topic 3-2 slides - mr. tuori's ap & honors chemistry€¦ · 3 single replacement double...
TRANSCRIPT
1
Chemical reactions Evidence a chemical RXN has occurred:
•Color change
•Solid forms (precipitate)
•Gas is produced
•Heat generated
Chemical RXN:•Rearrangement of atoms
•Atoms neither created nor destroyed
State subscripts• (aq) - dissolved in water
• (s) -solid, precipitate
• (g) -gas
• (l) -liquid
Classification of Chemical
Reactions
!
H2O2 (l )MnO2" # " " H 2O(l ) +O2 (g)
Catalyst = substance that speeds up areaction but is not consumed
A + BA B
1. Decomposition Reaction- one reactants yield two or more products
General Types of Chemical Reactions
2. Synthesis Reaction- two or more reactants yield one product
A + B A B
!
S8(s ) +O2(g) "SO 2(g)
2
A + B C BC A +
•one element replaces another element in a compound
•products are different element and different compound
3. Single Replacement Reaction-
a) Halogen replaces the ion of another halogen:
!
Cl2(g) + NaI(aq) " I 2(s) +NaCl (aq)
!
Cl2(g) + NaI(aq) " I 2(s) +NaCl (aq)
!
Cl2(g) + NaI(aq) " I 2(s) +NaCl (aq)
!
Cl2(g) + NaI(aq) " I 2(s) +NaCl (aq)
c) active metal replaces H in acid:
!
Zn(s) +HCl(aq) " ZnCl 2(aq) + H 2(g)
d) very active metal replaces H in water:
!
Na(s) + HOH (l) " NaOH(aq) +H 2(g)
element elementcompound compound
!
Zn(s) +HCl(aq) " ZnCl 2(aq) + H 2(g)
!
Zn(s) +HCl(aq) " ZnCl 2(aq) + H 2(g)
!
Na(s) + HOH (l) " NaOH(aq) +H 2(g)
!
Na(s) + HOH (l) " NaOH(aq) +H 2(g)
b) metal replaces another metal in a solution:
!
Zn(s) +CuSO 4(aq) " ZnSO 4(aq) + Cu(S )
!
Zn(s) +CuSO 4(aq) " ZnSO 4(aq) + Cu(S )
!
Zn(s) +CuSO 4(aq) " ZnSO 4(aq) + Cu(S )
4. Double Replacement Reaction-
+ B+ C-
C-A+
A+ D-
+B+ D-
•Two cations of different compounds swap places
•Products are two different compounds
!
Zn(NO3)2(aq) + Na2CO3(aq) " NaNO 3(aq) + ZnCO3(s )
!
NaCl(aq) + AgNO3(aq) " AgCl(s) + NaNO3(aq)
Aqueouscompound
Aqueouscompound
Aqueouscompound
precipitate
a. Precipitation reaction- a precipitate forms
Neutralization reaction- acid + base yield saltand water
!
HCl(aq) + NaOH (aq) " HOH(l ) + NaCl(aq)
!
NaCl(aq) + AgNO3(aq) " AgCl(s) + NaNO3(aq)
!
NaCl(aq) + AgNO3(aq) " AgCl(s) + NaNO3(aq)
!
HCl(aq) + NaOH (aq) " HOH(l ) + NaCl(aq)
!
HCl(aq) + NaOH (aq) " HOH(l ) + NaCl(aq)
Aqueousacid
Aqueousbase
Aqueoussalt
water
!
Zn(NO3)2(aq) + Na2CO3(aq) " NaNO 3(aq) + ZnCO3(s )
!
Zn(NO3)2(aq) + Na2CO3(aq) " NaNO 3(aq) + ZnCO3(s )
decomposition synthesis
3
Single replacementDouble replacement
5. Combustion-•A reaction in which a C-containing compound is
reacted with molecular oxygen
•releases enough E to sustain a flame
a. Complete: more than enough O2 present
b. Incomplete: not enough O2 present
!
CH4
+ O2"CO
2+ 2H
2O
!
CH4
+ O2"CO + H
2O
!
CH4
+ O2"CO
2+ H
2O
!
CH4
+ O2"CO + H
2O
Always add O2as a reactant
Insert two rxns here:One with methanol combusted inexcess O2Other with C2H2 in limiting O2
Sample problem
1. CaSO4 + 2 AgNO3→ Ca(NO3)2 + 2AgSO4
2. CaCO3 (s) → CaO (s) + CO2 (g)
3. 4 V (s) + 5 O2 (g) → 2 V2O5 (s)
4. Cl2 (g) + 2 NaBr (s) → 2 NaCl (s) + Br2 (g)
5. Zn (s) + CuSO4 (aq) → Cu (s) + ZnSO4
6. H2O (l) + Na2O (s) → 2 NaOH(aq)
7. KClO3 (s) → KCl (s) + 3 O2(g)
8. FeS (g) + 2 HCl (g) → FeCl2 (s) + H2S (g)
DR
Decomp
Synth
SR
SR
Synth
Decomp
DR
Na2S (aq)
Aqueous solution of sodium sulfide is mixed with asolution of aluminum chloride producing solidaluminum sulfide and aqueous sodium chloride
+ AlCl3 (aq) → Al2S3 (s) + NaCl (aq)
1. Write formulas
3 62
2. Balance
3. What type of chemical reaction
Double Replacement
4
Aqueous solution of calcium chromate is mixed witha solution of silver nitrate producing solid silverchromate and aqueous calcium nitrate
CaCrO4 (aq) + AgNO3 (aq) → Ag2CrO4 (s)+ Ca(NO3)2 (aq)
1. Write formulas
2. Balance
3. What type of chemical reaction
Double Replacement
2
Aqueous solution of iron (III) chloride is mixed withsolid copper producing solid iron and aqueouscopper (II) chloride
FeCl3 (aq) + Cu (s) → Fe (s) + CuCl2 (aq)
1. Write formulas
2. Balance
3. What type of chemical reaction
Single Replacement
2 33 2
“solid metal” =
metal is element not ion
Cu(s) not Cu+2
Mg(s) not Mg+2
diatomic elements=
H O F Br I N Cl
Cl2 not Cl O2 not O H2 not H