university of south alabama · amount of disorder to them (e.g., “saddle” dolomite) and in some...
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GY 302: Crystallography & Mineralogy
UNIVERSITY OF SOUTH ALABAMA
Lecture 6: Polymorphism and Crystal
Habit
Instructor: Dr. Douglas Haywick
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Online Lecture Review
1. Polymorphs and Polymorphism 2. Pseudomorphs and other definitions
3. Crystal Habit
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Polymorphs & Polymorphism Polymorphism: literally translates as “many forms” In crystallography/mineralogy, it generally means that one mineral can exist in more than one crystal form under certain conditions (normally pressure/temperature).
Crystal forms of fluorite versus temperature (this is not polymorphism. It is only a change of Crystal Habit)
http://www.clmc.bas.bg/minsoc/Crystal-morphological-evolution/Fluorit.jpg
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Polymorphs & Polymorphism Polymorphic transformations can occur in one of 3 ways: 1) Reconstructive: requires extensive breaking and recombining of chemical bonds in the crystal lattice. This transformation generally occurs only when the pressure/temperature threshold is reached and may be very slow*. * really slow transformations may produce long-lived metastable Polymorphs (e.g., diamond)
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Polymorphs & Polymorphism Polymorphic transformations can occur in one of 3 ways: 2) Displacive: requires relatively minor changes in the crystal lattice (e.g., modification of α, β or γ angles). There is generally no change in energy at the transformation threshold so polymorphic transformations are instantaneous and reversible. No metastable polymorphics exist (e.g., α-quartz and β-quartz)
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Polymorphs & Polymorphism Quartz has 6 polymorphs related to pressure and temperature
β -quartz
α -quartz
If you heat “quartz” above 600 ºC it transforms to the β- polymorph (also known as high quartz). When the temperature falls below 600ºC it transforms back to the α- polymorph (also known as low quartz).
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Polymorphs & Polymorphism Polymorphic transformations can occur in one of 3 ways: 3) Order-Disorder transformations: all crystals have a certain amount of disorder to them (e.g., “saddle” dolomite) and in some cases, polymorphic transitions can occur once an appropriate level of order-disorder is attained.
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Polymorphs & Polymorphism
Well ordered dolomite CaMg(CO3)2
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Polymorphs & Polymorphism
Less well ordered dolomite CaMg(CO3)2
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Polymorphs & Polymorphism
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Polymorphs & Polymorphism
CO32- “planes”
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Polymorphs & Polymorphism
Ca2+ cations
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Polymorphs & Polymorphism
Mg2+ cations
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Polymorphs & Polymorphism
Mg2+ cations
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Polymorphs & Polymorphism
Mg2+ cations
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Polymorphs & Polymorphism
Mg2+ cations Strained extinction
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Polymorphs & Polymorphism Polymorphic transformations can occur in one of 3 ways: 3) Order-Disorder transformations: all crystals have a certain amount of disorder to them (e.g., “saddle” dolomite) and in some cases, polymorphic transitions can occur once an appropriate level of order-disorder is attained. But… … there is no threshold temperature or pressure for the transformation. e.g., potassium feldspars
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Polymorphs & Polymorphism
KAlSi3O8
Sanidine Orthoclase Microcline (triclinic) (monoclinic) (monoclinic) High Temperature Low Temperature
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Polymorphs & Polymorphism Examples of Polymorphs: 1) C- Diamond-Graphite
(Reconstructive)
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Polymorphs & Polymorphism Examples of Polymorphs: 2) Al2SiO5
Kyanite-Sillimanite-Andalusite (Reconstructive)
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Polymorphs & Polymorphism Examples of Polymorphs: 3) SiO2
(all reconstructive except α to β quartz)
Cristabolite: isometric Tridymite: hexagonal α, β: hexagonal Coesite: monoclinic Stishovite: tetragonal
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Other Crystal “Structures” Metamict Minerals: crystals with partially “nuked” lattices (e.g., zircon; Zr(U,Th)SiO4). Mineraloids: Amorphous minerals that do not have crystalline form (e.g., limonite: FeOOH·nH2O) Pseudomorph: A mineral which has the crystal form of another mineral (nasty, sneaky minerals in disguise)- several types
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Other Crystal “Structures” Pseudomorphs: Form due to one of three mechanisms:
Dolomite crystals mimicking aragonite http://www.mindat.org/gallery-4223.html
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Other Crystal “Structures” Pseudomorphs: Form due to one of three mechanisms: 1) Substitution: molecule by molecule replacement of one mineral by
another (e.g., quartz replacement of aragonite) 2) Encrustation: a coating of a new mineral top of an existing mineral
(then the first mineral is dissolved; e.g., hematite on pyrite) 3) Alteration: Partial removal of one mineral and infilling by a second
can also result in pseudomorphing (e.g., anhydrite in gypsum)
Terminology: anhydrite pseudomorphed after gypsum
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Mineral Habits Habit: The external appearance of a mineral (not necessarily the same as crystal form) e.g., malachite Cu2CO3(OH)2 (monoclinic: 2/m)
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Mineral Habits Habit: The external appearance of a mineral (not necessarily the same as crystal form) e.g., malachite Cu2CO3(OH)2 (monoclinic: 2/m)
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Today’s Homework 1. Assignments 2 and 3 now next week
2. SI Session request by email (first come; first serve) 3. Study and organize: crystallography exam (take
home) issued next Tuesday
Next Time
1. Optical Microscopy
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GY 302: Crystallography and Mineralogy
Lecture 6: Polymorphism and Crystal Habit
Instructor: Dr. Doug Haywick [email protected]
This is a free open access lecture, but not for commercial purposes.
For personal use only.