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Author(s)

Citation Bulletin of the Institute for Chemical Research, KyotoUniversity (1973), 50(6)

Issue Date 1973-03-15

URL http://hdl.handle.net/2433/76467

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Type Others

Textversion publisher

Kyoto University

BULLETIN 3F THE INST7TUTE

FOk CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 50, No. 6

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

KYOTO, JAPAN

November, 1972

(Bull. Inst. Chem. Res., Kyoto Univ.)

INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Director

Eiji SUITO

Members of Council

Eiichi FuJITAOsamu HAYAISHIHiroshi INAGAKI

Keinosuke KOBAYASHI Naokazu KOIzuMIMichio KURATA

Masaya OKANOTatsuo OoiTsunenobu SHIGEMATSU Sakae SHIMIZuEiji SUITOToshio TAKADA

Mitsuru TAKANAMI Tohru TAKENAKAYoshimasa TAKEZAKI

Megumi TASHIROWaichiro TsujiTatsuo YAMAMOTO Takuji YANABU

Publication Committee

Eiich FuJITAMasaya OKANOTatsuo Ooi

Sakae SHIMIZUToshio TAKADATohru TAKENAKA

Business Staff

Ryonosuke FUJIMOTOShigeo HOTTA

History of Publications

TermVol.TitlePublished

Jan., 1939-! 4EOF'LP7"t„r'i4% Dec.19471-16 (The Reports of the Institute for Chemical Indeterminately Research)

April, 1933—10 JahretrInstitut fiir chemische Forschung

March,1949-4L FUMNI 17-19 (The Reports of the Institute for Chemical Indeterminately Dec., 1949Resear ch)

March, 1950-Tf;'WF5Ph<° Sept., 195220-30 (Bulletin of the Institute for Chemical Re- Quarterly search)

The Commemoration Volume for the Silver Dec., 1951 — Jubilee—

j (fL*WFDphaa) T.-1-E i az-vg-)

Jan., 1953 31 Bulletinof theInstitute for Chemical Research Bi-monthly onwardsNo. 1- (~~*~}F9J?V-)

CONTENTS

Tokuji Yamamoto and Megumi Tashiro: Growth of Crystals Out of Silver— Containing Glass under Electron Bombardment .................................591

Toshio Maki and Megumi Tashiro : Loss of Ag and Cl from Photochromic Glasses during Melting in Various Atmospheres .................................596

Tadashi Kokubo, Keizo Yamashita and Megumi Tashiro: Effects of Al2O3 Addition on Glassy Phase Separation and Crystallization of a PbO-TiO2—

SiO2 Glass ....................................................................................608 Toshio Maki and Megumi Tashiro : Effects of Various Manufacturing Conditions

on Darkening and Fading of Photochromic Glasses ..............................621 Tsunenobu Shigematsu, Masakazu Matsui and Katsuya Uesugi: Spectro-

photometric Determination of Palladium with Eriochrome Cyanine R ...... 634 Tsunenobu Shigematsu, Osamu Fujino and Masakazu Matsui: Coprecipitation

of Copper with Hydroxyapatite .........................................................645 Kazumasa Ueda, Toru Aoki, Masakazu Matsui and Tsunenobu Shigematsu :

The Solvent Extraction of Zinc Pivaloyltrifluoroacetonate adducts with Monodentate and Bidentate Ligands ...................................................653

Mamoru Taniuchi : The Synthesis of Methylacetylene by the Pyrolysis of Propylene (IX) The Mechanism of the Iodine-catalyzed Pyrolysis of

Propylene ....................................................................................660

Abstracts ...................................................................................................669

IILLETIN OF TIE INSTITLTE

FOP CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 50

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

KYOTO, JAPAN

1972

(Bull. Inst. Chem. Res., Kyoto Univ.)

Contents of Volume 50, 1972

Originals

Tsuneto Nagatomo, Hiromasa Mazaki and Sakae Shimizu: Study on

Geometrical Stability of Multi-Anvil High Pressure Device by Gamma Rays ........................................................................ 1

Hiroaki Matsumoto and Yoshimitsu Nakamura: Optical and EPR Studies on the 5e V Band of CdC12 Crystals .................................8

Yoshito Ikada, Yasuko Nishizaki and Ichiro Sakurada: Chemical Structure of Cellulose-Styrene Graft Copolymer ..............................20

Yoshito Ikada and Fumitaka Horii: Effect of Graft Copolymer on Protection of Homopolymer from Precipitation.............................. 27

Saburo Matsuoka: Response of Some Nucleotides in Vivo to Gamma Radiation on Euglena Cells in Two Different Growth Phases............ 38

Hirotake Inagaki: Thermoluminescence in Quartz Irradiated by Gamma Rays—A Mineralogical and Geological Application— ............45

Rikizo Imamura, Takeo Ueno and Koji Murakami: Depolymeriza- tion of Cellulose by Electron Beam Irradiation .............................. 51

Nobuyuki Tanaka and Akio Nakajima: Thermal Shrinkage of Fibrous Polymer by Partial Melting of Crystalline Regions............... 65

Nobuyuki Tanaka and Akio Nakajima: Partial Melting, Recrystal- lization and Thermal Shrinkage of Polyethylene Terephthalate

Fibers ....................................................................................70

Nobuyuki Tanaka and Akio Nakajima: Thermal Shrinkage of Polypropylene Fibers in Several Solvents by Partial Metling

of Crystalline Regions ...............................................................75 Waichiro Tsuji, Tetsuo Ikeda, Mikiko Hamanaka and Yoko Ikeda:

Properties of Acrylic Acid Grafted Polypropylene Fiber .....................83 Ken Nishikawa and Tatsuo Ooi: Energy Calculations on Di- and

Polypeptide of L-Proline............................................................ 94 Takeshi Tanaka and Tadao Kotaka: Molecular Dimensions of

Block Copolymers in Solution ......................................................107 Hisashi Odani, Norio Nemoto and Michio Kurata: The Viscoelastic

Properties of Undiluted Linear Polymers of Narrow Molecular Weight Distribution in the Terminal Zone.................................... 117

Akikazu Hatanaka: Leaf Alcohol XX: Alcohol: NAD Oxidore- ductase from Tea Seeds............................................................ 135

Koichi Koshimizu, Akio Kobayashi, Tetsuo Mitsui, Sachiko Matsubara and Yotaro Tsukamoto: Isolation and Structure

of Tulip Flower Factors which Stimulate the Germination of Chrysanthemum Pollen ...............................................................142

Naomichi Baba, Mitsunori Kirihata, Takenosuke Takano and Minoru

Il

Ohno: Color Reaction of Pyrethrins and Eugenol with Orthophosphoric, Sulfuric and Hydrochloric Acids ........................... 150

Kazuyoshi Kawazu, Hajime Ohigashi, Norio Takahashi and Tetsuo Mitsui: Piscicidal Constituents of Calop/yllum Inoplyllum .................. 160

Masayuki Hamada and Mitsuo Chubachi: Photoinduced Oxygena- tion of Rotenoids. I. Ring Contraction of Dehydrorotenone

to Coumarono-chromone ............................................................168

Masayuki Hamada and Eiko Kawano: The Stereochemistry of Tritium Labeling of Hexachlorocyclohexane Isomers. I. Gas

Exposure Method .....................................................................175

Jun-ichi Oda, Michio Horiike and Yuzo Inouye: Reaction of Chloramines Part IV. The Reaction of Chloramines with

13-Ketoesters and /'-Diketones...................................................... 183 Akikazu Hatanaka: Leaf Alcohol XXI. Photochemical and

Thermal Isomerization among Leaf Aldehyde and its

Isomers................................................................................. 192

Hiromichi Matsubara: Studies on Synergist for Insecticides.

(XXVII) On the Synergistic Effect of Several Lignans on Pyrethrins and Allethrin............................................................ 197

Eiichi Fujita, Kaoru Fuji, Shigetaka Nakamura and Yoshihisa Takaishi : Investigation of the Non-basic Constituents of Lythrum Anceps

MAKINO .................................................................................206

Akio Nakajima and Toshio Hayashi: Synthesis and Conformation Studies of Copolypeptides Composed of y-Benzyl-L-Glutamate

and €-N-Carbobenzoxy-L-Lysine................................................ 303

Hiroshi Watanabe and Yasuaki Kozai: Studies on Polypeptides. (V). Thermal Polycondensation of Alanine in the Presence of

Carboxylic Acids..................................................................... 318

Eiichi Fujita, Yukikazu Saeki, Masahito Ochiai and Takehisa Inoue: Investigation of the Neutral Constituents of Lythrum Salicaria L ............ 327

Susumu Hirase and Kyoko Watanabe: The Presence of Pyruvate Residues in A-Carrageenan and a Similar Polysaccharide.................. 332

Yasuo Kita, Naokazu Koizumi and Kazuhiro Maruyama: The Reaction of Nitrosobenzene with Benzylamine in Non-Aqueous

Media................................................................................. 337

Kazuhiro Maruyama, Tetsuo Otsuki, Akio Takuwa and Saburo Kako : Photochemical Reaction of I,4-Naphthoquinone with Olefins ............344

Kazuhiro Maruyama, Akio Takuwa, Tetsuo Otsuki and Saburo Kato: Syntheses of 9-Acyloxy-l0-hydroxyphenanthrenes by Photo- chemical Reaction .....................................................................348

Jun-ichi Hayami, Nobuo Tanaka and Nobuhisa Hihara: SN2 Reaction in Dipolar Aprotic Solvents. II. Direct Displace-

ment Reactions of Substituted Benzyl Chlorides with Halide Anion in Acetonitrile ..................................................................354

Takao Katagiri, Osamu Nakachi, Toshihiro Suzuki, Kunihiko Takabe and Juntaro Tanaka: The Hydration of Isoprene with a

Cation Exchange Resin Catalyst................................................ 363 Shigeo Tanimoto, Yoshihisa Imazu, Mitsuru Imuta and Masaya

Okano: Syntheses of Some Derivatives of 1,4-Dioxane and 1,3-Dioxolane ...........................................................................368

Yasumasa Sakakibara, Tsutomu Tagano, Mutsuji Sakai and Norito Uchino : The Dimerization Reaction of Propylene by Nickel

Acetylacetonat—Triethyl-aluminum Sesequichloride . Tertiary Phosphine Catalyst. Electronic and Steric Effect of

Phosphorous Ligands............................................................... 375 Mamoru Taniuchi : The Synthesis of Methylacetylene by the

Pyrolysis of Propylene. (VII). The Catalysis of Iodine..................... 383

Sango Kunichika, Yasumasa Sakakibara, Mamoru Taniuchi and Ryoji Okuda: The Synthesis of Methylacetylene by the Pyrolysis of Propylene. (VIII). The Pyrolysis of Allyl Bromide ............393

Jun Yamauchi, Kohji Watanabe, Hiroaki Nishiguchi and Yasuo Deguchi: Magnetic Properties of 2,2,6,6-Tetramethyl-4-

Hydroxypiperidine-1-Oxy1-4-Derivatives....................................... 483 Takayuki Kobayashi and Sakae Shimizu: Elastic Scattering of

100- and 200-keV Positrons by Selenium and Bismuth........................488 Naokazu Koizumi and Yasuo Kita: Numerical Tables of Response

Functions and their Integrals for Debye, Cole-Cole, and

Davidson-Cole types of Dielectric Relaxation ....................................499 Tohru Takenaka and Rempei Gotoh: Studies on Ion-Exchange

Reaction of Metal Salts of Fatty Acids in Alkali-Halide Pellets

by Means of Infrared Absorption Spectra.................................... 577 Yuzuru Hiragi: Molecules and Structure of Regular Molecular

Assemblies. I. Ring Forming Ellipse .............................................584 Tokuji Yamamoto and Megumi Tashiro: Growth of Crystals Out

of Silver-Containing Glass under Electron Bombardment .....................591 Toshio Maki and Megumi Tashiro : Loss of Ag and Cl from Photo-

chromic Glasses during Melting in Various Atmospheres .....................596 Tadashi Kokubo, Keizo Yamashita and Megumi Tashiro: Effects

of Al2O3 Addition on Glassy Phase Separation and Crystalliza- tion of a PbO-TiO2-SiO2 Glass................................................... 608

Toshio Maki and Megumi Tashiro : Effects of Various Manufacturing Conditions on Darkening and Fading of Photochromic Glasses............ 621

Tsunenobu Shigematsu, Masakazu Matsui and Katsuya Uesugi : Spectrophotometric Determination of Palladium with Erio-

chrome Cyanine R.................................................................. 634 Tsunenobu Shigematsu, Osamu Fujino and Masakazu Matsui:

Coprecipitation of Copper with Hydroxyapatite.............................. 645 Kazumasa Ueda, Toru Aoki, Masakazu Matsui and Tsunenobu

Shigematsu : The Solvent Extraction of Zinc Pivaloyl-

iv

trifluoroacetonate adducts with Monodentate and Bidentate Ligands................................................................................. 653

Mamoru Taniuchi: The Synthesis of Methylacetylene by the Pyrolysis of Propylene (IX) The Mechanism of the Iodine— catalyzed Pyrolysis of Propylene................................................ 660

Notes

Kentaro Okumura, Tameo Iwasaki, Tadashi Okawara and Kazuo Matsumoto: Synthesis of L-,B-Chloroalanine Derivative from

L-Aspartics Acid..................................................................... 209 Toshio Sugita, Keiichi Honda Osamu Itoh and Katsuhiko Ichikawa:

Effects of Anions of Mercuric Salts in Oxymercuration ..................... 216 Makoto Ichii, Takashi Sugiyama and Shinzaburo Oka: Friedel—

Crafts Aralkylation III. The Reaction of Benzene with 2-Phenylethyl-1,1-d2 and 2-(p-Chlorophenyl)-ethyl-1, 1-d2

Chlorides.............................................................................. 404

Communications

Tameo Iwasaki, Kazuo Matsumoto, Manabu Matsuoka and Muneji Miyoshi : Simultaneous Cleavage of N-Tosyl and S-Benzyl

Groups in Amino Acid and Peptide by Electrolytic Reduction ............... 220 Takeshi Igarashi, Jun-ichi Oda and Yuzo Inouye: Partial Asym-

metric Synthesis of d-2-Octalone with Chiral Enamine ..................... 222

Reviews

Katsuhiko Ichikawa and Sakae Uemura: Oxidation Involved in Organometallic Reactions ............................................................225

Hajime Ohigashi and Tetsuo Mitsui: Studies on the Biologically Active Substances of Sapium japonicum (Euphorbiaceae) ..................... 239

Katsuhiko Kitahara, Hideki Kohno and Minoru Nakajima: Synthetic Studies of Kasugamycin and Related Compounds ............... 275

Hitomi Suzuki : Unusual Aromatic Nitrations ..........................................407 Sakae Uemura and Masaya Okano : Liquid Phase Halogenations

with Metal Halides.................................................................. 423

Kazuhiko Tanaka: The Cyanide-Ion Cleavage of Organic Disulfides.............................................................................. 433

Aritsune Kaji and Masatoshi Ogura: Thermal Rearrangement of Thiocaboxylates..................................................................... 441

Tadashi Okamoto: Recent Progress in the Chemistry of Allenes ..................... 450

V

Author Index to Vo/u ne 50, 1972

Aoki, Toru.................................................................................... 653 Baba, Naomichi.............................................................................. 150 Chubachi, Mitsuo........................................................................... 168 Deguchi, Yasuo.............................................................................. 483 Fuji, Kaoru.................................................................................... 206 Fujino, Osamu .................................................................................645 Fujita, Eiichi...........................................................................206, 327 Gotoh, Rempei .................................................................................577 Hamada, Masayuki............................................................... 168, 175 Hamanaka, Mikiko ..............................................................................83 Hatanaka, Akikazu.................................................................. 135, 192 Hayami, ,Jun-ichi.............................................................................. 354 Hayashi, Toshio.............................................................................. 303 Hihara, Nobuhisa ..............................................................................354 Hiragi, Yuzuru.............................................................................. 584 Hirase, Susumu.............................................................................. 332 Honda, Keiichi.............................................................................. 216 Horii, Fumitaka.............................................................................. 27 Horiike, Michio.............................................................................. 183 Ichii, Makoto................................................................................. 404 Ichikawa, Katsuhiko............................................................... 216, 225 Igarashi, Takeshi........................................................................... 222

Ikada, Yoshito ..............................................................................20, 27 Ikeda, Tetsuo................................................................................. 83 Ikeda, Yoko................................................................................. 83

Imamura, Rikizo........................................................................... 51 Imazu, Yoshihisa........................................................................... 368 Imuta, Mitsuru.............................................................................. 368 Inagaki, Hirotake........................................................................... 45 Inoue, Takehisa.............................................................................. 327 Inouye, Yuzo........................................................................ 183, 222 Itoh, Osamu................................................................................. 216 Iwasaki, Tameo........................................................................ 209, 220 Kaji, Aritsune................................................................................. 441 Kako, Saburo........................................................................... 344, 348 Katagiri, Takao.............................................................................. 363 Kawano, Eiko.............................................................................. 175 Kawazu, Kazuyoshi........................................................................ 160 Kirihata, Mitsunori........................................................................ 150 Kita, Yasuo.............................................................................. 337, 499 Kitahara, Katsuhiko..................................................................... 275

vi

Kobayashi, Akio........................................................................... 142 Kobayashi, Takayuki........................................................................ 488 Kohno, Hideki.............................................................................. 275 Koizumi, Naokazu..................................................................... 337, 499 Kokubo, Tadashi.............................................................................. 608 Koshimizu, Koichi........................................................................... I42 Kotaka, Tadao .................................................................................107 Kozai, Yasuaki................................................................................. 318 Kunichika, Sango........................................................................... 393 Kurata, Michio.............................................................................. 117 Maki, Toshio........................................................................... 596, 621

Maruyama, Kazuhiro......................................................... 337, 344, 348 Matsubara, Hiromichi..................................................................... 197 Matsubara, Sachiko........................................................................ 142 Matsui, Masakazu............................................................... 634, 645, 653 Matsumoto, Hiroaki........................................................................ 8 Matsumoto, Kazuo.................................................................. 209, 220 Matsuoka, Manabu........................................................................ 220 Matsuoka, Saburo........................................................................... 38 Mazaki, Hiromasa1 Mitsui, Tetsuo.................................................................. 142, 160, 239

Miyoshi, Muneji.............................................................................. 220 Murakami, Koji........................................................................... 51 Nagatomo, TsunetoI Nakachi, Osamu ..............................................................................363 Nakajima, Akio ..................................................................65, 70, 75, 303 Nakajima, Minoru........................................................................... 275 Nakamura, Shigetake..................................................................... 206 Nakamura, Yoshimitsu..................................................................... 8

Nemoto, Norio.............................................................................. 117 Nishiguchi, Hiroaki........................................................................... 483 Nishikawa, Ken.............................................................................. 94 Nishizaki, Yasuko........................................................................... 20 Ochiai, Masahito.............................................................................. 327 Oda, Jun-ichi........................................................................ 183, 222 Odani, Hisashi................................................................................. 117 Ogura, Masatoshi.............................................................................. 441

Ohigashi, Hajime..................................................................... 160, 239 Ohno, Minoru................................................................................. 150 Oka, Shinzaburo.............................................................................. 404

Okamoto, Tadashi ..............................................................................450 Okano, Masaya..................................................................... 368, 423

Okawara, Tadashi........................................................................... 209 Okuda, Ryoji ....................................................................................393 Okumura, Kentaro........................................................................... 209

vii

Ooi, Tatsuo.................................................................................... 94 Otsuki, Tetsuo........................................................................... 344, 348 Saeki, Yukikazu.............................................................................. 327 Sakai, Mutsuji................................................................................. 375 Sakakibara, Yasumasa............................................................ 375, 393 Sakurada, Ichiro.............................................................................. 20 Shigematsu, Tsunenobu .........................................................634, 645, 653

Shimizu, Sakae.............................................................................. 1, 488 Sugiyama, Takashi........................................................................... 404 Sugita, Toshio................................................................................. 216 Suzuki, Hitomi .................................................................................407 Suzuki, Toshihiro........................................................................... 363 Tagano, Tsutomu........................................................................... 375 Takabe, Kunihiko........................................................................... 363 Takahashi, Norio........................................................................... 160 Takaishi, Yoshihisa........................................................................... 206 Takano, Takenosuke........................................................................ 150 Takenaka, Tohru ..............................................................................577 Takuwa, Akio........................................................................ 344, 348 Tanaka, Juntaro.............................................................................. 363 Tanaka, Kazuhiko........................................................................... 433 Tanaka, Nobuo.............................................................................. 354 Tanaka, Nobuyuki.................................................................. 65, 70, 75 Tanaka, Takeshi.............................................................................. 107 Tanimoto, Shigeo ..............................................................................368 Taniuchi, Mamoru ...............................................................383, 393, 660 Tashiro, Megumi............................................................ 591, 596, 608, 621 Tsuji, Waichiro.............................................................................. 83 Tsukamoto, Yotaro........................................................................... 142 Uchino, Norito.............................................................................. 375 Ueda, Kazumasa ..............................................................................653 Uemura, Sakae..................................................................... 225, 423 Ueno, Takeo ....................................................................................51 Uesugi, Katsuya.............................................................................. 634

Watanabe, Hiroshi........................................................................... 318 Watanabe, Kohji ..............................................................................483 Watanabe, Kyoko ..............................................................................332 Yamamoto, Tokuji........................................................................... 591 Yamashita, Keizo ..............................................................................608 Yamauchi, Jun................................................................................. 483