This week sample test

QUESTION 1. Determine A, B, C structure in following reaction sequences

QUESTION 2. Identify the final products of below reaction sequences

OCH3

NH2 NaNO2 / HCl

0 - 5 oC

KI HNO3

H2SO4

H2

Pt

NaNO2 / HCl

0 - 5 oC

H3O+

to

NaOH

CH2Br

(A)

C2H5

HNO3

H2SO4

1. Fe/ HCl

2. NaOH / H2O

CH3COCl HNO3

H2SO4

H3O+

to

NaNO2 / HCl

0 - 5 oC

H3PO2

Fe / HCl1. NaNO2 / HCl

0 - 5 oC

CuCN H3O+ 1. LiAlD4

2. H3O+

(B)

2. NaOH / H2O

QUESTION 3. Identify the major products of following transformations

CH2CCl

O

AlCl3(E)

AlCl3H3C +

O

O

O

(F)

QUESTION 4.

1. Synthesize following compound with given organic compounds and other inorganics and bases

2. Suggest the synthetic route to construct the following compound from the provided starting material.