Immediate pain anddifficulties in swallowing and speaking may also be evident.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This isbecause of the lack of corroborating animal or human evidence.
Skin Contact
Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowlywith the formation of scar tissue.Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still producehealth damage following entry through wounds, lesions or abrasions.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
EyeIf applied to the eyes, this material causes severe eye damage.Direct eye contact with acid corrosives may produce pain, tears, sensitivity to light and burns. Mild burns of the epitheliagenerally recover rapidly and completely.
Chronic
Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs.Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-termoccupational exposure.
VACUUM PIPECLEANER
TOXICITY IRRITATION
Not Available Not Available
sulfamic acid
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg[1] Eye (rabbit): 20 mg - moderate
Oral (rat) LD50: ca.1450 mg/kg[1] Eye (rabbit): 250 ug/24 h - SEVERE
Skin (human): 4 %/5 days (I)- mild
Skin (rabbit): 500 mg/24 h-SEVERE
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
VACUUM PIPECLEANER
Oral (Rat) LC50: 3160 mg/kg
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to anon-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to highlevels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratorydisease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of adocumented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severebronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, withouteosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalationis an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. for acid mists, aerosols, vapoursData from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when thepH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protectthe cells of the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting thegastric epithelium from its auto-secreted hydrochloric acid. ln considering whether pH itself induces genotoxic events in vivoin the respiratory system, comparison should be made with the human stomach, in which gastric juice may be at pH 1-2under fasting or nocturnal conditions, and with the human urinary bladder, in which the pH of urine can range from <5 to > 7and normally averages 6.2. Furthermore, exposures to low pH in vivo differ from exposures in vitro in that, in vivo, only aportion of the cell surface is subjected to the adverse conditions, so that perturbation of intracellular homeostasis may bemaintained more readily than in vitro.
SULFAMIC ACID
for acid mists, aerosols, vapoursData from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when thepH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protectthe cells of the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting thegastric epithelium from its auto-secreted hydrochloric acid. ln considering whether pH itself induces genotoxic events in vivoin the respiratory system, comparison should be made with the human stomach, in which gastric juice may be at pH 1-2under fasting or nocturnal conditions, and with the human urinary bladder, in which the pH of urine can range from <5 to > 7and normally averages 6.2. Furthermore, exposures to low pH in vivo differ from exposures in vitro in that, in vivo, only aportion of the cell surface is subjected to the adverse conditions, so that perturbation of intracellular homeostasis may bemaintained more readily than in vitro.
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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severeulceration.
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to anon-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to highlevels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratorydisease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of adocumented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severebronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, withouteosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalationis an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance.
Acute Toxicity Carcinogenicity
SkinIrritation/Corrosion
Reproductivity
Serious EyeDamage/Irritation
STOT - SingleExposure
Respiratory or Skinsensitisation
STOT - RepeatedExposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
12.1. Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
sulfamic acid EC50 384 Crustacea 6.40973mg/L 3
sulfamic acid LC50 96 Fish 14.2mg/L 4
sulfamic acid NOEC 1560 Fish 0.025mg/L 2
sulfamic acid EC50 48 Crustacea 71.6mg/L 2
sulfamic acid EC50 72 Algae or other aquatic plants 33.8mg/L 2
Legend:
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOCAquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. VendorData
Harmful to aquatic organisms.
Ecotoxicity:The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines arebetween 6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5
DO NOT discharge into sewer or waterways.
12.2. Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
sulfamic acid HIGH HIGH
12.3. Bioaccumulative potential
Ingredient Bioaccumulation
sulfamic acid LOW (LogKOW = -4.3438)
12.4. Mobility in soil
Ingredient Mobility
sulfamic acid LOW (KOC = 6.124)
12.5.Results of PBT and vPvB assessment
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P B T
Relevant available data Not Available Not Available Not Available
PBT Criteria fulfilled? Not Available Not Available Not Available
12.6. Other adverse effectsNo data available
SECTION 13 DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Product / Packagingdisposal
Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if nosuitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-limefollowed by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in alicenced apparatus (after admixture with suitable combustible material). Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water.
Waste treatmentoptions
Not Available
Sewage disposaloptions
Not Available
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1.UN number Not Applicable
14.2.Packing group Not Applicable
14.3.UN propershipping name
Not Applicable
14.4.Environmentalhazard
Not Applicable
14.5. Transport hazardclass(es)
Class Not Applicable
Subrisk Not Applicable
14.6. Specialprecautions for user
Hazard identification (Kemler) Not Applicable
Classification code Not Applicable
Hazard Label Not Applicable
Special provisions Not Applicable
Limited quantity Not Applicable
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. Packing group Not Applicable
14.3. UN propershipping name
Not Applicable
14.4. Environmentalhazard
Not Applicable
14.5. Transport hazardclass(es)
ICAO/IATA Class Not Applicable
ICAO / IATA Subrisk Not Applicable
ERG Code Not Applicable
Catalogue number: 740498
Version No: 11.33
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14.6. Specialprecautions for user
Special provisions Not Applicable
Cargo Only Packing Instructions Not Applicable
Cargo Only Maximum Qty / Pack Not Applicable
Passenger and Cargo Packing Instructions Not Applicable
Passenger and Cargo Maximum Qty / Pack Not Applicable
Passenger and Cargo Limited Quantity Packing Instructions Not Applicable
Passenger and Cargo Limited Maximum Qty / Pack Not Applicable
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. Packing group Not Applicable
14.3. UN propershipping name
Not Applicable
14.4. Environmentalhazard
Not Applicable
14.5. Transport hazardclass(es)
IMDG Class Not Applicable
IMDG Subrisk Not Applicable
14.6. Specialprecautions for user
EMS Number Not Applicable
Special provisions Not Applicable
Limited Quantities Not Applicable
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. Packing group Not Applicable
14.3. UN propershipping name
Not Applicable
14.4. Environmentalhazard
Not Applicable
14.5. Transport hazardclass(es)
Not Applicable Not Applicable
14.6. Specialprecautions for user
Classification code Not Applicable
Special provisions Not Applicable
Limited quantity Not Applicable
Equipment required Not Applicable
Fire cones number Not Applicable
Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
SULFAMIC ACID(5329-14-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS
European Customs Inventory of Chemical Substances ECICS (English)
European Union - European Inventory of Existing Commercial ChemicalSubstances (EINECS) (English)
European Union (EU) Annex I to Directive 67/548/EEC on Classificationand Labelling of Dangerous Substances - updated by ATP: 31
European Union (EU) Regulation (EC) No 1272/2008 on Classification,Labelling and Packaging of Substances and Mixtures - Annex VI
This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : 67/548/EEC, 1999/45/EC, 98/24/EC,92/85/EC, 94/33/EC, 91/689/EEC, 1999/13/EC, Commission Regulation (EU) 2015/830, Regulation (EC) No 1272/2008 and their amendments as well asthe following British legislation: - The Control of Substances Hazardous to Health Regulations (COSHH) 2002 - COSHH Essentials - The Management ofHealth and Safety at Work Regulations 1999
15.2. Chemical safety assessment
Catalogue number: 740498
Version No: 11.33
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For further information please look at the Chemical Safety Assessment and Exposure Scenarios prepared by your Supply Chain if available.
National Inventory Status
Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (sulfamic acid)
China - IECSC Y
Europe - EINEC /ELINCS / NLP
Y
Japan - ENCS Y
Korea - KECI Y
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredientsin brackets)
SECTION 16 OTHER INFORMATION
CONTACT POINT
- For quotations contact your local Customer Services - https://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 104877775
Full text Risk and Hazard codes
H412 Harmful to aquatic life with long lasting effects.
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.
For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:EN 166 Personal eye-protectionEN 340 Protective clothingEN 374 Protective gloves against chemicals and micro-organismsEN 13832 Footwear protecting against chemicalsEN 133 Respiratory protective devices
Definitions and abbreviationsPC-TWA: Permissible Concentration-Time Weighted AveragePC-STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index
Catalogue number: 740498
Version No: 11.33
Page 12 of 12
VACUUM PIPE CLEANER
Issue Date: 05/05/2016
Print Date: 10/05/2016
end of SDS