unioleo fa c1299 - unilever oleochemical indonesia | · pdf file ·...
TRANSCRIPT
UNIOLEO FA C1299 Issuance Date: 1-Dec-14 Revision Date: Nov-15 Version: 1511/1501
Material Safety Data Sheet SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Product Name: Product Description: CAS Number: Formula:
UNIOLEO FA C1299 Lauric Acid 99% 143-07-7 C12H24O2
1.2 INTENDED USE OF THE PRODUCT
Use of the Product: Soap & Detergents, Personal Care & Toiletries, Textiles, Rubber/ Plastic Additives.
1.3 SUPPLIER DETAIL
Manufacturer: Address:
PT Unilever Oleochemical Indonesia Industrial Estate of Sei Mangkei Huta VI Sei Mangkei Bosar Maligas, Simalungun North Sumatra 21183-Indonesia
1.4 EMERGENCY CONTACT
Emergency Telephone: Quality Department: Tel. +62-6226979000
SECTION 2 : HAZARD IDENTIFICATION
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
GHS Classification: Information concerning particular hazard:
Serious eye damage (Category 1) H318 Xi, R41
2.2 LABEL ELEMENT
Pictogram:
SECTION 2 : HAZARD IDENTIFICATION contd.
2.2 LABEL ELEMENT
Signal word: Danger
Hazard statement(s): H318: P218:
Causes Serious eye damage. Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) P305 + P351 + P338:
IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 OTHER HAZARDS
This substance/mixture contains no components considered to be either persistent, bio-accumulative and toxic (PBT) or very persistent and very bio-accumulative (vPvB) at level of 0.1 % or higher.
SECTION 3 : COMPOSITION/INFORMATION OF INGREDIENTS
3.1 COMPONENT
Synonyms: Formula: Molecul weight: CAS No: EC No:
Lauric Acid/Dodecanoic Acid C12H24O2 200.32 g/mol 143-07-7 205-582-1
SECTION 4 : FIRST AID MEASURES
4.1 DESCRIPTION OF FIRST AID MEASURES
General Advice: Inhalation:
Skin contact: Eye contact: Ingestion:
Consult a physician. Show this safety data sheet to doctor in attendance. If breath in, move person into fresh air. If no breathing, give artificial respiration. Consult a physician. Wash off with soap and plenty of water. Consult a physician. Rinse opened eye for several minutes under running water. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
The most important known symptoms and effects are described in the labelling and or section 11.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
No data available.
SECTION 5 : FIREFIGHTING MEASURES
5.1 EXTINGUISHING MEDIA
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or CO.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Fire Hazard: Carbon oxides
5.3 ADVICE FOR FIREFIGHTERS
Wear self-contained breathing apparatus for fire-fighting if necessary.
SECTION 6 : ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8.
6.2 ENVIRONMENTAL PRECAUTIONS
Avoid discharge into drains, water course or onto the ground.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
Pick up and arrange disposal without creating dust. Sweep up and shovel. Collect leakage in sealable containers, soak up with sand or other inert absorbent and remove to safe place. Wash site with sodium bicarbonate solution or soda ash. Can also allow spillage to solidify, then shovel into containers. Clean up area immediately.
SECTION 7 : HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Store in cool place. Keep container tightly closed in a dry well-ventilated place. Storage class (TRGS 510) Non Combustible Solids Storage temperature: at maximum 35°C Suitable material for storage: In flake, laminated paper bag. Exposure to ultraviolet light and sunlight must be minimized to prevent quality loss.
SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
No Occupational Exposure Limits (OELs) have been establish for this product or its chemical components.
8.2 EXPOSURE CONTROLS
Appropriate engineering controls: Emergency eye wash should be available in the immediate vicinity or any potential exposure.
Personal Protective Equipment: Safety glasses
Dust formation
Dust mask
Eye/Face protection: Skin protection: Respiratory protection Other Information:
Safety glasses or chemical goggles. Chemically resistant protective gloves are recommended. In case of inadequate ventilation wear respiratory protection When using, do not eat, drink or smoke.
SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Appearance: Odour: Odour Threshold: pH: Melting point: Freezing point: Boiling point: Flash point: Evaporation rate: Flammability (solid, gas): Upper/lower flammability or explosive limits: Vapour pressure: Vapour density: Relative density: Water solubility: Partition coefficient : n-octanol/water: Auto-ignition temperature: Decomposition temperature:
Solid. White crystalline. Characteristic, like oil of bay. No data available. Not applicable. 44 – 46°C No data available. ca. 225°C at 100mmHg 160°C-open cup No data available. The product is not flammable. No data available. >= 0.00141 mm Hg at 15°C No data available. 0,883 g/cm3 at 25°C 4.81 mg/L at 25°C log Pow 4,6 at 20*C >250°C No data available.
SECTION 10 : STABILITY AND REACTIVITY
10.1 REACTIVITY 10.2 CHEMICAL STABILITY 10.3 POSSIBILITY OF HAZARDOUS REACTIONS 10.4 CONDITION TO AVOID 10.5 INCOMPATIBLE MATERIAL 10.6 HAZARDOUS DECOMPOSITION PRODUCTS
No data available. Stable under recommended storage conditions. No data available. No data available. Bases, Oxidizing agents. No data available. In event of fire : see section 5.
SECTION 11 : TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Acute toxicity LD50 Oral-rat: LD50 Dermal-rat: LC50 Inhalation-rat:
> 5000 mg/kg bw > 2000 mg/kg > 0.1621 mg/L air (nominal) , duration : 4 hours, vapour
Skin corrosion/irritation: No skin irritation-24 hours (rabbit).
Serious eye damage/eye irritation: Irritating.
Respiratory or skin sensitization: No sensitising (guinea pig)
Germ cell mutagenicity: No data available.
Carcinogenicity: No data available.
Reproductive toxicity: No data available.
Specific target organ toxicity= single exposure:
No data available.
Specific target organ toxicity= repeat exposure:
No data available.
Aspiration hazard: No data available.
Additional Information: RTECS : OE9800000
SECTION 12 : ECOLOGICAL INFORMATION
12.1 TOXICITY
LC50 Fish EC50 Invertebrate EC50 algae
EC50 Microorganism
5 mg/L (exposure time : 96 h, Species : Oryzias latipes, semi-static test) 3.6 mg/l (exposure time : 48 h, Species : Daphnia magna) > 7.6 mg/l (exposure time : 72 h, Species : Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) > 1000 mg/l (exposure time : 30 min, Species : Pseudomonas putida)
12.2 PERSISTANCE AND DEGRADABILITY
Biodegradability: 86% readily biodegradable in water (exposure time : 30 days)
12.3 BIOACCUMULATIVE POTENTIAL
No data available.
12.4 MOBILITY IN SOIL
No data available.
12.5 OTHER ADVERSE EFFECTS
Toxic to aquatic life. Avoid release to the environment.
SECTION 13 : DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Waste disposal recommendation: Disposal must be made according to official regulation. Do not dump into any sewers, on the ground, or into any body of water.
SECTION 14 : TRANSPORTATION INFORMATION
14.1 UN NUMBER
Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:
Not regulated. Not regulated. Not regulated.
14.2 UN PROPER SHIPPING NAME
Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:
Not applicable. Not applicable. Not applicable.
14.3 TRANSPORT HAZARD CLASS(ES)
Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:
Not applicable. Not applicable. Not applicable.
14.4 PACKAGING GROUP)
Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:
Not applicable. Not applicable. Not applicable.
14.5 ENVIRONMENTAL HAZARDS
Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:
No No No
14.6 SPECIAL PRECAUTIONS FOR USE
No data available.
SECTION 15 : REGULATORY INFORMATION
INVENTORY LIST
Listed in TSCA, DSL, EINECS, NZIoC, PICCS, AICS, IECSC, ENCS, KECI.
SECTION 16 : OTHER INFORMATION
MSDS updated on: Nov-15
MSDS creation date: 1-Jan-15:
MSDS No: UOI-MSDS-QA-007