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  • Copyright 2008, 1997, 1984, 1973, 1963, 1950, 1941, 1934 by The McGraw-Hill Companies, Inc. All rights reserved. Manufactured in the UnitedStates of America. Except as permitted under the United States Copyright Act of 1976, no part of this publication may be reproduced or distributedin any form or by any means, or stored in a database or retrieval system, without the prior written permission of the publisher.

    0-07-154209-4

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    DOI: 10.1036/0071511253

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  • GENERAL REFERENCES

    PHYSICAL PROPERTIES OF PURE SUBSTANCES Tables

    2-1 Physical Properties of the Elements and Inorganic Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-7

    2-2 Physical Properties of Organic Compounds . . . . . . . . . . . . . . 2-28

    VAPOR PRESSURES OF PURE SUBSTANCESUnits Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-48Additional References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-48Tables

    2-3 Vapor Pressure of Water Ice from 0 to 40 C . . . . . . . . . . . . 2-482-4 Vapor Pressure of Supercooled Liquid Water

    from 0 to 40 C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-482-5 Vapor Pressure (MPa) of Liquid Water

    from 0 to 100 C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-482-6 Substances in Tables 2-8, 2-32, 2-141, 2-150,

    2-153, 2-155, 2-156, 2-179, 2-312, 2-313, 2-314, and 2-315 Sorted by Chemical Family . . . . . . . . . . . . 2-49

    2-7 Formula Index of Substances in Tables 2-8, 2-32, 2-141, 2-150, 2-153, 2-155, 2-156, 2-179, 2-312, 2-313, 2-314, and 2-315 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-52

    2-8 Vapor Pressure of Inorganic and Organic Liquids,ln P =C1 + C2/T +C3 ln T+C4 TC5, P in Pa . . . . . . . . . . . . . 2-55

    2-9 Vapor Pressures of Inorganic Compounds, up to 1 atm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-61

    2-10 Vapor Pressures of Organic Compounds, up to 1 atm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-65

    VAPOR PRESSURES OF SOLUTIONS Units Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-80Tables

    2-11 Partial Pressures of Water over Aqueous Solutions of HCl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-80

    2-12 Partial Pressures of HCl over Aqueous Solutions of HCl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-80

    Vapor Pressures of H3PO4 Aqueous: Partial Pressure of H2O Vapor (Fig. 2-1) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-81

    Vapor Pressures of H3PO4 Aqueous: Weight of H2Oin Saturated Air (Fig. 2-2) . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-81

    2-13 Partial Pressures of H2O and SO2 over Aqueous Solutions of Sulfur Dioxide . . . . . . . . . . . . . . . . . . . . . . . . . 2-81

    2-14 Water Partial Pressure, bar, over Aqueous Sulfuric Acid Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-82

    2-15 Sulfur Trioxide Partial Pressure, bar, over Aqueous Sulfuric Acid Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-84

    2-16 Sulfuric Acid Partial Pressure, bar, over Aqueous Sulfuric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-86

    2-17 Total Pressure, bar, of Aqueous Sulfuric Acid Solutions . . . . . . 2-872-18 Partial Pressures of HNO3 and H2O over Aqueous

    Solutions of HNO3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-882-19 Partial Pressures of H2O and HBr over Aqueous

    Solutions of HBr at 20 to 55 C . . . . . . . . . . . . . . . . . . . . . . 2-89

    2-1

    Section 2

    Physical and Chemical Data*

    Bruce E. Poling Department of Chemical Engineering, University of Toledo (Physical andChemical Data)

    George H. Thomson AIChE Design Institute for Physical Properties (Physical and Chem-ical Data)

    Daniel G. Friend National Institute of Standards and Technology (Physical and ChemicalData)

    Richard L. Rowley Department of Chemical Engineering, Brigham Young University(Prediction and Correlation of Physical Properties)

    W. Vincent Wilding Department of Chemical Engineering, Brigham Young University(Prediction and Correlation of Physical Properties)

    *Contribution in part of the National Institute of Standards and Technology; not subject to copyright in the United States.

    Copyright 2008, 1997, 1984, 1973, 1963, 1950, 1941, 1934 by The McGraw-Hill Companies, Inc. Click here for terms of use.

  • 2-20 Partial Pressures of HI over Aqueous Solutions of HI at 25 C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-89

    2-21 Vapor Pressures of the System: Water-Sulfuric Acid-Nitric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-89

    2-22 Total Vapor Pressures of Aqueous Solutions of CH3COOH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-89

    Vapor Pressure of Aqueous Diethylene Glycol Solutions (Fig. 2-3) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-89

    2-23 Partial Pressure of H2O over Aqueous Solutions of NH3 (psia) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-90

    2-24 Mole Percentages of H2O over Aqueous Solutions of NH3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-91

    2-25 Partial Pressures of NH3 over Aqueous Solutions of NH3 (psia) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-92

    2-26 Total Vapor Pressures of Aqueous Solutions of NH3 (psia) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-93

    2-27 Partial Pressures of H2O over Aqueous Solutions of Sodium Carbonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-94

    2-28 Partial Pressures of H2O and CH3OH over Aqueous Solutions of Methyl Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . 2-94

    2-29 Partial Pressures of H2O over Aqueous Solutions of Sodium Hydroxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-94

    WATER-VAPOR CONTENT OF GASES

    Chart for Gases at High Pressures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-95Water Content of Air (Fig. 2-4) . . . . . . . . . . . . . . . . . . . . . . . 2-95

    DENSITIES OF PURE SUBSTANCESTables

    2-30 Density (kg/m3) of Saturated Liquid Water from the Triple Point to the Critical Point . . . . . . . . . . . . . . . . . . 2-96

    2-31 Density (kg/m3) of Mercury from 0 to 350C . . . . . . . . . . . . 2-972-32 Densities of Inorganic and Organic Liquids (mol/dm3) . . . . . 2-98

    DENSITIES OF AQUEOUS INORGANIC SOLUTIONS AT 1 ATMUnits and Units Conversions . . . . . . . . . . . . . . . . . . . .