unfolding the potential of mechanical activation for fly ... (1).pdf · is1489-91 is:1489-91...
TRANSCRIPT
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Unfolding the Potential of Mechanical
Activation for Fly ash Geopolymer
Sanjay KumarCSIR-National Metallurgical Laboratory
Jamshedpur 831007, India
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Founded in 1950 by Pandit Jawahar Lal Nehru, First PM of India
Research mandate is Minerals, Metals, Materials and Waste
Website: www.nmlindia.org
CSIR-National Metallurgical Laboratory
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Fly Ash
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Geopolymerisation
Science of
making artificial
stone at ambient
or near ambient
temperature
Geopolymers are inorganic binder
which result from geosynthesis, i.e.
reaction between alumino-silicates
and oxides in alkaline media
yielding 3-dimensional polymeric
framework. It is represented by
following equation:
Mn [ – (Si – O2)z – Al – O ]n . wH2O
M : Alkaline element,
‘–‘ : Presence of a bond,
z : 1, 2 or 3, and
n : degree of polymerisation
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Why Fly Ash for Geopolymer
Desirable properties
Alumino-silicate composition,
Al:Si ratio in desirable range
for geopolymerisation
Consists of glassy and
crystalline phase, glassy
phase reacts with alkali
solution
Good flow properties due to
spherical shape
Easy & cheap availability
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Reactivity of Fly Ash in Geopolymer
Guided by the amount of
reactive glassy phase, which
undergoes dissolution in
alkali solution
Influenced by the particle
size, finer particles have
better reactivity
The crystalline phases such
as quartz and mullite remains
unreacted
Mechanical activation
is promising solution
to alter fly ash
reactivity
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Mechanical Activation
Gastroliths
Dinosaurs eats stone to grind tough food for
easy digestion
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Mechanical Activation
Grinding and Mechanical Activation
Grinding time, h
Deg
ree
of d
ispe
rsio
n
AgglomerationAggregation
Rittinger Stage
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Mechanical Activation
Bulk Activation
• Crystallite size
• Lattice distortion
• Phase transformation
• Exchange reactions
• Amorphization
Milling Dynamics
• Stress mechanism
• Stress intensity
• Stress number
(frequency)
• Environment (Dry or
wet)
Surface Activation
• Surface area
• Fresh surface
• Surface topography
• Surface modification
• Surface charge
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Mechanical Activation of Fly Ash
What changes occur
Increase in surface area
Stresses and defects in solid structure
Fracture leading to dynamic creation of fresh surfaces for
reactions etc.
Energy storage in defect which releases during alkali activation
leading to faster reaction
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0.1 1 10 100
0
20
40
60
80
100
2.24.3
5.0
C
um
ula
tive
un
de
rsiz
e, %
Size, m
RFA
CFA
VMFA
AMFA
34 m
Particle Size Distribution
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RFA
VMFA AMFA
CFA
Classified & Mechanically Activated Fly Ash
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2000 1800 1600 1400 1200 1000 800 600 400
0
10
20
30
40
50
724
620
1160
1090
913
798
560
460
Tra
nsm
itta
nce
(%
)
Wave numbers (cm-1)
VMFA
CFA
MA Vs Classified Fly Ash
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XRD Results
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0 5 10 15 20 25 30 35 40 45 50 55 60 65 705
10
15
20
25
30
35
40
45
50
55
60
65
Lab c
em
ent w
ith v
ibra
tory
mill
ed fly
ash
Pla
nt D
ata
UT
UT
FA Range as per
IS1489-91
IS:1489-91
IS:1489-91 3 days
28 days
C
om
pre
ssiv
e S
tre
ng
th,
MP
a
Fly Ash, Wt. %
Compressive Strength
Benchmarking, BIS Specification and Target
Patent Application No. 0644DEL2006, 10/3/2006
MA Fly Ash in PPC
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MA Fly Ash in PPC
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Unit operation/process Energy PPC 25% FA PPC 50% FA
Raw material (RM) grinding (kWh/t) 15 11 7.5
RM blending & homogenisation (kWh/t) 10 8 5
Coal grinding (kWh/t) 3 2.5 1.5
Clinker section Thermal (MJ/t)
Electrical (kWh/t)
3200
40
2400
30
1600
20
Cement grinding OPC (kWh/t Cement)
PPC (kWh/t Cement)
33
-
-
35
-
-
PPC (kWh/t Cement) (with MA of FA) - - 45-52
Overall Energy Saving(25% FA-50% FA) : Thermal 800 MJ/t, Electrical : 5-12 kWh/t
Resource Conservation (Fly Ash 25% 50%)
Lime stone (t/t cement) 0.25
Clay Sand etc (t/t Cement) 0.125
Coal (t /t Cement) 0.03
Refractory (g/t Cement) 90-100
Air (Nm3/tonne Cement) 750
Implication of Using MA Fly Ash in PPC
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Duxton et al., J Mater Sci (2007) 42:2917–2933
Mechanical Activation & Geopolymerisation
Enhances dissolution
Change in Gel
Character
Faster polymerization
& hardening
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Calorimetry of Geopolymer
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FTIR of Geopolymer
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Mechanical activation
more effective than increasing glass
content
Geopolymerisation of fly ash
X50 ~ 5 μm
X50 ~ 5 μm
X50 ~ 3 μm
X50 ~ 36 μm
60 oCReactivity of Fly
Ash
Reactivity is the Key
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Activation Mechanism
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Patent : 2626/DEL/2005, 30/09/2005 and 728/DEL/2006, 30/11/2005
Very high (120 MPa) strength
Geopolymer Cement
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Growth of Zeolite from Geopolymer Gel
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Reduction in Thermonatrite Formation
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Uniform distribution of Elements
Na-green, Al-red, Si-blue
Geopolymer from Raw Fly Ash Geopolymer from MA Fly Ash
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Towards Products Development
Development of fast
setting geopolymer
grout using
mechanically activated
fly ash
Flexible lightweight
geopolymer for
prefabricated wall
application
High strength
geopolymer cement
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Integrated Scheme
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Thank You