CHM 2210 Test #2 Review SI – Emeil

Disclaimer(s):

1.) These are NOT comprehensive and should not be your only study tool, these are intended to supplement your learning.

2.) These questions may or may not have mistakes, if so, I will explain the mistake during the review however, I am not a professor and cannot guarantee correctness. Questionable questions will be presented to the professor for review.

3.) These problems may in some cases come directly from an outside source that is copyrighted, I renounce any ownership to these problems,  and they are always sourced from ACS reviews, the textbooks, and  other universities.

1.) Predict the product(s):

A.

B.

C.

D.

2.) Predict the product (s):

A.

B.)

C.)

D.)

3.) What is the IUPAC name of this compound? (Please write your answer)

___________________________

4.) Draw the structure that corresponds with the name: (2S, 3R)-3-isopropylhexan-2-ol

A.)

B.)

C.)

D.) None of the above are correct.

5.) Determine the missing reagent:

A.) NaCl B.) PBr3

C.) TsCl D.) SOCl, pyridine E.) None of the above

6.) Determine the minor product(s) through elimination.

A.)

B.)

C.)

D.) Both A and C are correct.E.) No reaction

7. Determine the product(s) with mechanism:

A.) SN1

B.) SN2

C.) E1

D.) SN2

7.) Determine the best product:

A.)

B.)

C.)

D.)

8.) What would be the mechanism and best reagent(s) to form the halohydrin.

A. NaOH, SN2B. NaOH, SN1C. HBr, SN2D. HBr, E1E. HBr, E2

9.) Synthesize the product:

A.

B.

C.

D.

E. No Reaction

10.) Which of the following is not a characteristic of a SN2 mechanism?

A.) Concerted Reaction B.) Strong Nucleophile C.) Usually in protic solventsD.) Prefers less substituted alkyl halidesE.) These are all characteristics of a SN2 mechanism

11.) Name the following molecule:

A.) Sec-butoxy propane B.) 2-ethylethoxy propane C.) Propoxy butane D.) None of the above

12.) Which statement is false? A.) Elimination with a bulky base favors the Hoffman product. B.) Elimination with a weak base favors the Hoffman product. C.) Elimination with a strong base favors the Zaitsev product.

D.) B and C. E.) All of the AboveF.) None of the above.

The remainder of this review is free response meant to enhance understanding this part is intended to be more interactive and encourage participation:

13.) Synthesize the product (Draw mechanisms):

14.) Determine the products when reacting with EtOH and NaOH