use of alternativeuse of alternative cement formulations pres/ieaghg bond presentation... · use of...
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Use of AlternativeUse of Alternative CementCement
FormulationsFormulations
Don GetzlafMarty StromquistMarty Stromquist
Cemblend Systems Inc.
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
WellboreRemoving formationRemoving drill fluidsRemoving drill fluids
Replacing with p gCasing and Cementing
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Portland
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Cement HistoryBentonite
SilicaF
FlyashSilicafumeZ lit
FonduPlasterFoams
LatexZeolites
MetakaolinBeads
Plaster
Beads
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Chemically Bonded Phosphate Ceramics
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Development
ARGONNE NATIONAL LABDeveloped for
Nuclear waste containmentNuclear waste containment
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
DevelopmentArgonne saw benefits in:
• Good mechanical properties• Good mechanical properties• Unleachable
D t d d ti• Does not degrade over time• Neutral PH• Incorporate organics
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
What we saw
Benefits in:• Good mechanical properties• Good mechanical properties• Does not degrade over time• Quick setting• Incorporate organics (OBM)p g ( )• Covalent internal bond
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Mechanic Properties
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Bond TestingBond tests between 200 C and 3150 C are Typically 3 – 5 times higher then Portland.
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
X 250
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
X 250
X 1000IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
X 1000
Strength• Most of the strength is obtained in
first few hoursSli htl di• Slightly expanding
10.5
MC2 vs Premium Microfine Portland 200 C Ceramic vs Portland @ 200 C
7.0
engt
h M
Pa
C i
3.5
essi
ve S
tre MC2
Premium Microfine Portland Cement
MC2CeramicPortland
0.0
0 12 24
Com
pre
Time Hours
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
e ou s
MC2 vs Premium Microfine Portland 70 CCeramic vs Portland @ 70 C10.5
h M
Pa
MC2
Premium Microfine P tl d C t
MC2CeramicPortland
7.0S
tren
gth Portland Cement
3.5
ess
ive S
0.0Co
mp
re
0 12 24
C
Time Hours
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Thickening time lexample
1 % retarder
80
100
120
1 % retarder
20
40
60Bc
00 10 20 30 40 50 60 70 80 90
Time minutes
32 Bc to 100 Bc in 2 minutesBearden units of consistency
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
hOther Properties
• Concentrated filter cake• Compatible with most p
common drilling fluids and Portland cement
• Temperature independence• Broad PH application• Broad PH application
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Latex Permeability yFlyash
Porosity Fondue SilicaPorosity Fondue SilicaPortland Tension
Silicafume SolubilityM t k li C iMetakaolin Ceramics
Beads FibersBeads FibersBentonite Zeolite
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Where have we been~100 remedial jobs completed
Gas migration• Gas migration• Casing repair• Water conformance• Vent repairsVent repairs
Thickening time extended (6 hrs)Thickening time extended (6 hrs)
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
Where are ceramics goingg gPrimary work
ThermalThermalPermafrost
Injection wells
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Do “YOU” have a Do YOU have a question?
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
X 2000
IEAGHG 5th Wellbore Integrity Network Meeting MAY 15th 14 2009 www.cemblend.com
X 25000X 10000