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Privileged and Confidential
TID Micro and Mobile RefiningWELLHEAD AND LOCAL PROCESSING OF CRUDE AND CONDENSATE INTO HIGHER VALUE PRODUCTS
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Micro and Mobile Refining
TID’sTechnologicalAdvantage 3-8Economics 10-18RevenueMaximizingProcessFabricationOptions 20-22TID’sProcessIntensificationExperience 24-29ContactInformation 30
Ø Table of Contents PAGE(S)
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TheScience attheCOREofTID’sCUBECapabilities
Process Intensification“disproportioned output volume to physical size”
Catalyst Control
Utilities Kinetics
IntensificationZONE®
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TID DeliversCommercial-Scale Chemical Production at Pilot-Scale Size and Costs
by utilizing ourPatented Process Intensification Technology
TID DELIVERS:Commercial-Scale Chemical Production at Pilot-Scale Size and Cost
byutilizingourPatentedProcessIntensificationTechnology
PI
Technology§ TID’stransformationalvaluepropositionisenabledbyourpatented
processintensificationIP.Thisproprietarytechnologyexploitsbreakthroughcontrol,catalysts,kineticsandutilitiestogiveTIDcustomersanunequalledcompetitiveadvantage.
§ TID’stechnologyDOESNOTnotpresumetochangethelawsofchemistryorphysics.Itdoeshowever,representthelinchpininputsthatdeterminetherelativeefficienciesofallchemicalreactions.
§ UsingitsIntensificationZONE®,utilities,kinetics,andcatalystsarefocusedandcontrolledinawaythatemulateslabscaleefficienciesforcommercial-scaleoutputs.
DramaticCostSavings(Capex&Operational)
HighProductSelectivity
OptimizedOperationalEfficiency
SaferProcesses
SmallerEquipment/PlantQbD (QualitybyDesign)
ShortTimeToMarket
LessWaste/By-Products
HighProductPurity
THEBENEFITSOFPROCESSINTENSIFICATION
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Core Competencies:ü IntensificationMethodSpecificChemistryResearch&Development
ü Modular,MicroManufacturing&AutomatedProcessControlEngineering
ü TIDModularProcessFabrication
ü TIDProcessSiteInstallation
ü TIDProcessTechnicalSupport&ContractPlantOperation
We Do Process Intensification Better Than Anyone Else
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TID’s Value PropositionTID’S VALUE PROPOSITION§ TheCUBEisatruedisruptivetechnology—It’sIntense!
§ TheTIDvaluepropositionincreasesacustomer’snetprofitbetween25%and100%.
• Norisktothecustomerorinvestorstoremovebarrierstoadoptingthetechnology.
• TIDprovidestheproprietarytechnologyandIP.• Customerdeliversexistingdemandfromthe
market.• TheCUBEsolutionprovidescustomerswith
strategicoptionsto(a)exploiteconomicrentsor(b)becomeacostandpriceleader.
• Adisruptivetechnologythatenablescustomerstobackwardorforwardintegrateatwill.
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Seem too good to be true?We guarantee our deliverables.
üCustomershaveNO capitalriskifTIDfailstodeliver
üProfit– Ourprofitinterestsareparalleled– WeonlyPROFITwhenyoudo
üGrowth– Organic&Horizontal
üCompetewithacostadvantagethatcanbeconvertedintoaddedprofitormarketshare.
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TID’s Intensified Process Vs. Conventional an actual scale comparison
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TIDIP{v1.0}RefiningModuleVs.aConventionalRefinery
TID IP {v 1.0} Conventional RefiningProcessScale
bbl./day 2,000 300,000
gallonsperday 84,000 12,600,000
gallons/minute 58 8,750
PhysicsProcesspipesizeinches(avg) 3 228
Processpipesizecm(avg) 7 579
Actual Relative Scale Comparison
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TID’s Intensified Process Vs. Conventional capital efficiency that’s facilitating a new business paradigm
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$20,000
$18,000
Capital$/Bbl. Capital$/Bbl.
CapitalEfficiency
TID
Conventional
UntilTID’sProcessIntensificationTechnology,thecapitalefficiencyofasmallplatformrefiningoperationmadecommercializationanunattainable“need”.
Today,plantspecificpetrochemicalsupplychaindisruption,localrefinedproductsupplyandmobilerefiningareallareality.
Welcometoanewpetrochemicalparadigm.WelcometoTID.
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Process Intensified Vs. Conventional an actual chemical comparison
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TIDIP{v1.0}RefiningModuleVs.aConventionalRefinery
TIDIP{v.1.0} ConventionalRefiningChemistry
CrudepretreatmentIP{flexcrude-treatment}Process TIDIPRationalization Electrostatic Desalted
Desaltedoperationsisthe InlineQA/QCdeterminingprecursorfor Aqua-SolCentrifugal
Consistent,high-quality refiningsuccessand Washdistillatefeed efficiencies. InlineQA/QC
TID’sFlexCrude-Treatment LowHLBsurfactanttechnologyseparates, optionanalyzesandoptimizeseachcriticalprocesssteptobroadenourcustomer’s InlineQA/QCcrudeuseoptionsand HighHLBsurfactantovercomeconventional optiondesaltedlimitations.
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Process Intensified Vs Conventional a base engineering comparison
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Engineering TIDIP {v1.0} ConventionalRefiningAtmosphericDistillation CrudeDistillationUnit(CDU) CrudeDistillationUnit(CDU)
DesignBasis McCabe–Thiele VariousRefluxcooling HeatExchangerorCryogenic HeatExchangerTotalNumberofTrays 25-30"Total"Shelves 25-34TotalShelvesExternalSize 3’’Dx30'H 19''Dx90'H
PostAtmosphericDistillationProcesses*Customizedforcustomer'sneeds
VacuumDistillationDesignCapacity 2000bbl. 160,000bbl.Refluxcooling HeatExchangerorCryogenic HeatExchangerExternalSize 3'Dx30'H 46'Dx164'H
DesignVacuumRange 10-40mmHg 10to40mmHgTrayEngineering Proprietary VariousPacking Proprietary Various
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Process Intensified Vs. Conventional an actual scale comparison
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CustomEngineeringTIDIP{v.1.0} ConventionalRefining
CustomerEngineeringOptionsCatalyticreforming Catalyticreforming
Alkylation Alkylation
Isomerization Isomerization
Distillatehydrotreater Distillatehydrotreater
Merox Merox
Aminegastreater,clausunit Aminegastreater,clausunit
Fluidcatalyticcracking(FCC) Fluidcatalyticcracking(FCC)
Hydrocrackerunit Hydrocrackerunit
Visbreaker Visbreaker
Delayedcoking Delayedcoking
CUSTOMIZATION OPTIONSTID Custom Engineered Modules can process the gamut of crude types and empowers maximum customer flexibility in choosing
Production Yield
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Thefutureofpetroleumproductexportsisgrowingrapidlyamong
globalmarkets.TheU.S.continuestoalsodemandincreasedpetroleum
productsexports.
U.S. petroleumproductexports continuetoincrease.TotalU.S. petroleumproduct
exports continuedtoincreasein2015,up467,000barrelsperday(b/d)from2014to
4.3millionb/d,drivenbyincreasedexports ofdistillatefuel,motorgasoline,and
propane.Mar25,2016
U.S. MARKETS & OPPORTUNITIES
TheMiddleEastandCISare
likelytostrengthentheir
positionsasnetexporters,
whileEurope,LatinAmerica,
Asia-Pacificcountriesand
Africawillimportmore.
Global MARKETS & OPPORTUNITIESGLOBAL MARKETS & OPPORTUNITIES
ADU, Vacuum Distillation Module Options
Present your process/ product needs or wants
We’ll deliver your customized modular solution
CRUDE MODULE PROCESS OPTIONS
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2000 BPD CRUDE OR DISTILLATE MOBILE REFINING SOLUTION
DISTILLATION COLUMN
HEATER
COMBUSTION GAS RECIRCULATIN BLOWER
REFINERY GAS ENGINE
ADJUSTABLE COLUMN HEIGHT TO 40 FEET
53 Ft.
8 Ft 6 In.
13.6 FeetTID’smobilerefiningsolutionsinclude:
• ADU(Below)• VDU• TripleStepDesulfurization,Desaltingand
De-EmulsificationUnit• HydrogenationUnit• CrackingUnits
• Eachunitismountedonatransportablesemitrailerforshort-to-long-termuseatthewell-head.
2,000 bbl./Day ADU, Vacuum Distillation Module
407-413-4500407-413-4500407-413-4500 407-413-4500
ALL-IN-ONE 2000 BPD CRUDE OR DISTILLATE REFINING SOLUTION
TID’smodularrefiningprocessdesignedwithourturnkey:
• ADU• VDU• TripleStepDesulfurization,
DesaltingandDe-EmulsificationUnit
• HydrogenationUnit• CrackingUnits
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THE SUCCESS Based Evolution of TID’s Commercial Process IntensificationMicro Modular Reaction Platforms
§ IL,USA:96Mtonne/year.SoldtoCibaChemical (NowBASF)
§ IL,USA:10Mtonne/year.SoldtoAlliedColloids/Ciba (NowBASF)
§ CA,USA:96Mtonne/year.SoldtoCibaChemical (NowBASF)
§ MA,USA:50Mtonne/year.SoldtoDeltaSearsport (NowGAC)
§ MD,USA:50Mtonne/year.SoldtoDeltaBaltimore (NowUSALCO)
§ Japan/VA,USA:26tonne/year.MitsubishiChemical
§ MI,USA:40Mtonne/year.SoldtoAlchemyInc. (OwnedbySNF)
§ GA,USA:Existingtechnologyupgrade&processenhancement.CallawayChemical (NowKemira)
§ Chile:Technologyupgradeandprocessenhancement.OricaChileS.A.
§ NJ,USA:JDAprocessenhancements.WatsonPharmaceuticals (NowActavis)
§ MS,USA:10Mtonne/year.MonolyteLabs/PRCPolymersJ.V
§ MX,USA:20Mtonne/year.QuimicaEcotec (aCydsaMXCompany)
§ MS,USA:55Mtonne/year.PRCPolymers
§ CA,USA:Technologyupgradeandprocessenhancement.SapphireEnergy
§ LA,USA:20Mtonne/year.MonolyteLabs (SoldtoRockwater)
§ TX,USA:Technologyupgrade/processenhancement.Cori-Tech/Haliburton (NowNalco-Champion)
§ IL&IN,USA:Existingtechnologyupgradeandprocessenhancement.Nalco (NowEcolab)
§ TX,USA:50Mtonne/yearMonolyteLabs (SoldtoRockwater)
§ TX,USA:20Mtonne/year. ConfidentialCustomer
§ TX,USA:50Mtonne/year. ConfidentialCustomer
§ TX,USA:50Mtonne/year. ConfidentialCustomer
§ TX,USA:70Mtonne/year.ConfidentialCustomer
§ Romania:35Mtonne/year (UnderContract)
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BUILT FROM EXTENSIVE CONVENTIONAL EXPERIENCE
• RefiningwithMobil,ExxonMobil,Valero,Sunoco,PESandPetróleosdeVenezuela,S.A.(PDVSA)• Refiningprocesses–
• crudeatmosphericandvacuumdistillation,naphthareforming(semi-regenerativeandcontinuous),hydrotreating(naphtha,distillate,gasoline,andlubricants),hydrocracking,fluidcracking,coking(delayedandfluid),alkylation(sulfuricandhydrofluoric),gasseparation,steam-mbasegas(es)reforming,lubeproduction(conventionalandcatalytic),asphaltmanufacturing,aromaticsextraction,andpetroleumcokegasification
• GastoLiquidsconcepttocommercialization• Offshoretechnologiesforgasandoilproduction• Utilitiesproduction:Steam,hydrogen,nitrogen,boilers,coolingsystem• Researchanddevelopmentofnewtechnologies:Operationalconditions,catalystsandtechnologiesevaluation• Pilotplantdesign;fabricationandoperationforevaluationofnewandexistingtechnologies• Energyintegrationbaseddesign;evaluationofheaters,furnacesandheatexchangers• HSEDevelopmentalAuditing• Expertiseinon-siteandoff-sitelogisticssystems
• crudedelivery(marine,pipelineandrail),fuelproducts(blending,storage,marineandpipelinedeliveries),LPG(truck,rail,pipeline,pressurizedstorageandundergroundcaverns)
• Projectexperiencefrominitialconceptionthroughengineering,procurement,constructionandstartup• recentlyoversawconstructionoflargestcruderailunloadingfacilityinNorthAmericaandlargestLPGrailloading/unloading
facilityontheEasternSeaboard• Extensivecommercialinvolvementandoptimizationofrefineryconfigurationandstreamdispositions• Evaluationofprocessoperationalhazard
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TID PROCESS INTENSIFIED (PI) MODULES/CHEMISTRYCOMMERCIAL EXAMPLES
§ AcrylicMonomers§ Alkyl Amines§ EpiPolyamines§ QuaternaryAmmoniumMonomer,Polymer§ Peptides, Nucleotides, Antibiotics,and Alkaloids (e.g. Tropinone)§ Agrochemicals,PlantGrowthRegulators§ Catalysts
§ Organic§ Inorganic§ Organometallic
§ CleaningApplications/Formulations§ AutomotiveFuelTreatments§ Epoxy Coatings§ EmulsifiersandDEEmulsifiers
§ NovelEmulsificationChemistries§ NovelPIProcesses
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TID PROCESS INTENSIFIED (PI) MODULES/CHEMISTRYCOMMERCIAL EXAMPLES CONTINUED . . .
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§ HydrolysisReaction§ InitiallyViaAlloyCatalysis§ UpgradedtoBio/EnzymaticProcess
§ PetroleumDistillation§ DownstreamValueUpgrading
§ JointResearchProject(NotYetCommercial):§ PharmaceuticalDrugs (e.g. Rolitetracycline (theMannichBaseofTetracycline,Fluoxetine(Antidepressant),Tramadol,andTolmetin(Anti-Inflammatory
Drug)andAzacyclophanes)
§ Polymers§ WaterSoluble§ PlasticsBased§ PAO:IV(1-DodeceneHomoandCopolymers)
§ SoapandDetergents
§ SyngasProduction
§ PolyetheraminesfromSubstitutedBranchedChainAlkyl Ethers
§ α,β-Unsaturated Ketones viaTheThermalDegradationofMannichReactionProducts(e.g.MethylVinylKetonefrom1-Diethylamino-3-Butanone)
§ VinylEsterMonomers,Polymers
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ContactName Title Email
JamesKane CEO,CTO [email protected]:(321)559-2916
BachoVega ChiefofStaff [email protected]:(321)559-2916Cell:(480)307-4774
DonnaFuller SeniorMarketingManager [email protected]:(321)559-2916Cell:(407)413-4500
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1136CelebrationBoulevardCelebration,Florida34747
www.tidipx.com