,

}'(~ .. ~/f ,I'fllf

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY. ~

DOUGLAS V. CURTIS HEMDRIX AND DAIL, INC 803 INDUSTRIAL BLVD. GREENVILLE, N.C. 27835

WASHINGTON, D.C. 20460

NOV 2 I 199~

OFFICE OF PREVENTION, PESTICIDES AND

TOXIC Sl.eSTAHCES

Subject: Label Amendment Submission of7/8/94 in Response to PR Notice 93-7 EPA Reg. No. 8853-4 HD-PIC FUMIGANT

Dear Registrant:

The labelillg cited above and submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA). as amended. is accepted. A copy of your proposed labeling stamped "ACCEPTED WITH COMMENTS" is enclosed.

WHAT THIS ACCEPTANCE MEANS:

Based on your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part 156. subpart K. described in PR Notices 93-7 and 93-11. Any other labeling changes submitted in connection with this amendment application but not directly related to compliance with the WPS have not been reviewed or accepted by the Agency. If you wish to make such changes, you must suhmit a separate amendment application proposing them. If your product is currently suspended. the acceptance of this labeling amendment does not affect the suspension in any way.

WHAT YOU NEED TO DO NEXT:

Send t6 EPA one (1) copy of the final printed labeling:

• BEFORE selling or distributing any product bearing the final printed labeling AND • WITHIN one year from date of this acceptance.

Page 2

Submit the final printed labeling via the U.S. Postal Service to:

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs (7505C) U.s. Environmental Protection Agency 401 M Street, SW Washington, D.C. 2046().00()1

Hand or courier deliveries of fmal printed labeling may be made to:

Attachment

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs Room 266A, Crystal Mall 2 1921 Jefferson Davis Highway Arlington, V A 22202

Sin erely,

; ;.gPUIY Chlee gistration Support Branch

egistration Division (7505W)

PRECAUTIONARY STATEMENTS HI\lA.~D TC.tIUMANS

AND DONiEST~C ANIMALS: . . DANGER ... : PELIGRO

• •• • ••• ,... ,.t! __ .· __ • Poisonous liquid an:! v . ~ nuy be faIaI. ~ril is readily lIIidenIIfoabie by srOOiI.~ kI Wf./1oM corc_atiaIs 01 vapor wi cause irriIaIiM to eyeS. nose. and tIVOaL Ca1Ii"lJ9d ~e alter in1tation is _ or tigI1 ooncentratims may caJSe ChlrricaI bIms to skII Of eyes. 00 no! gel OIl skII. in e)'8S. Of OIl CIottWlg. HowrnU or IaIaIIs _.

THIS PROOUCT CONTAINS CHlOROPICRtN WHICH MAY BE IRRITATING TO THE UPPER RESPIRATORY TRACT. AND EVEN AT LOW LEVELS CAN CAUSE PAINFUL IRRITATION TO THE EYES. PROOUCING TEARING. IF THESE SYMPTOMS OCCUR. LEAVE THE FUMIGATION AREA IMMEDIATELY. EARLY SYMPTOMS OF CHLOROPICRIN OVEREXPOSURE ARE LACHRYMATION. I:ESPIRATQRY DISTRESS lIND VOMITING.

AIR CONCENTRATION LEVEL

The aocepoabIo eir"''''lation IoYaIlorpnono ftPOS8dto c:tbopiai. is 0.1 ppm (0.7 rr9m'). The ........ "' .... loYal is _ by 0 <Irec:I reading detection _. ouch as a t.Iatieso:Jn.KUwa.

PERSONAL PROTECTIVE EQUIPMENT

AppIicatOlS and _ hancIe!s rrusI wear. I..oose-titting or __ ad long sleeved sIirIs and long pwots Shoes and Socb FuI-Iaca shield or solely ~ with _ ..-.:I terrc>te shields (00 NOT _goggles.)

When ... """""_ ...... """ .. lilian ..... ia abow 0.1 ppm and 0 raopinotor 10 ntq<iNd, pooIect" oyeo by -r.g 0 ~ reopirator.

No respio_1o racpad .......... """ .......... 01 moIhyt_ .... worIIilg _ illIIMSW8d to flo ........ 0.1 I'P'I'.

A " ... ab iI~"""''''fcIoo.W1g~ • _ .... alrcor_ttrollon _...-10 0.1 ppm al any_ . .......... ..-.:1 __ IIUII_ (0) 0 NOpirator with an organ;o.v.,por........mg COJIridgo _ 0 ~ ~Ior

I""'" i 1M (MSHMOOSH """"",","""'" pefix TCZIC) OR (b) a,._ caniH-approved lor p-tio . 100 (MSHMIIOSH JII)IIItMIi ,...,..,. pnix TC.I4G)

• I .... air concen __ ...-10 4 ppm II any_. JIIlP'o"knand __ IIUII_(a)o~ I8IIpiIMor ~IOSH apprOIII pnix TX.I9C) OR (b) .... -<XJJ1Iainad ...... og ___ ~IOSH approval number pefix TC.I3F)

SAFETY REQUIREMENTS

1. 00 ncI_ jowotry. gm.. goggIoo.1iItot dotWog. ~ proIedive dati1g or~booII_ honrIi1g. a"opiai. iI ..... ..." ... ..-.:Icon flo !lopped iWdo dati1gond ...... iPY. .

2. ~ dati1g..-.:l __ .... __ 1111 '-.been di .. dled or t..wy 0IJI1IaJriW0d _ tio procld. 00 ncI_1Iom.

3. c:ae..PPE ... ..nct.v' ...... Ilmw,.OStj .... Ui .. 'ti ........ norrtcNe..- -*'II. 11-.-,..-.:1 __ doncl_ .....

Ilorou!tI'f --or _ n t 1 KMp 8UCh dati1g..-.:l ohoM CUdoo!1! rnilllorou!tI'f __ Thwt faIaw .. PPE IIW'lAcUWO i1IIruo:Iioni 1or~PPE. ...... ,.,8UChinotru:lionslor w--. ... doIaigo.'..-.:I hcI_. KMp..-.:l_ PPE..-.:I_ dati1g OIIp8IlIIoI'f ""'" ofwloordy. .

4. FotkJw PPE mrnIacture(. ~ lor derri1g hnai-CaiWlg prtJI«:Gva _ • ...,. -. ..-.:I~.

USER SAFETY RECOMMENDATIONS

lJaa<s ohol*I: • __ boIoN --.g. dmIoOlg. dlewi1g epm • .-.g toboc:co. or

•

.-.g,,-

FIemcM doH1g ~ .... c ... 1j '~gata _. n..._ I"oon>u!ttf - 1M on -. dati1g.

.~ c::s L2

LA.-' ,~

CD -= ...... --= --= ~ .... ... -

3 f) flI )

RESTRICTED USE PES DUE TO ACUTE TOXI . ' . . .,

ror relall aalr to and us~ only,';,), .'':e-i'1.rlf d ApjiI',crlors or p direct s.upervlslon, ~rdCl"lty'for U"tOst'~ .... ch ... e·r.cib)':t~'CI certification. • • • : t. •• • .. • :

HD-P~IC FU~ Acllve Ingredienls

ChloropIcrin •.•.•••••.••••..•••• _ .••.••..••.••••...............•....•.•••• Inert Ingredients ..... _ .............................................. _

FOR CONTROL OF CEF SOIL-BORNE PEST:

AND DISEASES

KEEP OUT OF REACH OF C~

DANGER PE

POISON Si Usted no entiende la el'queta. bUSqUE a alguien para Usted en detalle. (If you do not understand the label. find ptaln ~ 10 you in detaiL)

IN ·ALL CASES OF OVEREXPOSURE, GE ATTENTION IMMEDIATELY. TAKE PERSON

OR TO AN EMERGENCY TREATMENT

STATEMENT OF PRACT TREATMENT

In •• COMS of overel!pOlUlO!. get _I lItentlon fti_ to • doctor or emergency Ir .. trnent f.cllfty. IF INHALED: Gel e"""sed porson 10 fresh .~. Koop .. porson c.n brealho freely. II breathing h •• otopp.' rnpImlon. preferably m ... li-I ...... outh. Do net gfYo on)'ll In unconscious person.

IF ON SKIN: tmmedlolety re_ COI'IIImlno1od clothing . lern. covering okll'. Wnh cont.mlnatod .kln ..... lhor end .. ter

IF I~ EYES: Hold eyelkl. open .nd flush wt:h • If .. cty. water tor ., tnst 15 mlnut ••.

Do not Induce voml~'''g CIIl. ph~ Con1rol Cenler Immedlltely. Never give Inythlng unconSCIOUS person.

NOTE TO PHYSICIAN: Chloroplcrtn II • ""latllo liquid Ingroditnt In t ... g ....... gas • Is • """,,'1ul lachryrn.tO' or ov,re'posure Ire Ilchrymitlon, resplf'!Ory d:stre! 1'1 ••• ___ • -...t-____ .• "'_._'--- .... _. ". __ 1 ___ 1 ... ___ _

........ caue •• b.tlcn laVIII .. ceedII4 ppm III MY lime, ",+ .... ani __ must _ (.) a auppIie<HIir

...... "" (MSHAHOSH ~ Pf8b TX.I9C) OR (b) a MII-<XlnIained baatW'II ___ (MSHMj1OSH appIOIIOI ....- proIiK TC-I3F)

SAFETY REQUIREMENTS

I. 00 naI_ joweIoy. gbMa. goggjaa, ~ cioIIW1g. n.t>ber proIedivo ~ ... n.t>ber_when hIndIi'Q. Oobopiuio._t\anair ani con be INpped ilooide ~ and _lIOn rpy. .

2. IliocMI ~ and _ ot.:>oboo~ ...... fill ~beon dodo .. eol<idhfoedod ... ~w ................ tilprocb1. Ooncl_1lem.

3. CIoonPPE_..ncloy'l-. lime' I ·i_W'OIIoO ..... ....... _c:IatW1g...,., and oadaI anddD ncI_1rIIiI ~..-ad ..... 1' rl KMop IUItIcIotIi1gand_ oorloorI unIi~..-d. n-........ PPEnwdocUWa ilIIrucIior8 tar_.~oIaio''II PPE. • __ ... IUItI .......... tar ............ _ j I ""hndhol_. KMopand .... PPEand_ ~~tom_~ .

4. FoIow PPE morU8cUar'. iwIIuctiDna tar daIrWIg hreinIIoio_ 'II praIoIc:Iiw~,""-'anI~

USER SAFETY RECOMMENDATIONS

Uoera should: • WI$h hondo boIo:>N 8IIIi1g. doWcing. dwwilg gI01I. U8ing 1o:lbecIx>. or

IIIilg tlIlOMl

• Aeno\Ie doIIWog imMrlalellll peotic:Ide goIa ilooide. n-wuh ~ and JU on cIoon cIofWlg.

• Aeno\Ie PPE """"eIy alief hancIrog!hie procU:\. AI aoon as possible. wash ~ ani change no dean cIoIhi>g.

DIRECTIONS FOR USE

It is a violatIOn DC F~ral L1w to usa rio; pr-c:rl.Jd in a rnarner inc::onslSltof'lt WIth

ots IabeIoog

00 naI apply !his p<Odud II a way IhaI will a>rIact _ or ..... persons, oiIhor directly or fIrou!tl drift. CJrjy po:lIedod _ may be II ... __ <bi1g application. For any nqioamoo lIS &peeific 10 y<U SIal. or Tri>e. CXln5Ul e. agency ~ lor pesIiQdo ~

1lis UrigonI is • ~ hezardcuI malarial and ohWd be uaed any by __ trained II its proper \Me. BoIont IIIilg. 01I0d ard IoIow allabel JftC8IJiono and ciI ectioo II.

~ ~ -""II .... til bnigorC must be laoowloodgoablo abW!he Iwardo ani nNd ~ ... I""I*-"Ieqlirad equipnWC anI_ .............. ""ocy proceoine and proper _ .. hllmlgonL Whon UI8d lor fInigoIicn" tncIcoed _ (houM ani _1Ir\JC.1uIaI, w ......... -. cIwnberI. ~ 1Nct<s, .... bolCalos,.,.,.. anI_ IiwlIport veticIM, IWD paracn !raNd il .......... til p<Odud ""* be prMOnI_ aI ........ cUilg hlllrt>Wc:lion 0I"1\mgIW1 • .-.g and "IiIIion periods.

00 ncI Urigate with !hie p<Odud _~ .. t"""""" ...... is below 40' F.

PLACARDING OF FUMIGATED AREAS

The ~ (or """""""'" 01 .. oppIo" 0) must pIatard .. a ........ 10 "1IonigaIed --...., Ii!JlII ~

• SIoA ani Co """"'" ... , DANGEM'EUGAO • Atea onIer fImgetion, DO NOT ENTEAINO EtmtE. • o ibopiai I Ft miganI in we, • ... dote ani _ 0I1\rnigotkln. and • nome. _ and toIoiP ... rurber 01 the appIicalor.

00 ""' ..... ertry by ~ peraor-. no ....... "Tiglltrl."'" oroIiI sigls era ~ Such ....... nul my be rarn<J\I9(j when ... air ooncenIrallon ...... cI ctobopiai 0 illo be _ """ 0.1 PI"" SiglO must rernaillegiJie <bIlg ........... pooIilg period. CJrjy a oorttoed appkator (or 1M 0 ...... ...-oor ~ ---.) rTWf rem<Mt wormg Il9'1O at ontrancee 10 Itmgalod 1iIr\Jt1InO.

I . POISON L1)9 / ~ , 5. Usted no enliende la etlquet ... busque a alguien par .. se

USled en delalle, (If you dO nol understand the label, hnd '0 ! pfain it to you in detail.)

IN'ALL CASES OF OVEREXPOSURE, GET I ATTENTION IMMEDIATELY. TAKE PERSON Te

OR TO AN EMERGENCY TREATMENT FA

STATEMENT OF PRACTIC TREATMENT

In .n .... 01 OYe,ellpOSIft. get rnedieal aftentlon Immedtal, 10 0 doctor or emergency tre.tment lactlfty. IF INHALED: Col ._d porson 10 Ite.h .Ir. Keep ... por.on can b, •• II,. 1, •• ly. II br.athlng h ... topped. C ...pratlon. pr.f.rably m .... lHo-mouth. Do no! give an~ an unconacloua potIOn . F ON SKIN: ~oomeclol .. ly,,- OUO"'-ocI ctcIhIng, the ..... covering akin. Wash corotamnted akin a_ Ihoruug and _te,.

F IN EYES: Hold eyelids open and flush with a --.:y. III' Wlter lor .t tetoll 15 minutes.

Do not induce yom:ting. Can a physic: Control Center immediately. Never give anything by unconsc~us person.

NOTE TO PHYSICIAN: Chlorcptcrln Is I ..,tatlle Nquld thai Ingredient In tear gas. As • gu • Is • powerful tachrymator. EI of overtr:posure ate lachrymation, respiratory distress I!

Pulmonary edema "",y develop later. Tr.atment Is symptom

See Side P.net for Add~lonal Precautionary St.te

~-------------------------------

HENDRIX and DAI TELEPHONE (919)75&-4263 1103

So GREENVOUE. NORTH CAROliNA 2

'"'"' NET CONTENTS: .............. Pounds

E.P.A est. EP.A. REGISTRATION

No. 8853--4

CHLOROPICRIN UQUID WEIGHT.13.7POUNDS PER CAUON

\. BESl ~'~~iU~L~ '~~ff1 A(;CEI"IW

"iih f;OM!lIEI'iTS In ,"Y,", ,.,.11,.,. U.trd

NOV 2' 1994 t:ndf't lhl" .'rlff"". In'''t'Ctir.id4''. "·ulMlkld ... An4t Hod,.nlidt~ Act ... M'le.df',t. r('Or Ih,- ~.ll~id~ ,.. ..... t't'd IIntlt'r f: .. ,\ Rr_. No.

8}S}- Sf

RESTRICTED USE PESTICIDE DUE TO ACUTE TOXICITY

for fe-tan Ulf' to IIncl us.:' onlyl.;.,. Cprt~f4d AP ... ·.Cftofs or pt'fsons under thell

direct supervision, ill'l-1~'lty'yOf I~I!' uk.c, c& ... e',ct:by:'t'~ CertIfIed "pphcalor"s certification. • • • • • • • .. . • .. .

HD-P.~IG FUMIGANT

Active Ingredients By W.ight

,

Chloropicrin ..•..•.••..•.....•.••..••...•...••••.........•...•......•••.•.••••••••••.•.......... '6.6\1 Inert Ingr.di.nts .•.•.••.•...••...•..•••..••••...••••••..•.•.•.•••..•. _ •••..•.•••..••..•..•... 3.6\1

Tot.1 100.0\1

FOR CONTROL OF CERTAIN SOIL-BORNE PESTS

AND DISEASES

KEEP OUT OF REACH OF CHILDREN

DANGER PELIGRO

POISON , 5i Usled no enltende la etiQueta. busQue • alguien para se la expliQue a

USled en detalle. (!f you do nol unde'~tand the label, •• rJ(f someone to ex­plain it to you in detail.)

IN'ALL CASES OF OVEREXPOSURE, GET MEDICAL ATTENTION IMMEDIATELY. TAKE PERSON TO A DOCTOR

OR TO AN EMERGENCY TREATMENT FACILITY

STATEMENT OF PRACTICAL TREATMENT

In il cnes of _re,qx.ure, get _I Ittentlon Immedlltely. Tlke pe .. I doctor or .",..rgency t"",_ Ildllly. IF INHALED: :-.et ._d peroon 10 fresh I~. Keep WIIrm. Mike sur. person cln brt.thl 're.ly. " bruthlng hi' 1I0pped, glv. Irlllleill rnp""lon, pr.'.rably mouth-to-mouth. 00 not g"'- Inyllt!ng by mouth to "" unconscious pereon. IF ON SKIN: 1_ .... 1y "'!nOlle _mtnoIed clolhlng. ehoeI, Ind Clther .ems covertng akin. WISh contamlNled Ikln Ira lhonoughly wlh soap and .. ter.

IF IN EYES: Hold eyelids ~ Ind ftush o.1!h I aield)'. gentle stream 01 WIlier for .1 teest 15 m4nutea

00 not Induce vomit,ng Colli. phYSlCiiln Of POison Control ';enler Immediately. Nt'f'!' give anything by mouth to an unconSCIOUS person,

NOTE TO PHYSICIAN: Chlo<oplcrtn Is I ",,'-to. Iquld that Is the Ie"'" Ingredient In te .. gl' AI I gos • Is I powerful '-<hrymotor. flrty symptoms of o'iereXpOsuf' Ire I,chrymltton, resplralory dlslress .nd yom lUng Pulmonory _mo moy develop ,-t.r. Tr .. tment Is symptomatiC.

~ { ~,

PRECAUTIONARY STATEMENTS (CONTINUED).

AGRICULTURAL USE REQUIR£MENTf

Use this product only in accordance wrth "5 IabehF1g Inc: Protechon Standard. 40 CFR 170. This Standard contain! the protection of ag;' cu'tur31 wo"kers I')n.!arm&, ffrresl~ greenhouses, anti :.,ah~(ers 01 \ag,r~llIu'al .~·efiliej( requirements for Irainin'g, rlecon\'I"'oinftioj1. notIf,cdtion. assistance. It also contains specif.c instructions and ext. to the statements in this labeling about personal prOle restriCled·entry intervals, and .... i(,<o ...... to_<5. Tho lhis box only apply to uses " tht~ pC,d~ t.,..oie eov,,, Protection Standard (WPS). : •• : •• : : • • .••• r . No instructions elsewhere on thIS IIDe Ing rell. complying with the requirem.nts 01 thl WPS.

ENTRY RESTRICTIONS Outdoor Soil Fumigation: Entry (including early e otherwise be Plrmnted under the WPS) by any persor correctly Irained and equipped handler who is performins permitted on this "'beling - is PROHIBITED from the stan, 48 hours aner appliCalion. In addition, il tarps Ire used I, non-handier entry is prohibited while t.rps are being rer

NOTIFICATION: Notify workers of the application by wal and by posting lumigant warning signs. as described in II Fumigaled Areas' section 01 this "'boling. Post the lumig instead olthe WPS sign lor this application, but loIlow aH W pertaining to location. legibility, size. and timing 01 posliM{

Outdoor Soil Fumig.tion: Post the lumigant warning si! to trealed areas.

PPE FOR ENTRY DURING THE ENTRY -RESTRICTED P entry that is permined by thIS labeling is listed in the 'Haz and Domestic Animals' section of thIS labeling.

STORAGE AND DISPOSAl STORAGE: Store in a cool, dry. place. well·venlilaled are. key. Post as a pesticide storage area. 00 not contaminatt feed by Slorage or disposal. Persons moving. handling. ( tainers must wear the personal protective equipment (mclu respirator) speCified in the Hazards to Human~ secbon of tN! containers only in well·ventilated area.

DISPOSAL: Close by turning clockwise until had tIght [ and replace safety caps and bonnet.

RETURN OF CYLINDERS

Cylinders are lhe property 01:

HENDRIX AND DAIL.INC. 803 Industri.1 Blvd.

Greenville. North C.roliNl 27634 (919) 758-'1263

Ind should be returned promptly by eollec1 truck lreighl Irom which shipment WlS made. When I cylinder is portio is no lurther requirement lor the product. contact HENDRIX for return Instructions. Pelticide Wlltes Ire toxic. Imprc excess pesticide, Iprly mixture or rjoSite ... v;oIatu)n o' these wastes cannot be di&poMd of by use according to 12! contact your State Pesticide or Envlronmenta' Control Hazardou. Waste representative at the nearest EPA R~ guid.nce.

SHIPPING

This lumigant is <Iassilled in the U.S ~p.r1men1 01 Trln ardous Materials RegulatIons as Chloropicrin. 6 1. UN 158 latlon hazard. Hazard Zone B and no exemptions from spec aging. marking. Of labeling are allowed. Descnbe empty c~ '"g last contained ChloropICrin (InhalatIon Hazard). Do not feeds. or clothing.

WARRANTY DISCLAIMER

NOTfCE: SeHer warrants thai thiS producl conforms to tn. c~ on the llbet and is rC!'asonabfy fll for th@ I''HKN'Ml.'' .... ,aA

I Si USled no entiende la ellQueta, bus-Que a alguien para se la expliQue a : Usted en detalle. (If you do not understand the label, find someone to ex' I p'.in it to you in detail.)

IN'ALL CASES OF OVEREXPOSURE, GET MEDICAL ATTENTION IMMEDIATELY. TAKE PERSON TO A DOCTOR

OR TO AN EMERGENCY TREATMENT FACILITY

STATEMENT OF PRACTICAL TREATMENT

~ it _ 01 overellpOSUf1!. get _t lItentton _latety. Take pe 10 • doctor or ..... rgency treatmenl laclNty. IF INHALED: Get e.:posed penon to 'r •• h .Ir. K_ep warm. M.ke sure person can br.ltt •• IrOlly. " br.lthlng has Itopped. glv. Inlllcll' ~ preIe"b'Y mcdh-lCHnOUlh. Do nat gtve anything by mouth 10 an ....-.. cloua peraon.

IF ON SKIN: ~t.ty ...,.,.. cOlltJunlMled clcllhlng. Ihoes. Ind -...... _rtng Ikln. WISh contlmntecl akin 1_ lhoraughty wlh aolP MId_.r. tF IN EYES: Hold eyelids open Ind ltush wt!h I ateedy. gentle stream 01 _ lor II leaat 15 mIn"'e •.

Do not induce vornit~ng. Call. physician or Poison Control Center immealltely. Never give anything by mouth to an unconscious person.

NOTE TO PHYSICi"'~I; Chlorcplcrtn '" I "" .. tile liquId that Is lhe Icli .. Ingredient In leor gas. A, a gas ft Is I poworfullathrymalor. Early symptoms of overexposure .re lachrymation, res pita tory distress and vomiting. Pulmonary edema mlY de .. top lal.,. Tre.lmenl Is symptomalic.

See Side Pinel For Addftlonal PreeauUonory Sialemonis.

HENDRIX and DAIL, Inc. TELEPHONE (9191758-<263 803 INDUSTRIAL BlVO.

S. GREENVILLE. NORTH CAROliNA 21&30

'"""' NET CONTENTS: .............. Pounds

E.P.A est. E.P A. REGISTRATION

No. 8853-4

11153· fl • I I I I8S3.GA. I I J 11153· NC· I I ~ 11153· ICY • 2 I I 11153· NC • 2 I I

CHLOROPICRIN UQUIO WEIGHT 13.7POUNDS PER GALLON

,\cct;vn;o .. ith COIlt!lIENTS

III t:1'.\ I ... u" .. Uatrd

(JOV 2' 1994 l nd" Ihr .·4>II"r,,1 In .. t'f'ti('.f,, •• t'unctkld ....... 1 Hndf'nlH:i.)t" Act II" .... 'ndr.1. r(lr lh.· ",,,II,.id,, ,.. .... e ..... \Irwin EP,\ K"II' ~o.

8'KS)'- y

HD 7·94

-._. -_.-_. _._-- -I -_ ....... -.~ ..... -- _ •• _. ,._- •• 11·· ....... _ ..... n.~ ...... _ and replace salety caps and bonnet.

RETURN OF CYUNOERS

Cylinders are lhe prope"y of:

HENDRIX AND OAll.INC. 603 Induslrial BM!.

Greenville. Nonh Corow 27834 (919) 7511-4263

! 'l(

and should be returned promptly by collect truck 'reight to the kleaf from whiCh shipment WilS made. When 0 cylinder is partially IuU ond I is no '''''her requirement for lhe product, contact HENDRIX AND OAIL IN 101 return instructions. Pesticide WIIlte. afe toxic. Improper diSPO~1 excess ~.Ucide, spray mixture or rin ... t. is • violation of Federal J.w. lhese wastes cannot be disposed 01 by use according 10 labellnslruc' contact your St.te Pesticide or Environmental Control Agency, or t Hazordous WISI. represenillive lllhe nelrosl EPA Regional Ollice guidance.

SHIPPING

This fumiganl is classified in the U.S. Depar1menl 01 Tronspollalion Ardous Mlterials Regufations as ChloropiCrin. 6. I. UN 1580. Poison·1 lalion hUard. Hazard Zone B and no .xemptions from specificationS. p aging. marking. or labeling are allowed. Describe empty cylinders as ing taSI contained Chloropicrin (Inhalalion Hazard). Do not ship with I feeds. or clothing.

WARRANTY DISCLAIMER

NOTICE: Seller warranls Ihal Ihis producl conlorms 10 lhe chemical on the label and is r.asonably fit for the purposes staled on the label used in accordance with directtons under normal con~rtions of use, but Ihis warranty nor any olher warranty 01 MERCHANTABILITY or FITNESS PARTICULAR PURPOSE. express or implied. oldend, 10 lhe use ollhis contrary to label instructions, or under abnormal condihons, or \M'KIer c not reasonably foreseeable to seller, and buyer assumes the risk of an use.

INHERENT RISKS OF USE: II is impoSSible 10 eliminale all risks A'SOCIII use of this product. Crop injury. lack of performance, or other unin consequences may result because of such factors as use of the contrary to label and label booklet Instructions (including condrtions the label Ind label booklet, such as unfavorable temperatures, 5041 c elc.), abnormal conditions (such as excessive ,alnfall. drought, torn hurneanes), presence of other matenals. the manner of appleabon. all I!'e beyond the control of the company Of the seller AU such risks assumed by Buyer.

LIMITATION OF REMEDfES: The exclUSive remedy for los.e, or d resulting from this product (including claIms bas~d on contract, n~gl sillciliability. or other legailheorie'l. shall 00 lim~ed 10. at lhe company's one ollhe loIlowing: (I) Refund of purchase pllce p",d by buyer or producl bought; or. (2) Replacemenl of al1lOunl 01 prodUCI used. The shan not be liable lor losses or damages resuning from handling or producl unless the company is promptly nolifted of such 10$5 Of da writing. In no ease $hall the company be liable for consequenlial or i damages or losses. Th~ terms of the Warranty Disclaimer above limitatton of Remedies cannot be varied by any wrinen or vlMbal 51afe agreements. No employee or $oales agent of the company or the authorized to vary or e.ceed the terms of the Warranty Dlsc&iime limitatton of Remedies in .ny manner.

l BEST AVAILABLE CD" 1 -~-,- ...

PRECAUTIONARY STATEMENTS (CONTINUED)

AGRICULTURAL USE REQUlREME'lTS

Use thIs product only in accordance ~th its labehng and with the Worker ProtecttOn Standard. 40 CFR 170. This Standard contains requirements (or the protechon of ag:cl.IrI'tu'31 w~kejs .In.!arms., ·'frests. nurseries, and greenhouses, art\:1 !1a~~l\rl o.! ·agri'l::illtu"al.·)·e~licides_ II contains requirements for traininb,. ~econ1~rnin~4~. noftfl~dhon. and emergency assistance It also contains specifIC instructIOnS and exceptions pertaining 10 the statements in this labeling about personal protective equipment. restricted.entry tntervals, and _tjflCati'lt,.to .. ,.~~rs. The requirements in lhis 00. onty apply 10 u~ ~ Ihi( pC.cI~ I~ .,ze coveted by lhe Wor1<er Protection Standard (WPS).:· .: •• : :

No instructions elsewhe;e ';n this ·1 .. L~nng relieve users from complying wilh Ihe requiremenls of Ihe WPS.

ENTRY RESTRICTIONS Ouldoor Soil Fumigalion: Enlry (inCluding early enlry thaI would olherwise be perm~led under Ihe WPS) by any person -. other Ihan a correclly Irained and equipped handler who is performing a handling lask permilled on IhlS labeling - is PROHIBITED from lhe slart 01 applicatlOR unlil 48 hours aner applicalion In addilion. if larps are used for lhe Ipphcalion. non-handler entry is prohibiled while tarps are being removed.

NOTIFICATION: Nolify workers oflhe appllcalion by warning lhem orally and by posling fumiganl warning signs. as described in lhe "Placarding of Fumigaled Areas" seclion of lhis labeling. Posllhe fumiganl _ning sign instead of lhe WPS sign for Ihis applicalion. bulfollow all WPS requirements pertaining 10 Iocalion. legibliitf. size. and liming of posting and removal.

Ouldoor Soil Fumigation: Posl lhe fumigant warning signs at enlrances to treated areas.

PPE FOR ENTRY DURING THE ENTRY -RESTRICTED PERIOD: PPE for entry that is permitted by this labeling is listed in the ~Hazi1rds to Humans and Domestic Animafs- section of thiS labeling.

STORAGE AND DISPOSAL STORAGE: Slore in a cool. dry. place. well·venliialed area under lock and key. Post as a pestiCide storage area. 00 not contammate water, 'ood, or feed by storage or disposal. Persons moving, handling. or opening con· tainers must wear the personal protective equipment (mcluding prescribed respiralor) specified in Ihe Hazards 10 Humans S8C~on of this labeling. Open ",ontainers only In well·yentilated area.

DISPOSAL: Close by turning clockwise un~1 had tight. DisconneCI lines and replace safety caps and bonnel.

RETURN OF CYLINDERS

Cylinders are the property of:

HENDRIX AND DAIL.INC. 803 Induslrial Blvd.

Greenville. North Carolina 27634 (919) 758"263

and lhould be returned promptly by collect lruck freighl 10 Ihe Iocalion from wI1ich shipmenl was made. When I cylinder is partially lug and lhere II no further requirement for lhe prodUCI. conIoct HENDRIX AND DAIL. INC. 'or return InltNctions. Pesticide WIIlt.S Ire toxic. Improper disposal of ueess pesticide. Spray mixture or rinNle ... VIolation of Federal law If lhese wastes cannot bo disposed of by use according 10 label instrucllOns. conllct your Stile Pesticide or Environmen'a' Control Ageney, or Ih~ HUlrdous Waste representative at the neernl EPA. RegtO"lI' Office for Quid.nce.

SHIPPING

Thts fumigant tS classified m the U.S. Department of Transportation !-tal­ardous Materials Regulations as Chloropicrin, 6.1, UN 1580, POIson-Inha­latIon hazard. Hazard Zone B and no exemptions from spec.heabons. pack· aging, marking, Of labehng are allowed. Descnbe empty cyhnders as hav­Ing last contained Chloropterin (Inhalation Hazard) 00 not shiP with foods. teeds. or clothing.

WARRANTY DISCLAIMER

NOTfCE: Seller warrants thai thiS product conforms 10 the chemical descnpllOn on 1M libel ,nd IS reasonably fll for I"'" DurnM .. .." "'aiM 1"1" ..... 1 ...... 1 ", .. ,. ..

HD-PIC OOSAGE RATFS AND METHOOS OF APPUCATIC

crop Manner or Seilling 0,

AJI ClOPS (mcludlng CuN,pac',ing (:. 'I Jler se ... 1 .\85-10

QIMnhous~, nUfsery, and . ." " . . " " ol1'ls.de bed~_ " .

----. ---. .------,.--- . ---Plulec: ("', " 15G-32

Greenhouse beds Ptastk: (A) :Hw

Mushroom Casl~ 5Oi1 M'~I •• pl.., ~laaic ~. ,'WIII\8IINS~<er S.10~

Poning 50~ :'JI:c.:er ~pla~.c i\) : :Hw, ------.--Soodbods-Celory (Flo<ido) : -Valor "t ptashe (A) 1021 b

6wsq

S-...spn.) Waler or pIaslic (A) :H cch

Seed Rat5 pa.slic (A) 2"'cc!t 10wel

(A) &101 '.10"~ a'. obtained by covertng beds "fIIf'Ith • tarpaulin CII' Pil10tlC c~' lOt 24 I tr ... t",.nI A wal.'loUI "' ...... ta.nedfor 24 hour$ItItop orw;;h otW>ol m .. yal1oObe "W'<I -=-_pto

por.ong 10QtI .. rtd Ned rla~ fof 24 ~,.

APPLICATION INFORMATION: For besl results Wllh HD·PIC. soli 51 tiled to II fine, loose condition with the soil temperature at the c apphcallOR preferably between 60" F. and 65' F. Soil should conlOin a mOIsture to support good seed germination. Chisel or ptow sole app should be an uniform streams 10 to 12 inches apart and 6 to 8 Inche the soil surface. When the ptow sGle method is used, disc well a insure the seal by rolling or cultipacking Wdh chisel application culhpacker or Itoa' can follow the chisel bar or these can be pt another closely rollowing tractor.

The soli should nol be disturbed for 14 days following Irealrrenl AI of Ihe .xposure period. aNow the soil 10 aerale compIelely Heavy ra retard dIffUSion of the fumigant, thus requiring II longer exposure Should these conditions occur, taasten aeration by working the SOl

depth of the treatment zone Avoid relnfestalton of treated se contaminated 100ls, equipment, transplants, manure or composts

Fumigation of smart volumes of SOil for seed flats, pottIng 5011, or mu casing soli may be made by injechng lhe proper volu"" of HO·PIC inches deep in a grid pattem nol 10 e.teed 12·,nch spacmg Keep I, on fumigated soil fOl 24 hours.

WARNING AGENT: HD·PIC may be used for cle.ring slruelures fumigating with methyl bromide or sulfuryl fluoride Prepare struel fumigation and wal all except one entrance. Use 1 ounce per 10.00 feet of space to be fumigated. When building is evacuated. seal t entrance and start the fans. Check seals for bghtnft'. FIVe to ten r loler. inlroduee melhyl bromide or sulfuryt nuoide

SOIL FUMIGATION: HD·PIC may be used as a preplanl SOIl fumiganl control of sott·borne diseases such IS VertJcillum, Fus.rium, Rhlzo and Pythium Control or soil-borne grubs. wireworms, nema.,ldes and grass seeds may also be obtained.

AFTER FUMIGATION

Keep pets, livestock, and other domestic animals oul of the treated dUring apphcation. during the exposure period as specified for apphca to O.,ectlOns for use, and duri"O removaJ 01 tarpauh".1f used.

'After fumigatIOn, fuml9ated areaS must be aer.ted unfit the lit concentr. level of c_opic,m IS measured 10 be less lhan 0 I ppm UnN lhe occepo Ilf concentration level IS reached, do nol lilow any person to enter the fumloated .re. unless he/she is wearing the speCified pers protectIve equipment (Including prescribed resplraror) speCified In HazArds to Humans section of this libeling In greenhouses. addl" Wor1{er Protecfton Standard restrichons .pply

Two trained persons must be present dunng remov.1 of the t,rpaull'

l BEST AYAltABLf"Cii)

. ~ ~ .. ·_- . ~ ... and replace salety caps and bonnet.

RETURN OF CYUNDERS

Cylinders ar. Ih. property 01:

HENDRIX AND DAll. INC. 803 Indusl"al Blvd.

Greenville. North Carolina 27834 (919) 756-4263

and should be returned promptly by collect truck freight to the location Irom which shipmenl WlS mad •. When a cylInder is partially lull Ind lhere is no lurther requi<emenl 10< lhe produCI. conloel HENDRIX AND DAll. INC. fOf return instructions. Pesticide wastes Ire toxic Improper dIsposal of excess pesticide. sprly mixture or rinHte IS I violation of Federal Jaw. If lhese Wlsles cannot be disposed 01 by use acco<dlng 10 libel inSlructlons. contlet your State Pesticide or Environmrntal Control Agency, or the Hlzardous Waste representative at the nelrest EPA. Regional Office for guidlnce.

SHIPPING

This fumiganl is classil",d in the U.S. Department 01 Transportation Haz· ardous Materials Regulalions as Chloropicrin. 6.1. UN 1580. "oison·lnha· lation hazard. Hazard Zone B and no exemptions from specifica_. pack· aging. marking. or labehng are allowed. Describe empty cylinders as hav· ing lasl contained Chloropicrin (Inhalation Hazard). Do not ship with foods. leeds. 0< Clothing.

WARRANTY DISCLAIMER

NOTICE: Seller warrants that this product conforms to the chemical descnp!1On on the label and is reasonably fit for the purposes stated on the tabel w!'len used in accordance with directions under normal conclltons of use. but ne-ther Ihis walTllnty nor any other warranty 01 MERCHANTABILITY or FITNESS ~ vR A PARTICULAR PURPOSE. express 0< implied .• ><I.nds 10 lhe use 01 I~,s producl contrary to label instructions, or under abnormal conditions, or uncIer COnd~lons not reasonably foreseeable to seller, and ~uyer assumes the risk' If any such use.

INHERENT RISKS OF USE: It is imPlsslb!e to eliminate all flsks associated ·Nrth use of this product Crop injury, lack of performance. or other uninten::!ed consequences may result because of such factors as use of the pro~:Jct

contrary te label and label booklet instructions (inc!udlr"Q conditions r"ott~ on the label and label booklet. such as unfavorable temperatures. sod condl:'O~S. etc.). abnormal conditions (such as excessive rainfall. drought. torna<:!::es. hurricanes), presence of other matena's. the manner of application. aU of .... hrch a~e beyon1 the control of tne company or the seller All such rrsKs sha.; be assumed by Buyer

LIMITATION OF REMEDIES: TI)e eJlclusiy-e remedy for losses or dar."a;es resulting from thiS product (including claims based on contract. negh;;~~ce. stnct liability. or other legal theOries). shall be hmlfed to, at the compa.,ys elec~ ::'1. one of the follOWing' (1) Refund of purchase pnce paid by buyer or use~ for product bought or, (2) Replacement of amount of product used The cO!T'~any shall not be liable fot losses or damages resuntng from handling cr use of :h,s producl unless the company is prom pity notified of such loss or dama;e In

wriling In no case shaH the company be hable for consequenllal Clf inCIdental damages or losses. The terms of the Warranty Disclalme, above and thIs limitation of Remedies cannot be varied by any written or verbal statement or agreements No employee or sales agent of the company or the seller IS authorized to vary or exceed the terms of the Warranty Disclaimer or th:s limitation of RemedieS in any manner.

- ... -.. -.- -_._. ._.- -.~ --- .......... , ... .. laler. introduce melhyl bromide or su~uryt nuoide. "1' ~ SOIl FUMIGATION: HD·PIC may be used as a preplanl lu cortrol of sOlI-borne cheases luch as Ve",cillufTr. ~us.num. Rlwz and Pythium Control 01 sott·borne grubs. WlreWOfi 1S. nematode and 9r15s seeds may 1150 be Obtained.

AFTER FUMIGATION

Keep pets, hvestock. and other domestIC ammals out of the treate during application, dUring the exposure period as speclfted tor applic In DirecttOns for Use, and dUring reJTl(Wal o' tarpaulin, I' used.

After fumigation, fumtgated areas must be aerated unltl the air cone level of chaoropicrln IS measured to be less than 0.1 ppm Unltl the ac ." concent~tlon level IS reached, do not allOw any person 10 ent the fumig.led .r •• unless he/she is wearing the epecifi.d pe

protective equipment (including prescribed resplrltor) specified Hazards to Humans seclion 01 this labeling. In greenhouses. ad Work .. lIrolection Standard restrictions apply.

Two 11_ persons must be preunt during removal 01 lhe I.rpa

lBEST lVlllUlE ca"1

HOoPlC DOSAGE RATES AND METHODS OF APPLICATION

Crop Manner of Se.lling Dos,age

All Clops (mcludlng , CuMip .. d.tngc:nute. ~ea" • 485-107611I15.JA

greenhou58. nUfsery. and •• •• • •• • • • • • • • • • • outSide bed~\ • • • • .. ...

--~-...,-- .---. • Plasti~ <", • .. • 250-3201 .. JA

GreenhouWl beds Plas.tic (A) ~ccJsq ft

Mu$hfoom easinn soil ~.,w ~a5hC W.,.,. fl8W5DaDfH S-10ecJcu • • • • • • Poning soil 41;1/1.", ~plast.c fII') • ... . .. ~ 3-4ccJsq ft.

S_bod..coiofy (FIord,) :y~\r otpl,sl'" f) • • 10211J5i,ACIf 6CC1sq ft.

S ",ws (Other) w ..... or plastic (A) 3-4 ccJsq. ft.

s.ectnals Plastic (A) 2'" ccJsq II or 10ce/cu'

(~) Best reSIJftt. are otutned by ~OoOelmo be<h """'" • t.fpalJlIn 01' pI.I~t:c cower fQI' 204 ~ aft., treatm.nt ,. ....... 1.fHalma~ IQf 24 ~1n1op Inc;;h 01 $011 ma,. altoo be uWd KftptlrpauhnClrl

PGft""" 5001 al'ld ~ flab lor 24 hoIJrf,

APPLICATION INFORMATION: For besl resuMs with HO·PIC, soil should be tiled to I tine, loose condition with the soil temperature al the depth of applicailOn preferably between 60" F. and 85' F. Soil should conla" adequate motSlure to support good seed germination. Chisel or plow sole applicatIOns should be in uniform stre.ms tOto t 2 inches apart and 6 to 8 InChes below the soil surf.ce. When the plow sole method is used. disc well .nd then insure the seal by rolling or culttpacking With chisel application a roller, cultipacker or float can follow the chisel bar or these can be pulled by another closely following tractor.

The SOlI should not be disturbed for t 4 days following treatment At the end 01 the ekpOSure pe'iod, allow the soil to aerate completely Heavy rains may r~ard diffusi~"'I of the fum;gant, thus requiring a longer exposure period Should these conditions occur, hasten aeration by working the soli to the depth of the treatment lone. Avoid remfestahon of treated SOil from contaminated tools, equipment, transplants, manure or composts

Fumigatoon of sm •• volumes of soil for seed nat., potting SOIl. or mushroom casing soil may be made by injecting the proper volume of HO-PIC 6 to 8 inches deep in a grid pattem not to exceed t2·inch spacing Keep tarpaulin on fumigated soil for 24 heurs.

WARNtNG AGENT: HO-PIC may be used for cleanng structures pllor 10 fumigating whh methyt bromide or sulfuryl fluoride Prepare structure for fumigitlOn and seal all except one entrance. Use 1 ounce per 10,000 cubic feet of space to be fumigated. When building is ev.cu.ted, seal the 1.51 entrance and start the fans. Check seals for tightness. Five to ten minutes tat .. , introduce methyt bromide or sulfuryt nuoide.

SOIL FUMIGATION: HO-PIC may be used as a preplant soil f"'"'9.nt for the control of sait-borne diseases such as Verticilum, Fus.rium, RlHzocton •• lnet Pythium. Control of soil-borne grubs, wireworms, nematodes. weed and g .... leed. may also be Obtained.

AFTER FUMIGATION

Keep pets. westock, and other dornestK: animals out of the treated area during application. during the eJ(posure period as specif.ed for apphcations in Directions for Use. 100 during removal of tarpaulin. if used.

After fumigation, fumigated areas must be RfIIted until the •• r concentration level 01 chloropicrin is me.sured to be less than 0 t ppm UnU the accepl.bIe .w concentration level IS reached, do not allow any person to enter Into the fumlglted .rea unless he/she is wearing the speCified personal protective eqUipment (including prescribed respirator) speCified in the Haz.rds to Humans section of this labeling. In greenhouses, addItional Wo"' .. ProtectIOn Standard restrictions apply .

. Two trained persons must be present during removal of the tarpaulin

Spill and le.k Procedure. for Soli Fumig.tlon

Evacuate everyone from the Immechale area of the spill or leak For Inlo affected area to cOrlect problem, wear the personal prolE equipment (including pr"sc'lDf"d res~llltor ... ) ,"pecifieO.ln the Hazar Humans section of t'lls.la1if!lillg' Move I~ci,king' or ,6a,maged conta outdoors or to an iSvlated location O:'servt. stric: s',Jfety precaul Work upwind. it possible AltoW spilted fum;gant to eVaporate or to al onto vermlcutite, dry sand, earth, or similar absorbent material SUCh mi should be disposed of on site 00: et In .• ~~ro-.:.<l tiisposal facilhy. correctly trained and PPE-.qu\o>peG h~ndl~rs ar! ;permitted to pel such c .... nup. Do not permft ent.")' .-.0 thl""';. or leak are. by any person until the concent~1on at chtO-optc"n is ~ured to be less 0.1 ppm. Report spill to the Nltional Response Center (800-424-8& the reportable qUlN>tKy of tOOO n.. 10 exceeded.

DO NOT SPILL OR DISCHARGE CONTEN­OUTSIDE GROUND COVER

E~RONMENTALHAZARD

This product Is toxic to fISh and wildkfe. Keep out of lakes, stream ponds. Do not cont.minate water by cleaning of equipment or dispo' wastes. Open dumping Is prohibited. Do no! .1Iow HO-PIC or hs vaPC come into contact with any desirable living plants. Avoid spiltlng, dill or otherwise cont.cting HO-PIC with crops In adjacent fields as Injury m.y resuft. Do not apply HO-PIC where there Is little or no air "', or during air inversion condillons.

CHEMICAL HAZARD

HO-PIC may be conoslve under cert.in cond~ions. DO NOT USE WATE clean equipment Flush equipment wMh kerosene or fuel oil. Do not h.ndling equipment or containers made from magnesium alloy. aluml or alkak met.ls. HO-PIC Is a non-flammable liquid.

ted no enllende la e"que~. bu!tQue a alguien para se la explique a I en detaUe. (If you do not understand the label, find someone 10 ex' it 10 you in delall.)

IN'ALL CASES OF OVEREXPOSURE, GET MEDICAL !'ENnON IMMEDIATELY. TAKE PERSON TO A DOCTOR

OR TO AN EMERGENCY TREATMENT FACILITY

STATEMENT OF PRACTICAL TREATMENT

caMS 01 OYerexposu •• 11"' medicll .!len!1on Immedll'ely. T.ke pe doctor or emergency 'rntrnenl 'Icl.y. IHALEO: G.t exposed pe'-On to fr •• h elr. Keep W8fm. Mak •• ur. on c.n bre.'h. Ir •• ly. II brtllhlng h ••• 'opped, gl ••• rtlllcl.1 .. Ion, pr.'.rably rncMlHo-rnCUh. Do not glva an)1h~ by rnouth \0 ~_peraon.

N SKIN: l~oIIy ......... OOi_ed clothing, ahoes, .nd other I _ring akin. Wah 00I'II ....... r.d .kln ... lhoroughly wIIh ... p ... er.

I EYES: Hold eyelids open .nd flush with • lIady, II"nIIe strelm 01 , lor ., IetIII 15 minute •.

Do not induce vomiting. Call I physician or Poison lrol Center immedlltely. Never give anything by mouth to an onscious person.

E TO PHYSICIAN: Chloropicrin Is 0 .. latMe liquid 'hoi Is the oclive dienl In te.r gls. As • gls ft Is 0 ~rfullachrymalor. Elrty symptoms 'erexposure .re Ilchrymation. respiratory distress .nd vomiting. I onary edo'mo rnly develop laler. Trealmenl Is symptomalic.

See .:. ~"'e Panel For Additional ~recau~~~~Stateme:~s .. _ _J

HENDRIX and DAIL, Inc. TELEPHONE (919) 758-4263 eo3 INDUSTRiAl BLVD. S...... GREENVillE, NORTH CAROLINA 271134

NET CONTENTS: .............. Pounds

E.P.A est. . REGISTRATION No,8853-4

CHLOROPICRIN UQUID WEIGH'r 13.7POUNDS PER GALl.ON

,\CCEl'1lill ~ith COIlftlIF.NTS

t" t:P4 I .... " .. r Oalrd

1153· fl - 1 11153· GA. 1 1153· He· 1 11153· KI' - 2 11153· HC - 2

I J

I~ I J I I

i Ji"JV 2 r 19911 HD 7·94

l ndf'l" .hr ""If"rlil Inoot'1"lir';d.'. "·u'Ntlt'ld". a".1 UOI' .. n.id.J, .. ,'\'cl .. " amend..... (or th." pf""th·id .. ,.. .... el"Ml ulul .. r Et",\ ftfOjIII. ~o.

8'KS-';'- V

.... ""' .... _'"_. ~'''''''''""'''1 ", •••.••• '::1 '""U\o"'"'''~ U'U" II"", I'~"I. and replace safety caps and bonnet.

RETURN Of CYUNDERS

Cylinder, are Ihe property 01:

HENDRIX AND DAIl,INC. 803 Industrial Blvd.

Greenville, North Clrolino 27834 (919) 758 .. 263

,t. q ! I( "

and should be returned promptly by collect truck f,eight to the IOCltion Irom which shipment WlS mode. When I cylinder IS portially lUll Ind there is no lurther requirement lor lhe product, conlect HENDRIX AND DAIl, INC. for return instructions. Pesticide Wlstel .r. toxic. Improper dilpoSiI of excess pesticide, spray mixture or rin ... te is I violation of Federal Jaw. If these Wlstes cannot be disposed 01 by use according to label instruclions. contlct your Stat. Pesticide or EnYironmenta' Control Agency, or the Hazardous WI.te represent.tive at the nearHt EPA ReglDnll Office for guidln.e .

SHIPPING

This fumigant is classified in the U.S. Department 01 Transportation Haz· ardous Materials Regulation, as Chloropicrin, 6.1, UN 1580, Poison·lnha· lation hazard, Hazard Zone B and no e.emptionsfrom opecilicalions, pack • aging, marking, 0< labeling Ire aHowed. Describe empty cylinder, as ha •• ing last contained Chloropicrin (Inhalation Hazard). Do not ship with loods, leeds, 0< clothing.

WARRANTY DISCLAIMER

NOTICE: Seller warranls Ihal this producl conlorm. '0 lhe chemical description on lhe label and is reasonably lit 10< the purposes stated on the label when used in accordance with directions under normal conditions of use, but neither this warranty nor any other warranty 01 MERCHANTABILITY or FITNESS FOR A PARTICULAR PURPOSE, e.press or implied. extends 10 the use ollhis product contrary to label instructions. Of under abnormal condrtions. or under conditions not reasonably foreseeable to seller. and buyer assumes the risk of Iny such use,

INHERENT RISKS OF USE: "is Impo'Siblelo elim;nale all risks associated with use of this product. Crop injury, lack of performance, or other unintended consequences may result because of such factors as use of the product contrary to label and label booklet instruchons (includIng conditions noted on the label Ind label booklet. such as unfavorable temperatures, SOil conditions. etc.), abnormal conditions (such as excessive rainfall. drought. tornadoes. hurricanes). presence of other materials. the manner of apphcabon. all of which a~e beyond the control of the company or the seller AU such risks shall be assumed by BlOyer.

LIMITATION OF REMEDIES: The e'clusive remedy lor losse' or damages resulting from this product (including claims based on contract. negligence. stnct liability. or other legal theori!'S). shall be hmllf.'d to. at the companys election. one of the following: (1) Refund of purchase price paId by buyer or user for producl bought: or, (2) Replacement 01 amount 01 producl used. The company shan not be liable for losses or damages resulting from handling or use of thiS product unless the company is promptly notified of such loss or damage in WTrting. In no case shan the company be liabfe for consequential N incte.:~ntal damages or losses. The terms of the Warranty Disclaimer above and this limrtation of Remedies cannot be vaned by any written or verbal statement or agreements. No employee or sates agent of Ihe company or the seiler is authorized 10 vary or exceed the terms of the Warranty Disclaimer or this limitation of Remedies in any manner.

'lARY STATEMENTS (CONnNUED)

AGRICULTURAL USE REQUIREMENTS

roduct onty in accordance wdh its labeling and with the WOlker Stlndard, ~ erR 170. T~'s Slandard c.ontains requirements for teon of agFcu'tunl workers ..,n.!armS( fcresls, nUfseries. and sel, lOt' :.,ar-t4(ers oI'agrit"lIlufal -"eel-heide-s. It contains nts fo< Irainirfg. rfeco",ljIfointtlo1>. no!If~:'tion. and emergency '. " atso contains specifIC instructlOl'ls and excepticn$ pertaining 'ements in this labeling about personal protective equipment. tnlry intervals. and .. lIfIca""".to-,loers. The requirements in 1ly 8ppIy to uses cf thi' pC,du., Ih~ otIe covered by lhe Worl<er Stendllrd (WPS).: •• : •• : :

.. clio"& .Isewhe~e on this·IIL~n~g relieve users from 'I with the requirement. of the WPS.

,STRICTIONS 5011 Fumigation: Entry (inCluding early enlry that would be permnted under Ihe WPS) by any person -- other Ihan a

rained and equipped handler who is performing a handling task :on this labeling - is PROHIBITED frOfn lhe start of applicalion unl~ Iller 8ppIication. In addil/on. if tarps are USed for the application, or errtry is p<ohibiled wh~e tarps are being removed.

ITION: Notify wo<kers 01 lhe application by warning lhem orally sting fumigant warning signs. as descrit:ed in the 'Placarding of I Ar ... • section 01 this labeling. Post the fumiganl warning sign the WPS sign for this application. but follow all WPS requirements to Iocali"", legibility, size. and timing of posling and removal.

Soit Fumigalion: Post lhe fumiganl warning signs at entrances .reas.

ENTRY DURING THE ENTRY -RESTRICiED PERIOD: PPE for is permined by thIS labekng is IIsled in Ihe -Hazards to Humans IStic A",mals' seclion of IhlS labehng.

STORAGE AND DISPOSAL E: Slor. in. coot, dry. place, well-venlilaled .rea under lock and as a pesticide storage area. Do not contaminate water, tood, or lorloe or disposal. Persons moving. handling. Of' opening con­.1St wear the personal protective equipment {including prescnbed I specified in the Hazards 10 Humans section of this labeling Open 5 only in well-venbSated area.

.L: Close by turning clockwise unlil had tight. Disconnecl lines c. safety caps and bonnet.

RETURN Of CYUNDERS

, .re the property of:

HENDRIX AND DAll.INC. 803 Industrial Blvd.

Greenville. North Carolina 27834 (919) 758-4263

,Id be returned p<omptly by collect truck freighl to the local Ion ch shipment .... made. When. cytinder is partiltly lull and lhere ller '*Iuirement for lhe p<oduct, contact HENDRIX AND DAIL. INC. 1"1 Instructions. Pesticide Wlstes Ire toxic. Improper disposal of leslie .. , .~y mixture or rensate is • violabon of Federal JIW If stn cannot be disposed of by use according to tibet instructions. your State P.sticide or Environmental Control Ag.ney, or the IJS Wist. representative at the "e.f"1 EPA Regional omce 'or

•• SHIPPING

ligant is ciassi'led in the U.S. Department at Transportation Hal­.4aterials Regulahons as Chloropicrin. 6.1, UN 1580. POison-lnha­zard. Hazard Zone B and no exemptions from specifICations, pack· .rking, or labeling are allowed. Descnbe empty cylinders as hay­:ontained ChlorOpicrin (Inhalation Hazard). 00 not shIp with foods, , clothing.

WARRANTY OISCLAIMER Sener warrants thai thIS product conforms 10 the c~1 descriphon

HD.f'IC OOSAGE RATES AND MElltODS Of APPLICATION

Crop Manner of S~aling Doug.

48~ 107611~ J" AJI ClOp$. (including , ' .CU"lp~'.i:-'O':' "/t" se:,,". ~ greenhou'!:>e. nuf~e~. and • f f , •••••

1--'0~u1~'~KI~.'.!bed~S!.L' ___ ""';'~--.~_':_-~~:_----_~ 1-_________ ·~P~I.~.~IH!:..!:(\':!~ __ • ___ ·_· ___ • _ _:2=50-3201b'5.J"

Greenhouse beds

Potting soil

S-(0Ih«)

Plastic (A) )...4 W5q "

c •••• IN",", ""pta"c!l'l) • 3-4 cclsq ft.

:1~'rOCpla'hCf) : 10211)5J"0I" 6 cclsq ft.

Plastic (A)

3-4 ccJsq. ft.

2004 wsq " Of

10Wtu •

tA) B.s' results .te otU;ned by ~f.ng beds WIth • larpauhfl 01 plastIC (:Over to! 24 ho~ .ft". tr •• l",-,f'lt A ....at •• SUi m.II'1(.I.-..cI f 01"4 houtt. ."top .nc:tloIloOICm.)'ats-ot. uw<! KHptatpallkn I)n

pofI,rtg SOlI a"'CI w.c! trat'S. tot 24 houl'1o

APPLICATION INFORMATION: Fo< best resull~ with HD-PIC. soil should be tiled to a fine, loose condition with the soil temperature at the depth of application preferably between 60" F. and 85· F. Soil should conlaln odequale moISlure 10 support good seed germination. Chisel 0< plow sole applicallOOs should be in Uniform slreams 10 to 12 inches apart and 610 8 Inches below lhe soil surface Whe, lhe plow sof. method is used. disc wen .nd lhen insure the seal by rolling or cultipacking With chisel application a roller. cullipacker or floal can fotlow the chisel bar or Ih.se can be pulled by another closely following tractor.

The soli should not be disturbed for 14 days following trealment AI the end of lhe .. posure period. allow lhe soil to aerale completefy. Heavy rains may retard dIffUSIon of the fumigant, thus requiring I tonger exposure periOd Should tnese condrtlons occur. hasten aeration by working the soil to the depth of the treatment zone Avoid reinfestalion of treated soil from contaminated tools, C!quipment. transplants, manure or composts.

Fumlgatoo of sma. volumes of soil for seed flats. potting soil, Of mushroom cas'"9 soli may be made by injecting lhe proper volume of HD-PIC 6 10 8 inches d..,p In • gild pa~em not to .xceed 12-inch spacing K..,p tarpauhn on fumlgaled soli fo< 24 hours.

WARNING AGENT: HD-PIC may be used for clearing struclures prior 10 fumigating with methyt bromide or sulfuryl nuoride Prepare structure 'or fumi9itton and seal all ell.cept one entrance. use 1 ounce per 10.000 cubic f..,1 of space 10 be fumigated. Wh.n buHding is evacualed. "" Ihe lasl entrance and slart lhe fans. Check .. als for tlQhlness. Five 10 len minutes laler. inlroduce methyl bfOfnide or sulfuryl nuoid •.

SOIL FUMIGATION: HD-PIC may be used as a p<eplanl soil fumigant for the control of sOII·bome disea'" such _$ Veri/cilium, Fus.rium, Rhilocton., and Pythium Control of soil·borne grubs, wireworms, nematodes, weed and 91l1ss seeds may .tso be obtained.

AFTI'R FUMIGATION

Keep pets, kveslock. and ~Ltler domestic antmats oul 0' the trealed area during appkatton, dur",~ the exposure period as specihed .or applicalions in Directions 'or USf" .. nd durtng removal of tarpaulin, if used.

·AIl .. fumigabon. bmigaled Ireas must be _ated untillhe •• concentralion _ of c_opocrin IS measured to be less lhan 0.1 Pl"". Unllilhe lCGepIabie a., con~nl~tion level is reached, do not .alow any person to enter into the fumig.ted .rea unless he/she is wearing the speCified personal protective equIpment (including prescribed respirator) speCified in the Hazards to Humans secltcn of this labeling. In greenhouses. ~tlOnal Worker Pr~ecllon Slandard reslrictions apply.

.Two lralned persons musl be pr....,t during removal of lhe Ilrpaulin

IlJ . ,

_ ........ _, .w······1111 _. __ ••••. _- w .............. :1 ... .

safety caps and bonnet

RETURN OF CYUNDERS

re Ihe property of:

HENDRIX AND DAll,INC. 803 Induslrial Blvd.

GreenVIlle, North Carolk'll 27634 (919) 758-4263

be returned promptly by collect truck freight to the location ahipmenl .... mlde. When I cylinder IS parlilily lull .nd lhere requirement fo< the product, conloel HENDRIX AND DAIL, INC.

"structions. Pesticide wastes are toxic. Improper disposal of ticide. sprly mixture or r;osite il • violatIOn 0' Feder.l.law. If IS cannot be disposed of by u.e Icco<ding 10 label inslruct"",s. Jr Stlte Pesticide or EnvironlT.entl' Control Agency. or the Wlste representative II lhe nea~est EPA RegIOnal Olfice for

SHIPPING

I,ll is classified in the U.S. Department 01 Transponalion Haz­erills Regulalions as Chloropicrin, 6.1, UN 1580, Poison-Inha­'d, Hazard Zone B and no exemplions from opeeifoe.alions, pack­tin;. Of libeling are allowed. Describe empty cyfinders as ha,,· rained Chloropicrin (Inhalation Hazard). Do nol ship with foods, :>thing.

WARRANTY DISCLAIMER

er warrants that thiS product conforms to the chemical description "lind is reasonably fit for the purposes stated on the label when dance with directions under normal conditions of use. but neither ,0< any olher warranty of MERCHANTABILITY or FITNESS FOR A , PURPOSE, express or implied, extends 10 Ihe use of Ihis producl lei instructions. or under abnormal conditions. or lM'K1er conditions y foreseeable to seller. and buyer assumes the risk of any such

ISKS OF USE: It is impoSSible to efiminate all risks associated With roduct Crop injury. lack of performance. or other unintended s may result because of such factors as use of the product !:leI and label oooklet instructions (including conditions noted on label booklet. such as unfavorable temperatures. sorl conditions. al conditLons (suCh as uceSsL ... ·e rainfall. drought. tornadoes. resenee of other matenals. the manner of apphcatton. all of which 1e control at the company or the seller. All such risks snail be ~uyer.

OF REMEDIES: The exclUSive remedy for losses or damages 1 this product (includrng claims based on contract. negligence . ... other legal theorieS). shall be hmrted to. at the company's electron. lowing: (1) Refund of purchase price paid by buyer or user for ,t; or. (2) Replacement of amount ot product us~. The company Jble for losses or damages resulting from handling cr use of thiS ·5 the company is promptly noftfled of such loss or d Jmage in Clse shall the company be liable for consequential Cli inCidental osses. The terms of the Warranty Disclaimer above and this ~emedie$ cannot be varied by any wntt.en or verbal statement or No employee or sales agent of the company or the seller is Ylry or exceed the terms of the Warranty Disclaimer or this

tentedles in Iny manner.

.··.·_ •• v __ • ____ ••• - • oJ

loler, inlroduce melhyl bromide or sulfuryt ftuoide. ,.:: f ! Y SOIL FUMIGATION: HD-PIC may be used as a ",eplont sod furnoganl fo< Ihe control of soil·borne dfseases such IS V.tfjcijIJm. Fus.n·um. Rhilocton •• and Pythium Control of soil-borne grubs. wireworms. nematodes. weed and g .. ss seeds may also be oblained.

AFTER FUMIGATION

Keep pets. ~\"estock. and other domestic .n",\3ls out of the treal~d ~rea dunng application. durrng the exposure period as specified tor applications In Directions tor Use. and during remov~ 01 tarpaulin. If used.

After rumigation. fumigated areas must be aeraled un'it the IN' concentration level of chloropienn IS measured 10 be lesslhan O. t ppm. Unllilhe accepIible .., concentration level is reached. do not altow .ny person to enter into the fumigated .r •• unle •• he/a he la weering the specified per.onel proleclive equtpmenl (including prescribed respiralo<) speclfted in Ihe Hazords 10 Humans section 0/ this :abeling. In gr_nhouses, addilional Worker Rraleclion Standard resltictions apply.

:rwo trainad persona must be IW .... I during removal ollhe tarpaulin.

fBEsT AVAILABLE can]

- -

~ DOSAGE RATES AND METHODS Of APPLICATION

P Manner of Sealing Dos.ge

ncl""'ng Cuttipao'.ing (:' '4 Jhn SII!I.loI. . 48S-1016tb6JA , " f ••

........ 'V. and • • . . ) , . .

--.. --,--..------~ • paa5ti~ lAj . • • 25().32010.1A

.. - Plasltc: (A) J..4cdoq ft

,_ooil IN.., pI,e. ,.aagie., .... newspapef S.10CGIcu'

" . , • , , i'fa!fH Ofplasllc fII') • J..4cdoq ft.

c • • • •• CeIo<y (F1",Ola) :JYosl,r otpiashC f) • • 1021 .. 1"01'

6C<1oq. ft.

toR-) Water 01 plastic (A) J..4C<1oq. ft.

PI .. I", (A) 2~ ee.'sq." 01 10cclcu. I.

Jub ... CIbU.ned by Ccr.oefl"" bed5 WIth • ~Ipau&.n 01' pta~hC «Nt! lOf 24 hQurs. .litle' ~....., .... m •• nUur>ed IOf 24 hou" .nlop I:"ICI'I of I0OI1 may also be ~SeC:I KHp tlfpilu"l'1 on

aflCI Ned ftatt. tOf 2. !'Iou"

~TION INFORMATION: For besl results Wllh HO·PIC. SOIl should be • fine. loose condition with the soil temperature at the depth of "' prelerably between 60" F. and 85' F. SOlI should cont .. n adequale 10 support good seed g<'rminalion. Chisel or plow sole appllcatioos • in uniform streams to It 12 inches apart and 6 10 8 IflChes below ... rface. When the plow ..,\e method is used. disc well and lhen Ie seal by rolling or cultipacking. WIth Chisel applicalion a roller, ,er or noal can 100Iow Ihe chisel bar or Ihese can be pulled by closely lollowing traclor.

should no! be disturbed lor 14 days 100Iowing treatmenl. At the end rposure period. atlow the soil to aerate complelely. Heavy rains may ffusion of the fumigant, thus requiring a longer exposure peritXL :hese condItions occur, hasten aeraHon by working the soil to the f the treatment lone. Avoid reznfestation of treated 5011 from ,.ted tools, eqUipment, transplants, manure or composts.

on 01 small volumes 01 sOlI lor seed nats. potting soil. or mushroom oil may be made by injecting lhe proper volume 01 HO·PIC 6 to 8 eep in I gtid pattern no! to exceed 12-inch spacing Keep tarpaulin ""ed soil lor 24 hours.

IG AGENT: HO·PIC may be used lor Clelring structures prior 10 no with methyl bromide or sulfuryl nUOfide. Prepare structure for '" and seal aft except one entra""... Use 1 ounce per 10.000 cubic opace to be lumigated. When building is evacualed. seal the last ! and stlrt the fans. C~eck seals ~or tightness. Five to ten minutes roduce melhyl bromide or sutluryl nuoide.

IMIGATION: HO·PI'; may be used as • preplanl soil lumigant lor the .f lOit-bome disease:. s'.Jch as Verticllium, Fus,rium, Rhizocton., hium. Coni.rol of soil-borne grubs. w;reworms, nematodes, weed IS seeds may liso be oblained.

AFTER FUMIGATION

ta, livestock, and other domestic a!'limals out of the treated area ~tion. dUring the exposure perKKI as speCified for applications tuns for Use, and during removal of tarpauhn, If used.

>igItion. lumigated Ifeas must be aerated until the IW concer.Iratioo hIoropicrin is me .. ured to be less than 0 1 ppm Unt~ the accept_ entflltion level is reached. do not allow any person to enter into 19ated area unless he/she is wearing the specihed personal ,. equipment (including prescribed respirator) speCified in the i to Humlns section of this iabeling. In greenhouses, additional Protection Standard restrictions Ipply.

ned persons must be present during removal of the tlrpaulin.

-------------------------------------------------------------,

Spill Ind Leak Procoduru 1<>< Soli Fumiglllo~

Evacuat. everyone from the Immechate area of the spill or leak For entry Into affected area to correct problem, welit the personal protective equipment (Including pr,,"sc';Df'd res~irator.~) <IOpecified In Ihe Hazards to '"Iumans section of ~",s laj.tll,lg' M,ove lea,king'or,Ga,maged containers outdoor. or to an Isvlated'locltion.' OllserV(. strice; sufely precautions Work upwind. il possible A.o.;. .piIIed lumiganl 10 e';"porale or to absorb onlo vermlcul'e, dry sand, earth, or similar absorbent malerial. Such material should be disposed 01 on site ~ ~t In I'pgro~ lIisposal IlCil~y. Only correclly lralned and PPE -equJi>pecf ~nd'irs ... , !Dermilted to perform .uch cleanup. Do no! permit ent:} 1:-::0 tlYl'a;>i" or klk Ifea by Iny other person untn the concernmion of. chki'opIcrki Is.",..;ured to be less lhan 0.1 ppm. Report .pIIl to the NIIionII Response Center (800-424-8802) • the reportlble quant~y 01 1000 I .... Ia exceeded.

DO NOT SPILL OR DISCHARGE CONTENTS ~UTSIDE GROUND COVER

EN\IIRONMENTALHAZARD

This product Is toxic 10 fish and wildlile. Keep out 01 lakes. slreams, or ponds. Do no! contaminlte water by c'.aning 01 equipment or disposal 01 wastes. Open dumping Is prohibited. Do not atlow HD-PIC or ~s vapors 10 corne into contact with Iny desirable living plants Avoid spiling, drippIng or olherwlse contacling HO-PIC wilh crops In adjacenl Ileids as planl Injury may resuK. Do not apply HD-PIC where there Is lottie or no air moving or dur1ng air inversion conditionS.

CHEMICAL HAZARD

HO-PtC may be corrostve under certain cond~ions. DO NOT USE WATER 10 clean equtpment. Flush equipmenl w~h kerosene or luel oil. Do not use haNlling equipment or conlainers made Irom magnesium altoy, aluminum, or .-metals. HO·PIC Is a non·namIMbie liquid

_ .. - .. - .. ~ .~ - - -_ .. --_.- ...... ~ ........... -.............. . >duee melhyl bromide 01 sulfuryl nuoide.

ItIIGATION: HO-Ple may be uoed IS I preplanllOilfumiganlfOf lhe , _.borne dis.ases such IS V.t&cilium, Fus.rium, Rhizoc:ton •• ';Um. Control of soil· borne grubs, wireworms, nemltode., weed • steds mly Iiso be obtained.

AFTER FUMIGATION

s liveslock, and oiher domeslic animals oul of !he trealed area p'he.tlCn, during the exposure period as specified for appltcations )ns'OI Use, Ind during removal of tarpaulin, if used.

ogattOn. fumigated .,eos musl be ler.led unt~ lhe lir concentration "o'op!Cnn IS measured 10 be res.lhan 0.1 ppm. Unl~ lhe acceptable nU'lbOO level is reached. do not allow any person 10 enter into g.ted .r •• unlea. he/.he i. we.ring the apecified person .. ~ equipment (inCluding prescribed respirator) specified in the 10 Hu",.". seclion 01 this labeting. In greenhOUSes, additional Itolection Stlndll'd ,est,ictions Ipply.

ed persons must be pr_t dUring ,e""",11 of the tlrpaulin

POISON GAS