thermal properties of matter

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THERMAL PROPERTIES OF MATTER Specific heat capacity Melting and boiling Evaporation Thermal Expansion of Solids, Liquids and Gases Thermal Properties of Matter

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Specific Heat Capacity Melting and Boiling Evaporation Thermal Expansion of Solids, Liquids and Gases

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Page 1: Thermal Properties of Matter

THERMAL PROPERTIES OF MATTER

Specific heat capacityMelting and boiling

EvaporationThermal Expansion of Solids, Liquids and Gases

Thermal Properties of Matter

Page 2: Thermal Properties of Matter

The internal energy of a body is the combination of the total kinetic energy (due to its motion) and potential energy (due to intermolecular forces) of the molecules in the body.

In Brownian motion, as the temperature is higher smoke particles are more agitated due to increase in the internal energy of the substance and energy is released.

Therefore as temperature rises, there will be an increase in the internal energy of the substance.

Thermal Properties of Matter

Internal Energy

Page 3: Thermal Properties of Matter

In the above figure, the transfer of energy, Q, into the body causes the internal energy to increase by ΔU, and the temperature to rise by Δθ.

The heat capacity, C, of a body is the amount of thermal energy required to raise the temperature of the body by 1 K or 1 C.

Thermal Properties of Matter

Heat Capacity

Q

C

Page 4: Thermal Properties of Matter

1. In a simple experiment, 100 g of water requires 12 600 J of heat to raise it from 30 ⁰C to 60 ⁰C.

a) Find the heat capacity of 100 g of water.b) Find the heat capacity of 1000 g of water.

2. Find the heat needed to raise 1000 g of water from 30 ⁰C to 40 ⁰C.

3. A cup of coffee at 80 ⁰C is left to cool to 30 ⁰C. If the heat capacity of the cup and coffee is 2.0 kJ K-1, how much heat is released during the cooling?

Thermal Properties of Matter

Example

Page 5: Thermal Properties of Matter

4. The temperature of an object increases by 5 ᵒC when it is given 4000 J of energy. The temperature of the object is 30 ᵒC. The object is then given 4800 J of energy. What is the final temperature?

5. When 800 J of energy are given to object A its temperature rises by 8 ᵒC. When 1000 J of energy are given to object B its temperature rises by 12 ᵒC. Explain which object has the larger heat capacity?

Thermal Properties of Matter

Page 6: Thermal Properties of Matter

Heat capacity is a property of a body. It depends on the amount of material

involved. As heat capacity varies with the mass of the

material, therefore we should also considered the heat capacity per unit mass or specific heat capacity of the material.

Thermal Properties of Matter

Specific Heat Capacity

Page 7: Thermal Properties of Matter

The specific heat capacity, c, of a material is defined as the amount of thermal energy required to raise the temperature if a unit mass of the material by 1 K or 1 C.

Thermal Properties of Matter

m

Qc

Page 8: Thermal Properties of Matter

Material Specific Heat Capacity

J kg-1 C-1 J g-1 C-1

Aluminium 900 0.90

Brass 380 0.38

Copper 400 0.40

Glass 670 0.67

Ice 2100 2.10

Iron 460 0.46

Lead 130 0.13

Mercury 140 0.14

Sea water 3900 3.90

Water 4200 4.20

Zinc 390 0.39

Thermal Properties of Matter

Page 9: Thermal Properties of Matter

Conversion of energy◦ Electrical energy from heater transformed to

heat energy.P t = m c

◦ Potential energy of falling object transformed to heat energy.

m g h = m c

◦ Kinetic energy of a moving object transformed into heat energy when it is stop due to friction.

½ m v 2 = m c

Thermal Properties of Matter

Page 10: Thermal Properties of Matter

1. A domestic hot water tank contains 200 kg of water at 20 C. How much energy must be supplied to heat this water to 70 C? The specific heat capacity of water is 4200 J/(kgC).

2. A copper block weighing 2 kg is dropped from a height of 20 m. What is the rise in temperature of the copper block after it hits the floor. The specific heat capacity of copper is 400 J/(kgC).

3. Calculate the specific heat capacity of a new alloy if a 15.4 g sample absorbs 393 J when it is heated from 0.0 ⁰C to 37.6 ⁰C.

4. How much energy is needed to heat 100 g of water from 10 ⁰C to 30 ⁰C?

Thermal Properties of Matter

Example

Page 11: Thermal Properties of Matter

5. A 2 kg block of iron is given 10 kJ of energy and its temperature rises by 10 ⁰C. What is the specific heat capacity of iron?

6. A 700 W electric heater is used to heat 2 kg of water for 10 minutes. Calculate the temperature rise of the water. The specific heat capacity of water is 4200 J/(kgC).

7. A bullet traveling at 60 m/s hit a sand bag. The temperature of the bullet rises by 4.5 C. Calculate the specific heat capacity of the bullet.

8. A 1000 W heater supplies energy for 100 s to a 2 kg metal containing 1 kg of water. The temperature rises by 20 ⁰C. Calculate the specific heat capacity of the metal.

Thermal Properties of Matter

Page 12: Thermal Properties of Matter

9. A 2 kW electric heater supplies energy to a 0.5 kg copper kettle containing 1 kg of water. Calculate the time taken to raise the temperature by 10 ⁰C.

10. A 210 W heater is placed in 2 kg of water and switched on for 200 seconds. The specific heat capacity of water is 4200 J/(kgC).

a. How much energy does the heater supply?b. Assuming that no thermal energy is lost, what is

the temperature rise of the water?

Thermal Properties of Matter

Page 13: Thermal Properties of Matter

Material has a high specific heat

capacity

Material has a low specific heat

capacityIt takes a longer time

to be heated.It becomes hot very

quickly.

It does not lose heat easily. It lose heat easily.

It is a heat insulator. It is a good heat conductor.

Smaller rise in temperature

Greater rise in temperature

Thermal Properties of Matter

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1. What is the definition of heat capacity?A. the quantity of heat required to raise the

temperature of an object through 1 °CB. the quantity of heat required to raise the

temperature of 1 kg of a substance through 1 °CC. the quantity of heat required to convert an

object from solid to liquid without a change in temperature

D. the quantity of heat required to change 1 kg of a substance from solid to liquid without a change in temperature

Thermal Properties of Matter

Page 15: Thermal Properties of Matter

2. Equal masses of two different liquids are put into identical beakers. They are heated from 20 °C to 30 °C by heaters of the same power. Liquid 2 takes twice as long to heat as liquid 1.

Thermal Properties of Matter

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Which statement is correct?A. Both liquids receive the same amount of energy.B. Liquid 1 receives more energy than liquid 2.C. The thermal capacity of liquid 1 is equal to the

thermal capacity of liquid 2.D. The thermal capacity of liquid 1 is less than the

thermal capacity of liquid 2.

Thermal Properties of Matter

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3. A knife is being sharpened on a rotating sharpening-stone. A spark flies off and lands on the operator’s hand. The spark is a very hot, very small piece of metal. The operator feels nothing.

What does this show about the piece of metal?

A. It has a high thermal capacity.B. It has a low thermal capacity.C. It is a good conductor of heat.D. It is a poor conductor of heat.

Thermal Properties of Matter

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4. Four blocks, made of different materials, are each given the same quantity of internal (heat) energy.

Which block has the greatest thermal capacity?

Thermal Properties of Matter

A

Page 19: Thermal Properties of Matter

5. The diagram shows four blocks of steel. The same quantity of heat is given to each block.

6. Which block shows the greatest rise in temperature?

Thermal Properties of Matter

B

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6. 1 kg of water and 1 kg of aluminium are heated to the same temperature and then allowed to cool in a room.

7. Why does the aluminium cool more quickly than the water?

A. Aluminium contracts more than water.B. Aluminium does not evaporate but water does.C. Aluminium has a higher thermal capacity than

water.D. Aluminium has a lower thermal capacity than

water.

Thermal Properties of Matter

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7. The same quantity of heat energy is applied to four different blocks. The temperature rise produced is shown on each block.

Which block has the highest thermal capacity?

Thermal Properties of Matter

A

Page 22: Thermal Properties of Matter

8. In an experiment to find the specific heat capacity of a metal, it is found that 5200 J is needed to raise the temperature of a 2 kg block by 20 °C.

What value for the specific heat capacity is given by these results?

A. 130 J / (kg °C)B. 520 J / (kg °C)C. 52 000 J / (kg °C)D. 104 000 J / (kg °C)

Thermal Properties of Matter

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9. Heat energy is supplied at the same rate to 100 g of paraffin and to 100 g of water in similar containers.

Why does the temperature of the paraffin rise more quickly?

A. The paraffin has a larger specific heat capacity than water.

B. The paraffin has a smaller specific heat capacity than water.

C. The paraffin is less dense than water.D. The paraffin is more dense than water.

Thermal Properties of Matter

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10. A 2 kg mass of copper is heated for 40 s by a heater that produces 100 J/s.

The specific heat capacity of copper is 400 J/(kg K).

What is the rise in temperature?A. 5 KB. 10 KC. 20 KD. 50 K

Thermal Properties of Matter

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Matter exists in three states, that is solid, liquid and gas.

The heat released or absorbed at constant temperature during a change of state of matter is known as latent heat.

Thermal Properties of Matter

Latent Heat

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Latent heat of fusion is the energy needed to change a substance from solid to liquid without a change in temperature.

Latent heat of vaporisation is the energy needed to change a substance from liquid to gas without a change in temperature.

The latent heat or energy needed to change a substance from a solid to liquid or from liquid to gas depends on the mass of the substance.

Thermal Properties of Matter

Latent Heat and Specific Latent Heat

Page 27: Thermal Properties of Matter

The specific latent heat of fusion (lf) of a substance is the amount of energy needed to change a unit mass of the substance from solid to liquid without a change in temperature.

Thermal Properties of Matter

Specific Latent Heat of Fusion

m

Ql f

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The specific latent heat of vaporisation (lv) of a substance is the amount of energy needed to change a unit mass of the substance from liquid to gas without a change in temperature.

Thermal Properties of Matter

Specific Latent Heat of Vaporisation

m

Qlv

Page 29: Thermal Properties of Matter

The SI unit for specific latent heat is J kg-1. Rewriting the equation,

Q = mlThermal Energy = Mass × Specific

Latent Heat

Thermal Properties of Matter

Specific heat capacity of ice 21 00 J kg-1 C-1 2.1 J g-1 C-1

Specific heat capacity of water

4 200 J kg-1 C-1 4.2 J g-1 C-1

Specific latent heat of ice 300 000 J kg-1 300 J g-1

Specific latent heat of steam

2 500 000 J kg-1 2500 J g-1

Page 30: Thermal Properties of Matter

Thermal Properties of Matter

Time (second)

Temperature (°C)

Solid Heating Solid Melting Liquid Heating Liquid Boiling Gas Heating

SOLID

SOLID + LIQUID LIQUID LIQUID + GAS GAS

Latent heat of fusion is absorbed.

The temperature is called meting point.

The particles obtain more kinetic energy and move faster. The temperature keeps

rising.

Latent heat of vaporization is

absorbed.

The temperature is called boiling point.

The particles are now completely free to

move.

Melting completes

Melting begins Boiling begins Boiling completes

Boiling Point

Melting/Freezing Point

HEATING CURVE

The kinetic energy of the particles increases and the particles move fast. The temperature increases when heated

The heat energy is absorbed to break the forces of attraction between the particles. No change in temperature

The heat energy is absorbed to break the forces between liquid particles to become gas. No change in temperature

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Thermal Properties of Matter

Time (second)

Temperature (°C)

Gas Cooling Gas Condensing Liquid Cooling Liquid Freezing Solid Cooling

SOLID

GAS + LIQUID LIQUID LIQUID + SOLID

GASLatent heat of

vaporization is released, intermolecular bond are

formed.The temperature is called boiling point

The particles losing kinetic energy and

increasingly slowing down. The

temperature keeps falling

Latent heat of fusion is released as

intermolecular bonds are formed

The temperature is called freezing point.

.

The temperature decrease

Condensation completes

Condensation begins

Freezing begins Freezing completes

Boiling Point

Melting/Freezing Point

COOLING CURVE

The particles losing kinetic energy and slowing down. The temperature falls when cooled

The forces of attraction gained between the particles. The particles getting closer. No change in temperature

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1. An ice cream has a mass of 150 g. If the specific latent heat of fusion of ice is 300 J/g, find the heat required to melt the ice cream.

2. A heater which supplies heat at a constant rate of 1000 W completely immersed in a 3 kg block of ice at 0 ⁰C. The block of ice takes 1020 s to melt completely. Calculate a value for the specific latent heat of fusion of ice.

3. A beaker containing 0.250 kg of water at 10 ⁰C has a 2.0 kW heater immersed in it. Find the time needed to turn the water completely to steam.

Thermal Properties of Matter

Example

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4. A 460 W water heater is used to boil water. Assuming no thermal energy losses, what mass of steam will it produce in 10 minutes?

5. What is the amount of energy released when 5 g of steam at 100 ⁰C changes to water at 80 ⁰C? [Specific latent heat of vaporisation of steam = 2500 J/g; specific heat capacity of water = 4.2 J/(g.⁰C)]

6. What is the amount of energy required to change 10 g of ice at 0 ⁰C to water at 20 ⁰C? [Specific heat latent heat of fusion of ice = 300 J/g, specific heat capacity of water = 4.2 J/(g.⁰C)]

Thermal Properties of Matter

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1. The diagram shows how the atoms in a substance rearrange themselves during a change of state.

Thermal Properties of Matter

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1. Which change of state is shown?A. gas to liquidB. liquid to gasC. liquid to solidD. solid to liquid

Thermal Properties of Matter

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2. Using an electric kettle, 100 g of water at 100 °C is converted into steam at 100 °C in 300 seconds.

3. The specific latent heat of steam is 2250 J/g.

4. What is the average electrical power used?

Thermal Properties of Matter

B

Page 37: Thermal Properties of Matter

3. When ice melts to become water, which force must be overcome?

A. the attraction between electrons and the nucleus

B. the attraction between the atoms in a moleculeC. the force between moleculesD. the force of gravity

Thermal Properties of Matter

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4. The energy required to change liquid water into water vapour at the same temperature is called latent heat of vaporisation.

5. What does this energy do?A. increases the average separation of the water

moleculesB. increases the average speed of the water

moleculesC. raises the temperature of the air near the waterD. splits the water molecules into their separate

atoms

Thermal Properties of Matter

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5. A 2 kW kettle containing boiling water is placed on a balance. It is left there and continues to boil for 5 minutes. The balance reading changes by 0.2 kg.

6. What does this information give as a value for the specific latent heat of vaporisation of water?

A. 2000 J / kgB. 3000 J / kgC. 50 000 J / kgD. 3 000 000 J / kg

Thermal Properties of Matter

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6. Ice is taken from a freezer and left in a room. The ice melts and eventually the water reaches room temperature.

7. Which energy transfers take place?

Thermal Properties of Matter

C

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7. What is the name given to the amount of energy needed to turn 1 kg of water at 100 °C into steam at 100 °C?

A. heat capacityB. latent heatC. specific heat capacityD. specific latent heat

Thermal Properties of Matter

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8. The table lists the melting points and the boiling points of four different substances A, B, C and D.

9. Which substance is a gas at 25 °C?

Thermal Properties of Matter

A

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9. A block of ice is heated until it has all melted. The water that is produced is then heated until it boils.

10. Which line in the table states what happens to the temperature of the ice while it is melting, and to the temperature of the water while it is boiling?

Thermal Properties of Matter

D

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10. Which substance is a liquid at a room temperature of 25 °C?

Thermal Properties of Matter

B

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11. A substance that is originally a solid is heated strongly for some time.

12. At one stage, the energy given to the substance is used as latent heat of vaporisation.

13. At this stage, what change does the energy cause?A. It breaks the bonds holding the molecules together.

Molecules escape from the liquid.B. It breaks the bonds holding the molecules together. The

solid becomes liquid.C. It makes the molecules move faster but there is still a

strong attraction between them.D. It makes the molecules move faster and so the

temperature rises.

Thermal Properties of Matter

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Thermal Properties of Matter

Melting, Boiling & Evaporation

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Melting is the process whereby energy supplied changes the state of a substance from a solid state to a liquid state, without a change in temperature.

This temperature is called the melting point of the substance. For a pure substance, melting occurs at a definite temperature.

The energy that is absorbed without a change in temperature is termed latent heat of fusion (melting) of the substance.

Thermal Properties of Matter

Melting & Freezing

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The reverse process of changing from liquid to solid is called freezing.

A pure substance will freeze at a temperature equal to its melting point.

When a liquid freezes, latent heat of fusion is released without any change in its temperature.

Thermal Properties of Matter

Substance Melting Point / CMercury -39

Ice 0

Gold 1063

Copper 1083

Glass 1127

Iron 1535

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Boiling is process whereby energy supplied changes the state of a substance from liquid state to gaseous state without a change in temperature.

The temperature at this change of state is called boiling point of the substance.

For a pure substance, boiling occurs at a definite temperature.

The energy gained without any rise in temperature when liquid boils is called the latent heat of vaporisation.

Thermal Properties of Matter

Boiling & Condensation

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Thermal Properties of Matter

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The reverse process of changing a gas to a liquid is called condensation.

The same substance in its gaseous state will condense at the same temperature known as the condensation point.

When steam condenses, it releases its latent heat of vaporisation.

Thermal Properties of Matter

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Boiling and evaporation involve a change in state from liquid to gas.

A liquid boils at a definite temperature called boiling point whereas evaporation occurs at all temperature.

Evaporation takes place only from the exposed surface of the liquid, while boiling occurs throughout the body of the liquid.

Thermal Properties of Matter

Evaporation and Boiling

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Thermal Properties of Matter

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The similarity between boiling and evaporation lies in the fact that in both process, liquid is changed to gas and latent heat of vaporisation is needed.

During evaporation, the energy required is absorbed from the environment resulting in cooling (cooling by evaporation)

Thermal Properties of Matter

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1. Temperature – the higher the temperature of the liquid, the higher the average kinetic energy of the molecules.

2. Area of the exposed surface – when the exposed area is large, the liquid molecules have more opportunities to leave the surface of the liquid.

3. Humidity of the surrounding air – if the humidity is high, there is a lot of water vapour in the air and liquid vapourisation is suppressed.

Thermal Properties of Matter

Factor Affecting the Rate of Evaporation

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4. Motion of air – the motion of the air carries away the water vapour formed by evaporation.

5. Pressure – the lower the external pressure, the higher the rate of evaporation.

6. Nature of liquids – under similar conditions, a liquid with a low boiling point evaporates more rapidly.

Thermal Properties of Matter

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Thermal Properties of Matter

Cooling by Evaporation

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The molecules of liquid are in continuous motion.

They move at different speeds and the average kinetic energy of the molecules increases with temperature.

The escape of a faster moving molecules leaves behind molecules having lower speeds.

As average speed decreases, the average kinetic energy of the molecules remained in the liquid also decrease.

Therefore the temperature of the liquid falls.

Thermal Properties of Matter

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1. The graph shows the cooling curve of a hot substance.

Thermal Properties of Matter

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1. In which part of the curve is latent heat released?

A. PQB. QRC. RSD. ST

Thermal Properties of Matter

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2. A substance is heated in an enclosed space until it becomes a gas.

3. After the heater is removed, the temperature is recorded at regular intervals. The graph shows temperature plotted against time.

Thermal Properties of Matter

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Thermal Properties of Matter

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1. What does the section PQ represent?A. boilingB. condensingC. meltingD. solidifying

Thermal Properties of Matter

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3. Some ice cubes are taken from a deep-freeze and placed in a metal container. The container is heated at a constant rate and readings of temperature and time are taken. The results are recorded on a graph.

Thermal Properties of Matter

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Thermal Properties of Matter

C

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4. Ice at –10 °C is heated at a constant rate until it is water at +10 °C.

5. Which graph shows how the temperature changes with time?

Thermal Properties of Matter

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Thermal Properties of Matter

B

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5. Equal masses of two different liquids are heated using the same heater. The graph shows how the temperature of each liquid changes with time.

Thermal Properties of Matter

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1. What does the graph tell us about the liquids?

A. Liquid 1 has a higher melting point than liquid 2.B. Liquid 1 has a higher boiling point than liquid 2.C. Liquid 1 starts to melt sooner than liquid 2.D. Liquid 1 starts to boil sooner than liquid 2.

Thermal Properties of Matter

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6. A block of ice is heated at a constant rate. Eventually the melted ice boils.

7. The graph shows how the temperature changes with time.

Thermal Properties of Matter

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1. How many minutes did it take to melt all the ice?

A. 4B. 7C. 11D. 13

Thermal Properties of Matter

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7. A sample of a solid is heated for 12 minutes and its temperature noted every minute.

8. The results are shown in the table.

Thermal Properties of Matter

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1. How should the sample be described at the end of the 12 minutes?

A. all solidB. in the process of meltingC. all liquidD. in the process of boiling

Thermal Properties of Matter

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8. The graph shows how the temperature of hot liquid wax changes with time as the wax is allowed to cool.

9. At which labelled point on the graph are both liquid wax and solid wax present?

Thermal Properties of Matter

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Thermal Properties of Matter

B

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9. The graph shows the change in temperature of a material as it is heated.

10. Which part on the graph shows when the material is boiling?

Thermal Properties of Matter

D

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10. A substance is heated at a steady rate. It changes from a solid to a liquid, and then to a gas.

11. The graph shows how its temperature changes with time.

Thermal Properties of Matter

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1. Which parts of the graph show a change of state taking place?

A. P and RB. P and SC. Q and RD. Q and S

Thermal Properties of Matter

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11. The graph shows the change in temperature of a substance as it is heated steadily.

12. Which part of the graph shows when the substance is boiling?

Thermal Properties of Matter

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12. Which factors increase the rate of evaporation of a liquid?

Thermal Properties of Matter

B

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13. On a hot day, a drink in a bottle can be kept cool by standing it in a bowl of water and placing a wet cloth over it.

Thermal Properties of Matter

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1. Why is the drink kept cool?A. Hot air cannot escape from the bottle.B. The cloth conducts heat from the bottle into the

water.C. The drink cannot evaporate from the bottle.D. Water evaporating from the cloth cools the

drink.

Thermal Properties of Matter

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14. What will not affect the rate of evaporation from the surface of a liquid?

A. depth of the liquidB. draughts above the surface of the liquidC. surface area of the liquidD. temperature of the liquid

Thermal Properties of Matter

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15. A hot liquid is carefully poured into a beaker. The graph shows how its temperature changes as it cools towards room temperature.

Thermal Properties of Matter

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1. Which processes are taking place at region X?

A. boiling and evaporationB. condensation onlyC. evaporation onlyD. solidification and evaporation

Thermal Properties of Matter

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16. The diagram shows a cross-section through a rain-water puddle formed in a shallow hole in a road surface.

Thermal Properties of Matter

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1. Over a period of time, air temperature, wind speed and wind direction remain constant.

2. What happens to the rate of evaporation of water from the puddle?

A. It decreases, because the surface area decreases.

B. It increases, because the puddle gets shallower.C. It increases, because the surface area

decreases.D. It remains constant.

Thermal Properties of Matter

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17. A liquid evaporates rapidly.18. Why does it cool?

A. Air molecules remove heat by contact with the liquid surface.

B. Energy is lost by convection currents.C. Fewer molecules are left in the liquid.D. Some of the most energetic molecules leave the

liquid.

Thermal Properties of Matter

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18. A student is investigating the evaporation of water.

19. The student can change:◦ the depth of the water;◦ the surface area of the water;◦ the temperature of the water.

Thermal Properties of Matter

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1. How many of these changes, if any, would alter the rate at which evaporation occurs?

A. 0B. 1C. 2D. 3

Thermal Properties of Matter

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19. Some of the more energetic molecules in a liquid leave the surface, leaving the rest of the liquid slightly cooler.

20. What is the name given to this process?A. boilingB. condensationC. evaporationD. freezing

Thermal Properties of Matter

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20. A swimmer climbs out of a swimming pool on a warm, dry day. Almost immediately he begins to feel cold.

21. Why is this?A. The water allows a convection current to remove

heat from his skin.B. The water takes latent heat from his body in

order to evaporate.C. The water on his skin is a good conductor of heat.D. The water prevents infra-red radiation from

reaching his body.

Thermal Properties of Matter

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21. A beaker of liquid is placed under a bell jar. The pressure of the air above the liquid is reduced and some of the liquid evaporates. This causes the liquid to become colder.

Thermal Properties of Matter

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Thermal Properties of Matter

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1. Why does the temperature of the liquid fall?

A. The air molecules blow away the liquid molecules.

B. The air molecules cool down the liquid.C. The higher energy molecules leave the liquid.D. There are fewer molecules of liquid in the

beaker.

Thermal Properties of Matter

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22. A cup with a lid contains a hot drink.

Thermal Properties of Matter

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1. When the lid is removed, the rate of heat loss from the drink increases.

2. What causes this?A. convection onlyB. evaporation onlyC. both convection and evaporationD. neither convection nor evaporation

Thermal Properties of Matter

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23. Water spilled on the ground on a hot day evaporates.

24. Which diagram represents the change in arrangement of the particles in the water as it evaporates?

Thermal Properties of Matter

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Thermal Properties of Matter

C

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24. A drop of liquid falls on a student’s skin and quickly evaporates.

25. What is the effect on the skin and the reason?

A. The skin cools because the most energetic molecules escape from the liquid.

B. The skin cools because the most energetic molecules remain in the liquid.

C. The skin warms because the most energetic molecules escape from the liquid.

D. The skin warms because the most energetic molecules remain in the liquid.

Thermal Properties of Matter

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25. Some water molecules escape from the surface of a lake.

26. Which name is given to this process?A. boilingB. convectionC. evaporationD. radiation

Thermal Properties of Matter

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26. The diagrams show four identical cans with their outside surfaces painted either dull black or polished silver. Each can contains the same volume of water, initially at 80 °C.

27. After five minutes in a cool room, which can contains the coolest water?

Thermal Properties of Matter

A

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27. In an experiment, some of a substance changes from a liquid to a gas. The temperature of the remaining liquid changes because of this.

28. What is the name for this change of state and how does the temperature change?

Thermal Properties of Matter

C

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Matter in general expands when heated. When a solid is heated, its molecules vibrate

faster about their fixed positions. As a result of this, the molecules move slightly

further apart than when they are cold. The cumulative effect of all the molecules result

in the volume expansion. The amount of expansion depends largely on the

intermolecular forces holding the molecules together.

The stronger the intermolecular force the least the expansion.

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Thermal Expansion

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Ball and Ring Experiment

• A metal ball that just slips through a metal ring is heated.

• The ball expands and can no longer pass through the ring.

• When cooled the ball contracts and passes through the ring.

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Disadvantages in Expansion of solids

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Application of Thermal Expansion

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Different metal expand unequally when heated to the same temperature.

Metal A is iron while metal B is a brass. When heated it is found to curve in such away

that brass expand more than iron does

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Bimetallic Strip

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A Simple Fire Alarm

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A Thermostat

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All liquid expand on heating and contract on cooling.

Immediately the level of water drops as the flask expands first.

Afterwards water level rises ad goes beyond the original level A.

This shows that◦ Water expand on heating◦ Expansion of water is more than that

of glass.

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Expansion of Liquids

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Like solids, different liquids expand unequally.

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Unlike solids and liquids, all gases expand equally.

The expansion of a gas is much greater than that of solid or a liquid.

A gas expands of its volume at 0 C for every C rise in temperature.

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Expansion of Gases

273

1

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Gases• ~ 30 times of liquid

Liquids• ~ 20 times of solid solid

Very Stron

g

StrongWeak

Expansion

Intermolecular forces

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1. What happens when a metal bar is heated?

A. The distance between the molecules increases, making the bar longer.

B. The molecules get larger, making the bar longer.C. The molecules vibrate more quickly, making the

bar denser.D. The speed of the molecules increases, making

the bar thinner.

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2. A long thin bar of copper is heated evenly along its length.

What happens to the bar?A. It becomes lighter.B. It becomes longer.C. It becomes shorter.D. It bends at the ends.

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3. A glass jug is designed so that it does not break when boiling water is poured into it.

What sort of glass should be used?

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D

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4. An engineer wants to fix a steel washer on to a steel rod. The rod is just too big to fit into the hole of the washer.

How can the engineer fit the washer onto the rod?

A. cool the washer and put it over the rodB. cool the washer and rod to the same

temperature and push them togetherC. heat the rod and then place it in the holeD. heat the washer and place it over the rod

Thermal Properties of Matter

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5. A person cannot unscrew the lid of a pot of jam. He finds that the lid can be unscrewed after it has been held under hot, running water for a few seconds.

Why is this?A. The air pressure in the jar falls.B. The glass expands.C. The jam melts.D. The lid expands.

Thermal Properties of Matter

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6. The fillings for a hole in a tooth should be made from a material that

A. expands more than the hole in the tooth.B. expands by the same amount as the hole in the

tooth.C. expands less than the hole in the tooth.D. does not expand when heated.

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7. The diagrams show a bimetallic strip when it is at room temperature and after it has been cooled.

The change in shape occurs becauseA. brass contracts more than invar.B. brass expands when it cools down.C. invar and brass contract by equal amounts.D. invar contracts more than brass.

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8. A wooden wheel can be strengthened by putting a tight circle of iron around it.

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A. Which action would make it easier to fit the circle over the wood?

A. cooling the iron circleB. heating the iron circleC. heating the wooden wheelD. heating the wooden wheel and cooling the iron

circle

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9. At regular intervals along a railway line there is a gap between the rail sections.

Thermal Properties of Matter

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1. What is the reason for the gap between the rail sections?

A. to allow for expansion of the rail sections during hot weather

B. to allow for vibrations of the rail sections as the train passes over them

C. to allow rain water to drain from the rail sectionsD. to keep the wheels of the train and carriages on

the rail sections

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10. A glass flask full of cool water is placed in a container of hot water.

What will happen to the level of water at X as the cool water becomes warmer?

A. It will fall.B. It will rise.C. It will rise then fall.D. It will stay the same.

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11. The diagram shows the design for an alarm.

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1. The mercury pellet moves and completes the circuit.

2. Why does this happen?

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D

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12. The table shows the increase in length of four metals when heated through the same temperature rise. Each metal initially has the same length.

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1. A bimetallic strip is made from two of the metals. When heated, it bends in the direction shown.

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1. Which metals produce the above effect?

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A

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Learning Outcomes

Thermal Properties of Matter

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Describe a rise in temperature of a body in terms of an increase in its internal energy (random thermal energy).

Define the terms heat capacity and specific heat capacity.

Calculate heat transferred using the formula thermal energy = mass x specific heat capacity x change in temperature.

Thermal Properties of Matter

Specific heat capacity

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Describe melting/solidification and boiling /condensation in terms of energy transfer without a change in temperature.

State the meaning of melting point and boiling point. Explain the difference between boiling and

evaporation. Define the terms latent heat and specific latent heat. Explain latent heat in terms of molecular behaviour. Calculate heat transferred in a change of state using

the formula thermal energy = mass x specific latent heat.

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Melting and boiling

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Evaporation Describe evaporation in terms of the escape

of more energetic molecules from the surface of a liquid.

Describe how temperature, surface area and draught over a surface influence evaporation.

Explain that evaporation causes cooling.

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Describe qualitatively the thermal expansion of solids, liquids and gases.

Describe the relative order of magnitude of the expansion of solids, liquids and gases.

List and explain some of the everyday applications and consequences of thermal expansion.

Describe qualitatively the effect of a change of temperature on the volume of a gas at constant pressure.

Thermal Properties of Matter

Thermal expansion of solids, liquids and gases