the world of materials linking physics and chemistry to engineering

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20-Jan- 2010 electrical, computer and energy engineering Prof. Subramaniam (“Subby”) D. Rajan, Prof. Narayanan Neithalath and Amie Baisley Graduate Students: Kirk Vance, Matt Aguayo, Joseph Harrington and Canio Hoffarth The World of Materials Linking Physics and Chemistry to Engineering

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The World of Materials Linking Physics and Chemistry to Engineering. Prof. Subramaniam (“Subby”) D. Rajan, Prof. Narayanan Neithalath and Amie Baisley Graduate Students : Kirk Vance, Matt Aguayo, Joseph Harrington and Canio Hoffarth. Structural Materials. - PowerPoint PPT Presentation

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Page 1: The World of Materials Linking Physics and Chemistry to Engineering

20-Jan-2010 electrical, computer and energy engineering

Prof. Subramaniam (“Subby”) D. Rajan, Prof. Narayanan Neithalath and Amie Baisley

Graduate Students: Kirk Vance, Matt Aguayo, Joseph Harrington and Canio Hoffarth

The World of MaterialsLinking Physics and Chemistry to Engineering

Page 2: The World of Materials Linking Physics and Chemistry to Engineering

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Structural Materialsn Concrete (Plain, Reinforced, Prestressed)n Metals (Steel, Aluminum)n Timber/Woodn Masonry

Reinforced concrete

Steel beams and columns

Concrete masonry blocks

Wood beams and columns

Page 3: The World of Materials Linking Physics and Chemistry to Engineering

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What are all Materials made of? n Fundamental chemistry – all materials are basically comprised of

elements/molecules, which are comprised of atomsn Investigate the periodic table.

Page 4: The World of Materials Linking Physics and Chemistry to Engineering

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Focus of this activityn There are a number of building materials. However this activity

will focus on CONCRETE.

Page 5: The World of Materials Linking Physics and Chemistry to Engineering

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What is CONCRETE? n From the Latin word “Concretus”n Means : To hold together or grow togethern It is a “Formable Rock”n A composite material – Binder(s) + Filler(s)

Page 7: The World of Materials Linking Physics and Chemistry to Engineering

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Scale of Concrete Use• Present consumption

of concrete of the order of 12 billion tons every year

• Humans consume no material except water in such tremendous quantities

Page 8: The World of Materials Linking Physics and Chemistry to Engineering

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Hoover Damn The dam overall weighs

6.6 million tonsn Took 3.25 million cubic

yards of concrete– Enough to lay a 4 foot wide

sidewalk around the earth

Page 9: The World of Materials Linking Physics and Chemistry to Engineering

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Ingredients of Concreten Cementn Watern Fine Aggregaten Coarse Aggregaten Many chemicals for

specific functions

Page 10: The World of Materials Linking Physics and Chemistry to Engineering

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Proportions - Range

Page 11: The World of Materials Linking Physics and Chemistry to Engineering

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What is CEMENT?n A fine powder, when mixed

with water, reacts with it, to form a glue that binds the aggregates together

n The heart and soul of concrete

n An old material, but “modern”

n Cement is to concrete, what flour is to bread….

Page 12: The World of Materials Linking Physics and Chemistry to Engineering

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Basic Constituents of Cementn Calciumn Silican Aluminan Iron

– Their oxides are present – see the table

Page 13: The World of Materials Linking Physics and Chemistry to Engineering

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A Typical Cement Plant

Page 14: The World of Materials Linking Physics and Chemistry to Engineering

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Other Constituentsn Cement production is environmentally sensitive

– Takes large amounts of energy– Releases a large amount of CO2 into the atmosphere

– GLOBAL WARMING - ???n Several waste materials from other sources used in concrete

– Fly ash, slag etc. (look at the table in Slide 11 for their composition too)– They serve several functions in concrete

n Chemical ingredients are also used to enhance concrete properties

Page 15: The World of Materials Linking Physics and Chemistry to Engineering

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Tailoring the Material

Page 16: The World of Materials Linking Physics and Chemistry to Engineering

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Aggregate Production• These are the rocks used to make concrete• In order to meet large volumes and ensure better properties, we need aggregates

Page 17: The World of Materials Linking Physics and Chemistry to Engineering

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Grading of Aggregates

Carefully notice the different sizes that are used

Page 18: The World of Materials Linking Physics and Chemistry to Engineering

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Why should we worry about Grading ? n What happens when you add

smaller and smaller balls into the given volume?

n Can you see voids reducing?n Voids (or holes) are bad for

concreten When there are more voids, the

strength is lower and the material is susceptible to more damage

n Thus we need to “pack” the materials better in a volume

Page 19: The World of Materials Linking Physics and Chemistry to Engineering

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Mixing – Ready Mixed Concreten Central mixed concrete –

Stationary mixed– Mixed completely in a stationary

mixer– Delivered in

– A truck agitator– Non agitating truck– Truck mixer operating at

agitating speed

Page 20: The World of Materials Linking Physics and Chemistry to Engineering

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Placing concrete in a bridge

Page 21: The World of Materials Linking Physics and Chemistry to Engineering

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What is important in placing concrete?

n It should flow welln You should be able to spread it evenly and consolidate so that it

provides a dense and strong material

Page 22: The World of Materials Linking Physics and Chemistry to Engineering

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Methods to enhance flow and control setting

n Special chemicals to enhance flow, yet keep the cement paste and rocks together– Called Superplasticizers

n Set controlling chemicals– How to speed up reactions in cold

climate?– Use an Accelerator (Calcium

chloride)– How to slow down reactions in hot

weather? – Use a retarder (Sugar)

Page 23: The World of Materials Linking Physics and Chemistry to Engineering

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Then……Cement reacts with watern And keeps on reacting as it ages…

n See how the black spaces (pores) are being filled in with yellow regions (reaction products) which are the result of the reaction of cement (red and blue particles)

Page 24: The World of Materials Linking Physics and Chemistry to Engineering

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Cement’s love for watern Reaction of cement with water is called Hydrationn Reaction of cement with water produces heat

n This is an exothermic reaction

http://chemistry.about.com/cs/generalchemistry/a/aa051903a.htm

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And then?

n After casting the concrete in the bridge, you need to take care of it by providing nourishment for it to strengthen

n Water is its nutrient

Curing – providing water for chemical reactions to proceed Concrete is hard and strong to

carry load

14-28 days

Page 26: The World of Materials Linking Physics and Chemistry to Engineering

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How do you test concrete? n Concrete is strong in compression – it can

take a large load when crushed. n Strength = Load taken to fail the material

divided by the area of cross section.n You have a circular cross section for the

cylinder shown. n Units of strength is pounds per square

inch (pounds of load needed to break divided by the number of square inches of cross sectional area)

Page 27: The World of Materials Linking Physics and Chemistry to Engineering

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How do you test concrete? n For a bridge, concrete is under

bending loadn The response is different when

the concrete is tested alone, or when it has steel “reinforcement” in it.

n Concrete is a brittle material and steel makes it ductile– See next slide to know the

difference

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Brittle and Ductile Materialsn Brittle and Ductile Property – Key to engineering / structural

materials– Brittle materials do not deform (bend, as an example) much before it fails.

Thus it is not desirable for structural applications such as in bridges. Examples of brittle materials include glass, cast iron etc.

– Ductile materials deform significantly before failure. This is the most desirable set of materials for structural applications because they give you warning before failure in the form of deflections. Steel is a very good example

– Since many common and cheaper materials are generally brittle, we can combine them with a ductile material (e.g.: steel + concrete) to make the “composite material” somewhat ductile.

http://www.youtube.com/watch?v=0NSG4WSRxmg

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Questions – Level 1n Q1: Materials in general applications

– (a) What are all the elements in nature made of (fundamental building blocks)?

– (b) What is the most abundant element in the earth’s crust? – (c) In the periodic table, you have metals and nonmetals. Enumerate the

key structural and physical differences between them. n Q2: Cement and Concrete

– (a) Distinguish between cement and concrete.– (b) What are the ingredients of concrete?– (c) Name three items you have encountered today which are concrete.– (d) How much concrete was used in Hoover Dam? – (e) What is an exothermic and an endothermic reaction? Give examples.

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Questions – Level 1n Q3: Why is concrete important?

– (a) Enumerate one very critical use of concrete that no other material can satisfy.

– (b) Can you think of an application for concrete for the future (i.e., it is not used now, but can be used later)?

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Questions – Level 2n Q4: Why is packing of different concrete

ingredients important? – (a) The square boxes are 50 mm in size, the black

circles are 10 mm in diameter, red circles are 5 mm in diameter and blue circles are 1 mm in diameter. What is the percentage increase in the filling efficiency of the second square when red and blue balls are used in addition to black balls?

– (b) In concrete, what does black, red, and blue balls stand for?

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Questions – Level 2n Q5: We will build on the concepts learned on Day 1 – Enumerate

on why you chose the materials you chose to build the bridge. Think about both the concepts of ductility/brittleness and strength.– Cardboard as the bridge slab – what would have happened if you used a

piece of glass? – Wooden columns – could you have used something else?– Suspension wires – would spaghetti work?

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Research and Write on a Concrete Structure

n Prepare a 2-page technical document on a well known concrete structure (use internet to choose the structure)– Introduction on what the structure is.– Location, application– What makes it unique/famous/innovative?– Who designed and built it?– What type of concrete and how much was used?– Estimated construction cost– Your assessment of what attracted you most to this structure.– Illustrate your report with photographs, drawings, tables etc.